172527

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172527 Rev A UTC Aerospace Systems Safety Data Sheet Material Name: POWEREX and Nitrogen * * * Section 1 - Identification of the Substance/Preparation and of the Company/Undertaking* * * Product Use: Fire Extinguishing Manufacturer Information UTC Aerospace Systems 4200 Airport Drive, NW Wilson, NC 27896 Phone: 252-237-7004 Emergency #: 1-800-451-8346 (3E Company) Site Code: 333067 Use of the Substance/Preparation: Fire Extinguisher Substance Registration Number(s): None identified. * * * Hazards Identification * * * Substance/Preparation Classification Not hazardous according to EC Directives 67/548/EEC and 1999/45/EC. Human and Environmental Hazards WARNING CONTENTS UNDER PRESSURE. The pressurized release of this product can cause injury or death. Pressurized container may explode when exposed to heat or flame. Contains nitrogen which, if released in a confined space, will displace oxygen and act as an asphyxiant. Medical Conditions Aggravated by Exposure Existing eye or skin sensitivity may be aggravated by exposure. Environmental Effects Surfactants can cause foaming problems in water. Foam may cause high BOD load in aquatic environments. * * * Section 3 - Composition/Information on Ingredients * * * EC # 213-631-3 231-791-2 231-783-9 Component Propanoic acid, 2-hydroxy-, monopotassium salt 996-31-6 Water 7732-18-5 Nitrogen 7727-37-9 Percent 49.8 Symbols - Risks - 48.6 - - 0.01 - - Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Potassium lactate (31981-04-1). Component Information/Information on Non-Hazardous Components This product has been evaluated according to EC directives 67/548/EC or 1999/45/EC as amended. Substance Registration Number(s): None identified. * * * Section 4 - First Aid Measures * * * First Aid: Eyes Immediately flush eyes with large amounts of water, including under the eyelids, for 15-30 minutes. Obtain medical attention. Page 1 of 7 172527 Rev A UTC Aerospace Systems Safety Data Sheet Material Name: POWEREX and Nitrogen First Aid: Skin If frostbite or freezing occurs, immediately flush with plenty of lukewarm water (105-115°F; 41-46°C) for at least 15 minutes. Do not use hot water. Get medical attention. In case of contact with foam, immediately flush skin with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash contaminated clothing before re-use. If irritation occurs, obtain medical attention. First Aid: Ingestion Do not induce vomiting. If a large amount is swallowed, get immediate medical attention. First Aid: Inhalation Remove the affected person immediately to fresh air. * * * Section 5 - Fire-Fighting Measures * * * General Fire Hazards This material is not flammable, however it is contained in a pressurized container which may explode if exposed to heat or flames. Hazardous Combustion Products Oxides of Carbon Suitable Extinguishing Media This product is a fire extinguisher. Use media appropriate for the surrounding materials. This product produces foam when mixed with water. Unsuitable Extinguishing Media None known. Fire Fighting Equipment/Instructions Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Use water to cool fire-exposed containers and to protect personnel. * * * Section 6 - Accidental Release Measures * * * Containment Procedures Stop flow if possible. Use appropriate protective equipment during clean up. For small volume releases, collect spilled concentrate with absorbent material; place in approved container. For large volume releases, contain and collect for use where possible. Do not allow to enter waterways or sewers. Clean-Up Procedures Stop the flow of material. Block any potential routes to water systems. Contain the discharged material. Evacuation Procedures Persons not wearing appropriate protective equipment should be excluded from area of spill until clean-up has been completed. Personal Precautions Review FIRE FIGHTING MEASURES and HANDLING (Personnel) sections before proceeding with clean-up. Use appropriate protective equipment during clean-up. Environmental Precautions Do not allow product to enter sewer or waterways. Special Measures Regulations vary. Consult local authorities before disposal. * * * Section 7 - Handling and Storage * * * Handling Procedures Avoid contact with eyes or skin. Inspect extinguisher to insure container integrity. Do not drag, slide or roll extinguishers. Do not drop extinguishers or permit them to strike against each other. Do not mix with other extinguishing agents. Review HAZARDS and FIRST AID sections. Storage Procedures Store in accordance with all current regulations and standards. Pressurized extinguishers should be properly stored and secured to prevent falling or being knocked over. Never apply flame or localized heat to any part of the extinguisher. Store pressurized extinguishers away from high heat sources. Storage area should be cool, dry, well-ventilated and under cover out of direct sunlight. Specific Use Fire extinguisher Page 2 of 7 172527 Rev A UTC Aerospace Systems Safety Data Sheet Material Name: POWEREX and Nitrogen * * * Section 8 - Exposure Controls / Personal Protection * * * Substance Exposure Limits Nitrogen (231-783-9) Ireland: Portugal: Asphyxiant Simple Asphyxiant Occupational Exposure Controls Ventilation should effectively remove and prevent buildup of any vapors generated from the use and discharge of this product. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Safety glasses, face shield or chemical splash goggles must be worn when possibility exists for eye contact. Contact lenses should not be worn. Eye wash facilities are recommended. Personal Protective Equipment: Skin Protective clothing such as long sleeves is recommended if excessive contact or splashing is likely to occur. Personal Protective Equipment: Hands Not normally needed when used as a portable fire extinguisher. Impervious gloves are recommended if excessive contact or splashing is likely to occur. Personal Protective Equipment: Respiratory None required where adequate ventilation conditions exist. If airborne concentrations are above the applicable exposure limits, use approved respiratory protection. The need for respiratory protection should be evaluated by a qualified health specialist. Personal Protective Equipment: General Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet facilities. Promptly remove soiled clothing and wash thoroughly before re-use. Environmental Exposure Controls Do not allow to enter waterways or sewers. * * * Section 9 - Physical and Chemical Properties * * * Appearance: Physical State: Vapor Pressure: Boiling Point: Solubility (H2O): Auto Ignition: Flash Point Method: UFL: Particle Size: Discharges as foam Aqueous solution and gas under pressure Not applicable. Not applicable. 100% Not applicable. Not applicable. Not applicable. Not applicable. Odor: pH: Vapor Density: Melting Point: Specific Gravity: Flash Point: LFL: Freezing Point: Evaporation Rate: Slight 8 Not applicable. Not applicable. 1.32 at 25° C (liquid) Not flammable. Not applicable. Not applicable. <1 (liquid) (butyl acetate=1) * * * Section 10 - Stability and Reactivity * * * Chemical Stability Stable under normal conditions. Conditions to Avoid Avoid temperature conditions above 392°F (200°C). Avoid use of product on burning metals, electricallyenergized equipment and contact with water reactive materials. Materials to Avoid Avoid contact with water reactive materials, burning metals and electrically energized equipment. Hazardous Decomposition Products Oxides of Carbon Hazardous Polymerization Will not occur. Page 3 of 7 172527 Rev A UTC Aerospace Systems Safety Data Sheet Material Name: POWEREX and Nitrogen * * * Section 11 - Toxicological Information * * * Acute Toxicity A: General Product Information Compressed gases, when discharged directly into eyes or onto skin, can produce frostbite. Contact with the foam may cause eye and skin irritation. This product has not been tested as a whole for acute oral and inhalation toxicity, primary eye irritation, or primary skin irritation. B: Component Analysis - LD50/LC50 None available. Repeated Dose Toxicity Repeated or prolonged skin contact with foam may lead to dryness, irritation and dermatitis. Foam can remove oils from the skin. Skin Effects Direct, sustained release onto the skin may cause frostbite. Contact with foam may cause moderate irritation or dermatitis due to removal of oils from the skin. Eye Effects Direct release into the eyes may cause frostbite. Contact with the foam will cause irritation. Ingestion Effects Ingestion of the foam may cause mild gastrointestinal irritation. Inhalation Effects Inhalation may cause mild respiratory irritation. This product contains nitrogen under pressure, which when discharged, may displace oxygen and act as an asphyxiant. Carcinogenicity A: General Product Information No information available for the product. B: Substance Carcinogenicity None of the substances in this preparation are listed by IARC, Austria, Belgium, Denmark, France, Germany, Ireland, Luxembourg, Netherlands, Spain, or United Kingdom. Mutagenicity No information available for the product. Reproductive Effects No information available for the product. * * * Section 12 - Ecological Information * * * Ecotoxicity A: General Product Information Surfactants can cause foaming problems in water. Foam is expected to cause high BOD load in aquatic environments. B: Component Analysis - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for this product's components. Mobility No information available for the product. Persistence & Degradation No information available for the product. Bioaccumulative Potential No information available for the product. Other Adverse Effects No information available for the product. Page 4 of 7 172527 Rev A UTC Aerospace Systems Safety Data Sheet Material Name: POWEREX and Nitrogen * * * Section 13 - Disposal Considerations * * * Waste Disposal Instructions Avoid disposal, attempt to utilize preparation completely. Prior to disposal of unused preparation, consult an approved waste disposal operative to ensure regulatory compliance. Refer to local statutory requirements for proper disposal instructions. Do not discharge into biological sewer treatment systems without prior approval. Specific concerns may be high BOD load and foaming tendency. Dilution will reduce BOD and COD factors proportionately. Low dosage flow rate or antifoaming agents acceptable to the treatment plant may be helpful. Do not flush to waterways. Disposal of Contaminated Packaging Do not puncture or incinerate cylinder Empty packaging may contain product residue. Dispose of in accordance with applicable local laws. * * * Section 14 - Transportation Information * * * IATA Information Shipping Name: Fire extinguishers UN #: UN1044 Hazard Class: 2.2 Required Label(s): NONFLAMMABLE GAS ICAO Information Shipping Name: Fire extinguishers UN #: UN1044 Hazard Class: 2.2 Required Label(s): NONFLAMMABLE GAS IMDG Information Shipping Name: Fire extinguishers UN #: UN1044 Hazard Class: 2.2 Required Label(s): NONFLAMMABLE GAS ADR Information Shipping Name: Fire extinguishers UN #: UN1044 Hazard Class: 2 Required Label(s): NONFLAMMABLE GAS RID Information Shipping Name: Fire extinguishers UN #: UN1044 Hazard Class: 2 Required Label(s): NONFLAMMABLE GAS Containers must be shipped with the appropriate safety caps. * * * Section 15 - Regulatory Information * * * EU MARKING AND LABELLING: Symbol(s): None. Risk Phrases None. Safety Phrases S9 – Keep container in a well-ventilated place. Chemical Safety Assessment Information None identified. Other Information A: General Product Information None available. Page 5 of 7 172527 Rev A UTC Aerospace Systems Safety Data Sheet Material Name: POWEREX and Nitrogen B: Component Analysis - Inventory Component/CAS Propanoic acid, 2-hydroxy-, monopotassium salt 996-31-6 Water 7732-18-5 Nitrogen 7727-37-9 EC # 213-631-3 EEC EINECS CAN DSL TSCA Yes 231-791-2 EINECS DSL Yes 231-783-9 EINECS DSL Yes * * * Section 16 - Other Information * * * Training Advice Any use, operation or discharge of a device containing compressed gas under high pressure has the potential to cause harm. Training in safe use by a qualified professional is recommended. Recommended Restrictions on Use Discharge in confined or enclosed spaces that lack sufficient ventilation is not recommended and may cause harm. This product contains nitrogen under pressure, which when discharged, may displace oxygen and act as an asphyxiant. Key/Legend TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NTP = National Toxicology Program; IATA = International Air Transport Association; IMO = International Maritime Organization; ADR/RID = European Agreement of Dangerous Goods by Road/Rail; DFG = Deutsche Forschungsgemeinschaft; MAC/MAK = Maximum Concentration Value in the Workplace; TWA = Time Weighted Average; STEL = Short-term Exposure Limit; EINECS = European Inventory of Existing Commercial Chemical Substances; EEC = European Economic Community; VLA/VLE = Work Exposure Threshold; OEL = Occupational Exposure Limit; NA = Not Applicable or Not Available. Revision History New SDS: approved 15 October, 2008 Revision A: 7/10/2013 renumbered, contact information updated and reviewed Contact: UTC Aerospace Systems (UTAS), Materials Engineering Contact Phone: 1-252-237-7004 End of Sheet 172527 Page 6 of 7 DWG NO:172527 SIMILAR TO Page 7 of 7 SH: 1 COPYRIGHT© UNITED TECHNOLOGIES AEROSPACE SYSTEMS. THIS DOCUMENT IS THE PROPERTY OF UNITED TECHNOLOGIES AEROSPACE SYSTEMS (UTAS). YOU MAY NOT POSSESS, USE, COPY OR DISCLOSE THIS DOCUMENT OR ANY INFORMATION IN IT, FOR ANY PURPOSE, INCLUDING WITHOUT LIMITATION, TO DESIGN, MANUFACTURE OR REPAIR PARTS, OR OBTAIN ANY GOVERNMENT APPROVAL TO DO SO, WITHOUT UTAS EXPRESS WRITTEN PERMISSION. NEITHER RECEIPT NOR POSSESSION OF THIS DOCUMENT ALONE, FROM ANY SOURCE, CONSTITUTES SUCH PERMISSION. POSSESSION, USE, COPYING OR DISCLOSURE BY ANYONE WITHOUT UTAS EXPRESS WRITTEN PERMISSION IS NOT AUTHORIZED AND MAY RESULT IN CRIMINAL AND/OR PROPRIETARY INFORMATION 61423 A REV: UTC Aerospace Systems 174 NEXT ASSY 172527 Rev A Material Name: POWEREX and Nitrogen Safety Data Sheet LTR DESCRIPTION REVISIONS DATE BY APPD A Release 14/05/28 PA RF CONTR NO: This document or file contains no EAR technology or ITAR technical data. P/C: DRWN: CHECK: Peter Anderson Robert Foster Sherwood Joyner 14/05/28 14/08/22 14/05/28 MSDS – Powerex (EU) ENG: Brett Standifer 14/05/28 SHIPPING: Edwin Sepulveda 14/05/28 Kidde Technologies, Inc. 4200 Airport Dr. NW Wilson, NC 27896-8630 USED ON: SIZE CAGE CODE DWG NO REV A 61423 172527 A SCALE -- 14/08/22 REL DATE SHEET 7 of 7