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A Study On Colour Removal Of Waste Water From Textile Dyeing Mill By

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trg nn ?539 nrrflnrrrmamrr{'rfrfrrarir rf,arnnlroo.rnbnfiarfirrffis Re-du A STI'DT ol| GOLOT'B REOVAL OF HASTE UATER Ff,OI IETTII.E DT'EIXG TILL BY RE-IX)X lrsffin nqs1lg 4 6o, onuuilt['1il'll' tl0 t ft tmfr n# r iilncundors lI{74r',9vllnov r/.VxirP "-\\G onrrflnrrm@nr&nrm ann rnnhlafinrrufinrdourffir EN +rb4qo gD37 frffimrf,E rrinarf,srfu Copyright by Mahidol University I.f. 25S 38946 qq6 :Yltl''lUl^nfD' i, t:o{ qouq?Ss.1[tesa.{ n't :rlfl ulYroa a.l n 1 :fr 1 aod? a.: u1 L dga 1 n L5 n.3 11rilong oljtJ'l lofj ?0' RE-Dox \ -,r t-t ,). -_l TI0l1 fil tryt; t('f n'rnnutd6 -a l.ldgl AI?Q€I ru - :Jtv o,run::lln''r?n ?!Fmine q rtuld sAA,Au4i!t ullJgr ?ff1t!':{Ba L: qq qa( fl :?iln'r:n ?lnil2Ylg q 1u1fir6 n ,n b)ry otfuln't'r-Csq-vq aong ?Tgt?tfln .tq 11.1l., F.R.C.P. sqqa ' ivrer oillunt :hg o'runilc D.sc. n::rn r:rhs 6 rufi noe: ivrerrtrdo{mrf,rrr?er Copyright by Mahidol University 1IIl79r??|fl1Ael 4l arz n$uo vqAg lttu?r9l?YtEl']ag 51fl1fi[719r 1,,1.lJ. . ridr rvrnfuJo$nr:uiur:dsuaefiar nru"dr u aofi aluae?;llerntdrdfl { l qa6 ??lg'trlutr!' d t?ail ^ Ttro'eil1dJn"fi61il{ laTo:raur:Ja{oanlad Jtrdsil'1fl1:Jaaa1# ua"Tdror'errnaal?d fiuadfilrj:r t nna ar dfi aluncdfiom as ar :aod r fi udrfinr lzrdenrlalo:3a1r,h{arrrl:oaofi?anfir rfre"tfimnnrr{asoc so a&ttlria'lfiIrrdeil lslo:fiat&{dn ru r fflfir 60 iln/ax. ;i:-il aili r rrffAlfi i:aofi a-d1td:.: 5. 0-6 . o og:*6,j :1nl?riln'ldlirnrm€Trn 4.8o-?.40:r-rrlar.l."Lunn"r :hvrnnfifiailfiaualefir1fi il r iti:h" r nnlriasar:rfi r$uriidc r ua{a fi s n:rirti1fi ern an i&Tsoilfiacirrr1fi -7J-illrr'- rilalflt lardsil'1fl1:Jnaa1:{arrl:naodna{i"',iulfirinndriaeas +.--.€ lsfon r au r :la{aan1adfi:J:"finf,nrr.rnr:aofidurn rfieildllnaa1r{dnaurfr:rfiu 1ss m-naaiutar.or.fi radfi rnrrvdl"[rnr:ooiae"lu ri:'r s.o-e.0 r1n''lr?lrirar:rnifi{rilo 11.1s-g8.4? ulnlarr.r. enriufrfiartrlr"ion ta"a,,sfi", Trrderrnaa'l# drlr:naoizuofur-dg]fo,,-:naj1i-aua" so frutJ rfia"lffIt rdenrnaa"t:#o:.,ulid* to-fro" d r nm u dr"[unl r url"luX s ^rfr 7 . 44-45.60 u"m/a:1. 11. u^.rr. i].J-J r *l d enrhdfiuu*Ji-1nil"lufil firar rar : rn iri arfr rr uur aeiluri:.r :u 6:::J:g r rnr Copyright by Mahidol University I Tbesis Title A sbudy on Colour Renoval of l{aste l{ater fron Te: DETTRIN ( II{SLUBLE ) ------ > DDflT,IN ( SLUBLE Z v' t'[IAsArEdrl ? (vfHasa1tru,l) nr:rir6oruflsfr16 z 1. iiltrd "r (aun']Eni"t) 't6uri nr:fi r6orloa:Jfrniurblo:1a?a ( Hydro lys z. nr:ririolerarl$nier aon? r offu-ifi is Method) ndt oxidat ion-reduet ion < nr:.ririeruirTrrmlfrniar"tslo:14?o ararirlimorgii ,l l.nl:tr.d{.r (Rot ) Z steeping) t o Qrr q l{ethod) fi a Q e q {racyrr-lfrufturfiruaofir ts*ett) rnctnn ,$niu.1a1*1^?o ;ufir usrrfio'tfifir fiararifertraruru z. nr:ud"[un:q t tcid steeping I n:orwrits'[fi r fiorl$nierlaJo:1o?as asuflr rfio"tfir6:f;u usifia.:drfi{fi.:ararfignrsfi:rfir n'afir'[fin:arrnrfiutj a"rir"[fifiril",utflae r1^r:"run:oevfrr1firior:J$nierlaJo:lnEdaar rfiu"[sflrsfirefufiasdrfitfu:Jilrrunr:"ltn:o t nics.l{o& ilaila\: fllln 2']X t dElT']EIg{ s. A-IAQY t nOfl U nrrlfidrrx:nr alrldi tEnzynatie Steepingt r au"tgirfiuer:ff[fieiaedarEl drrsrrr 1 ufieusrrieaa.: nr fiaoslilrad roultd raulzidruiusaerfu tfiuru:nrfiefilroult{'luirare (Anytase) "l3dasuflr'lfi,flufi''"lr usrrailt#[ffririouilctfieoueian Eragufl.r"[fifiaurofrranor5na,rr.rofiw1fiarorgfir$dffulfie.ruaufi: nr:"lf;rat1zifirdu r6:r:ftravfi.o,iliofiortilrrunr:"[fiuardrrrr"n4unilrsdil"Lunr:1fi.:ru nrn'Lflltcn",."dti r ::a"lfi fiunl rf,u t:jda.:Ios rrjtslsr{ raultfu:rrurn,fio g rio n'a oc pH l.Malt Enzyme rjilreunr:'[t s-zo ltl , 50-60 n = 6-?.5 oc pH = 6-7.5 Z.Pancreatic EnzJme :Jilrrunr:"lt Fg gll , 50-60 Copyright by Mahidol ,University nlrs drfi oo"lfi aradaen rfi n r, r :Jai 10 3.Bacterial Enzne :jtlrrunr:"[fi 0.s-1.0 gll , 60-z0 oc , pH = 5.5-7.5 q e LUnl?Fr ,, q -l .4 | -s 3 74 "i 16?1 LTIlIAYildlt t AU lzilTo',]Erdllo?1.tngaguil.: uau S , C L:Jtgtll dln :s l ulnvdtt 9.qstS ua?t|grlr?BYrtJHaa a nr:ririoruitleearfimJfrnier ndu aonfl r offu-tfi fi:sor:firfiu6:r6laan?rar(oridizing Agient) arfi ErrHnnr:dufl .: r-,naon?lod rdru:n "lal:Jrraal:d , uan ]:r:hd uavu:nrila4oon'ttd nnrerfirdrtd^u^.uil'tfi ar:fi"tfiialfi:rdr:oon?1or* 1fiun drr ziasrflan (tletting Agent) uavoir..: dfiorzo.,:dr:drerrflen q (Atkali) dsfifiorqirfirfirdrni:rif,nl:f,a*a nta oetergent fia.:rfian"[fiuurrvdrfiuarrdu t gruu$ !?n'uava.id:J:cnalerrr r 4o o '1 "[un:or:unr: v' undrilfirnrnlolluuilrcdilaslfiornrurufianrefi!firlfi 6:odr.: Recipe fi urrrsdrdrnS:rnr:rirteufl.:6:e1aJo: r ar t daioanltd L:R H.O" I{aOH LzZA 0.5 Volune 10 gll 2 gtl go oc l{etting Agent ailfinil q!u 60 trfi t ?a"r n1:n:?adaufirfiantn:s:J:unr:ririorufl.:ufi: "lfidr:a"arer"la]ofulu1:Jfio r?eflloJa'tod to. 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I =-tG Es€ (n -CltatN @ \0 -f, nt -G ]ir-C t6i =Aaro E .E"E al .G rF jir ar cg tttE € :5€G s .sF ol cl fa a'l art $ t (e a rg F tl * H ."s r"-=-r-rF zaa FE !E = E;E.F a'Ff dF .EF!' =EE H o EE BEI F Copyright by Mahidol University F EvE tr= @ e d ? TUC)ZT E F e"- F 'F ri o 7 r z \oolF zo Cof-or-r remorza.1 lcy re--d,o>< El 1[c.1 direct, dgre (gfeen tone) OI'I]R AIBII 400 :\ 200 100 0 300 zao mgrldm^3 100 .+ Sodium hydroculBhit€ + 500 400 -concenbration Sodlum chlorite Tfr o.t o.*tfii 4.r fi:a:ir,:firrfie trlc.1 irirfirdlfiru ssz ADltr rfrlr'drio 4r.Ortr--& fi6re Na"sroo "Ll:Jdlrordrs"rfiu6.:il fra 160, 1Bo, zoo, zzo, 24tr., ttac 260 ng/dn" d1rrlrnfil{fliaafiIrrfig No.1 $H.:{n'a zgl- 269, 1s4, Lsz, 52 40, rffi 36 AD!tr nruirdl firadrofirrfie gzo, 4(x), ras zas ADt{r flr!6r6! te.1 rlrilrririardfi:g Nacloz 1u:Jilrnrsir.:"rirufi.:fi a'a 4go ngldna arlr:nfir{od uo.r 1fi6sfi fiu gor, z9z, vay Copyright by Mahidol University CoLorr renorra,L lcrz re-d,,o>< 52 flc.1 direct dye (gfeen tone) CDLOI'R AIHI 510 20 concenbration 'ng-Ct/dm,-3 + Sodium bnroghlorito zrd +.2 I J,o,3{ 4.L q?oa'\ru'lrdn r1finln .I < m.2 direct dye (black tone) 6IOI'R 2500 r__ ADilII 2000 \-- 1500 \\ 1000 l_ 500 0 "\ \ tl I 0 100 + Sodium 500 400 300 concentration 1. mg,/dn^3 2. mg-Cl/dm^3 200 hydrosulphit Sodium hSrpochlorite d flm 4.3 tt a1q$i 4.s fi:aer.:firrfie No.z irirfirilfu fifi:e Narsroo "[u:Jirtusrra"rfiufufi 2166 N)t{r riurrir{o da 80, Lzo, 160, zo0, zftr,, LLav z4o ng/dnt drlr:nririoiaorirrfls I{o.z $Aofifia Lzss, ?66, ?oo, TEg, zsL, uas z5o enut oudrfi:r fi:adrsfirra'e alo.z ritrrrir{orfifiae Naffil "lu:Jiltusir.:"'iil6ri 154, LTg, 2o5, gal, goz, ras 461 ng-cl/dns dur:nririofr Uo.z 166.:i 1053,' 1014, g7O, 727, 494, uau 257 lOttt n1lrdrfilj n'a fia Copyright by Mahidol University CoLorr renorza.L lc:r red.o>< 54 fA.3 direcf dye tred tone) @IOT'R AI}UI t200, 1000 EOO 000 400 20{) 0 60 40 1. Sodlum - 80 100 120 mgldrn^3 2. m5-Cl/dmr3 bydroeulphite + Sodium blrpochlorite J 4.4 fllfl t r,rngrd 4ie fi:adr..rfirrfie l\o,s ieirfiril"Enr 1@z AInfi rirmdrto < lO.4 reactive dye (blue tone) @LC}TIR ADUI 400o 3000 2000 t500 t(Xlo 500 0 200 + 600 400 L.ng-Cl/dtn^g Sodium bJrpochlortte 800 Z.mdllm^3 + 1000 c'onc.entiC'titin Sodium cblorite d alm 4.5 r ernnd 4.s fiaadr.rirrfie ro.4 iirdrilfiu s611 ADr{r rflurr{rin d6:s l.taocr "lufilrnrsir.r'rirufufi R'a 2g6, zaz, gor, ggg, .gsa, uns gB4 mg-cl/dns arn:nririodaarfirrfie io.4 'tfi6.':fi6a 458, sog, zt:, Laz_ 155, uav 119 ADI{I nudrdr ' fiaadrsfirrils t€.4 rlrilrrir6qfifr:FJ Nacloz '[ufiilrseirr"liu6ri n'a 4&), 640, rac EOO 4/dn" aTn:nririolii Uo.A lfifi..rfi fiu tZZ, ?/14, rn3 9O5 aom srrrdrftr Copyright by Mahidol University Cof-or.ur rem,orza.l- Ic;r re-d.o>c 56 lO-5 reactive dye. (prnple) @IoI'R AI}ut &oo. 3500 3000 2500 2000 1500 1000 500 o 100 1. Sodlum 150 200 mgrlrtw.^3 2. mg-Cl/du^3 hydrosulphite + Sodiua hSpoehlorite d zilm 4.6 ! annnd 4.6 fi:adr.rfirrda ho.s ieirfirilfiu s4sz enn rirrrriria dfi:e Na"s"oo iuGrrrueir.:rfiu6.rfi 6a 40, Bo, Lzo, Ltgi,, 160, uay zoo ng/dn" orlrmririorfiaalfir,fis r'CI.s lfifufii'o gzas, 2445, 6a4, 6ss, ?s6, rac ?94 aom srrliirfil fi:adNfirrde No.s rirnrir{ofifi:e Naoct lurlilrrueiro"rffi.rfi 6a LzB, 1s4, rrg, zos, zgo ras, zs6 ng-cl/dn3 crlr:nririqi r,ro.s lfifi.1f, n'a 1086, 660, 424, 33O, 29O uns 264 aOrn erildrdr Copyright by Mahidol University Colorr remorza.f. Icy re-( t7 !O.6 reactive dye (bown tone) @LOIR AI}UI 35AA 3000 2500 2000 r500 t000 500 .o 50 * 100 150 l. mgldm^3 Sodium, hydrosulphite .{ TIFI ! zoo ". 300 250 + 350 concsrtration mg-g'/dm^3 Sodium hyTochlorite 4.7 ..ogtd 4.? fi:od.r.lfirri:l I\o.6 ilirdr*rfnr s344 ADl,[ rfiurriria aq?E Narsroo lu:Julrrunrl,rrnr6.:ti n'o 8O, L?jO, 160, 200, ttac 24O ng/dn" n'ril'r?nd1ft6aa.rfiriote ts.6 Ga.rfia'a 3o4o, 2535, Ltrfg, ?24, {rr6trqro-&€ BAs 342 ADUI o1r|a101 fira:ir.rfirrde ts.6 rirlrririodfi:e Naocl q 1r I u -&q lUlJ?llTl0.l.l'tflUq{U Ra zo5, 2go, 258, 282, go?,ttnc gg3 ng-cl/dns durr:nririod uo.e 1fifufi fia 1037, ?97, 663, 612, dB4, ua:r S93 anUI orrdrftJ Copyright by Mahidol University co1or.r renorra.f. Irlr re-d,o>< 58 fO.? acid dye (pink tone) . @IXIIR AI'UI 500 400 ,/ 300 200 100 :,-t I 0 ?'50 200 r5o 100 concentraf,ion t. ry-Cl/dm^3 Lmg/dm^S + Sodium bSrpochlorite + Sodium chlorite 50 d Tlm 4.8 l -t-d 4.s fi:adrrfirrds to.? iirfirilfiu 6fias luaoct"[uGlrueir.:1fiu6.1f, a'a < renorza.l- 59 llo.8 acid dye (dark hown tone) 300 @I!T'R ADI{I 250 zoo r50 100 50 0 0 1. * Sodlnro 200 150 50 100 mg/dm^3 l.ng-Cl/dm^3 3.mgrldm^3 conceutration hydrosqlphl{e + Sodlum hypochlodte + flodlun chlorlta tr$i +.g em?d 4.e fi:arir.lfirrds No.8 iiifirilfiu 269 ADr'tr rirlrrir{o < 1CI.9 60 acid dye tyeltow tone) @IOTIR AI}I{I 500 400 300 200 t00 o 50 100 l. ngldn^3 + + Sodtnn hyitromlpDlle 200 150 Z.mg-Cl/dm^s 3.meldn^S Scdlsm Dypochlorlte + concentr:afrion Sodlum chlortte .{ Trln 4- 10 ! d irrrilil 4.10 I A < 62 pord OIOT'R, AI}UI R \*\_ 1fi)O 800 \* 800 400 a0a) o I 50 0 .- Sodium 100 hydrosulphite + 150 200 250 Sodium bypochlorite J 4.12 flm t fln?rd 4.72 fi:adrrirrda r€.1s idrdrillnu ross ADr{r rlrrrririn d6:e Nars"oo turlirreiN"rfrufufi fia zo, 40, 60, Bo, 10o, uoc tzo ng/dng nur:nrir{oatzarfirrfis $o.lo$ifi{fidu gso, gozn B9?, eoz, 8?5. Bac 844 ADur nrrd,fil fieadr.rfirrfie [email protected] rlrurdriodfire Naoct "[ufirrssir.r,rffirfi fia 7?, !o2, !21t, !54, 1?9 uos Zos ug-Cl/fus Oln:nfirioil No.1O $e"fi a'a LozL. loog, ggr, TBgr 698, unc 64it aDl{r q,lrdrfix Copyright by Mahidol University Color.r remova.L I\0.14 600 500 400 6g lc:r re-d.o>< first pord .@IJI'R AIMI _v \ \- 300 + 300 100 llrrltr 0 20 - -'40 60 l.mgldm^3 80 Sodium hydrosulphite 100 tao Z.urg-C)/a't'^g + 140 160 concentration Sodium hyaoehlorite J flfn 4.13 f e to d dr st u d o o u t{ ' t,ltTrrjn 4.13 n?afl'r{u'] rdEt t\CI. 14 ilnldt?xenr 581 ADI{I [rlrnrao !?-^to,a,--&{-3 nq?8 Na=s"o.. Hil5lt1flFl,.lil"lfruo{il aa 20, 40, 60. 90, 100, $oc 12o ng/dnog { ? q vr,* &or n1!]?nnlaodta{u1tda M).14 loo.iuna 44o, rca, 4?4, M4, 436, uas 426 ADI{I qrrdr6il fiaairsfirrie rc. r+ rirlrriiiordfi:s Naoct lurlirrruEir{"'fu6ri fia 2f,, 5!, 77, :tftz, 128, uas 154 mg-Clrdt"Au,'',:nririoi Uo.f 16firf, da 35S, 2Tg, Xlz, Z#r 2!L, uou 193 ADI,II'q'lild16u'' Copyright by Mahidol University 38946 Color.r renova.f. tio.lS first Iey re-d.o>< 64 pord 7oory 800 000 \ \\ 400 \- 300 a-.- \-r-_ 200 100 Itttll 0 20 - 4A 60 80 l0o ,.120 t40 160 Lry/tan^3 2.mg-f,l/dm^3 conse[tr-ation Sodium bydronrlphite + Sodium h5poeblortte ..1 Trtn 4.14 JA;? a,lfrntil 4.t4 nlag1{u1rafl N).15 iln1dr5ilgnr 590 ADIII u"rlr1fr']ao t.. , dl dt o, - & ra no?a Na.S'424 O.. $1j?lt']tu9r'1.id|fru9h3u Ra ZO, 40, 80, 1OO, uns 1ZO ng/dn" qt,- &q o - { B C . d'lx'lrnn1?qdfla{u']ri{Et 10.15 tcleh:rrna 381, 387, 4OZ, 396, uns 394 ADMI qrldrfil fi:adr.rfirrda l*to.1s rlrlrrirtofifiae Naoct a -, ,. 26, "[trl:'ilrrusir.:"rfiu6.rfi a'a _._, - 5!, ?7, Loz, 12s, $ac-i.54 Agi-ct/dn" arlr:nririoil 25I, 255, 25g,,L2Or 114, uac -No.rs lfifi.1fi ffa 155 AInfi fllrdlfiil Copyright by Mahidol University Cof-orrr renorra.f- Ic;r re-d.o>< 55 10.16 last pord to0 OIiOUR ADUI €L 400 300 200 100 0 20 ll-*ro-$o ,.#-ozo#ro tto*""tntXh'o" .- Sodium hydroeulphlte + Sodium LSpochlorite .{ Ttn 4.15 4.rs fi:adrrfitfia ro.16 firirdr{rflnr seo ADt{r rlurrir{cl Aq?Et NarS=O., tt:JCarmsrrl'rfrudsu fia ZO, 40. 80, 1OO' Uau 12O ng/dna t'e c s..a --.,1 o- 8< 6i,il1:nd1{96aa{{1tdg lp.rolotd.lilna +i14, 42o, 39o' 359, 348, uns 312 ADI{[ e,rnnd 16 c*/(1 + O.OlglCr*) + 0.698 sc(Tf+1-f) t(or)o tE(&ro + 19ool!1/" 0.96 + o.c *rrn + ss) a*uadmr hue aruste | f fiaendr 164o uaurrnndr B4s' o.s6 + *"