Transcript
NIST Recommended Rest Frequencies for Observed Interstellar Molecular Microwave Transitions—2002 Revision Frank J. Lovasa… Optical Technology Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8441 共Received 23 January 2003; revised manuscript received 3 June 2003; accepted 30 April 2003; published online 26 February 2004兲
Critically evaluated transition frequencies for the molecular transitions detected in interstellar and circumstellar clouds are presented. The tabulated transitions are recommended for reference in future astronomical observations in the microwave and millimeter wavelength regions. The transition frequencies have been selected through a critical examination and analysis of the laboratory spectral data obtained from the literature. The information tabulated includes the species identity, transition frequency, uncertainty, and quantum state labels. For convenience, representative line antenna temperatures are listed for a typical astronomical source for each transition, and the references are cited for the laboratory and astronomical literature that have been employed. © 2004 by the U.S. Secretary of Commerce on behalf of the United States. All rights reserved. 关DOI: 10.1063/1.1633275兴 Key words: hyperfine structure; interstellar molecules; microwave spectra; molecules; radio astronomy; rotational spectra.
1. 2. 3. 4. 5. 6.
Contents Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sources and Selection of Transition Frequencies.. Description of the Tables. . . . . . . . . . . . . . . . . . . . . Acknowledgments. . . . . . . . . . . . . . . . . . . . . . . . . . References to Text. . . . . . . . . . . . . . . . . . . . . . . . . . References to Tables. . . . . . . . . . . . . . . . . . . . . . . .
List of Tables 1. Listing the empirical formula of the isotopic forms of the 114 interstellar species detected by their microwave spectrum and appearing in Table 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. The 22 other species observed in comets, circumstellar, and interstellar sources at IR and UV wavelengths, which are not included in Table 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3. List of telescope abbreviations employed in Table 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4. Recommended rest frequencies for observed interstellar molecular lines. . . . . . . . . . . . . . . . . . . .
now lists more than 10 100 entries. This report updates the previous summaries, provides a current source of radioastronomical molecular line observations, and improves the accuracy for many previously tabulated transition frequencies, important for determining physical properties of the molecular clouds investigated.
177 177 178 178 178 339
2. Sources and Selection of Transition Frequencies 180
The present tabulation covers the astrophysical literature through December 2002. The 114 molecular species listed in Table 1 have now been identified in interstellar and circumstellar astronomical sources by means of their microwave spectra. The 22 additional interstellar species, identified by their infrared or ultraviolet spectra, and comet molecular species are listed in Table 2. Since no microwave transitions of these species have been reported yet, there will be no entries in Table 4 for these species. The sources of the transition frequencies selected are as follows: laboratory measurements and predictions from the literature data, previously published tabulations of spectral frequencies,4 –27 spectral predictions of transition frequencies from reanalysis of the literature data carried out in the present work, and web-based catalogs.26,27 The primary criterion for selection of the transition frequencies is the magnitude quoted for the estimated uncertainty in the measured frequency or the standard deviation of calculated frequencies. For well-behaved species, i.e., those whose spectra are well fit by established Hamiltonians, the calculated frequencies are often more accurate than individual measurements,
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1. Introduction The present tabulation of recommended transition frequencies for interstellar molecular species is the third revision of the previously published tables.1–3 Since the last revision in 1991, approximately 5600 new transitions and 31 new molecular species have been added to the table which a兲
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thus many of the entries in Table 4 are calculated values and are identified with an asterisk ( * ) following the frequency entry. In entries where it was determined that the measured value had the lowest uncertainty value, a reference to the literature value is given. For many of the interstellar species the previously published tabulations of critically evaluated laboratory data4 –25 were the source of both measured and calculated frequencies cited here. In many cases for species treated in the publications indicated above, new spectral data have been reported and have been combined with the earlier data sets and reanalyzed to provide predicted frequencies employed here. Some of the earlier reviews also have a frequency limit of 200 or 300 GHz, while new interstellar observations range up to 725 GHz. Thus, for most of the smaller species 共diatomic, triatomic, etc.兲 calculations were extended to higher frequencies with new laboratory data included where available. The earlier reviews on CH3 OH, 6 CH3 CHO, 12 and HCOOCH3 19 are outdated and new reviews were used 共关Xu – 97兴, 关Kle91兴, and 关Oes99兴兲. In a few cases, e.g., for radical species such as C2 H, C3 N, C4 H, etc., the on-line catalogs developed at the Jet Propulsion Laboratory 共JPL兲26 and at the University of Cologne27 were used as the source of calculated frequencies.
3. Description of the Tables Table 1 provides the identity of molecular species detected in astronomical sources in the radio, microwave, millimeter, and submillimeter region. For a number of the species one or more isotopically substituted forms have been observed and these are listed as well in Table 1. In Tables 1 and 2 the species are listed in alphabetic sequence according to empirical formula 共Hill system兲 in the first column along with the common names of the molecule in the second column, and molecular formula in the third column. The reference共s兲 given in the last column of Tables 1 and 2 are for the original detection in the astronomical source. Table 3 provides the code and identification of the telescope used in the astronomical reference for each transition in Table 4. The major emphasis of the present work is to provide the most accurate transition frequencies available for all of the astronomically observed spectral lines which are listed in Table 4. In Table 4 the recommended frequency is listed in column 1, followed by an asterisk in the case of calculated values, and its expanded uncertainty (k⫽2 or 2兲 is shown in units of the least significant digit共s兲. Uncertainties28 for calculated frequencies are Type A with coverage factor k ⫽2 共2 s.d.兲. For measured frequencies, the uncertainties are Type B and taken directly from the reference cited. The chemical formula for each molecular species is given in column 2, the chemical name in column 3, and the quantum number labels are shown in column 4. Columns 5, 6, and 7 present astronomical information: antenna temperature (T r* or T a* ) or integrated intensity 共full line width at half intensity times peak intensity兲 molecular cloud for the observation and J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
abbreviation for the telescope employed 共see Table 2 for a list of telescopes referenced兲, respectively. Most often the molecular cloud listed is Orion A 共OriMC-1兲, Sagittarius B2 共SgrB2兲, Taurus Molecular Cloud 1 共TMC-1兲, or the circumstellar envelope of the infrared star IRC⫹10216, since these are the richest molecular sources and often provide the most intense emission lines. In column 8 the reference abbreviation for the astronomical observation is given and column 9 shows the reference to measured 共or calculated兲 frequencies when taken from the literature. The reference code is based on the first three letters of the lead author’s last name, plus the last two digits of the year of publication. If no laboratory reference appears, the frequencies presented are calculated in the present work. The reference list for Tables 1, 2, and 4 then follows Table 4.
4. Acknowledgments The author is pleased to acknowledge the following astronomers for providing preprints or unpublished observations: L. E. Snyder, F. Combs, and M. Ohishi. A special thanks goes to J. M. Hollis for assisting in checking the unidentified lines against the complete spectral catalog developed for this publication. Partial support for this work came from the Laboratory of Astronomical Imaging at the University of Illinois and NSF Grant No. AST 99-81363.
5. References to Text 1
F. J. Lovas, L. E. Snyder, and D. R. Johnson, Astrophys. J. Suppl. 41, 451– 480 共1979兲. 2 F. J. Lovas, J. Phys. Chem. Ref. Data 15, 251–303 共1986兲; 16, E153– E154 共1987兲. 3 F. J. Lovas, J. Phys. Chem. Ref. Data 21, 181–272 共1992兲. 4 D. R. Johnson, F. J. Lovas, and W. H. Kirchhoff, J. Phys. Chem. Ref. Data 1, 1011–1046 共1972兲. 5 W. H. Kirchhoff, D. R. Johnson, and F. J. Lovas, J. Phys. Chem. Ref. Data 2, 1–10 共1973兲. 6 R. M. Lees, F. J. Lovas, W. H. Kirchhoff, and D. R. Johnson, J. Phys. Chem. Ref. Data 2, 205–214 共1973兲. 7 P. Helminger, F. C. DeLucia, and W. H. Kirchhoff, J. Phys. Chem. Ref. Data 2, 215–224 共1973兲. 8 F. C. DeLucia, P. Helminger, and W. H. Kirchhoff, J. Phys. Chem. Ref. Data 3, 211–219 共1974兲. 9 A. G. Maki, J. Phys. Chem. Ref. Data 3, 221–244 共1974兲. 10 F. J. Lovas and P. Krupenie, J. Phys. Chem. Ref. Data 3, 245–257 共1974兲. 11 E. Tiemann, J. Phys. Chem. Ref. Data 3, 259–268 共1974兲. 12 A. Bauder, F. J. Lovas, and D. R. Johnson, J. Phys. Chem. Ref. Data 5, 53–77 共1976兲. 13 G. Winnewisser, W. H. Hocking, and M. C. L. Gerry, J. Phys. Chem. Ref. Data 5, 79–101 共1976兲.
MICROWAVE TRANSITIONS E. Tiemann, J. Phys. Chem. Ref. Data 5, 1147–1156 共1976兲. R. A. Beaudet and R. L. Poynter, J. Phys. Chem. Ref. Data 7, 311–362 共1978兲. 16 W. J. Lafferty and F. J. Lovas, J. Phys. Chem. Ref. Data 7, 441– 493 共1978兲. 17 M. C. L. Gerry, K. Yamada, and G. Winnewisser, J. Phys. Chem. Ref. Data 8, 107–123 共1979兲. 18 A. Bauer, D. Boucher, J. Burie, J. Demaison, and A. Dubrulle, J. Phys. Chem. Ref. Data 8, 537–558 共1979兲. 19 A. Bauder, J. Phys. Chem. Ref. Data 8, 583– 618 共1979兲. 20 F. J. Lovas, H. Lutz, and H. Dreizler, J. Phys. Chem. Ref. Data 8, 1051– 1107 共1979兲. 21 E. Willemot, D. Dangoisse, N. Mannanteuil, and J. Bellet, J. Phys. Chem. 14 15
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Ref. Data 9, 59–160 共1980兲. D. Boucher, J. Burie, A. Bauer, A. Dubrulle, and J. Demaison, J. Phys. Chem. Ref. Data 9, 659–734 共1980兲. 23 I. Ozier, M. C. L. Gerry, and A. G. Robiette, J. Phys. Chem. Ref. Data 10, 1085–1095 共1981兲. 24 F. J. Lovas, J. Phys. Chem. Ref. Data 11, 251–312 共1982兲. 25 F. J. Lovas, J. Phys. Chem. Ref. Data 14, 395– 488 共1985兲. 26 JPL Catalog: http://spec.jpl.nasa.gov 共see Pic98 in the reference list for Table 4兲. 27 Cologne Catalog: http://www.ph1.uni-koeln.de/vorhersagen/ 共see Mul00 in the reference list for Table 4兲. 28 B. N. Taylor and C. E. Kuyatt, NIST Tech. Note 1297, U.S. Government Printing Office, Washington, D.C. 共1994兲. 22
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TABLE 1. Listing by empirical formula of the isotopic forms of the 114 interstellar species detected by their microwave spectrum and appearing in Table 4 Empirical formula
Name
AlCN AlCl
Aluminum isocyanide Aluminum monochloride
AlF CH CH⫹ CHN
Aluminum monofluoride Methylidyne Methyliumylidene Hydrocyanic acid 共Hydrogen cyanide兲
CHN
Hydroisocyanic acid 共Hydrogen isocyanide兲
CHNO
Isocyanic acid
CHNS CHO CHO⫹
Isothiocyanic acid Oxomethyl 共formyl兲 Oxomethylium 共formylium兲
CHO⫹ CHO⫹ 2 CHS⫹ CH2 CH2 N⫹ CH2 N CH2 N2 CH2 O
Hydroxymethylidyne Hydroxyoxomethylium Thiooxomethylium Methylene Iminomethylium Methylene amidogen Cyanamide Formaldehyde 共methanal兲
CH2 O2
Formic acid
CH2 S
Methanethial 共thioformaldehyde兲
CH3 N
Methanimine
CH3 NO
Formamide
CH3 O⫹
Hydroxy methylium ion 共Protonated formaldehyde兲 Methanol 共methyl alcohol兲
CH4 O
CH4 S CH5 N CMgN CMgN
Methane thiol 共Methyl mercaptan兲 Methanamine 共methylamine兲 Magnesium cyanide Magnesium isocyanide
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Isotopic species
CA Number
Reference
关13595-81-8兴
Ziu02 Cer87c
关13595-82-9兴 关3315-37-5兴 关24361-82-8兴 关74-90-8兴
Cer87c Ryd74, Tur74a, McK40d Cer97, Dou41 Sny71a
关6914-07-4兴
Sny71
关75-13-8兴
Sny71
关3129-90-6兴 关2597-44-6兴 关17030-74-9兴
Fre79 Sny76 Buh70
关60528-75-8兴 关638-71-1兴 关59348-25-3兴 关2465-56-7兴 关38263-97-7兴 关15845-29-1兴 关420-04-2兴 关50-00-0兴
Woo83, Ziu95a Tha81 Tha81 Hol89, Hol95 Ziu86a Ohi94 Tur75a Sn
关64-18-6兴
Zuc71, Win75
关865-36-1兴
Sin73
关2053-29-4兴
God73
关75-12-7兴
Rub71
关17691-31-5兴
Ohi96
CH3 OH 13 CH3 OH CH3 18OH CH2 DOH CH3 OD CHD2 OH CH3 SH
关67-56-1兴
Bal70
关74-93-1兴
Lin79
CH3 NH2 MgCNa 24 MgNCa 25 MgNCa 26 MgNCa
关74-89-5兴 关74758-76-2兴 关96491-22-4兴
a
AlNC AlCla Al37Cla AlFa CH CH⫹ HCN H13CN HC15N DCN HNC H15NC HN13C DNC D15NC HNCO DNCO HNCS HCO HCO⫹ H13CO⫹ HC17O⫹ HC18O⫹ DCO⫹ D13CO⫹ HOC⫹ HOCO⫹ HCS⫹ CH2 HCNH⫹ CH2 N NH2 CN H2 CO H2 13CO H2 C18O HDCO D2 CO HCOOH H13COOH HCOOD DCOOH H2 CS H2 13CS H2 C34S HDCS CH2 NH 13 CH2 NH NH2 CHO NH2 13CHO H2 COH⫹
Fou74a, Kai74 Ziu95 Gue86, Gue93
MICROWAVE TRANSITIONS
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TABLE 1. Listing by empirical formula of the isotopic forms of the 114 interstellar species detected by their microwave spectrum and appearing in Table 4—Continued Empirical formula
Name
Isotopic species
CA Number
Reference
CN
Cyanogen
关2074-87-5兴
Jef70, McK40d
CNNa CNSi CO
Sodium cyanide Silicon cyanide Carbon monoxide
关143-33-9兴 关29210-66-0兴 关630-08-0兴
Tur94 Gue´00 Wil70
CO⫹ COS
Carbon monoxide ion Carbon oxide sulfide 共carbonyl sulfide兲
关12144-04-6兴 关463-58-1兴
Eri81, Lat93 Jef71
CP CS
Carbon monophosphide Carbon monosulfide
关12326-85-1兴 关2944-05-0兴
Sai89, Gue90 Lis75
CSi C2 H
Silicon monocarbide Ethynyl
关409-21-2兴 关2122-48-7兴
Cer89 Tuc78
C2 HN C2 H2 N C2 H2 O C2 H3 N
Cyanomethylene Cyanomethyl Ethanone 共ketene兲 Acetonitrile 共methyl cyanide兲
关2612-62-6兴 关2932-82-3兴 关463-51-4兴 关75-05-8兴
Gue91 Irv88a Tur77 Sol71
C2 H3 N
关593-75-9兴
Cer88
CH3 CHO c-C2 H4 Ob CH2 CHOH CH3 OCHO
关75-07-0兴 关75-21-8兴 关557-75-5兴 关107-31-3兴
Got73 Dic97 Tur01 Bro75
CH3 COOH CH2 OHCHO
关64-19-7兴 关141-46-8兴
Meh97 Hol00
关115-10-6兴 关107-21-1兴 关119754-08-4兴 关109545-32-6兴
Zuc75 Pea96 Sny74 Hol02 Ohi91 Yam90
C2 Si
Silicon carbide 共silacyclopropyne兲
关12071-27-1兴
Tha84
C3 C3 H C3 H C3 HN
Tricarbon Cyclopropenylidyne Propenylidyne 2-Propynenitrile 共cyanoacetylene兲
t-CH3 CH2 OH g-CH3 CH2 OH CH3 OCH3 HOCH2 CH2 OH CCO CCS CC34S SiC2 29 SiC2 30 SiC2 Si13CC C3 c-C3 Hb l-C3 Hc HCCCN H13CCCN HC13CCN HCC13CN
关64-17-5兴
C2 H6 O C2 H6 O2 C2 O C2 S
Isocyanomethane 共methyl isocyanide兲 Acetaldehyde 共ethanal兲 Oxirane 共ethylene oxide兲 Ethenol共vinylalcohol兲 Methyl ester formic acid 共methyl formate兲 Acetic acid Hydroxyacetaldehyde 共glycolaldehyde兲 trans-Ethanol 共ethyl alcohol兲 gauche-Ethanol Dimethyl ether 共oxybismethane兲 Ethylene glycol Oxoethenylidene Thioxoethenylidene
CN 13 CN C15N NaCNa SiCNa CO 13 CO C17O C18O 13 18 C O CO⫹ OCS OC34S O13CS 18 OCS CPa CS C33S C34S C36S 13 CS 13 34 C S SiCa C2 H 13 CCH C13CH C2 D HCCN CH2 CN H2 CCO CH3 CN 13 CH3 CN CH3 13CN CH3 C15N CH2 DCN CH3 NC
关175780-10-6兴 关16165-40-5兴 关53590-28-6兴 关1070-71-9兴
Gie01 Yam87a Tha85 Tur71
C2 H4 O C2 H4 O C2 H4 O C2 H4 O2 C2 H4 O2 C2 H4 O2 C2 H6 O
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TABLE 1. Listing by empirical formula of the isotopic forms of the 114 interstellar species detected by their microwave spectrum and appearing in Table 4—Continued Empirical formula
Name
Isotopic species
CA Number
Reference
关66723-45-3兴 关76092-41-6兴 关16165-40-5兴
Kaw92 Kaw92a Mat85a
关60731-10-4兴 关76092-42-7兴 关624-67-9兴 关107-13-1兴 关74-99-7兴
Cer91 Kaw94 Irv88 Gar75 Sny71
关107-12-0兴 关67-64-1兴 关62435-43-2兴 关11127-17-6兴 关109545-35-9兴 关184291-25-1兴
Joh77 Com87, Sny02 Gue77 Mat84 Yam87 App99
关53561-65-2兴
Gue77
关70571-89-0兴 关13752-78-8兴 关144920-67-2兴 关104602-63-3兴 关59866-32-9兴
Cer91a Bro84 Ohi89 Cer86 Ave76
关4911-55-1兴 关129066-48-4兴 关88053-50-3兴 关129066-05-3兴 关129066-03-1兴 关65937-22-6兴 关88053-51-4兴 关67483-72-1兴 关78950-25-1兴 关7647-01-0兴
Wal84 Gue98 Suz86 Lan97 Gue97 Kro78 Cer96 Bro78 Bel97 Sch95
关7447-40-7兴
Cer87c
关7647-14-5兴
Cer87c
关7664-39-3兴 关1345-25-1兴 关7580-67-8兴 关14332-28-6兴 关12357-66-3兴
Neu97 Wal02 Com98 Uli77, Sny93 Tur74, Gre74
15
C3 HN C3 HN C3 H2
Ethyneisocyanide 3-imino-1,2-Propadienylidene Cyclopropenylidene
C3 H2 C3 H2 N⫹ C3 H2 O C3 H3 N C3 H4
1,2-Propadienylidene Protonated 2-propynenitrile 2-Propynal 2-Propenenitrile 共vinyl cyanide兲 1-Propyne 共methyl acetylene兲
C3 H5 N C3 H6 O C3 N C3 O C3 S C3 Si
Propanenitrile 共ethyl cyanide兲 2-Propanone 共acetone兲 Cyanoethynyl 3-oxo-1,2-Propadienylidene 3-thioxo-1,2-Propadienylidene 3-silanetetrayl-1,2-Propadienylidene 共rhomboidal SiC3 ) 1,3-Butadiynyl radical
C4 H
C4 H2 C4 H3 N C4 Si C5 H C5 HN
Butatrienylidene 2-Butynenitrile Silicon tetracarbide 2,4-Pentadiynylidyne 2,4-Pentadiynenitrile 共cyanobutadiyne兲
C5 H4 C5 N C6 H C6 H2 C7 H C7 HN C8 H C9 HN C11HN ClH
1,3-Pentadiyne 共methyl diacetylene兲 4-Cyano-1,3-butadiynylium 1,3,5-Hexatriynyl 1,2,3,4,5-Hexapentaenylidene 2,4,6-Heptatriynylidyne 2,4,6-Heptatriynenitrile 1,3,5,7-Octatetraynyl 2,4,6,8-Nonatetraynenitrile 2,4,6,8,10-Undecapentaynenitrile Hydrochloric acid
ClK
Potassium chloride
ClNa
Sodium chloride
FH FeO HLi HNO HN⫹ 2
Hydrogen fluoride Iron monoxide Lithium hydride Nitrosyl hydride Hydrodinitrogen(1⫹) 共diazenylium兲
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HCCC N DCCCN HCCNC HNCCC c-C3 H2 b c-H13CCCH c-HC13CCH c-C3 HD l-H2 CCCc HCCCNH⫹ HCCCHO CH2 CHCN CH3 CCH CH3 C13CH 13 CH3 CCH CH2 DCCH CH3 CH2 CN (CH3 ) 2 CO CCCN CCCO CCCS SiC3 C4 H H13CCCC HC13CCC HCC13CC HCCC13C C4 D H2 CCCC CH3 CCCN SiC4 a C5 H HC5 N H13CCCCCN HC13CCCCN HCC13CCCN HCCC13CCN HCCCC13CN DC5 N CH3 C4 H C5 N C6 H H2 CCCCCC C7 Ha HC7 N C8 Ha HC9 N HC11N H35Cl H37Cl K35Cla K37Cl Na35Cla Na37Cla HF FeO 7 LiH HNO N2 H⫹ 15 NNH⫹ N15NH⫹ N2 D⫹
MICROWAVE TRANSITIONS
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TABLE 1. Listing by empirical formula of the isotopic forms of the 114 interstellar species detected by their microwave spectrum and appearing in Table 4—Continued Empirical formula
Name
Isotopic species
CA Number
Reference
HO
Hydroxyl
关3352-57-6兴
Wei63
H2 N H2 O
Amidogen Water
关13770-40-6兴 关7732-18-5兴
vDi93 Che69
H2 S
Hydrogen sulfide
关7783-06-4兴
Tha72
H⫹ 3
Hydrogen ion
关28132-48-1兴
H3 N
Ammonia
关7664-41-7兴
Geb96 Sta99 Che68
H3 O⫹ NO NP NS
Oxonium hydride Nitrogen oxide 共nitric oxide兲 Phosphorous nitride Nitrogen sulfide 共nitric sulfide兲
关28637-38-9兴 关10102-43-9兴 关17739-47-8兴 关12033-56-6兴
Hol86 Lis78a Tur87b Got75
NSi N2 O OS
Siliconmononitride Nitrogenoxide共nitrousoxide兲 Sulfurmonoxide
关12033-60-2兴 关10024-97-2兴 关13827-32-2兴
Tur92 Ziu94 Got73b
OS⫹ OSi
Sulfur(1⫹), oxo Silicon monoxide
关54724-05-9兴 关113443-18-8兴
Tur92a Wil71
O2 S
Sulfur dioxide
关7446-09-5兴
Sny75a
SSi
Silicon monosulfide
OH 17 OH 18 OH NH2 H2 O H2 18O HDO H2 S H2 34S HDS H⫹ 3 H2 D⫹ NH3 15 NH3 NH2 D NHD2 ND3 H3 O⫹ NO NP NS N34S SiNa N2 O SO 34 SO 33 SO S18O SO⫹ SiO 29 SiO 30 SiO SO2 33 SO2 34 SO2 OS18O SiS Si33S Si34S 29 SiS 30 SiS
关25423-24-9兴
Mor75
a
Reported only in circumstellar clouds. The ‘‘c’’ refers to cyclic form. c The ‘‘l’’ refers to linear form. d Identification of the optical lines in McK40 were confirmed by W.S. Adams 共Ada41兲. b
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TABLE 2. The 22 other species observed in comets, circumstellar, and interstellar sources at IR and UV wavelengths, which are not included in Table 4.
Empirical formula
Name
CH3 CH4 CO2 C2 C2 H2 C2 H4 C2 H6 C4 H2 C5 C6 H2 HN HS H2 H4 Si
Methyl Methane Carbon dioxide Carbon molecule Ethyne 共acetylene兲 Ethylene Ethane 1,3-Butadiyane Pentacarbon molecule 1,3,5-Hexatriyne Imidogen Mercapto 共thiohydroxyl兲 Hydrogen Silane
CN⫹ CN2 CO⫹ 2 HO⫹ H2 O⫹ N⫹ 2 S2
Cyanogen ion Cyano imidogen Carbon dioxide ion Oxoniumylidene Oxoniumyl Nitrogen ion Sulfur
Isotopic species
Spectral region
Interstellar and Circumstellar Species CH3 IR CH4 IR CO2 IR C2 UV HCCH IR H2 CCH2 IR CH3 CH3 IR HCCCCH IR C5 IR C6 H6 IR HN UV SH IR H2 UV SiH4 a IR Species Observed Only in Comets CN⫹ UV NCN UV UV CO⫹ 2 OH⫹ UV H2 O⫹ UV UV N⫹ 2 S2 UV
CA Number
Reference
关2229-07-4兴 关74-82-8兴 关124-38-9兴 关12070-15-4兴 关74-86-2兴 关74-85-11兴 关74-84-0兴 关460-12-8兴 关12595-82-3兴 关71-43-2兴 关13774-92-0兴 关13940-21-1兴 关1333-74-0兴 关7803-62-5兴
Feu00 Lac91 Jus96 Cha80 Lac89 Cer01a Wea99 Cer01a Ber89 Cer01 Mey91, Swi41 Yam00 Car70 Kea93
关12539-57-0兴 关1884-64-6兴 关12181-61-2兴 关12259-29-9兴 关56583-62-1兴 关13966-04-6兴 关23550-45-0兴
Val92 Val92 Swi50 Val92 Weh74 Lut93 A’H83
TABLE 3. List of telescope abbreviations employed in Table 4. ARO 46 m Arecibo 350 m BIMA Array BTL 7 m CAdY 13.7 m CSO 10.4 m FCRAO 14 m Hale 5 m HHT IRAM 30 m IRTF 3 m IRT 13.7 m ISO 0.6m JCMT 15 m KAO 1 m KOSMA 3m MMT MMWO 4.9 m MPI 100 m NASA-C 70 m NASA DSN 70 m NEROC 37 m 共120 ft兲 NMA Array NRAO 11 m 共12 m兲 NRAO 43 m 共140 ft兲 NRL 26 m 共85 ft兲 NRO 45 m OSO 26.6 m OSO 20 m OVRO 10.4 m Parkes 64 m Pushino 22 m PdBI Array PIROG7 SEST 15 m SRCAL 25 m TAO 6 m TRAO 14 m UKIRT 3.8 m UM/UCSD 1.5 m
Algonquin Radio Observatory, Lake Traverse, Ontario, Canada Arecibo Observatory, Puerto Rico Berkeley–Illinois–Maryland Association Array, Hat Creek Radio Observatory, Hat Creek, California Bell Telephone Laboratory, Holmdel, New Jersey Centro Astromico de Yebes, Guadalajara, Spain Caltech Submillimeter Observatory, Mauna Kea, Hawaii Five College Radio Astronomy Observatory, Quabbin Reservoir, Massachusetts Hale Telescope, Mount Palomar, California Heinrich Hertz Telescope, Mt. Graham, Arizona IRAM, Picoveleta, Spain Infrared Telescope Facility, Mauna Kea, Hawaii Itapetinga Radio Telescope, Sao Paulo, Brazil Infrared Space Observatory, European Space Agency James Clerk Maxwell Telescope, Mauna Kea, Hawaii G. P. Kuiper Airborne Observatory Ko¨lner Observatorium fu¨r Lubman-Astronomie Gornergrat, Switzerland Multiple Mirror Telescope, Mt. Lemmon, Arizona McDonald Millimeter Wave Observatory, Fort Davis, Texas Max-Planck-Institut fur Radioastronomie, Effelsberg, Germany NASA Canberra Deep Space Communications Complex, Australia NASA Goldstone Deep Space Network Telescope, Goldstone, California Northeast Radio Observatory Corporation, Haystack Observatory, Westford, Massachusetts Nobeyama Millimeter Array, University of Tokyo, Nobeyama, Japan National Radio Astronomy Observatory, Kitt Peak, Arizona National Radio Astronomy Observatory, Greenbank, West Virginia Naval Research Laboratory, Maryland Point Observatory, Maryland Nobeyama Radio Observatory, University of Tokyo, Nobeyama, Japan Onsala Space Observatory, Onsala, Sweden Onsala Space Observatory, Onsala, Sweden Owens Valley Radio Observatory, Owens Valley, California Division of Radiophysics CSIRO, Parkes, Australia Pushino, USSR IRAM Interfermeter on Plateau de Bure, De´partment des Hautes Alpes, France European Space Agency, Balloon experiment Swedish ESO Submillimeter Telescope, LaSilla, Chile SRC Appleton Laboratory, Chilbolton Observatory, Stockbridge, Hants, England Tokyo Astronomical Observatory, Tokyo, Japan Taeduk Radio Astronomy Observatory, Korea Astronomy Observatory, Whaam, Yusong, Taejon 305-348, Korea UK Infrared Telescope, Mauna Kea, Hawaii University of Minnesota/UCSD 60 in, Mt. Lemmon, Arizona
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
185
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines. Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r (K)/T a (K)
Source
Telescope
Astr. Ref.
Lab. Ref.
⌸3/2J⫽3/2 F⫽2⫺2
⫺0.6
W51
Arecibo 350 m
Ziu85
Ziu85
⌸3/2 J⫽3/2 F⫽2⫹⫺1⫺
⫺0.10
W51
Arecibo 350 m
Tur88
Tur88 Tur88
701.679 共4兲
CH
704.175*共10兲
CH
2
722.303*共10兲
CH
2
724.791 共4兲
CH
834.285*共1兲 1065.076*共0兲 1371.722*共7兲
CH3 OH CH3 CHO CH2 CHCN
1371.797*共2兲
CH2 CHCN
1371.934*共7兲
CH2 CHCN
1538.108*共3兲
2
⌸3/2J⫽3/2 F⫽1⫹⫺2⫺
⫺0.12
W51
Arecibo 350 m
Tur88
⌸3/2 J⫽3/2 F⫽1⫺1
⫺0.5
W51
Arecibo 350 m
Ziu85
Ziu85
2共1,1兲⫺2共1,2兲 F⫽1⫺1
0.58 0.3 0.012
Sgr A Sgr A Sgr B2共M兲
NRAO 43 m NRAO 43 m Parkes 64 m
Bal70 Got73 Gar75
Xu_97 Kle96 Gar75
2共1,1兲⫺2共1,2兲 F⫽3⫺3
0.034
Sgr B2共M兲
Parkes 64 m
Gar75
Gar75
2共1,1兲⫺2共1,2兲 F⫽2⫺2
0.019
Sgr B2共M兲
Parkes 64 m
Gar75
Gar75
NH2 CHO
1共1,0兲⫺1共1,1兲 F⫽1⫺1
0.08
Sgr B2共M兲
NRAO 43 m
Got73a
1538.676*共2兲
NH2 CHO
1共1,0兲⫺1共1,1兲 F⫽1⫺2
0.09
Sgr B2共M兲
NRAO 43 m
Got73a
1539.264*共2兲
NH2 CHO
1共1,0兲⫺1共1,1兲 F⫽2⫺1
0.10
Sgr B2共M兲
NRAO 43 m
Got73a
1539.527*共4兲
NH2 CHO
1共1,0兲⫺1共1,1兲 F⫽1⫺0
0.08
Sgr B2共M兲
NRAO 43 m
Got73a
1539.832*共1兲
NH2 CHO
1共1,0兲⫺1共1,1兲 F⫽2⫺2
0.36
Sgr B2共M兲
NRAO 43 m
Got73a
1540.998*共4兲
NH2 CHO
1共1,0兲⫺1共1,1兲 F⫽0⫺1
0.10
Sgr B2共M兲
NRAO 43 m
Got73a
1570.805 共5兲
NH2 13CHO
1共1,0兲⫺1共1,1兲 F⫽2⫺2
0.04
Sgr B2共M兲
Parkes 64 m
Gar80
Gar80
⫺0.05
Sgr B2共M兲
Parkes 64 m
Wil81a
Bea78
Sgr B2共M兲 Sgr B2共M兲
Parkes 64 m MPI 100 m
Bro75 Chu75
Oes99 Oes99
1584.274 共2兲 1610.247*共2兲 1610.900*共2兲 1612.2310共2兲
2
1共1,0兲⫺1共1,1兲 A⫺⫹ 1共1,0兲⫺1共1,1兲 A⫺⫹
18
2
OH CH3 OCHO CH3 OCHO OH
⌸3/2 J⫽3/2 F⫽1⫺2 1共1,0兲⫺1共1,1兲 A 1共1,0兲⫺1共1,1兲 E
0.07 0.061
⌸3/2 J⫽3/2 F⫽1⫺2
⫺0.80
OriMC⫺2
Parkes 64 m
Gar64
ter72
1624.518 共10兲
17
2
⌸3/2 J⫽3/2 F,F 1 ⫽7/2,4⫺7/2,4
⫺0.045
Sgr A
Parkes 64 m
Gar76
Got74
1626.161 共10兲
17
2
⌸3/2 J⫽3/2 F,F 1 ⫽9/2,4⫺9/2,4
⫺0.056
Sgr A
Parkes 64 m
Gar76
Got74
1637.564 共2兲
18
2
⌸3/2 J⫽3/2 F⫽1⫺1 1共1,0兲⫺1共1,1兲
⫺0.2
Sgr A
Parkes 64 m
Gar70
Lov74
18
2
⌸3/2 J⫺3/2 F⫽2⫺2
0.04 ⫺0.5
Sgr B2共M兲 Sgr A
NRA O43 m Parkes 64 m
Zuc71 Gar70
Zuc71 Lov74
1665.4018共1兲
OH OH
2
⌸3/2 J⫽3/2 F⫽1⫺1
⫺5.15
OriMC⫺2
NRAO 43 m
Wei68
ter72
1667.3590共1兲
OH
2
⌸3/2 J⫽3/2 F⫽2⫺2
⫺6.30
OriMC⫺2
NRAO 43 m
Wei63
ter72
2
⌸3/2 J⫽3/2 F⫽2⫺1
⫺0.04
Sgr B2共M兲
Parkes 64 m
Whi81
Bea78
2
⌸3/2 J⫽3/2 F⫽2⫺1
⫺1.10
1638.805 共3兲 1639.503 共2兲
1692.795 共2兲
OH OH
OH HCOOH
18
2
1720.5300共1兲
OH OH
OriMC⫺2
Parkes 64 m
Gar64
ter72
2661.61*共5兲
HC5 N
1⫺0 F⫽1⫺1
0.020
Sgr B2共M兲
Parkes 64 m
Bro76
Bro76
2662.87*共5兲
HC5 N
1⫺0 F⫽2⫺1
0.036
Sgr B2共M兲
Parkes 64 m
Bro76
Bro76
2664.76*共5兲
HC5 N
0.023
Sgr B2共M兲
Parkes 64 m
Bro76
Bro76
3139.404*共1兲 3195.162*共1兲 3263.794 共3兲
H2 CS CH3 CHO CH
1⫺0 F⫽0⫺1 2共1,1兲⫺2共1,2兲 2共1,1兲⫺2共1,2兲 A⫺⫹
⫺0.33 0.2
Sgr B2共M兲 Sgr B2共M兲
Parkes 64 m Parkes 64 m
Sin73 Fou74
Kle96
2
⌸1/2J⫽1/2 F⫽0⫺1
0.24
Cas A
OSO 25.6 m
Ryd76
Ryd74
3335.481 共2兲
CH
2
⌸1/2 J⫽1/2 F⫽1⫺1
0.25
Cas A
OSO 25.6 m
Ryd76
Ryd74
3349.193 共3兲
CH
2
⌸1/2 J⫽1/2 F⫽1⫺0
0.18
Cas A
OSO 25.6 m
Ryd76
Ryd74
4388.7786共3兲
H2 C18O
1共1,0兲⫺1共1,1兲 F⫽1⫺0
b
Sgr B2共M兲
Parkes 64 m
Gar71a
Tuc71
4388.7960*共4兲
H2 C18O
1共1,0兲⫺1共1,1兲 F⫽0⫺1
b
Sgr B2共M兲
Parkes 64 m
Gar71a
Tuc71
4388.7963共2兲
H2 C18O
1共1,0兲⫺1共1,1兲 F⫽2⫺2
n.r.c
Sgr B2共M兲
Parkes 64 m
Gar71a
Tuc71
4388.8011共2兲
H2 C18O
1共1,0兲⫺1共1,1兲 F⫽2⫺1
b
Sgr B2共M兲
Parkes 64 m
Gar71a
Tuc71
4388.8035共3兲
H2 C18O
1共1,0兲⫺1共1,1兲 F⫽1⫺2
b
Sgr B2共M兲
Parkes 64 m
Gar71a
Tuc71
4388.8084共3兲
H2 C18O
b
Sgr B2共M兲
Parkes 64 m
Gar71a
Tuc71
4592.9563共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 F⫽1⫺1 1共1,0兲⫺1共1,1兲 1/2,1/2⫺1/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4592.9738共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 1/2,1/2⫺3/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4592.9759共3兲
13
H2 CO
1共1,0兲⫺1共1,1兲 3/2,1/2⫺1/2,3/2
⫺0.1b
W33
MPI 100 m
Wil76b
Tuc71
4592.9857共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,1/2⫺5/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4592.9934共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,1/2⫺3/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0494共2兲
H2 13CO
1共1,0兲⫺1共1,1兲 1/2,1/2⫺1/2,1/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0690共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,1/2⫺1/2,1/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0800共3兲
H2 13CO
1共1,0兲⫺1共1,1兲 1/2,1/2⫺3/2,1/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0812共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 1/2,3/2⫺1/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0864共3兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,3/2⫺1/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.08654共5兲
H2 13CO
1共1,0兲⫺1共1,1兲 5/2,3/2⫺5/2,3/2
W33
MPI 100 m
Wil76b
Tuc71
4593.0942共2兲
H2 13CO
1共1,0兲⫺1共1,1兲 5/2,3/2⫺3/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0961共2兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,3/2⫺5/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0985共2兲
H2 13CO
1共1,0兲⫺1共1,1兲 1/2,3/2⫺3/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.0994共3兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,1/2⫺3/2,1/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.1039共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,3/2⫺3/2,3/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.1741共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 1/2,3/2⫺1/2,1/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.1795共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 3/2,3/2⫺1/2,1/2
b
W33
MPI 100 m
Wil76b
Tuc71
4593.2003共1兲
H2 13CO
1共1,0兲⫺1共1,1兲 5/2,3/2⫺3/2,1/2
⫺0.1b
W33
MPI 100 m
Wil76b
Tuc71
4593.2046共3兲
H2 13CO
1共1,0兲⫺1共1,1兲 1/2,3/2⫺3/2,1/2
b
W33
MPI 100 m
Wil76b
Tuc71
⫺0.55b
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
186
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 4593.2099共2兲 4617.121*共3兲
T r 共K兲/T a 共K兲
Formula
Quantum numbers
H2 13CO NH2 CHO
1共1,0兲⫺1共1,1兲 3/2,3/2⫺3/2,1/2 2共1,1兲⫺2共1,2兲 F⫽2⫺2
0.07
b
Telescope
Astr. Ref.
Lab. Ref.
W33
MPI 100 m
Wil76b
Tuc71
Sgr B2共M兲
NRAO 43 m
Rub71
Source
4618.967*共1兲
NH2 CHO
2共1,1兲⫺2共1,2兲 F⫽3⫺3
NRAO 43 m
Rub71
NH2 CHO
2共1,1兲⫺2共1,2兲 F⫽1⫺1
0.30d ⬍0.05
Sgr B2共M兲
4619.993*共3兲
Sgr B2共M兲
NRAO 43 m
Rub71
4660.242 共3兲
OH
2
⌸1/2 J⫽1/2 F⫽0⫺1
0.3
Sgr B2共M兲
NRAO 43 m
Tha70
Rad68
4750.656 共3兲
OH
2
⌸1/2 J⫽1/2 F⫽1⫺1
0.3e
Sgr B2共M兲
Parkes 64 m
Gar71
Rad68
2
⌸1/2 J⫽1/2 F⫽1⫺0
4765.562 共3兲
OH
W3
NRAO 43 m
Zuc68
Rad68
4829.6412共2兲
H2 CO
1共1,0兲⫺1共1,1兲 F⫽1⫺0
⫺0.2
TMC⫺1
NRAO 43 m
Pal69
Kuk75
1.7
4829.6587共2兲
H2 CO
1共1,0兲⫺1共1,1兲 F⫽0⫺1
b
TMC⫺1
NRAO 43 m
Pal69
Kuk75
4829.6594共2兲
H2 CO
1共1,0兲⫺1共1,1兲 F⫽2⫺2
b
TMC⫺1
NRAO 43 m
Pal69
Kuk75
4829.6639共2兲
H2 CO
1共1,0兲⫺1共1,1兲 F⫽2⫺1
⫺0.8b
TMC⫺1
NRAO 43 m
Pal69
Kuk75
4829.6664共2兲
H2 CO
1共1,0兲⫺1共1,1兲 F⫽1⫺2
b
TMC⫺1
NRAO 43 m
Pal69
Kuk75
4829.6710共2兲
H2 CO
b
TMC⫺1
NRAO 43 m
Pal69
Kuk75
4916.312 共8兲 5005.3208共2兲
HCOOH CH3 OH
1共1,0兲⫺1共1,1兲 F⫽1⫺1 2共1,1兲⫺2共1,2兲 3共1,2兲⫺3共1,3兲 A⫺⫹
0.04
Sgr B2共M兲 Sgr B2共M兲
MPI 100 m Parkes 64 m
Win75 Rob74
Win75 Heu73
5289.015*共19兲
CH2 NH
1共1,0兲⫺1共1,1兲 F⫽0⫺1
0.05
Sgr B2共M兲
Parkes 64 m
God73
5289.678*共22兲
CH2 NH
1共1,0兲⫺1共1,1兲 F⫽1⫺0
b
Sgr B2共M兲
Parkes 64 m
God73
0.05d
5289.813*共6兲
CH2 NH
1共1,0兲⫺1共1,1兲 F⫽2⫺2
0.15b
Sgr B2共M兲
Parkes 64 m
God73
5290.614*共13兲
CH2 NH
1共1,0兲⫺1共1,1兲 F⫽2⫺1
b
Sgr B2共M兲
Parkes 64 m
God73
5290.879*共11兲
CH2 NH
1共1,0兲⫺1共1,1兲 F⫽1⫺2
0.07b
Sgr B2共M兲
Parkes 64 m
God73
5291.680*共18兲
CH2 NH
1共1,0兲⫺1共1,1兲 F⫽1⫺1
0.05
Sgr B2共M兲
Parkes 64 m
God73
5324.058*共35兲
HC5 N
2⫺1 F⫽2⫺2
0.01
Sgr B2共M兲
Parkes 64 m
Gar78a
Gar78a
5324.270*共35兲
HC5 N
2⫺1 F⫽1⫺0
b
Sgr B2共M兲
Parkes 64 m
Gar78a
Gar78a
5325.330*共27兲
HC5 N
2⫺1 F⫽2⫺1
b
Sgr B2共M兲
Parkes 64 m
Gar78a
Gar78a
5325.421*共27兲
HC5 N
2⫺1 F⫽3⫺2
0.044
Sgr B2共M兲
Parkes 64 m
Gar78a
Gar78a
5327.451*共41兲
HC5 N
2⫺1 F⫽1⫺1
0.01
Sgr B2共M兲
Parkes 64 m
Gar78a
Gar78a
6016.746 共8兲
OH
2
⌸3/2 J⫽5/2 F⫽2⫺3
⫺0.12
G291.3⫺0.7
Parkes 64 m
Whi76
Rad68
6030.747 共5兲
OH
2
⌸3/2 J⫽5/2 F⫽2⫺2
7.
W3共OH兲
NRAO 43 m
Zuc72a
Mee75
6035.092 共5兲
OH
2
⌸3/2 J⫺5/2 F⫽3⫺3
20.
6049.084 共8兲
OH
2
6278.628*共3兲 6389.933*共2兲 6668.5192共8兲
H2 CS CH3 CHO CH3 OH
7761.747 共5兲
OH
2
⌸1/2 J⫽3/2 F⫽1⫺1
7820.125 共5兲
OH
2
⌸1/2 J⫽3/2 F⫽2⫺2
7895.989 共2兲
HC7 N
7⫺6 F⫽6⫺5
7896.010 共2兲
HC7 N
7896.023 共2兲
HC7 N
7987.782 共10兲
W3共OH兲
NRAO 43 m
Zuc72a
Mee75
⌸3/2 J⫽5/2 F⫽3⫺2
0.04
W33
MPI 100 m
Gar83
Bea78
3共1,2兲⫺3共1,3兲 3共1,2兲⫺3共1,3兲 A⫺⫹ 5共1,6兲⫺6共0,6兲 A⫹⫹
n.r. 0.045
Sgr B2共M兲 Sgr B2共M兲 W3共OH兲
ARO 46 m ARO 46 m NRAO 43 m
Mac75 Bel83b Men91
Kle96 Bre95
W3共OH兲
MPI 100 m
Wil90
Bal70a
W3共OH兲
MPI 100 m
Wil90
Bal70a
b
TMC⫺1
NEROC 37 m
Rod80
McC00
7⫺6 F⫽7⫺6
0.006b
TMC⫺1
NEROC 37 m
Rod80
McC00
7⫺6 F⫽8⫺7
b
TMC⫺1
NEROC 37 m
Rod80
McC00
HC5 N
3⫺2 F⫽2⫺1
0.040
TMC⫺1
NEROC 37 m
Rod80
Rod80
7987.994 共10兲
HC5 N
3⫺2 F⫽3⫺2
0.039
TMC⫺1
NEROC 37 m
Rod80
Rod80
7988.044 共10兲
HC5 N
3⫺2 F⫽4⫺3
0.055
TMC⫺1
NEROC 37 m
Rod80
Rod80
8135.870 共5兲
OH
W3共OH兲
MPI 100 m
Wil90
Mee75
3880e ⫺0.10 ⫺0.026
2
⌸1/2 J⫽5/2 F⫽2⫺2
⫺0.031
2
8189.587 共5兲
OH
⌸1/2 J⫽5/2 F⫽3⫺3
⫹0.009
W3共OH兲
MPI 100 m
Wil90
Mee75
8775.088 共10兲
CH3 NH2
2共0,2兲⫺1共0,1兲 F⫽1⫺0 Aa
0.05
Sgr B2共M兲
Parkes 64 m
Fou74a
Lov85
8777.442 共10兲
CH3 NH2
2共0,2兲⫺1共0,1兲 F⫽3⫺2 Aa
0.18
Sgr B2共M兲
Parkes 64 m
Fou74a
Lov85
8778.200 共10兲
CH3 NH2
2共0,2兲⫺1共0,1兲 F⫽2⫺2 Aa
0.04b
Sgr B2共M兲
Parkes 64 m
Fou74a
Lov85
8778.260 共10兲
CH3 NH2
2共0,2兲⫺1共0,1兲 F⫽1⫺1 Aa
b
Sgr B2共M兲
Parkes 64 m
Fou74a
Lov85
8779.496 共8兲
CH3 NH2
2共0,2兲⫺1共0,1兲 F⫽2⫺1 Aa
0.1
Sgr B2共M兲
Parkes 64 m
Fou74a
Lov85
8815.814 共6兲
H13CCCN
1⫺0 F⫽1⫺1
0.039
Sgr B2共M兲
MPI 100 m
Chu77
Chu77
8817.096 共2兲
H13CCCN
1⫺0 F⫽2⫺1
0.080
Sgr B2共M兲
MPI 100 m
Chu77
Chu77
8819.019 共9兲
H13CCCN HC7 N
1⫺0 F⫽0⫺1 8⫺7
0.025
Sgr B2共M兲
MPI 100 m
Chu77
Chu77
0.16
TMC⫺1
MPI 100 m
Tol81
9024.009*共1兲 9058.447*共6兲
HC13CCN
1⫺0 F⫽1⫺1
0.025
Sgr B2共M兲
MPI 100 m
Chu77
9059.318 共2兲
HCC13CN
1⫺0 F⫽1⫺1
n.r.
Sgr B2共M兲
MPI 100 m
Chu77
Chu77 Cre77
9059.736 共3兲
HC13CCN
1⫺0 F⫽2⫺1
0.055
Sgr B2共M兲
MPI 100 m
Chu77
Chu77
9060.6080共9兲
HCC13CN HCCCN
1⫺0 F⫽2⫺1
0.05
Sgr B2共M兲
MPI 100 m
Chu77
Cre77
9097.0346共3兲
1⫺0 F⫽1⫺1
0.82
Sgr B2共M兲
MPI 100 m
Chu77
deZ71
9098.3321共3兲
HCCCN
1⫺0 F⫽2⫺1
2.11
Sgr B2共M兲
MPI 100 m
Chu77
deZ71
9100.2727共5兲
HCCCN
0.16
Sgr B2共M兲
MPI 100 m
Chu77
deZ71
9118.823*共4兲
CH3 OCH3
1⫺0 F⫽0⫺1 2共0,2兲⫺1共1,1兲 AA
b
Sgr B2共M兲
Parkes 64 m
Win76
Gro98
9119.671*共2兲
CH3 OCH3
2共0,2兲⫺1共1,1兲 EE
0.05bg
SgrB2
Parkes 64 m
Win76
Gro98
9120.509*共2兲
CH3 OCH3
2共0,2兲⫺1共1,1兲 AE
b
Sgr B2共M兲
Parkes 64 m
Win76
Gro98
9120.527*共2兲
CH3 OCH3
2共0,2兲⫺1共1,1兲 EA
b
Sgr B2共M兲
Parkes 64 m
Win76
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
187
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U U U U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref. God84
Lab. Ref.
9235.119*共3兲
NH2 CHO
3共1,2兲⫺3共1,3兲 F⫽3⫺3
0.055
Sgr B2共M兲
NRAO 43 m
NH2 CHO
3共1,2兲⫺3共1,3兲 F⫽4⫺4
0.080
Sgr B2共M兲
NRAO 43 m
God84
9237.704*共2兲
NH2 CHO
3共1,2兲⫺3共1,3兲 F⫽2⫺2
b
Sgr B2共M兲
NRAO 43 m
God84
9486.71 9493.061*共4兲
unidentified C4 H
3/2⫺1/2 F⫽1⫺0
0.025 0.090
TMC⫺1 TMC⫺1
NRAO 43 m NRAO 43 m
Mat83a Bel83a
Got83
9496.4 共1兲 9497.616*共2兲
unidentified C4 H
3/2⫺1/2 F⫽2⫺1
0.008 0.245
CasA TMC⫺1
NRAO 43 m NRAO 43 m
Bel83 Bel83a
Got83
9508.005*共4兲
C4 H
3/2⫺1/2 F⫽1⫺1
0.080
TMC⫺1
NRAO 43 m
Bel83a
Got83
9547.953 共5兲
C4 H
1/2⫺1/2 F⫽1⫺0
0.095
TMC⫺1
NRAO 43 m
Bel83a
Gue82a
9551.717*共4兲
C4 H
1/2⫺1/2 F⫽0⫺1
0.080
TMC⫺1
NEROC 37 m
Bel83a
Got83
9562.904*共3兲
C4 H
1/2⫺1/2 F⫽1⫺1
0.115
TMC⫺1
NRAO 43 m
Bel83a
Got83
9703.508 共5兲
C6 H
2
⌸ 3/2 J⫽3.5⫺2.5 F⫽4⫺3 e
0.018
TMC⫺1
NRAO 43 m
Bel99
McC99
9703.600 共5兲
C6 H
2
⌸ 3/2 J⫽3.5⫺2.5 F⫽3⫺2 e
0.012
TMC⫺1
NRAO 43 m
Bel99
McC99
9703.835 共5兲
C6 H
2
⌸ 3/2 J⫽3.5⫺2.5 F⫽4⫺3 f
0.012
TMC⫺1
NRAO 43 m
Bel99
McC99
9703.936 共5兲
C6 H
2
TMC⫺1
NRAO 43 m
Bel99
McC99
HC9 N CCCN
⌸ 3/2 J⫽3.5⫺2.5 F⫽3⫺2 f 17⫺16
0.009
9877.606*共1兲 9885.89* 共1兲
TMC⫺1 TMC⫺1
NRAO 43 m ARO 46 m
Bel98 Mac81a
Gue82a
9936.202 共4兲
CH3 OH
1⫺0 J⫽3/2⫺1/2 F⫽5/2⫺3/2 9共⫺1,9兲⫺8共⫺2,7兲 E
0.025 0.02 0.25e
OriMC⫺1
NRAO 43 m
Sly93
Bre95
9978.686 共4兲
CH3 OH
4共3,2兲⫺5共2,3兲 E
0.04e
Sgr B2共M兲
NRAO 43 m
Sly93
Bre95
10058.257 共12兲
CH3 OH
4共3,1兲⫺5共2,4兲 E
NRAO 43 m
Sly93
Bre95
HC7 N HDO HC9 N H2 CS CH3 CHO HC5 N
9⫺8 2共2,0兲⫺2共2,1兲 18⫺17
0.17e 0.08 0.032 0.021
W33⫺Met
10152.008*共1兲 10278.246 共1兲 10458.639*共1兲 10463.962*共5兲
TMC⫺1 OriMC⫺1 TMC⫺1
ARO 46 m NRAO 43 m ARO 46 m
Kro78 Pet88 Bro78
Kuk77
Sgr B2共M兲 Sgr B2共M兲 TMC⫺1
ARO 46 m ARO 46 m NRO 45 m
Doh74 Bel83b Tak90
Kle91
4⫺3 F⫽3⫺2
⫺0.040 0.021 0.13 0.24b
TMC⫺1
NRO 45 m
Tak90
b
TMC⫺1
NRO 45 m
Tak90
TMC⫺1 TMC⫺1 TMC⫺1 Sgr B2共M兲 345.01⫹1.79
NRO 45 m NRO 45 m NRO 45 m NRAO 43 m Parkes 64 m
Ohi98 Ohi98 Ohi98 Mat87a Nor87
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 Sgr B2共M兲 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 DR21
NRO 45 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m MPI 100 m
Ohi98 Bel97 Bel97 Bel97 Cla78 Bel99 Bel99 Bel97 Bel97 Bel97 Bel97 Bel97 Gui84
3.2
W3共OH兲
NRAO 43 m
Tur70
0.475 ⫺0.47
TMC⫺1 Sgr B2共M兲
NRAO 43 m MPI 100 m
Bel97 Hen83a
TMC⫺1 TMC⫺1
NRAO 43 m NRAO 43 m
Bel85 Bel85
Bel85
b
Sgr B2共M兲
NRL 26 m
Eva70
Kuk75
4共1,3兲⫺4共1,4兲 4共1,3兲⫺4共1,4兲 A⫺⫹
10650.654*共5兲
HC5 N
4⫺3 F⫽4⫺3
10650.686*共5兲
HC5 N
11119.445*共2兲 11280.006*共1兲 11561.513*共1兲 12162.979 共1兲 12178.593 共4兲
CCS HC7 N CCCS OCS CH3 OH
4⫺3 F⫽5⫺4 1,0⫺0,1 10⫺9 2⫺1 1⫺0 2共0,2兲⫺3共⫺1,3兲 E
12408.003*共1兲 12782.769*共1兲 12848.48 12848.731*共2兲 13043.814 共4兲 13116.451 13116.569 13186.46 13186.853*共3兲 13186.98 13313.312*共1兲
HC7 N HC9 N unidentified HC11N SO unidentified unidentified unidentified HC11N unidentified HC5 N HC9 N
13363.801*共1兲 13434.596 共10兲
U
Quantum numbers
9237.034*共1兲
10648.419 共4兲 10650.563*共5兲
U
Formula
11⫺10 22⫺21 38⫺37 1共2兲⫺1共1兲
39⫺38 5⫺4 23⫺22
OH
2
⌸3/2 J⫽7/2 F⫽3⫺3
13441.4173共2兲
OH
2
13535.998*共1兲 13778.804*共1兲
HC7 N
⌸3/2 J⫽7/2 F⫽4⫺4 12⫺11 2共1,1兲⫺2共1,2兲
0.39 0.14 0.12 0.115 429.e 0.09 0.081 0.007 0.009 0.4 0.003 0.003 0.005 0.005 0.006 1.77 0.082 ⫺0.20
Kuk74 Lov88
Lov92
Des75 ter76
13880.54 13944.832*共1兲 14488.4589共2兲
H2 13CO unidentified HC9 N H2 CO
2共1,1兲⫺2共1,2兲 F⫽1⫺1
14488.4712共2兲
H2 CO
2共1,1兲⫺2共1,2兲 F⫽1⫺2
b
Sgr B2共M兲
NRL 26 m
Eva70
Kuk75
14488.4801共2兲
H2 CO
2共1,1兲⫺2共1,2兲 F⫽3⫺3
⫺1.3b
Sgr B2共M兲
NRL 26 m
Eva70
Kuk75
14488.4899共2兲
H2 CO
b
Sgr B2共M兲
NRL 26 m
Eva70
Kuk75
14525.862*共1兲 14663.993*共1兲 14686.634 共4兲
HC9 N HC7 N
2共1,1兲⫺2共1,2兲 F⫽2⫺2 25⫺24 13⫺12
0.073 0.06
TMC⫺1 TMC⫺1
NRAO 43 m Parkes 64 m
Bro78 Gar78
c⫺C3 H
1共1,0兲⫺1共1,1兲 J⫽1/2⫺1/2 F⫽1⫺1
0.04
TMC⫺1
NRO 45 m
Ohi98
Lov92a
14767.700 共8兲
c⫺C3 H
1共1,0兲⫺1共1,1兲 J⫽1/2⫺3/2 F⫽1⫺2 2共0,2兲⫺3共⫺1,3兲 E
0.04
TMC⫺1
NRO 45 m
Ohi98
Lov92a
0.30
Sgr B2共M兲
NASA⫺c 70 m
Kui89
Xu_97
NRO 45 m
Ohi98
Lov92a
14782.212*共19兲
13
CH3 OH
24⫺23
0.014 0.058
14812.002共8兲
c⫺C3 H
1共1,0兲⫺1共1,1兲 J⫽3/2⫺1/2 F⫽2⫺1
0.04
TMC⫺1
14877.671共8兲
c⫺C3 H
1共1,0兲⫺1共1,1兲 J⫽3/2⫺3/2 F⫽2⫺1
0.04
TMC⫺1
NRO 45 m
Ohi98
Lov92a
14893.050共4兲
c⫺C3 H
1共1,0兲⫺1共1,1兲 J⫽3/2⫺3/2 F⫽2⫺2
0.124
TMC⫺1
NRAO 43 m
Man90a
Lov92
14895.243共8兲
c⫺C3 H HC9 N C6 H
1共1,0兲⫺1共1,1兲 J⫽3/2⫺3/2 F⫽1⫺1 26⫺25
0.065
TMC⫺1
NRAO 43 m
Man90a
Lov92
0.07
TMC⫺1
NRO 45 m
Ohi98
⌸3/2 J⫽11/2⫺9/2 F⫽6⫺5 f
0.04
TMC⫺1
NRO 45 m
Ohi98
15106.892*共1兲 15248.225*共13兲
2
JPL01
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
188
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U U U U U U U U U U U U U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
15248.359*共17兲
C6 H
2
⌸3/2 J⫽11/2⫺9/2 F⫽5⫺4 f
0.03
TMC⫺1
NRO 45 m
Ohi98
JPL01
C6 H
2
⌸3/2 J⫽11/2⫺9/2 F⫽6⫺5 e
0.05
TMC⫺1
NRO 45 m
Ohi98
JPL01
15249.198*共17兲
C6 H
2
TMC⫺1
NRO 45 m
Ohi98
JPL01
0.07 0.32 0.61
TMC⫺1 TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m NRO 45 m
Ohi98 Ohi98 Ohi98
16849.979*共1兲 16886.312*共2兲
HC9 N HC7 N HC5 N HC9 N HC9 N DCCCN
⌸3/2 J⫽11/2⫺9/2 F⫽5⫺4 e 27⫺26 14⫺13 6⫺5
0.04
15687.921*共1兲 15791.986*共1兲 15975.966*共1兲 16268.950*共1兲
28⫺27 29⫺28
0.07 0.07 0.04
TMC⫺1 TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m NRO 45 m
Ohi98 Ohi98 Ohi98
Laf78
16886.405*共2兲
DCCCN
Laf78
16919.979*共1兲 17091.742*共1兲 17342.256*共1兲 17431.006*共1兲 17632.685*共7兲
2⫺1 F⫽2⫺1
0.08
TMC⫺1
NRO 45 m
Ohi98
HC7 N CH3 CCH CCCS HC9 N
2⫺1 F⫽3⫺2 15⫺14 1共0兲⫺0共0兲 3⫺2 30⫺59
0.32 0.07 0.27 0.07
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRO NRO NRO NRO
m m m m
Ohi98 Ohi98 Ohi98 Ohi98
45 45 45 45
H13CCCN
2⫺1 F⫽2⫺2
0.02
TMC⫺1
NRO 45 m
Ohi98
2⫺1 F⫽3⫺2
0.03
TMC⫺1
NRO 45 m
Ohi98
Laf78
17647.479 共10兲
H13CCCN C4 D
5/2⫺3/2 F⫽5/2⫺3/2
0.03
TMC⫺1
NRAO 43 m
Tur89a
Tur89a
17647.526 共10兲
C4 D
5/2⫺3/2 F⫽3/2⫺1/2
0.03
TMC⫺1
NRAO 43 m
Tur89a
Tur89a
17647.716 共10兲
C4 D
0.05
TMC⫺1
NRAO 43 m
Tur89a
Tur89a
17666.995*共5兲
HCCC15N C4 D
5/2⫺3/2 F⫽7/2⫺5/2 2⫺1
0.04
TMC⫺1
NRO 45 m
Ohi98
Laf78
3/2⫺1/2 F⫽5/2⫺3/2
0.04
TMC⫺1
NRAO 43 m
Tur89a
Tur89a
3/2⫺1/2 F⫽3/2⫺1/2
0.02
TMC⫺1
NRAO 43 m
Tur89a
Tur89a
W51 W51 TMC⫺1 W51 W51 W51 W51 W51 TMC⫺1 W51 W51 TMC⫺1
NRAO 43 m NRAO 43 m NASADSN 70 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m
Bel93 Bel93 Lan97 Bel93 Bel93 Bel93 Bel93 Bel93 Bel98 Bel93 Bel93 Bel99
Poy75 McC99
17683.961共10兲
U U U U
Quantum numbers
15249.064*共13兲
17633.844*共4兲
U
Formula
17684.662共10兲
C4 D
17736.75 17788.570*共3兲 17863.803*共3兲 17937.956*共4兲 17945.85 17951.95 17965.09 17974.01 18012.033*共1兲 18012.46 18017.337*共5兲 18020.574共5兲
unidentified H2 CCCC H2 CCCC H2 CCCC unidentified unidentified unidentified unidentified HC9 N unidentified NH3 C6 H
18020.644共5兲 18021.752共5兲
Laf78
2
⌸3/2 J⫽6.5⫺5.5 F⫽7⫺6 e
0.017 0.021 0.12 0.012 0.013 0.012 0.017 0.027 0.061 0.009 0.015 0.044
C6 H
2
⌸3/2 J⫽6.5⫺5.5 F⫽6⫺5 e
0.046
TMC⫺1
NRAO 43 m
Bel99
McC99
C6 H
2
⌸3/2 J⫽6.5⫺5.5 F⫽7⫺6 f
0.050
TMC⫺1
NRAO 43 m
Bel99
McC99
18021.818共5兲
C6 H
2
⌸3/2 J⫽6.5⫺5.5 F⫽6⫺5 f
0.042
TMC⫺1
NRAO 43 m
Bel99
McC99
18021.86 18047.969*共1兲 18119.029*共5兲
unidentified HC7 N
16⫺15
HC13CCN
2⫺1 F⫽2⫺1
0.069 0.37 0.022
W51 TMC⫺1 TMC⫺1
NRAO 43 m NRO 45 m NRO 45 m
Bel93 Ohi98 Tak98
Laf78
18120.773*共2兲
HCC13CN
2⫺1 F⫽2⫺1
0.033
TMC⫺1
NRO 45 m
Tak98
Laf78
18120.865*共2兲
2⫺1 F⫽3⫺2 1⫺0
0.06
TMC⫺1
NRO 45 m
Ohi98
Laf78
18154.884*共1兲 18186.652*共3兲
HCC13CN SiS C8 H
IRC⫹10216 TMC⫺1
MPI 100 m NRAO 43 m
Gra81 Bel99
McC97
18186.782*共3兲
C8 H
TMC⫺1
NRAO 43 m
Bel99
McC97
18194.9206*共8兲
HCCCN
2⫺1 F⫽2⫺2
b
Sgr B2共M兲
Parkes 64 m
McG77
Laf78
18195.3176*共6兲
HCCCN
2⫺1 F⫽1⫺0
b
Sgr B2共M兲
Parkes 64 m
McG77
Laf78
18196.2183*共5兲
HCCCN
2⫺1 F⫽2⫺1
0.36b
Sgr B2共M兲
Parkes 64 m
McG77
Laf78
18196.3119*共7兲
HCCCN
2⫺1 F⫽3⫺2
b
Sgr B2共M兲
Parkes 64 m
McG77
Laf78
18197.078*共1兲
HCCCN
2⫺1 F⫽1⫺2
b
Sgr B2共M兲
Parkes 64 m
McG77
Laf78
18198.3756*共9兲
HCCCN
2⫺1 F⫽1⫺1
b
Sgr B2共M兲
Parkes 64 m
McG77
Laf78
18222.65 18285.434*共5兲 18294.20 18299.5 18306.3 18320.7 18343.144*共1兲
unidentified NH3 unidentified unidentified unidentified unidentified
10共7兲⫺10共7兲
0.017 0.012
W51 W51
NRAO 43 m NRAO 43 m
Bel93 Bel93
Poy75
1共1,0兲⫺1共0,1兲
0.007 0.008 0.005 0.006 1.82
W51 W51 W51 W51 TMC⫺1
NRAO NRAO NRAO NRAO NRAO
43 43 43 43 43
m m m m m
Bel93 Bel93 Bel93 Bel93 Mat85a
6共1兲⫺6共1兲
0.007 0.003 0.003 0.003 0.004 0.006 0.005 0.005 0.006
W51 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 W51 W51 W51 W51
NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO
43 43 43 43 43 43 43 43 43
m m m m m m m m m
Bel93 Bel99 Bel99 Bel99 Bel99 Bel93 Bel93 Bel93 Bel93
18360.50 18363.045 18363.142 18363.306 18363.406 18368.0 18379.6 18383.3 18391.562*共5兲
2共1,2兲⫺1共1,1兲 2共0,2兲⫺1共0,1兲 2共1,1兲⫺1共1,0兲
31⫺30 7共3兲⫺7共3兲
2
⌸3/2 15.5⫺15.5 e
1.0 0.007
2
⌸3/2 15.5⫺15.5 f
0.007
c⫺C3 H2 unidentified unidentified unidentified unidentified unidentified unidentified unidentified unidentified NH3
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Poy76
MICROWAVE TRANSITIONS
189
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U
U U U
U U U U U
U U
U U
U U U U
U U U U
U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref. Bou80
18396.7252*共7兲
CH3 CN
1共0兲⫺0共0兲 F⫽1⫺1
0.081
TMC⫺1
NRAO 43 m
Mat83
18397.9965*共6兲
CH3 CN
1共0兲⫺0共0兲 F⫽2⫺1
0.120
TMC⫺1
NRAO 43 m
Mat83
Bou80
18399.8924*共3兲
CH3 CN
0.031
TMC⫺1
NRAO 43m
Mat83
Bou80
18413.822*共2兲
0.09
TMC⫺2
MPI 100 m
Cox89
18422.00 18485.07 18494.1共1兲 18499.390 共5兲 18513.316*共5兲
c⫺H13CCCH unidentified unidentified CH3 SH NH3 CH2 CHCN
1共0兲⫺0共0兲 F⫽0⫺1 1共1,0兲⫺1共0,1兲
0.012 0.016 0.014 0.3 0.021
W51 W51 W51 W51 TMC⫺1
NRAO NRAO NRAO NRAO NRAO
Bel93 Bel93 Bel93 Mad86 Mat83a
18586.06 18593.060*共1兲 18638.616*共1兲 18650.308*共4兲 18673.312*共36兲 18698.16 18729.12 18793.92 18802.235*共5兲 18807.888共10兲 18808.507共5兲 18817.66 18864.65 18884.695共5兲 18907.54 18918.50 18961.79 18965.588*共4兲
unidentified HC9 N HC5 N HCCCHO HNCCC unidentified unidentified unidentified H2 CCCCCC NH2 D NH3 unidentified unidentified NH3 unidentified unidentified unidentified CH2 CHCN
2共0,2兲⫺1共0,1兲 F⫽1⫺0
0.012 0.003 0.5 0.012 0.19 0.009 0.021 0.021 0.01 0.2 0.39 0.017 0.015 0.50 0.013 0.011 0.011 0.010
W51 IRC⫹10216 TMC⫺1 TMC⫺1 TMC⫺1 W51 W51 W51 TMC⫺1 OriMC⫺1 OriMC⫺1 W51 W51 OriMC⫺1 W51 W51 W51 TMC⫺1
NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRO 45 m NRAO 43 m NRAO 43 m NRAO 43 m NASADSN 70 m MPI 100 m MPI 100 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m
Bel93 Bel92b Jen82 Irv88 Ohi98 Bel93 Bel93 Bel93 Lan97 Wal87 Her88 Bel93 Bel93 Her88 Bel93 Bel93 Bel93 Mat83a
18966.535*共5兲
CH2 CHCN
2共0,2兲⫺1共0,1兲 F⫽2⫺1
0.032
TMC⫺1
NRAO 43 m
Mat83a
18966.616*共4兲
CH2 CHCN
2共0,2兲⫺1共0,1兲 F⫽3⫺2
0.045
TMC⫺1
NRAO 43 m
Mat83a
18968.48 18986.20 19014.7204共15兲
unidentified unidentified C4 H
5/2⫺3/2 F⫽2⫺1
0.011 0.013 0.44
TMC⫺1 W51 TMC⫺1
NRAO 43 m NRAO 43 m NRAO 43 m
Mat83a Bel93 Gue82a
Gue82a
19015.1435共15兲
C4 H
5/2⫺3/2 F⫽3⫺2
0.65
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
19025.107 共4兲
C4 H
5/2⫺3/2 F⫽2⫺2
0.048
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
19039.50 19043.0 19044.760 共4兲
unidentified unidentified C4 H
3/2⫺1/2 F⫽1⫺1
0.020 0.010 0.055
W51 W51 TMC⫺1
NRAO 43 m NRAO 43 m NRAO 43 m
Bel93 Bel93 Gue82a
Gue82a
19054.4762共15兲
C4 H
3/2⫺1/2 F⫽2⫺1
0.42
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
19055.9468共15兲
C4 H
3/2⫺1/2 F⫽1⫺0
0.15
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
19099.656 共6兲
C4 H
3/2⫺3/2 F⫽1⫺1
0.039
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
19119.764*共5兲
C4 H
0.05
TMC⫺1
NRO 45 m
Ohi98
JPL01
19174.086*共1兲 19175.958*共2兲 19218.465 共5兲 19243.521*共2兲 19262.140 共4兲 19265.137*共1兲 19316.70 19325.20 19336.10 19361.50 19418.661 共2兲
HC9 N HC7 N NH3 CCCO CH3 CHO CH3 CHO
J⫽3/2⫺3/2 F⫽2⫺2 33⫺32 17⫺16 7共4兲⫺7共4兲 2⫺1 1共0,1兲⫺0共0,0兲 E 1共0,1兲⫺0共0,0兲 A⫹⫹
0.003 0.465 0.6 0.035 0.014 0.016
IRC⫹10216 TMC⫺1 OriMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m NRAO 43 m NRAO 43 m
Mat85 Mat85 Her88 Mat84 Mat85 Mat85
W51 W51 W51 W51 L1498
NRAO NRAO NRAO NRAO NRAO
m m m m m
Bel93 Bel93 Bel93 Bel93 Bel87
Bel87
18共2兲⫺17共3兲 A⫹ 9共6兲⫺9共6兲 2共1,2兲⫺1共1,1兲 F⫽3⫺2 32⫺31 7⫺6 2共0,2兲⫺1共0,1兲 2⫺1
7共1,7兲⫺6共1,6兲 3共1,3兲⫺3共0,3兲 8共5兲⫺8共5兲
6共2兲⫺6共2兲
unidentified unidentified unidentified unidentified
43 43 43 43 43
Lee80 Poy75
Coh82 Poy75
Poy75
Poy75 Kle91 Kle96
c⫺C3 HD
1共1,0兲⫺1共0,1兲 F⫽1⫺1
0.013 0.007 0.014 0.008 0.014
19418.686 共1兲
c⫺C3 HD
1共1,0兲⫺1共0,1兲 F⫽2⫺1
0.032
L1498
NRAO 43 m
Bel87
Bel87
19418.712 共1兲
c⫺C3 HD
1共1,0兲⫺1共0,1兲 F⫽1⫺2
0.043
L1498
NRAO 43 m
Bel87
Bel87
19418.724 共1兲
c⫺C3 HD
1共1,0兲⫺1共0,1兲 F⫽0⫺1
0.034
L1498
NRAO 43 m
Bel87
Bel87
19418.740 共1兲
c⫺C3 HD
1共1,0兲⫺1共0,1兲 F⫽2⫺2
0.088
L1498
NRAO 43 m
Bel87
Bel87
19418.796 共2兲
1共1,0兲⫺1共0,1兲 F⫽1⫺0
0.021
L1498
NRAO 43 m
Bel87
Bel87
19426.679*共4兲
c⫺C3 HD CH2 CHCN
2共1,1兲⫺1共1,0兲 F⫽2⫺1
0.010
TMC⫺1
NRAO 43 m
Mat83a
19427.851*共4兲
CH2 CHCN
2共1,1兲⫺1共1,0兲 F⫽3⫺2
0.021
TMC⫺1
NRAO 43 m
Mat83a
19429.098*共7兲
CH2 CHCN
2共1,1兲⫺1共1,0兲 F⫽1⫺0
0.010
TMC⫺1
NRAO 43 m
Mat83a
19430.85 19609.78 19682.50 19692.50 19755.111*共1兲 19757.538 共5兲 19771.50 19780.800 共3兲
unidentified unidentified unidentified unidentified HC9 N NH3 unidentified CCCN
0.005 0.018 0.012 0.011 0.003 1.2 0.015 0.058
W51 W51 W51 W51 IRC⫹10216 OriMC⫺1 W51 TMC⫺1
NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m NRAO 43 m
Bel93 Bel93 Bel93 Bel93 Bel92b Her88 Bel93 Gue82a
34⫺33 6共3兲⫺6共3兲 2⫺1 J⫽5/2⫺3/2 F⫽5/2⫺3/2
43 43 43 43 43
m m m m m
Poy75 Gue82a
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
190
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
Source
Telescope
Astr. Ref.
Lab. Ref.
0.050
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
0.094
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
2⫺1 J⫽5/2⫺3/2 F⫽3/2⫺1/2
0.022
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
2⫺1 J⫽5/2⫺3/2 F⫽5/2⫺3/2 5共1兲⫺5共1兲 2⫺1 2共1,1兲⫺3共0,3兲 E
0.055
TMC⫺1
NRAO 43 m
Gue82a
Gue82a
OriMC⫺1 TMC⫺1 W3共OH兲 W51 W51 TMC⫺1 TMC⫺1
MPI 100 m NRO 45 m MPI 100 m NRAO 43 m NRAO 43 m NRO 45 m NRAO 43 m
Her88 Ohi98 Wil85 Bel93 Bel93 Ohi98 Irv88a
Poy75
1⫺03/2⫺1/25/2⫺3/25/2⫺5/2 1⫺01/2⫺1/23/2⫺3/25/2⫺5/2
0.56 0.08 73.2 0.007 0.009 0.05 0.060
1⫺03/2⫺1/25/2⫺3/23/2⫺1/2 1⫺03/2⫺1/25/2⫺3/25/2⫺3/2 1⫺03/2⫺1/21/2⫺1/23/2⫺3/2 1⫺03/2⫺1/25/3⫺3/27/2⫺5/2 1⫺03/2⫺1/23/2⫺3/23/2⫺3/2 1⫺03/2⫺1/21/2⫺1/23/2⫺3/2
0.050 0.111 0.030 0.160 0.050 0.030
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRAO NRAO NRAO NRAO NRAO NRAO
m m m m m m
Irv88a Irv88a Irv88a Irv88a Irv88a Irv88a
Irv88a Irv88a Irv88a Irv88a Irv88a Irv88a
1⫺01/2⫺1/23/2⫺1/23/2⫺1/2
b
TMC⫺1
NRAO 43 m
Irv88a
Irv88a
1⫺03/2⫺1/23/2⫺3/21/2⫺1/2 1⫺03/2⫺1/23/2⫺1/23/2⫺3/2 1⫺01/2⫺1/23/2⫺3/25/2⫺3/2 1⫺03/2⫺1/23/2⫺3/23/2⫺1/2
0.020 0.080 0.020 0.01
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRAO 43 m NRAO 43 m NRAO 43 m NRO 45 m
Irv88a Irv88a Irv88a Ohi98
Irv88a Irv88a Irv88a Ohi98
1⫺01/2⫺1/23/2⫺1/23/2⫺3/2 1⫺01/2⫺1/21/2⫺3/23/2⫺5/2
TMC⫺1 TMC⫺1 W51 W3共OH兲 W51 TMC⫺1 W51 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 SgrB2共N兲 OriMC⫺1 W51 TMC⫺1 TMC⫺1
NRO 45 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m NRAO 43 m NRAO 43 m NRO 45 m NRAO 43 m MPI 100 m MPI 100 m MPI 100 m MPI 100 m NRAO 43 m NRAO 43 m NRAO 43 m
Ohi98 Irv88a Bel93 Men86a Bel93 Mat86 Bel93 Ohi98 Bel98 Wal84 Wal84 Wal84 Hen87 Bel93 Bel99 Bel99
Ohi98 Irv88a
⌸3/2 17.5⫺16.5
0.06 0.060 0.010 ⫺0.65 0.007 0.017 0.013 0.43 0.035 0.073 0.077 0.9 0.16 0.008 0.006 0.005
McC97
⌸3/2 17.5⫺16.5
0.004 0.004
TMC⫺1 TMC⫺1
NRAO 43 m NRAO 43 m
Bel99 Bel99
McC97
0.004 0.043 0.011 0.7 0.017 0.014 0.25 0.014
TMC⫺1 TMC⫺1 W51 OriMC⫺1 W51 W51 OriMC⫺1 W51
NRAO 43 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m
Bel99 Bro84 Bel93 Her88 Bel93 Bel93 Her88 Bel93
1共0,1兲⫺0共0,0兲
0.007 0.233
W51 TMC⫺1
NRAO 43 m MPI 100 m
Bel93 Cer87a
Formula
Quantum numbers
19780.826 共4兲
CCCN
2⫺1 J⫽5/2⫺3/2 F⫽3/2⫺1/2
19781.094 共3兲
CCCN
2⫺1 J⫽5/2⫺3/2 F⫽7/2⫺5/2
19799.951 共5兲
CCCN
19800.121 共3兲
CCCN
19838.346 共5兲 19871.344*共2兲 19967.396 共2兲 19974.50 20064.21 20109.547 20115.77 20117.43
NH3 HCCNC CH3 OH unidentified unidentified CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN
20118.014 20118.16 20119.606 20121.61 20123.96 20124.22
T r 共K兲/T a 共K兲
43 43 43 43 43 43
Meh85
Ohi98 Irv88a
20139.76 20168.48 20171.089 共2兲 20203.31 20209.209*共5兲 20281.00 20303.946*共2兲 20336.135*共2兲 20357.226 共14兲 20357.423共14兲 20371.45共10兲 20460.01共10兲 20501.5 20533.235 20533.289*共3兲
CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN unidentified CH3 OH unidentified CH2 CO unidentified HC7 N HC9 N CH3 C4 H CH3 C4 H NH3 HDO unidentified unidentified C8 H
U
20533.338 20533.454*共3兲
unidentified C8 H
U
20533.660 20657.337*共3兲 20707.80 20719.221共5兲 20723.5 20728.67 20735.452共5兲 20765.80
unidentified CH3 CCCN unidentified NH3 unidentified unidentified NH3 unidentified
20790.00 20792.563*共5兲 20792.872*共5兲
unidentified H2 CCC C6 H
2
⌸3/2 J⫽15/2⫺13/2 F⫽8⫺7 e
0.40
TMC⫺1
MPI 100 m
Gue87
Gue87
20792.945*共5兲
C6 H
2
⌸3/2 J⫽15/2⫺13/2 F⫽7⫺6 e
0.36
TMC⫺1
MPI 100 m
Gue87
Gue87
20794.444*共5兲
C6 H
2
⌸3/2 J⫽15/2⫺13/2 F⫽8⫺7 f
0.37
TMC⫺1
MPI 100 m
Gue87
Gue87
20794.512 共5兲
C6 H
2
0.38
TMC⫺1
MPI 100 m
Gue87
Gue87
20804.830 共5兲 20838.20 20847.50 20852.527 共5兲 20878.00
NH3 unidentified unidentified NH3 unidentified
⌸3/2 J⫽15/2⫺13/2 F⫽7⫺6 f 7共5兲⫺7共5兲
0.8 0.006 0.003 0.17 0.006
OriMC⫺1 W51 W51 OriMC⫺1 W51
MPI 100 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m
Her88 Bel93 Bel93 Her88 Bel93
Poy75
20908.848*共21兲 20917.157*共2兲 20970.658*共37兲 20994.617 共5兲 20999.79 21070.739 共5兲 21134.311 共5兲 21143.18 21231.00 21285.275共5兲 21301.261*共1兲
CH3 OH HC9 N CH3 OH NH3 unidentified NH3 NH3 unidentified unidentified NH3 HC5 N
0.007 0.07 0.2 1.0 0.009 0.13 0.9 0.017 ⫺0.013 2.1 0.031
W51 TMC⫺1 W3共OH兲 OriMC⫺1 W51 OriMC⫺1 OriMC⫺1 W51 W51 OriMC⫺1 Sgr B2共M兲
NRAO 43 m NRO 45 m MPI 100 m MPI 100 m NRAO 43 m MPI 100 m MPI 100 m NRAO 43 m NRAO 43 m MPI 100 m ARO 46 m
Bel93 Ohi98 Men86a Her88 Bel93 Mau87 Her88 Bel93 Bel93 Her88 Bro76
20124.22 20124.45 20124.49 20126.031 20128.770 共4兲 U U U
U U
U U U U U
U U U
U
U U
11共1,11兲⫺10共2,8兲 A⫹ 1共0,1兲⫺0共0,0兲 18⫺17 35⫺34 5共1兲⫺4共1兲 5共0兲⫺4共0兲 5共2兲⫺5共2兲 3共2,1兲⫺4共1,4兲
2
2
5共0兲⫺4共0兲 8共6兲⫺8共6兲
9共7兲⫺9共7兲
10共8兲⫺10共8兲 16共⫺4,13兲⫺15共⫺5,10兲 E 36⫺35 10共1,10兲⫺11共,9兲 A⫹ vt ⫽1 6共4兲⫺6共4兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
11共9兲⫺11共9兲 4共1兲⫺4共1兲
5共3兲⫺5共3兲 8⫺7
Meh85
Wal84 Wal84 Poy75 Bel70
Poy75
Poy75
Poy75 Xu_97 Xu_97 Poy75 Poy75 Poy75
Poy75
MICROWAVE TRANSITIONS
191
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U U U U
U U U U U U U U U U
Frequency 共Unc.兲 共MHz兲
Formula
21322.50 21431.932*共2兲 21447.8 21453.93 21470.4 21480.809共2兲
unidentified HC7 N unidentified unidentified unidentified C5 H
2
21481.299共2兲
C5 H
2
21484.695共2兲
C5 H
21485.248共2兲
C5 H
21488.255*共5兲 21498.182*共2兲 21546.94 21550.342*共42兲 21569.5 21576.5 21582.6 21587.400*共1兲 21592.1 21595.8 21598.4 21606.30 21615.5 21703.3580共2兲 21715.8 21930.476*共6兲
U
Astr. Ref.
Lab. Ref.
⌸1/2 J⫽9/2⫺7/2 F⫽5⫺4 e
⫺0.010 0.89 0.005 ⫺0.010 0.007 0.08f
W51 TMC⫺1 W51 W51 W51 TMC⫺1
NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m MPI 100 m
Bel93 Buj81 Bel93 Bel93 Bel93 Cer87
McC99
⌸1/2 J⫽9/2⫺7/2 F⫽4⫺3 e
0.06f
TMC⫺1
MPI 100 m
Cer87
McC99
2
⌸1/2 J⫽9/2⫺7/2 F⫽5⫺4 f
0.07f
TMC⫺1
MPI 100 m
Cer87
McC99
2
⌸1/2 J⫽9/2⫺7/2 F⫽4⫺3 f 8共1,8兲⫺7共1,7兲 37⫺36
0.06f
TMC⫺1
MPI 100 m
Cer87
McC99
0.01 0.06 0.006 ⫺0.4 0.008 0.005 0.003 ⫺0.54 0.004 0.005 0.006 0.005 0.003 0.6 0.008 0.07
TMC⫺1 TMC⫺1 W51 W3共OH兲 W51 W51 W51 TMC⫺1 W51 W51 W51 W51 W51 OriMC⫺1 W51 TMC⫺1
NASADSN 70 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m MPI 100 m NRAO 43 m NRO 45 m
Lan97 Buj81 Bel93 Men86a Bel93 Bel93 Bel93 Mat86a Bel93 Bel93 Bel93 Bel93 Bel93 Nys78 Bel93 Ohi98
19⫺18
12共2,11兲⫺11共1,11兲 A⫹ vt ⫽1
2共2,0兲⫺2共1,1兲
4共2兲⫺4共2兲 2,1⫺1,0
Xu_97
Kuk70
CC34S HNCO
1共0,1兲⫺0共0,0兲 F⫽0⫺1
0.025
TMC⫺1
NRAO 43 m
Bro81
Kuk71
21981.4706共1兲
HNCO
1共0,1兲⫺0共0,0兲 F⫽2⫺1
0.107
TMC⫺1
NRAO 43 m
Bro81
Kuk71
21982.0854共1兲
HNCO
0.040
TMC⫺1
NRAO 43 m
Bro81
Kuk71
22079.204*共2兲 22235.044共5兲
HC9 N H2 O
1共0,1兲⫺0共0,0兲 F⫽1⫺1 38⫺37
0.07
6共1,6兲⫺5共2,3兲 F⫽7⫺6
b
TMC⫺1 W49
NRO 45 m NRAO 43 m
Ohi98 Mor73
Kuk69
22235.077共5兲
H2 O
6共1,6兲⫺5共2,3兲 F⫽6⫺5
b
W49
NRAO 43 m
Mor73
Kuk69
22235.120共5兲
H2 O
6共1,6兲⫺5共2,3兲 F⫽5⫺4
2000i
W49
NRAO 43 m
Mor73
Kuk69
22235.253共5兲
H2 O
6共1,6兲⫺5共2,3兲 F⫽6⫺6
b
W49
NRAO 43 m
Mor73
Kuk69
22235.298共5兲
H2 O
6共1,6兲⫺5共2,3兲 F⫽5⫺5 2,1⫺1,0 5共3,2兲⫺5共3,3兲 2,1⫺1,0 1共0,1兲⫺0共0,0兲 20⫺19
b
W49
NRAO 43 m
Mor73
Kuk69
NRAO 43 m MPI 100 m NRO 45 m NRAO 43 m NRO 45 m MPI 100 m
Ohi91 Hen87 Kai87 Irv90 Suz92 Her85
15
1共1兲⫺1共1兲 F,F 1 ⫽1.5,1⫺1.3,1
b
TMC⫺1 OriMC⫺1 TMC⫺1 L134N TMC⫺1 OriMC⫺1
22624.9331共2兲
15
1共1兲⫺1共1兲 F,F 1 ⫽1.5,1⫺0.8,1
b
OriMC⫺1
MPI 100 m
Her85
Kuk67
22624.9410共2兲
15
1共1兲⫺1共1兲 F,F 1 ⫽0.5,1⫺0.8,1
b
OriMC⫺1
MPI 100 m
Her85
Kuk67
22624.9469共2兲
15
1共1兲⫺1共1兲 F,F 1 ⫽1.5,2⫺1.5,2
CCO HDO CCS HCOOH HC7 N
OriMC⫺1
MPI 100 m
Her85
Kuk67
IRC⫹10216 IRC⫹10216 OriMC⫺1
NRAO 43 m NRAO 43 m MPI 100 m
Bel92b Bel92b Her85
Kuk68
OriMC⫺1
MPI 100 m
Nys78
Poy75
NH3 NH3 NH3
0.033 0.09 1.21 0.01 0.5
22649.843 共1兲
15
NH3
2共2兲⫺2共2兲
0.22b 0.003 0.002 0.36
22653.022 共5兲 22660.225*共3兲
NH3 HC9 N
5共4兲⫺5共4兲
0.6
22678.6 22688.312共5兲 22732.429共5兲 22789.421共1兲
unidentified NH3 NH3
22827.741*共8兲
CH3 OCHO CH3 OCHO NH3 DC5 N NH3
22639.3 22644.3
22828.134*共8兲 22834.1851共1兲 22878.949*共10兲 22924.940 共5兲 23046.0158共2兲 23098.8190共1兲 23121.024 共2兲 U U
Telescope
T r 共K兲/T a 共K兲
21980.5453共1兲
22258.173*共3兲 22307.670 共50兲 22344.030*共3兲 22471.180共1兲 22559.915*共2兲 22624.8892共2兲
U U
H2 CCCCCC HC9 N unidentified CH3 OH unidentified unidentified unidentified c⫺C3 H2 unidentified unidentified unidentified unidentified unidentified NH3 unidentified
Source
Quantum numbers
23122.983*共1兲 23142.2 23228.0 23232.238共5兲 23241.246*共3兲 23421.9823共2兲 23444.778共2兲 23565.160共20兲
NH3 unidentified unidentified
15
NH3
15
NH3 NH3 CH3 OH CCCS unidentified unidentified NH3 HC9 N 15 NH3 CH3 OH C6 H
Kuk69a Kuk67
39⫺38
0.003
IRC⫹10216
NRAO 43 m
Bel92b
4共3兲⫺4共3兲 6共5兲⫺6共5兲 3共3兲⫺3共3兲
0.001 1.2 0.6 0.53
IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 43 m MPI 100 m MPI 100 m MPI 100 m
Bel92b Nys78 Nys78 Her85
2共1,2兲⫺1共1,1兲 E 2共1,2兲⫺1共1,1兲 A 3共2兲⫺3共2兲 9⫺8 7共6兲⫺7共6兲 4共4兲⫺4共4兲
0.15 0.15 0.11 0.019 1.0 0.26
OriMC⫺1 OriMC⫺1 Sgr B2共M兲 TMC⫺1 OriMC⫺1 OriMC⫺1
MPI 100 m MPI 100 m NRAO 11m NRAO 43 m MPI 100 m MPI 100 m
Chu80 Chu80 Mor73 Sch81 Nys78 Her85
Oes99 Oes99 Kuk65
2共1兲⫺2共1兲 9共2,7兲⫺10共1,10兲 A⫹
0.29
Sgr B2共M兲 W3共OH兲
NRAO 11m MPI 100 m
Mor73 Wil84
Kuk70 Meh85
TMC⫺1 IRC⫹10216 IRC⫹10216 OriMC⫺1 IRC⫹10216 OriMC⫺1
NRO 45 m NRAO 12 m NRAO 43 m MPI 100 m NRAO 43 m MPI 100 m
Kai87 Bel93a Bel92b Nys78 Bel92b Her85
Kuk68
W3共OH兲
MPI 100 m
Men85
Meh85
TMC⫺1
NRO 45 m
Suz86
Suz86
4⫺3
8共7兲⫺8共7兲 40⫺39 5共5兲⫺5共5兲 10共1,9兲⫺9共2,8兲 A⫺ 2
Str48
⌸3/2 J⫽17/2⫺15/2 F⫽9⫺8 e
9.5e 0.55 0.001 0.003 0.2 0.003 0.14 ⫺0.77 0.156
Poy75 Poy75 Kuk67
Poy75 Kuk68
Poy75
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
192
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Telescope
Astr. Ref.
Lab. Ref.
C6 H
2
⌸3/2 J⫽17/2⫺15/2 F⫽8⫺7 e
0.144
TMC⫺1
NRO 45 m
Suz86
Suz86
2
⌸3/2 J⫽17/2⫺15/2 F⫽9⫺8 f
0.157
TMC⫺1
NRO 45 m
Suz86
Suz86
23567.238共20兲
C6 H
2
0.129
TMC⫺1
NRO 45 m
Suz86
Suz86
23600.242共4兲 23657.471共5兲 23687.898*共2兲 23692.9265共2兲
SiC2 NH3 HC7 N NH3
⌸3/2 J⫽17/2⫺15/2 F⫽8⫺7 f 1共0,1兲⫺0共0,0兲 9共8兲⫺9共8兲 21⫺20
0.11 0.1 0.21
IRC⫹10216 OriMC⫺1 TMC⫺1
MPI 100 m MPI 100 m NEROC 37 m
Sny85 Nys78 Kro78
Sue89 Poy75
1共1兲⫺1共1兲 F,F 1 ⫽1/2,1⫺1/2,0
0.16
L134N
OSO 20 m
Ryd77
Ryd77
23692.9688共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,1⫺1/2,0
0.24
L134N
OSO 20 m
Ryd77
Kuk67
23693.8722共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽1/2,1⫺3/2,2
0.17
L134N
OSO 20 m
Ryd77
Kuk67
23693.9051共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,1⫺5/2,2
0.30b
L134N
OSO 20 m
Ho77
Kuk67
23693.9145共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,1⫺3/2,2
b
L134N
OSO 20 m
Ho77
Kuk67
23694.4591共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽1/2,1⫺1/2,1
b
L134N
OSO 20 m
Ho77
Kuk67
23694.4700共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽1/2,1⫺3/2,1
0.40b
L134N
OSO 20 m
Ho77
Kuk67
23694.4709共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,2⫺5/2,2
b
L134N
OSO 20 m
Ho77
Kuk67
23694.4803共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,2⫺3/2,2
b
L134N
OSO 20 m
Ho77
Kuk67
23694.5014共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,1⫺1/2,1
b
L134N
OSO 20 m
Ho77
Kuk67
23694.5060共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽5/2,2⫺5/2,2
0.50b
L134N
OSO 20 m
Ho77
Kuk67
23694.5123共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,1⫺3/2,1
b
L134N
OSO 20 m
Ho77
Kuk67
23694.5153共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽5/2,2⫺3/2,2
b
L134N
OSO 20 m
Ho77
Kuk67
23695.0672共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,2⫺3/2,1
0.18b
L134N
OSO 20 m
Ho77
Kuk67
23695.0782共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽3/2,2⫺3/2,1
b
L134N
OSO 20 m
Ho77
Kuk67
23695.1132共1兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽5/2,2⫺3/2,1
0.25
L134N
OSO 20 m
Ho77
Kuk67
23696.0297共2兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽1/2,0⫺1/2,1
0.29b
L134N
OSO 20 m
Ho77
Kuk67
23696.0406共2兲
NH3
1共1兲⫺1共1兲 F,F 1 ⫽1/2,0⫺3/2,1
Kuk67
23697.9 23718.325*共11兲
unidentified 9⫺8
b
0.006 0.002
L134N
OSO 20 m
Ho77
IRC⫹10216 IRC⫹10216
NEROC 37 m NRAO 43 m
Bel82 Bel91
23720.575共5兲
HC13CCCCN NH3
2共2兲⫺2共2兲 F 1 ⫽1⫺2
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23721.336共5兲
NH3
2共2兲⫺2共2兲 F 1 ⫽3⫺2
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23722.6323共5兲
NH3
2共2兲⫺2共2兲 F 1 ⫽2⫺2
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23722.6336共1兲
NH3
2共2兲⫺2共2兲 F 1 ⫽3⫺3
0.43j
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23722.6344共5兲
NH3
2共2兲⫺2共2兲 F 1 ⫽1⫺1
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23723.929共5兲
NH3
2共2兲⫺2共2兲 F 1 ⫽2⫺3
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23724.691共5兲
NH3
2共2兲⫺2共2兲 F 1 ⫽2⫺1 9⫺8
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
0.12
TMC⫺1
NRO 45 m
Tak98
0.004 0.002 ⫺0.05
IRC⫹10216 IRC⫹10216 W3共OH兲
NRAO 43 m NRAO 43 m MPI 100 m
Bel92b Bel92b Win78
Mee75
0.003 ⫺0.13
IRC⫹10216 W3共OH兲
NRAO 43 m MPI 100 m
Bel92b Win78
Mee75
23804.5 23811.0 23817.6153共20兲
HCCCC13CN unidentified unidentified OH
23822.265*共3兲 23826.6211共30兲
HC9 N OH
2
2
⌸3/2 J⫽9/2 F⫽4⫺4 41⫺40
⌸3/2 J⫽9/2 F⫽5⫺5
23867.805共5兲
NH3
3共3兲⫺3共3兲 F 1 ⫽2⫺3
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23868.450共5兲
NH3
3共3兲⫺3共3兲 F 1 ⫽4⫺3
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23870.1279共5兲
NH3
3共3兲⫺3共3兲 F 1 ⫽3⫺3
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23870.1296共1兲
NH3
3共3兲⫺3共3兲 F 1 ⫽4⫺4
0.53j
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23870.1302共5兲
NH3
3共3兲⫺3共3兲 F 1 ⫽2⫺2
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23871.807共5兲
NH3
3共3兲⫺3共3兲 F 1 ⫽3⫺4
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
23872.453共5兲
NH3
3共3兲⫺3共3兲 F 1 ⫽3⫺2 6共6兲⫺6共6兲
b
OriMC⫺1
NEROC 37 m
Bar77
Kuk67
0.13
OriMC⫺1
MPI 100 m
Her85
Kuk68
HCC13CCCN
9⫺8
0.003
IRC⫹10216
NRAO 43 m
Bel91
HCC13CCN unidentified HC5 N unidentified unidentified unidentified unidentified unidentified unidentified unidentified NH3 NH3 CH3 OCHO CH3 OCHO OCS
9⫺8
0.002
IRC⫹10216
NRAO 43 m
Bel91
23959.5 23963.901*共1兲 23987.5 23990.2 23996.7 24004.5 24023.2 24037.1 24048.5 24139.4169共1兲 24205.287 共5兲 24296.491*共8兲 24298.481*共8兲 24325.927共1兲
4共4兲⫺4共4兲 10共9兲⫺10共9兲 2共0,2兲⫺1共0,1兲 E 2共0,2兲⫺1共0,1兲 A 2⫺1
0.003 1.2 0.003 0.002 0.005 0.005 0.002 0.006 0.004 0.25j 0.1 0.09 0.12 0.30
IRC⫹10216 TMC⫺1 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
NRAO 43 m SRCAL 25 m NRAO 43 m NRAO 12 m NRAO 43 m NRAO 43 m NRAO 43 m NEROC 37 m NRAO 43 m NEROC 37 m MPI 100 m NRAO 43 m NRAO 43 m NEROC 37 m
Bel91 Lit77 Bel92a Bel93a Bel92a Bel92a Bel92a Bel82 Bel92a Bar77 Nys78 Chu80 Chu80 Gol81
Kuk70 Poy75 Oes99 Oes99 Wan73
24375.2 24428.652 共16兲
unidentified CH3 C4 H
6共1兲⫺5共1兲
0.006 0.107
IRC⫹10216 TMC⫺1
NEROC 37 m MPI 100 m
Bel82 Wal84
Wal84
23941.99*共5兲
U
Source
C6 H
23939.089*共10兲
U U U U U U U
T r 共K兲/T a 共K兲
23565.226共20兲
23922.3132共2兲
U
Quantum numbers
23567.169共20兲
23727.162*共19兲 U U
Formula
15
NH3
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
9⫺8
MICROWAVE TRANSITIONS
193
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Source
Telescope
Astr. Ref.
Lab. Ref.
0.131 0.09j 0.048 0.076
TMC⫺1 OriMC⫺1 TMC⫺1 TMC⫺1
MPI 100 m NEROC 37 m NEROC 37 m NEROC 37 m
Wal84 Bar77 Bro84 Bro84
Wal84 Kuk70
22⫺21 3共2,1兲⫺3共1,2兲 E 4共2,2兲⫺4共1,3兲 E 2共2,0兲⫺2共1,1兲 E 5共2,3兲⫺5共1,4兲 E 43⫺42 8共2,6兲⫺8共2,7兲
0.24 1.2 1.0i 0.35 1.1i 0.012 0.013
TMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216 IRC⫹10216
SRCAL 25 m NEROC 37 m NEROC 37 m NEROC 37 m NEROC 37 m MPI 100 m MPI 100 m
Lit78 Bar75 Bar71 Bar75 Bar71 Tru93 Tru93
6共2,4兲⫺6共1,5兲 E 4共1,4兲⫺4共0,4兲 6共6兲⫺6共6兲
1.7i 0.08
OriMC⫺1 OriMC⫺1 OriMC⫺1
NEROC 37 m MPI 100 m NEROC 37 m
Bar71 Wal87 Bar77
Meh85 Coh82 Kak75
Formula
Quantum numbers 6共0兲⫺5共0兲 5共5兲⫺5共5兲 6共1兲⫺5共1兲 6共0兲⫺5共0兲
25023.792共10兲 25056.025共5兲
CH3 C4 H NH3 CH3 CCCN CH3 CCCN HC7 N CH3 OH CH3 OH CH3 OH CH3 OH HC9 N SiC2 CH3 OH NH2 D NH3
25124.872共2兲 25249.938共4兲
CH3 OH C5 N
25260.649共4兲
C5 N
24428.886 共16兲 24532.9887共1兲 24788.541*共4兲 24788.780*共4兲 24815.878*共2兲 24928.715*共14兲 24933.468 共2兲 24934.382 共5兲 24959.079 共2兲 24984.302*共4兲 24991.19*共21兲 25018.123共2兲
T r 共K兲/T a 共K兲
Xu_97 Gai74 Gai74 Meh85 Sue89
7共2,5兲⫺7共1,6兲 E
0.17j 1.5i
OriMC⫺1
NEROC 37 m
Bar71
Meh85
2
⌸1/2 N⫽9⫺8 J⫽9.5⫺8.5
0.020
TMC⫺1
MPI 100 m
Gue98
Gue98
2
⌸1/2 N⫽9⫺8 J⫽8.5⫺7.5 8共2,6兲⫺8共1,7兲 E 3⫺2 10⫺9 9共2,7兲⫺9共1,8兲 E 7共7兲⫺7共7兲 10共2,8兲⫺10共1,9兲 E 2,2⫺1,1 23⫺22
0.015
TMC⫺1
MPI 100 m
Gue98
Gue98
0.7i 0.6 0.027 ⫺0.17 3. 0.9 0.18 0.37
OriMC⫺1 TMC⫺1 TMC⫺1 W3共OH兲 OriMC⫺1 OriMC⫺1 TMC⫺1 TMC⫺1
NEROC 37 m MPI 100 m NEROC 37 m MPI 100 m MPI 100 m NRL 26 m NRO 45 m NRO 45 m
Bar71 How94 Mac81 Men86 Mau86 Mat80 Ohi98 Ohi98
Meh85
⌸3/2 J⫽19/2⫺17/2 F⫽10⫺9 f
0.17
TMC⫺1
NRO 45 m
Ohi98
JPL01
⌸3/2 J⫽19/2⫺17/2 F⫽9⫺8 f
0.17
TMC⫺1
NRO 45 m
Ohi98
JPL01
⌸3/2 J⫽19/2⫺17/2 F⫽10⫺9 e
0.16
TMC⫺1
NRO 45 m
Ohi98
JPL01
0.16
TMC⫺1
NRO 45 m
Ohi98
JPL01
Ohi98
25294.417共2兲 25329.441*共2兲 25421.036*共9兲 25541.398共2兲 25715.182共5兲 25878.266共2兲 25911.017*共2兲 25943.855*共2兲 26337.414*共10兲
CH3 OH DCCCN DC5 N CH3 OH NH3 CH3 OH CCS HC7 N C6 H
26337.463*共10兲
C6 H
26339.924*共10兲
C6 H
26339.973*共10兲
C6 H
26363.491*共17兲
HCCCC13CN
⌸3/2 J⫽19/2⫺17/2 F⫽9⫺8 e 10⫺9
0.09
TMC⫺1
NRO 45 m
26450.598*共5兲
H13CCCN
3⫺2
0.07
TMC⫺1
NRO 45 m
Ohi98
Laf78
26500.462*共7兲
HCCC15N NH3
3⫺2
0.11
TMC⫺1
NRO 45 m
Ohi98
Laf78
8共8兲⫺8共8兲
0.70
OriMC⫺1
MPI 100 m
Ziu81
Poy75
10⫺9
0.08
TMC⫺1
NRO 45 m
Ohi98
10⫺9 3共1,3兲⫺2共1,2兲 3共0,3兲⫺2共0,2兲 12共2,10兲⫺12共1,11兲 E 3共1,2兲⫺2共1,1兲
1.0 0.22 0.16 3.6 0.14
TMC⫺1 TMC⫺1 TMC⫺1 Ori共MEC兲 TMC⫺1
NRAO 43 m NRO 45 m NRO 45 m MPI 100 m NRO 45 m
Jen82 Ohi98 Ohi98 Wil96 Ohi98
26518.981 共10兲 26602.181*共10兲
2
2 2
2
Meh85 Poy75 Meh85
26626.533*共1兲 26682.814*共5兲 26795.635*共5兲 26847.205*共27兲 26906.891*共6兲 27071.824*共2兲
HCCC13CCN HC5 N H2 CCCC H2 CCCC CH3 OH H2 CCCC HC7 N
27084.348*共2兲
c⫺C3 H2
24⫺23 3共3,0兲⫺3共2,1兲
0.43 0.04
TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m
Ohi98 Ohi98
27178.511*共6兲
HC13CCN
3⫺2
0.10
TMC⫺1
NRO 45 m
Ohi98
Laf78
27181.127*共2兲
HCC13CN
3⫺2
0.14
TMC⫺1
NRO 45 m
Ohi98
Laf78
27292.903*共1兲
HCCCN
3⫺2 F⫽3⫺3
0.49
TMC⫺1
NRO 45 m
Ohi98
Laf78
27294.078*共1兲
HCCCN
3⫺2 F⫽2⫺1
0.70
HCL2C
OSO 20 m
Cer84
Laf78
27294.295*共1兲
HCCCN
3⫺2 F⫽3⫺2
0.96
HCL2C
OSO 20 m
Cer84
Laf78
27294.347*共1兲
HCCCN
3⫺2 F⫽4⫺3
1.1
HCL2C
OSO 20 m
Cer84
Laf78
27296.235*共1兲
HCCCN
0.47
TMC⫺1
NRO 45 m
Ohi98
Laf78
27472.501*共27兲 27477.943 共10兲 28009.975 共20兲 28169.437*共28兲 28199.804*共3兲
1.06 0.76 0.19 1.5
OriMC⫺1 OriMC⫺1 TMC⫺1 Ori共MEC兲
MPI 100 m MPI 100 m NRO 45 m MPI 100 m
Wil93 Ziu81 Kaw92a Wil96
Xu_97 Poy75 Kaw92a Xu_97
28199.805*共3兲 28316.031*共8兲
CH3 OH NH3 HNCCC CH3 OH HC7 N HC7 N CH3 OH
3⫺2 F⫽2⫺2 13共2,11兲⫺13共1,12兲 E 9共9兲⫺9共9兲 3⫺2 14共2,12兲⫺14共1,13兲 E
0.29 0.045
NRO 45 m NRO 45 m NRAO 43 m
Ohi98 Kaw95 Sly92
Xu_97
28440.980*共1兲 28470.391*共6兲 28532.31共1兲
CH2 CHCN HC9 N C4 H
3共0,3兲⫺2共0,2兲 49⫺48
4.2e 0.08 0.012
TMC⫺1 IRC⫹10216 OriMC⫺1 TMC⫺1 IRC⫹10216
NRO 45 m NRO 45 m
Ohi98 Kaw95
7/2⫺5/2 F⫽3⫺2
0.42
TMC⫺1
OSO 20 m
Irv81
Gue82a
28532.46共1兲
C4 H
7/2⫺5/2 F⫽4⫺3
0.49
TMC⫺1
OSO 20 m
Irv81
Gue82a
28542.284*共3兲
C4 H
J⫽5/2⫺5/2 F⫽3⫺3
0.05
TMC⫺1
NRO 45 m
Ohi98
JPL01
28571.37共1兲
C4 H
5/2⫺3/2 F⫽3⫺2
0.39
TMC⫺1
OSO 20 m
Irv81
Gue82a
28571.53共2兲
C4 H
5/2⫺3/2 F⫽2⫺1
0.23
TMC⫺1
OSO 20 m
Irv81
Gue82a
28604.737共5兲
NH3 CCCS CH3 OH CH3 CCCN CH3 CCCN CH3 OH
0.68 0.008 0.7 0.049 0.053 0.97
OriMC⫺1 IRC⫹10216 Ori共MEC兲 TMC⫺1 TMC⫺1 OriMC⫺1
MPI 100 m NRO 45 m MPI 100 m OSO 20 m OSO 20 m MPI 100 m
Wil93 Kaw95 Wil96 Bro84 Bro84 Wil93
Poy75
28903.688*共2兲
10共10兲⫺10共10兲 5⫺4 15共2,13兲⫺12共1,14兲 E 7共1兲⫺6共1兲 7共0兲⫺6共0兲 8共2,7兲⫺9共1,8兲A⫺⫺
28905.787*共29兲 28919.931*共4兲 28920.209*共4兲 28969.954*共20兲
25⫺24 25⫺24 4共0,4兲⫺3共1,2兲 E
Xu_97
Xu_97
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
194
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
Source
Telescope
Astr. Ref.
Lab. Ref.
H2 CO
3共1,2兲⫺3共1,3兲 F⫽2⫺2
b
Sgr B2共M兲
n.r.
Wel70
Tak59
H2 CO
3共1,2兲⫺3共1,3兲 F⫽4⫺4
n.r.b
Sgr B2共M兲
n.r.
Wel70
Tak59
28974.814共3兲
H2 CO
3共1,2兲⫺3共1,3兲 F⫽3⫺3 11⫺10
b
Sgr B2共M兲
n.r.
Wel70
Tak59
0.08
TMC⫺1
NRO 45 m
Ohi98
⌸3/2 J⫽21/2⫺19/2 F⫽11⫺10 f
0.011 0.16
IRC⫹10216 TMC⫺1
NRO 45 m NRO 45 m
Kaw95 Ohi98
⌸3/2 J⫽21/2⫺19/2 f
0.020
IRC⫹10216
NRO 45 m
Kaw95
JPL01
⌸3/2 J⫽21/2⫺19/2 F⫽10⫺9 f
0.16
TMC⫺1
NRO 45 m
Ohi98
JPL01
29109.644*共11兲
U U
T r 共K兲/T a 共K兲
28974.781共3兲
29051.403*共7兲
U
Quantum numbers
28974.804共2兲
28999.814*共15兲
U
Formula
HCCCC13CN HC9 N C6 H
29109.66* 共2兲
C6 H
29109.686*共11兲
C6 H
29112.709*共11兲
C6 H
29112.73*共3兲
C6 H
50⫺49 2
2 2 2
JPL01
⌸3/2 J⫽21/2⫺19/2 F⫽11⫺10 f
0.16
TMC⫺1
NRO 45 m
Ohi98
JPL01
⌸3/2 J⫽21/2⫺19/2 e
0.019
IRC⫹10216
NRO 45 m
Kaw95
JPL01 JPL01
2
29112.750*共11兲
C6 H
⌸3/2 J⫽21/2⫺19/2 F⫽10⫺9 f
0.16
TMC⫺1
NRO 45 m
Ohi98
29138.877*共3兲
CH2 CHCN
3共1,2兲⫺2共1,1兲 F⫽3⫺2
0.05
TMC⫺1
NRO 45 m
Ohi98
29139.215*共3兲
CH2 CHCN
TMC⫺1
NRO 45 m
Ohi98
0.04
TMC⫺1
NRO 45 m
Ohi98
29289.159*共2兲 29304.09*共31兲
HCC13CCCN HC5 N C6 H
3共1,2兲⫺2共1,1兲 F⫽4⫺3,2⫺1 11⫺10
0.08
29258.834*共8兲
29310.5 29327.776*共2兲 29332.45*共31兲
unidentified HC7 N C6 H
29333.3 29337.57*共10兲 29342.0 29353.8 29363.15*共10兲 29365.0 29477.704*共4兲 29632.406*共7兲 31032.803*共5兲
unidentified HC5 N unidentified unidentified HC5 N unidentified CCS HC9 N C5 H
2
31032.824*共25兲
C5 H
2
31033.037*共20兲
C5 H
2
31033.104*共5兲
C5 H
2
31092.1 31093.029*共8兲
unidentified C8 H
31093.409*共8兲
C8 H
31105.220*共2兲
2
11⫺10
0.038
IRC⫹10216
NRAO 43 m
Bel92a
⌸1/2 J⫽21/2⫺19/2 e
0.016
IRC⫹10216
NRO 45 m
Kaw95
JPL01
26⫺25
0.003 0.010 0.017
IRC⫹10216 IRC⫹10216 IRC⫹10216
NRAO 43 m NRAO 43 m NRO 45 m
Bel92a Bel92a Kaw95
JPL01
⌸1/2 J⫽13/2⫺11/2 F⫽7⫺6 e
0.004 0.004 0.009 0.004 0.005 0.004 0.15 0.07 0.05
IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 TMC⫺1 TMC⫺1 TMC⫺1
NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRAO 43 m NRO 45 m NRO 45 m NRO 45 m
Bel92a Bel92a Bel92a Bel92a Bel92a Bel92a Ohi98 Ohi98 Ohi98
Ohi98
⌸1/2 J⫽13/2⫺11/2 F⫽7⫺6 e
0.018b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
⌸1/2 J⫽13/2⫺11/2 F⫽6⫺5 e
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
⌸1/2 J⫽13/2⫺11/2 F⫽6⫺5 e
0.07
TMC⫺1
NRO 45 m
Ohi98
Ohi98
0.010
NRO 45 m IRAM 30 m
Kaw95 Cer96
McC97
2
2
⌸1/2 J⫽21/2⫺19/2 f
11⫺10 v11 ⫽1 ᐉ⫽1 c
11⫺10 v11 ⫽1 ᐉ⫽1 d 2,3⫺1,2 51⫺50
Hut80
Hut80
0.16fb
IRC⫹10216 IRC⫹10216
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
CH3 OCH3
⌸3/2 26.5⫺25.5 f 2共1,1兲⫺2共0,2兲 AE
b
OriMC⫺1
NRL 26 m
Sny74
Gro98
31105.226*共2兲
CH3 OCH3
2共1,1兲⫺2共0,2兲 EA
b
OriMC⫺1
NRL 26 m
Sny74
Gro98
31106.145*共2兲
CH3 OCH3
2共1,1兲⫺2共0,2兲 EE
0.2b
OriMC⫺1
NRL 26 m
Sny74
Gro98
31107.068*共4兲
CH3 OCH3
2共1,1兲⫺2共0,2兲 AA
b
OriMC⫺1
NRL 26 m
Sny74
Gro98
31226.709*共53兲
CH3 OH
19共2,17兲⫺19共1,18兲 E
0.5e
SgrB2共N兲
BIMAArray
Pei00
Xu_97
31241.512*共19兲
C5 H
2
⌸3/2 J⫽13/2⫺11/2 F⫽6⫺5 f
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
31241.765*共19兲
C5 H
2
⌸3/2 J⫽13/2⫺11/2 F⫽6⫺5 e
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
31242.282*共15兲
C5 H
2
⌸3/2 J⫽13/2⫺11/2 F⫽7⫺6 f
0.019b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
31242.536*共15兲
C5 H
2
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
31358.349*共68兲
CH3 OH
⌸3/2 J⫽13/2⫺11/2 F⫽7⫺6 e 20共2,18兲⫺20共1,19兲 E
Pei00
Xu_97
31424.943 共5兲 31583.710*共4兲
NH3 HC7 N
Poy75
31624.347*共7兲
HC13CCCCN
31636.129*共12兲 31881.849*共13兲
HCCCC13CN C6 H
31881.885*共12兲 31885.523*共12兲
2
⌸3/2 26.5⫺25.5 e
2
SgrB2共N兲
BIMAArray
12共12兲⫺12共12兲
0.4e 0.30
OriMC⫺1
MPI 100 m
Wil93
28⫺27 12⫺11
0.30 0.008
TMC⫺1 IRC⫹10216
OSO 20 m NRO 45 m
Sne81 Kaw95
12⫺11
0.008
IRC⫹10216
NRO 45 m
Kaw95
2
⌸3/2 J⫽23/2⫺21/2 F⫽12⫺11 f
0.20
TMC⫺1
NRO 45 m
Ohi98
C6 H
2
⌸3/2 J⫽23/2⫺21/2 F⫽11⫺10 f
0.20
TMC⫺1
NRO 45 m
Ohi98
JPL01
C6 H
2
⌸3/2 J⫽23/2⫺21/2 F⫽12⫺11 e
0.18
TMC⫺1
NRO 45 m
Ohi98
JPL01
31885.559*共12兲
C6 H
2
TMC⫺1
NRO 45 m
Ohi98
JPL01
H2 COH⫹
⌸3/2 J⫽23/2⫺21/2 F⫽11⫺10 e 3共0,3兲⫺2共1,2兲
0.18
31914.622*共43兲
0.097
Sgr B2共M兲
NRO 45 m
Ohi96
31918.695*共6兲
HCC13CCCN
12⫺11
0.005
IRC⫹10216
NRO 45 m
Kaw95
31922.565*共7兲
12⫺11
0.005
IRC⫹10216
NRO 45 m
Kaw95
31951.777*共2兲 31956.444*共9兲 32033.9 32095.98*共31兲
HCCC13CCN HC5 N HC9 N unidentified C6 H
12⫺11 55⫺54
TMC⫺1 IRC⫹10216 IRC⫹10216 IRC⫹10216
OSO 20 m NRO 45 m NRO 45 m NRO 45 m
Sne81 Kaw95 Kaw95 Kaw95
32124.78*共31兲
C6 H
32266.319*共8兲
C8 H
32266.728*共8兲
C8 H
32537.449*共10兲 32571.440*共15兲 32571.758*共19兲
HC9 N CH3 C4 H CH3 C4 H
JPL01
2
⌸1/2 J⫽23/2⫺21/2 e
1.77 0.006 0.005 0.011
2
⌸1/2 J⫽23/2⫺21/2 f
0.010
IRC⫹10216
NRO 45 m
Kaw95
JPL01
2
⌸3/2 27.5⫺26.5 e
0.10fb
IRC⫹10216
IRAM 30 m
Cer96
McC97
2
⌸3/2 27.5⫺26.5 f 56⫺55 8共1兲⫺7共1兲
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
0.011 0.08
IRC⫹10216 TMC⫺1
NRO 45 m NRO 45 m
Kaw95 Ohi98
8共0兲⫺7共0兲
0.08
TMC⫺1
NRO 45 m
Ohi98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
JPL01
MICROWAVE TRANSITIONS
195
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U
U
U
U U
Source
Telescope
Astr. Ref.
Lab. Ref.
l⫺C3 H
2
⌸1/2 J⫽3/2⫺1/2 F⫽1⫺1 f
0.08
TMC⫺1
NRO 45 m
Ohi98
JPL01
l⫺C3 H
2
⌸1/2 J⫽3/2⫺1/2 F⫽2⫺1 f
0.28
TMC⫺1
OSO 20 m
Tha85
JPL01
32634.390*共20兲
l⫺C3 H
2
⌸1/2 J⫽3/2⫺1/2 F⫽1⫺0 f
0.13
TMC⫺1
OSO 20 m
Tha85
JPL01
32660.655*共15兲
l⫺C3 H
2
⌸1/2 J⫽3/2⫺1/2 F⫽2⫺1 e
0.35
TMC⫺1
OSO 20 m
Tha85
JPL01
32663.375*共15兲
l⫺C3 H
2
⌸1/2 J⫽3/2⫺1/2 F⫽1⫺0 e
0.17
TMC⫺1
OSO 20 m
Tha85
JPL01
32667.637*共75兲
l⫺C3 H
2
0.06
TMC⫺1
NRO 45 m
Ohi98
JPL01
32711.673*共4兲 33044.8
HC7 N unidentified
⌸1/2 J⫽3/2⫺1/2 F⫽1⫺1 e 29⫺28
0.057 0.011
IRC⫹10216 IRC⫹10216
NRO 45 m NRO 45 m
Kaw95 Kaw95
33047.262*共5兲 33051.304*共5兲 33051.623*共5兲 33111.840*共7兲
DC5 N CH3 CCCN CH3 CCCN
0.06 0.043 0.057
TMC⫺1 TMC⫺1 TMC⫺1
NRO 45 m OSO 20 m OSO 20 m
Ohi98 Bro84 Bro84
33118.453*共10兲 33156.849共5兲 33332.3 33339.3 33699.456*共11兲 33742.683*共2兲 33751.370*共4兲 33772.538*共3兲 33839.632*共5兲 33839.634*共5兲 33844.240*共6兲
B⫽1377 J⫽12⫺11 13⫺12 8共1兲⫺7共1兲 8共0兲⫺7共0兲
CC34S HC9 N NH3 unidentified unidentified HC9 N SiC4 CCS DCCCN HC7 N HC7 N CCC34 S CH3 CCH CH3 CCH
3,2⫺2,1
0.18
TMC⫺1
NRO 45 m
Ohi98
57⫺56 13共13兲⫺13共13兲
58⫺57 11⫺10 3,2⫺2,1 4⫺3 30⫺29 30⫺29 6⫺5
0.008 0.10 0.008 0.008 0.010 0.017 0.032 0.19 0.21 0.074 0.05
IRC⫹10216 OriMC⫺1 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 TMC⫺1 TMC⫺1 IRC⫹10216 TMC⫺1
NRO 45 m MPI 100 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m
Kaw95 Wil93 Kaw95 Kaw95 Kaw95 Kaw95 Kaw95 Ohi98 Ohi98 Kaw95 Ohi98
2共1兲⫺1共1兲 2共0兲⫺1共0兲 13⫺12
0.20 0.25 0.013
TMC⫺1 TMC⫺1 IRC⫹10216
OSO 20 m OSO 20 m NRO 45 m
Irv81 Irv81 Kaw95
Poy75
Laf78
34183.413*共1兲 34259.672*共6兲
HC13CCCCN
34259.672*共7兲
HC13CCCCN
13⫺12
0.04
TMC⫺1
NRO 45 m
Ohi98
34272.435*共10兲
HCCCC13CN HC9 N H2 CS unidentified
13⫺12
0.011
IRC⫹10216
NRO 45 m
Kaw95
59⫺58 1共0,1兲⫺0共0,0兲
HCC13CCCN
13⫺12
0.007 0.684 0.013 0.04
IRC⫹10216 TMC⫺1 IRC⫹10216 TMC⫺1
NRO NRO NRO NRO
m m m m
Kaw95 Min97 Kaw95 Ohi98
HCCC13CCN HC5 N
13⫺12
0.03
TMC⫺1
NRO 45 m
Ohi98
13⫺12
1.50
TMC⫺1
OSO 20 m
Sne81
4⫺3
0.048
TMC⫺1
NRO 45 m
Kaw94
34654.029*共14兲
HCCCNH⫹ C6 H
2
⌸3/2 J⫽25/2⫺23/2 F⫽13⫺12 f
0.20
TMC⫺1
NRO 45 m
Ohi98
JPL01
34654.061*共14兲
C6 H
2
⌸3/2 J⫽25/2⫺23/2 F⫽12⫺11 f
0.20
TMC⫺1
NRO 45 m
Ohi98
JPL01
34658.366*共14兲
C6 H
2
34658.398*共13兲
C6 H
2
34673.9 34684.367*共2兲 34824.98*共18兲
unidentified CCCS C4 H
34887.83*共30兲
C6 H
2
34917.10*共30兲
C6 H
2
34967.591*共5兲 35010.3 35134.303 共10兲 35267.316*共8兲
HC7 N unidentified NH3 H13CCCN
35267.408*共7兲
34280.457*共12兲 34351.421*共13兲 34487.1 34578.547*共5兲
34614.385*共2兲 34631.914共20兲
U
T r 共K兲/T a 共K兲
32617.016*共79兲
34582.746*共5兲
U
Quantum numbers
32627.300*共15兲
34182.760*共1兲
U
Formula
45 45 45 45
Kaw94
⌸3/2 J⫽25/2⫺23/2 F⫽13⫺12e
0.19
TMC⫺1
NRO 45 m
Ohi98
JPL01
⌸3/2 J⫽25/2⫺23/2 F⫽12⫺11 e
0.19
TMC⫺1
NRO 45 m
Ohi98
JPL01
6⫺5 J⫽7/2⫺5/2 e v7 ⫽1
0.009 0.022 0.013
IRC⫹10216 IRC⫹10216 IRC⫹10216
NRO 45 m NRO 45 m NRO 45 m
Kaw95 Kaw95 Kaw95
JPL01
⌸1/2 J⫽25/2⫺23/2 e
0.017
IRC⫹10216
NRO 45 m
Kaw95
JPL01
⌸1/2 J⫽25/2⫺23/2 f 31⫺30
0.025
IRC⫹10216
NRO 45 m
Kaw95
JPL01
14共14兲⫺14共14兲
0.070 0.010 0.06
IRC⫹10216 IRC⫹10216 OriMC⫺1
NRO 45 m NRO 45 m MPI 100 m
Kaw95 Kaw95 Wil93
Poy75
4⫺3 F⫽3⫺2
0.084
TMC⫺1
NRO 45 m
Tak98
Laf78
H13CCCN
4⫺3 F⫽4⫺3
b
TMC⫺1
NRO 45 m
Tak98
Laf78
35267.440*共7兲
H13CCCN
0.19b 0.11
NRO 45 m
Tak98
Laf78
TMC⫺1
NRO 45 m
Ohi98
Laf78
35393.2 35577.009*共7兲 35589.319*共6兲 35717.4 35727.383*共7兲 35786.170*共10兲
HCCC15N unidentified H2 CCCC DC5 N unidentified H2 CCCC C8 H
4⫺3 F⫽5⫺4 4⫺3
TMC⫺1
35333.892*共9兲
0.013 0.006 0.05 0.006 0.17 0.10fb
IRC⫹10216 IRC⫹10216 TMC⫺1 IRC⫹10216 TMC⫺1 IRC⫹10216
NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m IRAM 30 m
Kaw95 Kaw95 Ohi98 Kaw95 Ohi98 Cer96
McC97
35786.672*共10兲
C8 H
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
0.008
IRC⫹10216
NRO 45 m
Kaw95
B⫽1377 J⫽13⫺12 5/2,3⫺3/2,2
0.011
IRC⫹10216
NRO 45 m
Kaw95
0.014
IRC⫹10216
NRO 45 m
Kaw95
2
⌸1/2 J⫽15/2⫺13/2 F⫽8⫺7 f
0.05
TMC⫺1
NRO 45 m
Ohi98
35787.5
unidentified
35793.
unidentified
35793.315*共10兲
24
4共1,4兲⫺3共1,3兲 14⫺13 4共0,4兲⫺3共0,3兲 2
⌸3/2 30.5⫺29.5 e
2
⌸3/2 30.5⫺29.5 f
35802.789*共5兲
MgNC C5 H
35803.023*共5兲
C5 H
2
⌸1/2 J⫽15/2⫺13/2 F⫽7⫺6 f
0.03
TMC⫺1
NRO 45 m
Ohi98
Ohi98
35806.837*共5兲
C5 H
2
⌸1/2 J⫽15/2⫺13/2 F⫽8⫺7 e
0.06
TMC⫺1
NRO 45 m
Ohi98
Ohi98
C5 H
2
⌸1/2 J⫽15/2⫺13/2 F⫽7⫺6 e 7/2,3⫺5/2,2
0.05
Ohi98
4共1,3兲⫺3共1,2兲
0.38
35807.084*共5兲 35808.534*共10兲
24
35875.776*共8兲
H2 CCCC
MgNC
b
TMC⫺1
NRO 45 m
Ohi98
IRC⫹10216
NRO 45 m
Kaw95
TMC⫺1
NRO 45 m
Ohi98
Ohi98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
196
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
U
Frequency 共Unc.兲 共MHz兲
Formula
36023.454*共14兲 36048.538*共14兲
HC9 N C5 H
36048.877*共14兲
C5 H
36095.546*共6兲
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
62⫺61
0.016
2
⌸3/2 J⫽15/2⫺13/2 F⫽8⫺7 f
0.028b
IRC⫹10216 IRC⫹10216
NRO 45 m NRO 45 m
Kaw95 Kaw95
JPL01
2
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
36169.290*共14兲 36202.041*共12兲 36237.862*共9兲
HC7 N CH3 OH SO
⌸3/2 J⫽15/2⫺13/2 F⫽7⫺6 e 32⫺31 4共⫺1,4兲⫺3共0,3兲 E 2共3兲⫺2共2兲
HC13CCN
4⫺3 F⫽3⫺2
IRC⫹10216 Sgr B2共M兲 OriMC⫺1 TMC⫺1
NRO 45 m NRAO 11 m Parkes 64 m NRO 45 m
Kaw95 Lov76 Bro80 Tak98
36237.954*共9兲
HC13CCN
4⫺3 F⫽4⫺3
b
TMC⫺1
NRO 45 m
Tak98
Laf78
36237.987*共9兲
HC13CCN
4⫺3 F⫽5⫺4
0.19b
Laf78
0.083 12.5 0.4 0.083
Xu_97 Laf78
TMC⫺1
NRO 45 m
Tak98
36241.350*共3兲
HCC CN
4⫺3 F⫽3⫺2
0.12
TMC⫺1
NRO 45 m
Tak98
Laf78
36241.442*共3兲
HCC13CN
4⫺3 F⫽4⫺3
b
TMC⫺1
NRO 45 m
Tak98
Laf78
36241.475*共3兲
HCC13CN
NRO 45 m
Tak98
Laf78
H2 COH⫹
4⫺3 F⫽5⫺4 1共1,1兲⫺2共0,2兲
TMC⫺1
36299.951*共40兲
Sgr B2共M兲
NRO 45 m
Ohi96
36306.630*共3兲 36309.624*共3兲 36390.888*共1兲
H13CCCCCN SiS HCCCN
36392.238*共1兲
HCCCN
36392.332*共1兲
13
0.29b ⫺0.123
14⫺13
0.036
TMC⫺1
NRO 45 m
Tak90
2⫺1 4⫺3 F⫽4⫺4
0.5 0.66
IRC⫹10216 TMC⫺1
MPI 100 m NRO 45 m
Gra81 Ohi98
Laf78
4⫺3 F⫽3⫺2
0.7
L1512
NEROC 37 m
Ful93
Laf78
HCCCN
4⫺3 F⫽4⫺3
0.8
L1512
NEROC 37 m
Ful93
Laf78
36392.365*共1兲
HCCCN
4⫺3 F⫽5⫺4
1.0
L1512
NEROC 37 m
Ful93
Laf78
36394.178*共1兲
HCCCN
4⫺3 F⫽3⫺3
0.69
TMC⫺1
NRO 45 m
Ohi98
Laf78
36418.1 36451.973*共21兲 36480.671*共22兲
unidentified HCCCN HCCCN
4⫺3 v6 ⫽1 ᐉ⫽1 e 4⫺3 v6 ⫽1 ᐉ⫽1 f
0.023 0.8f
IRC⫹10216 G10.47⫹0.03 G10.47⫹0.03
NRO 45 m MPI 100 m MPI 100 m
Kaw95 Wyr99 Wyr99
Laf78 Laf78
36481.690*共13兲 36488.813*共2兲 36534.098*共13兲 36581.92*共4兲
HCCCN OCS HCCCN HCCCN
4⫺3 v7 ⫽1 ᐉ⫽1 e 3⫺2 4⫺3 v7 ⫽1 ᐉ⫽1 f 4⫺3 v6 ⫽1 v7 ⫽1 ᐉ⫽0⫹
3.2bf 0.06 2.4f b
G10.47⫹0.03 TMC⫺1 G10.47⫹0.03 G10.47⫹0.03
MPI 100 m NRO 45 m MPI 100 m MPI 100 m
Wyr99 Ohi98 Wyr99 Wyr99
Laf78 Wyr99
36582.15*共8兲
HCCCN
4⫺3 v6 ⫽1 v7 ⫽1 ᐉ⫽0⫺
b
G10.47⫹0.03
MPI 100 m
Wyr99
Wyr99
36583.53*共4兲
HCCCN
4⫺3 v6 ⫽1 v7 ⫽1 ᐉ⫽2⫺
b
G10.47⫹0.03
MPI 100 m
Wyr99
Wyr99
36583.54*共8兲
HCCCN
4⫺3 v6 ⫽1 v7 ⫽1 ᐉ⫽2⫹
0.6bf
G10.47⫹0.03
MPI 100 m
Wyr99
Wyr99
36623.177*共23兲
HCCCN
4⫺3 v7 ⫽2 ᐉ⫽2 e
b
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
36623.329*共23兲
HCCCN
4⫺3 v7 ⫽2 ᐉ⫽2 f
b
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
36623.461*共20兲
HCCCN
4⫺3 v7 ⫽2 ᐉ⫽0
1.6bf
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
36642.812*共27兲
CH3 C4 H
9共1兲⫺8共1兲
36643.0 36643.170*共28兲 36793.739*共1兲
unidentified CH3 C4 H CH3 CN
2共1兲⫺1共1兲 F⫽2⫺1
0.06 0.020 0.08 0.08
TMC⫺1 IRC⫹10216 TMC⫺1 TMC⫺1
NRO NRO NRO NRO
m m m m
Ohi98 Kaw95 Ohi98 Min93
Bou80
36794.204*共1兲
CH3 CN
2共0兲⫺1共0兲 F⫽2⫺2
0.04
TMC⫺1
NRO 45 m
Min93
Bou80
36794.340*共1兲
CH3 CN
2共1兲⫺1共1兲 F⫽2⫺2
0.03
TMC⫺1
NRO 45 m
Min93
Bou80
36794.417*共1兲
CH3 CN
2共0兲⫺1共0兲 F⫽1⫺0
0.06
TMC⫺1
NRO 45 m
Min93
Bou80
36795.024*共1兲
CH3 CN
2共1兲⫺1共1兲 F⫽3⫺2
0.15
TMC⫺1
NRO 45 m
Min93
Bou80
36795.475*共1兲
CH3 CN
2共0兲⫺1共0兲 F⫽2⫺1
0.13
TMC⫺1
NRO 45 m
Min93
Bou80
36795.568*共1兲
CH3 CN
2共0兲⫺1共0兲 F⫽3⫺2
0.24
TMC⫺1
NRO 45 m
Min93
Bou80
36796.348*共1兲
CH3 CN
2共1兲⫺1共1兲 F⫽1⫺0
0.04
TMC⫺1
NRO 45 m
Min93
Bou80
36797.584*共1兲
CH3 CN
2共0兲⫺1共0兲 F⫽1⫺1
0.04
TMC⫺1
NRO 45 m
Min93
Bou80
36810.136*共2兲
SiC4
12⫺11
TMC⫺1
NRO 45 m
Ohi89
36894.988*共7兲
HC13CCCCN
14⫺13
0.53f 0.032
TMC⫺1
NRO 45 m
Tak90
36908.733*共11兲
14⫺13
0.058
TMC⫺1
NRO 45 m
Tak90
2
⌸3/2 31.5⫺30.5 e
0.21fb
IRC⫹10216
IRAM 30 m
Cer96
McC97
2
⌸3/2 31.5⫺30.5 f 4共1,4兲⫺3共1,3兲
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
0.05
TMC⫺1
NRO 45 m
Ohi98
9共1兲⫺8共1兲 9共0兲⫺8共0兲 64⫺63 33⫺32
0.06 0.07 0.015 0.092
TMC⫺1 TMC⫺1 IRC⫹10216 IRC⫹10216
NRO NRO NRO NRO
m m m m
Ohi98 Ohi98 Kaw95 Kaw95
HCC13CCCN
14⫺13
0.042
TMC⫺1
NRO 45 m
Tak90
14⫺13
0.044
TMC⫺1
NRO 45 m
Tak90
37276.985*共2兲 37290.154*共8兲 37346.556 共20兲 37426.187*共15兲
HCCC13CCN HC5 N HCCCHO HNCCC C6 H
14⫺13
2.09
TMC⫺1
NRO 45 m
Suz84a
4共0,4兲⫺3共0,3兲 4⫺3
0.043 0.27 0.18
TMC⫺1 TMC⫺1 TMC⫺1
NRAO 43 m NRO 45 m NRO 45 m
Irv88 Kaw92a Ohi98
37426.215*共15兲
C6 H
2
⌸3/2 J⫽27/2⫺25/2 F⫽13⫺12 f
0.18
TMC⫺1
NRO 45 m
Ohi98
JPL01
37431.240*共15兲
C6 H
2
⌸3/2 J⫽27/2⫺25/2 F⫽14⫺13 e
0.16
TMC⫺1
NRO 45 m
Ohi98
JPL01
37431.268*共15兲
C6 H
2
⌸3/2 J⫽27/2⫺25/2 F⫽13⫺12 e
0.16
TMC⫺1
NRO 45 m
Ohi98
JPL01
37679.64* 共30兲
C6 H
⌸1/2 J⫽27/2⫺25/2 e
0.015
IRC⫹10216
NRO 45 m
Kaw95
JPL01
36959.446*共10兲
HCCCC13CN C8 H
36959.982*共10兲
C8 H
37018.922*共1兲 37182.660*共4兲
CH2 CHCN CH3 CCCN CH3 CCCN HC9 N HC7 N
37183.019*共6兲 37185.446*共15兲 37223.497*共6兲 37238.390*共6兲 37242.920*共6兲
9共0兲⫺8共0兲
2
⌸3/2 J⫽27/2⫺25/2 F⫽14⫺13 f
2
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
45 45 45 45
45 45 45 45
Laf78
Kaw92a JPL01
MICROWAVE TRANSITIONS
197
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
U U
Frequency 共Unc.兲 共MHz兲
Formula
Astr. Ref.
Lab. Ref.
NEROC 37 m
Has89
Xu_97
NRO 45 m
Kaw95
JPL01
TMC⫺1
NRO 45 m
Ohi98
IRC⫹10216 IRC⫹10216
NRO 45 m NRO 45 m
Kaw95 Kaw95
TMC⫺1
NRO 45 m
Ohi98
JPL01
IRC⫹10216
NRO 45 m
Kaw95
JPL01
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
7共⫺2,6兲⫺8共⫺1,8兲 E
4.0e 0.030
W3共OH兲
⌸1/2 J⫽27/2⫺25/2 f
IRC⫹10216
0.17 0.016
37703.696*共13兲
CH3 OH
37709.41* 共30兲
C6 H
37904.849*共1兲
CH2 CHCN
4共0,4兲⫺3共0,3兲 F⫽3⫺2
38044.1 38049.617*共2兲
unidentified C4 H
J⫽9/2⫺7/2 F⫽4⫺3 e
38049.691*共2兲
C4 H
J⫽9/2⫺7/2 F⫽5⫺4
38049.691*共2兲
C4 H
J⫽9/2⫺7/2 F⫽5⫺4 e
38059.431*共3兲
C4 H
J⫽7/2⫺7/2 F⫽4⫺4
0.088b 0.06
TMC⫺1
NRO 45 m
Ohi98
JPL01
38078.930*共3兲
C4 H
J⫽7/2⫺7/2 F⫽3⫺3
0.08
TMC⫺1
NRO 45 m
Ohi98
JPL01
38088.440*共2兲
C4 H
J⫽7/2⫺5/2 F⫽4⫺3,3⫺2
1.69
TMC⫺1
NRO 45 m
Ohi98
JPL01
38088.441*共2兲
C4 H
J⫽7/2⫺5/2 F⫽4⫺3 f
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
38088.481*共2兲
C4 H
0.064b 0.05
NRO 45 m
Kaw95
JPL01
DC5 N C4 H
J⫽7/2⫺5/2 F⫽5⫺4 f 15⫺14
IRC⫹10216
38131.371*共9兲 38212.637*共6兲
TMC⫺1
NRO 45 m
Ohi98
38224.456*共7兲
2
b
1.47
J⫽7/2⫺5/2 F⫽3⫺3 2共1,1兲⫺2共0,2兲
0.06
TMC⫺1
NRO 45 m
Ohi98
0.11
TMC⫺1
NRO 45 m
Ohi98
JPL01
JPL01
38231.962*共8兲
c⫺C3 HD C4 H
J⫽9/2⫺7/2 F⫽4⫺4
0.05
TMC⫺1
NRO 45 m
Ohi98
JPL01
38293.292*共14兲
CH3 OH
6共2,5兲⫺5共3,2兲 A⫺
W3共OH兲
NEROC 37 m
Has89
Xu_97
38347.432*共17兲 38351.446*共7兲 38351.446*共7兲 38452.653*共14兲
HC9 N HC7 N HC7 N CH3 OH
66⫺65 34⫺33 34⫺33
9.0e 0.015 0.093 0.19
IRC⫹10216 IRC⫹10216 TMC⫺1
NRO 45 m NRO 45 m NRO 45 m
Kaw95 Kaw95 Ohi98
38486.892*共4兲 38551.9
CCCO unidentified
38594.9 38847.735*共1兲
unidentified CH2 CHCN
38866.422*共3兲 38899.910*共5兲
CCS
6共2,4兲⫺5共3,3兲 A⫹ 4⫺3 B⫽1377 J⫽14⫺13 4共1,3兲⫺3共1,2兲 F⫽5⫺4 3,3⫺2,2 15⫺14
15.0e 0.09 0.023
W3共OH兲
NEROC 37 m
Has89
TMC⫺1 IRC⫹10216
NRO 45 m NRO 45 m
Ohi98 Kaw95
Xu_97
0.020 0.08
IRC⫹10216 TMC⫺1
NRO 45 m NRO 45 m
Kaw95 Ohi98
0.43 0.018
TMC⫺1 IRC⫹10216
NRO 45 m NRO 45 m
Kai87 Kaw95
0.097
IRC⫹10216 TMC⫺1
NRO 45 m NRO 45 m
Kaw95 Ohi98
Got83
39571.326*共9兲
H13CCCCCN HC7 N CCCN
4⫺3 J⫽9/2⫺7/2 F⫽7/2⫺5/2
b
39571.333*共9兲
CCCN
4⫺3 J⫽9/2⫺7/2 F⫽9/2⫺7/2
TMC⫺1
NRO 45 m
Ohi98
Got83
39571.405*共9兲
CCCN
TMC⫺1
NRO 45 m
Ohi98
Got83
39581.600*共4兲
4⫺3 J⫽9/2⫺7/2 F⫽11/2⫺9/2 1共0,1兲⫺0共0,0兲
0.14b 0.11 0.08
SgrB2共N兲
NEROC 37 m
Dic97
39479.391*共8兲
35⫺34
39590.209*共10兲
c⫺C2 H4 O CCCN
4⫺3 J⫽7/2⫺5/2 F⫽7/2⫺5/2
b
TMC⫺1
NRO 45 m
Ohi98
Got83
39590.217*共10兲
CCCN
4⫺3 J⫽7/2⫺5/2 F⫽9/2⫺7/2
0.17b
TMC⫺1
NRO 45 m
Ohi98
Got83
39742.547*共4兲 39877.571*共3兲
HCCNC SiC4
4⫺3 13⫺12
0.50
NRO 45 m NRO 45 m
Kaw92 Ohi89
39903.085*共10兲
15⫺14
TMC⫺1
NRO 45 m
Ohi98
39939.574*共2兲 40039.018*共10兲 40198.356共30兲
HCCC13CCN HC5 N CH2 CO C6 H
0.36f 0.06
TMC⫺1 TMC⫺1
15⫺14 2共1,2兲⫺1共1,1兲
1.8 0.09
TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m
Tak90 Ohi98
⌸3/2 J⫽29/2⫺27/2 e
0.084
TMC⫺1
NRO 45 m
Suz86
Suz86
40204.150共30兲
C6 H
⌸3/2 J⫽29/2⫺27/2 f 2⫺15/2⫺3/27/2⫺5/27/2⫺7/2 2⫺13/2⫺1/23/2⫺1/25/2⫺3/2
0.87
TMC⫺1
NRO 45 m
Suz86
Suz86
0.02 0.038
TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m
Ohi98 Irv88a
Ohi98 Irv88a
2⫺15/2⫺3/27/2⫺5/25/2⫺3/2 2⫺15/2⫺3/27/2⫺5/27/2⫺5/2 2⫺15/2⫺3/27/2⫺5/29/2⫺7/2 2⫺15/2⫺3/25/2⫺5/27/2⫺7/2 2⫺15/2⫺3/25/2⫺3/23/2⫺1/2 2⫺15/2⫺3/23/2⫺3/23/2⫺5/2
0.112 0.141 0.241 0.062 0.04
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRO NRO NRO NRO NRO NRO
45 45 45 45 45 45
m m m m m m
Irv88a Irv88a Irv88a Irv88a Ohi98 Irv88a
Irv88a Irv88a Irv88a Irv88a Ohi98 Irv88a
CH2 CN CH2 CN CH2 CN CH2 CN
2⫺15/2⫺3/25/2⫺3/23/2⫺1/2 2⫺15/2⫺3/25/2⫺3/25/2⫺3/2 2⫺15/2⫺3/23/2⫺3/25/2⫺3/2 2⫺15/2⫺3/25/2⫺5/23/2⫺5/2
0.034 0.066 0.103
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRO NRO NRO NRO
45 45 45 45
m m m m
Irv88a Irv88a Irv88a Irv88a
Irv88a Irv88a Irv88a Irv88a
2⫺15/2⫺3/25/2⫺3/27/2⫺5/2 2⫺13/2⫺1/25/2⫺3/25/2⫺3/2
0.098
40247.556
CH2 CN CH2 CN
TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m
Irv88a Irv88a
Irv88a Irv88a
40247.556
CH2 CN
2⫺13/2⫺3/25/2⫺3/27/2⫺5/2
NRO 45 m
Irv88a
Irv88a
CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN
2⫺15/2⫺3/23/2⫺1/23/2⫺1/2
0.206b 0.04
TMC⫺1
40247.849 40248.212
TMC⫺1
NRO 45 m
Ohi98
Ohi98
2⫺15/2⫺3/25/2⫺5/23/2⫺3/2 2⫺13/2⫺1/25/2⫺3/23/2⫺1/2 2⫺13/2⫺1/21/2⫺1/23/2⫺3/2 2⫺13/2⫺1/23/2⫺1/21/2⫺1/2 2⫺13/2⫺1/25/2⫺3/25/2⫺5/2 2⫺13/2⫺1/25/2⫺3/23/2⫺3/2
0.02 0.05 0.03 0.02 0.03 0.02
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRO NRO NRO NRO NRO NRO
45 45 45 45 45 45
m m m m m m
Ohi98 Ohi98 Ohi98 Ohi98 Ohi98 Ohi98
Ohi98 Ohi98 Ohi98 Ohi98 Ohi98 Ohi98
CH2 CN CH2 CN CH2 CN CH2 CN
2⫺13/2⫺1/23/2⫺3/23/2⫺3/2 2⫺13/2⫺3/23/2⫺3/25/2⫺5/2 2⫺15/2⫺1/23/2⫺3/21/2⫺1/2 2⫺13/2⫺1/21/2⫺1/21/2⫺3/2
0.03 0.05 0.02 0.02
TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1
NRO NRO NRO NRO
45 45 45 45
m m m m
Ohi98 Ohi98 Ohi98 Ohi98
Ohi98 Ohi98 Ohi98 Ohi98
40229.643 40232.796 40239.188 40239.684 40239.993 40240.520 40241.356 40241.360 40241.360 40242.208 40243.207 40243.207 40244.330
40248.588 40249.341 40250.438 40251.887 40253.903 40256.270 40256.813 40258.143 40260.256
CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN CH2 CN
2 2
b
b
b
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
198
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
40417.945*共11兲 40465.013*共2兲 40471.40* 共59兲
CH2 CO CCCS C6 H
2共0,2兲⫺1共0,1兲 7⫺6
40479.254*共10兲
C8 H
40479.895*共10兲
C8 H
40501.74* 共60兲
C6 H
40576.729*共5兲
C5 H
40576.931*共5兲 40580.866*共5兲
Astr. Ref.
Lab. Ref.
⌸1/2 J⫽29/2⫺27/2 e
0.08 0.88 0.020
TMC⫺1 TMC⫺1 IRC⫹10216
NRO 45 m NRO 45 m NRO 45 m
Ohi98 Kai87 Kaw95
JPL01
2
⌸3/2 34.5⫺33.5 e
0.15fb
IRC⫹10216
IRAM 30 m
Cer96
McC97
2
⌸3/2 34.5⫺33.5 f
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
0.025
IRC⫹10216
NRO 45 m
Kaw95
JPL01
2
⌸1/2 J⫽17/2⫺15/2 F⫽9⫺8 f
0.04
TMC⫺1
NRO 45 m
Ohi98
Ohi98
C5 H
2
⌸1/2 J⫽17/2⫺15/2 F⫽8⫺7 f
0.05
TMC⫺1
NRO 45 m
Ohi98
Ohi98
C5 H
2
⌸1/2 J⫽17/2⫺15/2 F⫽9⫺8 e
0.07
TMC⫺1
NRO 45 m
Ohi98
Ohi98
40581.077*共5兲
C5 H
2
TMC⫺1
NRO 45 m
Ohi98
Ohi98
0.093
IRC⫹10216
NRO 45 m
Kaw95
40673.413*共14兲 40714.164*共40兲 40714.561*共41兲 40793.839*共10兲 40854.363*共29兲
HC7 N HC9 N DC5 N CH3 C4 H CH3 C4 H CH2 CO C5 H
⌸1/2 J⫽17/2⫺15/2 F⫽8⫺7 e 36⫺35
0.08
40607.333*共8兲 40671.388*共20兲
70⫺69 16⫺15 10共1兲⫺9共1兲 10共0兲⫺9共0兲 2共1,1兲⫺1共1,0兲
0.020 0.05 0.10 0.12 0.11
2
⌸3/2 J⫽17/2⫺15/2 F⫽8⫺7
b
IRC⫹10216 TMC⫺1 TMC⫺1 TMC⫺1 TMC⫺1 IRC⫹10216
NRO NRO NRO NRO NRO NRO
m m m m m m
Kaw95 Ohi98 Ohi98 Ohi98 Ohi98 Kaw95
JPL01
40854.775*共27兲
C5 H
2
⌸3/2 J⫽17/2⫺15/2 F⫽9⫺8
0.047b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
40854.796*共29兲
C5 H
2
⌸3/2 J⫽17/2⫺15/2 F⫽8⫺7
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
40855.210*共27兲
C5 H
2
⌸3/2 J⫽17/2⫺15/2 F⫽9⫺8
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
40880.0 41198.320*共14兲 41305.4
unidentified H2 CCC unidentified
0.07 0.17 0.025
Sgr B2共M兲 TMC⫺1 IRC⫹10216
NRAO 11 m NRO 45 m NRO 45 m
Kut80 Ohi98 Kaw95
41313.996*共6兲 41314.394*共6兲 41493.180*共8兲
CH3 CCCN CH3 CCCN
0.08 0.09 0.05
TMC⫺1 TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m NRO 45 m
Ohi98 Ohi98 Ohi98
4共2,2兲⫺4共1,3兲
0.05
SgrB2共N兲
NRO 45 m
Dic97
2共0,2兲⫺1共0,1兲
0.11
NRO 45 m IRAM 30 m
Ohi98 Cer96
McC97
H13CCCCCN
2
2共1,2兲⫺1共1,1兲 B⫽1377 J⫽15⫺14 10共1兲⫺9共1兲 10共0兲⫺9共0兲 16⫺15
41584.627*共9兲 41652.515*共10兲
c⫺C2 H4 O H2 CCC C8 H
41653.194*共10兲
C8 H
41712.1 41735.271*共8兲 41735.271*共9兲 41967.661*共11兲 42215.539*共5兲
unidentified HC7 N HC7 N H2 CCC DCCCN
37⫺36 37⫺36 2共1,1兲⫺1共1,0兲 5⫺4 F⫽4⫺3
b
42215.590*共5兲
DCCCN
5⫺4 F⫽5⫺4
42215.613*共5兲
DCCCN
5⫺4 F⫽6⫺5 1⫺0 v⫽0
42373.365*共22兲
45 45 45 45 45 45
2
⌸3/2 35.5⫺34.5 e
0.23fb
TMC⫺1 IRC⫹10216
2
⌸3/2 35.5⫺34.5 f
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
0.012 0.085 0.12 0.20
IRC⫹10216 IRC⫹10216 TMC⫺1 TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m NRO 45 m NRO 45 m FCRAO 14 m
Kaw95 Kaw95 Ohi98 Ohi98 Lan80
Laf78
0.14b
TMC⫺1
FCRAO 14 m
Lan80
Laf78
b
TMC⫺1
FCRAO 14 m
Lan80
Laf78
CadY 13.7 m
Bar89
VXSgr IRC⫹10216
IRT 13.7 m NRO 45 m
Sca78 Kaw95
42519.373*共27兲 42558.044*共14兲
HCC13CCCN
1⫺0 v⫽3 16⫺15
42563.241*共15兲
HCCC13CCN
16⫺15
0.015
IRC⫹10216
NRO 45 m
Kaw95
42563.241*共15兲
HCCC13CCN HC5 N
16⫺15
0.04
TMC⫺1
NRO 45 m
Ohi98
HCS⫹ SiO
16⫺15 1⫺0
0.40 0.085
TMC⫺1 TMC⫺1
NEROC 37 m NEROC 37 m
Irv83 Irv83
1⫺0 v⫽2
HC7 N HC7 N
38⫺37 38⫺37
15.i 0.086 0.11
42820.582*共23兲 42863.206*共10兲 42863.206*共10兲 42879.922*共22兲
30
VYCMa
28.e 2.0 0.010
42602.153*共2兲 42674.197*共7兲
U
Telescope
⌸1/2 J⫽29/2⫺27/2 f
41579.445*共10兲
U
2
Source
T r 共K兲/T a 共K兲
SiO SiO
VYCMa
NRAO 11 m
Buh74
IRC⫹10216 TMC⫺1 VYCMa
NRO 45 m NRO 45 m CadY 13.7 m
Kaw95 Ohi98 Bar89
0.74f 0.108 0.13
TMC⫺1
NRO 45 m
Ohi89
TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m
Suz86 Suz86
IRC⫹10216 OriMC⫺1
NRO 45 m NRAO 11 m
Kaw95 Sny75
SiO SiC4
1⫺0 v⫽0
42944.988*共3兲 42970.453 共30兲 42977.115 共30兲 42995.321*共24兲
C6 H C6 H HC9 N
31/2⫺29/2 e 31/2⫺29/2 f 74⫺73
0.01
43122.079*共21兲
SiO
1⫺0 v⫽1 ⌸1/2 J⫽31/2⫺29/2e
29.i 0.028
IRC⫹10216
NRO 45 m
Kaw95
JPL01
4⫺3
0.048
TMC⫺1
NRO 45 m
Kaw94
Kaw94
0.022
IRC⫹10216
NRO 45 m
Kaw95
JPL01
0.50 0.016 0.05
OriMC⫺1 IRC⫹10216 TMC⫺1
NEROC 37 m IRAM 30 m NRO 45 m
Sny78 Gue91 Ohi98
29
43263.11* 共29兲
C6 H
43289.809 共20兲
14⫺13
2
3.1e
Suz86 Suz86
43294.04* 共29兲
HCCCNH⫹ C6 H
43423.864*共22兲 43624.353*共10兲 43962.014*共8兲
SiO HCCN HNCO
43962.998*共2兲
HNCO
2共0,2兲⫺1共0,1兲 F⫽3⫺2
⬍1b
Sgr B2共M兲
NRAO 11 m
Sny72
Win76
43963.042*共2兲
HNCO
2共0,2兲⫺1共0,1兲 F⫽2⫺1
b
Sgr B2共M兲
NRAO 11 m
Sny72
Win76
43963.659*共5兲
HNCO
0.07
TMC⫺1
NRO 45 m
Ohi98
43981.024*共5兲 43991.137*共11兲 43991.137*共11兲 44059.1
CCS HC7 N HC7 N unidentified
2共0,2兲⫺1共0,1兲 F⫽1⫺0,2⫺2 3,4⫺2,3 39⫺38 39⫺38
0.38 0.064 0.08 0.020
TMC⫺1 IRC⫹10216 TMC⫺1 IRC⫹10216
NRO NRO NRO NRO
Kai87 Kaw95 Ohi98 Kaw95
2
⌸1/2 J⫽31/2⫺29/2f 1⫺0 v⫽0 3,2⫺2,1
2共0,2兲⫺1共0,1兲 F⫽1⫺1
B⫽1377 J⫽16⫺15
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
45 45 45 45
m m m m
MICROWAVE TRANSITIONS
199
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
44069.476*共15兲 44084.172*共13兲
CH3 OH
7共0,7兲⫺6共1,6兲 A⫹ 5⫺4
3.9 0.066
Sgr B2共M兲 IRC⫹10216
NRO 45 m NRO 45 m
Mor85 Kaw95
Xu_97
H13CCCN
44084.172*共13兲
H13CCCN
5⫺4
0.17
TMC⫺1
NRO 45 m
Ohi98
Laf78
44104.781*共3兲
c⫺C3 H2
3共2,1兲⫺3共1,2兲
0.025
IRC⫹10216
NRO 45 m
Kaw95
44167.274*共10兲
HCCC15N H2 CCCC H2 CCCC
44471.139*共9兲 44471.139*共9兲 44497.600*共8兲 U
U
U
44507.7 44596.992*共4兲 44659.020*共9兲 44730.271*共4兲 44785.538*共56兲 44785.931*共57兲 44844.592*共10兲 44844.592*共10兲 44864.5 44878.104*共4兲 44911.75共1兲 44955.778*共12兲 45033.5 45103.868*共6兲 45119.064*共12兲 45259.076*共5兲 45264.720*共2兲 45297.346*共14兲 45301.707*共7兲
CC34S unidentified CH3 CH2 CN H2 CCCC CH3 CH2 CN CH3 C4 H CH3 C4 H H2 CCCC H2 CCCC unidentified CH3 CH2 CN HCOOH CH3 OH unidentified c⫺H13CCCH HC7 N NaCN HC5 N
5⫺4
0.08
TMC⫺1
NRO 45 m
Ohi98
5共1,5兲⫺4共1,4兲 5共1,5兲⫺4共1,4兲 4,3⫺3,2
0.018 0.28 0.13
IRC⫹10216 TMC⫺1 L1498
NRO 45 m NRO 45 m NRO 45 m
Kaw95 Ohi98 Yam90
共U48292.3USB兲 5共0,5兲⫺4共0,4兲
0.06 0.31
OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m
Sai89 Sai89
5共0,5兲⫺4共0,4兲 5共2,4兲⫺4共2,3兲 11共1兲⫺10共1兲 11共0兲⫺10共0兲 5共1,4兲⫺4共1,3兲 5共1,4兲⫺4共1,3兲 共U47935.5USB兲 5共2,3兲⫺4共2,2兲 2共0,2兲⫺1共0,1兲 2共0,2兲⫺3共1,3兲 E vt ⫽1 共U47976.5USB兲 2共1,1兲⫺2共0,2兲
0.14 0.23 0.04 0.05 0.020 0.19 0.04 0.30 0.044 0.85 0.10 0.09
TMC⫺1 OriMC⫺1 TMC⫺1 TMC⫺1 IRC⫹10216 TMC⫺1 OriMC⫺1 OriMC⫺1 L134N OriMC⫺1 OriMC⫺1 TMC⫺1
40⫺39 3共1,3兲⫺2共1,2兲 17⫺16 5⫺4
0.105 0.020 0.83 0.22
CRL2688 IRC⫹10216 TMC⫺1 TMC⫺1
5⫺4
0.34
HC13CCN
Tak98 Kaw95
JPL01
⌸1/2 J⫽19/2⫺17/2 e F⫽9⫺8
0.047b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
⌸1/2 J⫽19/2⫺17/2 f F⫽10⫺9
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
⌸1/2 J⫽19/2⫺17/2 f F⫽9⫺8
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m
Suz84 Ohi98
Laf78
b
Sgr B2共M兲
NRAO 11 m
Mor76
Laf78
5⫺4 F⫽5⫺4
2.05j
Sgr B2共M兲
NRAO 11 m
Mor76
Laf78
5⫺4 F⫽6⫺5
b
Sgr B2共M兲
NRAO 11 m
Mor76
Laf78
0.37
TMC⫺1
NRO 45 m
Ohi98
Laf78
1.1f
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
5⫺4 v6 ⫽1 ᐉ⫽1 f
b
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
5⫺4 v7 ⫽1 ᐉ⫽1 e
7.1bf
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
C5 H
2
45354.97*共3兲
C5 H
45379.029*共2兲 45488.839*共1兲
CCS HCCCN
5⫺4 F⫽5⫺5
45490.264*共1兲
HCCCN
5⫺4 F⫽4⫺3
45490.316*共1兲
HCCCN
45490.340*共1兲
HCCCN
45492.110*共1兲
HCCCN
45564.872*共24兲
HCCCN
5⫺4 F⫽4⫺4 5⫺4 v6 ⫽1 ᐉ⫽1 e
45600.738*共25兲
HCCCN
45602.145*共25兲
HCCCN
C5 H C5 H
45661.52*共1兲
C5 H
⌸1/2 J⫽19/2⫺17/2 e F⫽10⫺9
2
4,3⫺3,2
2 2
Fuk94 Kaw95 Buj81 Tak98
NRO 45 m
45354.92*共3兲
45661.21*共1兲
Bel71 Xu_97
NRO 45 m
2
45660.98*共1兲
NRO 45 m NRO 45 m NRAO 11 m NRO 45 m
Ohi98 Sai89 Ohi98 Ohi98 Kaw95 Ohi98 Sai89 Sai89 Irv90 Sai89 Sai89 Ohi98
TMC⫺1
C5 H
C5 H
m m m m m m m m m m m m
IRC⫹10216
45350.73*共3兲
45660.66*共1兲
45 45 45 45 45 45 45 45 45 45 45 45
b
45350.68*共3兲
HCC13CN C5 H
2
NRO NRO NRO NRO NRO NRO NRO NRO NRO NRO NRO NRO
Laf78
⌸3/2 J⫽19/2⫺17/2 e F⫽9⫺8
⌸3/2 J⫽19/2⫺17/2 e F⫽10⫺9
2
2.23 0.37
0.057b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
⌸3/2 J⫽19/2⫺17/2 f F⫽9⫺8
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
5.7f
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
45667.519*共16兲
HCCCN
⌸3/2 J⫽19/2⫺17/2 f F⫽10⫺9 5⫺4 v7 ⫽1 ᐉ⫽1 f
45727.13*共5兲
HCCCN
5⫺4 v6 ⫽1 v7 ⫽1 ᐉ⫽0⫹
b
G10.47⫹0.03
MPI 100 m
Wyr99
Wyr99
45727.49*共10兲
HCCCN
5⫺4 v6 ⫽1 v7 ⫽1 ᐉ⫽0⫺
b
G10.47⫹0.03
MPI 100 m
Wyr99
Wyr99
45729.40*共5兲
HCCCN
5⫺4 v6 ⫽1 v7 ⫽1 ᐉ⫽2⫺
b
G10.47⫹0.03
MPI 100 m
Wyr99
Wyr99
45729.48*共10兲
HCCCN
5⫺4 v6 ⫽1 v7 ⫽1 ᐉ⫽2⫹
G10.47⫹0.03
MPI 100 m
Wyr99
Wyr99
45742.443*共58兲
C6 H
2
⌸3/2 J⫽33/2⫺31/2 f F⫽17⫺16
4.7bf 0.056b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
45742.521*共40兲
C6 H
2
⌸3/2 J⫽33/2⫺31/2 f F⫽16⫺15
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
45750.040*共40兲
C6 H
2
⌸3/2 J⫽33/2⫺31/2 e F⫽17⫺16
0.056b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
45750.061*共40兲
C6 H
2
b
IRC⫹10216
NRO 45 m
Kaw95
JPL01
45778.864*共28兲
HCCCN
⌸3/2 J⫽33/2⫺31/2 e F⫽16⫺15 5⫺4 v7 ⫽2 ᐉ⫽2 e
b
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
45779.105*共26兲
HCCCN
5⫺4 v7 ⫽2 ᐉ⫽0
4.5bf
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
45779.167*共28兲
HCCCN
5⫺4 v7 ⫽2 ᐉ⫽2 f
b
G10.47⫹0.03
MPI 100 m
Wyr99
Laf78
45826.733*共4兲 46012.386*共3兲
CCO SiC4
3,2⫺2,1 15⫺14
0.050
TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m
Ohi91 Ohi89
46054.76* 共28兲
C6 H
2
⌸1/2 J⫽33/2⫺31/2 e
0.029
IRC⫹10216
NRO 45 m
Kaw95
JPL01
46086.32* 共29兲
C6 H
2
0.033
IRC⫹10216
NRO 45 m
Kaw95
JPL01
46245.621*共5兲 46246.988*共13兲 46247.580*共10兲
CCCS HC7 N
⌸1/2 J⫽33/2⫺31/2 f 8⫺7 41⫺40 1⫺0
0.84 0.05 0.148
TMC⫺1 TMC⫺1 Sgr B2共M兲
NRO 45 m NRO 45 m NRAO 11 m
Kai87 Ohi98 Tur73
5共1,5兲⫺4共1,4兲 5⫺4 2共1,1兲⫺2共0,2兲
0.10 0.30 1.00
TMC⫺1 TMC⫺1 TMC⫺1
NRO 45 m NRO 45 m NRO 45 m
Ohi98 Kaw92a Suz85
46266.934*共1兲 46683.086 共20兲 46755.614*共3兲
13 CS CH2 CHCN HNCCC c⫺C3 H2
2
b
Kaw92a
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
200
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U
Formula
Quantum numbers
46812.8
unidentified
46847.734*共3兲 47064.813*共16兲 47094.974*共10兲
NaCN SiC2 c⫺C2 H4 O CH2 CHCN HC7 N unidentified unidentified
B⫽1377 J⫽17⫺16 3共0,3兲⫺2共0,2兲 2共0,2兲⫺1共0,1兲
47354.648*共1兲 47374.907*共14兲 47408.5 47423.6 47436.151*共32兲 47534.069*共16兲 47536.941*共16兲 47556.928*共16兲 47566.80*共2兲 47595.991*共3兲 47605.49*共2兲 47643.113*共34兲 47660.624*共2兲 47674.961*共2兲 47726.482*共10兲 47741.702*共10兲
U U
47746.980*共5兲 47752.82*共1兲 47820.620*共4兲 47913.426*共2兲 47927.275*共2兲 47935.5 47976.5 48108.475*共5兲 48120.435*共3兲 48178.333*共6兲 48192.12 共10兲 48206.946*共4兲 48247.572*共2兲 48257.302*共4兲
U
48284.520*共3兲 48292.3 48372.4670共2兲 48376.889*共1兲 48502.823*共15兲 48514.59* 共2兲
Telescope
Astr. Ref.
0.025
IRC⫹10216
NRO 45 m
Kaw95
IRC⫹10216 IRC⫹10216
NRO 45 m NRO 45 m
Kaw95 Kaw95
0.05 0.18 0.078 0.026 0.029 0.022
Sgr B2共N兲 TMC⫺1 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216
NRO NRO NRO NRO NRO NRO
45 45 45 45 45 45
m m m m m m
Dic97 Ohi98 Kaw95 Kaw95 Kaw95 Kaw95
OriMC⫺1 OriMC⫺1 Sgr B2共N兲 Sgr B2共M兲 TMC⫺1
NRO NRO NRO NRO NRO
45 45 45 45 45
m m m m m
Sai89 Sai89 Dic97 Sai89 Ohi98
JPL01
45 45 45 45
Gro98
J⫽9/2⫺9/2 F⫽4⫺4
C4 H HC9 N SO2 CH3 OCH3
9/2⫺7/2 82⫺81 31共5,27兲⫺30共6,24兲 1共1,1兲⫺0共0,0兲 EE
0.09 0.02 0.08 0.09
Sgr B2共M兲 IRC⫹10216 OriMC⫺1 OriMC⫺1
NRO NRO NRO NRO
m m m m
Sai89 Kaw95 Sai89 Sai89
7/2,4⫺5/2,3
0.030
IRC⫹10216
NRO 45 m
Kaw95
9/2,4⫺7/2,3
0.039
IRC⫹10216
NRO 45 m
Kaw95
1共1,0兲⫺1共0,1兲 E 1共1,0兲⫺1共0,1兲 1共1,0兲⫺1共0,1兲 A⫹⫹ 14共2,12兲⫺13共3,11兲 18⫺17 共U4864.5LSB兲 共U45033.5LSB兲 5⫺4 21共2,20兲⫺20共3,17兲 1共0,1兲⫺0共0,0兲 E vt ⫽2 1共0,1兲⫺0共0,0兲 A⫹ vt ⫽2 1⫺0
0.06 0.13 0.06 1.15 1.50 0.04 0.10 0.158 0.39 0.03 0.06 0.380
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 TMC⫺1 OriMC⫺1 OriMC⫺1 TMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 DR21共OH兲
NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRAO 11 m
Sai89 Sai89 Sai89 Sai89 Suz84a Sai89 Sai89 Suz84a Sai89 Sai89 Sai89 Tur73
24
MgNC
24 MgNC CH3 CHO DCOOH CH3 CHO SO2 HC5 N unidentified unidentified CCCO SO2 CH3 OH CH3 OH
C34S CH3 OH CH3 OH H2 CO unidentified CH3 OH CH3 OH HC7 N C6 H
Lab. Ref.
0.020 0.233
0.25 0.23 0.12 0.10 0.06
4共0,4兲⫺3共0,3兲 E 4共0,4兲⫺3共0,3兲 A 5共5,0兲⫺5共4,1兲 11/2⫺9/2
Oes99 Oes99
Kle96 Wil80 Kle96
And90 Ven55
1共0,1兲⫺0共0,0兲 E vt ⫽1
0.23
OriMC⫺1
NRO 45 m
Sai89
Xu_97
1共0,1兲⫺0共0,0兲 A⫹ vt ⫽1 4共1,3兲⫺4共1,4兲 共U44507.7LSB兲 1共0,1兲⫺0共0,0兲 A⫹ 1共0,1兲⫺0共0,0兲 E 43⫺42
0.09 0.63 0.06 0.44 0.29 0.105
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
NRO 45 m NRAO 11 m NRO 45 m NRAO 11 m NRAO 11 m NRO 45 m
Sai89 Hol77 Sai89 Hol77 Hol77 Kaw95
Xu_97
Heu73 Xu_97
2
⌸3/2 J⫽35/2⫺33/2 f
0.064
IRC⫹10216
NRO 45 m
Kaw95
JPL01
2
0.066
IRC⫹10216
NRO 45 m
Kaw95
JPL01
NaCN CH2 CHCN
⌸3/2 J⫽35/2⫺33/2 e 3共1,2兲⫺2共1,1兲 5共1,4兲⫺4共1,3兲
0.025 0.07
IRC⫹10216 TMC⫺1
NRO 45 m NRO 45 m
Kaw95 Ohi98
C33S
1⫺0 F⫽1/2⫺3/2
Sgr B2共M兲
NRAO 11 m
Tur73
Bog81
C33S
1⫺0 F⫽5/2⫺3/2
Sgr B2共M兲
NRAO 11 m
Tur73
Bog81
b
Sgr B2共M兲
NRAO 11 m
Tur73
Bog81
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
1.5 0.06
TMC⫺1 OriMC⫺1
FCRAO 14 m NRAO 12 m
Mad86a Pet91
0.35
OriMC⫺1
NRAO 12 m
Hol89
0.03 0.05 0.06
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO
m m m m
Hol89 Hol89 Hol89 Hol89
OriMC⫺1
NRAO 12 m
Hol89
OriMC⫺1
NRAO 12 m
C6 H
48548.217*共5兲 48552.562*共1兲 48583.290共30兲 48585.918共30兲 48589.074共30兲
C33S C8 H
1⫺0 F⫽3/2⫺3/2 ⌸3/2 42.5⫺41.5 f 1共1,1兲⫺0共0,0兲 6共1,5兲⫺6共0,6兲 1共1,0兲⫺2共0,2兲 E
51841.418*共4兲 67768.778*共2兲
2
c⫺C3 H2 34
b
⬍0.12b
68305.680*共7兲
SO2 CH3 OH
68320. 68354.502*共1兲 68361.035*共1兲 68364.955*共1兲
unidentified CH3 CCH CH3 CCH CH3 CCH
4,3⫺3,3 4,2⫺3,2 4,1⫺3,1
68366.262*共1兲
CH3 CCH
4,0⫺3,0
68371.278*共41兲
CH2
4共0,4兲⫺3共1,3兲 J⫽5⫺4 F⫽6⫺5
0.18b 0.017
Hol89
Lov82b
68375.875*共39兲
CH2
4共0,4兲⫺3共1,3兲 J⫽5⫺4 F⫽5⫺4
0.012
OriMC⫺1
NRAO 12 m
Hol89
Lov82b
68380.873共41兲
CH2
0.019
OriMC⫺1
NRAO 12 m
Hol95
Lov82b
68972.154*共2兲 69002.890共3兲
SO2 NS
4共0,4兲⫺3共1,3兲 J⫽5⫺4 F⫽4⫺3 6共1,5兲⫺6共0,6兲
0.8
OriMC⫺1
NRAO 11 m
Joh76
2
⌸1/2 J⫽3/2⫺1/2 F⫽5/2⫺3/2 e
0.141
W51M
NRAO 12 m
Hol95
69017.895共3兲
NS
2
⌸1/2 J⫽3/2⫺1/2 F⫽3/2⫺3/2 e
0.055
W51M
NRAO 12 m
Hol95
Lee95
69019.187*共44兲
CH2
4共0,4兲⫺3共1,3兲 J⫽3⫺2 F⫽4⫺3
0.009
OriMC⫺1
NRAO 12 m
McG97
Lov82b Lee95
b
12 12 12 12
Xu_97
Lee95
69037.336共10兲
NS
2
⌸1/2 J⫽3/2⫺1/2 F⫽3/2⫺3/2e
0.049
W51M
NRAO 12 m
Hol95
69040.324共2兲
NS
2
⌸1/2 J⫽3/2⫺1/2 F⫽1/2⫺1/2e 17共⫺4,14兲⫺16共⫺5,11兲 E
0.034
W51M
NRAO 12 m
Hol95
Lee95
0.044
W51M
NRAO 12 m
Hol95
Xu_97
⌸1/2 J⫽3/2⫺1/2 e
0.051
CB24
NRAO 12 m
Tur96
Ama91
⌸ 1/2 J⫽3/2⫺1/2 F⫽5/2⫺3/2 f
0.33g
TMC⫺1
NRAO 12 m
McG94
Lee95
0.18
OriMC⫺1
NRAO 11 m
Tur89
69055.064*共23兲 69408.371共20兲 69411.943共2兲 U
18⫺17
Source
HC13CCCCN CH3 OCHO CH3 OCHO c⫺C2 H4 O C4 H C4 H
48523.04* 共2兲
49866.198*共12兲
U
4共4,1兲⫺4共3,2兲 5共0,5兲⫺4共0,4兲 42⫺41
T r 共K兲/T a 共K兲
69460.
CH3 OH SO⫹ NS
2 2
unidentified
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
201
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
U U U U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
69464.082*共2兲 69534.307*共7兲 69575.923*共2兲 69591.
SO2 CH3 CH2 CN SO2 unidentified
14共4,10兲⫺15共3,13兲 8共1,8兲⫺7共1,7兲 1共1,1兲⫺0共0,0兲
69606.856*共33兲
CH3 OH
69653.580*共2兲 70260.203*共25兲 70525. 70534.033*共9兲
SO2 SiC2 unidentified
9共1,9兲⫺10共2,8兲 A⫹ vt ⫽1 3共2,2兲⫺4共1,3兲 3共0,3兲⫺2共0,2兲
OSO 20 m OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m
Joh84 Sch83 Tur89 Tur89 Tur89
NRAO 11 m NRAO 11 m NRAO 12 m
Tur89 Tur89 Hol95
Lov82b
Xu_97
Laf78
b
OriMC⫺1
NRAO 12 m
Hol95
Lov82b
70680.720共38兲
CH2
b
OriMC⫺1
NRAO 12 m
Hol95
Lov82b
70733.206*共38兲
0.079
TMC⫺1
BTL 7 m
Gue82b
3共2,2兲⫺2共2,1兲 3共3,0兲⫺4共2,3兲 AA
0.10
70844.454*共10兲
D13CO⫹ SiC2 CH3 OCH3
4共0,4兲⫺3共1,3兲 J⫽4⫺3 F⫽5⫺4 1⫺0
IRC⫹10216 Sgr B2共M兲
NRAO 12 m NRAO 11 m
Hol89 Tur89
Gro98
70845.85*共3兲
CH3 OCH3
3共3,0兲⫺4共2,3兲 EE
0.06b
Sgr B2共M兲
NRAO 11 m
Tur89
Lov79
70847.66*共7兲
CH3 OCH3
Lov79
71055. 71067. 71152.973*共14兲 71208. 71228. 71324.608*共24兲
71362. 71452.983*共14兲 71464.138*共33兲
33
SO2
t⫺CH3 CH2 OH CH3 CH2 CH
0.13 0.05
3共3,0兲⫺4共2,3兲 AE
b
Sgr B2共M兲
NRAO 11 m
Tur89
0.05
OriMC⫺1
NRAO 11 m
Tur89 Tur89
5共2,3兲⫺5共1,4兲
0.06b
Sgr B2共M兲
NRAO 11 m
8共0,8兲⫺7共0,7兲
b
Sgr B2共M兲
NRAO 11 m
Tur89
1共0,1兲⫺0共0,0兲
0.06
OriMC⫺1
BTL 7 m
Kah84
8共1,8兲⫺7共1,7兲
0.02 0.08 0.122 0.08 0.05
NRAO NRAO NRAO NRAO NRAO NRAO
m m m m m m
Tur89 Tur89 Tur00 Tur89 Tur89 Tur89
Oes99 Wil80
H2 13CO unidentified unidentified H2 CCCC unidentified unidentified CH3 OCHO
17共4,13兲⫺17共3,14兲 A
b
OriMC⫺1 OriMC⫺1 TMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
HCOOH
3共1,2兲⫺3共0,3兲
0.04b
OriMC⫺1
NRAO 11 m
Tur89
8共0,8兲⫺7共0,7兲
0.10 0.056
OriMC⫺1 TMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 12 m NRAO 11 m
Tur89 Tur00 Tur91
SgrB2
unidentified H2 CCCC 13
CH3 CN
13
4共1兲⫺3共1兲
b
4共0兲⫺3共0兲
0.03b 0.11 0.04 0.034 0.04
NRAO 11 m
Tur91
0.09b
NRAO NRAO NRAO NRAO NRAO
m m m m m
Tur89 Hol00 Hol00 Hol00 Tur89
b
OriMC⫺1
NRAO 11 m
Tur89
0.10 0.06 0.05
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Tur89 Tur89
Oes99
6共3,4兲⫺6共2,5兲 A
0.03 0.12
OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Tur89 Tur89
Oes99
1共1,1兲⫺0共0,0兲
0.030
Sgr B2共N兲
NRAO 12 m
Tur01
27⫺26 10共1,9兲⫺10共0,10兲
0.15 0.05
Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
1⫺0
0.87
L134
NRAO 11 m
Hol76
0.03 0.07
NRAO 11 m BTL 7 m NRAO 11 m
Tur89 Cum86 Tur89
Gro98
71643.198*共6兲
CH3 CH2 CN
8共6,*兲⫺7共6,*兲
71674.924*共6兲
CH3 CH2 CN CH3 CH2 CN CH3 OCHO
8共3,6兲⫺7共3,5兲 8共3,5兲⫺7共3,4兲 6共3,4兲⫺6共2,5兲 E
unidentified CH3 OCHO a⫺CH2 CHOH HC5 N t⫺CH3 CH2 OH
11 11 12 11 11 11
OriMC⫺1 Sgr B2共N兲 Sgr B2共N兲 Sgr B2共N兲 OriMC⫺1
71500.528*共7兲 71532. 71542.200*共8兲 71578. 71643.168*共6兲
71692.939*共6兲 71703.602*共28兲 71732. 71743.983*共21兲 71830.386*共12兲
b
23共3,21兲⫺22共4,18兲
CH3 CN CH3 CH2 CN unidentified CH2 OHCHO unidentified CH3 CH2 CN
8共2,7兲⫺7共2,6兲 7共0,7兲⫺6共1,6兲 8共5,*兲⫺7共5,*兲
11 12 12 12 11
But01
72075. 72108.605*共7兲 72298.455*共6兲
DCO⫹ unidentified CH3 CH2 CN CH3 OCH3
8共2,6兲⫺7共2,5兲 10共1,9兲⫺10共0,10兲 AE⫹EA
b
OriMC⫺1 Sgr B2共M兲 OriMC⫺1
72299.970*共4兲
CH3 OCH3
10共1,9兲⫺10共0,10兲 EE
0.05b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
72301.485*共6兲
CH3 OCH3
10共1,9兲⫺10共0,10兲 AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
72403. 72409.092*共4兲 72413.4843共10兲
unidentified H2 CO DCN
0.03 0.1
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Wil73
1⫺0 F 1 ⫽1⫺1 F⫽1⫺0,1,2
b
OriMC⫺1
NRAO 11 m
Wil73
DeL69
72413.5143共10兲
DCN
1⫺0 F 1 ⫽1⫺1 F⫽2⫺1,2
0.2b
OriMC⫺1
NRAO 11 m
Wil73
DeL69
72413.5584共10兲
DCN
1⫺0 F 1 ⫽1⫺1 F⫽0⫺0,1
b
OriMC⫺1
NRAO 11 m
Wil73
DeL69
72414.9054共10兲
DCN
1⫺0 F 1 ⫽2⫺1 F⫽1⫺0,1,2
b
OriMC⫺1
NRAO 11 m
Wil73
DeL69
72414.9270共10兲
DCN
1⫺0 F 1 ⫽2⫺1 F⫽2⫺1,2
0.25b
OriMC⫺1
NRAO 11 m
Wil73
DeL69
72414.9732共10兲
DCN
1⫺0 F 1 ⫽2⫺1 F⫽3⫺2
b
OriMC⫺1
NRAO 11 m
Wil73
DeL69
72417.0297共10兲
DCN
1⫺0 F 1 ⫽0⫺1 F⫽1⫺0,1,2
0.2
OriMC⫺1
NRAO 11 m
Wil73
DeL69
OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m OSO 20 m
Tur89 Tur89 Joh84
Laf78
IRC⫹10216
OSO 20 m
Joh84
Laf78
72039.331*共13兲
U U
OriMC⫺1 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲
0.026b
71889.596*共3兲 71971.774*共25兲
U
Sch83 Joh84 Sch83 Tur89
4共0,4兲⫺3共1,3兲 J⫽4⫺3 F⫽4⫺3
71465.497*共34兲
U
OSO 20 m OSO 20 m OSO 20 m NRAO 11 m
4共0,4兲⫺3共1,3兲 J⫽4⫺3 F⫽3⫺2
71324.81*共1兲
U
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CH2
71024.781*共3兲
U
Lab. Ref.
70679.543共45兲
70976.795*共12兲
U
Astr. Ref.
Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1
70979.627*共7兲
U
n.r.a 0.30 0.60 0.08 0.10 0.24
Telescope
H13CCCN unidentified unidentified CH2
70926.227*共55兲
U U
0.70 0.20 1.3
Source
70540. 70592. 70678.633共42兲
70762.549*共21兲
U U
8⫺7
T r 共K兲/T a 共K兲
72420. 72426.
5共1,4兲⫺5共1,5兲
unidentified unidentified
72475.074*共11兲
HC13CCN
8⫺7
0.08 0.05 0.08
72482.055*共5兲
HCC13CN
8⫺7
0.08
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
202
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U
U U
U
72500. 72568.90共10兲 72578. 72618.102*共5兲 72668.076*共4兲 72680.767*共20兲 72685.593*共21兲 72707. 72758.235*共2兲 72783.818*共3兲 72823. 72837.948*共3兲 72942. 72962.731*共23兲 72976.7794共10兲 73001.958*共19兲
U
U
unidentified CH3 NH2 unidentified SiS SO2 CH3 OCHO CH3 OCHO unidentified SO2 HCCCN unidentified H2 CO unidentified HCCCN OCS
6共1,6兲⫺6共0,6兲 4⫺3 26共4,22兲⫺25共5,21兲 6共2,5兲⫺5共2,4兲 E 6共2,5兲⫺5共2,4兲 A 6共0,6兲⫺5共1,5兲 8⫺7 1共0,1兲⫺0共0,0兲 8⫺7 v7 ⫽1 ᐉ⫽1 e 6⫺5 14共3,11兲⫺13共4,10兲
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
0.02 0.08 0.13 0.77 0.30 0.18 0.18 0.10 3.4 2.29 0.15 0.5 0.20 0.15 0.25 0.08
OriMC⫺1 Sgr B2共M兲 OriMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m OSO 20 m OSO 20 m OSO 20 m OSO 20 m NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m TAO 6 m NRAO 11 m OSO 20 m TAO 6 m NRAO 11 m
Tur89 Tur89 Tur89 Joh84 Sch83 Joh84 Joh84 Tur89 Sch83 Mor76 Tur89 Aka74 Tur89 Joh84 Aka74 Tur89
0.05
Lab. Ref. Tak71
Oes99 Oes99
Laf78 Dub80
t⫺CH3 CH2 OH unidentified CH3 NH2
5共1,5兲⫺5共0,5兲 F⫽4⫺4
b
OriMC⫺1 Sgr B2共M兲
NRAO 11 m TAO 6 m
Tur89 Kai74
Kai74
73044.20共10兲
CH3 NH2
5共1,5兲⫺5共0,5兲 F⫽6⫺6
0.5b
Sgr B2共M兲
TAO 6 m
Kai74
Kai74
73045.15共10兲
CH3 NH2
5共1,5兲⫺5共0,5兲 F⫽5⫺5 4共2,2兲⫺4共1,3兲
b
Sgr B2共M兲
TAO 6 m
Kai74
Kai74
0.11
Sgr B2共M兲
BTL 7 m
Cum86
3共2,2兲⫺4共1,3兲 v2 ⫽1
0.03 0.04 0.03
8⫺7 v7 ⫽2 ᐉ⫽0
NRAO NRAO NRAO NRAO
m m m m
Tur91 Tur89 Tur89 Tur91
Laf78
U73152. 73162.008*共2兲 U73178. 73245.034*共38兲
t⫺CH3 CH2 OH unidentified SO2 unidentified HCCCN
0.03b
Sgr B2共M兲 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
73245.435*共42兲
HCCCN
8⫺7 v7 ⫽2 ᐉ⫽2 e
b
Sgr B2共M兲
NRAO 11 m
Tur91
Laf78
73246.708*共40兲
HCCCN
8⫺7 v7 ⫽2 ᐉ⫽2 f
b
Sgr B2共M兲
NRAO 11 m
Tur91
Laf78
73315.754*共59兲 73345.486*共20兲 73346.304*共7兲
65⫺64 1共0,1兲⫺0共0,0兲 5/2⫺3/2 5/2⫺3/
0.05 20.018
OriMC⫺1 TMC⫺1
NRAO 11 m NRAO 12 m
Tur89 Ohi94
Yam92
73349.648*共20兲 73462. 73462.31*共7兲
HC7 N CH2 N CH3 CH2 CN CH2 N unidentified C6 H
8共1,7兲⫺7共1,6兲 1共0,1兲⫺0共0,0兲 5/2⫺3/2 7/2⫺5/
OriMC⫺1 TMC⫺1 Sgr B2共M兲 IRC⫹10216
NRAO 11 m NRAO 12 m NRAO 11 m IRAM 30 m
Tur89 Ohi94 Tur89 Gue87
73466.884*共6兲
CH3 OCH3
2 ⌸3/2 J⫽53/2⫺51/2 e 10共2,8兲⫺10共1,9兲 EA⫹AE
0.03 20.022 0.08 0.04 b
OriMC⫺1
OSO 20 m
Joh84
Gro98
73468.670*共2兲
CH3 OCH3
10共2,8兲⫺10共1,9兲 EE
0.20b
OriMC⫺1
OSO 20 m
Joh84
Gro98
73470.456*共6兲
CH3 OCH3
10共2,8兲⫺10共1,9兲AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
73481.31*共7兲
C6 H
0.03
IRC⫹10216
IRAM 30 m
Gue87
JPL01
73552.419*共5兲
CH3 13CN
⌸3/2 J⫽53/2⫺51/2f 4共1兲⫺3共1兲
b
Sgr B2共M兲
NRAO 11 m
Tur89
73553.828*共5兲
4共0兲⫺3共0兲
0.06b 0.83 1.00
Sgr B2共M兲
NRAO 11 m
Tur89
73584.545*共1兲 73588.801*共1兲
CH3 13CN CH3 CN CH3 CN CH3 CN
2.20b
OriMC⫺1 OriMC⫺1 OriMC⫺1
OSO 20 m OSO 20 m OSO 20 m
Joh84 Joh84 Joh84
73590.220*共1兲
CH3 CN
4共0兲⫺3共0兲
b
OriMC⫺1
OSO 20 m
Joh84
73605.385*共26兲
CH2 CHCN
14共1,13兲⫺14共0,14兲 6共0,6兲⫺5共1,5兲
0.14 0.06
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Hol89 Hol89
73577.454*共1兲
73609.893*共7兲
U
Quantum numbers
73013. 73044.01共10兲
73081.181*共12兲 U
Formula
2
4共3兲⫺3共3兲 4共2兲⫺3共2兲 4共1兲⫺3共1兲
33
SO2
11 11 11 11
Yam92 JPL01
73658.210*共24兲 73663.875*共20兲
CH3 OCHO CH3 OCHO
6共5,1兲⫺5共5,0兲 E
0.04
OriMC⫺1
NRAO 12 m
Hol89
Oes99
6共5,2兲⫺5共5,1兲 E
b
OriMC⫺1
OSO 20 m
Joh84
Oes99
73665.605*共21兲
CH3 OCHO
6共5,2兲⫺5共5,1兲 A
0.15b
OriMC⫺1
OSO 20 m
Joh84
Oes99
73665.745*共21兲
CH3 OCHO
6共5,1兲⫺5共5,0兲 A
b
OriMC⫺1
OSO 20 m
Joh84
Oes99
73699.370*共14兲
14共5,10兲⫺15共4,11兲 9共2,7兲⫺9共1,8兲 AE⫹EA
0.03
73720.490*共8兲
CH3 CH2 CN CH3 OCH3
b
OriMC⫺1 OriMC⫺1
NRAO 11 m OSO 20 m
Hol89 Joh84
Gro98
73722.376*共2兲
CH3 OCH3
9共2,7兲⫺9共1,8兲 EE
0.25b
OriMC⫺1
OSO 20 m
Joh84
Gro98
73724.261*共6兲
CH3 OCH3
9共2,7兲⫺9共1,8兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
73766. 73782.929*共24兲
unidentified CH3 OCHO
0.03 6共4,2兲⫺5共4,1兲 E
b
Sgr B2共M兲 OriMC⫺1
NRAO 11 m OSO 20 m
Tur89 Joh84
Oes99
73784.532*共21兲
CH3 OCHO
6共4,3兲⫺5共4,2兲 A
0.15b
OriMC⫺1
OSO 20 m
Joh84
Oes99
73787.494*共20兲
CH3 OCHO
6共4,3兲⫺5共4,2兲 E
b
OriMC⫺1
OSO 20 m
Joh84
Oes99
73796.803*共21兲 73810.008*共7兲
CH3 OCHO CH3 CN
6共4,2兲⫺5共4,1兲 A
0.10
OriMC⫺1
OSO 20 m
Joh84
Oes99
4共0兲⫺3共0兲 v8 ⫽1 ᐉ⫽1
0.03b
OriMC⫺1
NRAO 11 m
Tur91
Bou80
73811.589*共8兲
CH3 CN
4共2兲⫺3共2兲 v8 ⫽1 ᐉ⫽1
73839.235*共31兲 73883.958*共2兲
CH3 OH SO2
9共1,8兲⫺10共2,9兲 A⫺ vt ⫽1
73885.108*共21兲
CH3 OCHO
6共3,4兲⫺5共3,3兲 A
73905.842*共25兲 73968.0*共4兲
CH3 OCHO C6 H
73981.562*共18兲
CH2 CHCN C5 H
73993.8共3兲
b
OriMC⫺1
NRAO 11 m
Tur91
Bou80
0.30
OriMC⫺1
OSO 20 m
Joh84
Xu_97
b
OriMC⫺1
NRAO 11 m
Tur89
OriMC⫺1
NRAO 11 m
Tur89
Oes99
6共3,4兲⫺5共3,3兲E
0.12b 0.12
2
⌸1/2 J⫽53/2⫺51/2 e 8共1,8兲⫺7共1,7兲
1.3f 0.04
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Cer86
Oes99 JPL01
2
⌸1/2 J⫽31/2⫺29/2 e
2.0f
Sgr B2共M兲 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Cer86
Cer86
4共2,2兲⫺5共1,5兲 v2 ⫽1
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
203
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U U U
Telescope
Astr. Ref.
Lab. Ref.
C5 H
2
⌸1/2 J⫽31/2⫺29/2 f
1.9f
IRC⫹10216
IRAM 30 m
Cer86
Cer86
2
⌸1/2 J⫽53/2⫺51/2 f
IRC⫹10216
IRAM 30 m
Cer86
JPL01
74034. 74040. 74111.24*共8兲
unidentified unidentified
OriMC⫺1 OriMC⫺1 TMC⫺1
NRAO 11 m NRAO 11 m NRAO 12 m
Tur89 Tur89 Ziu92
Ziu92
74111.312*共7兲
HCNH⫹
1⫺0 F⫽1⫺1 1⫺0
1.3f 0.02 0.05 0.13 0.10
Sgr B2共M兲
NRAO 12 m
Ziu86a
74111.42*共8兲
HCNH⫹
1⫺0 F⫽2⫺1
0.21
TMC⫺1
NRAO 12 m
Ziu92
74111.60*共8兲
HCNH⫹ C4 H
1⫺0 F⫽0⫺1
0.05
TMC⫺1
NRAO 12 m
Ziu92
Ziu92
1.38f
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
HCNH⫹
Ziu92
74149.200*共4兲
CH3 OCH3
⌸1/2 J⫽15/2⫺13/2 v7 ⫽1 e 11共2,9兲⫺11共1,10兲 EA⫹AE
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
74150.895*共2兲
CH3 OCH3
11共2,9兲⫺11共1,10兲 EE
0.30b
OriMC⫺1
OSO 20 m
Joh84
Gro98
74152.589*共4兲
CH3 OCH3
11共2,9兲⫺11共1,10兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
74155.73共10兲 74263.388*共35兲 74296.766*共21兲 74395. 74404.573*共3兲
NH2 D CH3 OCHO CH3 OCHO unidentified
2共1,2兲⫺2共0,2兲 U 6共3,3兲⫺5共3,2兲 E 6共3,3兲⫺5共3,2兲 A
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m OSO 20 m OSO 20 m NRAO 11 m OSO 20 m
Tur89 Joh84 Joh84 Tur89 Sch83
DeL75 Oes99 Oes99
Got86
2
6共0,6兲⫺5共1,5兲
0.04 0.15 0.20 0.02 0.30
74497.18*共5兲
C5 H
2
⌸3/2 J⫽31/2⫺29/2 e
5.2fb
IRC⫹10216
IRAM 30 m
Cer86a
74498.62*共5兲
C5 H
2
⌸3/2 J⫽31/2⫺29/2 f
b
IRC⫹10216
IRAM 30 m
Cer86a
Got86
74501.839*共12兲
C8 H
2
⌸3/2 63.5⫺62.5 e
0.35fb
IRC⫹10216
IRAM 30 m
Cer96
McC97
74502.992*共12兲
C8 H
2
⌸3/2 63.5⫺62.5 f
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
74510. 74551.988*共3兲 74655. 74661. 74747.514*共4兲
unidentified HC5 N unidentified unidentified CH3 OCH3
0.003 0.30 0.05 0.06
8共2,6兲⫺8共1,7兲 AE
b
IRC⫹10216 IRC⫹10216 OriMC⫺1 Sgr B2共M兲 OriMC⫺1
IRAM 30 m OSO 20 m NRAO 11 m NRAO 11 m OSO 20 m
Cer96 Joh84 Tur89 Tur89 Joh84
Gro98
74747.521*共4兲
CH3 OCH3
8共2,6兲⫺8共1,7兲 EA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
74749.506*共4兲
CH3 OCH3
8共2,6兲⫺8共1,7兲 EE
0.20b
OriMC⫺1
OSO 20 m
Joh84
Gro98
74751.495*共6兲
CH3 OCH3
8共2,6兲⫺8共1,7兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
74866.502*共2兲 74891.681*共5兲 74924.137*共5兲 74971.479*共36兲
SO2 CH3 CHO CH3 CHO CH3 OCH3
24共6,18兲⫺25共5,21兲 4共1,4兲⫺3共1,3兲 A⫹⫹ 4共⫺1,4兲⫺3共⫺1,3兲 E 12共6,7兲⫺13共5,8兲 EE
0.20 0.13 0.07
OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1
OSO 20 m BTL 7 m BTL 7 m NRAO 11 m
Sch83 Cum86 Cum86 Tur89
Kle96 Kle96 Gro98
74975.248*共24兲
CH3 OCH3
12共6,6兲⫺13共5,9兲 EE
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
t⫺CH3 CH2 OH unidentified CH3 SH CH3 NH2
3共1,3兲⫺2共0,2兲
0.23
Sgr B2共M兲
BTL 7 m
Cum86
3共1,3兲⫺2共1,2兲 A⫹⫹
0.05 0.05 0.12
OriMC⫺1 Sgr B2共N⫺LMH兲 Sgr B2共N⫺LMH兲
NRAO 11 m NRAO 12 m NRAO 12 m
Tur89 Hol02 Hol02
2.3f 0.046
IRC⫹10216
IRAM 30 m
Cer87b
SgrB2共N⫺LMH兲
NRAO 12 m
Hol02
Hol02
0.03b
OriMC⫺1 Sgr B2共N⫺LMH兲
NRAO 11 m NRAO 12 m
Tur89 Hol02
Kle96 Hol02
b
Sgr B2共N⫺LMH兲
NRAO 12 m
Hol02
Hol02
Sgr B2共N⫺LMH兲 Sgr B2共N兲 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲
NRAO 12 m NRAO 12 m NRAO 12 m NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m BTL 7 m BTL 7 m BTL 7 m BTL 7 m NRAO 11 m
Hol02 Hol00 Ziu94a Wil81 Joh84 Tur89 Tur89 Cum86 Tur89 Tur89 Lin79 Cum86 Lin79 Lin79 Tur89
Hol02 But01
75052. 75085.91共5兲 75134.58共5兲 75147.910*共4兲
U U
Source
C6 H
34
SO2
CCCS
28⫺27
4共1,4兲⫺4共0,4兲 Aa F⫽5⫺5 13⫺12
0.05b
Lee80 Tak73
8共4,5兲 v⫽0 ⫺7共4,4兲 v⫽1
75160.001*共6兲 75186.1共20兲
HOCH2 CH2 OH CH3 CHO HOCH2 CH2 OH
75186.1共20兲
HOCH2 CH2 OH
8共4,4兲 v⫽0 ⫺7共4,3兲 v⫽1
75299.9共20兲 75347.389*共8兲 75369.230*共5兲 75406. 75515.344*共21兲 75527.23*共14兲 75571.341*共65兲 75585.695*共12兲 75595. 75717.
HOCH2 CH2 OH CH2 OHCHO N2 O unidentified CH3 OH HC9 N HC7 N CH2 CHCN unidentified unidentified CH3 SH CH2 CHCN CH3 SH CH3 SH CH3 OCHO
7共0,7兲 v⫽1 ⫺6共0,6兲 v⫽0 8共1,7兲⫺7共2,6兲 3⫺2
3共2兲⫺2共2兲 A⫹ 12共2,10兲⫺12共1,11兲 AE⫹EA
0.07
75906.353*共4兲
CH3 SH CH3 OCH3
b
Sgr B2共M兲 OriMC⫺1
NRAO 11 m OSO 20 m
Tur89 Joh84
Lee80 Gro98
75907.967*共4兲
CH3 OCH3
12共2,10兲⫺12共1,11兲 EE
0.30b
OriMC⫺1
OSO 20 m
Joh84
Gro98
75909.581*共4兲
CH3 OCH3
12共2,10兲⫺12共1,11兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
75921.979*共10兲
CH2 CHCN
8共4,5兲⫺7共4,4兲
b
Sgr B2共M兲
BTL 7 m
Cum86
75922.001*共10兲
CH2 CHCN
8共4,4兲⫺7共4,3兲
b
Sgr B2共M兲
BTL 7 m
Cum86
75926.796*共12兲
CH2 CHCN
8共5兲⫺7共5兲
b
Sgr B2共M兲
BTL 7 m
Cum86
75927.706*共10兲
CH2 CHCN
8共3,6兲⫺7共3,5兲
0.06b
Sgr B2共M兲
BTL 7 m
Cum86
75151.4共20兲
U
T r 共K兲/T a 共K兲
73998.9共4兲
74976.034*共10兲 U
Quantum numbers
74007.8*共4兲
74141.7共3兲
U
Formula
75816.45共5兲 75838.867*共10兲 75862.92共7兲 75864.43共5兲 75869.630*共16兲 75880.49共5兲
6共0,6兲 ⫺5共1,5兲A⫹⫹ 8共3,6兲 v⫽0 ⫺7共3,5兲 v⫽1
13共⫺5,8兲⫺14共⫺4,11兲 E 130⫺129 67⫺66 8共0,8兲⫺7共0,7兲
3共⫺1兲⫺2共⫺1兲 E 8共2,7兲⫺7共2,6兲 3共0兲⫺2共0兲 A⫹ 3共0兲⫺2共0兲 E 3共2,2兲⫺2共1,1兲 A
0.08
0.023 0.015 0.030 0.04 0.37 0.06 0.05 0.10 0.05 0.20 ⬍0.05 0.06 0.19 0.12 b
Xu_97
Lee80 Koj80 Lee80 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
204
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U
U
U U U
U
CH2 CHCN
8共3,5兲⫺7共3,4兲
CH2 CHCN unidentified DCCCN C4 H CH2 CHCN unidentified C4 H unidentified l⫺C3 H
8共6兲⫺7共6兲
76199.925*共15兲
l⫺C3 H
76204.198*共20兲
l⫺C3 H
2
⌸1/2 3⫺2 J⫽7/2⫺5/2 F⫽4⫺3
0.129
76205.108*共20兲
l⫺C3 H
2
76247.312*共23兲 76305.717*共5兲 76362.181*共4兲
CH3 OH DNC CH3 OCH3
⌸1/2 3⫺2 J⫽7/2⫺5/2 F⫽3⫺2 11共1,10兲⫺10共2,9兲 A⫺ 1⫺0 7共2,5兲⫺7共1,6兲 AE
76362.194*共4兲
CH3 OCH3
7共2,5兲⫺7共1,6兲 EA
76364.277*共4兲
CH3 OCH3
76366.367*共8兲
CH3 OCH3
76379. 76383.84*共4兲 76405.166*共48兲 76412.158*共2兲 76415. 76491. 76499. 76509.628*共8兲 76539.02共10兲 76648.6共15兲 76662.423*共13兲
unidentified HCOOD CH3 OH SO2 unidentified unidentified unidentified CH3 OH CH3 SH unidentified
U U
Telescope
Astr. Ref.
Sgr B2共M兲
BTL 7 m
Cum86
BTL 7 m NRAO 11 m FCRAO 14 m OSO 20 m OSO 20 m OSO 20 m OSO 20 m NRAO 11 m OSO 20 m
Cum86 Tur89 Sch81 Joh84 Joh84 Joh84 Joh84 Tur89 Tha85
Lab. Ref.
2
⌸1/2 J⫽7/2⫺5/2, F⫽4⫺3 f
0.12b
Sgr B2共M兲 Sgr B2共M兲 TMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1 IRC⫹10216
2
⌸1/2 J⫽7/2⫺5/2, F⫽4⫺3 f
b
IRC⫹10216
OSO 20 m
Tha85
JPL01
TMC⫺1
NRAO 12 m
Tur00
Yam90a
0.102
TMC⫺1
NRAO 12 m
Tur00
Yam90a
0.6 0.34
NRAO 11 m NRAO 11 m OSO 20 m
Jen79 God77 Joh84
Xu_97
b
OriMC⫺1 NGC2264 OriMC⫺1
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
7共2,5兲⫺7共1,6兲 EE
0.30b
OriMC⫺1
OSO 20 m
Joh84
Gro98
7共2,5兲⫺7共1,6兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
0.10 0.03 0.10 2.5 0.12 0.20 0.10 0.6 0.07 0.09 0.07
OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m
Tur89 Tur89 Tur89 Sch83 Tur91 Tur89 Tur91 Jen79 Tur89 Cum86 Tur89
9⫺8 17/2⫺15/2 8共2,6兲⫺7共2,5兲 15/2⫺13/2
6共1,5兲⫺6共0,6兲 13共2,11兲⫺12共1,12兲 A⫹ vt ⫽1 10共1,9兲⫺9共2,8兲
5共0,5兲⫺4共1,3兲 E 7共0兲⫺6共1兲 A⫹
Laf78 Got83
Got83 JPL01
Gro98
Wil80 Xu_97
Xu_97 Lee80
t⫺CH3 CH2 OH HC7 N
2共2,0兲⫺2共1,1兲 68⫺67
0.05b
OriMC⫺1
NRAO 11 m
Tur91
76701.743*共21兲
CH3 OCHO
6共2,4兲⫺5共2,3兲 E
0.25b
OriMC⫺1
OSO 20 m
Ell80
Oes99
76711.177*共24兲
CH3 OCHO CH3 OCHO CH3 OCHO CH3 NH2 CH3 CHO
6共2,4兲⫺5共2,3兲 A 6共1,5兲⫺5共1,4兲 E 6共1,5兲⫺5共1,4兲 A 3共1,3兲⫺3共0,3兲 Aa 4共0,4兲⫺3共0,3兲 E
0.22 0.22 0.23 0.05 0.13b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
OSO 20 m OSO 20 m OSO 20 m NRAO 11 m BTL 7 m
Ell80 Joh84 Joh84 Tur89 Cum86
Oes99 Oes99 Oes99 Tak73 Kle96
CH3 OD
6共1,6兲⫺5共2,3兲 E
CH3 CHO unidentified CCCO CH3 CHO unidentified
4共0,4兲⫺3共0,3兲 A⫹⫹
b
Sgr B2共M兲
NRAO 11 m
Tur89
Kau80
Sgr B2共M兲 Sgr B2共M兲 TMC⫺1 Sgr B2共M兲 OriMC⫺1 L134N
BTL 7 m NRAO 11 m NRAO 12 m NRAO 11 m NRAO 11 m NRAO 11 m
Cum86 Tur89 Bro85 Tur89 Tur89 Sny77
Kle96
And77
N 2 D⫹
1⫺0 F 1 ⫽1⫺1
0.10 0.02 0.059 0.04 0.10 0.25
77109.61共8兲
N 2 D⫹
1⫺0 F 1 ⫽2⫺1
0.30
L134N
NRAO 11 m
Sny77
And77
77112.2共1兲
1⫺0 F 1 ⫽0⫺1 4共2,2兲⫺3共2,1兲 E
0.15
L134N
NRAO 11 m
Sny77
And77
77125.695*共5兲
N 2 D⫹ CH3 CHO
0.05b
OriMC⫺1
NRAO 11 m
Tur89
Kle96
77126.418*共5兲
CH3 CHO
4共⫺2,3兲⫺3共⫺2,2兲 E
b
OriMC⫺1
NRAO 11 m
Tur89
Kle96
77214.360*共3兲 77218.295*共5兲
HC5 N CH3 CHO
29⫺28 4共2,2兲⫺3共2,1兲 A⫹⫹
0.25 0.17b
IRC⫹10216 Sgr B2共M兲
OSO 20 m NRAO 11 m
Joh84 Tur89
Kle96
20共3,17兲⫺19共4,16兲
0.04b
OriMC⫺1
NRAO 11 m
Tur89
8共5,3兲⫺9共4,6兲
0.03b 0.12 0.12 0.05
OriMC⫺1
NRAO 11 m
Tur89
Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Tur89 Tur89
0.04 0.05
Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Tur89
0.05 0.12 0.10 0.07
NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Cum86 Tur89 Tur91 Tur89
Gro98
76878.958*共5兲 76966. 76972.590*共7兲 77038.605*共5兲 77071. 77107.86共9兲
77235.127*共22兲
U
b
0.13 0.03 0.11 0.17 0.10 0.10 0.17 0.20
Source
76699.124*共68兲
77231.384*共5兲
U U
T r 共K兲/T a 共K兲
75931.858*共10兲
76868.83共5兲
U
Quantum numbers
75937.823*共14兲 75979. 75987.149*共4兲 76117.43*共1兲 76128.890*共10兲 76152. 76156.02*共1兲 76162. 76198.724*共13兲
76795.962*共20兲 76804.025*共21兲 76838.70共10兲 76866.437*共5兲
U
Formula
34
SO2
8⫺7 4共2,3兲⫺3共2,2兲 A⫺
Kle96
77269.81*共15兲 77290. 77445.
t⫺CH3 CH2 OH HC9 N unidentified unidentified
77458. 77498.900*共16兲 77511. 77633.828*共12兲 77687. 77731.725*共7兲 77735.05*共14兲
unidentified CH3 CH2 CN unidentified CH2 CHCN unidentified CCS CH3 OCH3
6,6⫺5,5 18共8,11兲⫺19共7,13兲 EA
b
OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 Sgr B2
77736.28*共14兲
CH3 OCH3
18共8,11兲⫺19共7,13兲 EE
b
Sgr B2
NRAO 11 m
Tur89
Gro98
77737.34*共14兲
CH3 OCH3
18共8,11兲⫺19共7,12兲 AA
b
Sgr B2
NRAO 11 m
Tur89
Gro98
77737.57*共14兲
CH3 OCH3
18共8,10兲⫺19共7,13兲 AA
0.20b
Sgr B2
NRAO 11 m
Tur89
Gro98
77737.80*共14兲
CH3 OCH3
18共8,11兲⫺19共7,12兲 AE
b
Sgr B2
NRAO 11 m
Tur89
Gro98
77738.03*共14兲
CH3 OCH3
18共8,10兲⫺19共7,13兲 AE
b
Sgr B2
NRAO 11 m
Tur89
Gro98
133⫺132
19共2,17兲⫺18共3,16兲 8共1,7兲⫺7共1,6兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
205
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
U U U U U U U
U
U
U U U
U U
U U
U U
Quantum numbers 18共8,10兲⫺19共7,12兲 EE
77739.09*共14兲
CH3 OCH3
77744. 77826.902*共71兲 77836.702*共12兲 77930.4 77976. 77978.5共13兲 77988. 78063. 78068. 78183.628*共7兲 78262. 78361.417*共6兲
unidentified HC7 N NaCN unidentified unidentified unidentified unidentified unidentified unidentified CH3 CH2 CN unidentified CH3 OCH3
6共2,4兲⫺6共1,5兲 AE
78361.442*共6兲
CH3 OCH3
6共2,4兲⫺6共1,5兲 EA
78363.614*共4兲
CH3 OCH3
78365.799*共8兲
CH3 OCH3
78397.020*共3兲
U
Formula
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref. Gro98
Sgr B2
NRAO 11 m
Tur89
b
Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216 IRC⫹10216 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 12 m NRAO 12 m NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m OSO 20 m
Tur89 Tur91 Tur94 Tur94 Tur89 Cum86 Tur89 Tur89 Tur89 Joh84 Tur89 Joh84
Gro98
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
6共2,4兲⫺6共1,5兲 EE
0.25b
OriMC⫺1
OSO 20 m
Joh84
Gro98
6共2,4兲⫺6共1,5兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
69⫺68 5共0,5兲⫺4共0,4兲
9共1,9兲⫺8共1,8兲
b
0.14 0.05 0.01 0.008 0.10 0.13 0.06 0.06 0.04 0.25 0.05
Tur94
8共3,5兲⫺9共2.8兲
0.05
OriMC⫺1
NRAO 11 m
Tur91
78436.847*共16兲 78479.327*共24兲
SO2 CH3 CH2 CN CH3 OCHO
23共2,21兲⫺23共1,22兲 7共1,7兲⫺6共1,6兲 E
0.05
Sgr B2 OriMC⫺1
NRAO 11 m OSO 20 m
Tur91 Joh84
Oes99
78481.411*共24兲
CH3 OCHO
7共1,7兲⫺6共1,6兲 A
OriMC⫺1
OSO 20 m
Joh84
Oes99
78517.409*共58兲 78633.527*共16兲 78637.457共50兲
CH3 OCHO NH2 CHO
10共1,9兲⫺10共0,10兲 E 16共2,14兲⫺15共3,13兲 5共0,5兲⫺5共1,5兲 vt ⫽1⫺0
0.65b 0.09 0.04 0.05
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRO 45 m
Tur89 Tur89 Tur89
Oes99
0.05 0.05
NRAO 11 m NRAO 11 m OSO 20 m
Tur89 Tur89 Joh84
Gro98
34
0.75b
Pea97
78711.403*共3兲
g⫺CH3 CH2 OH SO2
19共5,15兲⫺20共4,16兲 v2 ⫽1
78752. 78856.274*共4兲
unidentified CH3 OCH3
13共2,11兲⫺13共1,12兲 AE⫹EA
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
78857.824*共4兲
CH3 OCH3
13共2,11兲⫺13共1,12兲 EE
0.38b
OriMC⫺1
OSO 20 m
Joh84
Gro98
78859.373*共4兲
CH3 OCH3
13共2,11兲⫺13共1,12兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
78867. 78954.672*共74兲 79007.11共10兲
unidentified HC7 N CH3 NH2
0.04 0.03
1共1,1兲⫺1共0,1兲 Aa F⫽0⫺1
b
OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m NRAO 11 m
Tur91 Tur91 Tur89
79008.70共10兲
CH3 NH2
1共1,1兲⫺1共0,1兲 Aa F⫽2⫺2
0.08b
Sgr B2共M兲
NRAO 11 m
Tur89
79010.36共10兲
CH3 NH2
1共1,1兲⫺1共0,1兲 Aa F⫽1⫺0
b
Sgr B2共M兲
NRAO 11 m
Tur89
79012.35*共16兲
HC9 N
136⫺135
b
Sgr B2共M兲
NRAO 11 m
Tur89
79055. 79099.313*共5兲 79150.172*共5兲 79151.01*共2兲
unidentified CH3 CHO CH3 CHO CCCN
4共1,3兲⫺3共1,2兲 E 4共1,3兲⫺3共1,2兲 A⫺⫺ 8⫺7 J⫽17/2⫺15/2
0.03 0.15 0.3 0.27
Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216
NRAO 11 m BTL 7 m NRAO 11 m OSO 20 m
Tur91 Cum86 Lis78 Joh84
Kle96 Kle96 Got83
79169.77*共2兲
CCCN
8⫺7 J⫽15/2⫺13/2
0.27
IRC⫹10216
OSO 20 m
Joh84
Got83
79221.9共50兲 79289. 79334. 79350.476*共8兲
unidentified unidentified unidentified 9⫺8
0.05 0.05 0.05 0.56
Sgr Sgr Sgr Sgr
B2共M兲 B2共M兲 B2共M兲 B2共M兲
BTL 7 m NRAO 11 m NRAO 11 m BTL 7 m
Cum86 Tur89 Tur89 Wan78
Laf78
9共3,7兲⫺9共2,8兲 A
0.06
Sgr B2共M兲
NRAO 11 m
Tur89
Oes99
0.06 0.27 0.08 0.05 0.15
Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 W51 M OriMC⫺1
NRAO 11 m BTL 7 m NRAO 11 m NRAO 12 m OSO 20 m
Tur89 Wan78 Tur89 Woo92 Joh84
0.10 0.25 0.06
NRAO 12 m OSO 20 m NRAO 11 m OSO 20 m
Woo92 Joh84 Tur89 Joh84
Gro98
79432.720*共28兲 79438. 79449.73共9兲 79465. 79488.290*共58兲 79581.804*共19兲
H13CCCN CH3 OCHO unidentified NH2 CN unidentified CH3 OCHO 13
70⫺69
4共1,4兲⫺3共1,3兲 9共2,8兲⫺9共1,9兲 A 5共⫺1,5兲⫺4共0,4兲 E
Joh76a Oes99 Xu_97
79624. 79677.504*共7兲 79699. 79753.698*共4兲
CH3 OH unidentified CH3 CH2 CN unidentified CH3 OCH3
15共3,13兲⫺14共4,10兲 AA
b
W51 M OriMC⫺1 OriMC⫺1 OriMC⫺1
79756.610*共6兲
CH3 OCH3
15共3,13兲⫺14共4,10兲 EE
0.06b
OriMC⫺1
OSO 20 m
Joh84
Gro98
79759.451*共8兲
CH3 OCH3
15共3,13兲⫺14共4,10兲 EA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
79759.595*共8兲
CH3 OCH3
15共3,13兲⫺14共4,10兲 AE
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
79781.648*共24兲
CH3 OCHO
7共0,7兲⫺6共0,6兲 E
0.30b
OriMC⫺1
OSO 20 m
Joh84
Oes99
79783.908*共24兲
CH3 OCHO
7共0,7兲⫺6共0,6兲 A
b
OriMC⫺1
OSO 20 m
Joh84
Oes99
79812.322*共14兲 79813. 79870. 79876.711*共4兲 79963.261*共2兲
c⫺C3 HD unidentified unidentified HC5 N NH2 CN
2共1,2兲⫺1共0,1兲
30⫺29 4共2,3兲⫺3共2,2兲
TMC⫺1 Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216 Sgr B2共M兲
NRAO 12 m NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m
Ger87 Tur89 Tur89 Joh84 Tur89
JPL01
79965.006*共2兲
NH2 CN
4共2,2兲⫺3共2,1兲
0.07b
Sgr B2共M兲
NRAO 11 m
Tur89
JPL01
79979.596共90兲
4共0,4兲⫺3共0,3兲 4共1,4兲⫺3共1,3兲
0.07 0.1b
Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Tur77 Tur77
Joh76a
80076.644*共20兲
NH2 CN CH2 CO
80082.436*共77兲
HC7 N
71⫺70
b
Sgr B2共M兲
NRAO 11 m
Tur91
9共0,9兲⫺8共0,8兲
0.34 0.05 0.05 0.25 b
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
206
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U
U
80160. 80266.195*共13兲 80319. 80383.895*共15兲 80393. 80404.894*共7兲 80421.883*共5兲 80479. 80480.25 80484.5 80504.60共10兲 80522.3共10兲
U
80525.0共10兲
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
2共2,1兲⫺2共1,2兲
0.03 0.07
OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Tur89 Tur89
0.02 0.10 0.03 0.25 2.7f 0.04 0.12
OriMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲
NRAO 11 m IRAM 30 m NRAO 11 m OSO 20 m IRAM 30 m NRAO 11 m FCRAO 14m
Tur89 Cer91a Tur89 Joh84 Cer88 Tur89 Irv88a
Irv88a
0.12 0.36g
Sgr B2共M兲 Sgr B2共M兲
FCRAO 14m NRAO 11 m
Irv88a Tur75a
Irv88a Joh76a Gue95
unidentified t⫺CH3 CH2 OH unidentified H2 CCCC unidentified CH3 CH2 CN CH3 NC unidentified CH2 CN CH2 CN
9共0,9兲⫺8共0,8兲 9共2,8兲⫺8共2,7兲 4⫺3 4⫺311/2⫺9/2
NH2 CN
4⫺39/2⫺7/2 4共1,3兲⫺3共1,2兲
26
13/2,7⫺11/2,6
MgNC
unidentified 15/2,7⫺13/2,6
0.60f
IRC⫹10216
IRAM 30 m
Gue95
0.45f
IRC⫹10216
IRAM 30 m
Gue95
0.52f
IRC⫹10216
IRAM 30 m
Gue95
Gue95
5共2,3兲⫺5共1,4兲 AE
b
Sgr B2共M兲
NRAO 11 m
Tur75a
Gro98
80536.405*共6兲
CH3 OCH3
5共2,3兲⫺5共1,4兲 EA
b
Sgr B2共M兲
NRAO 11 m
Tur75a
Gro98
80538.646*共4兲
CH3 OCH3
5共2,3兲⫺5共1,4兲 EE
0.2bg
Sgr B2共M兲
NRAO 11 m
Tur75a
Gro98
80540.913*共8兲
CH3 OCH3
5共2,3兲⫺5共1,4兲 AA
b
Sgr B2共M兲
NRAO 11 m
Tur75a
Gro98
80547.628*共9兲
CH3 CH2 CN
9共2,8兲⫺9共1,9兲 1共1,0兲⫺1共1,1兲
0.03
Sgr B2 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Tur75b
OriMC⫺1
OSO 20 m
Olo84
OSO 20 m OSO 20 m NRAO 11 m
Olo84 Olo84 Hol80
26
MgNC
⬍0.4g 0.3
80578.283*共53兲
HDO
80602.135*共6兲 80604.578*共7兲
9共6,*兲⫺8共6,*兲
80606.213*共6兲 80619.231*共7兲
CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN
0.12b
OriMC⫺1 OriMC⫺1 OriMC⫺1
80619.686*共7兲
CH3 CH2 CN
9共4,5兲⫺8共4,4兲
b
OriMC⫺1
NRAO 11 m
Hol80
80649.870*共7兲
CH3 CH2 CN
80662.304*共14兲 80682.810*共7兲 80723.186*共5兲
SiC3 CH3 CH2 CN
9共3,7兲⫺8共3,6兲 8共0,7兲⫺6共0,6兲 9共3,6兲⫺8共3,5兲 4共2,2兲⫺4共1,3兲
0.04 0.005 0.05 0.05
OriMC⫺1 IRC⫹10216 OriMC⫺1 Sgr B2共M兲
NRAO NRAO NRAO NRAO
m m m m
Hol80 App99 Hol80 Tur89
0.06
Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Hol80 Tur89
80733.共1兲 80802.061*共20兲
9共5,*兲⫺8共5,*兲 9共7,*兲⫺8共7,*兲 9共4,6兲⫺8共4,5兲
c⫺C3 H2 unidentified CH2 CO
0.4 0.2
4共3,1兲⫺3共3,0兲
b
4共3,2兲⫺3共3,1兲
0.10b 0.12
CH2 CO
80808. 80820.409*共18兲
unidentified CH2 CO
4共2,3兲⫺3共2,2兲
b
80824.314*共18兲
CH2 CO
4共2,2兲⫺3共2,1兲
CH2 CO unidentified SiC
4共0,4兲⫺3共0,3兲
U
80832.107*共21兲 80876. 80988.*
0.06b 0.1 0.12 0.03
U
80993.257*共19兲 81033. 81062.*
CH3 OH unidentified SiC
81210.194*共81兲 81230. 81261.436*共7兲 81392.284*共17兲 81398. 81469. 81477.49共10兲 81505.208*共10兲 81518. 81534.125*共11兲
HC7 N unidentified CH3 CH2 CN CH3 OCHO unidentified unidentified HNO CCS unidentified HC13CCN
81541.981*共5兲
HCC13CN
81570. 81586.229*共20兲 81652.931*共40兲 81674. 81683.433*共21兲
unidentified CH2 CO CH3 OH unidentified
U
U U
U
U
U
U U u U U
Kil90
CH3 OCH3
5兲
80802.062*共20兲 U
Lab. Ref.
80536.354*共6兲
80535.1共
U
Formula
81693.444*共1兲 81727. 81737. 81742. 81746.513*共29兲 81768. 81777. 81777.90*共8兲
t⫺CH3 CH2 OH NH2 CHO unidentified unidentified unidentified CH3 CH2 CN unidentified unidentified C6 H
81789.000*共16兲
共CH3 兲2 CO
81789.275*共16兲
共CH3 兲2 CO
81801.25*共8兲
C6 H
Sgr B2共M兲
NRAO 11 m
Tur89
OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Tur89 Tur89
Sgr B2共M兲
NRAO 11 m
Tur89
Sgr B2共M兲 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Tur77 Tur89 Cer89
1.50 0.14 0.03
OriMC⫺1 OriMC⫺1 IRC⫹10216
OSO 20 m NRAO 11 m IRAM 30 m
Joh84 Tur89 Cer89
9⫺8
0.04 0.05 0.40 0.06 0.02 0.03 0.033 0.19 0.05 0.050
Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m BTL 7 m
Tur91 Tur89 Joh84 Tur89 Tur89 Tur91 Uli77 Cum86 Tur89 Wan78
9⫺8
0.052
Sgr B2共M兲
BTL 7 m
Wan78
Laf78
0.02 0.15 0.35 0.05 0.10
OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m
Tur89 Tur77 Joh84 Tur89 Tur89
Xu_97
⌸3/2 J⫽59/2⫺57/2e
0.18 0.03 0.03 0.04 0.05 0.03 0.02 0.05
Sgr B2共M兲 Sgr B2共N⫺LMH兲 Sgr B2共N⫺LMH兲 OriMC⫺1 Sgr B2共N⫺LMH兲 Sgr B2共N⫺LMH兲 Sgr B2共N⫺LMH兲 IRC⫹10216
BTL 7 m NRAO 12 m NRAO 12 m NRAO 11 m NRAO 12 m NRAO 12 m NRAO 12 m IRAM 30m
Cum86 Sny02 Sny02 Tur89 Sny02 Sny02 Sny02 Gue87
JPL01
7共1,6兲⫺6共2,5兲 AE
0.03b
Sgr B2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
b
Sgr B2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
IRC⫹10216
IRAM 30 m
Gue87
JPL01
3 ⌸1 2⫺1 e 7共2,6兲⫺8共1,7兲 A⫺
3
⌸1 2⫺1 f 72⫺71
9共2,7兲⫺8共2,6兲 3共2,1兲⫺2共1,2兲 A
1共0,1兲⫺0共0,0兲 7,6⫺6,5
4共1,3兲⫺3共1,2兲 18共4,14兲⫺19共3,16兲 E 8共1,7兲⫺7共2,6兲 4共1,4兲⫺3共1,3兲
18共1,17兲⫺18共0,18兲
2
7共1,6兲⫺6共2,5兲 EA 2
11 12 11 11
⌸3/2 J⫽59/2⫺57/2 f
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
0.04
Cer89 Xu_97 Cer89
Oes99
Sai72
Laf78
MICROWAVE TRANSITIONS
207
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U U U
Telescope
Astr. Ref.
Lab. Ref.
共CH3 兲2 CO
7共2,6兲⫺6共1,5兲 EA
0.03b
Sgr B2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
7共2,6兲⫺6共1,5兲 AE
b
Sgr B2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
81813.725*共12兲
共CH3 兲2 CO 共CH3 兲2 CO 共CH3 兲2 CO unidentified 共CH3 兲2 CO unidentified HCCCN unidentified HCCCN unidentified unidentified
7共1,6兲⫺6共2,5兲 EE 7共2,6兲⫺6共1,5兲 EE 7共1,6兲⫺6共2,5兲 AA
Sgr Sgr Sgr Sgr Sgr Sgr
Gro02 Gro02 Gro02
81833.051*共12兲 81838.238*共18兲 81847. 81858.110*共18兲 81866. 81881.462*共3兲 81906. 81935.004*共59兲 81948. 81957. 81970.0共20兲
82124.345*共3兲
7⫺6
0.04 0.03 0.03 0.04 0.05 0.10 2.51 ⫺0.03 0.04 0.04 0.03 1.40f
B2共N⫺LMH兲 B2共N⫺LMH兲 B2共N⫺LMH兲 B2共N⫺LMH兲 B2共N⫺LMH兲 B2共N⫺LMH兲 Sgr B2共M兲 Sgr B2共N⫺LMH兲 Sgr B2共N⫺LMH兲 Sgr B2共N⫺LMH兲 Sgr B2共N⫺LMH兲 IRC⫹10216
NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m BTL 7 m NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m IRAM 30 m
Sny02 Sny02 Sny02 Sny02 Sny02 Sny02 Wan78 Sny02 Sny02 Sny02 Sny02 Gue95
11共2,9兲⫺11共2,10兲 9⫺8 v7 ⫽1 ᐉ⫽1 e 2共0,2兲⫺1共1,1兲
0.04 0.30 0.12
Sgr B2共N⫺LMH兲 OriMC⫺1 Sgr B2共M兲
NRAO 12 m OSO 20 m BTL 7 m
Sny02 Joh84 Cum86
7共0,7兲⫺6共0,6兲 3共2,2兲⫺3共1,3兲
0.05 0.05
Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Fre79 Tur89
7共2,6兲⫺6共1,5兲 AA 9⫺8 9⫺8 v5 ⫽1 ᐉ⫽1 f
25
MgNC CH2 NH HCCCN
c⫺C3 H2 HNCS t⫺ CH3 CH2 OH
Gro02
Laf78
Gue95 Laf78
10共1,9兲⫺9共2,8兲
0.10
OriMC⫺1
OSO 20 m
Joh84
HCCCN CH3 OCHO
9⫺8 v7 ⫽1 ᐉ⫽1 f 7共1,7兲⫺6共0,6兲 E
0.23
OriMC⫺1
OSO 20 m
Joh84
Laf78
0.03b
Sgr B2共OH兲
IRAM 30 m
Gom86
Oes99
82244.488*共28兲
CH3 OCHO
7共1,7兲⫺6共0,6兲 A
b
Sgr B2共OH兲
IRAM 30 m
Gom86
Oes99
82303.756*共26兲
2共1,2兲⫺1共0,1兲
0.035
Sgr B2共OH兲
IRAM 30 m
Gom86
82337.944*共84兲 82383.4*共4兲
c⫺HC13CCH HC7 N C6 H
73⫺72
82399.91*共4兲 82456.986*共6兲
HCCCN CH3 OCH3
82458.611*共7兲 82458.660*共6兲
82200.372*共26兲 82242.942*共25兲
34
SO2
⌸1/2 J⫽59/2⫺57/2 f 9⫺8 v7 ⫽2 ᐉ⫽0 11共1,10兲⫺11共0,11兲 AE⫹EA
0.04 1.10f
Sgr B2共OH兲 IRC⫹10216
IRAM 30 m IRAM 30 m
Gom86 Cer87a
JPL01
0.04 b
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Tur89
Laf78 Gro98
CH3 CH2 CN
9共1,8兲⫺8共1,7兲
0.45b
OriMC⫺1
OSO 20 m
Joh84
CH3 OCH3
11共1,10兲⫺11共0,11兲 EE
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
82460.334*共8兲
CH3 OCH3
11共1,10兲⫺11共0,11兲 AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
82470.670*共8兲 82516. 82518. 82539.040*共4兲 82539.375*共47兲
CH2 OHCHO unidentified unidentified HC5 N HCCCN
8共0,7兲⫺7共1,7兲
0.03b
Sgr B2共N兲 OriMC⫺1 Sgr B2共N兲 OriMC⫺1 Sgr B2共M兲
NRAO NRAO NRAO NRAO NRAO
m m m m m
Hol00 Tur91 Hol00 Buj81 Tur89
But01
31⫺30 9⫺8 v7 ⫽3 ᐉ⫽1 e
0.045 0.04 0.06 0.13
82548.615*共4兲
NH2 CHO
1共1,1兲⫺0共0,0兲 F⫽0⫺1
b
Sgr B2共M兲
NRAO 11 m
Tur89
82549.561*共2兲
NH2 CHO
1共1,1兲⫺0共0,0兲 F⫽2⫺1
0.07b
Sgr B2共M兲
NRAO 11 m
Tur89
82550.034*共2兲
NH2 CHO
b
Sgr B2共M兲
NRAO 11 m
Tur89
82649.435*共8兲
CH3 OCH3
1共1,1兲⫺0共0,0兲 F⫽1⫺1 3共1,3兲⫺2共0,2兲 AE⫹EA
b
OriMC⫺1
NRAO 11 m
Cla79
82650.306*共27兲
11共1,10兲⫺11共0,11兲
b
OriMC⫺1
NRAO 11 m
Tur91
82650.316*共2兲
t⫺CH3 CH2 OH CH3 OCH3
3共1,3兲⫺2共0,2兲 EE
0.2b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
82651.197*共4兲
CH3 OCH3
3共1,3兲⫺2共0,2兲 AA
b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
82659.675*共35兲
HCCCN CH3 OCH3
9⫺8 v7 ⫽3 ᐉ⫽3 4共2,2兲⫺4共1,3兲 AE
0.036 b
Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Cla79
Laf78 Gro98
4共2,2兲⫺4共1,3兲 EA
0.10
OriMC⫺1
NRAO 11 m
Cla79
Gro98
82691.073*共8兲 82713.423*共12兲
CH3 OCH3 CH3 OCH3 CH3 OCH3 C8 H
4共2,2兲⫺4共1,3兲 EE 4共2,2兲⫺4共1,3兲 AA
0.12 0.08
2
⌸3/2 70.5⫺69.5 e
0.24fb
OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Cla79 Cla79 Cer96
Gro98 Gro98 McC97
82716.069*共12兲
C8 H
2
⌸3/2 70.5⫺69.5 f
82776.235*共44兲
HCCCN
82686.358*共6兲 82686.482*共6兲 82688.746*共4兲
2
12 11 12 11 11
Laf78
Gro98
IRC⫹10216
IRAM 30 m
Cer96
McC97
0.07b
Sgr B2共N⫺LMH兲
NRAO 12 m
Sny02
Laf78
b
Sgr B2共N⫺LMH兲
NRAO 12 m
Sny02
0.03 0.04 0.05
Sgr B2共M兲 SgrB2共N⫺LMH兲 SgrB2共N⫺LMH兲
IRAM 30 m NRAO 12 m NRAO 12 m
Com87 Sny02 Sny02
5共2兲⫺4共2兲
0.06 0.04 0.06 0.03
OriMC⫺1 SgrB2共N⫺LMH兲 OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 12 m NRAO 11 m IRAM 30 m
Tur89 Sny02 Tur89 Com87
CH3 C13CH
22共5,18兲⫺23共4,19兲 A⫹ 5共1兲⫺4共1兲
0.03 0.02
Sgr B2共M兲 Sgr B2共M兲
IRAM 30 m IRAM 30 m
Com87 Com87
CH3 C13CH 共CH3 兲2 CO
5共0兲⫺4共0兲
0.01
Sgr B2共M兲
IRAM 30 m
Com87
82908.641*共20兲
8共0,8兲⫺7共1,7兲 AE
0.02b
Sgr B2共M兲
NRAO 43 m
Com87
Gro02a
82908.666*共20兲
共CH3 兲2 CO
8共1,8兲⫺7共0,7兲 AE
b
Sgr B2共M兲
NRAO 43 m
Com87
Gro02a
82908.690*共18兲
共CH3 兲2 CO
8共0,8兲⫺7共1,7兲 EA
0.02b
Sgr B2共M兲
NRAO 43 m
Com87
Gro02a
82908.714*共18兲
共CH3 兲2 CO
8共1,8兲⫺7共0,7兲 EA
b
Sgr B2共M兲
NRAO 43 m
Com87
Gro02a
82777.116*共46兲
U U U
Source
共CH3 兲2 CO
82101.67*共5兲 82115.670*共13兲
U
T r 共K兲/T a 共K兲
81807.889*共14兲
82082.730*共26兲 82093.555*共7兲
U
Quantum numbers
81807.951*共16兲
81980.071*共33兲
U U
Formula
33
SO2
82783. 82825.639*共10兲 82833.
unidentified CH3 CHO unidentified
82870. 82875. 82889. 82894.863*共14兲
unidentified unidentified unidentified
82897.08*共10兲 82899.528*共15兲 82901.083*共16兲
CH3 C13CH CH3 OH
9⫺83 v7 ⫽1 ᐉ⫽1 f 26共4,22兲25共5,21兲 10共1,9兲⫺10共0,10兲 A⫺⫹
b
Kle96
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
208
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
82916.512*共14兲
共CH3 兲2 CO
8共0,8兲⫺7共1,7兲 EE
0.04b
Sgr B2共M兲
IRAM 30 m
Com87
Gro02a
82916.538*共14兲
共CH3 兲2 CO
8共1,8兲⫺7共0,7兲 EE
b
Sgr B2共M兲
IRAM 30 m
Com87
Gro02a
82924.311*共22兲
共CH3 兲2 CO
8共0,8兲⫺7共1,7兲 AA
0.03b
Sgr B2共M兲
IRAM 30 m
Com87
Gro02a
82924.338*共22兲
共CH3 兲2 CO
8共1,8兲⫺7共0,7兲 AA
b
Sgr B2共M兲
IRAM 30 m
Com87
Gro02a
82951.942*共2兲
SO2
13共4,10兲⫺14共3,11兲 3共1,2兲⫺3共0,3兲
1.10 0.16
OriMC⫺1 Sgr B2共M兲
OSO 20 m BTL 7 m
Sch83 Cum86
32⫺31
0.24f
IRC⫹10216
IRAM 30 m
Gue00
⌸1/2 J⫽15/2⫺13/2 e
0.16f
IRC⫹10216
IRAM 30 m
Gue00
App00
0.04 0.15f
SgrB2共N⫺LMH兲 IRC⫹10216
NRAO 12 m IRAM 30 m
Sny02 Gue00
App00
0.06
SgrB2共N⫺LMH兲
NRAO 12 m
Sny02
82966.201*共5兲
c⫺C3 H2
82983.51*共17兲 82990.44*共2兲
H13CCCCCN SiCN
82995. 83015.62*共2兲
unidentified SiCN
83025.430*共19兲 83043.818*共3兲
CH3 CH2 CN
83048.423*共23兲
CCC13CH
83057.970*共2兲
OC34S C7 H
OriMC⫺1
OSO 20 m
Sch83
IRC⫹10216
IRAM 30 m
Gue97
7⫺6
0.040
Sgr B2共M兲
BTL 7 m
Gol81
COL01
0.06f
IRC⫹10216
IRAM 30 m
Gue97
McC97
0.006
IRC⫹10216
IRAM 30 m
Gue97
COL01
83097.425*共4兲
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
83098.929*共4兲
CH3 OCH3
14共2,12兲⫺14共1,13兲 EE
0.35b
OriMC⫺1
OSO 20 m
Joh84
Gro98
83100.433*共4兲
CH3 OCH3
14共2,12兲⫺14共1,13兲 AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
2.10f
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
0.02 0.002
IRAS16293⫺2422 IRC⫹10216
IRAM 30 m IRAM 30 m
Par02 Gue97
Su_89
4共0,3兲⫺3共0,2兲 9共1,9兲⫺8共1,8兲
0.12 0.060 0.20
⌸3/2 47.5⫺46.5 f
0.08bf
IRC⫹10216 TMC⫺1 OriMC⫺1 IRC⫹10216
OSO 20 m NRAO 12 m OSO 20 m IRAM 30 m
Joh84 Tur00 Joh84 Gue97
McC97
b
IRC⫹10216
IRAM 30 m
Gue97
McC97
IRAS16293⫺2422 IRAS16293⫺2422 OriMC⫺1
IRAM 30 m IRAM 30 m OSO 20 m
Par02 Par02 Joh84
Su_89 Su_89 Gro98
C4 H
2
2
2
CHD2 OH 13
83163. 83165.256*共18兲 83207.510*共12兲 83260.240*共12兲
CH3CCH unidentified H2 CCC CH2 CHCN C7 H
83260.473*共12兲
C7 H
⌸1/2 J⫽17/2⫺15/2 v7 ⫽1 f 2共0兲⫺1共0兲 e1 5共0兲⫺4共0兲
2
83303.74共4兲 83319.414*共8兲
CHD2 OH CHD2 OH CH3 OCH3
⌸3/2 47.5⫺46.5 e 2共0兲⫺1共0兲 e0 2共0兲⫺1共0兲 o1 8共1,7兲⫺7共2,6兲 AA
0.02 0.02
83321.256*共6兲
CH3 OCH3
8共1,7兲⫺7共2,6兲 EE
0.17b
OriMC⫺1
OSO 20 m
Joh84
Gro98
83323.091*共6兲
CH3 OCH3
8共1,7兲⫺7共2,6兲 AE
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
83323.105*共6兲
CH3 OCH3
8共1,7兲⫺7共2,6兲 EA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
83336. 83345.812*共17兲
unidentified 8共1,7兲⫺8共0,8兲
0.04 0.04
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Tur89
83465.687*共85兲 83523.142*共10兲
HC7 N
74⫺73
0.04
Sgr B2共M兲
NRAO 11 m
Tur89
24
MgNC
13/2,7⫺11/2,6
3.7
IRC⫹10216
IRAM 30 m
Gue93
Kaw93
83538.361*共10兲
24
MgNC
15/2,7⫺13/2,6
3.9
IRC⫹10216
IRAM 30 m
Gue93
Kaw93
18共5,13兲⫺19共4,16兲
0.02
OriMC⫺1
NRAO 11 m
Tur89
2
33
SO2
33
SO2
b
83541.5共8兲
C5 H
2
⌸1/2 J⫽35/2⫺33/2 e
1.7f
IRC⫹10216
IRAM 30 m
Cer86
Cer86
83547.1共6兲
C5 H
2
⌸1/2 J⫽35/2⫺33/2 f 2共⫺1,2兲⫺1共0,1兲 E
2.2f 0.05
IRC⫹10216
IRAM 30 m
Cer86
Cer86
Sgr B2共M兲
NRAO 12 m
Ziu86a
Kle96
8共1,7兲⫺8共0,8兲 ⌸0 2⫺1 e
0.86 0.02 0.02
OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Tur91 Tur89 Cer89
Cer89
⌸1/2 J⫽17/2⫺15/2 v7 ⫽1 e
1.52f
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
83584.282*共6兲 83688.086*共2兲 83805. 83842.*
CH3 CHO SO2 unidentified SiC
3
83879.8共4兲
C4 H
83886.478*共12兲
C8 H
2
⌸3/2 71.5⫺70.5 e
0.32fb
IRC⫹10216
IRAM 30 m
Cer96
McC97
83889.197*共12兲
C8 H
2
⌸3/2 71.5⫺70.5 f
b
IRC⫹10216
IRAM 30 m
Cer96
McC97
NRAO 11 m NRAO 12 m BTL 7 m
Tur89 Tur00 Cum86
Kau80
83903.30共10兲
U U
0.50 0.006
⌸3/2 J⫽9.5⫺8.5 14共2,12兲⫺14共1,13兲 AE⫹EA
83540.677*共20兲
U
8共1,7兲⫺8共0,8兲 ⌸3/2 J⫽8.5⫺7.5
⌸1/2 47.5⫺46.5 f
83289.63共4兲
U
2
CCC13CH CH3 OCH3
83129.18共 4兲 83131.077*共15兲
U
⌸1/2 J⫽15/2⫺13/2 f 10共2,9兲⫺10共1,10兲
SO2
83123.4共3兲
U
2
34
83072.857*共8兲 83085.838*共30兲
U
2
2
83933.681*共22兲 83978.60共10兲
CH3 OD H2 CCC CH3 NH2
4共2,2兲⫺5共1,5兲 A⫺ 4共1,3兲⫺3共1,2兲
0.12 0.083
5共1,5兲⫺5共0,5兲 As F⫽6⫺6
0.05b
Sgr B2共M兲 TMC⫺1 Sgr B2共M兲
83979.57共10兲
CH3 NH2
5共1,5兲⫺5共0,5兲 As F⫽5⫺5
b
Sgr B2共M兲
BTL 7 m
Cum86
Tak73
84108.58*共5兲
C5 H
2
⌸3/2 J⫽35/2⫺33/2 e
4.7fb
IRC⫹10216
IRAM 30 m
Cer86a
Got86
84110.41*共5兲
C5 H
2
CH3 CH2 CN
⌸3/2 J⫽35/2⫺33/2 f 11共0,11兲⫺10共1,10兲
Got86
84151.845*共8兲 84163. 84185.632*共13兲 84215. 84219.750*共6兲 84233.263*共34兲 84320.887*共5兲 84356. 84385. 84410.693*共6兲 84423.706*共21兲 84449.102*共21兲
b
IRC⫹10216
IRAM 30 m
Cer86a
Sgr B2共OH兲
IRAM 30 m
Gom86
2共1,2兲⫺1共0,1兲
0.10b 0.06 0.13
OriMC⫺1 TMC⫺1
NRAO 11 m NRAO 12 m
Tur89 Ger87
2共1,2兲⫺1共0,1兲 A⫹⫹
0.08 0.05
OriMC⫺1 Sgr B2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m BTL 7 m
Tur89 Joh84 Tur89 Tur91 Cum86
Oes99
2共2兲⫺1共1兲
0.06 0.10 0.07 0.08 0.03
13共⫺3,11兲⫺14共⫺2,13兲 E 7共2,6兲⫺6共2,5兲 E
0.80 0.45
OriMC⫺1 OriMC⫺1
OSO 20 m OSO 20 m
Joh84 Joh84
Xu_97 Oes99
unidentified c⫺H13CCCH Unidentified CH3 CHO CH3 OCHO SO2 unidentified unidentified 34 SO CH3 OH CH3 OCHO
Tak73
11共4,7兲⫺11共3,8兲 A 32共5,27兲⫺31共6,26兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Kle96
MICROWAVE TRANSITIONS
209
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U U U
84454.787*共24兲 84468. 84478. 84496. 84505.350*共10兲 84521.206*共14兲 84542.331*共3兲 84549.73*共8兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
CH3 OCHO unidentified unidentified unidentified
7共2,6兲⫺6共2,5兲 A
0.45 0.18 0.18 0.10 0.08
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m
Joh84 Tur89 Tur89 Tur89 Kui77
Oes99
2.8 0.21 0.04
Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216
NRAO 11 m BTL 7 m IRAM 30 m
Zuc72 Cum86 Gue87
Xu_97
JPL01
c⫺C2 H4 O CH3 OH NH2 CHO C6 H
84574.7*共5兲
C6 H
84575.208*共47兲
U
⌸3/2 J⫽61/2⫺59/2 f 2⫺1 v⫽2
0.03
IRC⫹10216
IRAM 30 m
Gue87
0.07
VYCMa
IRAM 30 m
Cer92
4共2,3兲⫺4共1,4兲
29
SiO
JPL01
0.06b
Sgr B2共M兲
BTL 7 m
Cum86
2共1兲⫺2共0兲 Ea F⫽2⫺2
b
Sgr B2共M兲
BTL 7 m
Cum86
Tak73
84598.54共10兲
CH3 NH2
2共1兲⫺2共0兲 Ea F⫽3⫺3
b
Sgr B2共M兲
BTL 7 m
Cum86
Tak73
84608. 84616. 84628. 84631.897*共6兲
unidentified unidentified unidentified CH3 OCH3
0.12 0.10 0.08 3共2,1兲⫺3共1,2兲 AE
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO
m m m m
Tur89 Tur89 Tur89 Cla79
Gro98
84632.275*共6兲
CH3 OCH3
3共2,1兲⫺3共1,2兲 EA
0.14b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
84634.413*共4兲
CH3 OCH3
3共2,1兲⫺3共1,2兲 EE
⬍0.09b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
84636.739*共10兲
CH3 OCH3
3共2,1兲⫺3共1,2兲 AA
b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
84727.691*共4兲
c⫺C3 H2
3共2,2兲⫺3共1,3兲
0.04
Sgr B2共M兲
BTL 7 m
Cum86
84738. 84743.896*共43兲
unidentified CH3 OH
0.02 19共4,15兲⫺18共5,14兲 E
0.46b
Sgr B2共M兲 OriMC⫺1
NRAO 11 m OSO 20 m
Tur89 Joh84
2⫺1 v⫽0
OriMC⫺1
NRAO 11 m
Cla77
4共2,3兲⫺3共2,2兲n,t
0.08b 0.18
Sgr B2共M兲
NRAO 11 m
Wil81
⌸1/2 48.5⫺47.5 e 7⫺6
0.08f 0.032
IRC⫹10216
IRAM 30 m
Gue97
Sgr B2共M兲
BTL 7 m
Gol81
4共3,2兲⫺3共3,1兲n,t
0.08b
30
84807.791*共1兲
SiO NH2 CHO
84819.719*共8兲
C7 H
84865.153*共3兲 84888.986*共1兲
O13CS NH2 CHO
84890.980*共1兲
NH2 CHO
84946.005*共12兲 84970.232*共23兲
CH2 CHCN
85012.850*共12兲
2
13
CH3 OH C7 H
85013.093*共12兲
C7 H
85093.268*共1兲 85131.3*共3兲
NH2 CHO C6 H
85139.104*共1兲 85162.157共44兲
OCS HC18O⫹ C6 H
2
Xu_97
McC97
Sgr B2共M兲
NRAO 11 m
Wil81
b
Sgr B2共M兲
NRAO 11 m
Wil81
0.10 0.20
OriMC⫺1 OriMC⫺1
OSO 20 m OSO 20 m
Joh84 Joh84
Xu_97
2
⌸3/2 47.5⫺46.5 f
0.08bf
IRC⫹10216
IRAM 30 m
Gue97
McC97
2
⌸3/2 47.5⫺46.5 e 4共2,2兲⫺3共2,1兲
b
IRC⫹10216
IRAM 30 m
Gue97
McC97
0.12
⌸1/2 J⫽61/2⫺59/2 e 7⫺6 1⫺0
1.37f 0.7 0.1
Sgr B2共M兲 IRC⫹10216
BTL 7 m IRAM 30 m
Cum86 Cer87a
JPL01
Sgr B2共M兲 L134N
NRAO 11 m BTL 7 m
Sol73 Lan78
Woo81
1.45f 0.030
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
BTL 7 m SEST 15 m
Gol81 Sal94
McC95
85201.347*共4兲
HC5 N
85229.326共16兲
C13CH
1⫺0 3/2⫺1/2 F⫽2,2.5⫺1,1.5
0.10f
IRC⫹10216 OriMC⫺1
2
11 11 11 11
4共3,1兲⫺3共3,0兲n,t 9共0,9兲⫺8共0,8兲 8共0,8兲⫺7共1,7兲 A⫹
⌸1/2 J⫽61/2⫺59/2 f 32⫺31
85175.3*共4兲
85232.792共17兲
C CH
1⫺0 3/2⫺1/2 F⫽2,1.5⫺1,0.5
0.08f
OriMC⫺1
SEST 15 m
Sal94
McC95
85247.798共18兲
C13CH
1⫺0 3/2⫺1/2 F⫽1,0.5⫺0,0.5
0.05f
OriMC⫺1
SEST 15 m
Sal94
McC95
85256.952共29兲
C13CH
1⫺0 3/2⫺1/2 F⫽1,1.5⫺0,0.5
0.07f
OriMC⫺1
SEST 15 m
Sal94
McC95
85265.507*共15兲
t⫺CH3 CH2 OH CH2 CHCN
6共0,6兲⫺5共1,5兲
0.25
Sgr B2共M兲
NRAO 11 m
Zuc75
c⫺C2 H4 O
9共2,8兲⫺8共2,7兲 9共6,4兲⫺9共5,5兲
0.12 0.03
Sgr B2共M兲 OriMC⫺1
BTL 7 m NRAO 11 m
Cum86 Tur89
85302.655*共12兲 85330.991*共12兲
U
⌸3/2 J⫽61/2⫺59/2 e
2
t⫺CH3 CH2 OH CH3 NH2
84746.047*共45兲
U
2
84597.64共10兲
84595.787*共13兲
U U U
8共5,4兲⫺8共4,5兲 5共⫺1,5兲⫺4共0,4兲 E 4共0,4兲⫺3共0,3兲
13
85338.906*共7兲
c⫺C3 H2
2共1,2兲⫺1共0,1兲
3.1
TMC⫺1
NRAO 11 m
Tha81
85347.878*共14兲
HCS⫹
2⫺1
0.4
OriMC⫺1
NRAO 11 m
Tha81
85396. 85416.763*共10兲
unidentified CH2 CHCN
0.05 9共4,6兲⫺8共4,5兲
0.12b
Sgr B2共M兲 OriMC⫺1
NRAO 11 m OSO 20 m
Tur89 Joh84
85416.814*共10兲
CH2 CHCN
9共4,5兲⫺8共4,4兲
b
OriMC⫺1
OSO 20 m
Joh84
85426.933*共10兲 85434.543*共15兲 85442.600*共1兲 85450.765*共1兲
9共3,7兲⫺8共3,6兲 9共3,6兲⫺8共3,5兲 5共3兲⫺4共3兲
0.10 0.03 0.11
OriMC⫺1 Sgr B2共M兲 OriMC⫺1
OSO 20 m NRAO 11 m NRAO 11 m
Joh84 Tur91 Chu83
85455.665*共1兲 85457.299*共1兲 85497.11*共37兲
CH2 CHCN CH2 CHCN CH3 CCH CH3 CCH CH3 CCH CH3 CCH CH3 C4 H
5共2兲⫺4共2兲 5共1兲⫺4共1兲 5共0兲⫺4共0兲 21共1兲⫺20共1兲
0.14 0.23 0.28
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
NRAO NRAO NRAO NRAO
m m m m
Chu83 Chu83 Chu83 Tur89
85497.95*共37兲
CH3 C4 H
21共0兲⫺20共0兲
Sgr B2共M兲
NRAO 11 m
Tur89
85506. 85531.480*共21兲
unidentified
0.10b 0.10 0.5
OriMC⫺1 Sgr B2共M兲
OSO 20 m NRAO 11 m
Joh84 Tha81
NRAO 11 m
Lov76a
Xu_97
NRAO NRAO NRAO NRAO
Gue78 Tur89 Cla81 Tur89
Got83 Oes99
85568.074*共13兲 85634.00*共1兲 85638.349*共17兲 85640.446*共47兲 85655.805*共17兲
HOCO⫹ CH3 OH C4 H CH3 OCHO SiO CH3 OCHO
4共0,4兲⫺3共0,3兲
b
6共⫺2,5兲⫺7共⫺1,7兲 E
0.3
OriMC⫺1
19/2⫺17/2 4共2,3兲⫺3共1,2兲 E 2⫺1 v⫽2 4共2,3兲⫺3共1.2兲 A
0.08 0.09 0.11
IRC⫹10216 OriMC⫺1 RCas OriMC⫺1
0.09b
11 11 11 11
11 11 11 11
m m m m
Gud81
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
210
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 85656.418*共4兲
U
U
85672.57*共1兲 85705. 85715.434*共12兲 85759.144*共45兲 85781. 85886.133*共6兲 85919.086*共28兲
U
U
Quantum numbers
c⫺C3 H2 C4 H unidentified CH2 CHCN
4共3,2兲⫺4共2,3兲
SiO unidentified SiC4
Source
Telescope
Astr. Ref.
OriMC⫺1
NRAO 11 m
Tur89
9共2,7兲⫺8共2,6兲 2⫺1 v⫽0
0.07 0.08 0.06 0.13
IRC⫹10216 OriMC⫺1 Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m
Gue78 Tur89 Cum86 Lov76a
0.08 28⫺27
0.41f
OriMC⫺1 TMC⫺1
NRAO 11 m NRO 45 m
Tur89 Ohi89
7共6,1兲⫺6共6,0兲 E
0.12 0.40
OriMC⫺1 L183
OSO 20 m OSO 20 m
Ell80 Olb85
17/2⫺15/2
29
T r 共K兲/T a 共K兲 b
Lab. Ref. Got83
85924.747共20兲
CH3 OCHO NH2 D
1共1,1兲0⫹⫺1共0,1兲0⫺ F⫽0⫺1
85925.684共20兲
NH2 D
1共1,1兲0⫹⫺1共0,1兲0⫺ F⫽2⫺1
0.40
L183
OSO 20 m
Olb85
Bes83
85926.263共10兲
1共1,1兲0⫹⫺1共0,1兲0⫺
0.14
1共1,1兲0⫹⫺1共0,1兲0⫺ F⫽2⫺2 7共6,2兲⫺6共6,1兲A⫹E
0.99b
OriMC⫺1 L183
NRAO 11 m OSO 20 m
Tur78 Olb85
Bes83 Bes83
0.3b
OriMC⫺1
OSO 20 m
Ell80
Oes99
0.40
L183
OSO 20 m
Olb85
Bes83
OriMC⫺1
OSO 20 m
Ell80
Oes99
0.40
L183
OSO 20 m
Olb85
Bes83
0.04
NRAO 11 m OSO 20 m
Tur89 Joh84
Gro98
Oes99 Bes83
85926.263共10兲
NH2 D NH2 D
85926.508*共21兲
CH3 OCHO
85926.858共20兲
NH2 D
85927.230*共24兲
CH3 OCHO
1共1,1兲0⫹⫺1共0,1兲0⫺ F⫽1⫺2 7共6,1兲⫺6共6,0兲A
85927.721共20兲
NH2 D
1共1,1兲0⫹⫺1共0,1兲0⫺ F⫽1⫺0
85943. 85973.249*共8兲
unidentified CH3 OCH3
13共2,12兲⫺12共3,9兲 AA
b
Sgr B2共M兲 OriMC⫺1
85976.131*共8兲
CH3 OCH3
13共2,12兲⫺12共3,9兲 EE
0.06b
OriMC⫺1
OSO 20 m
Joh84
Gro98
85979.002*共8兲
CH3 OCH3
13共2,12兲⫺12共3,9兲 EA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
85979.025*共8兲
CH3 OCH3
13共2,12兲⫺12共3,9兲 AE
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
86021.008*共25兲
7共5,2兲⫺6共5,1兲 E 7共5,3兲⫺6共5,2兲 E
0.12
86027.674*共21兲
CH3 OCHO CH3 OCHO
OriMC⫺1 OriMC⫺1
OSO 20 m OSO 20 m
Ell80 Ell80
Oes99 Oes99
86029.445*共24兲
CH3 OCHO
7共5,3兲⫺6共5,2兲 A
OSO 20 m
Ell80
Oes99
CH3 OCHO C4 H
7共5,2兲⫺6共5,1兲 A
0.20b 0.32
OriMC⫺1
86030.212*共24兲 86048.50共25兲
OriMC⫺1
OSO 20 m
Ell80
Oes99
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
86054.961共25兲
HC15N CH3 NH2
0.80g
OriMC⫺1
NRAO 11 m
Lin77
86074.20共10兲
4共1,4兲⫺4共0,4兲 F⫽3⫺3
b
Sgr B2共M兲
NRAO 11 m
Kai74
Tak73
86074.44共10兲
CH3 NH2
4共1,4兲⫺4共0,4兲 F⫽5⫺5
0.2b
Sgr B2共M兲
NRAO 11 m
Kai74
Tak73
86075.43共10兲
CH3 NH2
4共1,4兲⫺4共0,4兲 F⫽4⫺4
b
Sgr B2共M兲
NRAO 11 m
Kai74
Tak73
86093.983*共4兲 86104.44共25兲
SO C4 H
2共2兲⫺1共1兲
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Cla74 Gue87a
Gue87a
86181.413*共10兲
CCS
⌺ J⫽9⫺8 v7 ⫽2 U 6,7⫺5,6
⬍1.7 n.r.
IRC⫹10216
IRAM 30 m
Cer87b
Yam90
86210.079*共24兲
CH3 OCHO CH3 OCHO
7共4,4兲⫺6共4,3兲 A 7共4,3兲⫺6共4,2兲 E
0.35b
OriMC⫺1 OriMC⫺1
OSO 20 m OSO 20 m
Joh84 Joh84
Oes99 Oes99
86223.780*共6兲
CH3 OCH3
2共2,0兲⫺2共1,1兲 AE
b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
86224.106*共21兲
CH3 OCHO
7共4,4兲⫺6共4,3兲 E
b
OriMC⫺1
OSO 20 m
Joh84
Oes99
86225.615*共12兲
CH3 OCH3
2共2,0兲⫺2共1,1兲 EA
b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
86226.727*共4兲
CH3 OCH3
2共2,0兲⫺2共1,1兲 EE
0.28b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
86228.720*共10兲
CH3 OCH3
2共2,0兲⫺2共1,1兲 AA
b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
86243.440*共41兲
SiO
2⫺1 v⫽1
86250.576*共24兲 86265.826*共24兲
CH3 OCHO CH3 OCHO
7共4,3兲⫺6共4,2兲 A
86268.659*共21兲 86312.7
CH3 OCHO unidentified
86317. 86338.735*共5兲
unidentified H13CN
1⫺0 F⫽1⫺1
86340.167*共6兲
H13CN
86342.256*共6兲
H13CN unidentified unidentified CH2 DCN
86223.548*共25兲
U
Formula
U U
86395.8共15兲 86416.9共13兲 86458.271*共3兲
U U
86473. 86481. 86492.97*共2兲 86546.18*共1兲 86557.564*共38兲 86562.78*共16兲 86570.249*共8兲 86593.687*共8兲 86615.602*共14兲 86617.924*共22兲
2
2
⌺ J⫽9⫺8 v7 ⫽2 L 1⫺0
Si13CC C7 H CCCO CH3 OH 29
n.r.
1.6f 0.18
OriMC⫺1
NRAO 11 m
Sny74a
Sgr B2共M兲
NRAO 11 m
Tur89
Oes99
0.15 0.20 0.06
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OSO 20 m OSO 20 m SEST 15 m
Joh84 Joh84 Dic01
Oes99 Oes99
0.07 b
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Sny71
1⫺0 F⫽2⫺1
⬍2.b
OriMC⫺1
NRAO 11 m
Sny71
1⫺0 F⫽0⫺1
b
OriMC⫺1
NRAO 11 m
Sny71
0.06 0.05
Sgr B2共M兲 Sgr B2共M兲 G34.3
BTL 7 m BTL 7 m IRAM 30 m
Cum86 Cum86 Ger92a
OriMC⫺1 OriMC⫺1 Sgr B2共OH兲 Sgr B2共M兲 Sgr B2共N兲
NRAO 11 m NRAO 11 m SEST 15 m BTL 7 m NRAO 12 m
Tur91 Tur91 Ger89 Cum86 Tur01
5共1,5兲⫺4共1,4兲
4共0,4兲⫺3共0,3兲 4共1,4兲⫺3共1,3兲 2共1,2兲⫺1共0,1兲
s⫺CH2 CHOH
b
17.4i 0.08
7共3,5兲⫺6共3,4兲 A 7共3,5兲⫺6共3,4兲 E
unidentified unidentified HCOOD HCOOH
b
4共1,4兲⫺3共1,3兲
0.41f 0.10 0.07 0.05 0.07 0.027
Pea76
Wil80 Wil80
n.r.
IRC⫹10216
IRAM 30 m
Gue97
⌸1/2 49.5⫺48.5 f
0.07f
IRC⫹10216
IRAM 30 m
Gue97
McC97
9⫺8 7共2,6兲⫺6共3,3兲 A⫺ 5⫺4
0.028 0.6 0.006
TMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m NRAO 11 m IRAM 30 m
Bro85 Lov76a Gue97
Xu_97
8共3,5兲⫺9共2,8兲
0.2 0.15
OriMC⫺1 OriMC⫺2
NRAO 11 m NRAO 11 m
Tur91 Sny76
Pic78
0.04
Sgr B2共M兲
BTL 7 m
Cum86
Pic78
2.4f
IRC⫹10216
IRAM 30 m
Cer87b
2
86639.095*共2兲
Si34 S SO2
86670.82共4兲
HCO
1共0,1兲⫺0共0,0兲 3/2⫺1/2 F⫽2⫺1
86708.35共4兲
HCO
86708.374*共5兲
CCCS
1共0,1兲⫺0共0,0兲 3/2⫺1/2 F⫽1⫺0 15⫺14
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
211
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 86745.317*共9兲 86754.330共50兲
U
U U
U U U
U
U U
U
Astr. Ref.
Lab. Ref.
0.02 0.6
Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Sny76a
Woo81
1共0,1兲⫺0共0,0兲 1/2⫺1/2 F⫽1⫺1
0.021
DR21
OSO 20 m
Sch86
Pic78
0.015
DR21
OSO 20 m
Sch86
Pic78
0.11f
G34.3
IRAM 30 m
Ger92a
0.50
OriMC⫺1 G34.3
OSO 20 m IRAM 30 m
Joh84 Ger92a
CH3 CH2 CN
8共1,8兲⫺7共0,7兲 1⫺0
86777.43共4兲 86805.75共4兲
HCO
T r 共K兲/T a 共K兲
86814.388*共4兲
CH2 DCN
1共0,1兲⫺0共0,0兲 1/2⫺1/2 F⫽0⫺1 5共4,*兲⫺4共4,*兲
86819.848*共8兲 86824.595*共3兲
CH3 CH2 CN CH2 DCN
10共1,10兲⫺9共1,9兲 5共3,3兲⫺4共3,2兲
86824.597*共4兲
CH2 DCN
5共3,2兲⫺4共3,1兲
b
G34.3
IRAM 30 m
Ger92a
86833.932*共3兲
CH2 DCN
5共0,5兲⫺4共0,4兲
G34.3
IRAM 30 m
Ger92a
86847.010*共45兲 86864. 86902.947*共14兲 86993.51*共20兲 87056.966共20兲
SiO unidentified CH3 OH SiC2
2⫺1 v⫽0 7共2,5兲⫺6共3,4兲 A⫹ 4共1,4兲⫺3共1,3兲 v3 ⫽1
0.24f 1.5 0.08 0.2 0.005
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m OSO 20 m NRAO 11 m NRAO 12 m
Dic76 Dow82 Lov76a Gen97
Xu_97 Bog91
HC17O⫹
1⫺0 F⫽3/2⫺5/2
0.02
L1544
IRAM 30 m
Dor01
Dor01
87057.258共20兲
HC17O⫹
1⫺0 F⫽7/2⫺5/2
0.04
L1544
IRAM 30 m
Dor01
Dor01
87058.294共20兲
HC17O⫹
1⫺0 F⫽5/2⫺5/2
0.02
L1544
IRAM 30 m
Dor01
Dor01
87090.735共46兲
HN13C
1⫺0 F⫽0⫺1
0.08
L134N
BTL 7 m
Fre79a
Fre79a
87090.859共46兲
HN13C
1⫺0 F⫽2⫺1
0.42
L134N
BTL 7 m
Fre79a
Fre79a
87090.942共46兲
HN13C
1⫺0 F⫽1⫺1
0.25
L134N
BTL 7 m
Fre79a
Fre79a
0.04 0.03
OriMC⫺1 Sgr B2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Yam87b
Yam87b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OSO 20 m OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m
Joh84 Joh84 Tur89 Tur89 Got83a
Got83a
1⫺0 3/2⫺1/2 F⫽2⫺1
0.05 0.18 4.00
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Tur89 Got83a
Got83a
1⫺0 3/2⫺1/2 F⫽1⫺0
0.23 2.27
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Got83a
Got83a
⌸3/2 J⫽63/2⫺61/2 f
0.05
IRC⫹10216
IRAM 30 m
Gue87
JPL01
⌸3/2 J⫽19/2⫺17/2 v7 ⫽1 f
IRC⫹10216
IRAM 30 m
Gue87
Yam87b Got83a
0.18bf
87110. 87116. 87142.3共4兲
unidentified unidentified C4 H
87143.198*共28兲 87161.313*共24兲 87215. 87260. 87284.156共30兲
CH3 OCHO CH3 OCHO unidentified unidentified C2 H
87299. 87312.827*共18兲 87316.925共4兲
unidentified CH2 CHCN C2 H
87323. 87328.624共6兲
uniden tified C2 H
87348.02*共8兲
C6 H
87371.8共4兲
C4 H
87402.004共5兲
C2 H
1⫺0 1/2⫺1/2 F⫽1⫺1
2.40f 2.25
OriMC⫺1
NRAO 11 m
Got83a
87407.165共11兲
C2 H
1⫺0 1/2⫺1/2 F⫽0⫺1
1.02
OriMC⫺1
NRAO 11 m
Got83a
Got83a
87446.512共23兲
C2 H
0.56
OriMC⫺1
NRAO 11 m
Tuc78
Got83a
87458.286*共42兲
Al35Cl unidentified unidentified
1⫺0 1/2⫺1/2 F⫽1⫺0 6⫺5
87479. 87525. 87550.556*共17兲
2
⌸3/2 J⫽19/2⫺17/2 v7 ⫽1 e 7共3,4兲⫺6共3,3兲 E 7共3,4兲⫺6共3,3兲 A
1⫺0 3/2⫺1/2 F⫽1⫺1 9共1,8兲⫺8共1,7兲
2 2
5⫺4
30
1.45f 0.37 0.25 0.04 0.05 0.53
0.73f
IRC⫹10216
IRAM 30 m
Cer87c
0.05 0.18 0.027
IRC⫹10216 OriMC⫺1 IRC⫹10216
OSO 20 m NRAO 11 m FCRAO 14m
Joh84 Tur89 Ziu85
Oes99 Oes99
87559.811共11兲
SiS SiN
2⫺1 J⫽5/2⫺3/2 F⫽7/2⫺5/2
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
87567.496共12兲
SiN
2⫺1 J⫽5/2⫺3/2 F⫽5/2⫺3/2
0.006b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
87571.654共12兲
SiN
2⫺1 J⫽5/2⫺3/2 F⫽3/2⫺1/2
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
0.10
Sgr B2共M兲
NRAO 11 m
Tur89
87580.
unidentified t⫺CH3 CH2 OH unidentified CH3 OCHO
4共1,4兲⫺3共1,3兲 5共2,4兲⫺5共1,5兲
0.13 0.06
OriMC⫺1 Sgr B2共M兲
OSO 20 m BTL 7 m
Joh84 Cum86
0.05 8共0,8兲⫺7共1,7兲 E
0.03b
OriMC⫺1 Sgr B2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
HCCN
5,4⫺4,3
0.85f
IRC⫹10216
IRAM 30 m
Gue91
87769.067*共25兲
CH3 OCHO
8共0,8兲⫺7共1,7兲 A
87777. 87779. 87782.23共10兲
unidentified unidentified CH3 NH2
87783.09共10兲
CH3 NH2
87848.871*共1兲 87863.631*共4兲 87876.544*共22兲
NH2 CHO HC5 N
U87726. 87766.301*共25兲 87767.302*共15兲
87890.195*共18兲
HNCO
b
Sgr B2共M兲
BTL 7 m
Cum86
Oes99
0.05 0.08
NRAO 11 m NRAO 11 m BTL 7 m
Tur89 Tur89 Cum86
Tak73 Tak73
3共1,3兲⫺3共0,3兲 As F⫽4⫺4
0.03b
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲
3共1,3兲⫺3共0,3兲 As F⫽3⫺3 4共1,3兲⫺3共1,2兲 33⫺32
b
Sgr B2共M兲
BTL 7 m
Cum86
0.31 0.23
Sgr B2共M兲 IRC⫹10216
BTL 7 m OSO 20 m
Cum86 Joh84
4共5兲⫺4共4兲
0.04
OriMC⫺1
NRAO 11 m
Tur89
4,4⫺3,3
0.72f
IRC⫹10216
IRAM 30 m
Gue91
S18O HCCN
Oes99
87898.416*共4兲
HNCO
4共2,3兲⫺3共2,2兲
0.06b
Sgr B2共M兲
BTL 7 m
Cum86
87898.620*共4兲
HNCO
4共2,2兲⫺3共2,1兲
b
Sgr B2共M兲
BTL 7 m
Cum86
1.19f
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
3.7
NRAO 11 m IRAM 30 m
Tur91 Cer87a
JPL01
IRAM 30 m NRAO 11 m
Cer87a Tur89
Lee80
87922.0*共3兲 87925.238*共4兲 87967.1*共3兲 U
Telescope
Quantum numbers
H13CO⫹ HCO
87597.333*共3兲 87716.024*共13兲
U U
Source
Formula
88018.共1兲 88085.86共5兲
C6 H HNCO C6 H unidentified CH3 SH
2
⌸1/2 J⫽63/2⫺61/2 e 4共0,4兲⫺3共0,3兲
2
⌸1/2 J⫽63/2⫺61/2 f
1.31f
Sgr B2共M兲 IRC⫹10216
14共1兲⫺13共2兲 A⫺
0.10 0.08
IRC⫹10216 OriMC⫺1
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
212
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
88130. 88166.808*共8兲 88204. 88211.347*共21兲 88239.027*共3兲 88285.828*共20兲
U
U U U U U
U U
U
U U U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
10⫺9
0.03 0.15
OriMC⫺1 IRC⫹10216
NRAO 11 m OSO 20 m
Tur89 Joh84
Laf78
0.03
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Gue91
Sgr B2共M兲 IRC⫹10216
NRAO 11 m OSO 20 m
Tur91 Joh84
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Cer86
Cer86 Cer86
unidentified H13CCCN unidentified HCCN
3,4⫺2,3 4共1,3兲⫺3共1,2兲 5⫺4
0.9f 0.09 0.10
2
⌸1/2 J⫽37/2⫺35/2 e
0.8f
2
⌸1/2 J⫽37/2⫺35/2 f 10共0,10兲⫺9共0,9兲
1.1f 0.12 0.03
IRC⫹10216
IRAM 30 m
Cer86
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Joh77 Tur89
22共5,17兲⫺22共4,18兲 A
0.07 0.04 0.03 0.05 0.02 0.73 9.6
OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 G327.3⫺0.6 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m SEST 15 m OSO 20 m NRAO 11 m
Tur89 Tur89 Tur89 Tur91 Dic01 Joh84 Uli76
Xu_97 DeL69
HNCO
88292. 88315.2共4兲
Si34S unidentified C5 H
88321.0共4兲
C5 H
0.03
88323.754*共8兲 88349. 88358.420*共37兲
CH3 CH2 CN unidentified CH3 OCHO
88402. 88445. 88481. 88540.6 88594.809*共19兲 88630.4157共10兲
unidentified unidentified unidentified unidentified CH3 OH HCN
88631.8473共10兲
HCN
1⫺0 F⫽2⫺1
17.2
OriMC⫺1
NRAO 11 m
Uli76
DeL69
88633.9360共10兲
HCN
6.8
OriMC⫺1
NRAO 11 m
Uli76
DeL69
b
Sgr B2共M兲
NRAO 11 m
Kai75
Kai75
15共3,13兲⫺14共4,10兲 A⫹ 1⫺0 F⫽1⫺1
88668.06共10兲
CH3 NH2
1⫺0 F⫽0⫺1 2共0,2兲⫺1共0,1兲 Aa
88668.62共10兲
CH3 NH2
2共0,2兲⫺1共0,1兲 Es
0.15b
Sgr B2共M兲
NRAO 11 m
Kai75
Kai75
88668.63共10兲
2共0,2兲⫺1共0,1兲 A⫹E 2共0,2兲⫺1共0,1兲 As,Ea
0.04
88669.61共10兲
CH3 NH2 CH3 NH2
b
Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Kut80 Kai75
Joh72 Kai75
88706.220*共4兲
CH3 OCH3
15共2,13兲⫺15共1,14兲 EA⫹AE
b
OriMC⫺1
NRAO 11 m
Kut80
Gro98
88707.701*共4兲
CH3 OCH3
15共2,13兲⫺15共1,14兲 EE
OriMC⫺1
NRAO 11 m
Kut80
Gro98
88709.181*共4兲 88720.567*共3兲
CH3 OCH3
15共2,13兲⫺15共1,14兲 AA 7共3,5兲⫺8共2,6兲
0.05b 0.06
NRAO 11 m OSO 20 m
Kut80 Sch83
Gro98
0.10b
OriMC⫺1 OriMC⫺1
Oes99
34
SO2
88723.239*共40兲
CH3 OCHO
88741.8 88749.8 88758.419*共14兲 U88770.8 88843.117*共21兲 88851.641*共24兲 U88861. 88865.692共26兲
unidentified unidentified CH3 CH2 CN unidentified CH3 OCHO CH3 OCHO unidentified
88914.14*共5兲
H15NC C5 H
88916. 88916.19*共5兲
unidentified C5 H
88939.993*共20兲 88940.238*共18兲
CH3 OH H2 CCCC unidentified unidentified unidentified CCCN
88957. 88977. 89043.5 89045.59*共2兲 89060.827*共20兲 89064.36*共2兲
t⫺CH3 CH2 OH CCCN
11共3,9兲⫺11共2,10兲 A
27共3,24兲⫺27共2,25兲 7共1,6兲⫺6共1,5兲 E 7共1,6兲⫺6共1,5兲 A 1⫺0 2
⌸3/2 J⫽37/2⫺35/2 e
⌸3/2 J⫽37/2⫺35/2 f 15共3,12兲⫺14共4,11兲 A⫺ 2
10共1,10兲⫺9共1,9兲
9⫺8 J⫽19/2⫺17/2 18共4,14兲⫺17共5,13兲
4.9fb 0.16
IRC⫹10216
IRAM 30 m
Cer86a
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Cer86a
Got86
1.30
OriMC⫺1
OSO 20 m
Joh84
Xu_97
0.099 0.04 0.09 0.04 0.13l
IRC⫹10216 OriMC⫺1 OriMC⫺1 Sgr B2共N兲 IRC⫹10216
IRAM 30 m NRAO 11 m NRAO 11 m SEST 15 m NRAO 11 m
Cer91a Tur89 Tur89 Dic01 Gue77
Kil90
0.08
OriMC⫺1
NRAO 11 m
Tur89
b
Oes99 Oes99 Say76 Got86
Got83
Gue77
SEST 15 m
Dic01
0.07 b
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Luc88
Mak02
1⫺0 F⫽2⫺1 2vᐉ ⫽0
0.20b
IRC⫹10216
IRAM 30 m
Luc88
Mak02
1⫺0 F⫽0⫺1 2vᐉ ⫽0
b
IRC⫹10216
IRAM 30 m
Luc88
Mak02
0.05 0.07
Sgr B2共N兲 IRC⫹10216
SEST 15 m OSO 20 m
Dic01 Joh84 Tur91
unidentified HCN
1⫺0 F⫽1⫺1 2vᐉ ⫽0
89087.914*共3兲
HCN
89090.130*共3兲
HCN
89093.2 89103.743*共9兲
unidentified
89104.30*共11兲 89188.526*共21兲
HC7 N
79⫺78
HCO⫹
1⫺0
89234. 89251.16共8兲 89275.41共7兲 89297.647*共8兲 89314.589*共25兲
unidentified CH2 DOH CH2 DOH CH3 CH2 CN CH3 OCHO
89316.668*共25兲
CH3 OCHO
U
Kut80 Kut80 Tur89 Kut80 Kut80 Kut80 Gol81b Bro77
NRAO 11 m
89084. 89086.423*共3兲
89407.91共7兲 89411.
Sch83
NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m
Sgr B2共N兲
U
89331.267*共14兲
OSO 20 m
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 DR21共OH兲
IRC⫹10216
unidentified
89329.586*共14兲
OriMC⫺1
0.14l
89082.2
U
b
0.03 0.03 0.08 0.03 0.09 0.07 0.15 0.15
0.05
9⫺8 J⫽17/2⫺15/2
U
U
Oes99
29
SiS
13
CH3 CN
13
CH3 CN
CH2 DOH unidentified
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
5⫺4
OriMC⫺1
NRAO 11 m
OriMC⫺1
NRAO 11 m
Uli76
2共0,2兲⫺1共0,1兲 o1 2共0,2兲⫺1共0,1兲 e1 10共2,9兲⫺9共2,8兲
0.15 0.04 0.06 0.32
OriMC⫺1 IRAS16293⫺2422 IRAS16293⫺2422 OriMC⫺1
NRAO 11 m IRAM 30 m IRAM 30 m OSO 20 m
Tur89 Par02 Par02 Joh84
Qua80 Qua80
8共1,8兲⫺7共1,7兲 E
0.35b
OriMC⫺1
OSO 20 m
Joh84
Oes99
8共1,8兲⫺7共1,7兲 A
b
OriMC⫺1
OSO 20 m
Joh84
Oes99
5共1兲⫺4共1兲
b
Sgr B2共M兲
BTL 7 m
Cum86
5共0兲⫺4共0兲
0.22b 0.06 0.08
Sgr B2共M兲
BTL 7 m
Cum86
IRAS16293⫺2422 OriMC⫺1
IRAM 30 m NRAO 11 m
Par02 Tur89
2共0,2兲⫺1共0,1兲 e0
0.03
Got83
10.8
Qua80
MICROWAVE TRANSITIONS
213
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U U U U U
Astr. Ref.
Lab. Ref.
0.26 0.08
TMC⫺1 Sgr B2共M兲
NRO 45 m FCRAO 14 m
Kaw92 Woo83
Gud82
5⫺4
0.022
IRC⫹10216
IRAM 30 m
Kah88
8共⫺4,5兲⫺9共⫺3,7兲 E 10共9,1兲⫺9共9,0兲
1.5eb
OriMC⫺1 OriMC⫺1共HC兲
NRAO 11 m BIMA Array
Lov76a Liu01
b
OriMC⫺1共HC兲
BIMA Array
Liu01
OriMC⫺1
NRAO 11 m
Joh77
0.05b
OriMC⫺1
NRAO 11 m
Joh77
0.11b
OriMC⫺1
NRAO 11 m
Joh77
0.03b 0.05
OriMC⫺1
NRAO 11 m
Joh77
Sgr B2共M兲 OriMC⫺1
FCRAO 14 m NRAO 11 m
Woo83 Joh77
OriMC⫺1
NRAO 11 m
Joh77
b
OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m
Joh77 Tur89 Joh84 Tur89
Gro98
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
2共2,1兲⫺2共1,2兲 EE
0.06b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
2共2,1兲⫺2共1,2兲 AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
0.07 0.03
IRC⫹10216 IRC⫹10216
OSO 20 m IRAM 30 m
Joh84 Gue98
Gue98
0.06 0.035
OriMC⫺1 Sgr B2共N兲
NRAO 11 m NRAO 12 m
Tur89 Tur01
Oes99
89419.262*共8兲 89487.414共15兲
HCCNC
9⫺8 1⫺0
89489.238*共11兲
Si33S CH3 OH CH3 CH2 CN
89548.911*共6兲
CH3 CH2 CN
10共9,2兲⫺9共9,1兲
89562.318*共7兲
CH3 CH2 CN
10共6兲⫺9共6兲
0.08b
89565.034*共6兲
CH3 CH2 CN
10共7兲⫺9共7兲
89568.100*共7兲
CH3 CH2 CN
10共5兲⫺9共5兲
89573.057*共6兲
CH3 CH2 CN
10共8兲⫺9共8兲
89579.17*共1兲 89590.033*共7兲
HCOOH CH3 CH2 CN
4共0,4兲⫺3共0,3兲 10共4,7兲⫺9共4,6兲
89591.017*共7兲
CH3 CH2 CN
10共4,6兲⫺9共4,5兲
89628.448*共8兲 89651. 89684.715*共8兲 89695.902*共10兲
CH3 CH2 CN unidentified CH3 CH2 CN CH3 OCH3
10共3,8兲⫺9共3,7兲 10共3,7兲⫺9共3,6兲 2共2,1兲⫺2共1,2兲 EA
89697.737*共6兲
CH3 OCH3
2共2,1兲⫺2共1,2兲 AE
89699.797*共6兲
CH3 OCH3
89702.809*共10兲
CH3 OCH3
89726. 89730.54共10兲
unidentified l⫺C3 H
89745.662*共58兲 89757.105*共16兲
CH3 OCHO
HOC⫹
a⫺CH2 CHOH l⫺C3 H
2
⌸1/2 4⫺3 J⫽9/2⫺7/2 v4 ⫽1 ᐉ⫽2 11共1,10兲⫺11共0,11兲 E 2共1,2兲⫺1共0,1兲
0.3
0.05b 0.05b 0.13 0.06 0.22
Xu_97
Wil80
⌸1/2 4⫺3 J⫽7/2⫺5/2 v4 ⫽1 ᐉ⫽2
0.02
IRC⫹10216
IRAM 30 m
Gue98
Gue98
89785.6共4兲
C5 N
2
⌸1/2 N⫽32⫺31 J⫽32.5⫺31.5
0.003
IRC⫹10216
IRAM 30 m
Gue98
Gue98
89797.0共3兲
C5 N
2
⌸1/2 N⫽32⫺31 J⫽31.5⫺30.5
0.003
IRC⫹10216
IRAM 30 m
Gue98
Gue98
4共2,3兲⫺3共2,2兲
0.03 0.11 0.13 0.05 0.07
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1共CR兲
NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m BIMAArray
Tur89 Tur89 Cum86 Tur89 Tur89 Liu01
Lee80 Wil80
OriMC⫺1 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216
NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Joh84 Tur89 Tur89 Tur89 Gue87
JPL01
0.25g
Sgr B2共M兲
NRAO 11 m
Zuc75
0.06
IRC⫹10216
IRAM 30 m
Gue87
JPL01
0.32 0.25
OriMC⫺1 OriMC⫺1 OriMC⫺1共CR兲
OSO 20 m OSO 20 m BIMA Array
Joh84 Joh84 Liu01
Oes99 Oes99 Wil80
Rem02
89759.17共12兲
U U
Telescope
Quantum numbers
89505.778*共17兲 89548.911*共6兲
U
Source
T r 共K兲/T a 共K兲
Formula
89823. 89834. 89861.48*共1兲 89898. 89927.70共10兲 89948.21*共1兲
unidentified unidentified HCOOH unidentified CH3 SH HCOOH
89952. 89960. 90038. 90051. 90061. 90093.34*共9兲
unidentified unidentified unidentified unidentified unidentified C6 H
90117.593*共13兲 90121.43*共9兲
t⫺CH3 CH2 OH C6 H
2
17共1兲⫺16共2兲 A⫹ 4共3,2兲⫺3共3,1兲
2
2
⌸3/2 J⫽65/2⫺63/2 e 4共1,4兲⫺3共0,3兲 ⌸3/2 J⫽65/2⫺63/2 f 7共2,5兲⫺6共2,4兲 E 7共2,5兲⫺6共2,4兲 A
0.02e 0.02 0.20 0.04 0.02 0.02 0.05
Wil80
90145.634*共24兲 90156.511*共25兲 90164.62*共1兲
CH3 OCHO CH3 OCHO HCOOH
U
90166.
unidentified
0.29e
W51 e2
BIMA Array
U
90199.6
unidentified
0.3e
Sgr B2共N兲
BIMA Array
Meh97
U
90203.
unidentified
0.20e
W51 e2
BIMA Array
Rem02
90203.444*共20兲
CH3 COOH
8共⫺1,8兲⫺7共⫺1,7兲 E
b
Sgr B2共N兲
BIMA Array
Meh97
Ily00
90203.444*共20兲
CH3 COOH
8共⫺1,8兲⫺7共0,7兲 E
b
Sgr B2共N兲
BIMA Array
Meh97
Ily00
90203.444*共20兲 90203.444*共20兲
CH3 COOH CH3 COOH
8共0,8兲⫺7共⫺1,7兲 E
0.6be
Sgr B2共N兲
BIMA Array
Meh97
Ily00
8共0,8兲⫺7共0,7兲 E
b
Sgr B2共N兲
BIMA Array
Meh97
Ily00
90212.共1兲 90227.595*共25兲 90229.647*共28兲
unidentified CH3 OCHO
8共0,8兲⫺7共0,7兲 E
0.04 0.15
Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Hol80 Hol80
Oes99
CH3 OCHO
8共0,8兲⫺7共0,7兲 A
0.15
OriMC⫺1
NRAO 11 m
Hol80
Oes99
90240.
unidentified
0.08e
W51 e2
BIMA Array
Rem02
90246.250*共50兲
CH3 COOH
8共0,8兲⫺7共0,7兲 A⫹⫹
b
Sgr B2共N兲
BIMA Array
Meh97
Ily00
90246.250*共50兲 90246.250*共50兲
CH3 COOH CH3 COOH
8共0,8兲⫺7共1,7兲 A⫹⫹
0.21be
Sgr B2共N兲
BIMA Array
Meh97
Ily00
8共1,8兲⫺7共0,7兲 A⫹⫹
b
Sgr B2共N兲
BIMA Array
Meh97
Ily00
90246.250*共50兲
CH3 COOH
8共1,8兲⫺7共1,7兲 A⫹⫹
b
Sgr B2共N兲
BIMA Array
Meh97
Ily00
90251.
unidentified
0.06e
W51 e2
BIMA Array
Rem02
90254.
unidentified
0.06e 0.035
W51 e2
BIMA Array
Rem02
1⫺0
DR21共OH兲
BTL 7 m
Lin83
Gud82a
21共1,20兲⫺21共2,10兲 vt ⫽1⫺0
0.08
OriMC⫺1
NRO 45 m
Tur89
Pea97
10共2,8兲⫺9共2,7兲 7共4,4兲⫺8共3,5兲
0.35 0.02 0.12
OriMC⫺1 Sgr B2共OH兲 Sgr B2共M兲
OSO 20 m IRAM 30 m NRAO 11 m
Joh84 Gom86 Tur89
U
U
U U
90263.833共30兲 90354.336共50兲
U
90453.354*共8兲 90482.482*共12兲 90506.
15
NNH⫹
g⫺CH3 CH2 OH CH3 CH2 CN CH3 CH2 CN unidentified
4共2,2兲⫺3共2,1兲
0.05e
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
214
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U
U U
U U U U U U U U U
U
U U U
U U
U U U U U U U U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
90515.644*共12兲 90525.891*共4兲 90530.939*共11兲 90548.160*共3兲 90562.18*共26兲
CH3 CH2 CN HC5 N CH3 CH2 CN SO2
7共4,3兲⫺8共3,6兲 34⫺33 23共3,20兲⫺23共2,21兲 25共3,23兲⫺24共4,20兲
0.02 0.20 0.015 0.6
Sgr B2共OH兲 IRC⫹10216 OriMC⫺1 OriMC⫺1
IRAM 30 m OSO 20 m FCRAO 14 m OSO 20 m
Gom86 Joh84 Ziu88 Sch83
4共0,4兲⫺3共0,3兲
0.06
IRC⫹10216
IRAM 30 m
Cer86b
90593.059*共11兲
HC13CCN
10⫺9
0.35
Sgr B2共M兲
NRAO 11 m
Uli78
Laf78
90601.791*共5兲
HCC13CN
10⫺9
0.18
Sgr B2共M兲
NRAO 11 m
Uli78
Laf78
90609. 90619. 90635. 90663.450共10兲
unidentified unidentified unidentified HNC
0.015 0.008 0.015 n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 L134N
FCRAO 14 m FCRAO 14 m FCRAO 14 m BTL 7 m
Ziu88 Ziu88 Ziu88 Fre79a
Fre79a
90663.572*共4兲 90663.574共10兲
HNC HNC
L134 L134N
NRAO 11 m BTL 7 m
Sny77a Fre79a
Pea76 Fre79a
90663.656共10兲
HNC
90686.383*共8兲 90689. 90700. 90703.78共5兲
CCS unidentified unidentified CH3 OD
2共⫺1,2兲⫺1共⫺1,1兲 E
90705.77共5兲
CH3 OD
2共0,2兲⫺1共0,1兲 A⫹
90712.5*共3兲
C6 H
90727. 90729. 90743.56共5兲 90757. 90758.9*共3兲
unidentified unidentified CH3 OD unidentified C6 H
90760. 90771.553*共7兲 90809. 90812.39*共23兲 90814. 90820. 90820. 90838. 90841.134*共32兲
unidentified SiS unidentified CH3 OH unidentified unidentified unidentified unidentified 共CH3 兲2 CO
12共2,10兲⫺12共1,11兲 AE
b
90841.141*共32兲
共CH3 兲2 CO
12共3,10兲⫺12共2,11兲 AE
90841.223*共25兲
共CH3 兲2 CO
90841.230*共25兲
共CH3 兲2 CO
90864. 90889.253*共10兲
unidentified CH3 OCH3
15共3,12兲⫺14共4,11兲 AA
90892.254*共8兲
CH3 OCH3
15共3,12兲⫺14共4,11兲 EE
90895.183*共8兲
CH3 OCH3
90895.326*共8兲
CH3 OCH3
90908.共3兲 90912.
unidentified unidentified
90926.036*共20兲 90928.共1兲 90937.505*共4兲
13 34 C S unidentified CH3 OCH3
6共0,6兲⫺5共1,5兲 AA
90938.103*共4兲
CH3 OCH3
6共0,6兲⫺5共1,5兲 EE
90938.700*共4兲
CH3 OCH3
6共0,6兲⫺5共1,5兲 AE⫹EA
90949. 90964. 90978.989*共3兲 90987.005*共59兲 91000. 91007.729*共24兲
unidentified unidentified HCCCN HCCCN unidentified
91022. 91038.307*共61兲 91045. 91063. 91074. 91086. 91096. 91128.19*共3兲 91135. 91169.920*共53兲 91175.217*共14兲 91199.796*共32兲 91202.607*共27兲
30
SiC2
t⫺CH3 CH2 OH unidentified HCCCN unidentified unidentified unidentified unidentified unidentified HCCCN unidentified Na35Cl CH3 OCH3 HCCCN HCCCN
1⫺0 F⫽0⫺1 1⫺0 1⫺0 F⫽2⫺1
1.6 n.r.
L134N
BTL 7 m
Fre79a
Fre79a
0.14b
Sgr B2共M兲 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
NRAO 11 m FCRAO 14 m FCRAO 14 m NRAO 11 m
Sch85 Ziu88 Ziu88 Got79
Lov78
b
Sgr B2共M兲
NRAO 11 m
Got79
Lov78
1.09f
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
0.13 0.01 0.09 0.10
Sgr B2共M兲 W51 Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216
NRAO 11 m NRAO 12 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Ziu91a Tur91 Tur89 Cer87a
Kau80
Sgr B2共M兲 IRC⫹10216 OriMC⫺1 W51 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 Sgr B2
NRAO 12 m NRAO 11 m FCRAO 14 m NRAO 12 m FCRAO 14 m FCRAO 14 m NRAO 12 m FCRAO 14 m NRAO 11 m
Ziu91a Mor75 Ziu88 Ziu91a Ziu88 Ziu88 Ziu91a Ziu88 Cla79
Vac86
0.08b
Sgr B2
NRAO 11 m
Cla79
Vac86
12共2,10兲⫺12共1,11兲 EA
b
Sgr B2
NRAO 11 m
Cla79
Vac86
12共3,10兲⫺12共2,11兲 EA
b
Sgr B2
NRAO 11 m
Cla79
Vac86
b
Sgr B2共M兲 OriMC⫺1
NRAO 11 m FCRAO 14 m
Tur91 Ziu88
Gro98
0.04b
OriMC⫺1
FCRAO 14 m
Ziu88
Gro98
15共3,12兲⫺14共4,11兲 AE
b
OriMC⫺1
FCRAO 14 m
Ziu88
Gro98
15共3,12兲⫺14共4,11兲 EA
b
OriMC⫺1
FCRAO 14 m
Ziu88
Gro98
0.05 0.05 0.10
Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m
Cla79 Tur89 Tur89
0.07 b
Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Cla79 Sny74
Gro98
0.17b
OriMC⫺1
NRAO 11 m
Sny74
Gro98
b
OriMC⫺1
NRAO 11 m
Sny74
Gro98
14共2,13兲⫺13共3,10兲
0.01 0.04 1.77 0.43 0.01 0.015
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲 OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m NRAO 11 m IRAM 30 m FCRAO 14 m FCRAO 14 m
Ziu88 Ziu88 Mor76 Vic00 Ziu88 Ziu88
10⫺9 v5 ⫽1 ᐉ⫽1 f
0.008 0.32
OriMC⫺1 Sgr B2共N兲
FCRAO 14 m IRAM 30 m
Ziu88 Vic00
0.10 0.09 0.02 0.06 0.10 0.10h 0.10
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur91 Cer87c
OriMC⫺1 Sgr B2共N兲 OriMC⫺1
NRAO 11 m IRAM 30 m NRAO 11 m
Tur89 Vic00 Cla76
1⫺0 F⫽1⫺1 7,7⫺6,6
⌸1/2 J⫽65/2⫺63/2 e
2
2共1,1兲⫺1共1,0兲E 2
⌸1/2 J⫽65/2⫺63/2 f 5⫺4
20共⫺3,17兲⫺19共⫺2,17兲 E
n.r.
Lab. Ref.
0.2 0.025 0.010
1.21f 0.02 0.35 0.010 0.02 0.030 0.008 0.03 0.015
0.18
2⫺1
10⫺9 10⫺9 v5 ⫽1 ᐉ⫽1 e
10⫺9 v6 ⫽1 ᐉ⫽1 e 7⫺6 5共4,2兲⫺6共3,3兲 EE 10⫺9 v6 ⫽1 ᐉ⫽1 f 10⫺9 v7 ⫽ᐉ ᐉ⫽1 e
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
1.91f 0.04 0.49 0.2
JPL01
Laf78
Laf78
Laf78
Gro98 Laf78 Laf78
MICROWAVE TRANSITIONS
215
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U U
U U U
U
Telescope
Astr. Ref.
Lab. Ref.
N15NH⫹
1⫺0 F⫽1⫺1
0.02
DR21共OH兲
BTL 7 m
Lin83
Gud82a
1⫺0 F⫽2⫺1
0.025
DR21共OH兲
BTL 7 m
Lin83
Gud82a
91208.663共70兲
1⫺0 F⫽0⫺1 10⫺9 v7 ⫽1 ᐉ⫽1 f 9共4,5兲⫺9共3,6兲 E 3共2,2兲⫺3共1,3兲 EA
0.01
DR21共OH兲
BTL 7 m
Lin83
Gud82a
91333.308*共27兲 91366.593*共59兲 91473.760*共6兲
N15NH⫹ HCCCN CH3 OCHO CH3 OCH3
0.2 0.08 0.4b
OriMC⫺1 Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m NRO 45 m
Cla76 Tur89 Ohi95
Laf78 Oes99 Gro98
91474.139*共6兲
CH3 OCH3
3共2,2兲⫺3共1,3兲 AE
b
OriMC⫺1
NRO 45 m
Ohi95
Gro98
91476.596*共6兲 91479.244*共10兲 91485.095*共13兲
CH3 OCH3 CH3 OCH3
3共2,2兲⫺3共1,3兲 EE 3共2,2兲⫺3共1,3兲 AA
⬎0.5 0.4
OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m
Ohi95 Ohi95
Gro98 Gro98
t⫺CH3 CH2 OH
6共2,5兲⫺6共1,6兲
0.07
Sgr B2共M兲
NRAO 11 m
Tur89
91494.349共30兲
c⫺C3 H
2共1,2兲⫺1共1,1兲 5/2,3⫺3/2,2
0.19
TMC⫺1
NRO 45 m
Yam87a
Yam87a
91497.608共30兲
c⫺C3 H
2共1,2兲⫺1共1,1兲 5/2,2⫺3/2,1
0.13
TMC⫺1
NRO 45 m
Yam87a
Yam87a
91520. 91541. 91549.117*共8兲
unidentified unidentified CH3 CH2 CN
0.02 0.03 10共1,9兲⫺9共1,8兲
0.36b
Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Tur89 Tur89
91550.442*共2兲
SO2
18共5,13兲⫺19共4,16兲
b
OriMC⫺1
NRAO 11 m
Tur89
91554.521*共43兲
HCCCN
10⫺9 v7 ⫽2 ᐉ⫽0
b
OriMC⫺1
NRAO 11 m
Tur89
Laf78
91555.932*共49兲
HCCCN
10⫺9 v7 ⫽2 ᐉ⫽2 e
b
OriMC⫺1
NRAO 11 m
Tur89
Laf78
91558.432*共44兲
HCCCN
10⫺9 v7 ⫽2 ᐉ⫽2 f
b
OriMC⫺1
NRAO 11 m
Tur89
Laf78
91572.549*共14兲 91586.97共5兲
HCCCHO CH2 DOH
10共1,10兲⫺9共1,9兲 4共1,3兲⫺4共0,4兲
0.02
NRAO 11 m IRAM 30 m
Tur91 Jac93
Jac93
91603. 91605. 91609.12*共18兲
unidentified unidentified 4共2,3兲⫺3共2,2兲
1.0f 0.16 0.03 0.06
Sgr B2共M兲 OriMC⫺1 SgrB2共N⫺LMH兲 OriMC⫺1 IRC⫹10216
NRAO 12 m NRAO 11 m IRAM 30 m
Sny02 Tur89 Cer86b
91610.027*共18兲
共CH3 兲2 CO
8共1,7兲⫺7共2,6兲 AE
0.05b
SgrB2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
91610.153*共16兲
共CH3 兲2 CO
8共1,7兲⫺7共2,6兲 EA
b
SgrB2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
91612.792*共18兲
共CH3 兲2 CO
8共2,7兲⫺7共1,6兲 AE
b
SgrB2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
91612.866*共16兲
共CH3 兲2 CO
8共2,7兲⫺7共1,6兲 EA
b
SgrB2共N⫺LMH兲
NRAO 12 m
Sny02
Gro02
91634.636*共14兲
共CH3 兲2 CO 共CH3 兲2 CO unidentified 共CH3 兲2 CO unidentified 共CH3 兲2 CO unidentified
8共1,7兲⫺7共2,6兲 EE 8共2,7兲⫺7共1,6兲 EE
SgrB2共N⫺LMH兲 SgrB2共N⫺LMH兲 Sgr B2共M兲 SgrB2共N⫺LMH兲 IRC⫹10216 SgrB2共N⫺LMH兲 OriMC⫺1 TMC⫺1
NRAO 12 m NRAO 12 m NRAO 11 m NRAO 12 m IRAM 30 m NRAO 12 m NRAO 11 m NRO 45 m
Sny02 Sny02 Tur89 Sny02 Ziu95 Sny02 Tur89 Yam87a
Gro02 Gro02
Yam87a Yam87a
30
SiC2
91637.465*共14兲 91654. 91659.108*共20兲 91660. 91662.028*共20兲 91665. 91692.752共30兲
91703. 91709.980*共55兲 91711. 91737.258*共50兲
U U
Source
N15NH⫹
U
U
T r 共K兲/T a 共K兲
91204.328共30兲
91697. 91699.471共30兲
U
Quantum numbers
91205.999共30兲
U
U
Formula
91750. 91771.65*共22兲
c⫺C3 H unidentified
2共1,2兲⫺1共1,1兲 3/2,1⫺1/2,0
0.07 0.06 0.02 0.14 0.01 0.18 0.08 0.10
c⫺C3 H unidentified HCCCN unidentified
2共1,2兲⫺1共1,1兲 3/2,2⫺1/2,1
0.05 0.16
SgrB2共N⫺LMH兲 TMC⫺1
NRAO 12 m NRO 45 m
Sny02 Yam87a
g⫺CH3 CH2 OH unidentified
11共0,11兲⫺11共1,11兲 t⫽1⫺0
0.02 0.23 0.08 0.07
OriMC⫺1 Sgr B2共N兲 SgrB2共N⫺LMH兲 SgrB2共N⫺LMH兲
NRAO 11 m IRAM 30 m NRAO 12 m NRAO 12 m
Tur89 Vic00 Sny02 Sny02
SgrB2共N⫺LMH兲 IRC⫹10216
NRAO 12 m IRAM 30 m
Sny02 Cer86b
8共1,7兲⫺7共2,6兲 AA 8共2,7兲⫺7共1,6兲 AA
10⫺9 v7 ⫽3 ᐉ⫽1 e
Gro02 Gro02
Laf78 Pea97
4共0,4兲⫺3共0,3兲
0.14 0.08
91775.884*共25兲
CH3 OCHO
8共1,8兲⫺7共0,7兲 E
0.07b
SgrB2共N⫺LMH兲
NRAO 12 m
Sny02
Oes99
91777.248*共29兲
CH3 OCHO
8共1,8兲⫺7共0,7兲 A
b
SgrB2共N⫺LMH兲
NRAO 12 m
Sny02
Oes99
91808. 91844.796*共17兲 91848. 91913. 91925.708*共5兲
unidentified SiC3 unidentified unidentified CH3 13CN
5共3兲⫺4共3兲
0.05 0.007 0.15 0.06 0.03
OriMC⫺1 IRC⫹10216 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 12 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 App99 Tur91 Tur89 Cer88
91934.536*共4兲
CH3 13CN
5共2兲⫺4共2兲
b
Sgr B2共M兲
IRAM 30 m
Cer88
91939.834*共4兲
CH3 13CN
5共1兲⫺4共1兲
b
Sgr B2共M兲
IRAM 30 m
Cer88
91941.600*共5兲
5共0兲⫺4共0兲
0.15b
Sgr B2共M兲
IRAM 30 m
Cer88
91959.024*共2兲
CH3 13CN CH3 CN
5共4兲⫺4共4兲 F⫽6⫺5
0.08b
OriMC⫺1
NRAO 11 m
Lov76a
Bou80
91959.359*共2兲
CH3 CN
5共4兲⫺4共4兲 F⫽4⫺3
b
OriMC⫺1
NRAO 11 m
Lov76a
Bou80
91971.310*共1兲
CH3 CN
5共3兲⫺4共3兲 F⫽6⫺5
0.20b
OriMC⫺1
NRAO 11 m
Lov76a
Bou80
91971.465*共1兲
CH3 CN
5共3兲⫺4共3兲 F⫽4⫺3
b
OriMC⫺1
NRAO 11 m
Lov76a
Bou80
91980.089*共1兲
CH3 CN
0.16
OriMC⫺1
NRAO 11 m
Lov76a
Bou80
91985.316*共1兲
CH3 CN
5共2兲⫺4共2兲 F⫽6⫺5 5共1兲⫺4共1兲
0.28b
OriMC⫺1
NRAO 11 m
Lov76a
b
OriMC⫺1
NRAO 11 m
Lov76a
NRAO 11 m IRAM 30 m
Tur89 Gue95
Gue95
29
SiC2
8共0,8兲⫺7共0,7兲
91987.089*共1兲
CH3 CN
5共0兲⫺4共0兲
92000.901*共12兲 92019.8共5兲
CH3 CH2 CN SiC4
13共2,12兲⫺13共1,13兲 30⫺29
0.40f
Sgr B2 IRC⫹10216
0.10
92023.7共
兲
26
MgNC
15/2,8⫺13/2,7
0.50f
IRC⫹10216
IRAM 30 m
Gue95
Gue95
92038.4共
兲
26
MgNC
17/2,8⫺15/2,7
0.44f
IRC⫹10216
IRAM 30 m
Gue95
Gue95
0.50f
IRC⫹10216
IRAM 30 m
Gue95
92044.3共5兲
unidentified
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
216
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
Si13CC CH3 OD CH3 CN
2共1,1兲⫺1共1,0兲 A⫺ 5共0兲⫺4共0兲 v8 ⫽1 ᐉ⫽1
92263.992共60兲
CH3 CN
5共2兲⫺4共2兲 v8 ⫽1 ᐉ⫽1
92334. 92342. 92353.516共60兲 92426.260*共18兲 92488.488*共5兲
unidentified unidentified CH3 CN CH2 CHCN CCCS
92064.63*共6兲 92075.51共5兲 92261.440共60兲
U U
92494.303*共19兲 U
92715. 92794.24*共34兲
U
SiC2 C6 H
92894.88*共9兲
C6 H
U
U
NRAO 11 m
Tur91
Bou80
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Tur91 Tur89 Cer87b
Bou80
Tur73
2.2f 0.215
NRAO 11 m
Tur89
4共2,2兲⫺3共2,1兲
0.03
IRC⫹10216
IRAM 30 m
Cer86b
⌸3/2 J⫽67/2⫺65/2 e
0.05
IRC⫹10216
IRAM 30 m
Gue87
4共2,3兲⫺3共2,2兲
0.03 0.06
Sgr B2共M兲 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Cer86b
⌸3/2 J⫽67/2⫺65/2 f
0.06
IRC⫹10216
IRAM 30 m
Gue87
9共1,9兲 v⫽1⫺8共1,8兲 v⫽0 3共0,3兲⫺2共0,2兲 9共0,7兲⫺8共1,8兲 30共3,27兲⫺30共2,28兲 4共0,4兲⫺3共0,3兲
0.10 0.038 0.071 0.040 0.07 0.11 1.3f
Sgr B2共M兲 SgrB2共N⫺LMH兲 TMC⫺1 Sgr B2共N兲 Sgr B2共N兲 IRC⫹10216 IRC⫹10216
NRAO 11 m NRAO 12 m NRO 45 m NRAO 12 m NRAO 12 m NRAO 11 m IRAM 30 m
Tur89 Hol02 Min97 Hol00 Hol00 Sny83 Cer86
1.5f
IRC⫹10216
IRAM 30 m
Cer86
Cer86
Sgr B2共M兲 IRC⫹10216 IRC⫹10216 L134N
NRAO NRAO NRAO NRAO
m m m m
Tur89 App99 Tur94 Cas95
Wil80
Cas95
2
2
⌸1/2 J⫽39/2⫺37/2 e
2
⌸1/2 J⫽39/2⫺37/2 f
HCOOH SiC3 unidentified
4共1,3兲⫺3共1,2兲 8共2,7兲⫺7共2,6兲
JPL01 Hol02 But01 Got89 Cer86
0.7
L134N
NRAO 11 m
Cas95
Cas95
93172.053共7兲
N 2 H⫹
1⫺0 F 1 ⫽1⫺1 F⫽1⫺0
0.8
L134N
NRAO 11 m
Cas95
Cas95
93173.480共7兲
N 2 H⫹
1⫺0 F 1 ⫽2⫺1 F⫽2⫺1
0.9
L134N
NRAO 11 m
Cas95
Cas95
93173.777共7兲
N 2 H⫹
1⫺0 F 1 ⫽2⫺1 F⫽3⫺2
0.9
L134N
NRAO 11 m
Cas95
Cas95
93173.967共7兲
N 2 H⫹
1⫺0 F 1 ⫽2⫺1 F⫽1⫺1
0.6
L134N
NRAO 11 m
Cas95
Cas95
93176.265共7兲
N 2 H⫹ HC5 N CH3 OH NaCN
1⫺0 F 1 ⫽0⫺1 F⫽1⫺2
0.7
L134N
NRAO 11 m
Cas95
Cas95
NRAO NRAO NRAO NRAO
m m m m
Lov82 Lov82 Tur94 Tur89
Xu_97 Tur94
t⫺CH3 CH2 OH
35⫺34 1共0,1兲⫺2共1,2兲 E vt ⫽1 6共0,6兲⫺5共0,5兲 16共8,9兲⫺17共7,10兲
0.09 0.18 0.011
16共8,8兲⫺17共7,11兲
0.06b 0.01 0.07 0.06 0.006
b
NRAO 11 m
Tur89
NRAO NRAO NRAO NRAO
m m m m
Tur89 Tur89 Tur89 Tur94
Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 12 m
Tur89 Tur89 App99
IRC⫹10216
NRAO 12 m
App99
0.004b
TMC⫺1 IRC⫹10216
IRAM 30 m NRAO 12 m
Ger92 App99
93355. 93361. 93421.32*共19兲
unidentified unidentified SiC3
8共6,2兲⫺7共6,1兲
b
93421.32*共19兲
SiC3
8共6,3兲⫺7共6,2兲
0.002b 0.06
93454.2
0.1 0.10
unidentified 8共4,5兲⫺7共4,4兲
OriMC⫺1
11 11 12 11
Sgr B2 OriMC⫺1 OriMC⫺1 IRC⫹10216
93230.603*共14兲 93261.760*共77兲 93294. 93327.1
t⫺CH3 CH2 OH HCCCHO CH3 OCHO unidentified unidentified
10共2,9兲⫺9共2,8兲 14共2,12兲⫺14共1,13兲 A
OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1
11 12 12 11
JPL01
1⫺0 F 1 ⫽1⫺1 F⫽2⫺2
11 11 11 12
Oes99
93484.063*共37兲
SiC3
93484.939*共37兲
SiC3
b
IRC⫹10216
NRAO 12 m
App99
93503.0*共3兲
C6 H
2
⌸1/2 J⫽67/2⫺65/2 e
0.90f
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
93550.5*共3兲
C6 H
2
⌸1/2 J⫽67/2⫺65/2 f
1.20f
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
5共1,5兲⫺4共1,4兲 A⫹⫹
0.04 0.17
OriMC⫺1 Sgr B2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
Kle96
1.80f 0.17
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
Sgr B2共M兲 OriMC⫺1
BTL 7 m NRAO 11 m
Cum86 Tur89
Kle96 Xu_97
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Hol80 Gue95
Oes99 Gro98 Gue95
NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Tur89 Tur89
93561. 93580.914*共6兲 93586.5共3兲
93656.
93692.448*共2兲 93730. 93812.514*共21兲 93813.062*共21兲
U
OriMC⫺1
1⫺0 F 1 ⫽1⫺1 F⫽0⫺1
93660.027*共28兲 93666.459*共6兲 93679.5共10兲 U
b
0.03 0.02 0.04 0.05
N 2 H⫹
93595.238*共6兲 93619.431*共4兲 U
Kau80 Bou80
N 2 H⫹
93213.003*共34兲
U
Tur89 Tur91
93171.917共7兲
93196.657*共12兲 93206.081*共23兲 93212.885*共34兲
U U
0.04b
0.12 0.005 0.006 0.5
93188.126*共4兲
U U
Cer91b
NRAO 11 m NRAO 11 m
NRAO 11 m
SiC2
C5 H
IRAM 30 m
OriMC⫺1 OriMC⫺1
OriMC⫺1
29
93094.9共4兲
IRC⫹10216
0.4f 0.07
Lab. Ref.
OriMC⫺1
2
unidentified HOCH2 CH2 OH HDCS CH2 OHCHO CH3 CH2 CN SiC2 C5 H
Astr. Ref.
Source
0.03
30
unidentified
93098.35*共1兲 93125.626*共14兲 93126.1 93171.621共7兲
2⫺1
CS unidentified
92877. 92882.18*共20兲
92916. 92975.9共20兲 92981.593*共5兲 93052.672*共10兲 93059.801*共16兲 93063.639共9兲 93089.0共3兲
5共1兲⫺4共1兲 v8 ⫽1 ᐉ⫽1 10共1,10兲⫺9共1,9兲 16⫺15
13
92865.12*共9兲 U
4共2,3兲⫺3共2,2兲
Telescope
T r 共K兲/T a 共K兲
93830.050共20兲 93839.
unidentified CH3 CHO C4 H CH3 CHO 13
CH3 OH
unidentified CH3 OCHO CH3 OCH3 25
MgNC
8共4,4兲⫺7共4,3兲
2
⌸1/2 J⫽19/2⫺17/2 v7 ⫽1 e 5共⫺1,5兲⫺4共⫺1,4兲 E 2共1,2兲⫺1共1,1兲 A⫹ 8共4,4兲⫺8共3,5兲 A 12共1,11兲⫺12共0,12兲 EE 8⫺7
0.12b 0.07 0.09 0.10 0.75f
HNCS unidentified
8共1,8兲⫺7共1,7兲
0.03 0.03
t⫺CH3 CH2 OH
13共7,7兲⫺14共6,8兲
0.03b
OriMC⫺1 Sgr B2共M兲 OriMC⫺1
t⫺CH3 CH2 OH HNCS unidentified
13共7,6兲⫺14共6,9兲
b
OriMC⫺1
NRAO 11 m
Tur89
0.05 0.02
OriMC⫺1 OriMC⫺1
BTL 7 m NRAO 11 m
Fre79 Tur89
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
8共0,8兲⫺7共0,7兲
Yam79
MICROWAVE TRANSITIONS
217
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
93844.共2兲 93854.437*共6兲 93854.560*共6兲 93857.103*共4兲 93859.708*共10兲 93863.3共10兲
U
Cla79 Yam87b
Gro98 Yam87b
4共2,3兲⫺4共1,4兲 AA
0.03
⌸1/2 J⫽19/2⫺17/2 v7 ⫽1 f
2.4bf
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Sgr B2共M兲
NRAO 11 m
Cla79
b
Sgr B2共M兲
NRAO 11 m
Tur91
93979.78共10兲 93995.203*共3兲 94056.44*共2兲
PN HNCS SiCN
2⫺1 8共1,7兲⫺7共1,6兲
0.023 0.01
OriMC⫺1 Sgr B2共M兲 IRC⫹10216
NRAO 12 m NRAO 11 m IRAM 30 m
Tur87b Tur89 Gue00
94064.686*共2兲
SO2
OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Gue00
IRC⫹10216
IRAM 30 m
Cer86b
94175. 94195. 94200. 94237.
unidentified SiCN 29
SiC2 unidentified unidentified unidentified unidentified SiC2 NH2 CHO CH2 CHCN CH2 CHCN
2
2
0.16f
23共6,18兲⫺24共5,19兲
0.13 0.03
⌸1/2 J⫽17/2⫺15/2 f 4共2,2兲⫺3共2,1兲
0.13f 0.06
4共2,3兲⫺3共2,2兲 8共1,7兲⫺8共0,8兲
0.12 0.10 0.05 0.10 0.10 0.05
Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 IRC⫹10216 Sgr B2共M兲
NRAO NRAO NRAO NRAO NRAO NRAO
m m m m m m
Tur89 Tur89 Tur89 Tur89 Tha84 Tur89
0.08 0.12 b
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 11 m NRAO 11 m
Joh77 Tur89 Got79
Xu_97
0.8b
Sgr B2共M兲
NRAO 11 m
Got79
Xu_97
Sgr B2共M兲
NRAO 11 m
Got79
Xu_97 Xu_97
11 11 11 11 11 11
13
94407.129*共4兲
13
2共0,2兲⫺1共0,1兲 A⫹
94410.895*共4兲
13
2共0,2兲⫺1共0,1兲 E
b
2共1,1兲⫺1共1,0兲 E
0.03 1.0
G327.3⫺0.6 OriMC⫺1
SEST 15 m IRAM 30 m
Dic01 Men88
8共3,5兲⫺9共2,7兲 E 5共2,4兲⫺4共1,3兲 E 8共2,6兲⫺7共2,5兲
0.09 0.12 0.17 0.43 0.16 0.005
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO NRAO NRAO NRAO NRAO NRAO
m m m m m m
Tur91 Tur89 Tur89 Hol83 Tur89 App99
0.20f 0.2 0.16
NGC6334F
SEST 15 m
Num98a
NRAO 12 m NRAO 11 m NRAO 11 m
Ike01 Tur89 Tur89
94473. 94486. 94499. 94541.806*共19兲 94632.718*共20兲 94634.705*共22兲 94664.552*共12兲
CH3 OH CH3 OH CH3 OH
unidentified 13 CH3 OH unidentified unidentified unidentified CH3 OH CH3 OCHO SiC3
Wys72
⌸1/2 J⫽17/2⫺15/2 e
10共0,10兲⫺9共0,9兲 13共3,10兲⫺14共2,13兲 2共⫺1,2兲⫺1共⫺1,1兲 E
11 11 11 11 11 12
App00
App00
Got89
Xu_97 Oes99
c⫺C2 H4 O
3共1,3兲⫺2共0,2兲
94666.935*共45兲 94774. 94913.139*共14兲
CH3 OCHO unidentified CH2 CHCN
12共3,10兲⫺12共2,11兲 A 10共4,7兲⫺9共4,6兲
b
OriMC⫺1 OriMC⫺1 Sgr B2共M兲
94913.250*共14兲
CH2 CHCN
10共4,6兲⫺9共4,5兲
0.04b
Sgr B2共M兲
NRAO 11 m
Tur89
94964.915*共1兲
CH2 CHCN
10共8,2兲⫺9共8,1兲
2.5eb
Sgr B2共N兲
BIMAArray
Mia95
94964.915*共1兲
CH2 CHCN
10共8,3兲⫺9共8,2兲
Sgr B2共N兲
BIMAArray
Mia95
36
2⫺1
0.04
NGC6334A
SEST 15m
Mau96
21/2⫺19/2
0.03 0.24 0.08
OriMC⫺1 Sgr B2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Tur89 Gue78
2⫺1 J⫽3/2⫺1/2 F⫽2⫺1 8共0,8兲⫺7共1,7兲 A⫹ 19/2⫺17/2
0.015
IRC⫹10216
IRAM 30 m
Gue90
Sai89
0.85 0.08
OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m
Lov76a Gue78
Xu_97 Got83
2共1,1兲⫺1共1,0兲 A⫺
0.15
OriMC⫺1
NRAO 11 m
Tur89
Xu_97
0.03 0.11 0.03 0.12 0.04
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1
NRAO NRAO NRAO NRAO NRAO NRAO
Tur89 Tur89 Tur89 Tur89 Tur89 Joh77
95143. 95145. 95150.32*共2兲 95164.158共23兲
95220. 95247.990*共56兲 95295. 95325.490*共17兲 95339. 95442.479*共9兲 95444.067*共20兲
U
Gro98 Gro98 Gro98
m m m m
0.2bs
95169.516*共16兲 95188.94*共2兲 95208.776*共4兲
U
Cla79 Cla79 Cla79 Cla79
11 11 11 11
8,7⫺7,6
95016.679*共14兲
U
NRAO NRAO NRAO NRAO
0.06 0.14 0.14 0.20
3共2,2兲⫺4共1,3兲
U94414.6 94420.439*共5兲
U
Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1
4共2,3兲⫺4共1,4兲 EA 4共2,3兲⫺4共1,4兲 AE 4共2,3兲⫺4共1,4兲 EE
CCS
94351.596*共3兲 94405.223*共4兲
U U
Lab. Ref.
Source
NH2 CHO
94245.393共9兲 94247.464*共2兲 94276.640*共12兲
U
2
Astr. Ref.
T r 共K兲/T a 共K兲
93870.098*共12兲
94137.35*共29兲
U U U
unidentified CH3 OCH3 CH3 OCH3 CH3 OCH3 CH3 OCH3 C4 H
Telescope
Quantum numbers
93871.700*共7兲
U94077. 94081.38*共2兲
U U U U
Formula
C S unidentified unidentified C4 H CP CH3 OH C4 H 13 CH3 OH unidentified CH3 OCHO unidentified CH2 CHCN unidentified CH3 CH2 CN
t⫺CH3 CH2 OH
95454.077*共10兲
24
95469.296*共10兲
24
MgNC
7共4,3兲⫺7共3,4兲 E 10共2,8兲⫺9共2,7兲 11共1,11兲⫺10共1,10兲 16共2,14兲⫺16共1,13兲
b
0.20b
11 11 11 11 11 11
m m m m m m
Oes99
Got83
Oes99
OriMC⫺1
NRAO 11 m
Tur89
15/2,8⫺13/2,7
3.2
IRC⫹10216
IRAM 30 m
Gue93
Kaw93
b
17/2,8⫺15/2,7
2.9
IRC⫹10216
IRAM 30 m
Gue93
Kaw93
95502.417*共13兲 95553.325*共64兲
MgNC CH3 CH2 CN CH3 OCH3
14共2,13兲⫺共14共1,14兲 14共7,8兲⫺15共6,9兲 EE
0.07 0.16b
OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m
Sai89 Sai89
Gro98
95553.757*共66兲
CH3 OCH3
14共7,8兲⫺15共6,9兲 AE
b
OriMC⫺1
NRO 45 m
Sai89
Gro98
95556.318*共66兲
CH3 OCH3
14共7,7兲⫺15共6,10兲 AA
b
OriMC⫺1
NRO 45 m
Sai89
Gro98
95556.750*共66兲
CH3 OCH3
14共7,7兲⫺15共6,10兲 EE
0.13b
OriMC⫺1
NRO 45 m
Sai89
Gro98
95557.422*共70兲
CH3 OCH3
14共7,7兲⫺15共6,10兲 EA
b
OriMC⫺1
NRO 45 m
Sai89
Gro98
95570. 95579.381共15兲 95585. 95611.13共25兲
unidentified SiC2 unidentified C4 H
Sgr B2共M兲 IRC⫹10216 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Cum80 Tur91 Gue87a
4共2,2兲⫺3共2,1兲 10⫺9 v7 ⫽2 L
0.07 0.10 0.06 n.r.
Got89 Gue87a
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
218
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U U U
U
U U
Astr. Ref.
Lab. Ref.
0.18 0.05
OriMC⫺1 IRC⫹10216
NRO 45 m IRAM 30 m
Sai89 Gue87
JPL01
n.r.
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
0.09b 0.34 0.018
IRC⫹10216
IRAM 30 m
Gue87
JPL01
OriMC⫺1 IRC⫹10216
NRO 45 m IRAM 30 m
Sai89 Gue90
Sai89
0.05 0.018
OriMC⫺1 IRC⫹10216
NRO 45 m IRAM 30 m
Sai89 Gue90
0.58 1.14 0.53 0.09 0.08 0.08 0.07
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRAO 11 m NRAO 11 m
Sai89 Sai89 Sai89 Sai89 Sai89 Tur89 Tur89
95689.778*共8兲 95710.245共22兲
CH3 CH2 CN CP
95710.7 95712.631共15兲
unidentified CP
95729.768*共6兲 95731.250*共4兲 95732.732*共6兲 95741.3 95747.2 95783. 95810.412*共3兲
CH3 OCH3 CH3 OCH3 CH3 OCH3 unidentified unidentified unidentified
95850.336*共4兲
HC5 N
36⫺35
19.5f
IRC⫹10216
IRAM 30 m
Cer86a
95870.37*共14兲
HC7 N
85⫺84
95877. 95914.310*共3兲 95947.439*共6兲 95963.465*共6兲 95989. 96033. 96070.654*共24兲 96076.878*共24兲 96086.660*共29兲 96167.640*共51兲 96204.058*共4兲
unidentified CH3 OH CH3 CHO CH3 CHO unidentified unidentified CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO
8共2,7兲⫺7共2,6兲 E 8共2,7兲⫺7共2,6兲 A 6共4,2兲⫺6共3,3兲 A 6共4,2兲⫺6共3,3兲 E
0.06 0.06 0.81 0.35 0.30 0.02 0.03 0.08 0.08 0.03 0.03
Sgr B2共M兲 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲 Sgr B2共M兲
NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO
m m m m m m m m m m m
Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89
34
27共7,21兲⫺28共6,22兲
0.11b
Sgr B2
NRAO 11 m
Tur91
33
32共5,27兲⫺31共6,26兲
b
Sgr B2
NRAO 11 m
Tur91
Sgr B2共M兲 VYCMa
NRAO 11 m IRAM 30 m
Tur89 Men89
Kuz80
NRAO 11 m IRAM 30 m
Tur89 Sai87
Kle96 JPL01
2
2
⌸3/2 J⫽69/2⫺67/2 e 10⫺9 v7 ⫽2 U ⌸3/2 J⫽69/2⫺67/2 f 3共2,2兲⫺2共1,1兲
2⫺1 J⫽5/2⫺3/2 F⫽3⫺2 2⫺1 J⫽5/2⫺3/2 F⫽2⫺1 16共2,14兲⫺16共1,15兲 EA⫹AE 16共2,14兲⫺16共1,15兲 EE 16共2,14兲⫺16共1,15兲 AA
2共2,0兲⫺3共1,3兲
34
SO2
2共1,2兲⫺1共1,1兲 A⫹ 5共0,5兲⫺4共0,4兲 E 5共0,5兲⫺4共0,4兲 A⫹⫹
SO2 SO2
96258. 96261.16共10兲
unidentified H2 O
96274.257*共5兲 96293.4*共3兲
CH3 CHO C6 H
0.02 4共4,0兲⫺5共3,3兲 v2 ⫽1 5共2,4兲⫺4共2,3兲 A⫺⫺
4.2f 0.09
⌸1/2 J⫽69/2⫺67/2 e
1.12f
Sgr B2共M兲 IRC⫹10216
2
11 11 11 11 11 11 11 11 11 11 11
Sai89 Gro98 Gro98 Gro98
Xu_97 Kle96 Kle96
Oes99 Oes99 Oes99 Oes99
IRC⫹10216
IRAM 30 m
Sai87
JPL01
CH3 CHO
⌸1/2 J⫽69/2⫺67/2 f 5共3,3兲⫺4共3,3兲 A⫹⫹
1.28f
96367.790*共5兲
b
Sgr B2共M兲
NRAO 11 m
Got78a
Kle96
96368.376*共5兲
CH3 CHO
5共3,2兲⫺4共3,1兲 E
0.07b
Sgr B2共M兲
NRAO 11 m
Got78a
Kle96
96371.794*共5兲
CH3 CHO
5共3,2兲⫺4共3,1兲 A⫺⫺
b
Sgr B2共M兲
NRAO 11 m
Got78a
Kle96
96384.417*共5兲 96396.055*共4兲 96412.961*共7兲
CH3 CHO CH3 OH
5共⫺3,3兲⫺4共⫺3,2兲 E 2共1,2兲⫺1共1,1兲 A⫹ vt ⫽1
0.1 0.09
Sgr B2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Got78a Tur89
Kle96 Xu_97
96425.620*共5兲 96437. 96475.523*共5兲 96478.3共3兲
96632.668*共5兲 96637.769*共28兲 96648.099*共37兲 96670.896*共45兲 96691.570共兲 96693.517*共29兲 96709.210*共25兲
U U
Telescope
C4 H C6 H
96493.553*共4兲 96501.698*共6兲 96513.671*共8兲 96536.802*共5兲 96588.593*共5兲 96613.156*共53兲
U
Source
95667.89共25兲 95668.35*共9兲
96492.164*共4兲
U
T r 共K兲/T a 共K兲
unidentified C6 H
96342.1*共3兲
U
Quantum numbers
95613.0 95636.90*共9兲
96205.252*共56兲 U
Formula
C6 H
C34S CH3 CHO unidentified CH3 CHO C4 H CH3 OH CH3 OH CH3 OH CH3 OH CH2 CHCN CH3 OH CH3 OCHO CH3 CHO CH3 OCHO CH3 OCHO CH3 OCHO CH2 DCCH CH3 OCHO CH3 OCHO
2
2
2⫺1
0.62
OriMC⫺1
NRAO 11 m
Tur73
5共⫺2,4兲⫺4共⫺2,3兲 E
NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Got78a Yam87b
5共2,3兲⫺4共2,2兲 E
0.10 0.05 0.08
⌸3/2 J⫽21/2⫺19/2 v7 ⫽1 e
2.85f
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 IRC⫹10216
2共1,2兲⫺1共1,1兲 E vt ⫽1 2共0,2兲⫺1共0,1兲 E vt ⫽1 2共⫺1,1兲⫺1共⫺1,0兲 E vt ⫽1 2共0,2兲⫺1共0,1兲 A⫹ vt ⫽1 31共5,27兲⫺32共4,28兲 2共1,1兲⫺1共1,0兲 A⫺ vt ⫽1
0.13 0.12 0.06 0.08 0.1 0.10
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO NRAO NRAO
11 11 11 11 11 11
m m m m m m
Hol83 Hol83 Hol83 Hol83 Sny83 Tur89
Xu_97
8共4,5兲⫺8共3,6兲 E 5共2,3兲⫺4共2,2兲 A⫹⫹ 7共4,4兲⫺7共3,5兲 A 5共4,1兲⫺5共3,2兲 E 5共4,2兲⫺5共3,3兲 E 6共1,6兲⫺5共1,5兲 6共4,3兲⫺6共3,4兲 A
0.2 0.12 0.2 n.r. 0.05 0.06 0.1
OMC⫺IRc2 OMC⫺IRc2 OMC⫺IRc2 OMC⫺IRc2 OMC⫺IRc2 TMC⫺1 OMC⫺IRc2
IRAM IRAM IRAM IRAM IRAM IRAM IRAM
30 30 30 30 30 30 30
m m m m m m m
Ger89 Ger89 Ger89 Ger89 Ger89 Ger92 Ger89
Oes99 Kle96 Oes99 Oes99 Oes99 Ger92 Oes99
8共4,5兲⫺8共3,6兲 A
0.2 0.10 0.96 1.13 0.88 0.54 0.20
OMC⫺IRc2 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m
Ger89 Tur89 Hol83 Hol83 Hol83 Hol83 Tur89 Tur89
Oes99
NRAO 11 m NRAO 11 m NRAO 11 m
Cla79 Tur89 Cla79
Gro98
NRAO 11 m
Cla79
Gro98
96720. 96739.393*共3兲 96741.377*共3兲 96744.549*共3兲 96755.507*共3兲 96775. 96781.827*共22兲
unidentified CH3 OH CH3 OH CH3 OH CH3 OH unidentified
96797.共3兲 96822. 96847.241*共6兲
unidentified unidentified CH3 OCH3
5共2,4兲⫺5共1,5兲 AE
0.11b
Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1
96847.241*共6兲
CH3 OCH3
5共2,4兲⫺5共1,5兲 EA
b
OriMC⫺1
34
2共⫺1,2兲⫺1共⫺1,1兲 E 2共0,2兲_1共0,1兲 A⫹ 2共0,2兲⫺1共0,1兲 E 2共1,1兲⫺1共1,0兲 E 4共5兲⫺4共4兲
SO
0.04b 0.05 0.06
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Kle96 Kle96 Yam87b Xu_97 Xu_97 Xu_97 Xu_97
Xu_97 Xu_97 Xu_97 Xu_97
MICROWAVE TRANSITIONS
219
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 96849.881*共4兲 96852.496*共8兲 96919.754*共9兲 96988.123*共3兲 U
U U
97069. 97080.695共兲 97169.513共50兲
Telescope
Astr. Ref.
Lab. Ref.
CH3 OCH3 CH3 OCH3 CH3 CH2 CN
5共2,4兲⫺5共1,5兲 EE 5共2,4兲⫺5共1,5兲 AA 11共0,11兲⫺10共0,10兲
0.14 0.13 0.08
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m
Cla79 Cla79 Joh77
Gro98 Gro98
O13CS unidentified CH2 DCCH
8⫺7
0.069
Sgr B2共M兲
BTL 7 m
Gol81
0.12 0.10 b
OriMC⫺1 TMC⫺1 Sgr B2共M兲
NRAO 11 m IRAM 30 m BTL 7 m
Tur89 Ger92 Cum86
Ger92 Bog81 Bog81
C33S
2⫺1 1/2⫺1/2 2⫺1 7/2⫺5/2 ⫹ 5/2⫺3/2
97174.996共30兲
C33S
2⫺1 5/2⫺5/2
97175.271共60兲
C33 S
2⫺1 3/2⫺1/2
97218.353*共4兲 97244.70*共19兲
CH2 CHCHO C4 H
11共2,10兲⫺10共2,9兲
97263.540共50兲
g⫺CH3 CH2 OH
97271.020*共11兲 97276. 97282. 97286.836*共28兲 97294.123*共77兲
CS unidentified unidentified CH2 CHCN CH3 OCH3
97295.48*共14兲
Si13CC OCS CH3 OCHO
b
Sgr B2共M兲
BTL 7 m
Cum86
0.17b
Sgr B2共M兲
BTL 7 m
Cum86
Bog81
b
SgrB2共M兲
BTL 7 m
Cum86
Bog81
SgrB2共M兲
BTL 7 m
Cum86
Bog81
0.05 0.003
OriMC⫺1 IRC⫹10216
NRO 45 m NRAO 12 m
Ohi88 Hig00
JPL01
0.01
OriMC⫺1
NRO 45 m
Tur89
Pea97
6共1,6兲⫺5共0,5兲
0.007 0.02 0.01 0.02
IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1
28共7,21兲⫺27共8,19兲 EE
0.03b
J⫽21/2⫺19/2 v7 ⫽2 ᐉ⫽2 23共0,23兲⫺23共1,23兲 vt ⫽1⫺0 2⫺1 v⫽1
b
NRAO NRAO NRAO NRAO
12 11 11 11
m m m m
Tur87 Tur89 Tur89 Tur89
SgrB2
NRAO 11 m
Tur89
4共1,3兲⫺3共1,2兲
0.6f
IRC⫹10216
IRAM 30 m
Cer91b
Gro98
0.85 0.01
NRAO 11 m NRAO 11 m NRO 45 m
Sol73 Tur89 Ohi88
Dij71 Oes99 Pea97
97301.2085共2兲 97318.571*共20兲 97535.908共50兲
g⫺CH3 CH2 OH
8⫺7 4共2,2兲⫺3共1,3兲 E 21共1,21兲⫺21共0,21兲 vt ⫽1⫺0
0.08b
SgrB2共M兲 OriMC⫺1 OriMC⫺1
97536.849共50兲
g⫺CH3 CH2 OH
23共1,23兲⫺23共0,23兲 vt ⫽1⫺0
b
OriMC⫺1
NRO 45 m
Ohi88
Pea97
97546.875共50兲
g⫺CH3 CH2 OH
29共1,28兲⫺29共2,28兲 vt ⫽1⫺0
0.06
OriMC⫺1
NRO 45 m
Ohi88
Pea97
97549.692共50兲
g⫺CH3 CH2 OH
26共0,26兲⫺26共1,26兲 vt ⫽1⫺0
0.05
OriMC⫺1
NRO 45 m
Ohi88
Pea97
97562.844共50兲
g⫺CH3 CH2 OH unidentified
24共1,24兲⫺24共0,24兲 vt ⫽1⫺0
0.05
OriMC⫺1
NRO 45 m
Ohi88
Pea97
g⫺CH3 CH2 OH unidentified CH3 OH
20共1,20兲⫺20共0,20兲 vt ⫽1⫺0
0.04 0.09
OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m
Ohi88 Ohi88
Pea97
0.14 ⬍2.5
OriMC⫺1 OriMC⫺1
NRO 45 m OSO 20 m
Ohi88 Fri84
Xu_97
g⫺CH3 CH2 OH
25共1,25兲⫺25共0,25兲 vt ⫽1⫺0
OriMC⫺1
NRO 45 m
Ohi88
Pea97
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRO 45 m NRO 45 m
Tur89 Ohi88 Ohi88
Pea97
2共1,1兲⫺1共1,0兲 A⫺
97603. 97618.7 97631.329共50兲
g⫺CH3 CH2 OH
27共0,27兲⫺27共1,27兲 vt ⫽1⫺0
0.21b 0.06 0.05 0.06
97632.226*共34兲
H2 13CS
3共1,3兲⫺2共1,2兲
0.04
SgrB2共M兲
BTL 7 m
Cum86
97649.502共50兲
g⫺CH3 CH2 OH CH3 OCHO unidentified CH3 OH CH3 OH CH3 OCHO SO2
19共1,19兲⫺19共0,19兲 vt ⫽1⫺0
0.12
OriMC⫺1
NRO 45 m
Ohi88
Pea97
0.22 0.21 0.29 0.34 0.2 ⬍0.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRAO 11 m
Ohi88 Ohi88 Ohi88 Ohi88 Ohi88 Sny75a
Oes99
3共2兲⫺2共1兲
0.14
OriMC⫺1
NRAO 11 m
Got78
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRO NRO NRO NRO
m m m m
Ohi88 Ohi88 Ohi88 Ohi88
Pea97
97651.392*共25兲 97662.0 97678.26*共10兲 97679.38*共10兲 97694.197*共24兲 97702.340*共2兲 97715.401*共16兲
unidentified unidentified
34
10共4,7兲⫺10共3,8兲 E 21共6,16兲⫺22共5,17兲 A⫺ 21共6,15兲⫺22共5,18兲 A⫹ 10共4,7兲⫺10共3,8兲 A 7共3,5兲⫺8共2,6兲
SO
g⫺CH3 CH2 OH
28共1,28兲⫺28共0,28兲 vt ⫽1⫺0
0.06 0.10 0.19 0.05
97774.307共50兲
g⫺CH3 CH2 OH
18共1,18兲⫺18共0,18兲 vt ⫽1⫺0
0.07
OriMC⫺1
NRO 45 m
Ohi88
Pea97
97815.987共50兲
g⫺CH3 CH2 OH H2 CCCC unidentified C5 H
29共1,29兲⫺29共0,20兲 vt ⫽1⫺0
0.05
OriMC⫺1
NRO 45 m
Ohi88
Pea97
11共1,11兲⫺10共1,10兲
0.106 0.12
IRAM 30 m NRO 45 m IRAM 30 m
Cer91a Ohi88 Cer86
Kil90 Cer86 Cer86
97833.634*共19兲 97846.3 97862.6共4兲
unidentified unidentified unidentified
C5 H
U U U U U U
97869.8 97874.0 97886.0 97897.5 97915.6 97926.
unidentified unidentified unidentified unidentified unidentified unidentified
U
97931.2 97932.445共50兲
unidentified
45 45 45 45
Xu_97 Xu_97 Oes99
97729.4 97739.3 97753.4 97755.610共50兲
97868.8共4兲
U
6共0,6兲⫺5共0,5兲 2⫺1 3/2⫺3/2
C33S
97577.9 97582.808*共3兲 97600.390共50兲
U
Source
C33S
U
U U U
T r 共K兲/T a 共K兲
97171.840共30兲
97569.0 97574.042共50兲
U
Quantum numbers
97171.84共10兲
U
U U
Formula
2
⌸ 1/2 J⫽41/2⫺39/2 e
1.2f
IRC⫹10216 OriMC⫺1 IRC⫹10216
2
⌸ 1/2 J⫽41/2⫺39/2 f
1.1f
IRC⫹10216
IRAM 30 m
Cer86
0.07 0.07 0.17 0.22 0.06
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRO 45 m NRAO 11 m
Ohi88 Ohi88 Ohi88 Ohi88 Ohi88 Tur89
OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m
Ohi88 Ohi88
Pea97
g⫺CH3 CH2 OH unidentified
31共0,31兲⫺31共1,31兲 vt ⫽1⫺0
0.02b 0.06 0.06
17共1,17兲⫺17共0,17兲 vt ⫽1⫺0
OriMC⫺1 OriMC⫺1
NRO 45 m NRO 45 m
Ohi88 Ohi88
Pea97
97980.953*共4兲 97995.212*共20兲
g⫺CH3 CH2 OH CS l⫺C3 H
0.04 0.09
OriMC⫺1 OriMC⫺1
NRAO 11 m NRO 45 m
Tur73 Ohi88
Yam90a
97995.951*共20兲
l⫺C3 H
OriMC⫺1
NRO 45 m
Ohi88
Yam90a
97957.2 97962.858共50兲
2⫺1 2
⌸ 1/2 J⫽9/2⫺7/2 F⫽5⫺4 e
6.94 0.1
2
⌸ 1/2 J⫽9/2⫺7/2 F⫽4⫺3 e
0.2
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
220
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
⌸ 1/2 J⫽9/2⫺7/2 F⫽5⫺4 f
0.09b
IRC⫹10216
OSO 20 m
Tha85
Yam90a
b
IRC⫹10216
OSO 20 m
Tha85
Yam90a
98177.578*共8兲
0.15
98182.199*共29兲
CH3 CH2 CN CH3 OCHO
⌸ 1/2 J⫽9/2⫺7/2 F⫽4⫺3 f 11共2,10兲⫺10共2,9兲 8共7,1兲⫺7共7,0兲 E
0.07b
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Joh77 Tur89
Oes99
98190.653*共28兲
CH3 OCHO
8共7,1兲⫺7共7,0兲 A
0.08b
OriMC⫺1
NRAO 11 m
Tur89
Oes99
98190.653*共28兲
CH3 OCHO
8共7,2兲⫺7共7,1兲 A
b
OriMC⫺1
NRAO 11 m
Tur89
Oes99
98191.414*共25兲
CH3 OCHO
8共7,2兲⫺7共7,1兲 E
b
OriMC⫺1
NRAO 11 m
Tur89
Oes99
98218.353*共20兲
H2 CCCC
11共3,9兲⫺10共3,8兲
0.08b
IRC⫹10216
IRAM 30 m
Cer87b
Kil90
98218.355*共20兲
H2 CCCC
11共3,8兲⫺10共3,7兲
b
IRC⫹10216
IRAM 30 m
Cer87b
Kil90
98230.313共50兲
g⫺CH3 CH2 OH H2 CCCC H2 CCCC unidentified unidentified CCCS
16共1,16兲⫺16共0,16兲 vt ⫽1⫺0
0.02
OriMC⫺1
NRO 45 m
Kut80
Pea97
11共2,9兲⫺10共2,8兲 11共0,11兲⫺10共0,10兲
0.03 0.038 0.03 0.04
Cer87b Cer91a Kut80 Cum86 Cer87b
98278.870*共24兲
CH3 OCHO CH3 OCHO
8共6,2兲⫺7共6,1兲 E 8共6,3兲⫺7共6,2兲 E
2.2f 0.06
IRAM 30 m IRAM 30 m NRAO 11 m BTL 7 m IRAM 30 m
Kil90 Kil90
17⫺16
IRC⫹10216 IRC⫹10216 OriMC⫺1 SgrB2共M兲 IRC⫹10216
b
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Kut80 Kut80
Oes99 Oes99
98279.746*共25兲
CH3 OCHO
8共6,3兲⫺7共6,2兲 A
0.12b
OriMC⫺1
NRAO 11 m
Kut80
Oes99
98279.788*共25兲
CH3 OCHO
8共6,2兲⫺7共6,1兲 A
b
OriMC⫺1
NRAO 11 m
Kut80
Oes99
98333.9 98351.9 98408.66*共9兲
unidentified unidentified C6 H
OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Kut80 Kut80 Gue87
JPL01
98424.082*共28兲 98431.748*共24兲
CH3 OCHO CH3 OCHO
⌸ 3/2 J⫽71/2⫺69/2 e 8共5,3兲⫺7共5,2兲 E 8共5,4兲⫺7共5,3兲 E
0.02 0.02 0.04 0.10 b
OriMC⫺1 SgrB2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
Oes99 Oes99
98432.773*共25兲
CH3 OCHO
8共5,4兲⫺7共5,3兲 A
0.04b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
98435.820*共25兲
CH3 OCHO
8共5,3兲⫺7共5,2兲 A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
IRC⫹10216
IRAM 30 m
Gue87
JPL01
b
OriMC⫺1
NRAO 11 m
Tur89
98244.941*共18兲 98257.7 98265.9共9兲 98268.515*共5兲
2
⌸ 3/2 J⫽71/2⫺69/2 f
0.04
98441.85*共9兲
C6 H
98474.55*共13兲
33
SO
3共2兲⫺2共1兲 F⫽3/2⫺1/2
98482.15*共8兲
33
SO
3共2兲⫺2共1兲 F⫽5/2⫺3/2
b
OriMC⫺1
NRAO 11 m
Tur89
98489.08*共7兲
33
SO
3共2兲⫺2共1兲 F⫽7/2⫺5/2
0.10b
OriMC⫺1
NRAO 11 m
Tur89
98493.68*共13兲
33
3共2兲⫺2共1兲 F⫽9/2⫺7/2 37⫺36 11共6兲⫺10共6兲 11共7兲⫺10共7兲
b
OriMC⫺1
NRAO 11 m
Tur89
0.08 0.13 0.10
2
⌸ 3/2 J⫽41/2⫺39/2 e
4.5fb
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Buj81 Joh77 Joh77 Cer86a
Got86
2
⌸ 3/2 J⫽41/2⫺39/2 f 11共8兲⫺10共8兲 11共5兲⫺10共5兲
b
IRC⫹10216
IRAM 30 m
Cer86a
Got86
0.06 0.17
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Joh77 Joh77
11共9,*兲⫺10共9,*兲 11共4,8兲⫺10共4,7兲 11共4,7兲⫺10共4,6兲 8共3,6兲⫺7共3,5兲E
0.08 0.09 0.09 b
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m NRAO 11 m BTL 7 m
Tur89 Joh77 Joh77 Cum86
11共3,9兲⫺10共3,8兲
0.14
OriMC⫺1
NRAO 11 m
Joh77
8共3,6兲⫺7共3,5兲 A
SgrB2共M兲
BTL 7 m
Cum86
11共3,8兲⫺10共3,7兲 8共4,5兲⫺7共4,4兲 E 8共4,4兲⫺7共4,3兲 E
0.08b 0.10 0.124 0.06 0.02 0.05 0.12 0.04 0.04
SgrB2共M兲 IRC⫹10216 OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲 SgrB2共M兲
NRAO 11 m IRAM 30 m NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m BTL 7 m BTL 7 m
Tur89 Cer91a Tur89 Cum86 Tur89 Joh77 Cum86 Cum86
8共4,4兲⫺7共4,3兲 A
0.03 0.05
OriMC⫺1 SgrB2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
0.23 0.2 0.18
SgrB2共M兲 OriMC⫺1 SgrB2共M兲 IRC⫹10216
BTL 7 m NRAO 12 m BTL 7 m IRAM 30 m
Cum86 Ike01 Cum86 Cer87c
98512.521*共4兲 98523.881*共7兲 98524.663*共7兲 98524.94*共5兲
SO HC5 N CH3 CH2 CN CH3 CH2 CN C5 H
98527.44*共5兲
C5 H
CH3 CH2 CN CH3 OCHO
U
98630.
U
98655.097*共22兲 98663.
unidentified H2 CCCC unidentified CH3 OCHO unidentified CH3 CH2 CN CH3 OCHO CH3 OCHO
98682.635*共25兲 98696. 98701.106*共8兲 98711.931*共24兲 98747.797*共32兲 98771. 98792.314*共25兲 98863.314*共6兲
2
11共1,10兲⫺10共1,9兲 8共4,5兲⫺7共4,4兲 A
unidentified CH3 OCHO CH3 CHO CH3 OCHO CH3 CHO AlF
5共1,4兲⫺4共1,3兲 E 11共4,8兲⫺11共3,9兲 A 5共1,4兲⫺4共1,3兲 A⫺⫺ 3⫺2
98940.02*共2兲
CCCN
10⫺9 J⫽21/2⫺19/2
98958.78*共2兲
CCCN
98976.278*共2兲 99011. 99068. 99083.7*共3兲
SO2 unidentified unidentified C6 H
10⫺9 J⫽19/2⫺17/2 28共7,21兲⫺29共6,24兲
99087. 99118.6共1兲 99120.
unidentified NH2 D unidentified
98875.160*共24兲 98900.951*共6兲 98926.723*共17兲
U
Lab. Ref.
2
98610.104*共8兲 98611.195*共25兲
U
Astr. Ref.
2
98564.832*共8兲 98566.797*共8兲 98606.771*共24兲
U U
Telescope
l⫺C3 H
CH3 CH2 CH CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN CH3 OCHO
U
Source
l⫺C3 H
98532.075*共7兲 98533.983*共13兲 98544.152*共6兲
U
T r 共K兲/T a 共K兲
98011.649*共20兲
98270.369*共29兲
U U
Quantum numbers
98012.576*共20兲
98238.285*共20兲 U U
Formula
2
0.97f 0.18
Oes99 Kil90 Oes99
Oes99 Oes99 Oes99 Kle96 Oes99 Kle96
IRC⫹10216
NRAO 11 m
Gue77
Got83
0.13
IRC⫹10216
NRAO 11 m
Gue77
Got83
0.08 0.08 0.08
NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur91 Tur89 Tur91 Sai87
JPL01
NRAO 11 m BTL 7 m OSO 20 m
Tur89 Cum86 Fri84
⌸ 1/2 J⫽71/2⫺69/2 e
0.97f
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
5共2,4兲⫺4共1,4兲
0.12 0.04 0.15
OriMC⫺1 SgrB2共M兲 OriMC⫺1
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Oes99
DeL75
MICROWAVE TRANSITIONS
221
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 99133.6*共3兲 99143.725共50兲
U
U
U U U U u
U U U U U
U U
U
IRAM 30 m
Sai87
JPL01
NRO 45 m
Tur89
Pea97
NRAO 11 m NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m
Tur89 Tur89 Got78 Cum86 Cla79
Lee80 Lee80
b
SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1
Joh76a Gro98
Telescope
2 ⌸ 1/2 J⫽71/2⫺69/2 f 27共2,26兲⫺27共1,26兲 vt ⫽1⫺0
1.05f 0.10
IRC⫹10216 OriMC⫺1
2共1兲⫺2共0兲 E 3共1兲⫺3共0兲 E 3共2兲⫺2共1兲 5共1,5兲⫺4共1,4兲 4共1,4兲⫺3共0,3兲 EA⫹AE
0.10 0.08 1.59m 0.40
C6 H
99264.98共5兲 99299.905*共14兲 99311.195共75兲 99324.358*共6兲 99325.208*共4兲
CH3 OCH3
4共1,4兲⫺3共0,3兲 EE
0.2b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
99326.058*共4兲
CH3 OCH3
4共1,4兲⫺3共0,3兲 AA
b
OriMC⫺1
NRAO 11 m
Cla79
Gro98
99361. 99378. 99392.526*共3兲 99409.74共10兲 99586. 99651.863*共11兲
unidentified unidentified SO2 CH3 SH unidentified
29共4,26兲⫺28共5,23兲 4共1兲⫺4共0兲 E
HC13CCN
11⫺10
0.03 0.03 ⬍0.50 0.05 0.12 0.13
SgrB2共M兲 SgrB2共M兲 OriMC⫺1 SgrB2共M兲 OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m OSO 20 m NRAO 11 m NRAO 11 m BTL 7 m
Tur89 Tur89 Fri84 Tur89 Tur89 Cum86
99661.471*共6兲
HCC13CN CH2 DOH
11⫺10
0.14
SgrB2共M兲
BTL 7 m
Cum86
Laf78
0.3f 0.05 0.04 0.20 ⬍0.2
OriMC⫺1
IRAM 30 m
Jac92
Jac93
SgrB2共M兲 SgrB2共M兲 OriMC⫺1 OriMC⫺1
BTL 7 m BTL 7 m NRAO 11 m OSO 20 m
Cum86 Cum86 Chu80 Gar85
Xu_97 Lov84
BTL 7 m NRAO 11 m IRAM 30 m
Cum86 Tur89 Cer87c
Clo64
99672.23共5兲 U
Lab. Ref.
Source
Quantum numbers
g⫺CH3 CH2 OH CH3 SH CH3 SH SO NH2 CN CH3 OCH3
99203.46*共10兲
U U
Astr. Ref.
T r 共K兲/T a 共K兲
Formula
99681.511*共8兲 99727.0共16兲 99730.959*共14兲 99774.15共5兲 99866.509*共12兲 99903. 99929.54共10兲
CH3 CH2 CN unidentified CH3 OH H2 C34S CCS unidentified
6共1,5兲⫺6共0,6兲 11共2,9兲⫺10共2,8兲 6共1,6兲⫺5共0,5兲 E vt ⫽1 3共1,3兲⫺2共1,2兲
K35Cl NH2 CN
13⫺12
0.43f
99953.27共6兲
5共2,4兲⫺4共2,3兲
0.08b
SgrB2共M兲
BTL 7 m
Cum86
Joh76a
99956.60共4兲
NH2 CN
5共2,3兲⫺4共2,2兲
b
SgrB2共M兲
BTL 7 m
Cum86
Joh76a
99972.66共8兲
NH2 CN
5共0,5兲⫺4共0,4兲 4共5兲⫺4共4兲
0.12
SgrB2共M兲 OriMC⫺1
BTL 7 m NRAO 11 m
Cum86 Got78
Joh76a
OriMC⫺1 SgrB2共M兲 SgrB2共M兲 OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m BTL 7 m BTL 7 m BTL 7 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRO 45 m
Mor76 Tur77 Lin79 Tur89 Tur77 Tur89 Tur89 Cum86 Tur77 Tur91 Cum86 Gol82 Gol82 Tur89 Tur89 Tur89 Tur89 Tur91 Tur89
b
OriMC⫺1
NRAO 11 m
Wil81
Gro98
SO
100076.385*共3兲 100094.500*共24兲 100110.27共10兲 100122. 100157.0 100173.10共10兲 100185. 100197.2共8兲 100200.4 100240.524*共31兲 100294.508*共25兲 100308.210*共25兲 100322.349*共29兲 100332. 100365. 100373. 100421. 100436. 100452.072 共50兲
HCCCN CH2 CO CH3 SH unidentified unidentified CH3 SH unidentified unidentified unidentified HCCCN CH3 OCHO CH3 OCHO HCCCN unidentified unidentified unidentified unidentified unidentified
11⫺10 5共1,5兲⫺4共1,4兲 4共1兲⫺3共1兲 A⫹
7共2兲⫺8共1兲 A⫹
11⫺10 v6 ⫽1 ᐉ⫽1 e 8共3,5兲⫺7共3,4兲 E 8共3,5兲⫺7共3,4兲 A 11⫺10 v7 ⫽1 ᐉ⫽1 e
24共2,23兲⫺24共1,23兲 vt ⫽1⫺0
0.08 0.15
Laf78
SgrB2共M兲 SgrB2共M兲 IRC⫹10216
100029.565*共29兲
7,8⫺6,7
Lee80
0.38m 1.28 0.17 0.06 0.10 0.07 0.08 0.05 0.09 0.09 0.02 0.05 0.08 0.07 0.06 0.18 0.10 0.06 0.06 0.08
Lee80
Lee80
Laf78 Oes99 Oes99 Laf78
Pea97
100460.412*共6兲
g⫺CH3 CH2 OH CH3 OCH3
100463.066*共4兲
CH3 OCH3
6共2,5兲⫺6共1,6兲 EE
0.12b
OriMC⫺1
NRAO 11 m
Wil81
Gro98
100465.708*共8兲
CH3 OCH3
6共2,5兲⫺6共1,6兲 AA
b
OriMC⫺1
NRAO 11 m
Wil81
Gro98
100466.106*共29兲 100482.174*共24兲 100490.715*共24兲 100491.715*共6兲 100498.5
HCCCN CH3 OCHO CH3 OCHO N2 O unidentified
11⫺10 v7 ⫽1 ᐉ⫽1 f 8共1,7兲⫺7共1,6兲 E 8共1,7兲⫺7共1,6兲 A 4⫺3
0.04 0.08 0.08 0.038 0.05
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1
NRAO 11 m BTL 7 m BTL 7 m NRAO 12 m NRAO 11 m
Tur91 Gol82 Gol82 Ziu94a Wil81
Laf78 Oes99 Oes99
100509. 100526.506*共8兲
unidentified CH3 NC
0.03 5⫺4
SgrB2共M兲 SgrB2共M兲
NRAO 12 m IRAM 30 m
Ziu94a Cer88
100598.34 100614.291*共8兲 100629.50共12兲 100638.870*共24兲
SgrB2共M兲 OriMC⫺1 SgrB2共M兲
FCRAO 14 m NRAO 11 m NRAO 11 m
Irv88a Joh77 Tur75a
Joh76a
100681.476*共25兲
CH2 CN CH3 CH2 CN NH2 CN CH3 OH CH3 OCHO
1.8f 0.55 0.10 0.17 0.07b
OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m
Tur89 Chu80
Xu_97 Oes99
100683.392*共28兲
CH3 OCHO
9共0,9兲⫺8共0,8兲 A
100708.837*共44兲
HCCCN
11⫺10 v7 ⫽2 ᐉ⫽0
100710.972*共52兲
HCCCN
100714.306*共46兲
HCCCN
100841.3
unidentified
100855.437*共20兲
CH3 COOH
6共2,5兲⫺6共1,6兲 EA⫹AE
5⫺411/2⫺9/2 11共1,10兲⫺10共1,9兲 5共1,4兲⫺4共1,3兲 13共2,11兲⫺12共3,9兲 E 9共0,9兲⫺8共0,8兲 E
0.35
Irv88a
b
SgrB2共M兲
NRAO 11 m
Chu80
Oes99
0.05b
SgrB2共M兲
BTL 7 m
Cum86
Laf78
11⫺10 v7 ⫽2 ᐉ⫽2 e
b
SgrB2共M兲
BTL 7 m
Cum86
Laf78
11⫺10 v7 ⫽2 ᐉ⫽2 f
b
SgrB2共M兲
BTL 7 m
Cum86
Laf78
0.5e
SgrB2共N兲
BIMA Array
Meh97
b
SgrB2共N兲
BIMA Array
Meh97
9共⫺1,9兲⫺8共⫺1,8兲 E
Ily00
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
222
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
100855.437*共20兲
CH3 COOH
9共⫺1,9兲⫺8共0,8兲 E
b
SgrB2共N兲
BIMA Array
Meh97
Ily00
100855.437*共20兲
CH3 COOH
9共0,9兲⫺8共⫺1,8兲 E
0.19be
SgrB2共N兲
BIMA Array
Meh97
Ily00
100855.437*共20兲
CH3 COOH
9共0,9兲⫺8共0,8兲 E
b
SgrB2共N兲
BIMA Array
Meh97
Ily00
U
100856.6
unidentified
0.2e
SgrB2共N兲
BIMA Array
Meh97
U
100864.8
unidentified
0.7e
SgrB2共N兲
BIMA Array
Meh97
u
100866.3
unidentified
SgrB2共N兲
BIMA Array
Meh97
100878.105*共3兲 100897.459*共20兲
SO2 CH3 COOH
2共2,0兲⫺3共1,3兲 9共*,9兲⫺8共*,8兲 A
0.8e 0.08
SgrB2共M兲 W51e2
BTL 7 m BIMA Array
Cum86 Rem02
Ily00
CH3 SH
7共1兲⫺7共0兲 E
SgrB2共N兲
BIMA Array
Meh97
Lee80
101002.355*共24兲
t⫺CH3 CH2 OH CH2 CO
101002.360*共24兲
CH2 CO
101024.438*共22兲
CH2 CO
101029.75共5兲
CH3 SH
4共⫺1兲⫺3共⫺1兲 E
101036.589*共27兲
CH2 CO
101139.16共5兲 101139.65共4兲
100898.58共5兲
8共2,7兲⫺8共1,8兲
0.2e 0.05
SgrB2共M兲
BTL 7 m
Lin79
5共3,3兲⫺4共3,2兲
0.06b
SgrB2共M兲
BTL 7 m
Cum86
5共3,2兲⫺4共3,1兲
b
SgrB2共M兲
BTL 7 m
Cum86
5共2,4兲⫺4共2,3兲
0.05b
SgrB2共M兲
NRAO 11 m
Tur89
b
SgrB2共M兲
BTL 7 m
Lin79
5共0,5兲⫺4共0,4兲
0.12b
SgrB2共M兲
NRAO 11 m
Tur77
CH3 SH
4共0兲⫺3共0兲 A
0.27b
SgrB2共M兲
BTL 7 m
Lin79
CH3 SH
4共0兲⫺3共0兲 E
b
SgrB2共M兲
BTL 7 m
Lin79
Lin79
101159.46共10兲 101167.15共4兲
CH3 SH CH3 SH
4共2兲⫺3共2兲 A⫺
0.03
SgrB2共M兲
BTL 7 m
Cum86
Lee80
4共⫺2兲⫺3共⫺2兲 E
0.13b
SgrB2共M兲
BTL 7 m
Cum86
Lin79
101168.34共4兲
CH3 SH
4共2兲⫺3共2兲 E
b
SgrB2共M兲
BTL 7 m
Cum86
Lin79
101174.678*共4兲
HC5 N
38⫺37
0.09b
SgrB2共M兲
BTL 7 m
Lin79
101179.76共10兲
CH3 SH
101180.40*(9) 101185.367*共17兲 101200.4 101211.5 101215.37*共9兲
C6 H
100990.034*共15兲
U U U U U U U
U
U U U U
U
U U U
101243.6 101253.8 101272.9 101279.2 101284.36共4兲 101287.3 101293.328*共16兲 101299.309*共18兲 101302.116*共37兲
CH3 OH unidentified unidentified C6 H
4共2兲⫺3共2兲 A 2
2
⌸ 3/2 J⫽73/2⫺71/2 e 6共⫺2,5兲⫺6共1,5兲 E
⌸ 3/2 J⫽73/2⫺71/2 f
b
1.20f n.r. 0.05 n.r.
Lin79
Lin79
SgrB2共M兲
BTL 7 m
Lin79
Lee80
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
IRAM IRAM IRAM IRAM
m m m m
Com96 Com96 Com96 Cer87a
Xu_97
0.70f
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
30 30 30 30
0.02 0.07 0.02 0.03 0.09 0.07 n.r. n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m BTL 7 m IRAM 30 m IRAM 30 m IRAM 30 m
Com96 Com96 Com96 Com96 Lin79 Com96 Com96 Com96
n.r. n.r. n.r. 0.02 ⬍0.1 0.08 0.02 0.03
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 SgrB2共M兲 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m BTL 7 m BTL 7 m IRAM 30 m IRAM 30 m
Com96 Com96 Com96 Com96 Lin79 Cum86 Com96 Com96
0.05 n.r. 0.02 n.r. 0.08b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m
Tur89 Com96 Com96 Com96 Com96
Oes99 Vac86
JPL01
101305.534*共34兲 101314.830*共7兲 101318.6 101332.987*共6兲 101343.448*共7兲 101348.8 101357.0
unidentified unidentified unidentified unidentified CH3 SH unidentified CH3 OH NH2 CHO CH3 OCHO CH3 OCHO DCCCN unidentified H2 CO CH3 CHO unidentified unidentified
101371. 101382.335*共4兲 101408.9 101414.723*共51兲 101426.664*共20兲
unidentified DNCO unidentified CH3 OCHO 共CH3 兲2 CO
13共3,11兲⫺13共2,12兲 A 9共1,8兲⫺8共2,7兲 AE
101426.759*共17兲
共CH3 兲2 CO
9共1,8兲⫺8共2,7兲 EA
b
OriMC⫺1
IRAM 30 m
Com96
Vac86
101427.041*共20兲
共CH3 兲2 CO
9共2,8兲⫺8共1,7兲 AE
b
OriMC⫺1
IRAM 30 m
Com96
Vac86
101427.130*共17兲
共CH3 兲2 CO
9共2,8兲⫺8共1,7兲 EA
b
OriMC⫺1
IRAM 30 m
Com96
Vac86
101435.9 101451.059*共14兲
unidentified 共CH3 兲2 CO
0.02 9共1,8兲⫺8共2,7兲 EE
n.r.b
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
Vac86
101451.446*共14兲
共CH3 兲2 CO
9共1,8兲⫺8共2,7兲 EE
OriMC⫺1
IRAM 30 m
Com96
Vac86
101469.719*共16兲 101477.764*共33兲 101499.2 101503.8 101523.6 101534.00* 共53兲
CH3 OH H2 CS unidentified unidentified unidentified
8共⫺2,7兲⫺8共1,7兲 E 3共1,3兲⫺2共1,2兲
n.r.b 0.17 0.49 0.06 0.05 0.02 n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m BTL 7 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m
Tur89 Van84 Com96 Com96 Com96 Com96
Xu_97
18共3,15兲⫺18共3,16兲 A 12共2,10兲⫺11共3,9兲 AA
n.r.
OriMC⫺1 OriMC⫺1
IRAM 30 m NRAO 11 m
Com96 Tur89
Oes99 Gro98
17共5,13兲⫺18共4,14兲
n.r.
101545.423*共70兲 101559.383*共10兲 101560.264*共18兲
U
0.11e
H13COOH CH3 OCHO CH3 OCH3
4共1兲⫺3共1兲 E 7共⫺2,6兲⫺7共1,6兲 E 18共2,16兲⫺18共2,17兲 25共6,19兲⫺25共5,20兲 A 25共6,19兲⫺25共5,20兲 E 12⫺11 6共1,5兲⫺6共1,6兲 3共⫺1,3兲⫺2共0,2兲 E
5共1,5兲⫺4共1,4兲
9共3,6兲⫺10共2,9兲
b
Lin79 Xu_97 Oes99 Oes99
Kle96
Wil80
OriMC⫺1
IRAM 30 m
Com96
101562.117*(8)
SO2 CH3 OCH3
12共2,10兲⫺11共3,9兲 EE
0.10b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
101564.832*(8)
CH3 OCH3
12共2,10兲⫺11共3,9兲 AE
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
101564.872*共8兲
CH3 OCH3
12共2,10兲⫺11共3,9兲 EA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
101575.5
unidentified
0.02
OriMC⫺1
IRAM 30 m
Com96
33
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
223
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U
U U
U
U U U U U U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
101626.822*共28兲
CH3 OCHO
9共1,9兲⫺8共0,8兲 E
n.r.b
OriMC⫺1
IRAM 30 m
Com96
Oes99
CH3 OCHO
9共1,9兲⫺8共0,8兲 A
OriMC⫺1
IRAM 30 m
Com96
Oes99
101637.243*共18兲
CH2 CHCN unidentified unidentified unidentified
11共1,11兲⫺10共1,10兲
n.r.b 0.05
OriMC⫺1
NRAO 11 m
Tur91
12共4,8兲⫺12共3,11兲
n.r. 0.03 0.02 0.03
OriMC⫺1 OriMC⫺1 SgrB2共M兲 SgrB2共M兲
IRAM 30 m IRAM 30 m NRAO 11 m NRAO 11 m
Com96 Com96 Tur89 Tur89
n.r. 0.02 0.02 0.36 0.06
IRAM 30 m IRAM 30 m IRAM 30 m OSO 20 m OSO 20 m IRAM 30 m
Com96 Com96 Com96 Mil87 Mil87 Cer87a
Xu_97 Oes99 JPL01
10⫺9 J⫽21/2⫺19/ 2
0.75f 0.006
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216 IRC⫹10216
IRAM 30 m
Ziu95
And94
⌸ 1/2 J⫽73/2⫺71/2 f
0.78f
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
8⫺7
0.68f
IRC⫹10216
IRAM 30 m
Cer87c
5共1,4兲⫺4共1,3兲 3共1,3兲⫺2共0,2兲
0.05 0.22 0.05
SgrB2共M兲 SgrB2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m
Tur89 Tur77 Tur89
7⫺6
0.82f
IRC⫹10216
IRAM 30 m
Cer87c
5共1,5兲⫺4共1,4兲 4共0,4兲⫺3共1,3兲
0.03 0.2 0.398
OriMC⫺1 SgrB2共M兲 SgrB2共M兲
NRAO 11 m NRAO 11 m NRO 45 m
Tur89 Tur78a Ohi96
11共1,11兲⫺11共0,11兲 vt ⫽1⫺0
0.41 0.08 0.09 0.02 0.03 0.10 0.10 0.10 0.03 0.05 0.04 0.03
OriMC⫺1 SgrB2共M兲 SgrB2共M兲 OriMC⫺1 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OSO 20 m BTL 7 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRO 45 m
Mil87 Lin79 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89
6共4兲⫺5共4兲 6共3兲⫺5共3兲 6共2兲⫺5共2兲 6共1兲⫺5共1兲 6共0兲⫺5共0兲
0.23 0.14 0.23 0.29 0.33
W51e1/e2 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m
Ala02 Chu83 Chu83 Chu83 Chu83
1.1f
IRC⫹10216
IRAM 30 m
Cer86
Cer86
0.08
OriMC⫺1 IRC⫹10216
OSO 20 m IRAM 30 m
Mil87 Cer86
Cer86
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m OSO 20 m OSO 20 m
Tur89 Tur89 Lov82 Mil87 Mil87
Xu_97
OriMC⫺1
OSO 20 m
Mil87
Oes99
SgrB2共M兲
NRAO 11 m
Tur89
101659.0 101668.7 101677. 101688.880*共13兲
33
SO2
101690.002*共18兲
CH3 CH2 CN
101708.8 101713.6 101737.211*共17兲 101771.892*共56兲 101873.9*共3兲
unidentified unidentified CH3 OH CH3 OCHO C6 H
101892.56共10兲
MgCN
101925.1*共3兲
C6 H
101961.512*共59兲
Na37Cl
101970. 101981.426*共24兲 102031.874*共4兲
unidentified CH2 CO
102043. 102064.263*共1兲 102065.856*共44兲 102122.701*共18兲
U
Quantum numbers
101628.167*共29兲
102031.94*共5兲 U
Formula
102202.49共4兲 102217.571*共2兲 102274. 102298.085*共16兲 102319. 102375. 102399. 102407. 102423. 102432. 102489.386 共50兲 102516.635*共3兲 102530.346*共1兲 102540.143*共1兲 102546.023*共1兲 102547.983*共1兲 102635.7共7兲
27共2,25兲⫺27共1,26兲
9共⫺2,8兲⫺9共1,8兲 E 24共5,19兲⫺24共4,20兲 A 2
2
34
SO2
Al35Cl unidentified NH2 CHO H2 COH⫹ CH3 OH CH3 SH NH2 CHO unidentified HCCCHO unidentified unidentified unidentified unidentified unidentified unidentified g⫺CH3 CH2 OH CH3 CCH CH3 CCH CH3 CCH CH3 CCH CH3 CCH C5 H
⌸ 1/2 J⫽73/2⫺71/2 e
10共⫺2,9兲⫺10共1,9兲 E 4共1兲⫺3共1兲 A⫺ 2共1,2兲⫺1共0,1兲 11共0,11兲⫺10共0,10兲
2
⌸ 1/2 J⫽43/2⫺41/2 e
Xu_97 Lin79
Pea97
U
102640. 102642.4共7兲
unidentified C5 H
U U
102644. 102650. 102658.096*共18兲 102690.055*共3兲 102734.338*共34兲
unidentified unidentified CH3 OH SO2 CH3 OCHO
11共⫺2,10兲⫺11共1,10兲 E 33共8,26兲⫺34共7,27兲 16共5,11兲⫺16共4,12兲 E
102736.773*共37兲
CH3 OCHO
16共5,11兲⫺16共4,12兲 A
102807.354*共76兲
H2 C34S SiC3 CH3 OH H2 CCC
3共1,2兲⫺2共1,1兲
0.12b 0.02
9共0,9兲⫺8共0,8兲 15共⫺2,13兲⫺16共⫺3,13兲 E
0.006 0.12
IRC⫹10216 OriMC⫺1
NRAO 12 m NRAO 11 m
App99 Tur89
5共1,5兲⫺4共1,4兲
0.230
TMC⫺1 SgrB2共M兲
IRAM 30 m NRAO 11 m
Cer91 Tur89
SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲
NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m
Got78a Van84 Tur89 Tur89 Tur89 Tur89
SgrB2共M兲 SgrB2共M兲 OriMC⫺1 IRC⫹10216
NRAO 11 m BTL 7 m NRAO 11 m IRAM 30 m
Tur89 Cum86 Tur89 Yam87b
Yam87b
NRAO 11 m FCRAO 14 m
Tur89 Tha85
Yam90a Yam90a
102916.085*共21兲 102957.99* 共11兲 102992.345*共32兲 U
103028.
unidentified
U U
103040.416*共35兲 103051.791*共34兲 103071. 103075.
H2 CS H2 CS unidentified unidentified CH3 OCHO NH2 D
U U U U
U
103114.824*共56兲 103188.64*共10兲 103196. 103216.6共12兲 103227. 103266.0共3兲
unidentified unidentified unidentified C4 H
103297. 103319.278*共20兲
unidentified l⫺C3 H
103319.818*共20兲
l⫺C3 H
103328.
unidentified
2
⌸ 1/2 J⫽43/2⫺41/2 f
3共0,3兲⫺2共0,2兲 3共2,1兲⫺2共2,0兲
21共4,17兲⫺21共3,18兲A 8共3,6兲⫺8共2,6兲U
1.0f 0.05 0.07 0.15 0.07 b
0.03b 0.2 0.13 0.02 0.02 0.05 0.01 0.03 0.04 0.03
2
⌸ 1/2 J⫽21/2⫺19/2 v7 ⫽1e
2.75f 0.05
2
⌸ 3/2 J⫽9/2⫺7/2 F⫽5⫺4f
0.054b
SgrB2共M兲 IRC⫹10216
2
⌸ 3/2 J⫽9/2⫺7/2 F⫽4⫺3f
b
IRC⫹10216
FCRAO 14 m
Tha85
OriMC⫺1
NRAO 11 m
Tur89
0.03
Oes99
Xu_97
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
224
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
0.078b
IRC⫹10216
FCRAO 14 m
Tha85
Yam90a
103373.129*共20兲
l⫺C3 H
2
b
IRC⫹10216
FCRAO 14 m
Tha85
Yam90a
103376.784*共37兲 103381.209*共19兲 103387.227*共34兲
CH3 OCHO CH3 OH CH3 OCHO
⌸ 3/2 J⫽9/2⫺7/2 F⫽4⫺3e 24共6,18兲⫺24共5,17兲A 12共⫺2,11兲⫺12共1,11兲E 24共6,18兲⫺24共5,17兲E
SgrB2共N兲 OriMC⫺1 SgrB2共N兲
NRAO 12 m NRAO 11 m NRAO 12 m
Hol00 Tur89 Hol00
Xu_97
103391.283*共10兲
CH2 OHCHO
10共0,10兲⫺9共1,9兲
b
103466.479*共25兲 103478.699*共25兲 103525.2共5兲
CH3 OCHO CH3 OCHO
8共2,6兲⫺7共2,5兲E 8共2,6兲⫺7共2,5兲A
0.07 0.04
2
0.06 0.07 0.06b
SgrB2共N兲
NRAO 12 m
Hol00
But01
BTL 7 m BTL 7 m IRAM 30 m
Cum86 Cum86 Gue95
Oes99 Oes99 Gue95 Gue95
26
MgNC
17/2,9⫺15/2,8
0.34f
SgrB2共M兲 SgrB2共M兲 IRC⫹10216
26
MgNC
19/2,9⫺17/2,8
0.36f
IRC⫹10216
IRAM 30 m
Gue95
11共0,11兲⫺10共0,10兲
0.04 0.07
SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m
Cum86 Cum86
0.10
IRC⫹10216
IRAM 30 m
Cer87b
Yam87b
0.05 0.025 0.04
SgrB2共M兲 SgrB2共N兲 OriMC⫺1
BTL 7 m NRAO 12 m NRAO 11 m
Cum86 Hol00 Tur89
But01
Cum86
unidentified CH2 CHCN C4 H
103640.754*共8兲 103667.907*共10兲 103699.756*共3兲 103702.897*共21兲
CCS CH2 OHCHO SO2
⌸1/2 J⫽21/2⫺19/2 v7 ⫽1f 8,8⫺7,7 10共1,9兲⫺9共2,8兲 7共3,5兲⫺8共2,6兲 v2 ⫽1
t⫺CH3 CH2 OH
9共1,8兲⫺8共2,7兲
0.04
SgrB2共M兲
BTL 7 m
s⫺CH2 CHOH unidentified HC5 N CH3 CH2 CN unidentified C6 H
3共1,3兲⫺2共0,2兲
0.049
SgrB2共N兲
NRAO 12 m
Tur01
39⫺38 21共1,20兲⫺21共0,21兲
0.10 0.05 0.03 0.01
2
⌸3/2 J⫽75/2⫺73/2e
1.25f
SgrB2共M兲 SgrB2共M兲 SgrB2 OriMC⫺1 IRC⫹10216
NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Cum86 Tur89 Tur89 Cer87a
JPL01
2
0.90f 3.0
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Hol76a Cer87b
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m
Joh77 Kui77 Tur89
Xu_97 Gro98
103714. 103836.808*共4兲 103867.284*共25兲 103932. 103952.13*共9兲
2
103988.91*共9兲
C6 H
104029.410*共3兲 104048.451*共5兲
SO2 CCCS
⌸3/2 J⫽75/2⫺73/2f 3共1,3兲⫺2共0,2兲 18⫺17
104051.278*共9兲 104060.717*共19兲 104175.867*共6兲
CH3 CH2 CN CH3 OH CH3 OCH3
12共1,12兲⫺11共1,11兲 13共⫺3,11兲⫺12共⫺4,9兲E 17共2,15兲⫺17共1,16兲EA⫹AE
104177.378*共6兲
CH3 OCH3
17共2,15兲⫺17共1,16兲EE
0.09b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
104178.889*共6兲
CH3 OCH3
17共2,15兲⫺17共1,16兲AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
104187.114*共19兲
c⫺C3 HD
3共0,3兲⫺2共1,2兲
0.39
TMC⫺1
NRAO 12 m
Ger87
104189.709*共59兲
Na35Cl CH2 DCN CH2 CHCN SO2 CH3 OH CH3 OH CH3 OH
8⫺7
1.24f 0.07 0.06 0.29
IRC⫹10216
IRAM 30 m
Cer87c
6共2,4兲⫺5共2,3兲 11共2,10兲⫺10共2,9兲 10共1,9兲⫺10共0,10兲
SgrB2 SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m BTL 7 m
Cum86 Cum86 Cum86
11共⫺1,11兲⫺10共⫺2,9兲E 13共⫺2,12兲⫺13共1,12兲E 10共4,7兲⫺11共3,8兲A⫺ 10共1,9兲⫺10共0,10兲
0.12 0.03 0.06 0.04
SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲
BTL 7 BTL 7 BTL 7 BTL 7
m m m m
Cum86 Cum86 Cum86 Cum86
34
SO2
2.1f 0.08 0.2
104408.903*共13兲
CH2 CHCN
11共5,*兲⫺10共5,*兲
0.08b
SgrB2共M兲
BTL 7 m
Cum86
104410.489*共17兲
CH3 OH
10共4,6兲⫺11共3,9兲A⫹
b
SgrB2共M兲
BTL 7 m
Cum86
104411.262*共13兲
CH2 CHCN
11共4,8兲⫺10共4,7兲
b
SgrB2共M兲
BTL 7 m
Cum86
Xu_97 Xu_97 Xu_97
Xu_97
104411.485*共13兲
CH2 CHCN
11共4,7兲⫺10共4,6兲
b
SgrB2共M兲
BTL 7 m
Cum86
104419.308*共15兲
CH2 CHCN
11共6,*兲⫺10共6,*兲
b
SgrB2共M兲
BTL 7 m
Cum86
104425. 104432.793*共15兲
unidentified CH2 CHCN
0.08 11共3,9兲⫺10共3,8兲
0.04b
SgrB2共M兲 SgrB2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
104437.516*共17兲
CH2 CHCN
11共7,*兲⫺10共7,*兲
b
SgrB2共M兲
BTL 7 m
Cum86
104453.927*共15兲 104477.51*共30兲 104487.254*共16兲
CH2 CHCN CH3 OD
11共3,8兲⫺10共3,7兲 4共2,2兲⫺5共1,5兲A⫹
0.06 0.10
SgrB2共M兲 SgrB2共M兲
BTL 7 m NRAO 11 m
Cum86 Tur89
t⫺CH3 CH2 OH
7共0,7兲⫺6共1,6兲
0.20
SgrB2共M兲
BTL 7 m
Cum86
0.05
SgrB2共M兲 SgrB2共M兲
NRAO 11 m NRAO 11 m
Tur89 Lis78
3共1,2兲⫺2共1,1兲 23/2⫺21/2 3共1,2兲⫺2共2,1兲
0.15x 0.77 0.10 0.07
SgrB2共M兲 IRC⫹10216 SgrB2共N兲
NRAO 11 m NRAO 11 m NRO 45 m
Lis78 Gue78 Dic97
SgrB2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Tur89
Gro98
OriMC⫺1
NRAO 11 m
Tur89
Gro98
IRC⫹10216 OriMC⫺1
NRAO 11 m NRAO 11 m
Gue78 Tur89
Got83 Gro98
104531. 104589. 104666.56*共2兲 104688.654*共10兲
U
C5 H
103549.0共19兲 103575.401*共14兲 103576.5共3兲
104616.988*共33兲
U
Lab. Ref.
0.07
104336.637*共20兲 104354.861*共17兲 104391.703*共4兲
U U
Astr. Ref.
⌸ 3/2 J⫽9/2⫺7/2 F⫽5⫺4e
104201.180*共3兲 104212.655*共12兲 104239.293*共3兲 104300.396*共16兲
U
Telescope
2
103705.964*共44兲
U
Source
l⫺C3 H
103540.2共5兲
U
⌸ 3/2 J⫽45/2⫺43/2
T r 共K兲/T a 共K兲
103372.506*共20兲
103330.共1兲
U
Quantum numbers
unidentified unidentified H2 CS C4 H
104696. 104700.574*共20兲
c⫺C2 H4 O unidentified CH3 OCH3
7共2,6兲⫺7共1,7兲AE⫹EA
104703.253*共4兲
CH3 OCH3
7共2,6兲⫺7共1,7兲EE
104705.10*共2兲 104705.932*共8兲
C4 H CH3 OCH3
21/2⫺19/2 7共2,6兲⫺7共1,7兲AA
104711.398*共2兲
0.04 b
0.08b 0.10 b
13C18O unidentified
1⫺0
n.r.
OriMC⫺2
NRAO 11 m
Wan76
104720. 104798.888*共36兲
a⫺CH2 CHOH
19共1,9兲⫺10共0,10兲
0.07 0.05
SgrB2共M兲 SgrB2
NRAO 11 m NRAO 11 m
Tur89 Tur89
104808.618*共15兲
t⫺CH3 CH2 OH
5共1,5兲⫺4共0,4兲
0.18
SgrB2共M兲
NRAO 11 m
Zuc75
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
And88
Got83
MICROWAVE TRANSITIONS
225
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
104819. 104873.45*共1兲 104891.35*共18兲 104915.562*共26兲 104960.550*共16兲 105011.1共3兲 105022.583*共71兲
U
105027. 105036.99共5兲 105059.202*共20兲 105063.761*共30兲 105121.98*共2兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
7共0,7兲⫺6共1,6兲 93⫺92 5共1,4兲⫺4共1,3兲
0.02 0.12 0.09 0.257
SgrB2共M兲 SgrB2 SgrB2共M兲 TMC⫺1
NRAO 11 m BTL 7 m NRAO 11 m IRAM 30 m
Tur89 Cum86 Tur89 Cer91
0.06
SgrB2共M兲 IRC⫹10216
BTL 7 m IRAM 30 m
Cum86 Gue00
OriMC⫺1
NRAO 11 m
Tur89
OriMC⫺1 OriMC⫺1
NRAO 11 m IRAM 30 m
Tur89 Jac92 Gue00
unidentified HCOOH HC7 N H2 CCC CH2 CHCN H2 CCCCCC
11共2,9兲⫺10共2,8兲 39共1,38兲⫺38共1,37兲 25共6,20兲⫺24共7,17兲
t⫺CH3 CH2 OH unidentified CH2 DOH
0.06f 0.04 0.05
Wil80
7共1,6兲⫺7共0,7兲
0.8f
6⫺5
IRC⫹10216
IRAM 30 m
13共1,13兲⫺12共2,10兲A⫹
4.75f 0.55
OriMC⫺1
FCRAO 14 m
Gol83
Xu_97
2
⌸1/2 J⫽19/2⫺17/2e
0.13f
IRC⫹10216
IRAM 30 m
Gue00
App00
2
30
SiS CH3 OH SiCN
Lab. Ref.
Jac93
105146.68*共2兲
SiCN
⌸1/2 J⫽19/2⫺17/2f
0.14f
IRC⫹10216
IRAM 30 m
Gue00
App00
105174.58共20兲
C4 H
2⌺ J⫽11⫺10 v7 ⫽2L
0.15
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
C4 H
2⌺ J⫽11⫺10 v7 ⫽2U
0.15
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
17共2,15兲⫺17共1,16兲
0.04 0.04
OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m
Tur89 Tur89
0.05 0.31 0.2 0.05 0.05
OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1
NRAO 11 m BTL 7 m NRAO 11 m OSO 20 m BTL 7 m NRAO 11 m
Tur89 Cum86 Kui77 Joh84 Fre79 Kui77
Xu_97
OSO 20 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m OSO 20 m
Joh84 Tur89 Tur89 Tur89 Tur89 Tur89 Joh84
Gro98
105230.65共20兲 U
105278. 105355.629*共22兲
U
105412. 105464.216*共1兲 105469.300*共9兲 105540. 105558.077*共4兲 105576.385*共21兲
t⫺CH3 CH2 OH unidentified NH2 CHO CH3 CH2 CN unidentified HNCS CH3 OH
105590. 105610. 105618. 105728. 105739. 105743.859*共3兲 105768.276*共8兲
unidentified unidentified unidentified unidentified unidentified HNCS CH3 OCH3
9共1,8兲⫺8共1,7兲 13共1,12兲⫺13共0,13兲EA⫹AE
b
OriMC⫺1 SgrB2共M兲 SgrB2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
105770.340*共6兲
CH3 OCH3
13共1,12兲⫺13共0,13兲EE
0.20b
OriMC⫺1
OSO 20 m
Joh84
Gro98
105772.403*共10兲
CH3 OCH3
13共1,12兲⫺13共0,13兲AA
b
OriMC⫺1
OSO 20 m
Joh84
Gro98
105787. 105794.057*共58兲
unidentified CH2 NH
0.02 4共0,4兲⫺3共1,3兲
OriMC⫺1 SgrB2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
105799.093*共10兲
H13CCCN
12⫺11
b
SgrB2共M兲
BTL 7 m
Cum86
105799.093*共10兲
H13CCCN C4 H
12⫺11
0.10
OriMC⫺1
OSO 20 m
Joh84
Laf78
⌸3/2 J⫽23/2⫺21/2 v7 ⫽1e 1⫺0
3.50f 0.002
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
IRC⫹10216
BTL 7 m
Wri94
Ros58
6⫺5
0.12
IRC⫹10216
BTL 7 m
Wri94
Tie76
5共2,4兲⫺4共2,3兲 12⫺11
0.1o 2.8f
SgrB2共M兲 G10.47⫹0.03
NRAO 11 m PdBI Array
Got78a Wyr99
Wyr99
12⫺11 v7 ⫽1ᐉ⫽1e
5.3f
G10.47⫹0.03
PdBI Array
Wyr99
Wyr99
3.10f
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
0.10b
SgrB2共M兲
BTL 7 m
Cum86
b
SgrB2共M兲
BTL 7 m
Cum86
OriMC⫺1 G10.47⫹0.03
NRAO 11 m PdBI Array
Tur89 Wyr99
BTL 7 m NRAO 11 m SEST 15 m
Cum86 Tur89 Ger89
U
U U U U U
U
105838.0共3兲 105871.110共4兲 105941.503*共24兲
U
U
14
5共0,5兲⫺4共0,4兲 12共0,12兲⫺11共0,11兲 9共0,9兲⫺8共0,8兲 14共⫺2,13兲⫺14共1,13兲E
2
CO
105972.593*共1兲
Si34S NH2 CHO
105998.3*共10兲
HCCC15N
106062.3*共10兲
H13CCCN C4 H
106134.418*共2兲
NH2 CHO
⌸3/2 J⫽23/2⫺21/2 v7 ⫽1f 5共3,3兲⫺4共3,2兲
106141.391*共2兲
NH2 CHO
5共3,2兲⫺4共3,1兲
106156. 106210.5*共10兲
unidentified
106132.8共3兲
U
unidentified
106347.740*共13兲 106367. 106374.247*共7兲
H13CCCN CCS unidentified
106386. 106474.1*共10兲
unidentified
106498.910*共4兲 106541.674*共1兲 106641.394*共17兲 106723.494*共17兲 106743.374*共18兲
12⫺11 v7 ⫽1ᐉ⫽1f
SO2
CH3 CH2 CN
9,8⫺8,7
3.8f 0.19 0.04
33共5,27兲⫺32共6,26兲
0.03b
SgrB2共M兲 OriMC⫺1 OMC⫺IRc2
b
OMC⫺IRc2
SEST 15 m
Ger89
OriMC⫺1 G10.47⫹0.03
NRAO 11 m PdBI Array
Tur89 Wyr99 Tur87b
15共3,12兲⫺12共2,13兲
0.03
H13CCCN
12⫺11 v7 ⫽2
9.5f
HOCO⫹ HC5 N
5共1,5兲⫺4共1,4兲
b
SgrB2共M兲
NRAO 12 m
40⫺39
0.04b
SgrB2共M兲
NRAO 12 m
Tur87b
NH2 CHO CH2 CHCN
5共2,3兲⫺4共2,2兲 11共1,10兲⫺10共1,9兲 9共2,8兲⫺9共1,9兲
0.15 0.05 0.06
SgrB2共M兲 SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m BTL 7 m
Cum86 Cum86 Cum86
t⫺CH3 CH2 OH 34
106762.47*共9兲
SO C6 H
106775.679*共8兲
CH3 OCH3
2
Wyr99
0.16d
OriMC⫺1
NRAO 11 m
Got78
1.00f
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
0.05b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
0.089
SgrB2共M兲
BTL 7 m
Gol81
SgrB2共M兲
BTL 7 m
Tha81
IRC⫹10216
BTL 7 m
Hen85
CH3 OCH3
9共1,8兲⫺8共2,7兲EE
CH3 OCH3
9共1,8兲⫺8共2,7兲EA⫹AE
106787.388*共2兲
OC34 S
9⫺8
106913.524*共25兲
HOCO⫹
5共0,5兲⫺4共0,4兲
SiS
Wyr99
2共3兲⫺1共2兲
106779.062*共14兲
29
Laf78
⌸3/2 J⫽77/2⫺75/2f 9共1,8兲⫺8共2,7兲AA
106777.371*共6兲
106922.973*共11兲
0.27b
0.04
34
106375.018*共11兲
106493.936*共43兲
2
0.22 0.15 0.05 0.03 0.02 0.05 0.13
6⫺5
0.4 0.012
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
226
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U U
U
U U
106942. 106949.482*共20兲 106963. 106981. 106995. 107013.770*共13兲 107043.521*共9兲 107060.225*共3兲 107103.2 107159.915*共23兲
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
3共1,3兲⫺2共0,2兲
0.03 0.034
OriMC⫺1 SgrB2共N兲
NRAO 11 m NRAO 12 m
Tur89 Tur01
0.02 0.06 0.08 4.5 0.05 0.07 0.08
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 SgrB2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m NRAO 11 m FCRAO 14 m BTL 7 m BTL 7 m IRAM 30 m
Tur89 Tur89 Tur89 Gol83 Cum86 Cum86 Com96
unidentified a⫺CH2 CHOH unidentified unidentified unidentified CH3 OH CH3 CH2 CN SO2 unidentified CH3 OH
3共1,3兲⫺4共0,4兲A⫹ 12共2,11兲⫺11共2,10兲 27共3,25兲⫺26共4,22兲
13
CH3 CN
15共⫺2,14兲⫺15共1,14兲E 6共4兲⫺5共4兲
0.31
107164.298*共16兲
0.9f
OriMC⫺1 G10.47
NRAO 11 m IRAM 30 m
Tur89 Olm96
CH3 CN
6共3兲⫺5共3兲
0.04b
SgrB2共M兲
BTL 7 m
Cum86
13
CH3 CN
6共2兲⫺5共2兲
b
SgrB2共M兲
BTL 7 m
Cum86
107194.547*共17兲
13
CH3 CN
6共1兲⫺5共1兲
b
SgrB2共M兲
BTL 7 m
Cum86
107196.564*共17兲
13
6共0兲⫺5共0兲
0.07b 0.10 0.06 0.029
SgrB2共M兲
BTL 7 m
Cum86
OriMC⫺1 OriMC⫺1 rhoOphC
NRAO 11 m IRAM 30 m SEST 15 m
Tur89 Com96 Ben01
5共1,4兲⫺4共1,3兲
b
SgrB2共M兲
NRAO 12 m
Tur87b
3共⫺1兲⫺3共0兲A
SgrB2共M兲
BTL 7 m
Cum86
OriMC⫺1 OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m
Com96 Com96 Gue93
Kaw93 Kaw93
107207. 107258.8 107288.948*共4兲
107350.0 107367.3 107384.201*共10兲
CH3 CN unidentified unidentified 13
1⫺0
C17O
HOCO⫹ CH3 SH
17/2,9⫺15/2,8
0.04b 0.03 0.03 2.8
MgNC unidentified unidentified
19/2,9⫺17/2,8
2.6
IRC⫹10216
IRAM 30 m
Gue93
3共1,3兲⫺2共0,2兲
0.06 n.r. 0.5
SgrB2共N兲 OriMC⫺1 TMC⫺1
SEST 15m IRAM 30 m IRAM 30 m
Dic01 Com96 Ger87
0.02
unidentified unidentified 24
MgNC
24
U U
107404.2 107406.5 107423.655*共19兲
U
107426. 107454.09*共22兲
c⫺C3 HD unidentified C6 H
107481.465*共15兲
0.66f
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Cer87a
CH3 CH2 CN
⌸1/2 J⫽77/2⫺75/2e 17共2,16兲⫺17共1,17兲
0.10b
SgrB2共OH兲
IRAM 30 m
Gom86
2
107485.181*共7兲
CH3 CH2 CN
12共7,*兲⫺11共7,*兲
0.05b
SgrB2共M兲
BTL 7 m
Cum86
107486.962*共8兲
CH3 CH2 CN
12共6,*兲⫺11共6,*兲
b
SgrB2共M兲
BTL 7 m
Cum86
107491.579*共7兲
CH3 CH2 CN
12共8,*兲⫺11共8,*兲
b
SgrB2共M兲
BTL 7 m
Cum86
107502.426*共8兲
CH3 CH2 CN
12共5,8兲⫺11共5,7兲
0.05b
SgrB2共M兲
BTL 7 m
Cum86
107502.473*共8兲
CH3 CH2 CN
12共5,7兲⫺11共5,6兲
b
SgrB2共M兲
BTL 7 m
Cum86
107507.90*共24兲
C6 H
0.58f
IRC⫹10216
IRAM 30 m
Cer87a
U
107516. 107519.944*共7兲
unidentified CH3 CH2 CN
0.03 12共10,*兲⫺11共10,*兲
SgrB2共M兲 G34.3⫹02
BTL 7 m BIMA Array
Cum86 Meh96
U
107520. 107537.189*共25兲
unidentified CH3 OCHO
9共2,8兲⫺8共2,7兲E
b
SgrB2共N兲 SgrB2共M兲
BIMA Array BTL 7 m
Sny94 Cum86
107539.857*共7兲
CH3 CH2 CN
12共11,*兲⫺11共11,*兲
0.7e
G34.3⫹02
BIMA Array
Meh96
U
U U U U U U
2
⌸1/2 J⫽77/2⫺75/2f
0.7e n.r.
107543.746*共25兲
CH3 OCHO
9共2,8兲⫺8共2,7兲A
0.07b
SgrB2共M兲
BTL 7 m
Cum86
107543.924*共8兲
CH3 CH2 CN
12共4,9兲⫺11共4,8兲
b
SgrB2共M兲
BTL 7 m
Cum86
107547.599*共8兲
CH3 CH2 CN
12共4,8兲⫺11共4,7兲
107574.6 107594.046*共9兲 107604.
unidentified CH3 CH2 CN unidentified
107611.54*共14兲
K35Cl H2 CCCC CH3 CH2 CN unidentified SO2
107622.956*共23兲 107734.738*共9兲 107751. 107843.478*共2兲 107971.65*共20兲
U
Xu_97
13
107399.420*共10兲
U
Xu_97
107178.410*共16兲
107316.46*共10兲
U
Lab. Ref.
107188.495*共16兲
107315.359*共49兲
U U
Formula
108024. 108126.71*共1兲 108210.388*共11兲 108216. 108255. 108394.288*共8兲 108412.3 108426.9 108444.2 108453. 108471.967*共38兲 108514.40*共24兲 108651.297共50兲 108657.646共50兲
Si13CC unidentified HCOOH CH3 CH2 CN unidentified unidentified SiS unidentified unidentified unidentified unidentified NaCN SiC2
12共3,10兲⫺11共3,9兲
12共1,11兲⫺11共1,10兲 12共3,9兲⫺11共3,8兲 12共4,8兲⫺13共3,11兲 5共1,4兲⫺4共1,4兲
SgrB2共M兲
BTL 7 m
Cum86
IRAM 30 m BTL 7 m NRAO 11 m
Com96 Cum86 Tur89
IRC⫹10216
IRAM 30 m
Cer87c
0.6f
IRC⫹10216 SgrB2共M兲 OriMC⫺1 SgrB2共M兲 IRC⫹10216
IRAM 30 m BTL 7 m NRAO 11 m BTL 7 m IRAM 30 m
Cer91a Cum86 Tur89 Cum86 Cer91b
OriMC⫺1 SgrB2共M兲 SgrB2 OriMC⫺1 OriMC⫺1 IRC⫹10216 IRC⫹10216 IRC⫹10216 IRC⫹10216 SgrB2共M兲 IRC⫹10216 IRC⫹10216 SgrB2共M兲
NRAO 11 m BTL 7 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m NRAO 11 m NRAO 12 m NRAO 12 m BTL 7 m
Tur89 Cum86 Tur89 Tur89 Tur89 Tur94 Tur94 Tur94 Tur94 Tur89 Tur94 Gen97 Ger84
Tur94 Bog91 Bog84a
SgrB2共M兲
BTL 7 m
Ger84
Bog84a
0.25f 0.103 0.04 0.02 0.06
CN
1/2⫺1/2 F⫽2⫺1, F 1 ⫽0, F 2 ⫽1⫺0
13
CN
1/2⫺1/2 F⫽2⫺2, F 1 ⫽1, F 2 ⫽1⫺1
0.07b
7共0,7兲⫺6共0,6兲 5共1,5兲⫺4共1,4兲 v3 ⫽1
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Oes99
OriMC⫺1 SgrB2共M兲 SgrB2共M兲
13
6⫺5 v⫽1
Oes99
b
0.15 0.06 0.08 0.07 0.07 0.012 0.012 0.020 0.012 0.03 0.013 0.002 0.07
5共1,5兲⫺4共1,4兲 11共1,11兲⫺10共0,10兲
JPL01
0.04 0.06 0.02b
14⫺13
JPL01
Kil90
Wil80
MICROWAVE TRANSITIONS
227
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 108658.948共50兲
U
Formula
SgrB2共M兲
BTL 7 m
Ger84
Bog84a
SgrB2共M兲
BTL 7 m
Cum86
Laf78
108721.008*共7兲
HCC13CN unidentified
12⫺11
0.15
SgrB2共M兲
BTL 7 m
Cum86
Laf78
0.035
FCRAO 14 m BTL 7 m
Ziu88 Ger84
Bog84a
108778. 108780.201共50兲
13
CN
3/2⫺1/2 F⫽3⫺2, F 1 ⫽1, F 2 ⫽2⫺1
0.13b
OriMC⫺1 SgrB2共M兲
108782.374共50兲
13
CN
3/2⫺1/2 F⫽2⫺1, F 1 ⫽1, F 2 ⫽2⫺1
b
SgrB2共M兲
BTL 7 m
Ger84
Bog84a
108786.982共50兲
13
CN
3/2⫺1/2 F⫽1⫺0, F 1 ⫽1, F 2 ⫽2⫺1
b
SgrB2共M兲
BTL 7 m
Ger84
Bog84a
108793.753共50兲
13
CN
3/2⫺1/2 F⫽1⫺1
b
SgrB2共OH兲
NRAO 12 m
Sav02
Bog84a
0.04
FCRAO 14 m NRAO 12 m
Ziu88 Sav02
Bog84a
unidentified CH2 CHCN CCCN CCCN
108853.02*共3兲 108866. 108883.548*共58兲 108893.929*共15兲 108909. 108924.288*共8兲 108940.596*共9兲 108955.895*共4兲 108987. 108998. 109008.67*共3兲 109012. U109018. 109023.3*共4兲
13
CN
unidentified CH3 OCHO CH3 OH unidentified SiS CH3 CH2 CN SO2 unidentified unidentified DCOOH unidentified unidentified HCCCN
3/2⫺1/2 F⫽2⫺2
0.04b
OriMC⫺1 SgrB2共OH兲
20共1,19兲⫺20共0,20兲 11⫺10 J⫽23/2⫺21/2
0.025 0.02 0.45
OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m OSO 20 m
Ziu88 Ziu88 Joh84
Got83
11⫺10 J⫽21/2⫺19/2
0.45
IRC⫹10216
OSO 20 m
Joh84
Got83
0.02 0.02 0.98 0.01 0.28 0.24
Ori⫺S OriMC⫺1 SgrB2共M兲 Ori⫺S IRC⫹10216 OriMC⫺1
NRAO 12 m FCRAO 14 m BTL 7 m NRAO 12 m NRAO 11 m FCRAO 14 m
Ziu91a Ziu88 Cum86 Ziu91a Mor75 Ziu88
0.05 0.01 0.02 0.04 0.02 0.15
SgrB2共M兲 Ori⫺S OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 G10.47⫹0.03
NRAO 12 m NRAO 12 m FCRAO 14 m NRAO 11 m FCRAO 14 m NRAO 11 m PdBI Array
Ziu91a Ziu91a Ziu88 Tur89 Ziu88 Tur89 Wyr99
OriMC⫺1 SgrB2共M兲
FCRAO 14 m BTL 7 m
Ziu88 Cum86
14共3,12兲⫺14共2,13兲A 0共0,0兲⫺1共⫺1,1兲E 6⫺5 12共2,10兲⫺11共2,9兲 39共6,34兲⫺38共7,31兲
9共1,8兲⫺9共0,9兲
12⫺11 v4 ⫽1
Oes99 Xu_97
Wil80
Wyr99
O13CS
12共1,11兲⫺11共1,10兲 9⫺8
5.0f 0.02 0.08
12⫺11 v7 ⫽1 ᐉ⫽1 f
6.3f
G10.47⫹0.03
PdBI Array
Wyr99
Wyr99
109153.210*共28兲 109160.983*共4兲 109173.638*共4兲 109182.946*共81兲
HC13CCN CH3 OH CH3 OH HC5 N HCCCN HCCCN
26共0,26兲⫺26共⫺1,26兲 E 16共⫺2,15兲⫺16共1,15兲 E 41⫺40 12⫺11 12⫺11 v5 ⫽1ᐉ⫽1e
0.3 0.3 0.018 2.57
OriMC⫺1 OriMC⫺1 IRC⫹10216 SgrB2共M兲 G10.47⫹0.03
FCRAO 14 m FCRAO 14 m NRAO 11 m NRAO 11 m IRAM 30 m
Gol82 Gol82 Jew84 Mor76 Wyr99
Xu_97 Xu_97
109244.339*共84兲
HCCCN
12⫺11 v5 ⫽1ᐉ⫽1f
G10.47⫹0.03
IRAM 30 m
Wyr99
Laf78
109252.212*共12兲 109292.081*共32兲 109302.206*共34兲
SO CH3 OCHO CH3 OCHO
2共3兲⫺1共2兲 10共1,9兲⫺9共2,8兲E
2.4f 2.42m 0.1
OriMC⫺1 OriMC⫺1
MMWO 4.9 m NRAO 11 m
Got78 Tur89
Oes99
0.22
OriMC⫺1 G10.47⫹0.03
NRAO 11 m IRAM 30 m
Tur89 Wyr99
Oes99 Wyr99
FCRAO 14 m PdBI Array
Gol85 Wyr99
Laf78 Wyr99
109092.761*共4兲 109110.844*共4兲
CH2 CHCHO
109125.8*共10兲 109137.57*共17兲
109306.7*共4兲
U U
Lab. Ref.
b
108802. 108813.575*共52兲 108834.27*共3兲
U U
Astr. Ref.
0.15
CN
U
U
Telescope
12⫺11
13
unidentified
U U
Source
HC13CCN
108796. 108796.400共50兲
U
1/2⫺1/2 F⫽1⫺2, F 1 ⫽1, F 2 ⫽1⫺1
T r 共K兲/T a 共K兲
108710.523*共11兲
U
U
Quantum numbers
HCCCN
109352.726*共38兲 109383.4*共10兲
HC13CCN
HCCCN
109401.9*共10兲
10共1,9兲⫺9共2,8兲A 12⫺11 v4 ⫽1 v7 ⫽1ᐉ⫽1e⫺
2.0f
0.6f 0.02
12⫺11 v6 ⫽1ᐉ⫽1e 12⫺11 v7 ⫽2
5.7f
OriMC⫺1 G10.47⫹0.03
6.3f
Laf78
HCC13CN
12⫺11 v7 ⫽2
G10.47⫹0.03
PdBI Array
Wyr99
Wyr99
109438.572*共49兲
HCCCN
12⫺11 v6 ⫽1ᐉ⫽1f
0.02b
OriMC⫺1
FCRAO 14 m
Gol85
Laf78
109441.944*共30兲
HCCCN
0.13
109441.944*共30兲
HCCCN
12⫺11 v7 ⫽1ᐉ⫽1e 12⫺11 v7 ⫽1ᐉ⫽1e
OriMC⫺1 G10.47⫹0.03
FCRAO 14 m IRAM 30 m
Gol82 Wyr99
Laf78 Laf78
109463.063*共1兲 109469.4*共4兲
OCS HCCCN
9⫺8 12⫺11 v4 ⫽1 v7 ⫽1ᐉ⫽1f⫹
SgrB2共M兲 G10.47⫹0.03
NRAO 11 m IRAM 30 m
Jef71 Wyr99
Wyr99
109496.007*共4兲
HNCO
5共1,5兲⫺4共1,4兲 12⫺11 v6 ⫽2ᐉ⫽0
OriMC⫺1 G10.47⫹0.03
FCRAO 14 m IRAM 30 m
Gol82 Wyr99
Wyr99
NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Wyr99
Wyr99
7.1f 0.70 0.6f 0.16
109522.5*共10兲
HCCCN
109530. 109538. 109549.5*共3兲
unidentified unidentified HCCCN
12⫺11 v5 ⫽1 v7 ⫽1ᐉ⫽0f⫹
1.1f
OriMC⫺1 OriMC⫺1 G10.47⫹0.03
109552.1*共3兲
HCCCN
12⫺11 v5 ⫽1 v7 ⫽1ᐉ⫽2f⫹
1.3f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
109558.0*共40兲
HCCCN
12⫺11 v5 ⫽1 v7 ⫽1ᐉ⫽0e⫺
1.3f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
109563.7*共30兲
HCCCN
12⫺11 v5 ⫽1 v7 ⫽1ᐉ⫽2e⫺
1.3f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
109571.390*共6兲
CH3 OCH3
8共2,7兲⫺8共1,8兲EA
b
OriMC⫺1
FCRAO 14 m
Gol85
Gro98
109571.398*共6兲
CH3 OCH3
8共2,7兲⫺8共1,8兲AE
0.10b
OriMC⫺1
FCRAO 14 m
Gol85
Gro98
109574.119*共4兲 109576.843*共8兲 109598.751*共30兲 109616.3*共2兲
CH3 OCH3 CH3 OCH3 HCCCN HCCCN
8共2,7兲⫺8共1,8兲EE 8共2,7兲⫺8共1,8兲AA 12⫺11 v7 ⫽1ᐉ⫽1f 12⫺11 v6 ⫽2ᐉ⫽2
0.16 0.12 0.19 1.1f
OriMC⫺1 OriMC⫺1 OriMC⫺1 G10.47⫹0.03
FCRAO 14 m FCRAO 14 m FCRAO 14 m IRAM 30 m
Gol85 Gol85 Gol85 Wyr99
Gro98 Gro98 Laf78 Wyr99
109650.301*共9兲
CH3 CH2 CN
12共1,11兲⫺11共1,10兲
109689.61共10兲
C15N unidentified unidentified NH2 CHO
1⫺0 J⫽1/2⫺1/2 F⫽1⫺1
0.07 0.10
OriMC⫺1 OriMC⫺1
NRAO 11 m KOSMA 3 m
Joh77 Sal94a
Sal94a
5共1,4兲⫺4共1,3兲
0.10 0.02 0.3
SgrB2共M兲 OriMC⫺1 SgrB2共M兲
NRAO 11 m FCRAO 14 m BTL 7 m
Tur89 Gol83 Lin81
109720. 109738.5 109753.499*共1兲
0.7f 0.08 0.10
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
228
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
109757.587*共2兲 109770.5 109771.918*共16兲
SO2 unidentified HCCN
17共5,13兲⫺18共4,14兲
0.30 0.03
6,5⫺5,4
FCRAO 14 m FCRAO 14 m IRAM 30 m
Gol82 Gol83 Gue91
109782.173*共2兲
1⫺0
109828.291*共5兲
C18O CCCS
1.0f 2.1
OriMC⫺1 OriMC⫺1 IRC⫹10216
19⫺18
2.7f
109833.489*共6兲
HNCO
5共3,2兲⫺4共3,1兲
109833.489*共6兲
HNCO
5共3,3兲⫺4共3,2兲
109861.999*共20兲
HCCN
5,5⫺4,4
109862.828*共46兲
HCCCN
12⫺11 v7 ⫽2ᐉ⫽0
109865.854*共55兲
HCCCN
12⫺11 v7 ⫽2ᐉ⫽2e
109870.188*共48兲
HCCCN
12⫺11 v7 ⫽2ᐉ⫽2f
109870.278
HNCO
5共1,5兲⫺4共1,4兲 v6 ⫽1
109872.366*共5兲
HNCO
5共2,4兲⫺4共2,3兲
109872.773*共5兲
HNCO
5共2,3兲⫺4共2,2兲
109905.753*共5兲 109990.0*共2兲
HNCO HCCCN
5共0,5兲⫺4共0,4兲 12⫺11 v6 ⫽1 v7 ⫽2ᐉ⫽1e⫺
110024.59共10兲
C15N HCCCN
1⫺0 J⫽1/2⫺1/2 F⫽2⫺1 12⫺11 v6 ⫽1 v7 ⫽2ᐉ ⫽⫺1f⫹ 4,5⫺3,4
110035.6*共2兲 110046.249*共22兲 110050.77*共9兲
12⫺11 v7 ⫽3ᐉ⫽1e 5共4兲⫺4共4兲 v5 ⫽1
OriMC⫺1
NRAO 11 m
Uli76
IRC⫹10216
IRAM 30 m
Cer87b
0.03b
OriMC⫺1
FCRAO 14 m
Gol82
b
OriMC⫺1
FCRAO 14 m
Gol82
IRC⫹10216
IRAM 30 m
Gue91
0.02b
OriMC⫺1
FCRAO 14 m
Gol83
b
OriMC⫺1
FCRAO 14 m
Gol83
Laf78
b
SgrB2共M兲
NRAO 11 m
Tur89
Laf78
b
Wyr99
0.4f
Laf78
G10.47⫹0.03
IRAM 30 m
Wyr99
0.09b
OriMC⫺1
FCRAO 14 m
Gol82
b
OriMC⫺1
FCRAO 14 m
Gol82
SgrB2共M兲 G10.47⫹0.03
NRAO 11 m IRAM 30 m
Sol73 Wyr99
Wyr99
OriMC⫺1
KOSMA 3 m
Sal94a
Sal94a
1.8f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
0.3f 0.10h
IRC⫹10216
IRAM 30 m
Gue91
0.3f
SgrB2共M兲 G10.47⫹0.03
NRAO 11 m IRAM 30 m
Tur89 Wyr99
Laf78 Wyr99
1.1 1.4f 0.18
110066.104
HNCO
110080.464
HNCO
5共3兲⫺4共3兲 v6 ⫽1
0.4f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
110084.368
HNCO
5共0,5兲⫺4共0,4兲 v5 ⫽1
0.8f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
110086.440
HNCO
5共0,5兲⫺4共0,4兲 v6 ⫽1
0.5f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
110089.690
HNCO
5共3兲⫺4共3兲 v5 ⫽1
0.5f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
HCCCN
12⫺11 v6 ⫽1 v7 ⫽2ᐉ⫽3
1.3f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
110104.112
HNCO
5共2,4兲⫺4共2,3兲 v5 ⫽1
0.5f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
110105.356
HNCO
5共2,3兲⫺4共2,2兲 v5 ⫽1
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
CH2 DOH HCCCN
9共1,8兲⫺9共0,9兲o1 12⫺11 v6 ⫽1 v7 ⫽2ᐉ ⫽⫺1e⫺
0.7f 0.05
IRAS16293⫺2422 G10.47⫹0.03
IRAM 30 m IRAM 30 m
Par02 Wyr99
Par02 Wyr99
110097.6*共2兲
110105.4 110148.8*共2兲
1.2f
110152.084共20兲
NH2 D
1共1,1兲0⫺⫺1共0,1兲0⫹ F⫽0⫺1
b
DR21共OH兲
OSO 20 m
Olb85
Bes83
110152.995共20兲
NH2 D
b
DR21共OH兲
OSO 20 m
Olb85
Bes83
110153.599共10兲 110153.599共10兲
NH2 D NH2 D
1共1,1兲0⫺⫺1共0,1兲0⫹ F⫽2⫺1 1共1,1兲0⫺⫺1共0,1兲0⫹
0.14
OriMC⫺1
NRAO 11 m
Kui78
Bes83
1共1,1兲0⫺⫺1共0,1兲0⫹ F⫽1⫺1
b
DR21共OH兲
OSO 20 m
Olb85
Bes83
110153.599共10兲
NH2 D
1共1,1兲0⫺⫺1共0,1兲0⫹ F⫽2⫺2
0.11b
DR21共OH兲
OSO 20 m
Olb85
Bes83
110154.222共20兲
NH2 D
1共1,1兲0⫺⫺1共0,1兲0⫹ F⫽1⫺2
b
DR21共OH兲
OSO 20 m
Olb85
Bes83
110155.053共20兲
NH2 D
b
DR21共OH兲
OSO 20 m
Olb85
Bes83
110164.245
HNCO
1共1,1兲0⫺⫺1共0,1兲0⫹ F⫽1⫺0 5共1,4兲⫺4共1,3兲 v6 ⫽1
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
0.6f
110188.860共50兲
CH3 OD
1共1,0兲⫺1共0,1兲E
0.5f
OriMC⫺1
IRAM 30 m
Mau88
And88
110189.8*共2兲
HCCCN
12⫺11 v6 ⫽1 v7 ⫽2ᐉ⫽1f⫹
1.8f 9.3
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
OriMC⫺1
NRAO 11 m
Uli76
2.2f
G10.47⫹0.03
IRAM 30 m
Wyr99
0.12
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur91 Cer87a
JPL01
OriMC⫺1
IRAM 30 m
Mau88
And88 JPL01
110201.353*共1兲 110211.4*共2兲 U
HCCN HCCCN
Lab. Ref.
13
1⫺0
CO
HCCCN
12⫺11 v7 ⫽3ᐉ⫽3
110240. 110244.03*共21兲
unidentified C6 H
2 ⌸1/2 J⫽79/2⫺77/2f
0.76f
110262.640共50兲
CH3 OD
2共1,1兲⫺2共0,2兲E
110298.098*共4兲 110299.19*共23兲
HNCO C6 H
2.0f 0.23
110309.847*共5兲
0.74f
SgrB2共M兲 IRC⫹10216
BTL 7 m IRAM 30 m
Cum86 Cer87a
CH3 13CN
2 ⌸1/2 J⫽79/2⫺77/2e 6共3兲⫺5共3兲
5共1,4兲⫺4共1,3兲
0.05
OriMC⫺1
NRAO 11 m
Tur89
Wyr99
110320.438*共5兲
CH3 13CN
6共2兲⫺5共2兲
3.0f
G10.47
IRAM 30 m
Olm96
110326.795*共5兲
CH3 13CN
6共1兲⫺5共1兲
b
SgrB2共M兲
BTL 7 m
Cum86
110328.914*共5兲
CH3 13CN CH3 CN
6共0兲⫺5共0兲
0.14b
SgrB2共M兲
BTL 7 m
Cum86
110330.627*共3兲
6共5兲⫺5共5兲 F⫽7⫺6
0.2bk
SgrB2共M兲
NRAO 11 m
Sol71
Bou80
110330.872*共2兲
CH3 CN
6共5兲⫺5共5兲 F⫽5⫺4
b
SgrB2共M兲
NRAO 11 m
Sol71
Bou80
110349.659*共2兲
CH3 CN
6共4兲⫺5共4兲 F⫽7⫺6
0.45b
SgrB2共M兲
NRAO 11 m
Sol73
Bou80
110349.797*共2兲
CH3 CN
6共4兲⫺5共4兲 F⫽5⫺4
b
SgrB2共M兲
NRAO 11 m
Sol73
Bou80
110364.469*共1兲
CH3 CN
6共3兲⫺5共3兲 F⫽7⫺6
0.31b
SgrB2共M兲
NRAO 11 m
Sol73
Bou80
110364.524*共1兲
CH3 CN
6共3兲⫺5共3兲 F⫽5⫺4
b
SgrB2共M兲
NRAO 11 m
Sol73
Bou80
110375.052*共1兲
CH3 CN
6共2兲⫺5共2兲 F⫽7⫺6
0.81
SgrB2共M兲
NRAO 11 m
Sol73
Bou80
110381.404*共1兲
CH3 CN
6共1兲⫺5共1兲 F⫽7⫺6
1.09b
SgrB2共M兲
NRAO 11 m
Sol73
Bou80
110383.522*共1兲
CH3 CN
SgrB2共M兲
NRAO 11 m
Sol73
Bou80
HCOOH CH3 OCHO
6共0兲⫺5共0兲 F⫽7⫺6 9共3,6兲⫺10共2,9兲 9共8,1兲⫺8共8,0兲A
b
110413.59*共2兲 110455.358*共29兲
0.04 0.06b
OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m
Tur89 Tur89
Wil80 Oes99
110455.358*共29兲
CH3 OCHO
9共8,2兲⫺8共8,1兲A
0.06b
SgrB2共M兲
NRAO 11 m
Tur89
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
229
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U U U
U
U
U U
U U U
U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
110457.971*共28兲
CH3 OCHO
9共8,2兲⫺8共8,1兲E
b
SgrB2共M兲
NRAO 11 m
Tur89
Oes99
CH3 OD unidentified CH3 OCHO CH3 OCHO
3共1,2兲⫺3共0,3兲E
b
SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m NRAO 11 m BTL 7 m
Tur89 Tur89 Tur89 Cum86
Kau80
9共7,2兲⫺8共7,1兲E 9共7,3兲⫺8共7,2兲A
0.10 0.03 0.03
110535.184*共28兲
CH3 OCHO
9共7,2兲⫺8共7,1兲A
0.03b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
110535.955*共25兲
CH3 OCHO
9共7,3兲⫺8共7,2兲E
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
110550.217*共28兲 110560.053*共29兲 110571.7 110575.9 110590.7 110599. 110609.554*共60兲 110637.370*共21兲
CH3 OCHO CH3 OCHO unidentified unidentified unidentified unidentified CH3 CN CH3 CN
7共2,6兲⫺6共1,5兲E 7共2,6兲⫺6共1,5兲A
6共1兲⫺5共1兲 v8 ⫽1ᐉ⫽1
0.05 0.05 0.36 0.03 0.03 0.05 0.06
6共5兲⫺5共5兲 v8 ⫽1ᐉ⫽⫺1 F⫽7⫺6
2.0f
SgrB2共M兲 SgrB2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1 G10.47
NRAO 11 m NRAO 11 m IRAM 30 m IRAM 30 m IRAM 30 m NRAO 11 m FCRAO 14 m IRAM 30 m
Tur89 Tur89 Com96 Com96 Com96 Tur89 Gol83 Olm96
Bou80 Bou80
110642.9 110652.678*共29兲 110660.869*共10兲
unidentified CH3 OCHO CH3 CN
9共6,3兲⫺8共6,2兲E 6共4兲⫺5共4兲 v8 ⫽1ᐉ⫽⫺1
OriMC⫺1 OriMC⫺1 SgrB2共N兲
IRAM 30 m FCRAO 14 m BIMAArray
Com96 Gol83 Mia98
Oes99 Bou80
110661.057*共15兲
CH3 CN
6共4兲⫺5共4兲 v8 ⫽1ᐉ⫽⫺1 F⫽7⫺6
G10.47
IRAM 30 m
Olm96
Bou80
110662.261*共25兲
CH3 OCHO
9共6,4兲⫺8共6,3兲E
b
OriMC⫺1
FCRAO 14 m
Gol83
Oes99
110663.263*共28兲
CH3 OCHO
9共6,4兲⫺8共6,3兲A
0.23b
OriMC⫺1
FCRAO 14 m
Gol83
Oes99
110663.456*共28兲
CH3 OCHO
9共6,3兲⫺8共6,2兲A
b
OriMC⫺1
FCRAO 14 m
Gol83
Oes99
110675.5 110680.350*共10兲
unidentified CH3 CN
0.11 6共3兲⫺5共3兲 v8 ⫽1ᐉ⫽⫺1
7.0e
OriMC⫺1 SgrB2共N兲
IRAM 30 m BIMA Array
Com96 Mia98
Bou80
110683.959*共10兲
CH3 CN
6共5兲⫺5共5兲 v8 ⫽1ᐉ⫽1
5.0e
SgrB2共N兲
BIMA Array
Mia98
Bou80
110695.506*共10兲
CH3 CN
6共2兲⫺5共2兲 v8 ⫽1ᐉ⫽⫺1
10.0e
SgrB2共N兲
BIMA Array
Mia98
Bou80
110698.701*共10兲
CH3 CN
6共4兲⫺5共4兲 v8 ⫽1ᐉ⫽1
8.0e
SgrB2共N兲
BIMA Array
Mia98
Bou80
110706.251*共60兲
CH3 CN
6共1兲⫺5共1兲 v8 ⫽1ᐉ⫽⫺1
9.5e
SgrB2共N兲
BIMA Array
Mia98
Bou80
110709.313*共11兲
CH3 CN
6共3兲⫺5共3兲 v8 ⫽1ᐉ⫽⫹1
9.5e
SgrB2共N兲
BIMA Array
Mia98
Bou80
110712.166*共11兲
CH3 CN
6共0兲⫺5共0兲 v8 ⫽1ᐉ⫽1
10.3e
SgrB2共N兲
BIMA Array
Mia98
Bou80
110716.212*共17兲
CH3 CN
6共2兲⫺5共2兲 v8 ⫽1ᐉ⫽1
8.5e 0.03
SgrB2共N兲
BIMA Array
Mia98
Bou80
OriMC⫺1
IRAM 30 m
Com96
Xu_97
IRAM 30 m FCRAO 14 m IRAM 30 m FCRAO 14 m
Com96 Gol83 Com96 Gol83
Oes99
13
CH3 OH
14共2,12兲⫺13共1,13兲A⫹⫹ vt ⫽1
0.04 0.10 7.0e 2.5f
unidentified unidentified unidentified CH3 OCHO
10共1,10兲⫺9共1,9兲E
0.23b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
110790.533*共29兲
CH3 OCHO
10共1,10兲⫺9共1,9兲A
b
OriMC⫺1
FCRAO 14 m
Gol83
Oes99
110812.59共10兲 110823.095*共60兲 110839.988*共18兲 110845.
NHD2 CH3 CN CH2 CHCN unidentified
1共1,0兲⫺1共0,1兲O⫺共s兲 6共1兲⫺5共1兲 v8 ⫽1ᐉ⫽⫹⫺1 12共1,12兲⫺11共1,11兲
0.025 0.05 0.06
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲
NRAO 12 m FCRAO 14 m FCRAO 14 m NRAO 11 m
Tur90a Gol83 Gol83 Tur89
Rou00 Bou80
110861.4 110873.828*共29兲
unidentified CH3 OCHO
9共5,4兲⫺8共5,3兲E
0.06b
OriMC⫺1 SgrB2共M兲
IRAM 30 m BTL 7 m
Com96 Cum86
Oes99
110879.684*共25兲
CH3 OCHO
9共3,7兲⫺8共3,6兲E
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
110880.466*共25兲
CH3 OCHO
9共5,5兲⫺8共5,4兲A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
110882.273*共24兲
CH3 OCHO
9共5,5兲⫺8共5,4兲E
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
110887.127*共25兲
CH3 OCHO
9共3,7兲⫺8共3,6兲A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
110890.275*共25兲
CH3 OCHO
9共5,4兲⫺9共5,3兲A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
110896.55共10兲 110900.9 110906.
NHD2 unidentified unidentified
1共1,0兲⫺1共0,1兲O⫺共s兲
0.016 n.r. 0.13
L134N OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m NRAO 11 m
Rou00 Com96 Tur89
Rou00
110912.9 110918.765*共82兲
unidentified CH3 OCHO
0.04 9共4,6兲⫺8共4,4兲E
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
Oes99
110923.54共10兲
C15N unidentified
1⫺0 J⫽1/2⫺1/2 F⫽1⫺0
n.r.b 0.07
OriMC⫺1
KOSMA3 m
Sal94a
Sal94a
t⫺CH3 CH2 OH
15共8,8兲⫺16共7,9兲
n.r.b
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
t⫺CH3 CH2 OH unidentified CH3 OD unidentified CH3 OCHO
15共8,7兲⫺16共7,10兲
n.r.b
OriMC⫺1
IRAM 30 m
Com96
4共1,4兲⫺4共0,4兲E
0.03 0.04 0.03
15共4,12兲⫺15共3,13兲A
IRAM 30 m NRAO 11 m IRAM 30 m NRAO 11 m
Com96 Tur89 Com96 Tur89
110924.9 110931.103*共30兲
110938.3 110950.75共10兲 U110954.5 110962.074*共32兲
0.03 0.04 0.37
Oes99 Oes99
110765.0 110770.5 110776.4 110788.590*共28兲
110931.153*共30兲 U
Quantum numbers
110475.76共10兲 110486. 110525.598*共32兲 110535.182*共28兲
110732.51*共18兲 U U U
Formula
0.03b 0.04
0.17
0.17b
OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1
U
110968.
unidentified
b
OriMC⫺1
NRAO 11 m
Tur89
U U U U U
110977.3 110986.4 111006.6 111013.4 111021.8
unidentified unidentified unidentified unidentified unidentified
0.03 0.05 0.22 0.03 0.03
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM IRAM
Com96 Com96 Com96 Com96 Com96
30 30 30 30 30
m m m m m
Kau80 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
230
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
0.04 0.03 0.02 0.03 0.05 0.26 0.03 0.03 0.04
OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m NRAO 11 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m
Com96 Com96 Tur89 Com96 Com96 Com96 Com96 Com96 Com96
0.04
OriMC⫺1 OriMC⫺1
IRAM 30 m NRAO 11 m
Com96 Tur89
Oes99
OriMC⫺1
NRAO 11 m
Tur89
Oes99
NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Tur89 Com96
Oes99
b
OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1
U U U U U U U U U
111029.1 111034.6 111038. 111047.5 111069.0 111094.9 111121.4 111127.9 111139.0
unidentified unidentified unidentified unidentified unidentified unidentified unidentified unidentified unidentified
U
111161.9 111169.831*共28兲
unidentified CH3 OCHO
10共0,10兲⫺9共0,9兲E
b
111171.659*共29兲
CH3 OCHO
10共0,10兲⫺9共0,9兲A
111195.990*共25兲 111211. 111223.397*共28兲 111243.339*共21兲
CH3 OCHO unidentified CH3 OCHO 共CH3 兲2 CO
9共4,6兲⫺8共4,5兲A 9共4,6兲⫺8共4,5兲E 10共1,9兲⫺9共2,8兲AE
0.09b 0.17 0.03 0.11
111243.388*共21兲
共CH3 兲2 CO
10共2,9兲⫺9共1,8兲AE
0.10b
OriMC⫺1
IRAM 30 m
Com96
Vac86
111243.424*共20兲
共CH3 兲2 CO
10共1,9兲⫺9共2,8兲EA
b
OriMC⫺1
IRAM 30 m
Com96
Vac86
111243.472*共20兲
共CH3 兲2 CO
10共2,9兲⫺9共1,8兲EA
b
OriMC⫺1
IRAM 30 m
Com96
Vac86
111254.4 111289.601*共19兲 111312. 111408.322*共37兲 111432.033*共58兲 111453.327*共25兲 111492.46*共10兲 111502.
unidentified CH3 OH unidentified CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO unidentified
0.06 0.58 0.05 0.10 0.04 0.34 0.02 0.18e
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共N兲
IRAM 30 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m BIMA Array
Com96 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Rem02
111507.270*共20兲
CH3 COOH
10共*,10兲⫺9共*,9兲E
0.13e
W51e2
BIMA Array
Rem02
Ily00
111508.64*共2兲
5共0,5兲⫺4共0,4兲
0.08e
W51e2
BIMA Array
Rem02
Wil80
111511.
H13COOH unidentified
U111522.
unidentified
U
U U
U
U
111538.210*共14兲 111541.432*共14兲
CH3 CCCN CH3 CCCN
U
111542.
unidentified
U
111542.501*共15兲 111548.
CH3 CCCN unidentified
U U
U
U U U U U
U U
7共2,5兲⫺8共1,8兲A⫹ 9共4,5兲⫺8共4,4兲E 13共1,12兲⫺13共0,13兲E 9共4,5兲⫺8共4,4兲A 13共1,12兲⫺13共0,13兲A
0.09e
W51e2
BIMA Array
Rem02
SgrB2共N兲
BIMA Array
Rem02
27共2兲⫺26共2兲
0.54e 0.02
OriMC⫺1
NRAO 11 m
Tur89
27共1兲⫺26共1兲
b
OriMC⫺1
NRAO 11 m
Tur89
0.32e 0.05
SgrB2共N兲
BIMA Array
Rem02
27共0兲⫺26共0兲
OriMC⫺1
NRAO 11 m
Tur89
0.10e
W51e2
BIMA Array
Rem02
111548.533*共20兲
CH3 COOH
10共*,10兲⫺9共*,9兲A
111574.617*共26兲 111580. 111589. 111626.550*共35兲 111674.070*共25兲 111678. 111682.224*共25兲 111733.936*共28兲
CH3 CH2 CN unidentified unidentified CH3 OH CH3 OCHO unidentified CH3 OCHO CH3 OCHO
22共1,21兲⫺22共0,22兲
17共⫺2,16兲⫺17共1,16兲E 9共1,8兲⫺8共1,7兲E
111735.329*共29兲
CH3 OCHO
111746.78*共1兲 111755.028*共4兲 111782.596*共4兲
HCOOH SO2 CH3 OCH3
111783.112*共4兲
Xu_97 Oes99 Oes99 Oes99 Oes99
BIMA Array
Rem02
Ily00
NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO
Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89 Tur89
Xu_97 Oes99
0.05b
OriMC⫺1 OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
10共1,10兲⫺9共0,9兲A
b
OriMC⫺1
NRAO 11 m
Tur89
Oes99
5共0,5兲⫺4共0,4兲 31共3,29兲⫺30共4,26兲 7共0,7兲⫺6共1,6兲AA
0.10 0.06
BTL 7 m NRAO 11 m BTL 7 m
Cum86 Tur91 Cum86
Wil80
b
SgrB2共M兲 SgrB2共M兲 SgrB2共M兲
Gro98
CH3 OCH3
7共0,7兲⫺6共1,6兲EE
0.12b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
111783.628*共4兲
CH3 OCH3
7共0,7兲⫺6共1,6兲EA⫹AE
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
111812.238*共8兲
CH3 OCH3
18共3,15兲⫺18共2,16兲AE⫹EA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
111813.810*共6兲
CH3 OCH3
18共3,15兲⫺18共2,16兲EE
0.12b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
111815.382*共10兲
CH3 OCH3
18共3,15兲⫺18共2,16兲AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
111823.026*共4兲
HC5 N
42⫺41
111827.6 111943.569*共16兲 111967. 111967. 112006. 112016.00*共14兲
unidentified CH3 CH2 CN unidentified unidentified unidentified
18共2,17兲⫺18共1,18兲
0.08 0.13 0.04
SgrB2共M兲 OriMC⫺1 OriMC⫺1
NRAO 11 m FCRAO 14 m NRAO 11 m
Tur91 Gol83 Tur89
IRC⫹10216 OriMC⫺1 SgrB2共M兲 IRC⫹10216
NRAO 12 m NRAO 11 m NRAO 11 m IRAM 30 m
Ziu95 Tur89 Tur89 Ziu95
9共1,8兲⫺8共1,7兲A 10共1,10兲⫺9共0,9兲E
0.16e 0.05 0.04 0.02 0.22 0.18 0.14 0.18
W51e2
Oes99 Vac86
11 11 11 11 11 11 11 11
m m m m m m m m
Oes99 Oes99
15⫺14
112035. 112063.44共10兲
K37Cl unidentified MgCN
0.008 0.05 0.02 0.005
11⫺10 J⫽21/2⫺19/2
0.016 0.006
IRC⫹10216 IRC⫹10216
IRAM 30 m IRAM 30 m
Ziu95 Ziu95
And94
112078.44共10兲
MgCN
11⫺10 J⫽23/2⫺21/2
0.006
IRC⫹10216
IRAM 30 m
Ziu95
And94
112114. 112150. 112166.938共10兲
unidentified unidentified l⫺C3 H
0.10 0.004 ⬃0.03
OriMC⫺1 IRC⫹10216 IRC⫹10216
NRAO 11 m IRAM 30 m IRAM 30 m
Tur89 Ziu95 Ziu95
Yam90a
112248.722*共6兲
CH3 CHO
0.25
SgrB2共M兲
NRAO 11 m
Tur91
Kle96
2
⌸1/2 5⫺4 J⫽11/2⫺9/2 v4 ⫽1 6共1,6兲⫺5共1,5兲A⫹⫹
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
231
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
112254.512*共6兲 112254.512*共6兲
CH3 CHO CH3 CHO
6共⫺1,6兲⫺5共⫺1,5兲E 6共⫺1,6兲⫺5共⫺1,5兲E
0.24
SgrB2共M兲 NGC6334F
NRAO 11 m SEST 15 m
Tur91 Num98a
Kle96 Kle96
112348. 112355.48*共43兲
unidentified
SgrB2共M兲 IRC⫹10216
IRAM 30 m IRAM 30 m
Com87 Cer87b
112358.780共15兲
C17O
1⫺0 F⫽3/2⫺5/2
0.10b 0.20
B335
BTL 7 m
Fre81
Fre81
112358.988共8兲
C17O
1⫺0 F⫽7/2⫺5/2
0.43
B335
BTL 7 m
Fre81
Fre81
112360.005共8兲
1⫺0 F⫽5/2⫺5/2 11共0,11兲⫺10共1,10兲EE
0.38
B335
BTL 7 m
Fre81
Fre81
112373.548*共18兲
C17O 共CH3 兲2 CO
0.03b
TMC⫺1
IRAM 30 m
Com87
Gro02a
112373.548*共18兲
共CH3 兲2 CO
11共1,11兲⫺10共0,10兲EE
0.03b
TMC⫺1
IRAM 30 m
Com87
Gro02a
112381.029*共28兲
共CH3 兲2 CO
11共0,11兲⫺10共1,10兲AA
b
TMC⫺1
IRAM 30 m
Com87
Gro02a
112381.029*共28兲
共CH3 兲2 CO
11共1,11兲⫺10共0,10兲AA
TMC⫺1
IRAM 30 m
Com87
Gro02a
HCOOH HCOOH
5共4,*兲⫺4共4,*兲 5共3,3兲⫺4共3,2兲
0.04b 0.06 0.06b
SgrB2共M兲 SgrB2共M兲
NRAO 11 m BTL 7 m
Tur89 Cum86
Wil80 Wil80
112467.00*共1兲
HCOOH
5共3,2兲⫺4共3,1兲
b
SgrB2共M兲
BTL 7 m
Cum86
Wil80
112532. 112585. 112593.44*共10兲
unidentified unidentified
SgrB2共M兲 SgrB2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Tur91 Tur89 Cer91b
112432.30*共1兲 112459.61*共1兲
U U
112646.233*共9兲 112654.117*共13兲 112807.096*共15兲
U
U
U
U U
U
U
U
U
5共0,5兲⫺4共0,4兲
30
SiC2
0.90f 0.08
0.05 0.02 5共0,5兲⫺4共0,4兲
Si13CC CH3 CH2 CN NH2 CHO
13共1,13兲⫺12共1,12兲
0.7f 0.10
SgrB2共M兲
BTL 7 m
Cum86
8共3,6兲⫺9共2,7兲 2共2,1兲⫺1共1,0兲
0.07 0.12
OriMC⫺1 SgrB2共M兲
NRAO 11 m NRAO 11 m
Tur89 Kut80
12共0,12兲⫺11共0,11兲 14共3,11兲⫺13共4,10兲A 5共2,3兲⫺4共2,2兲n,t
0.06 0.07 0.08 0.06
⌸1/2 J⫽23/2⫺21/2 v7 ⫽1e
3.01f
SgrB2共M兲 OriMC⫺1 OriMC⫺1 SgrB2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Kut80 Tur89 Tur89 Kut80 Yam87b
Wil80 Yam87b
b
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Tur89
Gro98
112840.655*共18兲 112869.993*共59兲 112874. 112891.43*共11兲 112922.5共4兲
t⫺CH3 CH2 OH CH2 CHCN CH3 OCHO unidentified HCOOH C4 H
112997. 112999.982*共8兲
unidentified CH3 OCH3
20共3,17兲⫺20共2,18兲AE⫹EA
113001.218*共6兲
CH3 OCH3
20共3,17兲⫺20共2,18兲EE
0.11b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
113002.455*共10兲
CH3 OCH3
20共3,17兲⫺20共2,18兲AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
113032.124*共30兲 113059.350*共6兲
CH2 CHCN CH3 OCH3
8共1,8兲⫺7共0,7兲
0.09
SgrB2共M兲
NRAO 11 m
Tur89
17共3,14兲⫺17共2,15兲EE
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
113061.121*共10兲
CH3 OCH3
17共3,14兲⫺17共2,15兲AA
OriMC⫺1
NRAO 11 m
Tur89
Gro98
113123.337*共10兲
CN
1⫺0 J⫽1/2⫺1/2 F⫽1/2⫺1/2
0.11b 0.17
G34.3⫹0.15
TRAO 14 m
Kim00
Ska83
113136.20*共10兲
⌸ 1/2 J⫽5/2⫺3/2 F⫽3/2⫺3/2e
0.10
SgrB2共M兲
NRAO 11 m
Tur89
113144.192共9兲
N34S CN
1⫺0 J⫽1/2⫺1/2 F⫽1/2⫺3/2
1.14
OriMC⫺1
NRAO 11 m
Tur75
113159. 113170.528共20兲
unidentified CN
1⫺0 J⫽1/2⫺1/2 F⫽3/2⫺1/2
0.10 0.97
SgrB2共M兲 OriMC⫺1
NRAO 11 m NRAO 11 m
Tur89 Tur75
Dix77
113191.317共40兲
CN
1⫺0 J⫽1/2⫺1/2 F⫽3/2⫺3/2
1.38
OriMC⫺1
NRAO 11 m
Tur75
Dix77
0.20 0.22
SgrB2共M兲 SgrB2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur87b Yam87b
Yam87b
NRAO 11 m NRAO 11 m
Tur89 Tur89
Gro98
2
0.10
2
Oes99
Dix77
113246. 113260. 113265.9共3兲
unidentified unidentified C4 H
113266.74*共4兲 113276.031*共28兲
CH2 CHCN CH3 OCH3
⌸1/2 J⫽23/2⫺21/2 v7 ⫽1f 20共2,18兲⫺20共1,19兲 10共6,4兲⫺11共5,7兲EE
3.67f 0.15 b
SgrB2共M兲 OriMC⫺1
113279.138*共28兲
CH3 OCH3
10共6,5兲⫺11共5,6兲EE
0.05b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
113279.455*共28兲
CH3 OCH3
10共6,4兲⫺11共5,7兲AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
113280.593*共28兲
CH3 OCH3
10共6,5兲⫺11共5,6兲AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
113314. 113350.80共10兲 113410.204*共14兲
unidentified CH3 OD CCS
6共1,5兲⫺6共0,6兲E 8,9⫺7,8
NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Cer87b
Kau80
113488.140共5兲
CN
1⫺0 J⫽3/2⫺1/2 F⫽3/2⫺1/2
2.1f 1.04
OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1
NRAO 11 m
Pen74
Dix77
113490.982共3兲
CN
1⫺0 J⫽3/2⫺1/2 F⫽5/2⫺3/2
3.23
OriMC⫺1
NRAO 11 m
Jef70
Dix77
113499.639共5兲
CN
1⫺0 J⫽3/2⫺1/2 F⫽1/2⫺1/2
0.79
OriMC⫺1
NRAO 11 m
Jef70
Dix77
113508.944共13兲
CN
1⫺0 J⫽3/2⫺1/2 F⫽3/2⫺3/2
0.94
OriMC⫺1
NRAO 11 m
Tur75
Dix77
1⫺0 J⫽3/2⫺1/2 F⫽1/2⫺3/2 12共2,11兲⫺11共2,10兲
2
113520.414*共10兲
CN
113657.647*共17兲 113729. 113743.007*共28兲 113756.646*共28兲 113766.420*共20兲 113818. 113820.12*共32兲
CH2 CHCN unidentified CH3 OCHO CH3 OCHO HCCCHO unidentified
113831.197*共41兲 113844. 113978.248*共10兲 114003.831*共6兲
CH2 CHCN unidentified CH3 CH2 CN CH3 OCH3
13共0,13兲⫺12共0,12兲 18共2,16兲⫺18共1,17兲AE⫹EA
114005.399*共6兲
CH3 OCH3
18共2,16兲⫺18共1,17兲EE
29
SiC2
9共3,6兲⫺8共3,5兲E 9共3,6兲⫺8共3,5兲A 12共1,11兲⫺11共1,10兲 5共0,5兲⫺4共0,4兲 18共2,16兲⫺18共1,17兲
0.07 0.04
⬍0.2
OriMC⫺1
NRAO 11 m
All78
0.12 0.04 0.13 0.09 0.04 0.20 n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 SgrB2共M兲 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Tur89 Tur89 Tur89 Tur91 Tur89 Cer91b
0.08 0.10 0.12 b
OriMC⫺1 SgrB2共M兲 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO
m m m m
Tur89 Tur89 Joh77 Tur89
Gro98
0.11b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
11 11 11 11
Oes99 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
232
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U
OriMC⫺1
NRAO 11 m
Tur89
Gro98
SgrB2共M兲
NRAO 11 m
Tur89
0.07
OriMC⫺1
NRAO 11 m
Tur89
5共2,4兲⫺4共2,3兲
0.07 0.23 0.40 0.09 0.05 0.05 n.r.
OriMC⫺1 IRC⫹10216 IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Tur89 Sco78 Sco78 Tur89 Tur89 Tur89 Cer91b
17共2,16兲⫺16共3,13兲
0.06
OriMC⫺1
NRAO 11 m
Tur89
43⫺42 29共3,27兲⫺28共4,24兲 6共3,3兲⫺7共2,6兲
0.11 0.17 0.05
SgrB2共M兲 OriMC⫺1 OriMC⫺1
BTL 7 m NRAO 11 m NRAO 11 m
Cum86 Tur89 Tur89
13⫺12
0.13b
SgrB2共M兲
BTL 7 m
Cum86
b
SgrB2共M兲
BTL 7 m
Cum86
18共2,16兲⫺18共1,17兲AA 2共2,0兲⫺1共1,1兲
18 OCS unidentified C4 H C4 H unidentified unidentified unidentified
10⫺9
114113. 114182.51*共2兲 114221.04*共2兲 114291. 114313. 114336. 114362.21*共33兲
25/2⫺23/2 23/2⫺21/2
30
SiC2
t⫺CH3 CH2 OH HC5 N SO2 34
SO2
T r 共K兲/T a 共K兲
Got83 Got83
Laf78
114621.577*共16兲
H13CCCN CH2 CHCN
12共2,10兲⫺11共2,9兲
114650.932*共46兲 114737.17共20兲
CH3 OH C4 H
18共⫺2,17兲⫺18共1,17兲E
0.35
OriMC⫺1
NRAO 11 m
Tur89
Xu_97
2⌺ J⫽12⫺11 v7 ⫽2L
0.15
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
2⌺ J⫽12⫺11 v7 ⫽2U 13⫺12
0.15
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
0.03
SgrB2共M兲
NRAO 11 m
Tur89
Laf78
0.06 0.03 0.10 0.07
OriMC⫺1 SgrB2共M兲 SgrB2共OH兲 TMC⫺1
NRAO 11 m NRAO 11 m IRAM 30 m NRAO 12 m
Tur89 Tur89 Gom86 Ger87
6共0,6兲⫺5共0,5兲E 6共0,6兲⫺5共0,5兲A⫹⫹
0.15 0.38 n.r.
2 ⌸3/2 J⫽83/2⫺81/2e 9共2,8兲⫺9共1,9兲AE⫹EA
0.52f
SgrB2共M兲 SgrB2共M兲 OriMC⫺1 IRC⫹10216
BTL 7 m BTL 7 m NRAO 11 m IRAM 30 m
Cum86 Cum86 Tur89 Cer87a
JPL01
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
C4 H
114793.82共20兲 114831.084*共11兲
U
b
0.12
CH3 OCH3 t⫺CH3 CH2 OH
114615.021*共11兲
U
Lab. Ref.
114006.968*共8兲
114485.039*共4兲 114565.381*共4兲 114574.438*共4兲
U
Astr. Ref.
114064.848*共15兲
114443.946*共32兲
U U
Telescope
Quantum numbers
114092.612*共5兲 U
Source
Formula
114840. 114861. 114888.234*共48兲 114897.372*共17兲
HC3 15N unidentified unidentified CH3 OCHO
23共6,18兲⫺22共7,15兲A 3共0,3兲⫺2共1,2兲
Oes99
114940.177*共6兲
c⫺H13CCCH CH3 CHO
114959.909*共6兲 115021. 115038.94*共9兲
CH3 CHO unidentified C6 H
115072.307*共10兲
CH3 OCH3
115075.086*共4兲
CH3 OCH3
9共2,8兲⫺9共1,9兲EE
0.10b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
115077.864*共8兲
CH3 OCH3
9共2,8兲⫺9共1,9兲AA
b
OriMC⫺1
NRAO 11 m
Tur89
Gro98
115083.30*共9兲
C6 H
IRC⫹10216
IRAM 30 m
Cer87a
JPL01
115141. 115153.935共6兲
unidentified NS
2
⌸1/2 J⫽5/2⫺3/2 F⫽7/2⫺5/2e
⬍0.3b
OriMC⫺1 SgrB2共M兲
NRAO 11 m MMWO 4.9m
Tur89 Got75
Lee95
115156.812共4兲
NS
2
⌸1/2 J⫽5/2⫺3/2 F⫽5/2⫺3/2e
b
SgrB2共M兲
MMWO 4.9m
Got75
Lee95
115185.411共2兲
NS
2
⌸1/2 J⫽5/2⫺3/2 F⫽3/2⫺3/2e
0.26
SgrB2共M兲
BTL 7 m
Cum86
Lee95
n.r.
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Tur89 Yam87b
Yam87b
OriMC⫺1 IRC⫹10216 SgrB2共M兲
NRAO 11 m NRAO 11 m NRAO 11 m
Uli76 Kui77 Got75
Lee95
NRAO 11 m
Got75
Lee95
115212. 115216.8共3兲
2
⌸3/2 J⫽83/2⫺81/2f
0.42f n.r.
unidentified C4 H
2
⌸1/2 J⫽5/2⫺3/2 F⫽7/2⫺5/2f
3.05f 60.0 0.22 0.24
NS
2
⌸1/2 J⫽5/2⫺3/2 F⫽5/2⫺3/2f
0.28b
SgrB2共M兲
115571.954共3兲
NS
2
⌸1/2 J⫽5/2⫺3/2 F⫽3/2⫺1/2f
b
115804.405共20兲
SO⫹ CH3 CH2 CN
115570.763共5兲
115894.365*共9兲 115944.52*共30兲
29
SiC2
SO⫹ D2 CO SiC2
116179.947共20兲 116688.442*共8兲 120250.148*共37兲 122023.531*共8兲 124496.477*共6兲 124569.976*共10兲 124614.087*共6兲 124729.067*共10兲 124789.84共12兲
2
⌸3/2 J⫽25/2⫺23/2 v7 ⫽1f 1⫺0 5共0,5兲⫺4共0,4兲
CO SiC2 NS
115271.202*共1兲 115382.375*共52兲 115556.253共3兲
⌸1/2 J⫽5/2⫺3/2e 12共2,12兲⫺12共2,11兲 5共2,4兲⫺4共2,3兲 2
13
NRAO 11 m
Got75
Lee95
IC443G
NRAO 12 m
Tur92a
Ama91
0.09 n.r.
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Joh77 Cer91b
0.032
IC443G
NRAO 12 m
Tur92a
0.07 n.r. 1.0
OriMC⫺1 IRC⫹10216 TMC⫺1
NRAO 12 m IRAM 30 m FCRAO 14 m
Tur90a Cer91b Mad86a
12共2,10兲⫺12共1,11兲
0.12
SgrB2共M兲
BTL 7 m
Cum86
6共0,6兲⫺5共1,4兲E 10共2,8兲⫺10共1,9兲
0.44 0.08
SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m
Cum86 Cum86
14共2,13兲⫺13共2,12兲
0.10
SgrB2共M兲
BTL 7 m
Cum86
2共0,2兲⫺1共0,1兲
0.07
SgrB2共M兲
BTL 7 m
Cum86
Pea77
0.07
BTL 7 m BTL 7 m
Cum86 Cum86
Bou80
34
SO2 CH3 CH2 CN
SgrB2共M兲
0.020
⌸1/2 J⫽5/2⫺3/2f 2共0,2兲⫺1共0,1兲 5共2,3兲⫺4共2,2兲 2共2,1兲⫺1共1,0兲
2
c⫺C3 H2 34 SO2 CH3 OH
Kle96 Kle96
CH2 NH SO2
Ama91
Xu_97
124864.764*共3兲 125040.163*共18兲
13
CH3 CN
11共4,8兲⫺12共3,9兲 7共3兲⫺6共3兲
0.04b
SgrB2共M兲 SgrB2共M兲
125051.926*共18兲
13
CH3 CN
7共2兲⫺6共2兲
b
SgrB2共M兲
BTL 7 m
Cum86
Bou80
125058.986*共18兲
13
CH3 CN
7共1兲⫺6共1兲
0.05b
SgrB2共M兲
BTL 7 m
Cum86
Bou80
125061.340*共19兲
13
CH3 CN
7共0兲⫺6共0兲
b
SgrB2共M兲
BTL 7 m
Cum86
Bou80
SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m
Cum86 Cum86
Sas86
125130.914共50兲
CH3 SH HC5 N
5共1兲⫺4共1兲A⫺ 47⫺46
0.07
t⫺CH3 CH2 OH CH3 OCH3
8共3,5兲⫺8共2,6兲
0.07
SgrB2共M兲
BTL 7 m
Cum86
125242.976*共10兲
2共2,1兲⫺1共1,0兲EA
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
125244.835*共6兲
CH3 OCH3
2共2,1兲⫺1共1,0兲AE
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
125246.882*共6兲
CH3 OCH3
2共2,1兲⫺1共1,0兲EE
0.08b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
125132.773*共4兲 125173.169*共15兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
MICROWAVE TRANSITIONS
233
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U
125249.894*共10兲
CH3 OCH3
2共2,1兲⫺1共1,0兲AA
CH3 CH2 CN unidentified N2 O unidentified unidentified CH2 CHCN
14共3,12兲⫺13共3,11兲
126980.698*共4兲
t⫺CH3 CH2 OH SO2
127076.162*共9兲 127112.669*共2兲
SiS NH2 CHO
5⫺4
13共1,12兲⫺12共1,11兲 10共1,9兲⫺9共2,8兲 35共5,31兲⫺34共6,28兲 7⫺6 6共2,5兲⫺5共2,4兲
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref. Gro98
b
SgrB2共M兲
BTL 7 m
Cum86
0.07 0.05 0.067 0.05 0.12 0.10 0.13
SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲
BTL 7 m NRAO 12 m NRAO 12 m NRAO 12 m BTL 7 m BTL 7 m BTL 7 m
Cum86 Ziu94a Ziu94a Ziu94a Cum86 Cum86 Cum86
0.06 0.8
SgrB2共M兲 IRC⫹10216 SgrB2共M兲
BTL 7 m OVRO 10.4 m BTL 7 m
Cum86 Sah84 Cum86 Cum86
0.16b b
SgrB2共M兲
BTL 7 m
7共3,4兲⫺7共2,5兲
0.05
SgrB2共M兲
BTL 7 m
Cum86
127288.1共11兲 127307.5共12兲 127329.929*共6兲 127348.292*共4兲
t⫺CH3 CH2 OH unidentified unidentified NH2 CHO NH2 CHO
6共5,*兲⫺5共5,*兲
0.04 0.03 0.03
SgrB2共M兲 SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m BTL 7 m
Cum86 Cum86 Cum86
6共4,3兲⫺5共4,2兲
0.08b
SgrB2共M兲
BTL 7 m
Cum86
127348.407*共4兲
NH2 CHO
6共4,2兲⫺5共4,1兲
b
SgrB2共M兲
BTL 7 m
Cum86
127367.660*共4兲 127393.518*共3兲 127412.092*共3兲 127428.228*共6兲 127748.594*共62兲
HCCCN NH2 CHO NH2 CHO SO2
14⫺13 6共3,4兲⫺5共3,3兲 6共3,3兲⫺5共3,2兲 28共4,24兲⫺27共5,23兲 3⫺2 v⫽1
1.85 0.10 0.09 0.04 4.0
OriMC⫺1 SgrB2共M兲 SgrB2共M兲 SgrB2共M兲 VYCMa
MMWO 4.9 m BTL 7 m BTL 7 m BTL 7 m IRAM 30 m
Mor77 Cum86 Cum86 Cum86 Cer91c
128020.526*共20兲
HCS⫹ NH2 CHO
127215.126*共16兲
128102.780*共2兲 128295.019*共29兲 128458.875*共70兲
3⫺2 v⫽0
30
SiO
29
SiO
HOCO⫹ SiO
3⫺2
0.28
OriMC⫺1
BTL 7 m
Tha81
Bog84
6共2,4兲⫺5共2,3兲 6共0,6兲⫺5共0,5兲
0.16 0.4
SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m
Cum86 Tha81
Tha81
3⫺2 v⫽2
83.e 0.58 0.097
OriMC⫺1
NRAO 11 m
Sch82
OriMC⫺1 IRC⫹10216
MMWO 4.9 m BTL 7 m
Lor84 Hen85
0.11
OriMC⫺1
MMWO 4.9 m
Lor84
128605.099*共4兲
SO2
12共2,10兲⫺12共1,11兲
128622.14*共3兲
CCCN 29
128640.90*共3兲
SiO CCCN
13⫺12 J⫽27/2⫺25/2 3⫺2 v⫽0
128668.785*共5兲
34
13⫺12 J⫽25/2⫺23/2 8共2,6兲⫺8共1,7兲
128636.968*共67兲
128689.620*共16兲
SO2
6共3,3兲⫺6共2,4兲
0.093
IRC⫹10216
BTL 7 m
Hen85
0.06
OriMC⫺1
MMWO 4.9 m
Lor84
0.09b 0.07 0.06y
SgrB2共M兲
BTL 7 m
Cum86
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor84 Lor84
Got83
Got83
128690.119*共3兲
t⫺CH3 CH2 OH CH3 CN
128705.792*共5兲
CH3 13CN
7共6兲⫺6共6兲 7共2兲⫺6共2兲
128713.207*共6兲
CH3 13CN
7共1兲⫺6共1兲
0.11b
SgrB2共M兲
BTL 7 m
Cum86
Bou80
128715.679*共6兲
CH3 13CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN
7共0兲⫺6共0兲
b
SgrB2共M兲
BTL 7 m
Cum86
Bou80
7共5兲⫺6共5兲 7共4兲⫺6共4兲
0.09 0.18
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor84 Lor84
7共3兲⫺6共3兲 7共2兲⫺6共2兲 7共1兲⫺6共1兲 7共0兲⫺6共0兲
0.39 0.38 0.52 0.62
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO4.9 m
Lor84 Lor84 Lor84 Lor84
HDCO HNCS
2共0,2兲⫺1共0,1兲 11共0,11兲⫺10共0,10兲 3共2,2兲⫺2共1,1兲
0.3 0.06 0.13
L134N SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m BTL 7 m
Lan79 Fre79 Cum86
8共1,7兲⫺7共1,6兲
2.73f 0.20 1.5 0.05
IRC⫹10216
IRAM 30 m
Cer00
SgrB2共M兲 rhoOphA SgrB2共M兲 IRC⫹10216
BTL 7 m MMWO 4.9 m BTL 7 m IRAM 30 m
Cum86 Lor84b Cum86 Cer91b
1.59f
SgrB2共M兲 SgrB2共M兲 OriMC⫺1 SgrB2共M兲 IRC⫹10216
BTL 7 m BTL 7 m MMWO 4.9 m BTL 7 m IRAM 30 m
Cum86 Cum86 Dav74 Cum86 Cer00
128717.367*共2兲 128739.675*共2兲 128757.035*共2兲 128769.439*共2兲 128776.884*共2兲 128779.366*共2兲 128812.865*共6兲 129013.260*共4兲 129077.575*共16兲 129081.270*共67兲 129105.779*共3兲 129138.939*共7兲 129219.221*共16兲 129248.12*共23兲
t⫺CH3 CH2 OH NaCN
12共1,11兲⫺11共2,10兲 3共3兲⫺2共2兲 14共1,14兲⫺13共1,13兲 6共1,6兲⫺5共1,5兲
SO2 SO CH2 CHCN Si13CC CH3 OCHO CH3 OCHO SiO CH3 OH CCS
10共2,8兲⫺9共2,7兲E 10共2,8兲⫺9共2,7兲A 3⫺2 v⫽1 12共1,11兲⫺11共2,10兲A⫺ 10,10⫺9,9
129723.89*共24兲
c⫺C3 H
4共1,4兲⫺3共1,3兲9/2⫺9/2 F⫽4⫺4
0.66fb
IRC⫹10216
IRAM 30 m
Cer00
129726.576*共18兲
CCC34 S
23⫺22
0.20f
IRC⫹10216
IRAM 30 m
Cer00
129727.43*共24兲
c⫺C3 H C6 H
4共1,4兲⫺3共1,3兲9/2⫺9/2 F⫽5⫺5
129296.274*共25兲 129310.206*共25兲 129363.366*共62兲 129433.406*共25兲 129548.452*共10兲
129770.973*共61兲 U
Quantum numbers
125564.486*共9兲 125603. 125613.694*共7兲 125621. 125848.6共12兲 125921.667*共17兲 125947.336*共21兲
127117.364*共67兲
U U
Formula
129773.0共8兲
2
⌸1/2 J⫽93/2⫺91/2e
unidentified
0.5f 0.03 0.05 0.9 0.07
Yam79
Oes99 Oes99 Xu_97 JPL01
b
IRC⫹10216
IRAM 30 m
Cer00
JPL01
0.48f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
0.27f
IRC⫹10216
IRAM 30 m
Cer00
129836.134*共70兲
C6 H
IRC⫹10216
IRAM 30 m
Cer00
JPL01
CH3 OCHO
⌸1/2 J⫽93/2⫺91/2f 11共2,10兲⫺10共2,9兲E
0.49f
130010.040*共25兲
0.04b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
130016.826*共28兲
CH3 OCHO
11共2,10兲⫺10共2,9兲A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
130171.477*共69兲
H2 13CS
4共1,4兲⫺3共1,3兲
0.04
SgrB2共M兲
BTL 7 m
Cum86
130223.681*共67兲
Na35Cl SiO
10⫺9
1.93f
IRC⫹10216
IRAM 30 m
Cer87c
IRC⫹10216
IRAM 30 m
Cer00
130268.722*共67兲
2
3⫺2
173.f
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
234
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
130268.722*共67兲 130456.439*共4兲
SiO HC5 N
3⫺2 v⫽0 49⫺48
1.34 0.94f
OriMC⫺1 IRC⫹10216
MMWO 4.9 m IRAM 30 m
Dic76 Cer00
130515.734*共3兲
OC34S CH3 OCH3
11⫺10
b
NGC6334I
IRAM 30 m
Bac90
130516.350*共8兲
10共1,9兲⫺9共2,8兲AA
b
NGC6334I
IRAM 30 m
Bac90
Gro98
130517.881*共6兲
CH3 OCH3
10共1,9兲⫺9共2,8兲EE
1.5b
NGC6334I
IRAM 30 m
Bac90
Gro98
130519.412*共12兲
CH3 OCH3
10共1,9兲⫺9共2,8兲AE⫹EA
b
NGC6334I
IRAM 30 m
Bac90
Gro98
130650.53*共15兲
17⫺16
0.51f
IRC⫹10216
IRAM 30 m
Cer87c
130707.096*共13兲
K35Cl SiN
3⫺2 J⫽5/2⫺3/2 F⫽7/2⫺5/2
0.88f
IRC⫹10216
IRAM 30 m
Cer00
Sai83
130713.185*共9兲
SiN
3⫺2 J⫽5/2⫺3/2 F⫽5/2⫺3/2
0.66f
IRC⫹10216
IRAM 30 m
Cer00
Sai83
130716.834*共11兲
SiN
3⫺2 J⫽5/2⫺3/2 F⫽3/2⫺1/2
0.31f
IRC⫹10216
IRAM 30 m
Cer00
Sai83
IRC⫹10216
IRAM 30 m
Cer00
12共1,11兲⫺12共0,12兲 5共3,3兲⫺5共2,4兲
0.44f 0.25 0.04
SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m
Cum86 Cum86
21/2,11⫺19/2,10
0.06 0.005
SgrB2共M兲 CRL2688
BTL 7 m NRAO 12 m
Cum86 Hig01
Kaw93 Kaw93
130765.5共3兲 131014.835*共3兲 131102.984*共17兲
U
131134.0共7兲 131241.612*共20兲
MgNC
0.005
CRL2688
NRAO 12 m
Hig01
14共0,14兲⫺13共0,13兲
0.09b
SgrB2共M兲
BTL 7 m
Cum86
131274.864*共3兲
SO2
16共5,11兲⫺17共4,14兲
b
SgrB2共M兲
BTL 7 m
Cum86
131394.241*共5兲 131405.032*共4兲
HNCO CH3 OCH3
6共1,6兲⫺5共1,5兲 6共1,6兲⫺5共0,5兲AE⫹EA
0.18 b
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor84 Lor84
Gro98
131405.788*共4兲
CH3 OCH3
6共1,6兲⫺5共0,5兲EE
0.17b
OriMC⫺1
MMWO 4.9 m
Lor84
Gro98
131406.543*共6兲
CH3 OCH3
6共1,6兲⫺5共0,5兲AA
b
OriMC⫺1
MMWO 4.9 m
Lor84
Gro98
131502.694*共16兲
t⫺CH3 CH2 OH CCS unidentified
6共3,4兲⫺6共2,5兲
0.05
SgrB2共M兲
BTL 7 m
Cum86
11,10⫺10,9
0.09 0.005 0.004
SgrB2共M兲 IRC⫹10216 IRC⫹10216
BTL 7 m IRAM 30 m IRAM 30 m
Cum86 Ziu02 Ziu02
0.23 0.003 0.005 0.019
SgrB2共M兲 IRC⫹10216 IRC⫹10216 IRC⫹10216
BTL 7 m IRAM 30 m IRAM 30 m IRAM 30 m
Cum86 Ziu02 Ziu02 Ziu02
JPL01
0.016
IRC⫹10216
IRAM 30 m
Ziu02
JPL01
0.6f
IRC⫹10216
IRAM 30 m
Gue91
131551.972*共15兲 131590. 131612.1
24
131617.898*共2兲 131620. 131642.204*共5兲 131668.80*共4兲
C13CCS NH2 CHO unidentified AlNC C6 H
131725.44*共4兲
C6 H
131762.841*共17兲
23⫺22 6共1,5兲⫺5共1,4兲 11⫺10 2
⌸3/2 J⫽95/2⫺93/2e
2
⌸3/2 J⫽95/2⫺93/2f 7,6⫺6,5
HCCN
131799.292*共7兲
HNCO
6共3,3兲⫺5共3,2兲
b
SgrB2共M兲
BTL 7 m
Cum86
131799.292*共7兲
HNCO
6共3,4兲⫺5共3,3兲
0.05b
SgrB2共M兲
BTL 7 m
Cum86
131833.306*共20兲
HCCN
6,6⫺5,5
IRC⫹10216
IRAM 30 m
Gue91
131845.880*共5兲
HNCO
6共2,5兲⫺5共2,4兲
SgrB2共M兲
BTL 7 m
Cum86
131846.590*共6兲
HNCO
6共2,4兲⫺5共2,3兲
b
131885.740*共6兲 131898.786*共21兲
HNCO AlF
6共0,6兲⫺5共0,5兲 4⫺3
3.41
131956.217*共21兲
HCCN
6,5⫺5,4
132089.900*共81兲
4共0,4兲⫺3共0,3兲
132105.427*共25兲
H2 13CS CH3 OCHO
132107.228*共29兲
CH3 OCHO
132114.050*共5兲 132158.692*共35兲 132163.136*共33兲
C5 H
132178.9共5兲
C4 H
132245.048*共25兲
2
H2 COH⫹ CH3 OCHO
0.8f 0.06b
SgrB2共M兲
BTL 7 m
Cum86
0.80f
SgrB2共M兲 IRC⫹10216
BTL 7 m IRAM 30 m
Cum86 Cer87c
0.71f
IRC⫹10216
IRAM 30 m
Cer00
0.08
SgrB2共M兲
BTL 7 m
Cum86
12共1,12兲⫺11共1,11兲E
0.10b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
12共1,12兲⫺11共1,11兲A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
12共1,11兲⫺12共0,12兲
b
SgrB2共M兲
BTL 7 m
Cum86
2
⌸3/2 J⫽55/2⫺53/2a
0.25f
IRC⫹10216
IRAM 30 m
Cer00
2
⌸3/2 J⫽55/2⫺53/2b
0.28f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
⌸1/2 J⫽27/2⫺25/2 v7 ⫽1e 2共1,1兲⫺1共1,0兲
5.90f 0.055
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
SgrB2共M兲
NRO 45 m
Ohi96
12共0,12兲⫺11共0,11兲E
0.18b
SgrB2共M兲
BTL 7 m
Cum86
34
SO2 C5 H
132219.704*共18兲
JPL01
Oes99
15⫺14
b
SgrB2共M兲
BTL 7 m
Cum86
Laf78
132246.752*共29兲
H13CCCN CH3 OCHO
12共0,12兲⫺11共0,11兲A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
132356.711*共5兲 132524.590*共15兲
HNCO CH2 CHCN
6共1,5兲⫺5共1,4兲 14共2,13兲⫺13共2,12兲
0.19 0.15b
SgrB2共M兲 SgrB2共M兲
BTL 7 m BTL 7 m
Cum86 Cum86
132524.820*共4兲
CH3 OCH3
8共0,8兲⫺7共1,7兲AA
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
132525.252*共4兲
CH3 OCH3
8共0,8兲⫺7共1,7兲EE
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
132525.683*共4兲
CH3 OCH3
8共0,8兲⫺7共1,7兲EA⫹AE
b
SgrB2共M兲
BTL 7 m
Cum86
Gro98
132546.54*共14兲
C4 H
COL01
132246.385*共13兲
132560.137*共55兲 132579.251共58兲 132586.8共3兲 132621.859*共18兲 132626.807*共64兲 U
24
23/2,11⫺21/2,10
131267.478*共17兲
U
SO2 t⫺CH3 CH2 OH unidentified
MgNC CH2 CHCN
131256.832*共20兲
U
unidentified
Lab. Ref.
132691.2共4兲 132743.681共43兲
2
⌸3/2 J⫽27/2⫺25/2 v7 ⫽2ᐉ⫽2
1.42f
IRC⫹10216
IRAM 30 m
Cer00
⌸1/2 J⫽95/2⫺93/2e 13.5⫺12.5
0.34f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
0.43f
IRC⫹10216
IRAM 30 m
Cer00
COL01
⌸1/2 J⫽27/2⫺25/2 v7 ⫽1f 6共2,5兲⫺7共1,6兲A⫺
5.30f 0.12
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
⌸1/2 J⫽95/2⫺93/2f
0.54f
SgrB2共M兲 IRC⫹10216
BTL 7 m IRAM 30 m
Cum86 Cer00
Xu_97 JPL01
0.21f
IRC⫹10216
IRAM 30 m
Cer00
0.85f
IRC⫹10216
IRAM 30 m
Cer00
C6 H
2
13
C CCCH C4 H CH3 OH C6 H
2
2
unidentified CC13CCH
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
14.5⫺13.5
COL01
MICROWAVE TRANSITIONS
235
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
132744.820*共5兲 132782.0共10兲
SO2 unidentified
14共2,12兲⫺14共1,13兲
0.57
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Pic79 Cer00
132782.090共38兲
CC13CCH CH3 OH CH2 CHCN
IRC⫹10216
IRAM 30 m
Cer00
COL01
BTL 7 m BTL 7 m
Cum86 Cum86
Xu_97
0.11b
SgrB2共M兲 SgrB2共M兲
132890.800*共14兲 132917.762*共12兲
CH2 CHCN
14共4,10兲⫺13共4,9兲
b
SgrB2共M兲
BTL 7 m
Cum86
CH3 OCHO
11共1,10兲⫺10共1,9兲E
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
132928.769*共28兲
CH3 OCHO
11共1,10兲⫺10共1,9兲A
b
SgrB2共M兲
BTL 7 m
Cum86
Oes99
132935.088*共16兲
t⫺CH3 CH2 OH
3共2,1兲⫺2共1,2兲
b
SgrB2共M兲
BTL 7 m
Cum86
132946.571*共6兲
CCCS
23⫺22
1.4f
IRC⫹10216
IRAM 30 m
Cer87b
132993.978共50兲
c⫺C3 H
3共1,3兲⫺2共1,2兲7/2⫺5/2 F⫽4⫺3
1.47fb
IRC⫹10216
IRAM 30 m
Cer00
JPL01
132994.679共50兲
3共1,3兲⫺2共1,2兲7/2⫺5/2 F⫽3⫺2 50⫺49
b
IRC⫹10216
IRAM 30 m
Cer00
JPL01
133118.220*共4兲
c⫺C3 H HC5 N
0.72f
IRC⫹10216
IRAM 30 m
Cer00
133186.451共50兲
c⫺C3 H
3共1,3兲⫺2共1,2兲5/2⫺3/2 F⫽2⫺1
1.27fb
IRC⫹10216
IRAM 30 m
Cer00
JPL01
133187.717共50兲
3共1,3兲⫺2共1,2兲5/2⫺3/2 F⫽3⫺2 14.5⫺13.5
b
IRC⫹10216
IRAM 30 m
Cer00
JPL01
133213.648*共8兲
c⫺C3 H C4 H
24.3f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
133252.147*共8兲
C4 H
13.5⫺12.5
IRC⫹10216
IRAM 30 m
Cer00
JPL01
133405.264*共24兲 133605.385*共13兲 133672.86共40兲
H2 CCCC CH3 OH
15共1,15兲⫺14共1,14兲 5共⫺2,4兲⫺6共⫺1,6兲E 6共0,6兲⫺5共0,5兲
25.4f 0.063 0.19 n.r.
IRC⫹10216 SgrB2共M兲 IRC⫹10216
IRAM 30 m BTL 7 m IRAM 30 m
Cer91a Cum86 Cer91b
Kil90 Xu_97 Cer91b
1.49
OriMC⫺1 IRC⫹10216
BTL 7 m IRAM 30 m
Gol81 Cer91b
30
SiC2 OCS
11⫺10 6共0,6兲⫺5共0,5兲
133830.494*共7兲 133847.3
Si13CC CH3 CHO CH2 DOH
133854.105*共7兲 133862.50共20兲
CH3 CHO C4 H
133872.9
CH2 DOH
133881.8 133892.9 133897.4 133918.54共20兲
CH2 DOH CH2 DOH CH2 DOH C4 H
133925.4共5兲 133930.2 133931.283*共25兲
CH3 OD CH2 DOH H2 CCCC
J⫽14⫺13 v7 ⫽2U 1共1,0兲⫺1共0,1兲A 3共2,1兲⫺2共2,0兲e1 15共3,13兲⫺14共3,12兲
133931.294*共25兲
H2 CCCC
15共3,12兲⫺14共3,11兲
133952.921*共22兲
H2 CCCC
133961.139*共22兲
7共0,7兲⫺6共0,6兲E
0.9f 0.16
SgrB2共M兲
BTL 7 m
Cum86
0.60f 0.15 0.2
IRAS16293⫺2422
IRAM 30 m
Par02
Par02
SgrB2共M兲 IRC⫹10216
BTL 7 m IRAM 30 m
Cum86 Gue87a
Kle96 Gue87a
0.60f
IRAS16293⫺2422
IRAM 30 m
Par02
Par02
0.07 0.05 0.08
IRAS16293⫺2422 IRAS16293⫺2422 IRAS16293⫺2422
IRAM 30 m IRAM 30 m IRAM 30 m
Par02 Par02 Par02
Par02 Par02 Par02
0.2
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
0.06 0.07
IRAS16293⫺2422 IRAS16293⫺2422 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m
Par02 Par02 Cer00
And88 Par02
0.83fb
IRC⫹10216
IRAM 30 m
Cer00
15共2,14兲⫺14共2,13兲
0.26f
IRC⫹10216
IRAM 30 m
Cer00
H2 CCCC
15共2,13兲⫺14共2,12兲
0.27f
IRC⫹10216
IRAM 30 m
Cer00
133963.133*共23兲
H2 CCCC
15共0,15兲⫺14共0,14兲
IRC⫹10216
IRAM 30 m
Cer00
134004.803*共4兲 134023.71*共12兲
SO2 C4 H
8共2,6兲⫺8共1,7兲
0.25f 0.65
⌸3/2 J⫽29/2⫺27/2e v7 ⫽1
7.58f
OriMC⫺1 IRC⫹10216
MMWO 4.9 m IRAM 30 m
Pic79 Cer00
OriMC⫺1
IRAM 30 m
Jac92
Jac93
IRAM 30 m IRAM 30 m MMWO 4.9 m MMWO 4.9 m IRAM 30 m
Par02 Par02 Lor85 Lor85 Yam87b
Par02 Par02 Xu_97 Yam87b
3共0,3兲⫺2共0,2兲e1 7共0,7兲⫺6共0,6兲A⫹⫹ 2⌺
J⫽14⫺13 v7 ⫽2L 3共0,3兲⫺2共0,2兲o1 3共2,2兲⫺2共2,1兲o1 3共2,2兲⫺2共2,1兲e1 3共2,1兲⫺2共2,0兲o1
2⌺
2
b
134065.60共5兲
CH2 DOH
3共0,3兲⫺2共0,2兲
134112.4 134185.4 134231.013*共20兲 134284.909*共6兲
CH2 DOH CH2 DOH CH3 OH HDCO C4 H
3共2,2兲⫺2共2,1兲e0 3共2,1兲⫺2共2,0兲e0 12共⫺3,10兲⫺13共⫺2,12兲E 2共1,1兲⫺1共1,0兲
0.4f 0.06 0.06 0.24 0.19
⌸3/2 J⫽29/2⫺27/2 v7 ⫽1f
Kle96
COL01
4.50f
IRAS16293⫺2422 IRAS16293⫺2422 OriMC⫺1 OriMC⫺1 IRC⫹10216
134440.406*共35兲
C6 H
2
⌸3/2 J⫽97/2⫺95/2e
0.64f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
134499.192*共37兲
C6 H
2
IRAM 30 m
Cer00
JPL01
134603.073共30兲
H2 CCCC l⫺C3 H
0.69f 0.070
IRC⫹10216
134525.237*共27兲
⌸3/2 J⫽97/2⫺95/2f 15共1,14兲⫺14共1,13兲 N⫽6⫺5 v4⫽1a
1.40f
IRC⫹10216 IRC⫹10216
IRAM 30 m IRAM 30 m
Cer91a Cer00
Kil90 Yam90a
134628.089共30兲
l⫺C3 H
N⫽6⫺5 v4⫽1b
1.83f
IRC⫹10216
IRAM 30 m
Cer00
Yam90a
134921.19*共14兲
C4 H
⌸5/2 J⫽29/2⫺27/2 v7 ⫽2ᐉ⫽2
1.59f
IRC⫹10216
IRAM 30 m
Cer00
COL01
0.28f 0.64
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1
MMWO 4.9 m
Van84
1.16f
IRC⫹10216
IRAM 30 m
Cer00
0.62f
IRC⫹10216
IRAM 30 m
Cer00
0.69f n.r.
IRC⫹10216
IRAM 30 m
Cer00
JPL01
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b
⌸1/2 J⫽97/2⫺91/2f
0.80f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
5共1,5兲⫺4共0,4兲 4共3兲⫺3共2兲
1.5 0.62
rhoOph rhoOphA
MMWO 4.9 m MMWO 4.9 m
Got78 Lor85
OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m
Com96 Com96 Com96
OriMC⫺1
IRAM 30 m
Com96
135237.8共7兲 135298.151*共49兲 135303.313*共94兲 135307.7共8兲 135349.197*共50兲 135371.19共30兲
2
2
unidentified H2 CS NaCN
4共1,4兲⫺3共1,3兲 9共1,9兲⫺8共1,8兲
unidentified C6 H
2
29
135417.393*共59兲
SiC2 C6 H
135696.004*共4兲
SO2
135775.648*共18兲 U U
2.00f 2.07
132921.889*共25兲
134415.5共3兲
U
13.5⫺12.5 6共⫺1,6兲⫺5共0,5兲E 14共4,11兲⫺13共4,10兲
132919.017*共12兲
133785.897*共1兲 133813.85*共14兲
U
2.00f
Lab. Ref.
34 SO unidentified unidentified
2
⌸1/2 J⫽97/2⫺95/2e 6共0,6兲⫺5共0,5兲
135811.3 135824.6 135830.612*共23兲
t⫺CH3 CH2 OH
13共2,12兲⫺13共1,13兲
0.03 0.05 n.r.
135839.240*共29兲
t⫺CH3 CH2 OH
24共3,21兲⫺24共2,22兲
n.r.
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
236
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U
U
U U U
U U U U U U
U
Source
Telescope
Astr. Ref.
Lab. Ref.
HC13CCN
15⫺14
0.012 n.r.
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
135898.630*共13兲
HCC13CN unidentified CH3 OCHO unidentified CH3 OCHO CH3 OCHO CH3 OD
15⫺14
n.r.
OriMC⫺1
IRAM 30 m
Com96
135915.9 135921.969*共25兲 135931.9 135942.911*共25兲 135948.857*共32兲 135958.38共5兲
0.07 n.r. 0.32 n.r. n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM IRAM
Com96 Com96 Com96 Com96 Com96
IRAM 30 m
Jac93
Jac93
SO2 CH3 OD
34共5,29兲⫺33共6,28兲 3共⫺1,2兲⫺2共⫺1,1兲E
0.7f n.r.
OriMC⫺1
135963.039*共7兲 135972.50共5兲
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Jac93
Jac93
135979.676*共13兲
CH3 CH2 CN CH3 OCHO unidentified unidentified CH3 OD
23共3,21兲⫺23共2,22兲 11共5,6兲⫺10共5,5兲A
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM IRAM
m m m m m
Com96 Com96 Com96 Com96 Jac93
IRAM 30 m
Cer00
JPL01
IRAM IRAM IRAM IRAM
Com96 Com96 Com96 Jac93
Kau80
135988.511*共25兲 U135999.0 136005.3 136026.40共5兲
C5 H
11共5,7兲⫺10共5,6兲A 11共5,7兲⫺10共5,6兲E 11共5,6兲⫺10共5,5兲E 3共0,3兲⫺2共0,2兲E
0.6f n.r. n.r. 0.15 0.04
3共0,3兲⫺2共0,2兲 A⫹⫹
1.2f
⌸1/2 J⫽57/2⫺55/2 a 3共2,兲⫺2共2,兲 A⫺⫺
0.88f n.r. 0.05 0.07
2
IRC⫹10216
30 30 30 30 30
30 30 30 30 30
Oes99 Oes99
Oes99
Jac93
3共2,1兲⫺2共2,0兲E
0.6f
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
136102.82共5兲
CH3 OD
3共2,1兲⫺2共2,0兲A⫹⫹
0.5f
OriMC⫺1
IRAM 30 m
Jac93
Jac93
136107.60共5兲
CH3 OD
3共⫺2,2兲⫺2共⫺2,1兲E
OriMC⫺1
IRAM 30 m
Jac93
Jac93
136118.0 136121.9 136142.7 136151.26共5兲
unidentified unidentified unidentified CH2 DOH
0.8f 0.08 0.11 0.08
3共2,1兲⫺2共1,1兲
0.6f
136171.61共5兲
CH3 OD
3共1,2兲⫺2共1,1兲E
0.8f 0.05 0.05 0.04 n.r 0.06 0.09 0.04
IRAM IRAM IRAM IRAM
30 30 30 30
m m m m
Oes99
CH3 OD unidentified unidentified CH3 OD
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1⫺6⬙
30 30 30 30
m m m m m
136055.46共5兲 136085.9 136094.8 136098.96共5兲
m m m m
Jac93
Com96 Com96 Com96 Jac92
Jac93
OriMC⫺1
IRAM 30 m
Jac93
Jac93
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m BTL 7 m BTL 7 m
Com96 Com96 Com96 Com96 Com96 Com96 Cum86 Cum86
Oes99
BTL 7 m
Cum86
Oes99
136188.2 136198.2 136208.3 136219.373*共26兲 136230.8 136246.5 136250.7共11兲 136279.960*共25兲
unidentified unidentified unidentified CH3 CCCN unidentified unidentified unidentified CH3 OCHO
11共4,8兲⫺10共4,7兲E
0.12b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲 SgrB2共M兲
136282.626*共25兲
CH3 OCHO
11共4,8兲⫺10共4,7兲A
b
SgrB2共M兲
136292.559*共12兲
CH3 CCCN
33共5兲⫺32共5兲
136298.7 136304.335*共13兲 136313.496*共14兲 136320.042*共15兲 136323.970*共15兲
unidentified CH3 CCCN CH3 CCCN CH3 CCCN CH3 CCCN
33共4兲⫺32共4兲 33共3兲⫺32共3兲 33共2兲⫺32共2兲
n.r 0.11 n.r. n.r. n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM IRAM
m m m m m
Com96 Com96 Com96 Com96 Com96
33共1兲⫺32共1兲
n.r.b
OriMC⫺1
IRAM 30 m
Com96
136325.279*共15兲
CH3 CCCN
33共0兲⫺32共0兲
n.r.b n.r.
OriMC⫺1
IRAM 30 m
Com96
OriMC⫺1
IRAM 30 m
Com96
0.49f
IRC⫹10216
IRAM 30 m
Cer00
3⫺2
0.63f
IRC⫹10216
IRAM 30 m
Cer00
HCCCN HCCCN
15⫺14 15⫺14 v5 ⫽1 ᐉ⫽1 e
1.5 0.88
Sgr B2共M兲 Sgr B2共N兲
MMWO 4.9 m IRAM 30 m
Mor77 Vic00
Laf78
CH3 CH2 CN HCCCN
15共1,14兲⫺14共1,13兲 15⫺14 v5 ⫽1 ᐉ⫽1 f
0.10 0.48
Sgr B2共M兲 Sgr B2共N兲
BTL 7 m IRAM 30 m
Cum86 Vic00
Laf78
SO CH3 CCH CH3 CCH CH3 CCH CH3 CCH HCCCN unidentified
5共6兲⫺5共5兲 8共3兲⫺7共3兲 8共2兲⫺7共2兲 8共1兲⫺7共1兲 8共0兲⫺7共0兲 15⫺14 v7 ⫽1 ᐉ⫽1 e
0.4 0.17 0.20 0.41 0.42 0.09
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
Mun84 Mun84 Mun84 Mun84 Mun84 Cum86
Laf78
0.72f
IRC⫹10216
IRAM 30 m
Cer00
0.65fb
IRC⫹10216
IRAM 30 m
Cer00
JPL01
b
IRC⫹10216
IRAM 30 m
Cer00
JPL01
1.65f n.r.
IRC⫹10216
IRAM 30 m
Cer00
Laf78
IRC⫹10216
IRAM 30 m
Cer91b
0.138
IRC⫹10216 OriMC⫺1
BTL 7 m MMWO 4.9 m
Tha84 Van84
136346.7共8兲 136386.984*共30兲 136464.403*共4兲 136475.32*(19) 136541.298*共10兲
U
T r 共K兲/T a 共K兲
unidentified
136343.656*共5兲 U
Quantum numbers
135852.9 135885.514*共20兲
136051.195*共33兲 U U
Formula
136551.67*(19) 136634.673*共39兲 136704.502*共1兲 136717.560*共1兲 136725.398*共1兲 136728.010*共1兲 136799.703*共30兲 136917.7共20兲
33共9兲⫺32共9兲
20共6,14兲⫺21共5,17兲
34
SO2 unidentified 13 34
C S
136963.005*共36兲
C5 H
2
136967.767*共35兲
C5 H
2
136995.636*共31兲
HCCCN
137016.23* 共60兲
⌸3/2 J⫽57/2⫺55/2 a
⌸3/2 J⫽57/2⫺55/2 b 15⫺14 v7 ⫽1 ᐉ⫽1 f
30
SiC2
6共2,5兲⫺5共2,4兲
30 30 30 30 30
MMWO 4.9 MMWO 4.9 MMWO 4.9 MMWO 4.9 MMWO 4.9 BTL 7 m
m m m m m
137180.777*共68兲
SiC2
137369.316*共58兲
H2 CS
6共0,6兲⫺5共0,5兲 4共3,2兲⫺3共3,1兲
137369.348*共58兲
H2 CS
4共3,1兲⫺3共3,0兲
b
OriMC⫺1
MMWO 4.9 m
Van84
137371.072*共56兲
H2 CS H2 CS H2 CS
4共0,4兲⫺3共0,3兲 4共2,3兲⫺3共2,2兲 4共2,2兲⫺3共2,1兲
0.37 0.10 0.09
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Van84 Van84 Van84
137381.962*共39兲 137411.810*共39兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
0.12b
MICROWAVE TRANSITIONS
237
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
13
2共1,2兲⫺1共1,1兲
0.2
OriMC⫺1
MMWO 4.9 m
Kut76
137637.10*共8兲
Si13CC
6共2,5兲⫺5共2,4兲
IRC⫹10216
IRAM 30 m
Cer91b
137739.28* 共47兲
30
6共4,3兲⫺5共4,2兲
0.8f n.r.
IRC⫹10216
IRAM 30 m
Cer91b
137742.30* 共47兲
30
6共4,2兲⫺5共4,1兲
n.r.
IRC⫹10216
IRAM 30 m
Cer91b
137449.957*共5兲
CO
H2
SiC2 SiC2
Lab. Ref.
137763.2共3兲
C13CCN
14⫺13 a
1.17f
IRC⫹10216
IRAM 30 m
Cer00
137778.3共5兲
C13CCN
14⫺13 b
0.55f
IRC⫹10216
IRAM 30 m
Cer00
Got83
0.70fb
IRC⫹10216
IRAM 30 m
Cer00
COL01
Got83
137806.92*共3兲
13
15.5⫺14.5
137810.85*共4兲
13
15.5⫺14.5
b
IRC⫹10216
IRAM 30 m
Cer00
COL01
137839.78* 共10兲
13
14.5⫺13.5
0.40fb
IRC⫹10216
IRAM 30 m
Cer00
COL01
137843.61* 共10兲
13
14.5⫺13.5
b
IRC⫹10216
IRAM 30 m
Cer00
COL01
0.8
BTL 7 m IRAM 30 m
Woo84 Cer00
Xu_97
0.75f
OriMC⫺1 IRC⫹10216
Got83
CCCCH CCCCH CCCCH
137935.7共8兲
CCCCH CH3 OH unidentified
137996.2共2兲
CC13CN
14⫺13 a
1.30f
IRC⫹10216
IRAM 30 m
Cer00
138014.7共3兲
CC13CN
14⫺13 b
1.17f
IRC⫹10216
IRAM 30 m
Cer00
Got83
138023.5共15兲
26
MgNC
23/2,12⫺21/2,11
0.42f
IRC⫹10216
IRAM 30 m
Gue95
Gue95
138038.0共15兲
26
MgNC C6 H
25/2,12⫺23/2,11
0.31f
IRC⫹10216
IRAM 30 m
Gue95
Gue95
138138.153*共45兲
⌸1/2 J⫽99/2⫺97/2 e
0.23f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
138178.682*共16兲 138207.892*共53兲
SO C6 H
2.0 0.15f
OriMC⫺1 IRC⫹10216
MMWO 4.9 m IRAM 30 m
Got73b Cer00
JPL01
138220.49*(14)
Si13CC
0.87bf
IRC⫹10216
IRAM 30 m
Cer00
138220.51*(14) 138259.9
Si13CC unidentified
6共5,2兲⫺5共5,1兲
b
IRC⫹10216
IRAM 30 m
Cer00
U
OriMC⫺1
TRAO 14 m
Lee01
CH3 CHO CH3 CHO unidentified
7共1,6兲⫺6共1,5兲 E 7共1,6兲⫺6共1,5兲 A⫺⫺
U
138284.995*共7兲 138319.636*共7兲 138343.2
Sgr B2共M兲 Sgr B2共M兲 OriMC⫺1
BTL 7 m BTL 7 m TRAO 14 m
Cum86 Cum86 Lee01
138351.052*共10兲
CH3 CH2 CN CH2 CHCN
16共1,16兲⫺15共1,15兲 15共1,15兲⫺14共1,14兲
1.3f
Sgr B2共M兲 OriMC⫺1
BTL 7 m TRAO 14 m
Cum86 Lee01
CCC13CH HC5 N
15.5⫺14.5
0.67f
IRC⫹10216
IRAM 30 m
Cer00
138441.671*共4兲
52⫺51
0.41f
IRC⫹10216
IRAM 30 m
Cer00
137902.997*共18兲 U
138395.145*共2兲 138419.531*共32兲
U
2
4共3兲⫺3共2兲 2
⌸1/2 J⫽99/2⫺97/2 f 6共5,2兲⫺5共5,1兲
0.9f 0.15 0.14 0.8f 0.15
Kle96 Kle96
COL01
138456.937*共37兲
CCC13CH
14.5⫺13.5
0.38f
IRC⫹10216
IRAM 30 m
Cer00
138509.19*(10)
Si13CC
6共4,3兲⫺5共4,2兲
0.65bf
IRC⫹10216
IRAM 30 m
Cer00
138513.45*(10) 138515.73*共4兲
Si13CC CCCN
6共4,2兲⫺5共4,1兲
b
IRC⫹10216
IRAM 30 m
Cer00
14⫺13 a
26.3f
IRC⫹10216
IRAM 30 m
Cer00
Got83
138534.49*共4兲
CCCN
14⫺13 b
27.9f
IRC⫹10216
IRAM 30 m
Cer00
Got83
IRC⫹10216 IRC⫹10216
NRAO 12 m IRAM 30 m
Tur94 Cer00
IRC⫹10216 IRC⫹10216
NRAO 12 m IRAM 30 m
Tur94 Cer00 Cer87b
138567.0 138581.895*共36兲
unidentified 8⫺7
0.78f
138652.053*共85兲 138652.053*共85兲
NaCN NaCN
9共0,9兲⫺8共0,8兲 9共0,9兲⫺8共0,8兲
0.010
138725.846*共6兲
CCCS
24⫺23
138739.313*共29兲
U
7共⫺4,4兲⫺8共⫺3,6兲 E
138901.86*(47) 139256.7 139315.191*共32兲 139335.995*共10兲 139355.033*共3兲
29
Si34S
0.006
1.80f
IRAM 30 m
3⫺2
1.6f 0.5
IRC⫹10216
CS
OriMC⫺1
MMWO 4.9 m
Wil71
SiC2
6共2,5兲⫺5共2,4兲
n.r.
IRC⫹10216
IRAM 30 m
Cer91b
0.9f 0.119
OriMC⫺1
TRAO 14 m
Lee01
5共1,5兲⫺4共0,4兲
Sgr B2共N兲
NRAO 12 m
Tur01
OriMC⫺1
TRAO 14 m
Lee01 Lee01
13 29
unidentified a⫺CH2 CHOH CH3 CH2 CN
16共0,16兲⫺15共0,15兲
2.5f
SO2
5共3,3兲⫺6共2,4兲
COL01
Tur94
3.8f
OriMC⫺1
TRAO 14 m
U
139371.7共3兲
unidentified
1.52f
IRC⫹10216
IRAM 30 m
Cer00
U
139416.9
unidentified
0.8f
OriMC⫺1
TRAO 14 m
Lee01
U
139432.5
unidentified
1.8f
OriMC⫺1
TRAO 14 m
Lee01
U
139436.0
unidentified
1.1f
OriMC⫺1
TRAO 14 m
Lee01
0.9f 0.17
OriMC⫺1
TRAO 14 m
Lee01
MMWO 4.9 m TRAO 14 m
Lor84a Lee01
Gro98
U U
139474.480*共4兲
SO2
26共7,19兲⫺27共6,22兲
139483.486*共49兲 139500.411*共6兲
H2 CS CH3 OCH3
4共1,3兲⫺3共1,2兲 9共3,6兲⫺9共2,7兲 AE
0.7f
rhoOphB1 OriMC⫺1
139503.666*共4兲
CH3 OCH3
9共3,6兲⫺9共2,7兲 EE
0.9f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
139506.852*共8兲
CH3 OCH3
9共3,6兲⫺9共2,7兲 AA
0.9f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
139561.9
unidentified
1.7f
OriMC⫺1
TRAO 14 m
Lee01
139582.1
unidentified
0.7f n.r.
OriMC⫺1
TRAO 14 m
Lee01
6共4,3兲⫺5共4,2兲
IRC⫹10216
IRAM 30 m
Cer91b
6共4,2兲⫺5共4,1兲
n.r.
IRC⫹10216
IRAM 30 m
Cer91b
1.5f
OriMC⫺1
TRAO 14 m
139676.81*(96) U
139680.21*(96) 139862.3
29
SiC2
29 SiC2 unidentified
Lee01
U U U U
139864.8 139873.4 139878.0 139880.9
unidentified unidentified unidentified unidentified
⬎0.3 0.18 0.58 0.20
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM
m m m m
Mau88a Mau88a Mau88a Mau88a
U
139896.5
unidentified
0.08
OriMC⫺1
IRAM 30 m
Mau88a
30 30 30 30
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
238
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U U U U U U U U U
U U
U U U U U U
139902.5 139907.2 139918.6 139934.5 139944.7 139954.453(20) 139960.3 139967.4 139983.590*共31兲 139999.9 140013.6 140019.7 140033.14*(16) 140042.1 140046.727*共33兲
U U U
Astr. Ref.
Lab. Ref.
7共0,7兲⫺6共0,6兲
0.10 0.09 0.16 0.12 0.15 0.08
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m BTL 7 m
Mau88a Mau88a Mau88a Mau88a Mau88a Cum86
unidentified unidentified C6 H
Rea86
0.18 0.16
OriMC⫺1 OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m
Mau88a Mau88a Cer00
unidentified unidentified unidentified CH3 OH
JPL01
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
IRAM 30 m IRAM 30 m IRAM 30 m BTL 7 m
Mau88a Mau88a Mau88a Cum86
unidentified C6 H
Xu_97
OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m
Mau88a Cer00
JPL01
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Mau88a Mau88a
2
⌸3/2 J⫽101/2⫺99/2 e
23共⫺2,22兲⫺23共1,22兲E
0.45f 0.17 0.08 0.76 0.03 0.06
2
⌸3/2 J⫽101/2⫺99/2 f 18共2,16兲⫺18共1,17兲 E 32共2,30兲⫺32共1,31兲
0.65f 0.20 0.21
140101.17*(45)
unidentified unidentified CH3 CH2 CN NaCN
27共4,23兲⫺27共3,24兲 9共7,2兲⫺8共7,1兲
140101.17*(45)
NaCN
9共7,3兲⫺8共7,2兲
140118.571*共84兲 140127.438*共32兲 140133.6共10兲
CH3 OCHO CH2 CO unidentified
18共2,16兲⫺18共1,17兲 A 7共1,7兲⫺6共1,6兲
1.39fb 0.30 0.15
140137.2 140141.6共6兲 140147.4共10兲
unidentified NH3 unidentified
2共1兲⫺1共1兲 v2 ⫽1
0.23f 0.02 0.11
140151.188*共37兲
CH3 OH unidentified unidentified unidentified
18共0,18兲⫺18共⫺1,18兲 E
11⫺10
140175.200 共50兲
Na37Cl CH3 OD
4共1,3兲⫺4共0,4兲 A⫺
140180.2 140180.747*共16兲
unidentified CCS
140194.094*共68兲
CH3 OCHO
140211.37*(24)
SiC3
24共4,20兲⫺24共4,21兲 A 12共6,6兲⫺11共6,5兲
SiC3
12共6,7兲⫺11共6,6兲
140160.6 140166.0 140174.6
140211.37*(24) 140236.6 140253.6 140283.0
8⫺7
30
SiS
10,11⫺9,10
11.7f
IRC⫹10216
IRAM 30 m
0.07 0.05 0.47
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
IRAM IRAM IRAM IRAM
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1 Sgr B2共M兲 IRC⫹10216
IRAM 30 m BTL 7 m IRAM 30 m
Mau88a Cum86 Cer00
OriMC⫺1 OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m
Mau88a Mau88a Cer00
0.5f
Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1
BTL 7 m IRAM 30 m IRAM 30 m TRAO 14 m
Cum86 Mau88a Mau88a Lee01
0.84f
IRC⫹10216
IRAM 30 m
Cer00
5.1f 0.10
OriMC⫺1
IRAM 30 m
Mau88
OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m
Mau88a Cer87b
OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m
Mau88a Cer00
b
0.21f 0.05 0.20 0.53
1.8f 0.15 b
0.24fb 0.12 0.16 0.05
140300.10*(37)
unidentified unidentified unidentified NaCN
9共6,3兲⫺8共6,2兲
b
140300.10*(37)
NaCN
9共6,4兲⫺8共6,3兲
140306.157*共4兲 140340.6*
SO2 SiC2
6共2,4兲⫺6共1,5兲 14共2,12兲⫺14共2,13兲 v3 ⫽1
0.66fb 0.75
140347.30*(12)
NaCN
9共2,8兲⫺8共2,7兲
140371.5
10共4,6兲⫺11共3,9兲
33
SO2
m m m m
IRC⫹10216
IRAM 30 m
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
IRAM IRAM IRAM IRAM
Cer00
Mau88a Mau88a Mau88a Cer00
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1 IRC⫹10216
MMWO 4.9 m IRAM 30 m
Pic79 Cer00
1.73f 0.13
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1
IRAM 30 m
Mau88a
0.29
IRAM 30 m BTL 7 m
Mau88a Cum86
3共1,3兲⫺2共1,2兲 A⫹
0.05b
140429.438*共17兲
15共0,15兲⫺14共0,14兲
b
Sgr B2共M兲
BTL 7 m
Cum86
140484.239*共30兲
NaCN
9共5,5兲⫺8共5,4兲
0.61fb
IRC⫹10216
IRAM 30 m
Cer00
140484.247*共30兲
NaCN
9共5,4兲⫺8共5,3兲
b
IRC⫹10216
IRAM 30 m
Cer00
0.44f
IRC⫹10216
IRAM 30 m
Cer00
140667.481*共23兲 140687.3共16兲
13
unidentified
And88
Oes99
Cer00
Xu_97
0.48f
IRC⫹10216
IRAM 30 m
Gue95
9共4,6兲⫺8共4,5兲
1.47f
IRC⫹10216
IRAM 30 m
Cer00
NaCN
9共4,5兲⫺8共4,4兲
1.50f 0.07
IRC⫹10216
IRAM 30 m
Cer00
Sgr B2共M兲 Sgr B2共M兲
BTL 7 m IRAM 30 m
Cum86 Cer88
Sgr B2共M兲 OriMC⫺1 IRC⫹10216
BTL 7 m MMWO 4.9 m IRAM 30 m
Fre79 Kut76 Cer00
Yam79
Rea86
7⫺6
40854.18*(17)
12共0,12兲⫺11共0,11兲 2共1,2兲⫺1共1,1兲 9共3,7兲⫺8共3,6兲
140877.729(20)
NH2 CN
7共1,6兲⫺6共1,5兲
140902.2共14兲 140920.168*共29兲
unidentified SiC2 NaCN
140937.75*(17)
Xu_97
12⫺11
HNCS H2 CO NaCN
140740.379*共4兲 140839.515*共7兲
Sch90
MgNC NaCN
35
unidentified CH3 NC
140733.941*共22兲
Oes99
Cer00
m m m m
0.51f
30 30 30 30
Oes99
Mau88a Mau88a Mau88a Cer00
CH3 OH CH2 CHCN
140486.0共20兲
unidentified
30 30 30 30
OriMC⫺1 Sgr B2共M兲
140666.62*(23)
U
Telescope
U140077.3 U140083.2 140097.142*共14兲
140504.1共15兲
U
Source
CH3 OCHO CH3 CH2 CN
140423.850*共6兲
U
T r 共K兲/T a 共K兲
unidentified unidentified unidentified unidentified unidentified NH2 CN
140348.748*共12兲 U
Quantum numbers
140047.327*共43兲 140058.000*共22兲 140073.959*共27兲
140174.636*共70兲
U
Formula
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
6共2,5兲⫺5共2,4兲 9共3,6兲⫺8共3,5兲
1.9f 0.05 4.5 0.50f 0.05
Sgr B2共M兲
BTL 7 m
Cum86
0.07 0.123
Sgr B2共M兲 IRC⫹10216
BTL 7 m BTL 7 m
Cum86 Tha84
1.40f
IRC⫹10216
IRAM 30 m
Cer00
Gue95
MICROWAVE TRANSITIONS
239
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 140956.20共50兲
SiC2
Lab. Ref.
IRAM 30 m
Mik89
Cer91b
BTL 7 m NRAO 12 m
Tur87b Tur87b
Wys72 Oes99
NRAO 12 m BTL 7 m
Tur87b Cum86
Oes99 Laf78 Laf78
Source
Telescope
6共2,4兲⫺5共2,3兲
0.03
IRC⫹10216
3⫺2 12共2,11兲⫺11共2,10兲 E
0.032 0.07
OriMC⫺1 OriMC⫺1
0.07 0.07
OriMC⫺1 Sgr B2共M兲
PN CH3 OCHO CH3 OCHO
141061.797*共15兲
H13CCCN
12共2,11兲⫺11共2,10兲 A 16⫺15
141061.797*共15兲
H13CCCN HC5 N
16⫺15
0.10
IRC⫹10216
IRAM 30 m
Mik89
53⫺52
0.50f 0.5
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Wil81 Cer00
141243.921*共28兲 141250.277*共32兲 141260.454*共28兲 141441.249*共12兲
CH3 OCHO
11共3,8兲⫺10共3,7兲 E 8⫺7
Si34S CH3 OCHO CH3 OH
Oes99
11共3,8兲⫺10共3,7兲 A
20.0f 0.4
OriMC⫺1
NRAO 11 m
Wil81
Oes99
0共0,0兲⫺1共1,1兲 E vt ⫽1
1.4f
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
141595.449*共5兲
13
3共0,3兲⫺2共0,2兲 E
0.44b
Sgr B2共M兲
BTL 7 m
Cum86
Xu_97
141597.135*共5兲
13
3共⫺1,3兲⫺2共⫺1,2兲 E
b
Sgr B2共M兲
BTL 7 m
Cum86
Xu_97
141602.486*共6兲
13
3共0,3兲⫺2共0,2兲 A⫹
b
Sgr B2共M兲
BTL 7 m
Cum86
Xu_97
141623.413*共5兲
13
3共⫺2,2兲⫺2共⫺2,1兲
b
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
141623.548*共5兲
13
3共2,1兲⫺2共2,0兲 E
2.0fb
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
3共1,2兲⫺2共1,1兲 E
2.0f
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
0.042b
IRC⫹10216
BTL 7 m
Tha85
Yam90a
b
Yam90a
CH3 OH CH3 OH CH3 OH CH3 OH
141629.277共6兲
CH3 OH CH3 OH
141635.836*共20兲
l⫺C3 H
2
⌸1/2 J⫽13/2⫺11/2 F⫽7⫺6 e
l⫺C3 H
2
⌸1/2 J⫽13/2⫺11/2 F⫽6⫺5 e
141636.395*共20兲
U
30
Astr. Ref.
T r 共K兲/T a 共K兲
Quantum numbers
140967.75共10兲 141037.639*共25兲 141044.385*共28兲
141103.341*共4兲
U
Formula
IRC⫹10216
BTL 7 m
Tha85
0.9f
OriMC⫺1
TRAO 14 m
Lee01
11共2,9兲⫺10共2,8兲 E
4.4f
OriMC⫺1
TRAO 14 m
Lee01
11共2,9兲⫺10共2,8兲 A
1.7f
OriMC⫺1
TRAO 14 m
Lee01
Oes99
0.062b
IRC⫹10216
BTL 7 m
Tha85
Yam90a
b
IRC⫹10216
BTL 7 m
Tha85
Yam90a
0.064 0.064
BTL 7 m BTL 7 m IRAM 30 m
Tha84 Tha84 Yam87b
Yam87b
141646.5
unidentified
141652.921*共25兲
CH3 OCHO
141667.046*共26兲
CH3 OCHO
141708.733*共20兲
l⫺C3 H
2
⌸1/2 J⫽13/2⫺11/2 F⫽7⫺6 f
141709.446*共20兲
l⫺C3 H
2
⌸1/2 J⫽13/2⫺11/2 F⫽6⫺5 f 6共4,3兲⫺5共4,2兲 6共4,2兲⫺5共4,1兲
Oes99
141751.54*共3兲 141755.41*共3兲 141783.3共4兲
SiC2 SiC2 C4 H
4.60f
141829.146*共6兲
CH3 OCH3
⌸1/2 J⫽29/2⫺27/2 v7 ⫽1 e 8共3,5兲⫺8共2,6兲 EA
IRC⫹10216 IRC⫹10216 IRC⫹10216
0.7f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
141832.251*共4兲
CH3 OCH3
8共3,5兲⫺8共2,6兲 EE
1.4f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
141835.501*共8兲
CH3 OCH3
8共3,5兲⫺8共2,6兲 AA
OriMC⫺1
TRAO 14 m
Lee01
Gro98
141983.748*共6兲
H2 13CO unidentified
2共0,2兲⫺1共0,1兲
0.8f 0.21
OriMC⫺1
BTL 7 m
Kah84
0.8f
OriMC⫺1
TRAO 14 m
Lee01
Si13CC C4 H
6共2,4兲⫺5共2,3兲
1.0f
IRC⫹10216
IRAM 30 m
Cer91b
⌸3/2 J⫽29/2⫺27/2 v7 ⫽2 ᐉ⫽2
0.93f
IRC⫹10216
IRAM 30 m
Cer00
COL01
⌸1/2 J⫽29/2⫺27/2 v7 ⫽1 f 9共0,9兲⫺8共1,8兲
4.70f 0.14
IRC⫹10216
IRAM 30 m
Yam87b
Yam87b
Sgr B2共M兲
BTL 7 m
Cum86
10⫺9
IRC⫹10216
IRAM 30 m
Cer87c
16共2,15兲⫺15共2,14兲 12⫺11
1.10f 0.07 0.08
Sgr B2共M兲 Sgr B2共M兲
BTL 7 m BTL 7 m
Cum86 Cum86
15共5,11兲⫺14共5,10兲
142054.4 142138.76* 共12兲 142214.24* 共13兲 142223.7共3兲 142285.096*共17兲 142321.60*共5兲 142346.313*共10兲 142379.431*共3兲
C4 H t⫺CH3 CH2 OH
2
2
2
Al37Cl CH3 CH2 CN
142399.489*共14兲
OC34 S CH2 CHCN
0.07b
Sgr B2共M兲
BTL 7 m
Cum86
142399.510*共14兲
CH2 CHCN
15共5,10兲⫺14共5,9兲
b
Sgr B2共M兲
BTL 7 m
Cum86
142401.867*共16兲
CH2 CHCN
15共6,*兲⫺14共6,*兲
b
Sgr B2共M兲
BTL 7 m
Cum86
142410.48* 共12兲
NaCN
9共2,7兲⫺8共2,6兲
1.33f
IRC⫹10216
IRAM 30 m
Cer00
142419.704*共19兲
CH2 CHCN
15共7,*兲⫺14共7,*兲
0.06b
Sgr B2共M兲
BTL 7 m
Cum86
142424.454*共13兲
CH2 CHCN
15共4,12兲⫺14共4,11兲
b
Sgr B2共M兲
BTL 7 m
Cum86
142426.506*共13兲
CH2 CHCN
15共4,11兲⫺14共4,10兲
b
Sgr B2共M兲
BTL 7 m
Cum86
142447.936*共21兲 142501.701*共11兲
CH2 CHCN CCS
15共8,*兲⫺14共8,*兲 11,11⫺10,10
Sgr B2共M兲 IRC⫹10216
BTL 7 m IRAM 30 m
Cum86 Cer00
142522.759*共21兲
C36S
3⫺2
142558.809*共14兲
29
8⫺7
SiS
0.07 1.50f 0.06 21.8f
NGC6334A
SEST 15m
Mau96
IRC⫹10216
IRAM 30 m
Cer00
U
142611.3共20兲
unidentified
0.30f
IRC⫹10216
IRAM 30 m
Cer00
U
142621.9共20兲
unidentified
0.16f
IRC⫹10216
IRAM 30 m
Cer00
U
142676.8共8兲
unidentified
0.38f
IRC⫹10216
IRAM 30 m
Cer00
U
142688.4共8兲
unidentified
0.65f
IRC⫹10216
IRAM 30 m
Cer00
U
142697.6共15兲
unidentified
0.20f 0.11
IRC⫹10216
IRAM 30 m
Cer00
Sgr B2共M兲
BTL 7 m
Cum86
142701.320*共2兲 142728.773*共36兲
NH2 CHO C4 H
7共1,7兲⫺6共1,6兲
IRC⫹10216
IRAM 30 m
Cer00
JPL01
142733.443*共25兲
CH3 OCHO
13共1,13兲⫺12共1,12兲 E
0.05b
Sgr B2共M兲
BTL 7 m
Cum86
Oes99
142735.161*共29兲
CH3 OCHO
13共1,13兲⫺12共1,12兲 A
b
Sgr B2共M兲
BTL 7 m
Cum86
Oes99
142755.167*共29兲
C6 H
IRC⫹10216
IRAM 30 m
Cer00
JPL01
142767.280*共32兲
C4 H
142768.913*共32兲
CH2 CO
142807.681*共6兲 142815.395*共25兲
13
CH3 OH
CH3 OCHO
15.5⫺14.5
2
⌸3/2 J⫽103/2⫺101/2 e 14.5⫺13.5
23.4f
0.50f 25.8f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
7共1,6兲⫺6共1,5兲 3共1,2兲⫺2共1,1兲 A⫺
0.11 b
Sgr B2共M兲 Sgr B2共M兲
BTL 7 m BTL 7 m
Cum86 Cum86
Xu_97
13共0,13兲⫺12共0,12兲 E
0.04b
Sgr B2共M兲
BTL 7 m
Cum86
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
240
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
142817.042*共29兲
CH3 OCHO
142820.512*共31兲
C6 H
142831.1共10兲
U
BTL 7 m
Cum86
Oes99
IRAM 30 m
Cer00
JPL01
0.22f
IRC⫹10216
IRAM 30 m
Cer00
0.9f
G10.47
IRAM 30 m
Olm96
8共5兲⫺7共5兲
0.68fb
IRC⫹10216
IRAM 30 m
Cer00
16共3,13兲⫺15共3,12兲
b
IRC⫹10216
IRAM 30 m
Cer00
142878.641 共16兲
CP
3⫺2 J⫽5/2⫺3/2 F⫽3⫺2 8共4兲⫺7共4兲
0.30f
IRC⫹10216
IRAM 30 m
Cer00
3.8f
G10.47
IRAM 30 m
Olm96
CH3 CN
142891.707*共24兲
CH3 CN H2 CCCC
16共0,16兲⫺15共0,15兲
0.40fb
IRC⫹10216
IRAM 30 m
Cer00
142891.831*共23兲
H2 CCCC
16共2,14兲⫺15共2,13兲
b
IRC⫹10216
IRAM 30 m
Cer00
142891.958 共25兲
CP
0.40f
IRC⫹10216
IRAM 30 m
Cer00
142892.174*共28兲
H2 CCCC
3⫺2 J⫽5/2⫺3/2 F⫽2⫺1 16共1,15兲⫺15共1,14兲
0.98f
IRC⫹10216
IRAM 30 m
Cer00
142901.308*共19兲
13
8共3兲⫺7共3兲
5.5f
G10.47
IRAM 30 m
Olm96
142914.750*共20兲
13
8共2兲⫺7共2兲
4.2f
G10.47
IRAM 30 m
Olm96
142922.817*共20兲
13
8共1兲⫺7共1兲
b
G10.47
IRAM 30 m
Olm96
OriMC⫺1
TRAO 14 m
Lee01
G10.47
IRAM 30 m
Olm96
143006.7
CH3 CN CH3 CN
CH3 CN CH3 OCHO
13共1,13兲⫺12共0,12兲 E 8共0兲⫺7共0兲
13
CH3 CN
unidentified
b
Sai89
Oes99
0.7f 0.57 n.r.
OriMC⫺1
TRAO 14 m
Lee01
OriMC⫺1 IRC⫹10216
MMWO 4.9 m IRAM 30 m
Pic79 Cer91b
15⫺14 a
0.71f
IRC⫹10216
IRAM 30 m
Cer00
Got83
17共0,17兲⫺17共⫺1,17兲 E
1.7f
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
0.92f 2.9
IRC⫹10216
IRAM 30 m
Cer00
Got83
IRC⫹10216
IRAM 30 m
Gue93
Kaw93 Xu_97
29
SiC2
13
143124.0共20兲
13
CCCN
15⫺14 b
24
23/2,12⫺21/2,11
143169.536*共18兲
MgNC CH3 OH
7共3,4兲⫺8共2,6兲 E
2.4f
OriMC⫺1
TRAO 14 m
Lee01
143175.538*共17兲
Si33S
8⫺7
IRC⫹10216
IRAM 30 m
Cer00
25/2,12⫺23/2,11
3.50f 3.2
IRC⫹10216
IRAM 30 m
Gue93
11⫺10
1.47f
IRC⫹10216
IRAM 30 m
Cer87c
12共1,11兲⫺11共1,10兲 A
1.4f
OriMC⫺1
TRAO 14 m
Lee01
0.8f
OriMC⫺1
TRAO 14 m
Lee01
24
Sai89
16共2,14兲⫺16共1,15兲 6共2,4兲⫺5共2,3兲
SO2 CCCN CH3 OH
1.5f
143168.699*共10兲
143237.414*共70兲
U
Sgr B2共M兲 IRC⫹10216
16共3,14兲⫺15共3,13兲
143183.919*共10兲
U U
b
0.43f
H2 CCCC
143108.339*共31兲
U
13共0,13兲⫺12共0,12兲 A
unidentified
13
Lab. Ref.
⌸3/2 J⫽103/2⫺101/2 f
H2 CCCC
143104.0共20兲
U
Astr. Ref.
142859.148*共26兲
143057.069*共6兲 143061.65共40兲
U U
Telescope
142859.133*共26兲
142925.506*共20兲
U U
Source
13
142924.429*共25兲
U
2
T r 共K兲/T a 共K兲
142858.325*共20兲
142882.498*共19兲
U
Quantum numbers
MgNC
Cer91b
Kaw93
143240.535*共28兲
Na35Cl CH3 OCHO
143263.3
unidentified
143337.706*共8兲
CH3 CH2 CN
16共7,*兲⫺15共7,*兲
4.1f
OriMC⫺1
TRAO 14 m
Lee01
143343.885*共8兲
CH3 CH2 CN
16共9,*兲⫺15共9,*兲
2.3f
OriMC⫺1
TRAO 14 m
Lee01
143357.179*共10兲
CH3 CH2 CN
16共6,*兲⫺15共6,*兲
2.8f
OriMC⫺1
TRAO 14 m
Lee01
143357.808*共5兲
31共8,24兲⫺32共7,25兲 16共10,*兲⫺15共10,*兲
n.r.
143360.374*共8兲
SO2 CH3 CH2 CN
OriMC⫺1 OriMC⫺1
IRAM 30 m TRAO 14 m
Com96 Lee01
143377.367*共61兲 143383.017*共8兲 143390.2 143393.6 143407.248*共9兲
CH3 OCHO CH3 CH2 CN unidentified unidentified CH3 CH2 CN
24共4,20兲⫺24共3,21兲 A 16共11,*兲⫺15共10,*兲
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m TRAO 14 m
Com96 Com96 Com96 Com96 Lee01
143410.770*共8兲 143424.39共20兲
CH3 CH2 CN C4 H
16共12,*兲⫺15共12,*兲
2.9f n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m
Com96
⌺ J⫽15⫺14 v7 ⫽2 L
0.2
IRC⫹10216
IRAM 30 m
Gue87a
143429.958 共12兲
CP
3⫺2 J⫽7/2⫺5/2 F⫽4⫺3
0.040
IRC⫹10216
IRAM 30 m
Gue90
Sai89
143431.758 共21兲
CP
0.040
IRC⫹10216
IRAM 30 m
Gue90
Sai89
143442.976*共9兲 143446.3共3兲
CH3 CH2 CN C4 H
3⫺2 J⫽7/2⫺5/2 F⫽3⫺2 16共13,*兲⫺15共13,*兲
n.r. 0.25
OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m
Com96 Gue87a
Yam87b
143456.2 143461.0 143472.29*共7兲 143474.0 143479.200*共9兲
unidentified unidentified HCOOH unidentified CH3 CH2 CN
0.03 0.06 n.r. 1.2
OriMC⫺1 OriMC⫺1 OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2
IRAM IRAM IRAM IRAM IRAM
m m m m m
Com96 Com96 Com96 Jac90 Jac90
Wil80
143480.41共20兲
C4 H
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2
IRAM 30 m IRAM 30 m IRAM 30 m
Com96 Jac90 Jac90
OMC⫺IRc2 OMC⫺IRc2
IRAM 30 m IRAM 30 m
Jac90 Jac90
OMC⫺IRc2 OriMC⫺1 OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2 IRC⫹10216
IRAM IRAM IRAM IRAM IRAM IRAM
143490.3 143506.978*共9兲 143519.142*共10兲
unidentified CH3 CH2 CN CH3 CH2 CN
143524.885*共9兲 143529.201*共10兲 143535.292*共9兲
DCCCN CH3 CH2 CN CH3 CH2 CN
143555.2 143559.4 143565.018*共55兲 143570.318*共4兲 143575.8共15兲
unidentified unidentified NH2 CHO DNCO unidentified
143577.724*共19兲
C34S unidentified
143583.4
16共5,*兲⫺15共5,*兲 2
2
⌸3/2 J⫽31/2⫺29/2 v7 ⫽1 e
32共3,30兲⫺31共4,27兲 16共14,*兲⫺15共14,*兲 2
⌺ J⫽15⫺14 v7 ⫽2 U 16共4,13兲⫺15共4,12兲 16共15,*兲⫺15共15,*兲 17⫺16 16共3,14兲⫺15共3,13兲 16共4,12兲⫺15共4,11兲
2.5f n.r. n.r. 0.19 0.17
0.7b 0.2 0.02 4.3 0.6b 1.5 4.1
24共6,19兲⫺25共5,20兲 7共1,6兲⫺6共1,5兲
4.4 0.02 0.03 1.0 0.7
3⫺2 v⫽1
0.20f n.r.
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
0.07
30 30 30 30 30
30 30 30 30 30 30
m m m m m m
Jac90 Com96 Com96 Jac90 Jac90 Cer00
OriMC⫺1
IRAM 30 m
Com96
OriMC⫺1
IRAM 30 m
Com96
Oes99
Oes99
Gue87a
Laf78
MICROWAVE TRANSITIONS
241
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
U U U U U U U U U U
U U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
143589.9 143599.414*共6兲 143600.080*共6兲 143602.988*共4兲 143605.394*共5兲 143606.1共15兲
unidentified CH3 OCH3 CH3 OCH3 CH3 OCH3 AlNC unidentified
7共3,4兲⫺7共2,5兲 AE 7共3,4兲⫺7共2,5兲 EA 7共3,4兲⫺7共2,5兲 EE 12⫺11
0.6 0.9 1.3 2.9 0.006
143606.229*共8兲 143617.5 143627.7 143642.2 143645.378*共34兲 143646.6 143652.4 143659.7 143663.838*共5兲 143682.5 143699.7 143707. 143715.746*共36兲
CH3 OCH3 unidentified unidentified unidentified SiC3 unidentified unidentified unidentified SO2 unidentified unidentified unidentified C6 H
143727.210 共37兲 143741.650 共50兲
HDO CH3 OD
4共2,2兲⫺4共2,3兲 5共1,4兲⫺5共0,5兲 A⫺
143759.252*共16兲 143764.973*共4兲 143768.4共15兲
CH2 CHCN HC5 N unidentified
15共2,13兲⫺14共2,12兲 54⫺53
6.6f 1.2 0.3
143772.3 143784.079*共40兲 143788.619*共43兲
unidentified CH3 OCHO C6 H
18共3,16兲⫺18共2,17兲 E
0.07z 0.8 0.3
⌸1/2 J⫽103/2⫺101/2 e
0.27f
143793.881*共10兲
33
143795.863*共8兲
33
143799.338*共12兲
33
U U
143814.3 143821.6
unidentified unidentified
U U
143829.2 143841.7 143850.434*共77兲 143865.795*共4兲 143870.0共3兲
unidentified unidentified CH3 OCHO CH3 OH C4 H
143880.12* 共54兲 144007.0共5兲
H13COOH unidentified
144031.6共10兲
unidentified
U
30 30 30 30 30 30
m m m m m m
Jac90 Jac90 Jac90 Jac90 Ziu02 Cer00
OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2 OMC⫺IRc2 IRC⫹10216 OMC⫺IRc2 OMC⫺IRc2 OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2 OriMC⫺1 OMC⫺IRc2 IRC⫹10216
IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM
30 30 30 30 30 30 30 30 30 30 30 30 30
m m m m m m m m m m m m m
Jac90 Jac90 Jac90 Jac90 Ziu02 Jac90 Jac90 Com96 Jac90 Jac90 Com96 Jac90 Cer00
JPL01
OMC⫺IRc2 OriMC⫺1
IRAM 30 m IRAM 30 m
Jac90 Mau88
DeL71 And88
OMC⫺IRc2 OMC⫺IRc2 Sgr B2共M兲
IRAM 30 m IRAM 30 m BTL 7 m
Jac90 Jac90 Cum86
OMC⫺IRc2 OMC⫺IRc2 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m
Jac90 Jac90 Cer00 Com96
Gro98 Gro98 Gro98
Gro98
Oes99 JPL01
4共2,2兲⫺4共1,3兲 F⫽5.5⫺5.5 4共2,2兲⫺4共1,3兲
n.r.
OriMC⫺1
IRAM 30 m
0.5
OMC⫺IRc2
IRAM 30 m
Jac90
4共2,2兲⫺4共1,3兲 F⫽4.5⫺5.5
0.20
OriMC⫺1
IRAM 30 m
Com96
0.02 8⫺7 v⫽2
0.34f 0.03
OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m
Com96 Cer00
OriMC⫺1 OriMC⫺1
IRAM 30 m TRAO 14 m
Com96 Lee01
IRAM 30 m IRAM 30 m IRAM 30 m BTL 7 m IRAM 30 m
Jac90 Com96 Jac90 Cum86 Yam87b
Oes99 Xu_97 Yam87b Wil80
18共3,16兲⫺18共2,17兲 A 3共1,3兲⫺2共1,2兲 A⫹
0.8f 0.8 0.02 0.3 1.27
⌸3/2 J⫽31/2⫺29/2 v7 ⫽1 f
5.10f
OMC⫺IRc2 OriMC⫺1 OMC⫺IRc2 Sgr B2共M兲 IRC⫹10216
0.7
OMC⫺IRc2
IRAM 30 m
Jac90
0.75f
IRC⫹10216
IRAM 30 m
Cer00
7共3,4兲⫺8共2,7兲
IRAM 30 m
Cer00
OriMC⫺1
MMWO 4.9 m
Gue77a
144241.96共3兲
2⫺1 J⫽5/2⫺3/2 F⫽7/2⫺5/2
0.13b
OriMC⫺1
BTL 7 m
Vrt85
Vrt85
144243.05共3兲
C2 D
2⫺1 J⫽5/2⫺3/2 F⫽3/2⫺1/2
b
OriMC⫺1
BTL 7 m
Vrt85
Vrt85
144243.05共3兲
C2 D
2⫺1 J⫽5/2⫺3/2 F⫽5/2⫺3/2 12,11⫺11,10
b
OriMC⫺1
BTL 7 m
Vrt85
Vrt85
0.13
NRAO 11 m TRAO 14 m
Hol81 Lee01
2⫺1 J⫽3/2⫺1/2 F⫽5/2⫺3/2
2.4f 0.09
Sgr B2共M兲 OriMC⫺1
144244.835*共16兲 144267.0
CCS unidentified C2 D unidentified
U
144370.2
unidentified
1.3f
BTL 7 m
Vrt85
TRAO 14 m
Lee01 Lee01
Vrt85
2.0f
OriMC⫺1
TRAO 14 m
0.72f
IRC⫹10216
IRAM 30 m
Cer00
COL01
16共6,10兲⫺16共5,11兲 A 16共6,10兲⫺16共5,11兲 E
n.r. n.r. 0.08
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
IRAM IRAM IRAM IRAM
m m m m
Com96 Com96 Com96 Cer00
Oes99 Oes99
OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m
Com96 Cer87b
C4 H
144388.7 144428.067*共32兲 144449.123*共35兲 144456.1共10兲
unidentified CH3 OCHO CH3 OCHO unidentified
144480.8 144504.991*共6兲
unidentified CCCS
25⫺24
1.4f
SiS
8⫺7 v⫽1
1.64f 0.06
2
OriMC⫺1 OriMC⫺1
⌸5/2 J⫽31/2⫺29/2 v7 ⫽2 ᐉ⫽2
144375.97* 共13兲
144520.383*共9兲 U
IRAM IRAM IRAM IRAM IRAM IRAM
IRC⫹10216
144351.4
U
2
0.22f 2.6
OMC⫺IRc2 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216 IRC⫹10216
0.70f 0.3
U
U
2
⌸1/2 J⫽103/2⫺101/2 f
Lab. Ref.
2⫺1
144296.72共8兲
U
2
0.25f 2.1 1.7 0.8 0.5 0.008 0.4 0.3 0.04 0.4 0.7 0.12 0.3
Astr. Ref.
DCO⫹ C2 D
144077.321*共24兲
U
6共2,4兲⫺6共1,5兲 v2 ⫽1
SO2
143810.0 143813.625*共12兲
U
12共2,10兲⫺11共2,9兲
SO2
SO2 unidentified SiS
U
7共3,4兲⫺7共2,5兲 AA
Telescope
0.59f 0.12
30 30 30 30
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1 OriMC⫺1
IRAM 30 m TRAO 14 m
Com96 Lee01
Her84
0.7f
OriMC⫺1 OriMC⫺1
IRAM 30 m TRAO 14 m
Com96 Lee01
Her84
n.r.b
OriMC⫺1
IRAM 30 m
Com96
n.r.b n.r.
OriMC⫺1
IRAM 30 m
Com96
3共1,3兲⫺2共1,2兲 A⫹⫹ vt ⫽1
OriMC⫺1
IRAM 30 m
Com96
3⫺2
1.2
OriMC⫺1
MMWO 4.9 m
Wil76a
144529.7 144571.97共5兲
unidentified CH3 OH
3共0,3兲⫺2共0,2兲 A vt ⫽2
0.6f
144573.145*共19兲
35共3兲⫺34共3兲 3共⫺1,2兲⫺2共⫺1,1兲 E vt ⫽2
n.r.
144583.91共5兲
CH3 CCCN CH3 OH
144584.247*共16兲
CH3 CCCN
35共1兲⫺34共1兲
144585.635*共16兲
CH3 CCCN
35共0兲⫺34共0兲
144589.856*共6兲 144617.114*共11兲
CH3 OH C34S
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
242
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U
U
U U U
144650.1 144683.1 144728.356*共6兲 144728.775*共6兲 144729.071*共6兲
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
3共2,1兲⫺2共2,0兲 A⫹⫹ vt ⫽1 3共⫺2,1兲⫺2共⫺2,0兲 E vt ⫽1
0.05 0.08 n.r. n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM
m m m m
Com96 Com96 Com96 Com96
3共2,2兲⫺2共2,1兲 A⫺⫺ vt ⫽1 3共2,2兲⫺2共2,1兲 E vt ⫽1 3共⫺1,2兲⫺2共⫺1,1兲 E vt ⫽1
n.r. n.r. n.r. 0.5f n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m TRAO 14 m
Com96 Com96 Com96 Lee01
144733.243*共7兲 144750.242*共9兲 144762.2 144768.170*共12兲 144826.574*共2兲
CH3 OH DCN
3共0,3兲⫺2共0,2兲 A⫹⫹ vt ⫽1
OriMC⫺1
IRAM 30 m
Com96
2⫺1 F 1 ⫽2⫺2
b
OriMC⫺1
MMWO 4.9 m
Pen77
DeL69
144826.8097共10兲
DCN
2⫺1 F 1 ⫽1⫺0 F⫽2⫺1
b
OriMC⫺1
MMWO 4.9 m
Pen77
DeL69
144826.8414共10兲
DCN
2⫺1 F 1 ⫽1⫺0 F⫽1⫺1
b
OriMC⫺1
MMWO 4.9 m
Pen77
DeL69
144828.002*共2兲
DCN
2⫺1 F 1 ⫽2⫺1
0.9b
OriMC⫺1
MMWO 4.9 m
Pen77
DeL69
144828.111*共2兲
DCN
2⫺1 F 1 ⫽3⫺2
b
OriMC⫺1
MMWO 4.9 m
Pen77
DeL69
144830.338*共2兲
DCN
b
OriMC⫺1
MMWO 4.9 m
Pen77
DeL69
144855.074*共6兲
CH3 OCH3
2⫺1 F 1 ⫽1⫺1 6共3,3兲⫺6共2,4兲 AE
n.r.b
OriMC⫺1
IRAM 30 m
Com96
Gro98
144856.766*共8兲
CH3 OCH3
6共3,3兲⫺6共2,4兲 EA
n.r.b
OriMC⫺1
IRAM 30 m
Com96
Gro98
144858.987*共6兲
CH3 OCH3
6共3,3兲⫺6共2,4兲 EE
n.r.b
OriMC⫺1
IRAM 30 m
Com96
Gro98
144862.032*共8兲
CH3 OCH3
6共3,3兲⫺6共2,4兲 AA
n.r.b
OriMC⫺1
IRAM 30 m
Com96
Gro98
144878.572*共7兲
CH3 OH
3共1,2兲⫺2共1,1兲 A vt ⫽1
0.9f
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
144896.6共10兲
unidentified
30 30 30 30
Lab. Ref.
unidentified unidentified CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH unidentified
1.42f
IRC⫹10216
IRAM 30 m
Cer00
144943.469*共21兲
HC13CCN
16⫺15
2.86f
IRC⫹10216
IRAM 30 m
Cer00
Laf78
144957.466*共13兲
HCC13CN
16⫺15
2.66f
IRC⫹10216
IRAM 30 m
Cer00
Laf78
1.35f n.r.
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1 IRC⫹10216
IRAM 30 m IRAM 30 m
Com96 Cer00
OriMC⫺1 Cha⫺MMS1
NRAO 11 m SEST 15m
Hol81 Kon00
NRAO NRAO NRAO NRAO
m m m m
Kut73 Kut73 Kut73 Kut73
Xu_97 Xu_97 Xu_97 Xu_97
144968.0共10兲
unidentified
144971.0
unidentified NaCN
145075.53*(10) 145075.9共5兲 145089.620*共7兲
9共1,8兲⫺8共1,7兲
unidentified 3共1,2兲⫺2共2,1兲
1.50f 0.25 0.54
145097.443*共4兲 145103.194*共4兲 145124.334*共4兲
c⫺C3 H2 CH3 OH CH3 OH CH3 OH CH3 OH
3共0,3兲⫺2共0,2兲 E 3共⫺1,3兲⫺2共⫺1,2兲 E 3共0,3兲⫺2共0,2兲 A⫹ 3共2,2兲⫺2共2,1兲 A⫺
1.45b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
145126.190*共4兲
CH3 OH
3共2,1兲⫺2共2,0兲 E
b
OriMC⫺1
NRAO 11 m
Kut73
Xu_97
145126.392*共4兲
CH3 OH
3共⫺2,2兲⫺2共⫺2,1兲 E
b
OriMC⫺1
NRAO 11 m
Kut73
Xu_97
145127.534*共31兲
HCCCN
16⫺15 v7 ⫽1 ᐉ⫽1 f
1.29f
IRC⫹10216
IRAM 30 m
Cer00
Laf78
145131.872*共4兲
CH3 OH
3共1,2兲⫺2共1,1兲 E
1.25b
OriMC⫺1
NRAO 11 m
Kut73
Xu_97 Xu_97
145093.760*共4兲
145133.418*共4兲
CH3 OH
3共2,1兲⫺2共2,0兲 A⫹
145136.95*(17) 145227.034*共11兲 145325.849*共45兲 145418.033*共10兲 145526.735*共27兲
Si13CC SiS SiC2 CH3 CH2 CN C6 H
6共1,5兲⫺5共1,4兲
145560.950*共4兲 145594.309*共29兲
HCCCN C6 H
145602.949*共7兲 145675.601*共6兲
1.25 1.45 1.35
b
11 11 11 11
OriMC⫺1
NRAO 11 m
Kut73
IRC⫹10216
IRAM 30 m
Cer91b
IRC⫹10216 IRC⫹10216 OriMC⫺1 IRC⫹10216
BTL 7 m IRAM 30 m BTL 7 m IRAM 30 m
Hen85 Cer91b Woo84 Cer00
Sgr B2共M兲 IRC⫹10216
MMWO 4.9 m IRAM 30 m
Mor77 Cer00
JPL01
NRAO 11 m BTL 7 m
Tha71 Woo84
Gro98
8⫺7 6共2,4兲⫺5共2,3兲 16共1,15兲⫺15共1,14兲
0.9f 0.25 n.r. 0.1
⌸3/2 J⫽103/2⫺101/2 e 16⫺15
0.40f 0.8
H2 CO CH3 OCH3
⌸3/2 J⫽103/2⫺101/2 f 2共0,2兲⫺1共0,1兲 5共3,2兲⫺5共2,3兲 AE
0.65f 1.9 b
OriMC⫺1 OriMC⫺1
145679.943*共14兲
CH3 OCH3
5共3,2兲⫺5共2,3兲 EA
b
OriMC⫺1
BTL 7 m
Woo84
Gro98
145680.395*共6兲
CH3 OCH3
5共3,2兲⫺5共2,3兲 EE
0.1b
OriMC⫺1
BTL 7 m
Woo84
Gro98
145682.667*共8兲
CH3 OCH3
5共3,2兲⫺5共2,3兲 AA
b
OriMC⫺1
BTL 7 m
Woo84
Gro98
145744.62*共5兲
Al35Cl
10⫺9
IRC⫹10216
IRAM 30 m
Cer87c
2
2
2.42f
Cer91b JPL01
145755.620 共50兲
C33S
3⫺2 F⫽7/2⫺5/2
b
OriMC⫺1
MMWO 4.9 m
Wil76a
Bog81
145755.620 共50兲
C33S
3⫺2 F⫽9/2⫺7/2
0.2b
OriMC⫺1
MMWO 4.9 m
Wil76a
Bog81
145756.500 共50兲
C33S
3⫺2 F⫽3/2⫺1/2
b
OriMC⫺1
MMWO 4.9 m
Wil76a
Bog81
145756.500 共50兲
C33S CH3 OH
3⫺2 F⫽5/2⫺3/2 16共0,16兲⫺16共⫺1,16兲 E
b
OriMC⫺1
MMWO 4.9 m
Wil76a
Bog81
0.4
OriMC⫺1 OriMC⫺1
BTL 7 m TRAO 14 m
Woo84 Lee01
Xu_97
0.39f
IRC⫹10216 IRC⫹10216 Sgr B2共M兲 IRC⫹10216
NRAO 12 m NRAO 12 m NRAO 11 m IRAM 30 m
Hig00 Hig00 Sol73 Cer87c
3.7f
OriMC⫺1
TRAO 14 m
Lee01
1.6f 0.007 0.37
OriMC⫺1
TRAO 14 m
Lee01
IRC⫹10216 G34.3⫹0.15 OriMC⫺1
NRAO 12 m TRAO 14 m TRAO 14 m
Gen97 Kim00 Lee01
145766.163*共27兲 U
Formula
145876.2 145904.123*共17兲 145918.572*共31兲 145946.815*共1兲 146003.33* 共15兲
unidentified CS HCCCN OCS
146120.074*共10兲
K35Cl CH3 CH2 CN
U
146129.6
unidentified
U
146300.96* 共28兲 146368.342*共4兲 146372.4
SiC2 CH3 OH unidentified
3⫺2 v⫽1 16⫺15 v7 ⫽1 12⫺11 19⫺18 16共2,14兲⫺15共2,13兲 6共1,5兲⫺5共1,4兲 v3 ⫽1 3共1,2兲⫺2共1,2兲 A⫺⫺
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
1.9f 0.054 0.006 0.45
2.4f
Laf78
Bog91 Xu_97
MICROWAVE TRANSITIONS
243
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
U
146428.4共5兲
unidentified
0.62f
IRC⫹10216
IRAM 30 m
Cer00
U
146435.6共5兲
unidentified
0.65f
IRC⫹10216
IRAM 30 m
Cer00
U
146506.1共10兲
unidentified
0.65f
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1
TRAO 14 m
Lee01
146550.052*共3兲
U
U
SO2
4共2,2兲⫺4共1,3兲
25.2f
OriMC⫺1
TRAO 14 m
Lee01
CH3 OH
14共1,14兲⫺13共2,11兲 A⫹⫹
b
G34.3⫹0.15
TRAO 14 m
Kim00
Xu_97
146618.838*共18兲
CH3 OH
9共0,9兲⫺8共1,8兲 A⫹⫹
0.29b
G34.3⫹0.15
TRAO 14 m
Kim00
Xu_97
OriMC⫺1
TRAO 14 m
Lee01
146622.4
U
2共1,1兲⫺1共1,0兲
5.7f n.r.
H2 13CO CH2 N
OriMC⫺1
MMWO 4.9 m
Wan76
2共0,2兲⫺1共0,1兲 7/2⫺5/25/2⫺3/
2b
TMC⫺1
NRAO 12 m
Ohi94
Yam92
146674.203*共20兲
CH2 N
2共0,2兲⫺1共0,1兲 7/2⫺5/27/2⫺5/
20.055b
TMC⫺1
NRAO 12 m
Ohi94
Yam92
146675.065*共20兲
CH2 N
2共0,2兲⫺1共0,1兲 7/2⫺5/29/2⫺7/
2b
TMC⫺1
NRAO 12 m
Ohi94
Yam92
146730.27* 共26兲
16⫺15 v7 ⫽3 ᐉ⫽1 e 7共1,6兲⫺6共1,5兲 17共1,17兲⫺16共1,16兲
Sgr B2共N兲 TMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m TRAO 14 m
Vic00 Cer91 Lee01
Laf78
146876.032*共33兲 146894.498*共10兲
HCCCN H2 CCC CH3 CH2 CN
146932.5共10兲 146969.026*共6兲 146977.608*共25兲 146984.5
unidentified CS CH3 OCHO unidentified
3⫺2 12共3,10兲⫺11共3,9兲 E
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m MMWO 4.9 m MMWO 4.9 m TRAO 14 m
Hol81 Lis75 Lor84 Lee01
146988.082*共25兲 147024.197*共6兲
CH3 OCHO CH3 OCH3
12共3,10兲⫺11共3,9兲 A 7共1,6兲⫺6共0,6兲 EE⫹AE
b
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor84 Lor84
Oes99 Gro98
147024.891*共4兲
CH3 OCH3
7共1,6兲⫺6共0,6兲 EE
0.20b
OriMC⫺1
MMWO 4.9 m
Lor84
Gro98
147025.585*共6兲
CH3 OCH3
7共1,6兲⫺6共0,6兲 AA
b
OriMC⫺1
MMWO 4.9 m
Lor84
Gro98
147035.846*共5兲
CH3 CN
8共7兲⫺7共7兲
6.1f
G10.47
IRAM 30 m
Olm96
147056.633*共7兲
CH3 13CN CH3 CN
8共4兲⫺7共4兲 8共6兲⫺7共6兲
4.0f 0.08
CH3 13CN
8共3兲⫺7共3兲
147090.507*共6兲
CH3 13CN
147098.980*共7兲
CH3 13CN
147101.804*共7兲
0.65 0.082 4.1f 0.6 8.1 ⬍0.08 0.8f 0.11
Oes99
G10.47
IRAM 30 m
Olm96
4.1f
OriMC⫺1 G10.47
MMWO 4.9 m IRAM 30 m
Lor84 Olm96
8共2兲⫺7共2兲
6.7f
G10.47
IRAM 30 m
Olm96
8共1兲⫺7共1兲
4.1f
G10.47
IRAM 30 m
Olm96
CH3 13CN CH3 CN unidentified
8共0兲⫺7共0兲
b
G10.47
IRAM 30 m
Olm96
8共5兲⫺7共5兲
0.12
OriMC⫺1 OriMC⫺1
MMWO 4.9 m TRAO 14 m
Lor84 Lee01
147149.073*共2兲 147163.248*共2兲 147171.755*共2兲 147174.591*共2兲 147202.064*共10兲
CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 OCH3
8共4兲⫺7共4兲 8共3兲⫺7共3兲 8共2兲⫺7共2兲 8共1兲⫺7共1兲 8共0兲⫺7共0兲 6共3,4兲⫺6共2,5兲 EA
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 W51e2
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m NMA Array
Lor84 Lor84 Lor84 Lor84 Lor84 Zha98
Gro98
147203.751*共6兲
CH3 OCH3
6共3,4兲⫺6共2,5兲 AE
b
W51e2
NMA Array
Zha98
Gro98
147206.810*共6兲
CH3 OCH3
6共3,4兲⫺6共2,5兲 EE
6.0b
W51e2
NMA Array
Zha98
Gro98
147210.732*共8兲
CH3 OCH3
6共3,4兲⫺6共2,5兲 AA
b
W51e2
NMA Array
Zha98
Gro98
147243. 147432.101*共48兲
unidentified CH3 CN
MMWO 4.9 m IRAM 30 m
Lor84 Olm96
Bou80
147475.143*共37兲
CH3 CN
147475.924*共28兲
147103.747*共3兲 147112.9
2.2f 0.16 0.32 0.34 0.50 0.54
8共7兲⫺7共7兲 v8 ⫽1 ᐉ⫽⫺1 F⫽9⫺8
0.3f
OriMC⫺1 G10.47
0.4f
G10.47
IRAM 30 m
Olm96
Bou80
CH3 CN
8共6兲⫺7共6兲 v8 ⫽1 ᐉ⫽⫺1 F⫽9⫺8 8共1兲⫺7共1兲 v8 ⫽1 ᐉ⫽⫹1
8.2f
G10.47
IRAM 30 m
Olm96
Bou80
147512.473*共28兲
CH3 CN
8共5兲⫺7共5兲 v8 ⫽1 ᐉ⫽⫺1 F⫽9⫺8
4.9f
G10.47
IRAM 30 m
Olm96
Bou80
147519.455*共43兲
CH3 CN
8共7兲⫺7共7兲 v8 ⫽1 ᐉ⫽⫹1 F⫽9⫺8
3.1f
G10.47
IRAM 30 m
Olm96
Bou80
147544.082*共24兲
CH3 CN
8共4兲⫺7共4兲 v8 ⫽1 ᐉ⫽⫺1 F⫽9⫺8
3.9f
G10.47
IRAM 30 m
Olm96
Bou80
147550.385*共32兲
CH3 CN
8共6兲⫺7共6兲 v8 ⫽1 ᐉ⫽⫹1 F⫽9⫺8
3.1f
G10.47
IRAM 30 m
Olm96
Bou80
0.37f
IRC⫹10216
IRAM 30 m
Cer00
147561.7共5兲
0.12
unidentified
147569.937*共21兲
CH3 CN
8共3兲⫺7共3兲 v8 ⫽1 ᐉ⫽⫺1 F⫽9⫺8
4.9f
G10.47
IRAM 30 m
Olm96
Bou80
147575.239*共24兲
CH3 CN
4.2f
G10.47
IRAM 30 m
Olm96
Bou80
147589.948*共90兲
CH3 CN
8共5兲⫺7共5兲 v8 ⫽1 ᐉ⫽⫹1 F⫽9⫺8 8共2兲⫺7共2兲 v8 ⫽1 ᐉ⫽⫺1
6.5f
G10.47
IRAM 30 m
Olm96
Bou80
147595.453*共21兲
CH3 CN
6.4f
G10.47
IRAM 30 m
Olm96
Bou80
147602.2共5兲
C13CCN CH3 CN
8共4兲⫺7共4兲 v8 ⫽1 ᐉ⫽⫹1 F⫽9⫺8 15⫺14 a
0.45f
IRC⫹10216
IRAM 30 m
Cer00
Got83
8共1兲⫺7共1兲 v8 ⫽1 ᐉ⫽⫺1
6.2f
G10.47
IRAM 30 m
Olm96
Bou80
147603.983*共30兲 147609.804*共25兲
CH3 CN
8共3兲⫺7共3兲 v8 ⫽1 ᐉ⫽⫹1
3.2f
G10.47
IRAM 30 m
Olm96
Bou80
147611.000*共40兲
CH3 CN
8共0兲⫺7共0兲 v8 ⫽1 ᐉ⫽⫹1
4.8f
G10.47
IRAM 30 m
Olm96
Bou80
147617.6共5兲
15⫺14 b
0.38f
IRC⫹10216
IRAM 30 m
Cer00
Got83
147619.872*共80兲
C13CCN CH3 CN
8共2兲⫺7共2兲 v8 ⫽1 ᐉ⫽⫹1
6.6f
G10.47
IRAM 30 m
Olm96
Bou80
147647.149*共33兲
CCC13CH
16.5⫺15.5
0.39f
IRC⫹10216
IRAM 30 m
Cer00
COL01
147684.547*共37兲
CCC13CH CH3 CN
15.5⫺14.5
0.47f
IRC⫹10216
IRAM 30 m
Cer00
COL01
8共1兲⫺7共1兲 v8 ⫽1 ᐉ⫽⫹1
5.7f
G10.47
IRAM 30 m
Olm96
Bou80
1.7f
OriMC⫺1
TRAO 14 m
Lee01
147760.644*共30兲 U
unidentified
146672.825*共20兲
147129.237*共2兲
U
10.2f
146617.419*共33兲
147072.612*共3兲 147076.389*共6兲
U
10共4,6兲⫺11共3,9兲
146605.511*共4兲
146635.672*共5兲
U
SO2
Lab. Ref.
147943.7
unidentified
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
244
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
Source
Telescope
Astr. Ref.
Lab. Ref.
unidentified
0.9f
OriMC⫺1
TRAO 14 m
Lee01
CH3 OCHO
12共6,6兲⫺11共6,5兲 E
1.1f
OriMC⫺1
TRAO 14 m
Lee01
Oes99
148039.439*共25兲
CH3 OCHO
12共6,7兲⫺11共6,6兲 A
b
OriMC⫺1
TRAO 14 m
Lee01
Oes99
148040.635*共25兲
CH3 OCHO
12共6,7兲⫺11共6,6兲 E
1.8fb
OriMC⫺1
TRAO 14 m
Lee01
Oes99
148045.834*共25兲
CH3 OCHO
12共6,6兲⫺11共6,5兲 A
0.9f
OriMC⫺1
TRAO 14 m
Lee01
Oes99
148111.919*共24兲
CH3 OH
15共0,15兲⫺15共⫺1,15兲 E
4.9f
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
148221.466*共12兲
HCNH⫹ NH2 CHO
0.09b
Sgr B2共M兲
MMWO 4.9 m
Ziu86a
7共2,6兲⫺6共2,5兲
b
Sgr B2共M兲
MMWO 4.9 m
Ziu86a
1.0f
OriMC⫺1
TRAO 14 m
Lee01
148249.2
2⫺1
unidentified
148359.772 共50兲
CH3 OD
6共0,6兲⫺5共1,5兲 A⫹
3.3f
OriMC⫺1
IRAM 30 m
Mau88
And88
148409.07*共4兲
CCCN
15⫺14 a
26.4f
IRC⫹10216
IRAM 30 m
Cer00
Got83
148427.82*共4兲
CCCN
15⫺14 b
28.0f
IRC⫹10216
IRAM 30 m
Cer00
Got83
148500.393*共4兲
CH3 OCH3
8共3,6兲⫺8共2,7兲 EE
1.0f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
148503.837*共8兲
CH3 OCH3
8共3,6兲⫺8共2,7兲 AA
0.7f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
148797.700*共25兲
CH3 OCHO
12共4,9兲⫺11共4,8兲 E
0.7f
OriMC⫺1
TRAO 14 m
Lee01
Oes99
148805.973*共25兲
CH3 OCHO
12共4,9兲⫺11共4,8兲 A
0.8f
OriMC⫺1
TRAO 14 m
Lee01
Oes99
149106.972 共50兲
l⫺C3 H
2
⌸3/2 J⫽13/2⫺11/2 a
4.68f
IRC⫹10216
IRAM 30 m
Cer00
Got85
149212.667 共50兲
l⫺C3 H
2
6.13f
IRC⫹10216
IRAM 30 m
Cer00
Got85
149311.57* 共14兲
0.25f
IRC⫹10216
IRAM 30 m
Cer00
149439.578*共8兲
K37Cl CH3 OCH3
⌸3/2 J⫽13/2⫺11/2 b 20⫺19
149524.0共10兲
unidentified
19共3,17兲⫺18共4,14兲 EE
1.0f
OriMC⫺1
TRAO 14 m
Lee01
0.30f
IRC⫹10216
IRAM 30 m
Cer00
Gro98
149532.527*共26兲
CH3 OH
14共2,12兲⫺13共3,10兲 E
4.0f
OriMC⫺1
TRAO 14 m
Lee01
Xu_97
149569.776*共4兲
CH3 OCH3
9共3,7兲⫺9共2,8兲 EE
0.9f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
149877.010*共30兲
17⫺16
IRAM 30 m
Cer00
Laf78
14共0,14兲⫺14共⫺1,14兲 E
1.76f 0.86
IRC⫹10216
150141.593*共22兲 150155.3
H13CCCN CH3 OH unidentified
FCRAO 14 m TRAO 14 m
Ziu91 Lee01
Xu_97
1.1f
OriMC⫺1 OriMC⫺1
150162.944*共14兲
CH3 OCH3
25共4,21兲⫺25共3,22兲 AE⫹EA
b
OriMC⫺1
FCRAO 14 m
Ziu91
Gro98
150163.408*共12兲
CH3 OCH3
25共4,21兲⫺25共3,22兲 AE⫹EA
0.12b
OriMC⫺1
FCRAO 14 m
Ziu91
Gro98
150163.871*共16兲
CH3 OCH3
25共4,21兲⫺25共1,24兲 AA
1.0f
OriMC⫺1
TRAO 14 m
Lee01
Gro98
150163.871*共17兲
CH3 OCH3
25共4,21兲⫺25共3,22兲 AE⫹EA
b
OriMC⫺1
FCRAO 14 m
Ziu91
Gro98
NRAO 11 m
Lis78a
Win94
Lee01
NO
2
⌸1/2 J⫽3/2⫺1/2 F⫽5/2⫺3/2共⫺⫹兲
0.25
Sgr B2共M兲
TRAO 14 m
NO
2
⌸1/2 J⫽3/2⫺1/2 F⫽3/2⫺1/2共⫺⫹兲
1.0f 0.03
OriMC⫺1
150198.759共3兲
OriMC⫺1
FCRAO 14 m
Ziu91
Win94
150218.744共3兲
NO
2
⌸1/2 J⫽3/2⫺1/2 F⫽3/2⫺3/2共⫺⫹兲
0.03b
OriMC⫺1
FCRAO 14 m
Ziu91
Win94
NO
2
⌸1/2 J⫽3/2⫺1/2 F⫽1/2⫺1/2共⫺⫹兲 44共9,35兲⫺44共9,36兲 E
b
OriMC⫺1
FCRAO 14 m
Ziu91
Win94
0.14
Sgr B2
NRAO 11 m
Hol81
Oes99
0.25 0.03 0.15
Sgr B2共M兲 OriMC⫺1 OriMC⫺1
NRAO 11 m FCRAO 14 m NRAO 11 m
Hol80a Ziu93 Hol80a
Win94
0.03 0.9f
OriMC⫺1 OriMC⫺1
FCRAO 14 m TRAO 14 m
Ziu93 Lee01
Oes99 Gro98
2.7 0.25
OriMC⫺1 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Tha71 Lis78a
Win94
b
OriMC⫺1
FCRAO 14 m
Ziu91
Gro98
150186.7
150225.652共3兲 150327.79* 共15兲 150381.075*共3兲
unidentified
150415.358*共34兲 150439.096共3兲
CH3 OCHO SO2 CH3 CH2 CN NO
150449.345*共32兲 150466.828*共12兲
CH3 OCHO CH3 OCH3
150498.336*共7兲
H2 CO
150546.462共2兲
NO
150592.304*共8兲
CH3 OCH3
⌸1/2 J⫽3/2⫺1/2F⫽5/2⫺3/2共⫹⫺兲 21共2,19兲⫺21共1,20兲 AE⫹EA
150594.202*共6兲
CH3 OCH3
21共2,19兲⫺21共1,20兲 EE
0.12b
OriMC⫺1
FCRAO 14 m
Ziu91
Gro98
150596.104*共10兲
CH3 OCH3
21共2,19兲⫺21共1,20兲 AA
b
OriMC⫺1
FCRAO 14 m
Ziu91
Gro98
150600.675*共28兲
CH3 OCHO CH3 OCHO CH3 OCHO
12共4,8兲⫺11共4,7兲 E 12共4,8兲⫺11共4,7兲 A 12共6,7兲⫺12共5,8兲 A
0.2 0.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
BTL 7 m BTL 7 m FCRAO 14 m
Woo84 Woo84 Ziu93
Oes99 Oes99 Oes99 Win94
150618.313*共28兲 150636.666*共29兲 150644.351共3兲
NO
U U
150689. 150702.
unidentified unidentified
U
150724.0 150735.040*共8兲 150736.0 150749.
unidentified N2 O unidentified unidentified
U U
T r 共K兲/T a 共K兲
147979.7
150176.459共2兲 U
Quantum numbers
148027.954*共29兲
148223.131*共2兲 U
Formula
150820.666*共5兲
c⫺C3 H2
150851.899*共5兲
150992.105*共6兲
c⫺C3 H2 CH3 OH CH3 OCHO CH3 OCH3
150992.175*共6兲
CH3 OCH3
150995.388*共4兲
CH3 OCH3 CH3 OCH3 CH3 OCHO
150884.597*共17兲 150980.658*共37兲
150998.636*共6兲 151008.932*共29兲
15共5,11兲⫺16共4,12兲 27共1,26兲⫺27共0,27兲 2
⌸1/2 J⫽3/2⫺1/2F⫽3/2⫺3/2共⫹⫺兲 12共6,6兲⫺12共5,7兲 E 22共2,21兲⫺21共3,18兲 EE 2共1,1兲⫺1共1,0兲
2
2
⌸1/2 J⫽3/2⫺1/2 F⫽3/2⫺1/2共⫹⫺兲
0.04b b
OriMC⫺1
FCRAO 14 m
Ziu91
0.7 0.3
Sgr B2共N兲 Sgr B2共N兲
NRAO 12 m NRAO 12 m
Hal01 Hal01
4共0,4兲⫺3共1,3兲
0.09 0.065 0.04 0.5 0.3
OriMC⫺1 Sgr B2共M兲 OriMC⫺1 Sgr B2共N兲 Sgr B2共M兲
FCRAO 14 m NRAO 12 m FCRAO 14 m NRAO 12 m NRAO 11 m
Ziu93 Ziu94a Ziu93 Hal01 Hol83a
6⫺5
4共1,4兲⫺3共0,3兲
0.3
Sgr B2共M兲
NRAO 11 m
Hol83a
12共⫺1,12兲⫺11共⫺2,10兲 E
1.5
Sgr B2共M兲
NRAO 11 m
Sny80
Xu_97
22共6,17兲⫺22共5,18兲 A 10共3,8兲⫺10共2,9兲 EA
0.05 0.24b
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
Oes99 Gro98
10共3,8兲⫺10共2,9兲 AE
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
10共3,8兲⫺10共2,9兲 EE 10共3,8兲⫺10共2,9兲 AA 11共6,6兲⫺11共5,7兲 E
0.32 0.30 0.07
OriMC⫺1 OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93 Ziu93
Gro98 Gro98 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
245
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
151009.110*共29兲 151036.133*共29兲 151127.251*共10兲 151154.62* 共30兲 151283.5 151305.5 151356.955*共17兲 151375.79* 共11兲
CH3 OCHO CH3 OCHO CH3 CH2 CN SiC2 unidentified unidentified CH2 CHCN C4 H
11共6,5兲⫺11共5,6兲 A 11共6,5兲⫺11共5,6兲 E 17共2,16兲⫺16共2,15兲 7共1,7兲⫺6共1,6兲 v3 ⫽1
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m FCRAO 14 m NRAO 12 m FCRAO 14 m FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Ziu93 Gen97 Ziu93 Ziu93 Ziu93 Cer00
Oes99 Oes99
151378.655*共4兲 151496.041*共32兲
rhoOphA
MMWO 4.9 m
Lor85
151511.215*共10兲
SO2 CH3 OCHO CH3 OCH3
151513.535*共8兲 151515.848*共8兲
16共2,15兲⫺15共2,14兲
0.12 0.07 0.22 0.008 0.1 0.05 0.03
⌸1/2 J⫽31/2⫺29/2 e v7 ⫽1 2共2,0兲⫺2共1,1兲
4.47f 0.32
10共6,5兲⫺10共5,6兲 A 14共2,12兲⫺13共3,11兲 AA
0.035 b
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
Oes99 Gro98
CH3 OCH3
14共2,12兲⫺13共3,11兲 EE
0.15b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
CH3 OCH3
14共2,12兲⫺13共3,11兲 AE
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
151515.861*共8兲
CH3 OCH3
14共2,12兲⫺13共3,11兲 EA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
151589.984*共9兲
CH3 CHO
6共⫺1,6兲⫺5共0,5兲 E
b
OriMC⫺1
FCRAO 14 m
Ziu93
Kle96
151590.741*共6兲
CH3 OCH3
14共2,13兲⫺14共1,14兲 AE⫹EA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
151593.921*共6兲
CH3 OCH3
14共2,13兲⫺14共1,14兲 EE
0.18b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
151597.101*共8兲
CH3 OCH3
14共2,13兲⫺14共1,14兲 AA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
151616.190 共26兲 151847.22* 共11兲
HDO C4 H
7共3,4兲⫺7共3,5兲
OMC⫺IRc2 IRC⫹10216
IRAM 30 m IRAM 30 m
Jac90 Cer00
DeL71 COL01
151860.170*共20兲 151899.098*共10兲
CH3 OH CH2 CHCN
Xu_97
151900.311*共8兲
CH2 CHCN
151900.349*共8兲
CH2 CHCN
151915.903*共11兲
CH2 CHCN CH2 CHCN
151933.627*共7兲
U U
U U
U
U
⌸1/2 J⫽31/2⫺29/2 f v7 ⫽1 13共0,13兲⫺13共⫺1,13兲 E
6.41f 0.48
OriMC⫺1
FCRAO 14 m
Ziu93
b
OriMC⫺1
FCRAO 14 m
Ziu93
16共5,12兲⫺15共5,11兲
0.08b
OriMC⫺1
FCRAO 14 m
Ziu93
16共5,11兲⫺15共5,10兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
16共7,*兲⫺15共7,*兲 16共4,13兲⫺15共4,12兲
0.07 b
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
16共6,*兲⫺15共6,*兲
CH2 CHCN
16共4,12兲⫺15共4,11兲
0.05b
OriMC⫺1
FCRAO 14 m
Ziu93
151949.998*共25兲 151956.643*共25兲 151986.775*共8兲 151993. 152200.9共10兲
CH3 OCHO CH3 OCHO CH2 CHCN unidentified unidentified
13共2,12兲⫺12共2,11兲 E 13共2,12兲⫺12共2,11兲 A 16共3,14兲⫺15共3,13兲
0.25 0.21 0.04 0.05
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Ziu93 Ziu93 Cer00
Oes99 Oes99
152243.618*共10兲
C4 H
16.5⫺15.5
IRC⫹10216
IRAM 30 m
Cer00
JPL01
152243.735*共3兲
HNCS
13共1,13兲⫺12共1,12兲
OriMC⫺1
FCRAO 14 m
Ziu93
IRC⫹10216
IRAM 30 m
Cer00
0.3b
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
b
OriMC⫺1
FCRAO 14 m
Ziu93
0.1 0.16b
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
2.20f 22.1f 0.05b
152282.089*共9兲
C4 H
15.5⫺14.5
152297.852*共8兲 152303.840*共8兲
CH3 CH2 CN CH3 CH2 CN
17共8,*兲⫺16共8,*兲 17共7,*兲⫺16共7,*兲
152304.658*共8兲
CH3 CH2 CN
17共9,*兲⫺16共9,*兲
152320.523*共8兲 152329.875*共9兲
CH3 CH2 CN CH3 CH2 CN
17共10,*兲⫺16共10,*兲 17共6,12兲⫺16共6,11兲
152329.895*共9兲
CH3 CH2 CN
17共6,11兲⫺16共6,10兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
152332.614*共36兲
CH2 CHCN CH3 CH2 CN
24共1,23兲⫺23共2,22兲 17共11,*兲⫺16共11,*兲
0.06 0.09
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
unidentified CH3 CH2 CN unidentified
17共12,*兲⫺16共12,*兲
0.05 0.08
FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Cer00
15共3,13兲⫺15共2,14兲
3.51f 0.03
OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1
FCRAO 14 m
Ziu93
17共5,13兲⫺16共5,12兲
0.24b
OriMC⫺1
FCRAO 14 m
Ziu93
152343.361*共8兲 152366.0 152371.921*共8兲 152380.6共10兲
25.0f 0.19
JPL01
152391.261*共9兲
t⫺CH3 CH2 OH CH3 CH2 CN
152392.466*共9兲
CH3 CH2 CN
17共5,12兲⫺16共5,11兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
152405.419*共9兲 152435.713*共28兲
CH3 CH2 CN
17共13,*兲⫺16共13,*兲 20共3,18兲⫺19共4,15兲
0.07 0.06
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
14共⫺3,12兲⫺13共⫺4,10兲 E 17共15,*兲⫺16共15,*兲 17共3,15兲⫺16共3,14兲 17共3,14兲⫺16共3,13兲
0.3 0.05 0.18 0.19 0.1 0.04 0.24 0.07
FCRAO FCRAO FCRAO FCRAO FCRAO FCRAO FCRAO FCRAO FCRAO
m m m m m m m m m
Ziu93 Ziu93 Ziu93 Ziu93 Ziu93 Ziu93 Ziu93 Ziu93 Ziu93
Xu_97
0.07b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
b
OriMC⫺1
FCRAO 14 m
Ziu93
Kle96
152485.309*共11兲 152505.408*共10兲 152509.622*共9兲 152514.5 152525.0 152552.917*共9兲 152579.5 152598.25* 共12兲
t⫺CH3 CH2 OH CH3 OH CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN unidentified unidentified CH3 CH2 CN unidentified CH3 OCHO
152607.615*共7兲
CH3 CHO
8共0,8兲⫺7共0,7兲 E
152609.770*共8兲
DNC
2⫺1
0.5b
L134
MMWO 4.9 m
Sne77
152621.5 152635.202*共7兲 152640.0共10兲
unidentified CH3 CHO
8共0,8兲⫺7共0,7兲 A⫹⫹
0.08 0.06
OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Cer00
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
152443.177*共20兲
U
2
0.2
COL01
151936.870*共7兲
152382.974*共17兲
U U
2
Bog91
152651.5 152656.820*共17兲
17共4,13兲⫺16共4,12兲 17共2,16兲⫺17共1,17兲 A
CCCN unidentified
16⫺15 a
t⫺CH3 CH2 OH
4共2,2兲⫺3共1,3兲
13
0.62f 0.04 0.05
14 14 14 14 14 14 14 14 14
Oes99
Kle96 Got83
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
246
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 152659.7共6兲 152669.538*共13兲
Formula
unidentified
b
152681.6共6兲
unidentified
152708.486*共17兲 152740.249*共17兲 152828.183*共6兲
CH3 OH CH3 OH CH3 OCH3
9共4,6兲⫺10共3,7兲 A⫺ 9共4,5兲⫺10共3,8兲 A⫹ 11共3,9兲⫺11共2,10兲 EA
0.82f 0.35 0.26
152828.220*共6兲
CH3 OCH3
11共3,9兲⫺11共2,10兲 AE
152831.364*共4兲
CH3 OCH3
11共3,9兲⫺11共2,10兲 EE
152834.528*共6兲
CH3 OCH3
11共3,9兲⫺11共2,10兲 AA
b
152841.6共15兲
unidentified
Cer00
Got83
FCRAO 14 m
Ziu93
OriMC⫺1
FCRAO 14 m
Ziu93
IRC⫹10216
IRAM 30 m
Cer00
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93 Ziu93
Xu_97 Xu_97 Gro98
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
0.1b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
0.87f
IRC⫹10216
IRAM 30 m
Cer00
152879.96* 共10兲
C4 H
IRC⫹10216
IRAM 30 m
Cer00
COL01
CH3 OCH3
⌸3/2 J⫽33/2⫺31/2 e v7 ⫽1 11共7,5兲⫺12共6,6兲 EA
4.90f
152889.341*共76兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152892.321*共76兲
CH3 OCH3
11共7,5兲⫺12共6,6兲 EE
0.07b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152893.160*共74兲
CH3 OCH3
11共7,5兲⫺12共6,6兲 AE
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152893.195*共74兲
CH3 OCH3
11共7,4兲⫺12共6,7兲 AE
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152895.283*共72兲
CH3 OCH3
11共7,4兲⫺12共6,7兲 AA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152895.283*共72兲
CH3 OCH3
11共7,5兲⫺12共6,6兲 AA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152895.318*共72兲
CH3 OCH3
11共7,4兲⫺12共6,7兲 EE
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152896.158*共74兲
CH3 OCH3
11共7,4兲⫺12共6,7兲 EA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
152898.202*共78兲 152907.906*共72兲
CH2 CHCN
16共4,13兲⫺17共3,14兲
0.02
12⫺11
0.72f 0.06
OriMC⫺1 IRC⫹10216
FCRAO 14 m IRAM 30 m
Ziu93 Cer00
152953.651*共5兲 152986.00共20兲
2
Na37Cl
9共4,6兲⫺10共3,7兲
34
SO2 C4 H
2
⌺ J⫽16⫺15 v7 ⫽2 L
OriMC⫺1
FCRAO 14 m
Ziu93
IRC⫹10216
IRAM 30 m
Gue87a
0.095 0.08
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
n.r.
Gue87a
152989.5 153015.048*共5兲
unidentified
153025.421*共12兲
CH3 OCH3
26共3,23兲⫺26共2,24兲 AE⫹EA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
153026.423*共10兲
CH3 OCH3
26共3,23兲⫺26共2,24兲EE
0.06b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
153027.425*共12兲
CH3 OCH3
26共3,23兲⫺26共2,24兲AA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
n.r.
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
3共2,2兲⫺3共1,3兲
34
SO2
153054.489*共6兲
CH3 OCH3
⌺ J⫽16⫺15 v7 ⫽2 U 9共0,9兲⫺8共1,8兲 AA
153054.837*共4兲
CH3 OCH3
9共0,9兲⫺8共1,8兲 EE
153055.185*共4兲
CH3 OCH3
9共0,9兲⫺8共1,8兲 EA⫹AE
U U
153064.5 153070.5 153105.802*共50兲
unidentified unidentified
U U
153106.1 153129.1 153135.193共5兲
unidentified unidentified FeO
U
153162. 153179.33* 共13兲 153226. 153272.214*共10兲 153281.207*共19兲 153288.745*共24兲
unidentified HDS unidentified CH3 CH2 CN CH3 OH CH3 OCHO
17共3,14兲⫺16共3,13兲 12共0,12兲⫺12共⫺1,12兲 E 14共0,14兲⫺13共1,13兲 E
153290.476*共29兲
CH3 OCHO
14共0,14兲⫺13共1,13兲A
153291.946*共6兲
HNCO
7共1,7兲⫺6共1,6兲
153323.998 共50兲
CH3 OD
153335.05* 共11兲
C4 H
153350.384*共24兲 153352.020*共29兲
153041.88共20兲
U U
IRAM 30 m
OriMC⫺1
1.26f 0.04b
152678.
U
IRC⫹10216
16⫺15 b
U
U
Lab. Ref.
22共4,18兲⫺22共3,19兲
CCCN
U
U
Astr. Ref.
Source
13
CH3 CH2 CN
Telescope
T r 共K兲/T a 共K兲
Quantum numbers
C4 H
2
b
Sgr B2共M兲
NRAO 11 m
Mer82
Gro98
0.39b
Sgr B2共M兲
NRAO 11 m
Mer82
Gro98
b
Sgr B2共M兲
NRAO 11 m
Mer82
Gro98
0.87f
OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Cer00
0.04 0.05 ⫺0.10
OriMC⫺1 OriMC⫺1 Sgr B2共M兲
FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Wao02
0.10 0.39 0.15 0.17 0.78 b
Sgr B2共M兲 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m FCRAO 14 m IRAM 30 m FCRAO 14 m FCRAO 14 m FCRAO 14 m
Wal02 Min90 Wal02 Ziu93 Ziu93 Ziu93
Xu_97 Oes99
0.19b
OriMC⫺1
FCRAO 14 m
Ziu93
Oes99
b
OriMC⫺1
FCRAO 14 m
Ziu93
0.045 0.04 9⫺8
30
Si34S
5
⌬I 5⫺4 ⍀⫽4
2共1,1兲⫺2共1,2兲
Kro87 Hel73
7共1,6兲⫺7共0,7兲 A⫺
7.6f
OriMC⫺1
IRAM 30 m
Mau88
And88
5.33f
IRC⫹10216
IRAM 30 m
Cer00
COL01
CH3 OCHO
⌸3/2 J⫽33/2⫺31/2 f v7 ⫽1 14共1,14兲⫺13共1,13兲 E
0.26b
OriMC⫺1
FCRAO 14 m
Ziu93
Oes99
CH3 OCHO
14共1,14兲⫺13共1,13兲 A
b
OriMC⫺1
FCRAO 14 m
Ziu93
Oes99
153353.606*共82兲
CH3 OCHO
19共3,17兲⫺19共2,18兲 A
b
OriMC⫺1
FCRAO 14 m
Ziu93
Oes99
153385.598*共14兲
CH3 OCH3
24共4,20兲⫺24共3,21兲 AE⫹EA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
153386.290*共10兲
CH3 OCH3
24共4,20兲⫺24共3,21兲 EE
0.14b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
153386.991*共16兲
CH3 OCH3
24共4,20兲⫺24共3,21兲 AA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
153399.367*共29兲 153432.171*共2兲
CH3 OCHO NH2 CHO
14共0,14兲⫺13共0,13兲 A
0.32
OriMC⫺1
FCRAO 14 m
Ziu93
Oes99
7共1,6兲⫺6共1,5兲
0.15 1.22f 0.1 0.13 0.08 0.1 0.13 0.13
Sgr B2共M兲 IRC⫹10216
NRAO 11 m IRAM 30 m
Hol83a Cer00
OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m NRAO 11 m FCRAO 14 m NRAO 11 m NRAO 11 m NRAO 11 m IRAM 30 m
Ziu93 Hol81 Ziu93 Hol83a Hol83a Hol83a Cer00
2
153449.778*共17兲
CCS
11,12⫺10,11
153460.911*共29兲 153487.5共5兲 153487.6 153512.661*共25兲 153518.736*共28兲 153553.151*共25兲 153557.87*共12兲
CH3 OCHO unidentified unidentified CH3 OCHO CH3 OCHO CH3 OCHO NaCN
14共1,14兲⫺13共0,13兲 A
13共1,12兲⫺12共1,11兲 E 13共1,12兲⫺12共1,11兲 A 12共2,10兲⫺11共2,9兲 E 10共0,10兲⫺9共0,9兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
1.77f
Oes99
Oes99 Oes99 Oes99
MICROWAVE TRANSITIONS
247
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
U
153566.956*共25兲 153668.3共10兲 153677.54* 共15兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
CH3 OCHO unidentified
12共2,10兲⫺11共2,9兲 A
0.11 0.08
NRAO 11 m NRAO 11 m IRAM 30 m
Hol83a Hol81 Cer87c
Oes99
20⫺19
0.71f
153746.218*共17兲
K35Cl HCCN
OriMC⫺1 Sgr B2共M兲 IRC⫹10216
8,7⫺7,6
0.45f
IRC⫹10216
IRAM 30 m
Gue91
153764.606*共8兲
HNCO
7共3,4兲⫺6共3,3兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
153764.606*共8兲
HNCO
7共3,5兲⫺6共3,4兲
0.09b
OriMC⫺1
FCRAO 14 m
Ziu93
153770.215*共3兲
CH3 CCH
9共4兲⫺8共4兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
IRC⫹10216
IRAM 30 m
Cer00
Sgr B2共M兲 IRC⫹10216
NRAO 11 m IRAM 30 m
Hol81 Cer00
b
Sgr B2共M兲 Sgr B2共M兲
NRAO 11 m NRAO 11 m
Hol81 Hol81
153782.5共12兲
unidentified
0.55f 0.23
153790.771*共2兲
CH3 CCH
153804.018*共18兲
HCCN
9共3兲⫺8共3兲 7,7⫺6,6
153805.459*共1兲 153814.274*共1兲
CH3 CCH CH3 CCH
9共2兲⫺8共2兲 9共1兲⫺8共1兲
153817.213*共1兲
CH3 CCH
9共0兲⫺8共0兲
0.59b
Sgr B2共M兲
NRAO 11 m
Hol81
153818.869*共6兲
HNCO
7共2,6兲⫺6共2,5兲
0.3b
OriMC⫺1
FCRAO 14 m
Ziu93
153820.007*共7兲
HNCO
7共2,5兲⫺6共2,4兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
153841.57* 共11兲
C4 H
153865.092*共6兲 153872.687*共6兲
0.67f 0.18
⌸5/2 J⫽33/2⫺31/2 v7 ⫽2 ᐉ⫽2
1.27f
IRC⫹10216
IRAM 30 m
Cer00
COL01
HNCO CH3 CHO
7共0,7兲⫺6共0,6兲 8共2,7兲⫺7共2,6兲 A⫺⫺
2.03
Sgr B2共M兲 OriMC⫺1
NRAO 11 m FCRAO 14 m
Chu86 Ziu93
Kle96
153894.121*共19兲
HCCN
6,7⫺5,6
IRC⫹10216
IRAM 30 m
Gue91
154001.216*共24兲
HC13CCN
17⫺16
0.5f 1.36f
IRC⫹10216
IRAM 30 m
Cer00
Laf78
154016.096*共11兲
HCC13CN
17⫺16
0.05
OriMC⫺1
FCRAO 14 m
Ziu93
Laf78
Cer00
2
0.06b
U
154076.5共10兲
unidentified
0.78f
IRC⫹10216
IRAM 30 m
U
154088.2共10兲
unidentified
0.63f
IRC⫹10216
IRAM 30 m
Cer00
U
U
154090.197
HNCO
7共4兲⫺6共4兲 v5 ⫽1
0.9f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154110.119
HNCO
7共3兲⫺6共3兲 v6 ⫽1
2.1f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154114.411
HNCO
7共0,7兲⫺6共0,6兲 v5 ⫽1
3.7f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154119.019
HNCO
7共0,7兲⫺6共0,6兲 v6 ⫽1
2.1f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154123.323
HNCO
7共3兲⫺6共3兲 v5 ⫽1
2.9f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154142.560
HNCO
7共2,6兲⫺6共2,5兲 v5 ⫽1
3.3f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154146.055
HNCO
7共2,5兲⫺6共2,4兲 v5 ⫽1
3.8f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154149.2共8兲
unidentified
1.33f
IRC⫹10216
IRAM 30 m
Cer00
154200.919*共6兲
CH3 CHO
8共4,5兲⫺7共4,4兲 A⫺⫺
0.03b
OriMC⫺1
FCRAO 14 m
Ziu93
154201.474*共6兲
CH3 CHO
8共4,4兲⫺7共4,3兲 A⫹⫹
b
OriMC⫺1
FCRAO 14 m
Ziu93
Kle96
154215.100*共50兲
N 2 D⫹
2⫺1 F 1 ⫽2⫺2 F⫽1⫺1
b
L134N
IRAM 30 m
Ger01
Ger01
154215.224*共50兲
N 2 D⫹
2⫺1 F 1 ⫽2⫺2 F⫽2⫺3
0.4b
L134N
IRAM 30 m
Ger01
Ger01
154215.266*共50兲
N2 D
⫹
2⫺1 F 1 ⫽2⫺2 F⫽2⫺2
b
L134N
IRAM 30 m
Ger01
Ger01
154215.358*共50兲
N 2 D⫹
2⫺1 F 1 ⫽1⫺0 F⫽1⫺1
b
L134N
IRAM 30 m
Ger01
Ger01
154215.569*共50兲
N 2 D⫹
2⫺1 F 1 ⫽1⫺0 F⫽2⫺1
0.4b
L134N
IRAM 30 m
Ger01
Ger01
154215.825*共50兲
N 2 D⫹
2⫺1 F 1 ⫽1⫺0 F⫽0⫺1
b
L134N
IRAM 30 m
Ger01
Ger01
154216.692*共50兲
N 2 D⫹
2⫺1 F 1 ⫽2⫺0 F⫽2⫺1
0.5b
L134N
IRAM 30 m
Ger01
Ger01
154216.756*共50兲
N 2 D⫹
2⫺1 F 1 ⫽3⫺2 F⫽3⫺3
b
L134N
IRAM 30 m
Ger01
Ger01
154216.828*共50兲
N 2 D⫹
2⫺1 F 1 ⫽2⫺1 F⫽2⫺2
b
L134N
IRAM 30 m
Ger01
Ger01
154217.053*共50兲
N 2 D⫹
2⫺1 F 1 ⫽3⫺2 F⫽3⫺2
b
L134N
IRAM 30 m
Ger01
Ger01
154217.074*共50兲
N 2 D⫹
2⫺1 F 1 ⫽3⫺2 F⫽2⫺1
b
L134N
IRAM 30 m
Ger01
Ger01
154217.084*共50兲
N 2 D⫹
2⫺1 F 1 ⫽2⫺1 F⫽3⫺2
1.8b
L134N
IRAM 30 m
Ger01
Ger01
154217.154*共50兲
N 2 D⫹
2⫺1 F 1 ⫽3⫺2 F⫽4⫺3
b
L134N
IRAM 30 m
Ger01
Ger01
154217.450*共50兲
N 2 D⫹
2⫺1 F 1 ⫽2⫺1 F⫽1⫺0
0.2b
L134N
IRAM 30 m
Ger01
Ger01
154217.565*共50兲
2⫺1 F 1 ⫽3⫺2 F⫽2⫺2
b
L134N
IRAM 30 m
Ger01
Ger01
154222.3共9兲
N 2 D⫹ unidentified
0.79f
IRC⫹10216
IRAM 30 m
Cer00
154227.515
HNCO
7共1,6兲⫺6共1,5兲 v6 ⫽1
4.0f
G10.47⫹0.03
IRAM 30 m
Wyr99
OC34S CH3 CH2 CN
13⫺12
1.b
OriMC⫺1
FCRAO 14 m
Ziu93
17共1,16兲⫺16共1,15兲
OriMC⫺1
FCRAO 14 m
Ziu93
154259.6*共20兲
HCC13CN
17⫺16 v6 ⫽1 ᐉ⫽1 e
1.9f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154365.8*共20兲
HCC13CN
17⫺16 v7 ⫽1 ᐉ⫽1 e
3.8f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154370.6*共20兲
HCC13CN
17⫺16 v6 ⫽1 ᐉ⫽1 f
2.4f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154383.2*共20兲
HC13CCN
17⫺16 v6 ⫽1 ᐉ⫽1 f
2.0f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154387.2*共20兲
HC13CCN
17⫺16 v7 ⫽1 ᐉ⫽1 e
4.1f 0.07 0.18 1.42
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
OriMC⫺1 OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m NRAO 11 m
Ziu93 Ziu93 Hol81
Xu_97
154242.770*共3兲 154244.345*共10兲
U
U
0.14b
Kle96
Wyr99
154391.1 154414.776*共6兲 154425.765*共17兲 154453.756*共8兲
unidentified HNCO CH3 OH CH3 OCH3
7共1,6兲⫺6共1,5兲 11共0,11兲⫺11共⫺1,11兲 E 11共1,10兲⫺10共2,9兲 AA
b
NGC6334I
IRAM 30 m
Bac90
Gro98
154455.118*共6兲
CH3 OCH3
11共1,10兲⫺10共2,9兲 EE
1.5b
NGC6334I
IRAM 30 m
Bac90
Gro98
154456.480*共12兲
CH3 OCH3
11共1,10兲⫺10共2,9兲 EA⫹AE
b
NGC6334I
IRAM 30 m
Bac90
Gro98
154512.5
unidentified
0.04
OriMC⫺1
FCRAO 14 m
Ziu93
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
248
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
T r 共K兲/T a 共K兲
Astr. Ref.
Lab. Ref.
OS17O
15共5,10兲⫺16共4,13兲
0.05
OriMC⫺1
FCRAO 14 m
Ziu93
6共1,6兲⫺5共0,5兲
0.050
Sgr B2共N兲
NRAO 12 m
Tur01
154657.289*共5兲 154663. 154669.02* 共30兲 154724.533*共10兲 154828.282
HCCCN unidentified HCCCN CH2 CHCN HNCO
17⫺16 17⫺16 v5 ⫽1 ᐉ⫽1 f 16共1,15兲⫺15共1,14兲 7共1,6兲⫺6共1,5兲 v4 ⫽1
1.54 0.5 1.24 0.07 0.7f
OriMC⫺1 NGC6334I Sgr B2共N兲 OriMC⫺1 G10.47⫹0.03
NRAO 11 m IRAM 30 m IRAM 30 m FCRAO 14 m IRAM 30 m
Hol81 Bac90 Vic00 Ziu93 Wyr99
154911.24* 共16兲
HCCCN
17⫺16 v6 ⫽1 ᐉ⫽1 e
6.6f
G10.47⫹0.03
IRAM 30 m
Wyr99
Laf78
154943.8*共30兲
HC13CCN
17⫺16 v7 ⫽2 ᐉ⫽0
1.3f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154954.5*共30兲
HC13CCN
17⫺16 v7 ⫽2 ᐉ⫽2 e
1.2f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154966.8*共30兲
HC13CCN
17⫺16 v7 ⫽2 ᐉ⫽2 f
1.6f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
154969.9*共30兲
HCC13CN CH3 OCHO CH3 OCHO HCCCN
17⫺16 v7 ⫽2 ᐉ⫽0
1.2f
G10.47⫹0.03
IRAM 30 m
Wyr99
Wyr99
0.135 0.15
OriMC⫺1 OriMC⫺1 G10.47⫹0.03
FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Wyr99
Oes99 Oes99 Laf78
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Ziu93 Gue93
Laf78 Kle96 Kaw93
12共3,9兲⫺11共3,8兲 E 12共3,9兲⫺11共3,8兲 A 17⫺16 v6 ⫽1 ᐉ⫽1 f
8共⫺4,5兲⫺9共⫺3,7兲 E 25/2,13⫺23/2,12
23.2f 0.15 0.05 0.04 1.2
27/2,13⫺25/2,12
1.2
17⫺16 v7 ⫽1 ᐉ⫽1 e
Laf78 Wyr99
155037.225*共30兲 155075.0 155088.126*共35兲 155094.573*共10兲
HCCCN unidentified CH3 CHO
155109.792*共10兲
24 MgNC CH3 OCH3
IRC⫹10216
IRAM 30 m
Gue93
Kaw93
155125.329*共6兲
12共3,10兲⫺12共2,11兲 EA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
155125.350*共6兲
CH3 OCH3
12共3,10兲⫺12共2,11兲 AE
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
155128.420*共4兲 155131.501*共6兲
CH3 OCH3 CH3 OCH3
12共3,10兲⫺12共2,11兲 EE
0.22b 0.3
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
unidentified unidentified unidentified
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Ziu93 Cer00
Gro98
155147.0 155154.0 155233.3共12兲
0.21 0.06 0.09
155262.003*共20兲 155320.834*共15兲 155342.095*共6兲 155389.615*共4兲 155404.496*共10兲 155426.769*共10兲 155454.493*共11兲
24
155518.313*共7兲 155533.080 共50兲
MgNC
HCCCN 13
CH3 OH CH3 OH CH3 CHO SO2 CH3 CH2 CN CH3 CH2 CN CCS
155506.813*共24兲
U
Telescope
a⫺CH2 CHOH
155259.211*共30兲
U
Source
154609.47* 共10兲
155002.327*共28兲 155032.45* 共19兲
U U U
Quantum numbers
154640.508*共41兲
154984.439*共25兲
U
Formula
34
12共3,10兲⫺12共2,11兲 AA
0.73f 17⫺16 v7 ⫽1 ᐉ⫽1 f 9共0,9兲⫺9共⫺1,9兲 E 10共0,10兲⫺10共⫺1,10兲 E 8共2,6兲⫺7共2,5兲 A⫹⫹ 20共6,14兲⫺21共5,17兲 17共2,15兲⫺16共2,14兲 18共1,18兲⫺17共1,17兲 12,12⫺11,11
SO
c⫺C3 H2 CH3 OD
b
OriMC⫺1
FCRAO 14 m
Ziu93
Laf78
0.23b 1.3 0.08
OriMC⫺1
FCRAO 14 m
Ziu93
Xu_97
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
Xu_97 Kle96
0.21 0.20 0.22
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Ziu93 Cer87b
3共4兲⫺2共3兲
1.3f 0.37
OriMC⫺1
FCRAO 14 m
Ziu93
3共2,2兲⫺2共1,1兲
1.72f
IRC⫹10216
IRAM 30 m
Cer00
Cer00
1共1,0兲⫺0共0,0兲 E
0.85f
OriMC⫺1
IRAM 30 m
Mau88
And88
155539.680*共33兲
CH3 CHO
8共4,4兲⫺9共3,7兲 A⫹⫹
0.07b
OriMC⫺1
FCRAO 14 m
Ziu93
Kle96
155540.380*共64兲
CH3 OCHO
22共3,19兲⫺22共3,20兲 A
b
OriMC⫺1
FCRAO 14 m
Ziu93
Oes99
155549.7 155567.470*共6兲 155601. 155614.895*共6兲
unidentified AlNC unidentified CH2 DCN
OriMC⫺1 IRC⫹10216 IRC⫹10216 OriMC⫺1
FCRAO 14 m IRAM 30 m IRAM 30 m IRAM 30 m
Ziu93 Ziu02 Ziu02 Ger92a
155617.84*共1兲
HCOOH
155626.881*共51兲 155637.393*共61兲
HCCCN HCCCN
OriMC⫺1 Sgr B2共N兲
FCRAO 14 m IRAM 30 m
Ziu93 Vic00
Wil80 Laf78
155649.759*共53兲 155695.740*共18兲
HCCCN
1.56 1.56 0.07
Sgr B2共N兲 Sgr B2共N兲 OriMC⫺1
IRAM 30 m IRAM 30 m FCRAO 14 m
Vic00 Vic00 Ziu93
Laf78 Laf78 Xu_97
1.65f 1.00
IRC⫹10216
IRAM 30 m
Cer00
IRAM 30 m IRAM 30 m
Vic00 Cer00
Laf78
2.17f
Sgr B2共N兲 IRC⫹10216
13
155837.88* 共16兲
CH3 OH NaCN
155899.64* 共32兲
HCCCN
155901.305*共40兲
29
13⫺12 9共1,9兲⫺8共1,8兲 7共0,7兲⫺6共0,6兲 17⫺16 v7 ⫽2 ᐉ⫽0 17⫺16 v7 ⫽2 ᐉ⫽2 e 17⫺16 v7 ⫽2 ᐉ⫽2 f 8共0,8兲⫺8共⫺1,8兲 E 10共2,9兲⫺9共2,8兲
Si34 S
17⫺16 v7 ⫽3 ᐉ⫽1 e 9⫺8
CH3 OH
0.13 0.005 0.014 2.0f 0.04 1.56
7共0,7兲⫺7共⫺1,7兲 E
0.53b
OriMC⫺1
FCRAO 14 m
Ziu93
Xu_97
155997.472*共14兲
CH3 OH
9共0,9兲⫺9共⫺1,9兲 E
2.3b
OriMC⫺1
FCRAO 14 m
Ziu93
Xu_97
156062.872*共6兲
CCCS
27⫺26
IRC⫹10216
IRAM 30 m
Cer87b
156091.249*共9兲
33 SO2 CH3 CH2 CN CH3 OH CH3 OCHO
1.0f 0.14
OriMC⫺1
FCRAO 14 m
Ziu93
25共2,23兲⫺24共3,22兲 6共2,4兲⫺7共17兲 A⫹ 22共3,19兲⫺22共2,20兲 A
0.18 1.45
OriMC⫺1 OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93 Ziu93
CH3 CH2 CN
Ziu93
155994.210*共17兲
156112.936*共17兲 156127.695*共18兲 156164.905*共61兲
13
4共3,1兲⫺5共2,4兲
18共0,18兲⫺17共0,17兲
0.07b 0.23
OriMC⫺1
FCRAO 14 m
6共0,6兲⫺6共⫺1,6兲 E
0.23
OriMC⫺1
FCRAO 14 m
Ziu93
156207.554*共14兲
CH3 OH CH2 DCN
9共6,*兲⫺8共6,3*
0.4f
OriMC⫺1
IRAM 30 m
Ger92a
156236.135*共10兲
CH2 DCN
9共5,*兲⫺8共5,*兲
0.6f
OriMC⫺1
IRAM 30 m
Ger92a
156248.681*共72兲
12⫺11
1.52f
IRC⫹10216
IRAM 30 m
Cer87c
156259.779*共7兲
Na35Cl CH2 DCN
9共4,*兲⫺8共4,*兲
0.7f
OriMC⫺1
IRAM 30 m
Ger92a
156278.861*共6兲
CH2 DCN
9共3,7兲⫺8共3,6兲
1.7bf
OriMC⫺1
IRAM 30 m
Ger92a
156171.663*共10兲 156186.515*共17兲
13
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Xu_97 Oes99 Xu_97
Clo64
MICROWAVE TRANSITIONS
249
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Telescope
Astr. Ref.
Lab. Ref.
CH2 DCN
9共3,6兲⫺8共3,5兲
b
OriMC⫺1
IRAM 30 m
Ger92a
9共0,9兲⫺8共0,8兲
3.2f
OriMC⫺1
IRAM 30 m
Ger92a
156286.524*(5)
CH2 DCN
9共2,8兲⫺8共2,7兲
5.4f
OriMC⫺1
IRAM 30 m
Ger92a
156304.660*(5)
CH2 DCN
9共2,7兲⫺8共2,6兲
2.8f
OriMC⫺1
IRAM 30 m
Ger92a
156323.27*(28)
NaCN
10共4,7兲⫺9共4,6兲
2.32fb
IRC⫹10216
IRAM 30 m
Cer00
156325.87*(28) 156456.48共30兲
NaCN
10共4,6兲⫺9共4,5兲
b
IRC⫹10216
IRAM 30 m
Cer00
7共0,7兲⫺6共0,6兲
n.r.
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b
8共0,8兲⫺8共⫺1,8兲 E 10共3,8兲⫺9共3,7兲
1.1
NRAO 11 m IRAM 30 m
Hol81 Cer00
Xu_97
1.02f
OriMC⫺1 IRC⫹10216
1.52f
IRC⫹10216
IRAM 30 m
Cer87c
0.85f 1.5
IRC⫹10216
IRAM 30 m
Cer00
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Hol81 Cer00
Xu_97
OriMC⫺1 OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Ger92a
Xu_97
IRC⫹10216
IRAM 30 m
Cer87b
OriMC⫺1 IRC⫹10216
FCRAO 14 m IRAM 30 m
Ziu93 Cer00
Yam90a
OriMC⫺1 IRC⫹10216
FCRAO 14 m IRAM 30 m
Ziu93 Cer00
Xu_97 Yam90a
OriMC⫺1
FCRAO 14 m
Ziu93
FCRAO 14 m FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93 Ziu93
Xu_97 Xu_97 Xu_97
29
SiC2 CH3 OH NaCN Al37Cl unidentified
11⫺10
156602.346*共13兲 156684.30* 共22兲
CH3 OH NaCN
2共1,2兲⫺3共0,3兲 A⫹ 10共3,7兲⫺9共3,6兲
156828.480*共13兲
CH3 OH unidentified CH2 DCN
7共0,7兲⫺7共⫺1,7兲 E 9共1,8兲⫺8共1,7兲
1.7f
CCS
13,12⫺12,11
1.7f 0.07
156547.15*(5) 156559.8共15兲
156842.2
157000.7 157038.926(30) 157048.586*共13兲 157061.172 共30兲
U U U
Source
CH2 DCN
156970.282*(6) 156981.664*共16兲 U
T r 共K兲/T a 共K兲
156278.905*(6)
156541.50* 共22兲
U
Quantum numbers
156281.370*(5)
156488.858*共13兲
U
Formula
unidentified l⫺C3 H CH3 OH l⫺C3 H
1.28f 1.75 0.07
N⫽7⫺6 v4 ⫽1 a 6共0,6兲⫺6共⫺1,6兲 E
1.46f 2.20 1.54f 0.095 2.25 2.25
157135.265*(5)
SO2
N⫽7⫺6 v4 ⫽1 b 33共4,30兲⫺32共5,27兲
157178.962*共13兲 157246.041*共14兲 157270.818*共15兲
CH3 OH CH3 OH CH3 OH
5共0,5兲⫺5共⫺1,5兲 E 4共0,4兲⫺4共⫺1,4兲 E 1共0,1兲⫺1共⫺1,1兲 E
2.32b
OriMC⫺1 OriMC⫺1 OriMC⫺1
157272.320*共14兲
CH3 OH
3共0,3兲⫺3共⫺1,3兲 E
b
OriMC⫺1
FCRAO 14 m
Ziu93
Xu_97
157276.004*共15兲 157286.7 157304.7 157337.2
CH3 OH unidentified unidentified unidentified
2共0,2兲⫺2共⫺1,2兲 E
2.0 0.08 0.05
FCRAO FCRAO FCRAO FCRAO
m m m m
Ziu93 Ziu93 Ziu93 Ziu93
Xu_97
0.04b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
157342.818*共15兲
CH3 CHO
3共⫺3,1兲⫺4共⫺2,3兲 E
b
OriMC⫺1
FCRAO 14 m
Ziu93
Kle96
157344.202*共12兲
CH3 CH2 CN
19共4,15兲⫺19共3,16兲
b
OriMC⫺1
FCRAO 14 m
Ziu93
14 14 14 14
U
157354.7
unidentified
0.04b
OriMC⫺1
FCRAO 14 m
Ziu93
U
157388.3共8兲
unidentified
0.60f 0.29
IRC⫹10216
IRAM 30 m
Cer00
IRC⫹10216
IRAM 30 m
Cer89
0.08b
OriMC⫺1
FCRAO 14 m
Ziu93
b
OriMC⫺1
FCRAO 14 m
Ziu93
OriMC⫺1 OriMC⫺1 IRC⫹10216
FCRAO 14 m FCRAO 14 m IRAM 30 m
Ziu93 Ziu93 Cer00
157494.101 共18兲
SiC
3 ⌸2 4⫺3 e, f 9共8,1兲⫺8共8,0兲
Cer89
U
157525.67*(9)
t⫺CH3 CH2 OH
U
157525.67*(9) 157557.7 157574.849*共24兲 157579.805*共30兲
t⫺CH3 CH2 OH unidentified CH3 OH
157598.615*(5)
0.07
OriMC⫺1
FCRAO 14 m
Ziu93
157929.337*(6)
O13CS CH3 OCH3
13共3,11兲⫺13共2,12兲 EA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
157929.349*(4)
CH3 OCH3
13共3,11兲⫺13共2,12兲 AE
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
157932.342*(4)
CH3 OCH3
13共3,11兲⫺13共2,12兲 EE
0.23b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
0.91f
IRC⫹10216
IRAM 30 m
Cer00
U
U
U
157935.2共6兲
unidentified
Xu_97
CH3 OCH3
13共3,11兲⫺13共2,12兲 AA
b
OriMC⫺1
FCRAO 14 m
Ziu93
Gro98
CH3 CHO
8共1,7兲⫺7共1,6兲 E
0.08
OriMC⫺1
FCRAO 14 m
Ziu93
Kle96
IRC⫹10216
IRAM 30 m
Cer00
8共1,7兲⫺7共1,6兲 A⫺⫺
1.42f 0.06
OriMC⫺1
FCRAO 14 m
Ziu93
IRC⫹10216
IRAM 30 m
Cer00
157980.7共8兲
unidentified CH3 CHO unidentified
Kle96
158107.357*(1)
OCS
13⫺12
0.74f 0.76
OriMC⫺1
FCRAO 14 m
Ziu93
158199.773*(4) 158297.219*共29兲
SO2
3共2,2兲⫺3共1,3兲
0.71
OriMC⫺1
FCRAO 14 m
Ziu93
CH3 OCHO CCCN
5共4,1兲⫺4共3,2兲 A 16⫺15 a
0.06
OriMC⫺1 IRC⫹10216
FCRAO 14 m IRAM 30 m
Ziu93 Cer00
Oes99 Got83
SiC2
7共0,7兲⫺6共0,6兲
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b
OriMC⫺1 IRC⫹10216
FCRAO 14 m IRAM 30 m
Ziu93 Cer00
OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93
OriMC⫺1 IRC⫹10216
FCRAO 14 m IRAM 30 m
Ziu93 Cer00
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 11 m FCRAO 14 m FCRAO 14 m FCRAO 14 m
Hol81 Ziu93 Ziu93 Ziu93
158499.23*(8) 158522.0 158616.72* 共16兲
unidentified NaCN
158657.435*共10兲
CH2 CHCN
158692.020*共19兲
H13CCCN CH3 OCHO
158704.431*共25兲 158903.105*共36兲 U U U
13⫺12
18.3f
157935.341*(6)
158302.14*(4) U
SiS
13共5,9兲⫺14共4,10兲 E 9⫺8
0.18 0.33
157937.695*(7) 157960.0共8兲 157974.598*(7)
U
30
9共8,2兲⫺8共8,1兲
158971.853*共14兲 159007.0 159030.0 159318.0
Si34S SO unidentified unidentified unidentified
22.5f n.r. 0.16
10共2,8兲⫺9共2,7兲 17共0,17兲⫺16共0,16兲 18⫺17
1.66f 0.06 0.32
13共3,11兲⫺12共3,10兲 A
0.30
9⫺8
25.8f 3.5 0.05 0.05 0.07
3共4兲⫺2共3兲
Laf78 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
250
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
159437.464 共50兲
CH3 OD
8共1,7兲⫺8共0,8兲 A⫺
3.7f n.r.
OriMC⫺1
IRAM 30 m
Mau88
And88
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b
159552.64共60兲 159571.086 共50兲 159582.070*共35兲 159654.733*共35兲 159662.739*共34兲 159670.820*共32兲 U
159888.873*共10兲 159915.6共10兲 160229.99*(9) 160312.16*(5) 160375.140*共16兲
U
SiC2 CH3 OD
6共0,6兲⫺5共1,5兲 E
Lab. Ref.
2.4f 0.06 0.07 0.12
OriMC⫺1
IRAM 30 m
Mau88
And88
OriMC⫺1 OriMC⫺1 OriMC⫺1
FCRAO 14 m FCRAO 14 m FCRAO 14 m
Ziu93 Ziu93 Ziu93
Oes99 Oes99 Oes99
13共10,4兲⫺12共10,3兲 E 18共2,17兲⫺17共2,16兲
0.13 0.15 0.07
7共2,6兲⫺6共2,5兲
1.1f
FCRAO 14 m NRAO 11 m NRAO 11 m IRAM 30 m
Ziu93 Hol81 Hol81 Cer91b
Oes99
Si13CC
OriMC⫺1 Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216
35
11⫺10
3.56f
Cer87c
CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO CH3 CH2 CN unidentified
13共11,*兲⫺12共11,*兲 A 13共10,3兲⫺12共11,2兲 E 13共10,*兲⫺12共10,*兲 A
Al Cl SiS
9⫺8
SiC2
29
IRC⫹10216
IRAM 30 m
IRC⫹10216
IRAM 30 m
Cer00
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b Cer91b
160815.53共40兲
30
7共4,4兲⫺6共4,3兲
30.0f n.r.
160825.62共40兲
30
7共4,3兲⫺6共4,2兲
n.r.
IRC⫹10216
IRAM 30 m
Cer91b
10共0,10兲⫺9共1,9兲
2.4
OriMC⫺1
NRAO 11 m
Hol81
160827.828*(4) 160941.90*共3兲
U
7共2,6兲⫺6共2,5兲
30
Astr. Ref.
SiC2
SO2
17.5⫺16.5
0.87f
IRC⫹10216
IRAM 30 m
Cer00
COL01
⌸1/2 J⫽33/2⫺31/2 e v7 ⫽1 16.5⫺15.5
8.85f
IRC⫹10216
IRAM 30 m
Cer00
COL01
0.42f
IRC⫹10216
IRAM 30 m
Cer00
COL01
9⫺8 v⫽3
0.33f
IRC⫹10216
IRAM 30 m
Cer00
NaCN
10共1,9兲⫺9共1,8兲
1.35f
IRC⫹10216
IRAM 30 m
Cer00
Si33S unidentified
9⫺8
4.75f
IRC⫹10216
IRAM 30 m
Cer00
1.19f
IRC⫹10216
IRAM 30 m
Cer00
161345.32* 共14兲
Si13CC
7共5,3兲⫺6共5,2兲
0.83bf
IRC⫹10216
IRAM 30 m
Cer00
161345.48* 共14兲
Si13CC
7共5,2兲⫺6共5,1兲
b
IRC⫹10216
IRAM 30 m
Cer00
161350.19* 共15兲
K35Cl unidentified
21⫺20
1.00f
IRC⫹10216
IRAM 30 m
Cer87c
160957.07* 共10兲
C13CCCH C4 H
160979.63*(3) 160991.442*共19兲
C13CCCH SiS
161014.75* 共13兲 161068.929*共20兲 161276.0共4兲
161451.8共8兲
2
1.18f
IRC⫹10216
IRAM 30 m
Cer00
⌸1/2 J⫽33/2⫺31/2 f v7 ⫽1
8.67f
IRC⫹10216
IRAM 30 m
Cer00
COL01
⌸3/2 J⫽33/2⫺31/2 v7 ⫽2 ᐉ⫽2
1.53f
IRC⫹10216
IRAM 30 m
Cer00
COL01
IRC⫹10216
IRAM 30 m
Cer00
JPL01
IRC⫹10216
IRAM 30 m
Cer00
161459.75* 共10兲
C4 H
161512.05* 共11兲
C4 H
161758.116*共11兲
C4 H
17.5⫺16.5
161786.667*共13兲
SiS
9⫺8 v⫽2
161796.573*共10兲
C4 H
16.5⫺15.5
161841.596*共6兲
CCCS
28⫺27
161977.186 共20兲
SiC
3
162121.467 共34兲
SiC
3
2 2
29.4f 1.63f
IRC⫹10216
IRAM 30 m
Cer00
IRC⫹10216
IRAM 30 m
Cer00
⌸1 4⫺3 e
1.85f 0.08
IRC⫹10216
IRAM 30 m
Cer89
Cer89
⌸1 4⫺3 f
0.12
IRC⫹10216
IRAM 30 m
Cer89
Cer89
35.2f
JPL01
IRC⫹10216
IRAM 30 m
Cer00
COL01
29
⌸3/2 J⫽35/2⫺33/2 e v7 ⫽1 7共6,1兲⫺7共6,0兲
8.47f
162372.1*
b
IRC⫹10216
IRAM 30 m
Cer00
Cer00
162372.1*
29
7共6,2兲⫺7共6,1兲
1.40bf
IRC⫹10216
IRAM 30 m
Cer00
Cer00
b
NGC6334I
IRAM 30 m
Bac90
Gro98
162322.19*共9兲
162409.479*共12兲
C4 H
2
SiC2
SiC2 CH3 OCH3
22共4,18兲⫺22共3,19兲 AE⫹EA
162410.721*共8兲
CH3 OCH3
22共4,18兲⫺22共3,19兲 EE
0.5b
NGC6334I
IRAM 30 m
Bac90
Gro98
162411.962*共14兲
CH3 OCH3
22共4,18兲⫺22共3,19兲 AA
b
NGC6334I
IRAM 30 m
Bac90
Gro98
162528.946*共6兲
CH3 OCH3
8共1,8兲⫺7共0,7兲 AE⫹EA
b
NGC6334I
IRAM 30 m
Bac90
Gro98
162529.571*共6兲
CH3 OCH3
8共1,8兲⫺7共0,7兲 EE
0.1b
NGC6334I
IRAM 30 m
Bac90
Gro98
162530.198*共6兲
CH3 OCH3
8共1,8兲⫺7共0,7兲 AA
b
NGC6334I
IRAM 30 m
Bac90
Gro98
162547.54*共8兲
C4 H
IRC⫹10216
IRAM 30 m
Cer00
COL01
162581.773*共10兲 162603.18共15兲
SiS C4 H
IRC⫹10216 IRC⫹10216
IRAM 30 m IRAM 30 m
Gue87a Gue87a
Gue87a Gue87a
162640.94*共8兲 162775.872*共7兲 162808.32* 共10兲 162937.95*共5兲 162958.651*共3兲 162965.13* 共21兲 163081.9共10兲 163093.1共10兲 163119.390*共5兲
2
⌺ N⫽17⫺16 v7 ⫽2 ᐉ⫽0 9⫺8 v⫽1 ⌺ J⫽17⫺16 v7 ⫽2U
2
0.65bf n.r.
IRC⫹10216
IRAM 30 m
Cer00
Sgr B2共M兲
FCRAO 14 m
Hol91
⌸3/2 J⫽35/2⫺33/2 f v7 ⫽1
8.33f
IRC⫹10216
IRAM 30 m
Cer00
COL01
2共0,2兲⫺1共0,1兲 8共1,8兲⫺7共1,7兲 7共3,5兲⫺6共3,4兲 v3 ⫽1 7共4,4兲⫺6共4,3兲
0.06 0.10 0.004 n.r.
Sgr B2共M兲 Sgr B2共M兲 IRC⫹10216 IRC⫹10216
FCRAO 14 m FCRAO 14 m NRAO 12 m IRAM 30 m
Hol91 Hol91 Gen97 Cer91b
Bog91 Cer91b Cer91b
7共3,4兲⫺6共3,3兲
Si13CC
7共1,7兲⫺6共0,6兲
34
SO2 C4 H
2
HNO NH2 CHO SiC2 29
SiC2
3.89f 0.1 0.2
7共4,3兲⫺6共4,2兲
n.r.
IRC⫹10216
IRAM 30 m
Cer91b
18共2,16兲⫺17共3,15兲
0.20
NRAO 11 m IRAM 30 m
Hol83a Cer00
8共1,7兲⫺7共1,6兲
0.75f 0.20
Sgr B2共M兲 IRC⫹10216
0.27f
Sgr B2共M兲 IRC⫹10216
NRAO 11 m IRAM 30 m
Hol83a Cer00
29
SiC2 SO2
U
163120.4共10兲
unidentified
U
163160.836*共38兲 163178.8共15兲
CH2 CO unidentified
U
163202.7共15兲
unidentified
0.33f
IRC⫹10216
IRAM 30 m
Cer00
U
163264.4共15兲
unidentified
0.33f
IRC⫹10216
IRAM 30 m
Cer00
0.76f
IRC⫹10216
IRAM 30 m
Cer00
IRC⫹10216
IRAM 30 m
Cer00
4.83f
IRC⫹10216
IRAM 30 m
Cer00
Got85
1.08f
IRC⫹10216
IRAM 30 m
Cer00
Laf78
163316.61* 共10兲
C4 H
163376.759*共12兲
SiS
163491.296 共50兲
l⫺C3 H
163508.740*共29兲
HC13CCN
2
⌸5/2 J⫽35/2⫺33/2 v7 ⫽2 ᐉ⫽2 9⫺8 2
⌸1/2 J⫽15/2⫺13/2 a 18⫺17
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
283.f
COL01
MICROWAVE TRANSITIONS
251
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 163597.566 共50兲
l⫺C3 H
163704.501*共15兲
HCC13CN HCCCN CH3 OCHO CH3 OCHO
163753.405*共5兲 163829.609*共24兲 163835.522*共25兲 163872.904*共16兲 U
163902.共1兲 163925.745*共24兲
13 CH3 OH unidentified CH3 OCHO
163927.362*共29兲
U
U
Quantum numbers 2
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
⌸1/2 J⫽15/2⫺13/2 b
5.12f
IRC⫹10216
IRAM 30 m
Cer00
Got85
18⫺17
2.66f 2.0 0.35 0.40 0.15
IRC⫹10216
IRAM 30 m
Cer00
Laf78
IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m NRAO 11 m NRAO 11 m NRAO 11 m
Aud94 Sny85a Sny85a Sny85a
Oes99 Oes99 Xu_97
0.10
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Sny85a Sny85a
Oes99
OriMC⫺1
NRAO 11 m
Sny85a
Oes99
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b
IRC⫹10216
IRAM 30 m
Cer00
IRC⫹10216 IRC⫹10216 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m
Cer91b Cer91b Cer87c
Cer91b Cer91b
W51e1/e2 W51e1/e2 W3共OH兲
IRAM 30 m IRAM 30 m IRAM 30 m
Kal02 Kal02 Kal02
Oes99 Oes99 Xu_97 Xu_97
18⫺17 14共1,13兲⫺13共1,12兲 E 14共1,13兲⫺13共1,12兲 A 7共0,7兲⫺6共1,5兲 E 15共0,15兲⫺14共1,14兲 E
b
CH3 OCHO
15共0,15兲⫺14共1,14兲 A
164069.081*共32兲 164498.36* 共44兲
SiC2 SiC2
7共2,6兲⫺6共2,5兲
0.15b n.r.
164770.534*共47兲 164770.535*共47兲 164867.840*共25兲
SiC2 SiC2 AlF
7共6,1兲⫺6共6,0兲 7共6,2兲⫺6共6,1兲 5⫺4
164955.654*共24兲 164968.659*共25兲 165050.229*共7兲
CH3 OCHO CH3 OCHO CH3 OH
13共2,11兲⫺12共2,10兲 E 13共2,11兲⫺12共2,10兲 A 1共1,0兲⫺1共0,1兲 E
13.4f
165061.187*共7兲
CH3 OH
2共1,1兲⫺2共0,2兲 E
11.7f
165083.30* 共17兲
NaCN
10共1,11兲⫺10共1,10兲
165099.300*共7兲
CH3 OH
3共1,2兲⫺3共0,3兲 E
165123.642*共4兲
SO2
9共4,6兲⫺10共3,7兲
196.f
OriMC⫺1
IRAM 30 m
Kal02
W3共OH兲
IRAM 30 m
Kal02
OriMC⫺1
IRAM 30 m
Kal02
4共2,3兲⫺4共0,4兲
165144.642*共4兲
SO2
5共2,4兲⫺5共1,5兲
165190.539*共7兲
CH3 OH
4共1,3兲⫺4共0,4兲 E
165225.436*共5兲
SO2
7共1,7兲⫺6共0,6兲
1.86f n.r. n.r. 1.90f n.r. n.r.
W3共OH兲
IRAM 30 m
Kal02
IRC⫹10216
IRAM 30 m
Cer00
12.5f
W3共OH兲
IRAM 30 m
Kal02
84.f
OriMC⫺1
IRAM 30 m
Kal02
1.27f
12.3f 288.f
165369.410*共7兲
CH3 OH
5共1,4兲⫺5共0,5兲 E
6.9f
W3共OH兲
IRAM 30 m
Kal02
165454.381*共4兲
CH3 CN
9共6兲⫺8共6兲
14.5f
NGC6334F
IRAM 30 m
Kal02
165489.400*共3兲
CH3 CN
9共5兲⫺8共5兲
14.5f
NGC6334F
IRAM 30 m
Kal02
165510.992*共28兲
SiC2
7共4,4兲⫺6共4,3兲
14.2f
IRC⫹10216
IRAM 30 m
Cer00
165518.071*共3兲
CH3 CN
9共4兲⫺8共4兲
16.2f
NGC6334F
IRAM 30 m
Kal02
165523.865*共28兲
SiC2
7共4,3兲⫺6共4,2兲
13.9f
IRC⫹10216
IRAM 30 m
Cer00
165540.383*共2兲
CH3 CN
9共3兲⫺8共3兲
IRC⫹10216
IRAM 30 m
Cer00
165540.383*共2兲
CH3 CN
9共3兲⫺8共3兲
21.8f
NGC6334F
IRAM 30 m
Kal02
165556.326*共3兲
CH3 CN
9共2兲⫺8共2兲
18.5f
NGC6334F
IRAM 30 m
Kal02
165565.895*共3兲
CH3 CN
9共1兲⫺8共1兲
IRC⫹10216
IRAM 30 m
Cer00
165565.895*共3兲
CH3 CN
9共1兲⫺8共1兲
165569.085*共3兲
CH3 CN
9共0兲⫺8共0兲
CH3 CN
9共0兲⫺8共0兲
165569.085*共3兲 U
Formula
165835.0共8兲
unidentified
165861.3共8兲
unidentified
3.98f
2.20f 26.4f 4.55f
NGC6334F
IRAM 30 m
Kal02
IRC⫹10216
IRAM 30 m
Cer00
NGC6334F
IRAM 30 m
Kal02
0.89f
IRC⫹10216
IRAM 30 m
Cer00
15.3f
Xu_97
Xu_97
Xu_97
1.12f
IRC⫹10216
IRAM 30 m
Cer00
CCC CH
18.5⫺17.5
0.92f
IRC⫹10216
IRAM 30 m
Cer00
COL01
17.5⫺16.5
0.83f
IRC⫹10216
IRAM 30 m
Cer00
COL01
166234.
CCC13CH CHD2 OH
4共0兲⫺3共0兲e1
IRAS16293⫺2422
IRAM 30 m
Par02
Par02
166271. 166297.
CHD2 OH CHD2 OH
4共2⫺兲⫺3共2⫺兲 e1 4共3⫹兲⫺3共3⫺兲 e1
0.39f 0.04
IRAS16293⫺2422 IRAS16293⫺2422
IRAM 30 m IRAM 30 m
Par02 Par02
Par02 Par02
166298.
CHD2 OH
4共3⫺兲⫺3共3⫺兲 e1
IRAS16293⫺2422
IRAM 30 m
Par02
Par02
166304. 166327.
CHD2 OH CHD2 OH
4共2⫹兲⫺3共2⫹兲 e1 4共0兲⫺3共0兲 o1
IRAS16293⫺2422 IRAS16293⫺2422
IRAM 30 m IRAM 30 m
Par02 Par02
Par02 Par02
166435.
CHD2 OH unidentified
4共0兲⫺3共0兲 e0
0.05
IRAS16293⫺2422 IRC⫹10216
IRAM 30 m IRAM 30 m
Par02 Cer00
Par02
27/2,14⫺25/2,13
1.58f 1.3
Kaw93
166101.432*共34兲 166138.817*共37兲
166837.9共8兲 167019.134*共10兲 167025.09* 共16兲 167034.354*共10兲 167160.642*共94兲 167620.173*共6兲 167910.516共2兲 167931.149*共14兲 168051.47* 共80兲
13
24
MgNC
Si13CC
7共2,5兲⫺6共2,4兲
0.03b 0.06 0.17f
1.35f 1.4
IRC⫹10216
IRAM 30 m
Gue93
IRC⫹10216
IRAM 30 m
Gue95
IRC⫹10216
IRAM 30 m
Gue93
SiO CCCS
4⫺3 v⫽2
0.3
VYCMa
IRAM 30 m
Cer92
29⫺28
IRAM 30 m
Cer87b
1共1,0兲⫺1共0,1兲
1.0f 0.1
IRC⫹10216
H2 34S CH3 OH
W49
FCRAO 14 m
Min91
Hui71
9共1,8兲⫺9共0,9兲 E 7共2,5兲⫺6共2,4兲
0.13 n.r.
Sgr B2共M兲 IRC⫹10216
FCRAO 14 m IRAM 30 m
Min91 Cer91b
Xu_97 Got83
24
MgNC
30
29
SiC2
29/2,14⫺27/2,13
b
Kaw93
168194.94*共4兲
CCCN
17⫺16 a
10.1f
IRC⫹10216
IRAM 30 m
Cer00
168213.68*共4兲
CCCN
17⫺16 b
10.9f
IRC⫹10216
IRAM 30 m
Cer00
Got83
168274.456 共16兲
13
2⫺15/2⫺3/2 F⫽3,3.5⫺2,1.5
0.25f
OriMC⫺1
IRAM 30 m
Sal94
McC95
168276.599 共16兲
13
2⫺15/2⫺3/2 F⫽3,2.5⫺2,1.5
0.20f
OriMC⫺1
IRAM 30 m
Sal94
McC95
168303.624 共16兲
13
2⫺15/2⫺3/2 F⫽2,2.5⫺1,1.5
0.19f
OriMC⫺1
IRAM 30 m
Sal94
McC95
168307.667 共16兲
13
2⫺13/2⫺1/2 F⫽2,2.5⫺1,1.5
0.12f
OriMC⫺1
IRAM 30 m
Sal94
McC95
VYCMa
IRAM 30 m
Cer92
168323.089*共83兲
CCH CCH CCH CCH
30
SiO
4⫺3 v⫽1
12.0
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
252
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 168401.148*共34兲 168406.788*共11兲 168657.72* 共18兲 168762.76237共2兲 168815.124*共10兲
Quantum numbers
T r 共K兲/T a 共K兲
Source
H2 COH⫹ CCS
1共1,0兲⫺1共0,1兲
⫺0.191
Sgr B2共M兲
NRO45 m
Ohi96
13,13⫺12,12 7共1,6兲⫺6共1,5兲
0.05
Sgr B2共M兲 IRC⫹10216
NRO45 m IRAM 30 m
Ohi96 Cer91b
OriMC⫺1 OriMC⫺1
NRAO 11 m NRAO 11 m
Tha72 Hol81
0.56f
IRC⫹10216
IRAM 30 m
Cer00
1.53f
IRC⫹10216
IRAM 30 m
Cer00
1.54f
IRC⫹10216
IRAM 30 m
Cer87c
0.7
OriMC⫺1 IRC⫹10216
NRAO 11 m IRAM 30 m
Wil72 Cer00
Si13CC H2 S
U
168967.7共10兲
U
169155.0共12兲
unidentified
169335.315*共17兲 169486.632*共90兲
1共1,0兲⫺1共0,1兲 4共3兲⫺3共3兲
34
SO unidentified
169257.256*共73兲
Astr. Ref.
Formula
13⫺12
Na35Cl CH3 OH
10共1,9兲⫺10共0,10兲 E 4⫺3
30
SiO
1.1f 2.3 0.9
10.2f
Telescope
U
169742.3共8兲
unidentified
1.05f
IRC⫹10216
IRAM 30 m
Cer00
U
170025.1共20兲
unidentified
1.96f
IRC⫹10216
IRAM 30 m
Cer00
U
170025.1共20兲
unidentified
IRC⫹10216
IRAM 30 m
Cer00
U
170070.31* 共11兲 170144.3共10兲
SiO unidentified
1.96f 40.0
VYCMa IRC⫹10216
IRAM 30 m IRAM 30 m
Cer93 Cer00
170161.4共10兲
unidentified
U
170322.749 共80兲 170328.194*共83兲
4⫺3 v⫽3
1.74f
HC18O⫹
2⫺1 4⫺3 v⫽1
29
SiO
1.54f 0.028 4.0
IRC⫹10216
IRAM 30 m
Cer00
Oribar
NRAO 12 m
App99a
VYCMa
IRAM 30 m
Cer91c
Lab. Ref.
Cup68
Xu_97
Bog81a
170490.665 共16兲
C13CH
2⫺15/2⫺3/2 F⫽3,3.5⫺2,2.5
0.38f
OriMC⫺1
KOSMA 3m
Sal94
McC95
170492.383 共16兲
C13CH
2⫺15/2⫺3/2 F⫽3,2.5⫺2,1.5
0.29f
OriMC⫺1
KOSMA 3m
Sal94
McC95
170505.040 共16兲
C13CH
2⫺15/2⫺3/2 F⫽2,1.5⫺1,0.5
0.14f
OriMC⫺1
KOSMA 3m
Sal94
McC95
170509.286 共16兲
C13CH C4 H
2⫺15/2⫺3/2 F⫽2,2.5⫺1,1.5
0.30f
OriMC⫺1
KOSMA 3m
Sal94
McC95
⌸1/2 J⫽35/2⫺33/2 e v7 ⫽1
2.82f
IRC⫹10216
IRAM 30 m
Cer00
COL01
C13CH SiC2
2⫺13/2⫺1/2 F⫽2,2.5⫺1,1.5 7共2,5兲⫺6共2,4兲
0.17f 0.16
OriMC⫺1
KOSMA 3m
Sal94
McC95
IRC⫹10216
NRAO 11 m
Tha84
Got89
12⫺11
1.16f 0.2 0.31 0.51 0.58
IRC⫹10216
IRAM 30 m
Cer00
170876.407*共2兲 170892.723*共1兲 170902.516*共1兲 170905.781*共1兲 171062.70*共9兲
Al37Cl CH3 CCH CH3 CCH CH3 CCH CH3 CCH C4 H
IRC⫹10216
IRAM 30 m
Cer00
COL01
C4 H
⌸1/2 J⫽35/2⫺33/2 f v7 ⫽1 18.5⫺17.5
4.83f
171272.249*共28兲
25.3f
IRC⫹10216
IRAM 30 m
Cer00
JPL01
171275.150*共94兲
SiO
4⫺3 v⫽2
87.e
X⫺Cyg
NRAO 11 m
Sch82
170529.03*共8兲 170533.594 共16兲 170740.916共9兲 170770.85* 共10兲
2
10共3兲⫺9共3兲 10共2兲⫺9共2兲 10共1兲⫺9共1兲 10共0兲⫺9共0兲 2
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO MMWO MMWO MMWO
4.9 4.9 4.9 4.9
m m m m
Mun84 Mun84 Mun84 Mun84
171310.707*共26兲
C4 H
17.5⫺16.5
29.8f
IRC⫹10216
IRAM 30 m
Cer00
171490.65* 共50兲
NaCN
11共6,5兲⫺10共6,4兲
b
IRC⫹10216
IRAM 30 m
Cer00
171490.65* 共50兲
NaCN
11共6,6兲⫺10共6,5兲
IRAM 30 m
Cer00
29
4⫺3 v⫽0
0.86fb 0.5
IRC⫹10216
171512.694*共90兲
VYCMa
IRAM 30 m
Cer92
171671.77* 共14兲
23⫺22
0.46f
IRC⫹10216
IRAM 30 m
Cer00
171733.47* 共42兲
K37Cl NaCN
11共5,7兲⫺10共5,6兲
1.08fb
IRC⫹10216
IRAM 30 m
Cer00
171733.52* 共42兲
NaCN
11共5,6兲⫺10共5,5兲
b
IRC⫹10216
IRAM 30 m
Cer00
⌸3/2 J⫽37/2⫺35/2 e v7 ⫽1
4.66f
IRC⫹10216
IRAM 30 m
171771.94*共8兲
SiO
C4 H
JPL01
Cer00
COL01
171958.650 共50兲
l⫺C3 H
2
⌸3/2 J⫽15/2⫺13/2 a
3.52f
IRC⫹10216
IRAM 30 m
Cer00
Got85
172094.778 共50兲
l⫺C3 H
2
IRAM 30 m
Cer00
Got85
OriMC⫺1
NRAO 11 m
Wil72
172108.36共50兲
HC15N C4 H
3.43f 0.45
IRC⫹10216
172107.962*共10兲
⌸3/2 J⫽15/2⫺13/2 b 2⫺1
172164.12共80兲
C4 H
172266.2*
2
⌺ J⫽18⫺17 v7 ⫽2 L
n.r.
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
⌺ J⫽18⫺17 v7 ⫽2 U 8共1,8兲⫺7共1,7兲v3 ⫽1
n.r.
IRC⫹10216
IRAM 30 m
Gue87a
Gue87a
1.51f 0.24
IRC⫹10216
IRAM 30 m
Cer00
Cer00
2共1,1兲⫺2共0,2兲
NRAO 12 m IRAM 30 m
Dic97a Cer00
COL01
2 2
SiC2
172267.01* 共10兲 172288.87*共9兲
CH2 NH C4 H
⌸3/2 J⫽37/2⫺35/2 f v7 ⫽1
6.16f
OriMC⫺1 IRC⫹10216
172463.355*共53兲
c⫺C3 H
4共1,4兲⫺3共1,3兲9/2⫺7/2 F⫽5⫺4
2.89fb
IRC⫹10216
IRAM 30 m
Cer00
JPL01
172463.719*共53兲
4共1,4兲⫺3共1,3兲9/2⫺7/2 F⫽4⫺3
b
IRC⫹10216
IRAM 30 m
Cer00
JPL01
172481.140*共83兲
c⫺C3 H SiO
4⫺3 v⫽1
50.e
X⫺Cyg
NRAO 11 m
Sch82
172676.573 共50兲
H13CN
2⫺1 F⫽1⫺0,2⫺2
b
OriMC⫺1
NRAO 11 m
Wil72
Pea76
172677.959 共50兲
H13CN
2⫺1 F⫽2⫺1,3⫺2
0.91b
OriMC⫺1
NRAO 11 m
Wil72
Pea76
172680.209 共50兲
2⫺1 F⫽1⫺1 14共7,8兲⫺13共7,7兲 A
b
OriMC⫺1
NRAO 11 m
Wil72
Pea76
172692.162*共25兲
H13CN CH3 OCHO
bf
W51e1/e2
IRAM 30 m
Kal02
Oes99
172693.142*共24兲
CH3 OCHO
14共7,8兲⫺13共7,7兲 E
W51e1/e2
IRAM 30 m
Kal02
Oes99
172693.624*共25兲
CH3 OCHO
14共7,7兲⫺13共7,6兲 A
W51e1/e2
IRAM 30 m
Kal02
Oes99
172849.287*共5兲
HCCCN
19⫺18
W51e1/e2
IRAM 30 m
Kal02
173377.38* 共10兲
HCO
173391.272*共19兲
2共0,2兲⫺1共0,1兲5/2⫺3/2 F⫽3⫺2 5共2,3兲⫺4共1,4兲
173391.704*共15兲
t⫺CH3 CH2 OH CH3 CH2 CN
173406.08* 共10兲
HCO
173443.06* 共10兲
HCO
2共0,2兲⫺1共0,1兲3/2⫺1/2 F⫽2⫺1
2
26.4bf bf
87.0f 0.12
OriMC⫺2
NRAO 11 m
Sny85a
b
OriMC⫺2
NRAO 11 m
Sny85a
10共2,8兲⫺9共1,9兲
0.05b
OriMC⫺2
NRAO 11 m
Sny85a
2共0,2兲⫺1共0,1兲5/2⫺3/2 F⫽2⫺1
0.05
OriMC⫺2
NRAO 11 m
Sny85a
Sny85a
0.06
OriMC⫺2
NRAO 11 m
Sny85a
Sny85a
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Sny85a
MICROWAVE TRANSITIONS
253
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Oribar
NRAO 12 m
App99a
Bog81a
OriMC⫺1
NRAO 11 m
Sch82
173766.893*共47兲
H2 COH⫹
5共0,5兲⫺4共1,4兲
177238.655*共7兲 178136.477*共7兲 178170.373*共3兲 178972.05共5兲
HCN HCN HCN
2⫺1 v2ᐉ ⫽1 e 2⫺1 v2ᐉ ⫽1 f 2⫺12 v2ᐉ ⫽0 2⫺1
80. 1. 0.8
3共1,3兲⫺2共2,0兲 21⫺20 4⫺3 16共1,15兲⫺16共0,16兲
10. 3.0 3.3 4.87
13共5,9兲⫺14共4,10兲 v2 ⫽1 22⫺21 v7 ⫽1 ᐉ⫽1 f 16共5,11兲⫺15共5,10兲 E 16共5,11兲⫺15共5,10兲 A 共U203918.兲 共U203806.兲 共U204707.兲 3共1,2兲⫺2共1,1兲 11共2,10兲⫺11共1,11兲
0.28 0.73 0.5 0.45 1.48 0.27 0.19 0.79 0.62
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO NRAO
m m m m m m m m m
Jew89 Jew89 Jew89 Jew89 Jew89 Jew89 Jew89 Jew89 Jew89
HOC⫹ H2 O HCCCN CS SO2 SO2
0.083
Sgr B2共M兲
NRO 45 m
Ohi96
IRC⫹10216 IRC⫹10216 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m
Luc89 Luc89 Luc89
Sgr B2共OH兲
NRAO 12 m
Ziu95a
Bla83
OriMC⫺1 W49N NGC2024 OriMC⫺1
KAO 1 m IRAM 30 m MMWO 4.9 m NRAO 12 m
Wat77 Cer90 Mun84a Jew89
Hui71
12 12 12 12 12 12 12 12 12
Mak02 Mak02 Mak02
Laf78 Oes99 Oes99
200913.79*共4兲 200936.080*共21兲 200956.380*共21兲 201088. 201200. 201323. 201341.377*共8兲 201376.478*共7兲
HCCCN CH3 OCHO CH3 OCHO unidentified unidentified unidentified HDCO
201429.63共10兲 201445.644*共17兲 201536.208*共8兲
HCCCN CH3 OH CH3 OCH3
22⫺21 v7 ⫽2 ᐉ⫽2 f 5共2,3兲⫺6共1,6兲 A⫹
0.12 2.52
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
Laf78 Xu_97
12共4,8兲⫺12共3,9兲 AE
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
201536.738*共8兲
CH3 OCH3
12共4,8兲⫺12共3,9兲 EA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
201539.699*共6兲
CH3 OCH3
12共4,8兲⫺12共3,9兲 EE
0.51b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
201542.925*共8兲
CH3 OCH3
12共4,8兲⫺12共3,9兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
201614.269*共8兲
H2 C18O
3共1,3兲⫺2共1,2兲
0.12
OriMC⫺1
NRAO 12 m
Jew89
201691.955*共5兲
OC34S
Jew89
34
SO2
34
17⫺16
0.30
OriMC⫺1
NRAO 12 m
4共5兲⫺3共4兲
2.33
OriMC⫺1
NRAO 12 m
Jew89
11共9兲⫺10共9兲 11共8兲⫺10共8兲
0.81 0.68
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
11共7兲⫺10共7兲 11共6兲⫺10共6兲 11共5兲⫺10共5兲
0.77 1.55 2.11 0.32 0.65 0.09
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO NRAO NRAO
m m m m m m
Jew89 Jew89 Jew89 Tur85 Tur85 Tur85
Bou80
11共9兲⫺10共9兲 v8 ⫽1 ᐉ⫽⫹1 11共6兲⫺10共6兲 v8 ⫽1 ᐉ⫽⫺1
0.18
W51 W51
NRAO 12 m NRAO 12 m
Tur85 Tur85
Bou80 Bou80
0.18b 0.18
W51
NRAO 12 m
Tur85
Bou80
W51
NRAO 12 m
Tur85
Bou80
OriMC⫺1 W51d
MMWO 4.9 m NRAO 12 m
Eri84 Jac88
DeL72
NRAO 12 m NRAO 12 m NRAO 12 m
Jac88 Jac88 Jac90
Gro98
202767.7*共1兲
SO CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN unidentified NH2 CHO CH3 CN CH3 CN CH3 CN
202769.65*共7兲
CH3 CN
11共1兲⫺10共1兲 v8 ⫽1 ᐉ⫽⫹1
202818.966*共66兲 203391.469*共6兲
CH3 CN SO2
11共5兲⫺10共5兲 v8 ⫽1 ᐉ⫽⫺1
202215.384*共5兲 202258.166*共4兲 202673. 202690.619*共7兲 202708.6*共1兲 202721.4*共1兲
203407.52共2兲
U
0.28 65e 0.192
2⫺1 4⫺3 v⫽0
202040.693*共10兲 202106.626*共8兲 202164.864*共6兲
U
Lab. Ref.
H13CO⫹ SiO
201846.667*共28兲
U
Astr. Ref.
173688.283*共90兲
183310.0906共15兲 191040.293*共6兲 195954.217*共8兲 200809.316*共5兲 200888.351*共9兲
U
Telescope
Quantum numbers
173506.782 共80兲
U U U
Source
T r 共K兲/T a 共K兲
Formula
203411.398*共8兲 203412.7 203418.702*共10兲
H2 18O CH3 OCH3 unidentified CH3 OCH3
203420.315*共12兲
CH3 OCH3
203423.124*共24兲 203806. 203853.696*共20兲 203864.194*共21兲 203918. 203936.77*共7兲
6共2,5兲⫺6共1,6兲 11共7兲⫺10共7兲 v8 ⫽1 ᐉ⫽⫺1
12共0,12兲⫺11共1,11兲 3共1,3兲⫺2共2,0兲
b
2.0
12 12 12 12 12 12
3共3,0兲⫺2共2,1兲 AE
0.10b 0.036 0.056
3共3,0兲⫺2共2,1兲 AA
0.10b
W51d W51d W51e1/e2
3共3,0兲⫺2共2,1兲 EE
b
W51e1/e2
NRAO 12 m
Jac90
Gro98
CH3 OCH3
3共3,0兲⫺2共2,1兲 EA
b
W51e1/e2
NRAO 12 m
Jac90
Gro98
unidentified CH3 OCHO CH3 OCHO unidentified
共U201200.兲 17共3,15兲⫺16共3,14兲 E 17共3,15兲⫺16共3,14兲 A 共U201088.兲
0.27 0.82 0.68 1.48
NRAO NRAO NRAO NRAO NRAO
m m m m m
Jew89 Jew89 Jew89 Jew89 Jew89
33
SO
4共5兲⫺3共4兲 F⫽9/2⫺7/2
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
203937.37*共8兲
33
SO
4共5兲⫺3共4兲 F⫽7/2⫺5/2
1.73b
OriMC⫺1
NRAO 12 m
Jew89
203939.24* 共16兲
33
SO
4共5兲⫺3共4兲 F⫽11/2⫺9/2
b
OriMC⫺1
NRAO 12 m
Jew89
203941.50* 共16兲
33
SO
4共5兲⫺3共4兲 F⫽5/2⫺3/2
b
OriMC⫺1
NRAO 12 m
Jew89
0.50 1.02
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
共U200936.兲 12共0,12兲⫺11共1,11兲
12 12 12 12 12
Gro98
Oes99 Oes99
204070. 204136.224*共8兲
unidentified
204158.441*共16兲
CH3 OCH3
9共4,5兲⫺9共3,6兲 EA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204158.883*共8兲
CH3 OCH3
9共4,5兲⫺9共3,6兲 EE
0.50b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204160.111*共10兲
CH3 OCH3
9共4,5兲⫺9共3,6兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204246.739*共11兲
SO2
18共3,15兲⫺18共2,16兲 7共4,4兲⫺8共3,5兲 16共3,13兲⫺16共2,14兲
3.88 1.77 0.94
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m NRAO 12 m
Jew89 Jew89 Jew89
204384.197*共5兲 204525.175*共16兲
34
SO2
SO2 34
SO2
204552.039*共10兲
CH3 OCH3
8共4,4兲⫺8共3,5兲 EE
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204552.507*共20兲
CH3 OCH3
8共4,4兲⫺8共3,5兲 EA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204552.601*共6兲
CH3 OCH3
11共4,8兲⫺11共3,9兲 EE
0.81b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
254
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Formula
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
204553.012*共10兲
CH3 OCH3
8共4,4兲⫺共83,5兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204628.452*共12兲
CH3 OCH3
10共4,7兲⫺10共3,8兲 EA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204630.869*共6兲
CH3 OCH3
10共4,7兲⫺10共3,8兲 AE
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204633.802*共6兲
CH3 OCH3
10共4,7兲⫺10共3,8兲 EE
1.03b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204638.018*共8兲
CH3 OCH3
10共4,7兲⫺10共3,8兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204707. 204736.683*共8兲
unidentified CH3 OCH3
共U201323.兲 9共4,6兲⫺9共3,7兲 EE
0.19 0.33b
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
Gro98
204741.805*共10兲
CH3 OCH3
9共4,6兲⫺9共3,7兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204758.613*共4兲
CH3 OCH3
14共4,11兲⫺14共3,12兲 EE
0.43b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204761.721*共8兲
CH3 OCH3
14共4,11兲⫺14共3,12兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204933.013*共10兲
CH3 OCH3
7共4,4兲⫺7共3,5兲 EE
0.62b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204933.087*共10兲
CH3 OCH3
7共4,4兲⫺7共3,5兲 AE
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204960.964*共10兲
CH3 OCH3
6共4,2兲⫺6共3,3兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204961.081*共20兲
CH3 OCH3
6共4,2兲⫺6共3,3兲 EA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
204961.331*共12兲
CH3 OCH3
6共4,2兲⫺6共3,3兲 EE
0.73b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
205018.110*共4兲 205045.498*共2兲 205048.150*共16兲
CH3 CCH CH3 CCH CH3 OCH3
12共4兲⫺11共4兲 12共3兲⫺11共3兲 5共4,1兲⫺5共3,2兲 EA
0.69 0.67 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m NRAO 12 m
Jew89 Jew89 Jew89
Gro98
205050.228*共10兲
CH3 OCH3
5共4,1兲⫺5共3,2兲 EE
1.54b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
205050.504*共12兲
CH3 OCH3
5共4,1兲⫺5共3,2兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
205060.792*共10兲
CH3 OCH3
5共4,2兲⫺5共3,3兲 AE
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
205061.068*共10兲
CH3 OCH3
5共4,2兲⫺5共3,3兲 EE
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
205065.068*共1兲
12共2兲⫺11共2兲 12共1兲⫺11共1兲
0.87
205076.814*共1兲
CH3 CCH CH3 CCH
0.91b
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
205080.729*共1兲
CH3 CCH
12共0兲⫺11共0兲
b
OriMC⫺1
NRAO 12 m
Jew89
205095.818*共10兲
CH3 OCH3
4共4,0兲⫺4共3,1兲 EE
0.60b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
205096.790*共10兲
CH3 OCH3
4共4,1兲⫺4共3,2兲 EE
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
205118.265*共4兲
CH3 OCH3 CH3 CH2 CN
15共4,12兲⫺15共3,13兲 EE 23共5,18兲⫺23共4,19兲 3共1,2兲⫺2共1,2兲
0.61 0.07 3.00
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m FCRAO 14 m
Jew89 Tur85 Eri84c
Gro98
4共5兲⫺3共4兲 5共0兲⫺4共0兲 e1
9.00 0.09
OriMC⫺1 IRAS16293⫺2422
FCRAO 14 m IRAM 30 m
Eri84c Par02
Par02
2共1,2兲⫺3共0,3兲 e0 5共2⫺兲⫺4共2⫺兲 e1 5共4⫺兲⫺4共4⫺兲 e1 5共3⫺兲⫺4共3⫺兲 e1
0.11 0.07 0.07
IRAS16293⫺2422 IRAS16293⫺2422 IRAS16293⫺2422 IRAS16293⫺2422
Par02 Par02 Par02 Par02
Par02 Par02 Par02 Par02
5共3⫹兲⫺4共3⫹兲 e1
0.05b 0.018
205736.535*共13兲 206131.625*共5兲
207827. 207864. 207868.
H2 13CO SO CHD2 OH CH2 DOH CHD2 OH CHD2 OH CHD2 OH
207869.
CHD2 OH
206176.062*共15兲 207771. 207780.8
208590.021*共30兲 208700.323*共6兲 208965.425*共30兲 209230.201*共6兲 211013.036*共14兲 211077.90* 共25兲 211211.448*共10兲 211803.245*共98兲 211853.17* 共11兲
U
Quantum numbers
SO⫹ SO2
2⌸
SO⫹
2⌸
212582.51* 共13兲 213068.415*共18兲 213159.369*共47兲
SiO SiO SO2 CH3 OH
213293.580*共13兲
H2 13CO
213360.659*共24兲
HCS⫹ unidentified CH3 OH CH3 OH
213376. 213377.521*共27兲 213427.118*共7兲 213553.060*共6兲 214088.56* 共12兲
OC34S SiO
IRAS16293⫺2422
IRAM 30 m
Par02
Par02
IC443G
NRAO 12 m
Tur92a
Ama91
MMWO 4.9 m
Lor84a
IC443G
NRAO 12 m
Tur92a
0.7 0.45
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor81 Tha84a
5⫺4 v⫽4 3共1,3兲⫺2共1,2兲 16共2,15兲⫺15共1,14兲A⫺ 5⫺4 v⫽0
0.7 1.9 0.6 4.0
VY CMa rho Oph B OriMC⫺1 VY CMa
IRAM 30 m MMWO 4.9 m OVRO 10.4 m IRAM 30 m
Cer93 Lor83 Sut85 Cer92
5⫺4 v⫽3 26共3,23兲⫺26共2,24兲
0.5 0.15
VY CMa IRAS16293⫺2422
IRAM 30 m JCMT 15 m
Cer93 Bla94
0.5 ⬍0.5
OriMC⫺1 OriMC⫺1
OVRO 10.4 m BTL 7 m
Sut85 Tha81
Xu_97
5⫺4
0.6
OriMC⫺1
BTL7 m
Tha81
Bog84
13共6,8兲⫺14共5,10兲 E 1共1,0兲⫺0共0,0兲 E 18⫺17
0.7 0.6 5.4 0.15
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRAS16293⫺2422
BTL7 m OVRO 10.4 m OVRO 10.4 m JCMT 15 m
Tha81 Sut85 Sut85 Bla94
Xu_97 Xu_97
34
30
m m m m
rho Oph A
J⫽9/2⫺7/2 f 23⫺22 5共5兲⫺4共4兲
1/2
20共⫺4,17兲⫺19共⫺5,14兲 E 3共2,1兲⫺2共2,0兲
0.5
30 30 30 30
0.012
HCCCN SO SiO H2 CO CH3 OH
J⫽9/2⫺7/2 e 3共2,2兲⫺2共1,1兲 1/2
b
IRAM IRAM IRAM IRAM
VXSgr
MMWO 4.9 m
Cle83
214229.414*共27兲
13
12共5兲⫺11共0兲
2.0f
G10.47
IRAM 30 m
Olm96
214309.889*共21兲
13
12共4兲⫺11共0兲
5.7f
G10.47
IRAM 30 m
Olm96
214338.081*共21兲
13
12共3兲⫺11共0兲
9.7f
G10.47
IRAM 30 m
Olm96
7共8兲⫺7共7兲 12共2兲⫺11共0兲
0.24
IRAS16293⫺2422 G10.47
JCMT 15 m IRAM 30 m
Bla94 Olm96
CH3 CN CH3 CN CH3 CN
214357.051*共64兲 214358.226*共22兲
13
214370.317*共22兲
13
214374.347*共23兲
13
214385.62*共11兲 214509.66* 共16兲
SO CH3 CN
5⫺4 v⫽2
110.e
b
CH3 CN
12共1兲⫺11共0兲
6.7f
G10.47
IRAM 30m
Olm96
CH3 CN
12共0兲⫺11共0兲
6.6f
G10.47
IRAM 30 m
Olm96
5⫺4 v⫽0
4.0
VY CMa
IRAM 30 m
Cer92
9共1,8兲⫺8共1,7兲
0.7f
IRC⫹10216
IRAM 30 m
Cer91b
29
SiO
Si13CC
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Ama91
Xu_97
MICROWAVE TRANSITIONS
255
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
214574.084*共8兲
13C17O
2⫺1
0.055
rho Oph C
SEST 15 m
Ben01
214778.432*共8兲
H2 C18O CH3 OCHO HNCO
3共1,2兲⫺2共1,1兲
0.19
OriMC⫺1
MMWO 4.9 m
Man90
18共3,16兲⫺17共3,15兲 E 47共0,47兲⫺46共1,46兲
0.10
OMC⫺IRc2 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Man90 Man90
Oes99 Hoc75
214792.534*共20兲
CH3 OCHO
18共3,16⫺17共3,15兲 A
0.20b
OriMC⫺1
MMWO 4.9 m
Man90
Oes99
215039.727*共9兲
24共9,*兲⫺23共9,*兲 24共10,*兲⫺23共10,*兲
1.1
215041.902*共9兲
CH3 CH2 CN CH3 CH2 CN
b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
215058.027*共9兲
CH3 CH2 CN
24共3,22兲⫺23共3,21兲
1.4b
OriMC⫺1
OVRO 10.4 m
Sut85
215058.588*共9兲
CH3 CH2 CN
24共8,*兲⫺23共8,*兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
215059.236*共10兲
CH3 CH2 CN
24共11,*兲⫺23共11,*兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
215088.240*共11兲 215109.062*共20兲
24共12,*兲⫺23共12,*兲
0.6
OriMC⫺1
OVRO 10.4 m
Sut85
215119.223*共10兲 215126.724*共11兲 215173.254*共12兲 215211.533*共9兲
CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN
24共7,*兲⫺23共7,*兲 25共0,25兲⫺24共0.24兲 24共13,*兲⫺23共13,*兲 24共14,*兲⫺23共14,*兲 24共6,19兲⫺23共6,18兲
1.2 1.1 0.5 0.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4m OVRO 10.4m
Sut85 Sut85 Sut85 Sut85 Sut85
215212.474*共9兲
CH3 CH2 CN
24共6,18兲⫺23共6,17兲
OriMC⫺1
OVRO 10.4m
Sut85
215220.708*共11兲 215247.2*共18兲
SO
5共5兲⫺4共4兲 9共2,7兲⫺8共2,6兲
3.0 0.069
OriMC⫺1 IRC⫹10216
MMWO 4.9 m IRAM 30 m
Cle84 Ziu02
6共1,6兲⫺7共2,5兲 A⫹ vt ⫽1 18⫺17 24共5,20兲⫺23共5,19兲 10共0,10兲⫺9共0,9兲
1.3 0.006 0.8 0.068
OriMC⫺1 IRC⫹10216 OriMC⫺1 IRC⫹10216
OVRO 10.4 m IRAM 30 m OVRO 10.4 m IRAM 30 m
Sut85 Ziu02 Sut85 Ziu02
214782.311*共17兲 214790.761 共18兲
30
SiC2
215302.205*共25兲 215357.918*共8兲 215400.819*共9兲 215418.9*共75兲
CH3 OH AlNC CH3 CH2 CN
215427.984*共9兲 215596.05* 共10兲
CH3 CH2 CN SiO
24共5,19兲⫺23共5,18兲 5⫺4 v⫽1
215620.199*共9兲 215839.917*共24兲
CH3 CH2 CN
24共4,21兲⫺23共4,20兲 6共5兲⫺5共4兲
215886.979*共22兲
13 CH3 OH CH3 CH2 CN
215965.591*共11兲 215999.724*共14兲
30
SiC2
34
SO
34
SO2
216077.207*共9兲 216109.716*共17兲
CH3 CH2 CN CH3 OCHO
216112.628*共29兲 216115.541*共20兲 216210.844*共17兲 216216.510*共20兲 216278.749*共9兲 U U
Formula
216325.0 216345.0 216360.002*共20兲 216373.32共2兲 216373.32共2兲
b
b b
1.0
OriMC⫺1
OVRO 10.4 m
Sut85
150.e 0.6 0.50
VXSgr
MMWO 4.9 m
Cle83
OriMC⫺1 OriMC⫺1
OVRO 10.4 m MMWO 4.9 m
Sut85 Sne84a
4共2,2兲⫺3共1,2兲 E
0.9
OriMC⫺1
OVRO 10.4 m
Sut85
25共1,25兲⫺24共0,24兲 14共3,11兲⫺14共2,12兲
0.3 0.7
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Xu_97
And87
24共4,20兲⫺23共4,19兲
0.7
OriMC⫺1
OVRO 10.4 m
Sut85
0.9 2.5
OriMC⫺1 ⫺Oph
OVRO 10.4 m MMWO 4.9 m
Sut85 Lor82
Oes99
DCO⫹ CH3 OCHO CH3 OCHO CH3 OCHO
19共2,18兲⫺18共2,17兲 E 3⫺2 19共2,18兲⫺18共2,17兲 A 19共1,18兲⫺18共1,17兲 E 19共1,18兲⫺18共1,17兲 A
1.1 0.8 0.9
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Oes99 Oes99 Oes99
c⫺C3 H2
3共3,0兲⫺2共2,1兲
3.4
TMC⫺1
FCRAO 14 m
Mad86a
19共2,18兲⫺18共1,17兲 A
0.08 0.20 n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m MMWO 4.9 m
Com96 Com96 Com96 Com85
Oes99 Vrt85 Vrt85
unidentified unidentified CH3 OCHO C2 D
1⫺0 J⫽7/2⫺5/2 F⫽7/2⫺5/2
b
C2 D
1⫺0 J⫽7/2⫺5/2 F⫽9/2⫺7/2
MMWO 4.9 m
Com85
216383.9 216402.3
unidentified unidentified
0.27b 0.11 0.22
OriMC⫺1
U U
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
U U
216428.8 216458.9
unidentified unidentified
n.r. 0.15
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
U U U
216501.2 216522.7 216546.4 216568.652*共15兲 216581.924*共7兲 216588.613*共43兲
unidentified unidentified unidentified H2 CO CH3 CHO CH3 OCHO
0.16 0.15 0.16 1.3 n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m OVRO 10.4 m IRAM 30 m
Com96 Com96 Com96 Sut85 Com96
216643.303*共10兲 216710.437*共2兲 216752.552*共11兲 216757.623*共14兲 216774.9 216830.151*共20兲 216838.880*共20兲 216936.68*共4兲 216945.559*共14兲 216964.763*共20兲
SO2 H2 S CH3 CH2 CN SiS unidentified CH3 OCHO CH3 OCHO CH2 CHCN CH3 OH CH3 OCHO
n.r. 0.3 0.32 0.17 0.046 n.r. 1.2 1.1 0.6 3.1
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m NRAO 12 m IRAM 30 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Com96 Lor84a Lor84a Lor84a Tur87a Com96 Sut85 Sut85 Sut85 Sut85 Sut85
Xu_97 Oes99
216965.938*共24兲
CH3 OCHO
20共1,20兲⫺19共1,19兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
216966.220*共20兲
CH3 OCHO
20共0,20兲⫺19共0,19兲 E
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
216967.392*共24兲
CH3 OCHO
20共0,20兲⫺19共0,19兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
217104.98* 共11兲 217151.3 217165.2
SiO unidentified unidentified
5⫺4 v⫽0
1.6 0.15 0.20
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m IRAM 30 m IRAM 30 m
Lor84a Com96 Com96
U
U U
9共1,8兲⫺9共1,9兲 11共1,10兲⫺10共1,9兲 E 33共9,25兲⫺33共8,26兲 A 22共2,20兲⫺22共1,21兲 2共2,0兲⫺2共1,1兲 26共1,25兲⫺25共2,24兲 12⫺11 v⫽1 18共2,16兲⫺17共2,15兲 E 18共2,16兲⫺17共2,15兲 A 23共2,22兲⫺22共2,21兲 5共1,4兲⫺4共2,2兲 E 20共1,20兲⫺19共1,19兲 E
2.0b
Oes99 Hui71
Oes99 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
256
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U U U U U
U U U U U U U
U U U U U U U U
U U U
U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
217176.599*共28兲
CH3 OCH3
36共4,32兲⫺36共3,33兲 AE⫹EA
b
OriMC⫺1
IRAM 30 m
Com96
Gro98
217177.084*共28兲
CH3 OCH3
36共4,32兲⫺36共3,33兲 EE
0.07b
OriMC⫺1
IRAM 30 m
Com96
Gro98
217177.609*共29兲
CH3 OCH3
36共4,32兲⫺36共3,33兲 AA
b
OriMC⫺1
IRAM 30 m
Com96
Gro98
217189.663*共8兲
CH3 OCH3
22共4,19兲⫺22共3,20兲 EA
b
OriMC⫺1
IRAM 30 m
Com96
Gro98
217189.664*共8兲
CH3 OCH3
22共4,19兲⫺22共3,20兲 AE
b
OriMC⫺1
IRAM 30 m
Com96
Gro98
217191.408*共6兲
CH3 OCH3
22共4,19兲⫺22共3,20兲 EE
1.16b
OriMC⫺1
IRAM 30 m
Com96
Gro98
217193.153*共8兲
CH3 OCH3
22共4,19兲⫺22共3,20兲 AA
b
OriMC⫺1
IRAM 30 m
Com96
Gro98
217209.1 217216.1 217238.539*共2兲 217262.955*共51兲 217266.473*共50兲 217278.9 217299.162*共24兲 217313.0 217338.054*共53兲 217364.0 217375.0 217391.0 217398.499*共28兲
unidentified unidentified DCN CH3 OCHO CH3 OCHO unidentified CH3 OH unidentified CH3 OCHO unidentified unidentified unidentified HC13CCN
24⫺23
0.09 n.r. 0.7 0.33 n.r. 0.07 1.2 0.69 0.04 0.12 n.r. 0.12 n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m NRAO 11 m IRAM 30 m IRAM 30 m IRAM 30 m OVRO 10.4 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m
Com96 Com96 Phi74 Com96 Com96 Com96 Sut85 Com96 Com96 Com96 Com96 Com96 Com96
217419.584*共40兲
24⫺23
n.r.
OriMC⫺1
IRAM 30 m
Com96
217429.0 217451.2 217458.5 217468.3 217497.8 217513.0 217524.9 217541.41*共7兲 217546.56*共4兲 217558.7 217568.5 217582.3 217588.3 217595.6 217609.0 217615.7 217636.4 217642.86* 共14兲
HCC13CN unidentified unidentified unidentified unidentified unidentified unidentified unidentified HCOOD HCOOD unidentified unidentified unidentified unidentified unidentified unidentified unidentified unidentified CH3 OH
0.33 0.08 0.08 0.08 0.37 0.12 0.24 n.r. n.r. 0.06 0.64 0.06 n.r. n.r. n.r. 0.22 0.27
15共6,10兲⫺16共5,11兲 A⫺⫺ vt ⫽1
1.06b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM IRAM
m m m m m m m m m m m m m m m m m m
Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96 Com96
Xu_97
217642.86* 共14兲
CH3 OH
15共6,9兲⫺16共5,12兲 A⫹⫹ vt ⫽1
b
OriMC⫺1
IRAM 30 m
Com96
Xu_97
217653.84*共8兲
CCCN
22⫺21 J⫽45/2⫺43/2
n.r.
OriMC⫺1
IRAM 30 m
Com96
217656.2 217668.7 217678.4 217689.34*共3兲
unidentified unidentified unidentified HCOOD
0.19 0.03 0.13 10共5,6兲⫺9共5,5兲
n.r.b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM IRAM IRAM IRAM
m m m m
Com96 Com96 Com96 Com96
Wil80
217689.53*共3兲
HCOOD
10共5,5兲⫺9共5,4兲
OriMC⫺1
IRAM 30 m
Com96
Wil80
SiS
n.r.b 0.66
IRC⫹10216 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Sah84 Lor84
3⫺2 37共10,27兲⫺37共9,28兲 A 30共4,26兲⫺30共3,27兲 A 6共1,5兲⫺7共2,6兲 A⫺ vt ⫽1 37共10,27兲⫺37共9,28兲 E
10共9,*兲⫺9共9,*兲 10共8,*兲⫺9共8,*兲
217817.624*共16兲 217822.045*共15兲
c⫺C3 H2
12⫺11 6共0,6兲⫺5共1,5兲
217822.168*共15兲
c⫺C3 H2
6共1,6兲⫺5共0,5兲
0.23b
30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30
30 30 30 30
Oes99 Oes99 Xu_97 Oes99
Wil80 Wil80
b
OriMC⫺1
MMWO 4.9 m
Lor84
217827.14* 共11兲
33
SO
6共5兲⫺5共4兲 F⫽9/2⫺7/2
b
OriMC⫺1
MMWO 4.9 m
Lor84
217829.806*共54兲
33
SO
6共5兲⫺5共4兲 F⫽11/2⫺9/2
b
OriMC⫺1
MMWO 4.9 m
Lor84
217831.762*共54兲
33
SO
6共5兲⫺5共4兲 F⫽13/2⫺11/2
0.15b
OriMC⫺1
MMWO 4.9 m
Lor84
217832.67* 共11兲
33
6共5兲⫺5共4兲 F⫽15/2⫺13/2 20共1,19兲⫺20共0,20兲 E
b
OriMC⫺1
MMWO 4.9 m
Lor84
b
OriMC⫺1 IRC⫹10216
OVRO 10.4 m NRAO 12 m
Sut85 Tur92
Xu_97 Tur92
217886.39* 共11兲 218006.38* 共10兲
SO CH3 OH SiN
5⫺4 J⫽9/2⫺9/2 F⫽11/2⫺9/2
218007.84* 共10兲
SiN
5⫺4 J⫽9/2⫺9/2 F⫽9/2⫺7/2
0.031b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
218009.08* 共10兲
SiN
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
218198.984*共8兲
O13CS H2 CO CH3 OCHO unidentified CH3 OCHO HCCCN
5⫺4 J⫽9/2⫺9/2 F⫽7/2⫺5/2 18⫺17
0.5
OriMC⫺1
OVRO 10.4 m
Sut85
4.0 1.0 0.08 1.2 0.9 8.8f
OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1 SgrB2共N兲
MMWO 4.9 m OVRO 10.4 m NRAO 12 m OVRO 10.4 m MMWO 4.9 m SEST 15 m
Lor84b Sut85 Tur92 Sut85 Lor81 Num98
24共3,21兲⫺23共3,20兲 23共7,*兲⫺22共7,*兲
0.8
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
218222.186*共10兲 218280.830*共20兲 218289. 218297.866*共21兲 218324.712*共7兲 218337.2*共10兲 218390.017*共10兲
3共0,3兲⫺2共0,2兲 17共3,14兲⫺16共3,13兲 E 17共3,14兲⫺16共3,13兲 A 24⫺23 24⫺23 v5 ⫽1 ᐉ⫽1 e
0.9
218398.50*共9兲
HCCCN CH3 CH2 CN CH2 CHCN
b
OriMC⫺1 OriMC⫺1
218402.40*共7兲
CH2 CHCN
23共6,*兲⫺22共6,*兲
0.4b
OriMC⫺1
OVRO 10.4 m
Sut85
218421.73* 共11兲
CH2 CHCN
23共8,*兲⫺22共8,*兲
0.3
OriMC⫺1
OVRO 10.4 m
Sut85
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Oes99 Oes99 Laf78
MICROWAVE TRANSITIONS
257
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
218440.050*共15兲 218451.25*共6兲
CH3 OH CH2 CHCN
4共2,2兲⫺3共1,2兲 E 23共5,19兲⫺22共5,18兲
218452.31*共6兲
CH2 CHCN
218459.203*共5兲
NH2 CHO
218475.637*共10兲 218489.428*共10兲
H2 CO CH3 OCH3
3共2,2兲⫺2共2,1兲 23共3,21兲⫺23共2,22兲 AE⫹EA
218491.919*共8兲
CH3 OCH3
23共3,21兲⫺23兲2,22兲 EE
218494.410*共12兲
CH3 OCH3
23共3,21兲⫺23共2,22兲 AA
218507.1共10兲
U
Lab. Ref.
OriMC⫺1 OriMC⫺1
MMWO 4.9 m OVRO 10.4 m
Lor84b Sut85
Xu_97
0.2b
23共5,18兲⫺22共5,17兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
10共1,9兲⫺9共1,8兲
19.4f 1.8
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84b Num98
SgrB2共N兲
SEST15 m
Num98
Gro98
Sgr B2共N兲
SEST 15 m
Num98
Gro98
9共2,7兲⫺8共2,6兲 5⫺4 J⫽11/2⫺9/2 F⫽13/2⫺11/2
218513.14* 共10兲
SiN
5⫺4 J⫽11/2⫺9/2 F⫽11/2⫺9/2
218513.89* 共10兲
SiN
218520.025*共4兲
CH2 CHCN
5⫺4 J⫽11/2⫺9/2 F⫽9/2⫺7/2 23共10,*兲⫺22共10,*兲
218554.382*共24兲
t⫺CH3 CH2 OH CH2 CHCN CH2 CHCN CH2 CHCN
21共5,16兲⫺21共4,17兲
218573.60*共5兲 218585.03*共5兲 218588.132*共5兲 218615.05*共5兲
CH2 CHCN
23共4,19兲⫺22共4,18兲 7共2,5兲⫺6共1,6兲
23共4,20兲⫺22共4,19兲 23共3,21兲⫺22共3,20兲 23共11,*兲⫺22共11,*兲
1.7
b
11.2fb b
Gro98
n.r.
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
0.018b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
10.2f
SgrB2共N兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
2.8f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
4.8f 0.3 0.3 b
0.2
218666.578*共6兲
t⫺CH3 CH2 OH CH2 CHCN
23共12,*兲⫺22共12,*兲
6.1f
SgrB2共N兲
SEST 15 m
Num98
218683.90*共55兲
HCCCN
24⫺23 v6 ⫽1 ᐉ⫽1 e
11.7f
SgrB2共N兲
SEST15 m
Num98
218719.83*共9兲
CH2 CHCN
23共8,*兲⫺22共8,*兲 v15 ⫽1
3.0f
SgrB2共N兲
SEST15 m
Num98
218732.679*共10兲
c⫺C3 H2
7共1,6兲⫺7共0,7兲
5.4fb
SgrB2共N兲
SEST15 m
Num98
218732.762*共10兲
c⫺C3 H2 H2 CO CH2 CHCN
7共2,6兲⫺7共1,7兲
b
Sgr B2共N兲
SEST 15 m
Num98
3共2,1兲⫺2共2,0兲 23共10,*兲⫺22共10,*兲 v15 ⫽1
1.5
OriMC⫺1 SgrB2共N兲
MMWO 4.9 m SEST 15 m
Lor84a Num98
218853.91* 共63兲
C4 H HCCCN
47/2⫺45/2 24⫺23 v6 ⫽1 ᐉ⫽1 f
IRC⫹10216 SgrB2共N兲
MMWO 4.9 m SEST 15 m
Lor84a Num98
218860.629*共58兲 218875.36*共6兲 218903.353*共1兲 218981.019*共12兲 219002.
HCCCN C4 H OCS HNCO unidentified
24⫺23 v7 ⫽1 ᐉ⫽1 e 45/2⫺43/2 18⫺17 10共1,10兲⫺9共1,9兲
12.8f 0.6 0.06 2.8 0.24 0.1u
OriMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m MMWO 4.9 m BTL 7 m MMWO 4.9 m MMWO 4.9 m
Sut85 Lor84a Gol81 Arm84a Arm84a
219027.097*共16兲
CH2 CHCN
23共7,*兲⫺22共7,*兲 v11 ⫽1
7.4f
SgrB2共N兲
SEST15 m
Num98
219039.405*共15兲
CH2 CHCN
23共6,18兲⫺22共6,17兲 v11 ⫽1
9.7fb
SgrB2共N兲
SEST15 m
Num98
219039.425*共15兲
CH2 CHCN
23共6,17兲⫺22共6,16兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
219042.615*共17兲
CH2 CHCN
23共8,*兲⫺22共8,*兲 v11 ⫽1
219068.22*共5兲
CH2 CHCN
23共16,*兲⫺22共16,*兲
218837.00*共6兲
U
Astr. Ref.
SiN
218760.066*共10兲 218830.76* 共12兲
U
SiC2
Telescope
218511.98* 共10兲
218654.008*共32兲
U
29
Source
6.2f 0.06
b
Sgr B2共N兲
SEST 15 m
Num98
4.4f
SgrB2共N兲
SEST 15 m
Num98
Laf78
Laf78 Laf78
219077.008*共18兲
CH2 CHCN
23共9,*兲⫺22共9,*兲 v11 ⫽1
4.6f
SgrB2共N兲
SEST 15 m
Num98
219085.43*共16兲
CH2 CHCN
23共13,*兲⫺22共13,*兲 v15 ⫽1
5.4f
SgrB2共N兲
SEST 15 m
Num98
219098.502*共15兲
CH2 CHCN
23共5,*兲⫺22共5,*兲 v11 ⫽1
8.0f
SgrB2共N兲
SEST 15 m
Num98
219125.675*共21兲
CH2 CHCN
23共10,*兲⫺22共10,*兲 v11 ⫽1
11.4f
SgrB2共N兲
SEST 15 m
Num98
219125.675*共21兲
CH2 CHCN
23共10,*兲⫺22共10,*兲 v11 ⫽1
11.4f
SgrB2共N兲
SEST 15 m
Num98
219151.5*共5兲
CH3 NH2
8共⫺2兲⫺8共1兲 Ea
6.5f
SgrB2共N兲
SEST 15 m
Num98
Num98
219173.582*共58兲
HCCCN
24⫺23 v7 ⫽1 ᐉ⫽1 f
0.6
OVRO 10.4 m SEST 15 m
Sut85 Num98
Laf78
18.4f
OriMC⫺1 SgrB2共N兲
12.4fb
Num98
219216.
unidentified
219233.341*共15兲
CH2 CHCN
23共4,20兲⫺22共4,19兲 v11 ⫽1
Sgr B2共N兲
SEST 15 m
219237.251*共15兲
CH2 CHCN
23共3,21兲⫺22共3,20兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
219256.582*共31兲
CH2 CHCN
23共12,*兲⫺22共12,*兲 v11 ⫽1
SgrB2共N兲
SEST 15 m
Num98
219275.939*共7兲 219275.939*共7兲
SO2 SO2
22共7,15兲⫺23共6,16兲 22共7,15兲⫺23共6,18兲
13.5f 0.3 21.8f
OriMC⫺1 SgrB2共M兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
219318.
unidentified
219336.331*共41兲
CH2 CHCN
219346.
unidentified
219355.001*共11兲 219400.54*共5兲 219407.69*共6兲
34
SO2 CH2 CHCN
26.0f
SgrB2共N兲
SEST 15 m
Num98
23共13,*兲⫺22共13,*兲 v11 ⫽1
3.9f
SgrB2共N兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
11共1,11兲⫺10共0,10兲
4.5f 1.3
OriMC⫺1
OVRO 10.4 m
Sut85
23共3,20兲⫺22共3,19兲
0.3
OriMC⫺1
OVRO 10.4 m
Sut85
CH3 18OH CH2 CHCN
4共2,2兲⫺3共1,2兲 E
11.3f
SgrB2共N兲
SEST 15 m
Num98
23共14,*兲⫺22共14,*兲 v11 ⫽1
3.8f
SgrB2共N兲
SEST 15 m
Num98
219441.599共20兲
NH2 CN
11共2,10兲⫺10共2,9兲 v⫽1
8.0f
SgrB2共N兲
SEST 15 m
Num98
219463.641*共15兲
CH3 CH2 CN
0.3
OriMC⫺1 SgrB2共M兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
219424.659*共54兲
219465.555*共19兲
SO2
22共2,21兲⫺21共1,20兲 22共2,20兲⫺22共1,21兲 v2 ⫽1
219505.595*共10兲 219513.274*共21兲
CH3 CH2 CN
24共2,22兲⫺23共2,21兲
c⫺C2 H4 O
6共3,4兲⫺5共2,3兲
10.4f 0.9
OriMC⫺1
OVRO 10.4 m
Sut85
0.38
Sgr B2共N兲
SEST 15 m
Dic97
219547.105*共11兲
HNCO
10共4,6兲⫺9共4,5兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
219547.105*共11兲
HNCO
10共4,7兲⫺9共4,6兲
0.4b
OriMC⫺1
OVRO 10.4 m
Sut85
Hos96
JPL01
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
258
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 219560.353*共4兲 219656.805*共11兲
U
2⫺1
3.5
DR21
NRAO 11 m
Phi77
10共3,7兲⫺9共3,6兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
Telescope
Lab. Ref.
HNCO
10共3,8兲⫺9共3,7兲
0.4b
OriMC⫺1
OVRO 10.4 m
Sut85
24⫺23 v7 ⫽2 ᐉ⫽0
22.9f
SgrB2共N兲
SEST 15 m
Num98
219706.89*共10兲
HCCCN
24⫺23 v7 ⫽2 ᐉ⫽2 e
SgrB2共N兲
SEST 15 m
Num98
Laf78
219709.2共10兲
C15N
2⫺1 J⫽3/2⫺1/2 F⫽1⫺0
20.0f 0.10
OriMC⫺1
KOSMA 3 m
Sal94a
Sal94a
219722.5共10兲
C15N HNCO HNCO unidentified HNCO CH3 CHO
2⫺1 J⫽3/2⫺1/2 F⫽2⫺1 10共2,9兲⫺9共2,8兲 10共2,8兲⫺9共2,7兲
13
3共1,2兲⫺2共1,1兲
3.3f 0.5
219934.04共10兲
C15N
2⫺1 J⫽5/2⫺3/2 F⫽2⫺1
219934.82共10兲
C15N
2⫺1 J⫽5/2⫺3/2 F⫽3⫺2 6共5兲⫺5共4兲 10共0,10兲⫺9共0,9兲 8共0,8兲⫺7共1,6兲E 16共3,13兲⫺16共2,14兲 v2 ⫽1
10.4f
219733.824*共11兲 219737.175*共13兲 219767.8 219798.282*共8兲 219820.392*共14兲
H2
10共0,10兲⫺9共0,9兲 4共⫺2,3兲⫺3共⫺1,3兲 E
CO
OriMC⫺1
KOSMA 3m
Sal94a
Sal94a
0.6 0.8 0.15 0.3
OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m NRAO 12 m MMWO 4.9 m SEST 15 m
Sut85 Sut85 Tur87a Arm84 Num98
Kle96
OriMC⫺1
MMWO 4.9 m
Arm84a
0.50
OriMC⫺1
KOSMA 3 m
Sal94a
Sal94a
0.60
OriMC⫺1
KOSMA 3 m
Sal94a
Sal94a
4.3 0.3 6.1
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲
MMWO 4.9 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Lor84a Sut85 Sut85 Num98
Wil80 Xu_97
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Sut85 Num98
SgrB2共N兲 OriMC⫺1
SEST 15 m NRAO 11 m
Num98 Phi77
OriMC⫺1 G10.47
OVRO 10.4 m IRAM 30 m
Sut85 Olm96
OriMC⫺1 OriMC⫺1 G10.47
MMWO 4.9 m OVRO 10.4 m IRAM30 m
Lor84 Sut85 Olm96
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m OVRO 10.4 m
Lor84 Lor84 Sut85 Num98
SO HCOOH CH3 OH SO2
220166.809*共20兲 220177.416*共75兲 220190.268*共21兲 220200.
CH3 OCHO CH2 CO CH3 OCHO unidentified
17共4,13兲⫺16共4,12兲 E 11共1,11兲⫺10共1,10兲 17共4,13兲⫺16共4,12兲 A
1.3 1.0 1.3
220323.645*共14兲
CH3 CN
12共10兲⫺11共10兲 2⫺1
13.9f 4.7f 17.
220561.33*共7兲 220570.379*共10兲 220584.762*共12兲 220594.438*共5兲 220599.987*共8兲
13
CO CH3 CN CH3 13CN CH3 CN CH2 CHCN CH3 13CN HNCO CH3 CN CH3
12共8兲⫺11共8兲
0.5
12共5兲⫺11共5兲
4.5f 0.10 0.4
12共7兲⫺11共7兲 24共1,24兲⫺23共1,23兲 12共4兲⫺11共4兲 10共1,9兲⫺9共1,8兲 12共6兲⫺11共6兲 12共3兲⫺11共3兲
13
CN
Laf78
0.15
219949.433*共17兲 220037.96*共1兲 220078.490*共13兲 220165.239*共17兲
220539.340*共6兲
7.1f 0.13 0.23 b
Oes99 Oes99
220601.941*共16兲
t⫺CH3 CH2 OH
13共1,13兲⫺12共0,12兲
10.8f
SgrB2共N兲
SEST 15 m
220621.143*共8兲
CH3 13CN
12共2兲⫺11共2兲
0.5
OriMC⫺1
OVRO 10.4 m
Sut85
220633.841*共9兲
CH3 13CN
12共1兲⫺11共1兲
0.5b
OriMC⫺1
OVRO 10.4 m
Sut85
220638.074*共10兲
CH3 13CN CH3 CN CH3 CH2 CN unidentified CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN
12共0兲⫺11共0兲
G10.47
IRAM 30 m
Olm96
12共4兲⫺11共4兲 12共3兲⫺11共3兲 12共2兲⫺11共2兲
3.3f 0.29 0.7 0.14 0.37 0.80 0.67
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m OVRO 10.4 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Lor84 Sut85 Lor84 Lor84 Lor84 Lor84
12共1兲⫺11共1兲 12共0兲⫺11共0兲 10共0,10兲⫺9共0,9兲
0.84 0.99 0.87
MMWO 4.9 m MMWO 4.9 m JCMT 15 m MMWO 4.9 m
Lor84 Lor84 Bel93b Lor84
18共3,16兲⫺17共2,15兲 E
0.17u 0.4
OriMC⫺1 OriMC⫺1 IRC⫹10216 OriMC⫺1 OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Num98
Num98
220641.096*共4兲 220660.918*共10兲 220664.5 220679.297*共3兲 220709.024*共3兲 220730.266*共3兲 220743.015*共3兲 220747.265*共3兲 220773.699 共77兲 220792.5
12共5兲⫺11共5兲 25共2,24兲⫺24共2,23兲
SiC2 unidentified
220826.8*共5兲
CH3 OCHO CH3 OCHO CH3 NH2
220811.828*共21兲 220815.204*共24兲 U
C18O HNCO
Source
HCCCN
220475.824*共8兲 220532.333*共15兲
U
T r 共K兲/T a 共K兲
219674.65* 共13兲
220398.681*共3兲
U
Quantum numbers
219656.805*共11兲
219908.487*共5兲
U
Astr. Ref.
Formula
18共3,16兲⫺17共2,15兲 A 7共0兲⫺6共1兲Aa⫹⫹
0.4 5.7f
220827.
unidentified
1.6f
SgrB2共M兲
SEST 15 m
220846.585*共16兲
CH3 OCH3
24共4,20兲⫺23共5,19兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
220847.666*共12兲
CH3 OCH3
24共4,20兲⫺23共5,19兲 EE
4.0fb
SgrB2共N兲
SEST 15 m
Num98
Gro98
220848.745*共14兲
CH3 OCH3
24共4,20兲⫺23共5,19兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
220848.749*共14兲
CH3 OCH3
24共4,20兲⫺23共5,19兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
220865.47* 共29兲
CH3 CHO
19共2,18兲⫺19共1,19兲 A⫺⫹ vt ⫽1
3.6f
SgrB2共N兲
SEST 15 m
Num98
Kle96
220888.8*共5兲
CH3 NH2
9共2兲⫺9共1兲 Es
SgrB2共N兲
SEST 15 m
Num98
Num98
CH3 OCHO CH3 OCH3
18共17,*兲⫺17共17,*兲 A 24共4,20兲⫺23共3,21兲 AE⫹EA
3.1fb 0.4
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Gro98
220889.185*共42兲 220891.832*共10兲
b
220893.415*共8兲
CH3 OCH3
24共4,20兲⫺23共3,21兲 EE
3.1fb
SgrB2共N兲
SEST 15 m
Num98
Gro98
220894.997*共12兲
CH3 OCH3
24共4,20兲⫺23共3,21兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
220926.353*共35兲 220961.583*共4兲
CH3 OCHO CH3 CH2 CN
18共16,*兲⫺17共16,*兲 A 46共6,40兲⫺46共5,41兲
0.5 3.3f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 JPL01
220977.949*共32兲 220983.607*共37兲
CH3 OCHO CH3 OCHO
18共15,*兲⫺17共15,*兲 A 18共15,3兲⫺17共15,2兲 E
5.9f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Oes99
220998.296*共35兲
CH3 OCHO
18共15,4兲⫺17共15,3兲 E
5.8f
SgrB2共N兲
SEST 15 m
Num98
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
0.5
MICROWAVE TRANSITIONS
259
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
221005.221*共16兲
CH2 CHCNr
24共1,24兲⫺23共1,23兲 v11 ⫽1
221047.747*共29兲 221049.884*共34兲
CH3 OCHO CH3 OCHO
18共14,*兲⫺17共14,*兲 A 18共14,4兲⫺17共14,3兲 E
5.8f 0.5
221059.81* 共10兲
CH3 CN
12共8兲⫺11共8兲 v8 ⫽1 ᐉ⫽⫺1
221066.878*共32兲 221086.094*共34兲
CH3 OCHO CH3 OCHO
18共14,5兲⫺17共14,4兲 E 29共9,21兲⫺29共8,21兲 E
221114.910*共16兲 221123.82*共4兲 221131.924*共91兲
34
SO2
CH2 CHCN CH3 CN
22共2,20兲⫺22共1,21兲 23共1,22兲⫺22共1,21兲 12共7兲⫺11共7兲 v8 ⫽1 ᐉ⫽⫺1
221139.628*共32兲
CH3 OCHO
18共13,5兲⫺17共13,4兲 E
221141.071*共28兲 221158.472*共28兲 221196.447*共51兲
CH3 OCHO CH3 OCHO CH3 CN
18共13,*兲⫺17共13,*兲 A 18共13,6兲⫺17共13,5兲 E 12共6兲⫺11共6兲 v8 ⫽1 ᐉ⫽⫺1
221198.962*共90兲
CH3 CN CH3 CN
12共1兲⫺11共1兲 v8 ⫽1 ᐉ⫽1 12共8兲⫺11共8兲 v8 ⫽1 ᐉ⫽⫹1
221209.973*共90兲
7.2f 0.3 5.3f
Astr. Ref.
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Lab. Ref. Oes99 Oes99
Oes99 Oes99
SgrB2共M兲
SEST 15 m
Num98
6.3f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
0.7 0.2
OriMC⫺1 OriMC⫺1 G10.47
OVRO 10.4 m OVRO 10.4 m IRAM 30 m
Sut85 Sut85 Olm96
Oes99 Oes99 Bou80
OriMC⫺1 G10.47
OVRO 10.4 m IRAM 30 m
Sut85 Olm96
Bou80 Bou80
13.3f 0.4
3.0f 0.7 3.6f
CH2 CN
11共0,11兲⫺10共0,10兲 25/2⫺23/2
6.4f
SgrB2共N兲
SEST 15 m
Num98
Num98
12共5兲⫺11共5兲 v8 ⫽1 ᐉ⫽⫺1 14共3,11兲⫺14共2,12兲
0.3
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Bou80
221255.248*共4兲
CH3 CN CH2 CHCN
221260.630*共28兲 221265.127*共81兲
CH3 OCHO CH3 CN
18共12,6兲⫺17共12,5兲 E 12共7兲⫺11共7兲 v8 ⫽1 ᐉ⫽⫹1
OriMC⫺1 G10.47
OVRO 10.4 m IRAM 30 m
Sut85 Olm96
Oes99 Bou80
221265.636*共25兲
CH3 OCHO CH3 OCHO
18共12,*兲⫺17共12,*兲 A 18共12,7兲⫺17共12,6兲 E 8共⫺1,8兲⫺7共0,7兲 E
OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
Oes99 Oes99 Xu_97
OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
Bou80 Bou80
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Bou80 Bou80
SEST 15 m
221241.5 221252.388*共83兲
221280.834*共24兲 221285.265*共20兲
13
CH3 OH
221311.925*共78兲 221312.635*共8兲
CH3 CN CH3 CN NH2 CHO
12共4兲⫺11共4兲 v8 ⫽1 ᐉ⫽⫺1 12共6兲⫺11共6兲 v8 ⫽1 ᐉ⫽1 12共0,12兲⫺11共1,11兲
221338.038*共90兲 221350.329*共81兲 221361.161 共20兲
CH3 CN CH3 CN NH2 CN
12共3兲⫺11共3兲 v8 ⫽1 ᐉ⫽⫺1 12共5兲⫺11共5兲 v8 ⫽1 ᐉ⫽1
221367.512*共90兲 221380.61* 共10兲 221387.33* 共10兲 221394.13* 共15兲 221403.51* 共11兲
12共2兲⫺11共2兲 v8 ⫽1 ᐉ⫽⫺1 12共4兲⫺11共4兲 v8 ⫽1 ᐉ⫽1 12共1兲⫺11共1兲 v8 ⫽1 ᐉ⫽⫺1 12共0兲⫺11共0兲 v8 ⫽1 ᐉ⫽1
221422.34* 共16兲
CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 OCHO CH3 OCHO CH3 OCHO unidentified
18共11,7兲⫺17共11,6兲 E 18共11,*兲⫺17共11,*兲 A 18共11,8兲⫺17共11,7兲 E
U
221424.503*共25兲 221432.987*共24兲 221445.561*共21兲 221480.
U
221524.
unidentified
221299.576*共80兲
11共1,10兲⫺10共1,9兲
12共3兲⫺11共3兲 v8 ⫽1 ᐉ⫽1 12共2兲⫺11共2兲 v8 ⫽1 ᐉ⫽1
9.2f 0.4 11.0f 0.6 0.4 15.6f 0.2 0.2 4.7f 0.3 0.2 7.1f 0.6 0.6 0.4 0.5 0.3 0.3b 0.8 0.9 0.6
Num98
JPL01
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
SgrB2共N兲
OVRO OVRO OVRO OVRO
m m m m
Sut85 Sut85 Sut85 Sut85
Bou80 Bou80 Bou80 Bou80
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Bou80 Bou80
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Oes99 Oes99 Oes99
10.4 10.4 10.4 10.4
2.1f
SgrB2共N兲
SEST 15 m
Num98
1.3f
SgrB2共NW兲
SEST 15 m
Num98
221527.464共50兲
CH3 NH2
5共0兲⫺4共0兲 Es
b
Sgr B2共N兲
SEST 15 m
Num98
221530.527 共50兲
CH3 NH2
5共0兲⫺4共0兲 Aa⫹⫹
b
Sgr B2共N兲
SEST 15 m
Num98
Kre92
221530.527 共50兲
CH3 NH2
5共0兲⫺4共0兲 Ea
3.7fb
SgrB2共N兲
SEST 15 m
Num98
Kre92
CH3 NH2
5共0兲⫺4共0兲 As⫹⫹
b
Sgr B2共N兲
SEST 15 m
Num98
Kre92
1.8f
SgrB2共M兲
SEST 15 m
Num98
221536.284 共50兲 U
b
Telescope
Source
221546.
unidentified
Kre92
NH2 CHO
9共4,5兲⫺10共3,8兲
3.0f
SgrB2共N兲
SEST 15 m
Num98
221649.273*共24兲 221660.460*共17兲
CH3 CN CH3 OCHO CH3 OCHO
12共1兲⫺11共1兲 v8 ⫽1 ᐉ⫽1 18共10,8兲⫺17共10,7兲 E 18共4,15兲⫺17共4,14兲 E
0.4 0.5 1.5b
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Bou80 Oes99 Oes99
221661.093*共21兲
CH3 OCHO
18共10,*兲⫺17共10,*兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
221670.675*共21兲 221674.675*共20兲 221693.027*共25兲
CH3 OCHO CH3 OCHO CH3 OCHO
18共10,9兲⫺17共10,8兲 E 18共4,15兲⫺17共4,14兲 A 10共4,6兲⫺9共3,7兲 E
0.4 0.8 3.1f
OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
Oes99 Oes99 Oes99
221717.5*共5兲
CH3 NH2
5共2兲⫺4共2兲 Es
b
Sgr B2共N兲
SEST 15 m
Num98
Num98
221718.076*共8兲
NH2 CHO
9共2,8兲⫺9共1,9兲
3.2f
SgrB2共N兲
SEST 15 m
Num98
221722.3*共5兲
CH3 NH2
5共2兲⫺4共2兲 Ea
221724.3*共5兲
CH3 NH2
5共⫺2兲⫺4共⫺2兲 Ea
221581.020*共31兲 221626.04*共9兲
221728.9*共5兲 221728.966*共16兲 221735.710*共9兲
CH3 NH2
5共⫺2兲⫺4共⫺2兲 Es
CH2 CHCN
23共1,22兲⫺23共1,21兲 v11 ⫽1
34
SO2
b
Sgr B2共N兲
SEST 15 m
Num98
Num98
4.3f
SgrB2共N兲
SEST 15 m
Num98
Num98 Num98
b
Sgr B2共N兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
13共2,12兲⫺13共1,13兲
4.3f 1.0
OriMC⫺1
OVRO 10.4 m
Sut85
24共0,24兲⫺23共0,23兲
0.4
OriMC⫺1
OVRO 10.4 m
Sut85
2.7f
SgrB2共N兲
SEST 15 m
Num98
U
221765.98*共6兲 221860.
CH2 CHCN unidentified
U
221899.
unidentified
3.1f
SgrB2共N兲
SEST 15 m
Num98
U
221914.
unidentified
SgrB2共N兲
SEST 15 m
Num98
221965.200*共7兲
SO2 CH3 OCHO
3.5f 13.9
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
221979.328*共20兲
11共1,11兲⫺10共0,10兲 18共9,*兲⫺17共9,*兲 A
24.8f
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
260
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
222005.
Formula
Quantum numbers
unidentified
T r 共K兲/T a 共K兲
Telescope
Astr. Ref.
Lab. Ref.
SgrB2共N兲
SEST 15 m
Num98
IRAM 30 m SEST 15 m
Cer91b Num98
Cer91b
5.0f
IRC⫹10216 SgrB2共N兲
21共2,20兲⫺21共1,21兲 AE⫹EA
5.0f
SgrB2共N兲
SEST 15 m
Num98
Gro98
21共2,20兲⫺21共1,21兲 EE
4.5fb
SgrB2共N兲
SEST 15 m
Num98
Gro98
CH3 OCH3
21共2,20兲⫺21共1,21兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
CH3 CCH
13共5兲⫺12共5兲
6.4f
SgrB2共N兲
SEST 15 m
Num98
9.2f 0.2 0.13 0.30 0.4 0.27
SgrB2共N兲
SEST 15 m
Num98
13共4兲⫺12共4兲 13共3兲⫺12共3兲 13共2兲⫺12共2兲 23共2,21兲⫺22共2,20兲 13共1兲⫺12共1兲
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m MMWO 4.9 m MMWO 4.9 m OVRO 10.4 m MMWO 4.9 m
Sut85 Lor84d Lor84d Sut85 Lor84d
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共N兲
MMWO 4.9 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Lor84d Sut85 Sut85 Num98
222009.366*共48兲 222014.474*共10兲
SiC2 CH3 CCH
9共2,7兲⫺8共2,6兲 13共6兲⫺12共6兲
222028.848*共12兲
CH3 OCH3
222032.946*共10兲
CH3 OCH3
222037.044*共16兲 222061.032*共7兲
6.4f n.r.
222077.
unidentified
222099.150*共4兲 222128.812*共3兲 222150.008*共2兲 222153.45*共5兲 222162.729*共2兲 222166.969*共2兲
CH3 CCH CH3 CCH CH3 CCH CH2 CHCN CH3 CCH CH3 CCH
222177. 222197.34* 共17兲 222199.887*共37兲
unidentified CH2 CO CH2 CO
11共0,11兲⫺10共0,10兲 11共3,9兲⫺10共3,8兲
222200.207*共37兲
CH2 CO
11共3,8兲⫺10共3,7兲
222228.587*共42兲 222238.877*共20兲 222242.39*共7兲
CH2 CO CH3 OCH3 CH2 CHCN
11共2,10兲⫺10共2,9兲 4共3,2兲⫺3共2,1兲 EA 24共0,24兲⫺23共0,23兲 v15 ⫽1
6.1f
222246.402*共4兲
CH2 CHCN
13共3,10兲⫺13共2,11兲
6.1f
222247.335*共8兲
CH3 OCH3
4共3,2兲⫺3共2,1兲 AE
1.3b
222247.611*共10兲
CH3 OCH3
4共3,2兲⫺3共2,1兲 EE
b
222254.597*共10兲
4共3,2兲⫺3共2,1兲 AA 4共3,1兲⫺3共2,1兲 EE
1.0
222258.711*共10兲
CH3 OCH3 CH3 OCH3
222259.610*共10兲
CH3 OCH3
4共3,1兲⫺3共2,1兲 EA
222314.457*共42兲 222321.31*共6兲
CH2 CO CH2 CHCN
11共2,9兲⫺10共2,8兲 23共2,21兲⫺22共2,20兲 v15 ⫽1
222323.853*共17兲
CH3 OCH3
25共3,23兲⫺24共4,20兲 AA
222325.122*共16兲
CH3 OCH3
25共3,23兲⫺24共4,20兲 EE
222326.391*共16兲
CH3 OCH3
25共3,23兲⫺24共4,20兲 AE⫹EA
222329.305*共15兲
3⫺2
222424.442*共9兲
HCNH⫹ CH3 OCHO SO2
222426.666*共8兲 222433.653*共10兲
CH3 OCH3 CH3 OCH3
222433.931*共10兲 222435.123*共20兲
222421.356*共21兲
Source
13共0兲⫺12共0兲
18共8,10兲⫺17共8,9兲 E 11共1,11兲⫺10共0,10兲 v2 ⫽1
0.41 0.4 0.6 15.2fb b
Sgr B2共N兲
SEST 15 m
Num98
0.2 0.02
OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
4.0fb
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Gro98 Gro98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
0.2 11.6f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
b
OriMC⫺1
IRAM 30 m
Sch91a
Gro98
0.4b
OriMC⫺1
IRAM 30 m
Sch91a
Gro98
b
OriMC⫺1
IRAM 30 m
Sch91a
Gro98
0.11
SgrB2共M兲
MMWO 4.9 m
Ziu86a
1.0
OriMC⫺1 SgrB2共M兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Gro98
Oes99
4共3,1兲⫺3共2,2兲 AE
12.1f 0.3
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
4共3,1兲⫺3共2,2兲 EE
1.5b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
CH3 OCH3
4共3,1兲⫺3共2,2兲 AA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
CH3 OCH3
4共3,1兲⫺3共2,2兲 EA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
222438.262*共20兲
CH3 OCHO
18共8,10兲⫺17共8,9兲 A
1.2b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
222440.374*共20兲
CH3 OCHO
18共8,11兲⫺17共8,10兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
222441.990*共20兲
CH3 OCHO
18共8,10兲⫺17共8,9兲 E
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
222707.218*共10兲 222722.796*共97兲 222869.105*共18兲 222918.177*共10兲 222963.570*共16兲
CH3 CH2 CN CH3 OH SO2 CH3 CH2 CN CH2 CHCN
26共0,26兲⫺25共1,25兲 16共2,14兲⫺15共1,15兲 A⫹ 36共3,33兲⫺37共2,36兲 25共1,24兲⫺24共1,23兲
0.3 0.6 5.7 0.9
OriMC⫺1 OriMC⫺1 W3共H2O兲 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m JCMT 15 m OVRO 10.4 m
Sut85 Sut85 Hel97 Sut85
23共2,21兲⫺22共2,20兲 v11 ⫽1
13.4f
SgrB2共N兲
SEST 15 m
Num98
U
223013.
unidentified
SgrB2共N兲
SEST 15 m
Num98
CH3 OCHO CH2 DOH unidentified
OriMC⫺1 IRAS16293⫺2422
OVRO 10.4 m IRAM 30 m
Sut85 Par02
U
223037.838*共17兲 223071.3 223073.
3.1f 0.3 0.17 5.5f
SgrB2共N兲
SEST 15 m
Num98
U
223088.
unidentified
5.2f
SgrB2共N兲
SEST 15 m
Num98
U
223097.
unidentified
SgrB2共N兲
SEST 15 m
Num98
223107.3
CH2 DOH CH3 OCHO CH3 OCHO CH2 DOH CH2 DOH
5共0,5兲⫺4共0,4兲 o1 18共7,12兲⫺17共7,11兲 A 18共7,11兲⫺17共7,10兲 E 5共2,4兲⫺4共2,3兲 e1 5共4,1兲⫺4共4,0兲 o1
7.0f 0.15 1.1 1.0 0.22 b
IRAS16293⫺2422 OriMC⫺1 OriMC⫺1 IRAS16293⫺2422 IRAS16293⫺2422
IRAM 30 m OVRO 10.4 m OVRO 10.4 m IRAM 30 m IRAM 30 m
Par02 Sut85 Sut85 Par02 Par02
Par02 Oes99 Oes99 Par02 Par02
CH2 DOH
5共4,2兲⫺4共4,1兲 o1
0.08b
Par02
223132.770*共17兲
CH3 CH2 CN
30共2,28兲⫺29共3,27兲
223132.970*共20兲
CH3 OCH3
31共3,28兲⫺31共2,29兲 EA⫹AE
223134.417*共20兲
CH3 OCH3
31共3,28兲⫺31共2,29兲 EE
223134.933*共17兲 223135.863*共20兲
CH3 OCHO CH3 OCH3
31共3,28兲⫺31共2,29兲 AA
223153.7
CH2 DOH
5共3,2兲⫺4共3,1兲 o1
223153.7
CH2 DOH
5共3,3兲⫺4共3,2兲 o1
223119.249*共20兲 223124.988*共20兲 223128.3 223131.1 223131.1
19共2,17兲⫺18共3,16兲 E 5共2,3兲⫺4共1,4兲 e1
18共7,12兲⫺17共7,11兲 E
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
IRAS16293⫺2422
IRAM 30 m
Par02
7.5f
SgrB2共N兲
SEST 15 m
Num98
Xu_97
Oes99 Par02
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
7.5fb 1.0
SgrB2共N兲
SEST 15 m
Num98
Gro98
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
0.58bf
IRAS16293⫺2422
IRAM 30 m
Par02
Par02
b
IRAS16293⫺2422
IRAM 30 m
Par02
Par02
MICROWAVE TRANSITIONS
261
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
223162.722*共20兲 223183.
CH3 OCHO unidentified
18共7,11兲⫺17共7,10兲 A
223200.063*共8兲
CH3 OCH3
223200.072*共8兲
CH3 OCH3
223202.243*共6兲
Source
Telescope
Astr. Ref.
Lab. Ref.
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
6.8f 8共2,7兲⫺7共1,6兲 AE
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
8共2,7兲⫺7共1,6兲 EA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
CH3 OCH3
8共2,7兲⫺7共1,6兲 EA
1.1b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
223204.418*共10兲
CH3 OCH3
8共2,7兲⫺7共1,6兲 EA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
223233.524*共13兲
12共2,11兲⫺11共1,11兲 vt ⫽0⫺1
5.3f
SgrB2共N兲
SEST 15 m
Num98
JPL01
3.3f
SgrB2共N兲
SEST 15 m
Num98
4.1f
SgrB2共N兲
SEST 15 m
Num98
U
223289.
g⫺CH3 CH2 OH unidentified
U
223296.
unidentified
0.8
CH3 OD
5共1,5兲⫺4共1,4兲 A⫹⫹
3.5f
SgrB2共N兲
SEST 15 m
Num98
And88
5共2,3兲⫺4共2,2兲 e1 11共1,10兲⫺10共1,9兲 25/2⫺23/2
0.16
223326.0
CH2 DOH CH2 CN
5.0f
IRAS16293⫺2422 Sgr B2共N兲
IRAM 30 m SEST 15 m
Par02 Num98
Par02 Num98
223332.021*共30兲
13
6共1,5兲⫺7共2,6兲 A⫺⫺ vt ⫽1
6.1f
SgrB2共N兲
SEST 15 m
Num98
Xu_97
13共2,12兲⫺13共1,13兲
5.7f 0.9
SgrB2共M兲
SEST 15 m
Num98
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Gro98
8.6fb
SgrB2共N兲
SEST 15 m
Num98
Gro98
223308.57共5兲 223315.4
223378.583*共32兲
U
T r 共K兲/T a 共K兲
CH3 OH 33
223385.326*共11兲 223406.886*共14兲
SO2 CH3 CH2 CN CH3 OCH3
26共1,26兲⫺25共1,25兲 26共2,24兲⫺26共1,25兲 AE⫹EA
223409.478*共12兲
CH3 OCH3
26共2,24兲⫺26共1,25兲 EE
223412.069*共16兲
CH3 OCH3
26共2,24兲⫺26共1,25兲 AA
Sgr B2共N兲
SEST 15 m
Num98
Gro98
223422.3 223422.5 223434.468*共9兲
CH2 DOH unidentified SO2 NH2 CHO CH3 OCHO
5共2,4兲⫺4共2,3兲 e0
0.10 0.10
IRAS16293⫺2422 OriMC⫺1
IRAM 30 m IRAM 30 m
Par02 Com96
Par02
27共6,20兲⫺28共7,21兲 11共1,11兲⫺10共1,10兲 11共4,8兲⫺10共3,7兲 E 10共2,9兲⫺9共2,8兲
0.3 0.20 0.15 0.03
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m IRAM 30 m IRAM 30 m IRAM 30 m
Sut85 Com96 Com96 Com96
Oes99 Wil80
0.02 0.02 0.05 0.22 0.6 0.03
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共N兲
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m OVRO 10.4 m IRAM 30 m SEST 15 m
Com96 Com96 Com96 Com96 Sut85 Com96 Num98
Oes99
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m OVRO 10.4 m
Com96 Com96 Com96 Com96 Sut85
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
7.4f
OriMC⫺1 SgrB2共N兲
IRAM 30 m SEST 15 m
Com96 Num98
223452.500*共6兲 223465.322*共34兲 223472.23*共3兲
b
223483.0 223490.7 223512.6 223534.4 223553.585*共11兲 223584.8 223591.869*共80兲
H13COOH unidentified unidentified unidentified unidentified CH3 CH2 CN unidentified CH3 OCHO
223617.3 223624.577*共50兲 223634.748*共50兲 223642.2 223650.097*共8兲 223660.610*共8兲
unidentified CH3 OCHO CH3 OCHO unidentified CH3 CHO CH3 CHO
U
223672.
unidentified
U U
223675.5 223680.
unidentified unidentified
223684.608*共24兲
共CH3 兲2 CO
17共6,11兲⫺16共7,10兲 AE
n.r.b
OriMC⫺1
IRAM 30 m
Com96
Vac86
223684.608*共24兲
共CH3 兲2 CO
17共6,11兲⫺16共7,10兲 EA
b
OriMC⫺1
IRAM 30 m
Com96
Vac86
223692.003*共24兲
共CH3 兲2 CO
17共7,11兲⫺16共6,10兲 EA
0.09b
OriMC⫺1
IRAM 30 m
Com96
Vac86
223692.103*共24兲
共CH3 兲2 CO
17共7,11兲⫺16共6,10兲 AE
b
OriMC⫺1
IRAM 30 m
Com96
Vac86
U
223694.8 223707.120*共4兲 223716.
0.07 n.r.
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
U
unidentified CH2 CHCN unidentified
U U U U U U
U
U U U U
223718.0 223722.4 223733.8 223747.3 223753.944*共15兲
U
223755.8 223767.585*共20兲 223775.252*共20兲 223796.0 223800.46*共8兲
U U U U U U
26共0,26兲⫺25共0,25兲 43共8,35兲⫺43共7,36兲 A
12共⫺1,12兲⫺11共⫺1,11兲 E
3.2f 0.04 0.04 n.r. n.r. 0.2
12共1,12兲⫺11共1,11兲 A⫹⫹
0.3
37共8,30兲⫺37共7,31兲 E 37共8,30兲⫺37共7,31兲 A
6.3f 0.06
11共3,8兲⫺11共2,9兲
unidentified unidentified unidentified unidentified OS18O unidentified 共CH3 兲2 CO 共CH3 兲2 CO
223812.4 223821.594*共42兲 223838.8 223845.3 223854.123*共43兲 223858. 223866.
unidentified
223883.573*共6兲
SO2
223915.56*共1兲 223933.734*共10兲
HCOOH CH3 CH2 CN
SgrB2共N兲
SEST 15 m
Num98
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m SEST 15 m
Com96 Com96 Com96 Com96 Num98
Kle96 Kle96
14共3,11兲⫺14共2,12兲
5.9f
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲
17共6,11兲⫺16共7,10兲 EE 17共7,11兲⫺16共6,10兲 EE
0.07 0.10 0.06
OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m IRAM 30 m
Com96 Com96 Com96
Vac86 Vac86
8共2,7兲⫺8共1,8兲
n.r. n.r.
OriMC⫺1 OriMC⫺1
IRAM 30 m IRAM 30 m
Com96 Com96
Wil80
0.12 0.06 0.03 0.04 n.r. 4.1f
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共M兲
IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m IRAM 30 m SEST 15 m
Com96 Com96 Com96 Com96 Com96 Num98
9.8f 1.4 0.3 0.6
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
unidentified H13COOH unidentified CH3 OCHO unidentified unidentified CH3 OCHO unidentified
3.7f 0.03 0.06 0.03 0.04
Oes99 Oes99
35共7,29兲⫺35共6,30兲 E
35共7,29兲⫺35共6,30兲 A
6共4,2兲⫺7共3,5兲 10共2,9兲⫺9共2,8兲 25共3,23兲⫺24共3,22兲
Oes99
Oes99
Wil80
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
262
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
0.05 0.06
OriMC⫺1 OriMC⫺1 SgrB2共N兲
IRAM 30 m IRAM 30 m SEST 15 m
Com96 Com96 Num98
7.6f
OriMC⫺1 SgrB2共N兲
IRAM 30 m SEST 15 m
Com96 Num98
b
OriMC⫺1
OVRO 10.4 m
Sut85
0.9b 0.6
OriMC⫺1
OVRO 10.4 m
Sut85
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Oes99 Oes99
U U U
223955.6 223964.2 223967.
unidentified unidentified unidentified
U U
223970.6 223976.
unidentified unidentified
224002.121*共10兲
CH3 CH2 CN
25共10,*兲⫺24共10,*兲
224003.440*共9兲
CH3 CH2 CN
25共9,*兲⫺24共9,*兲
224017.539*共10兲 224021.766*共20兲
CH3 CH2 CNr CH3 OCHO
25共11,*兲⫺24共11,*兲 18共6,13兲⫺17共6,12兲 E
1.0b
OriMC⫺1 OriMC⫺1
224024.091*共20兲
CH3 OCHO
18共6,13兲⫺17共6,12兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
224028.141*共9兲 224045.749*共11兲 224084.280*共12兲
CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN
25共6,*兲⫺24共6,*兲 25共12,*兲⫺24共12,*兲 25共13,*兲⫺24共13,*兲
0.8 0.3 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
224088.193*共9兲
CH3 CH2 CN
25共7,19兲⫺24共7,18兲
0.8b
OriMC⫺1
OVRO 10.4 m
Sut85
224088.229*共9兲
CH3 CH2 CN
25共7,18兲⫺24共7,17兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
224131.512*共12兲 224144.510*共21兲
CH3 CH2 CN
25共14,*兲⫺24共14,*兲
0.2
OriMC⫺1
OVRO 10.4 m
Sut85
8共7,*兲⫺8共6,*兲 vt ⫽0⫺1
5.3f
SgrB2共N兲
SEST 15 m
Num98
JPL01
224167.899*共37兲
g⫺CH3 CH2 OH CH3 OCHO
27共9,19兲⫺27共8,20兲 E
14.8fb
SgrB2共N兲
SEST 15 m
Num98
Oes99
224173.380*共34兲
CH3 OCHO
27共9,19兲⫺27共8,20兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
224186.346*共13兲
25共15,*兲⫺24共15,*兲 25共6,20兲⫺24共6,19兲
0.2
224206.606*共9兲
CH3 CH2 CN CH3 CH2 CN
0.7b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
224208.082*共9兲
CH3 CH2 CN
25共6,19兲⫺24共6,18兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
224231.694*共11兲
CH3 CH2 CN
26共1,26兲⫺25共0,25兲
6.4f
SgrB2共N兲
SEST 15 m
Num98
224248.007*共14兲
CH3 CH2 CN
25共16,*兲⫺24共16,*兲
SEST 15 m
Num98
SO2 CH3 OCHO CH3 CH2 CN
20共2,16兲⫺19共3,17兲
12.7f 2.6
SgrB2共N兲
224264.833*共7兲 224313.084*共17兲
OriMC⫺1
OVRO 10.4 m
Sut85
17.0f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98 Sut85
224315.934*共15兲
U
11.9f 0.11
18共5,14兲⫺17共5,13兲 E 25共17,*兲⫺24共17,*兲
224327.109*共75兲
CH2 CO
11共1,10兲⫺10共1,9兲
224328.310*共20兲
CH3 OCHO
18共5,14兲⫺17共5,13兲 A
224377.
unidentified
b
OriMC⫺1
OVRO 10.4 m
0.8b
OriMC⫺1
OVRO 10.4 m
Sut85
8.2f
SgrB2共N兲
SEST 15 m
Num98
224389.709*共16兲
CH3 CH2 CN
9.1f
SgrB2共N兲
SEST 15 m
Num98
U
224398.
unidentified
5.4f
SgrB2共N兲
SEST 15 m
Num98
U
224409.
unidentified
SgrB2共N兲
SEST 15 m
Num98
224419.821*共9兲
U
224458.856*共9兲 224469.011*共18兲 224481.
CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN unidentified
9.3f 0.4 0.7 0.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Sut85 Num98
U
224490.
unidentified
U U
224493. 224502.
unidentified unidentified
224553.589*共21兲
CH3 CH2 CN
224563.333*共68兲
CH3 CHO
224582.293*共21兲 224609.365*共20兲 224638.704*共9兲
CH3 OCHO CH3 OCHO CH3 CH2 CN
18共6,12兲⫺17共6,11兲 E 18共6,12兲⫺17共6,11兲 A 25共4,22兲⫺24共4,21兲
224643.239*共25兲
CH3 CH2 CN
25共21,*兲⫺24共21,*兲
224656.971*共12兲
CH3 CHO
12共3,9兲⫺12共2,10兲 A⫺⫹
224699.714*共68兲
CH3 OH
224714.389*共3兲 224771.
C17O unidentified
20共⫺2,19兲⫺19共⫺3,17兲 E 2⫺1
224878.486*共4兲
CH2 CHCN
8共3,5兲⫺8共2,6兲
224888.371*共17兲
CH3 CH2 CN
7共4,4兲⫺6共3,3兲
224894.492*共17兲
CH3 CH2 CN
7共4,3兲⫺6共3,4兲
224946.040 共50兲
g⫺CH3 CH2 OH CH3 CHO
U
224951.610*共10兲 225085.44*共1兲 225091.21*共1兲 U
U
225101.
25共18,*兲⫺24共18,*兲
0.8
25共5,21兲⫺24共5,20兲 25共5,20兲⫺24共5,19兲 25共19,*兲⫺24共19,*兲
10.2f
Oes99
Oes99
SgrB2共N兲
SEST 15 m
Num98
15.5f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
25共20,*兲⫺24共20,*兲
18.8f
SgrB2共N兲
SEST 15 m
Num98
17共⫺2,16兲⫺17共⫺1,17兲 E
6.3f 0.8 0.8
SgrB2共N兲
SEST 15 m
Num98
Kle96
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Oes99 Oes99
0.6b
OriMC⫺1 OriMC⫺1 OriMC⫺1
b
OriMC⫺1
OVRO 10.4 m
Sut85
5.0f
SgrB2共N兲
SEST 15 m
Num98
Kle96
0.7 1.5
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Xu_97
4.4f
Sgr B2共N兲
SEST 15 m
Num98
7.2f
SgrB2共N兲
SEST 15 m
Num98
7.3fb
SgrB2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
13共8,*兲⫺12共8,*兲 vt ⫽1⫺1
5.0f
SgrB2共N兲
SEST 15 m
Num98
16共⫺3,13兲⫺16共⫺2,14兲 E vt ⫽1
5.0f
SgrB2共N兲
SEST 15 m
Num98
Kle96
HCOOH
10共4,7兲⫺9共4,6兲
4.3e
OriMC⫺1
BIMAArray
Liu02
Wil80
HCOOH
10共4,6兲⫺9共4,5兲
5.2e
OriMC⫺1
BIMAArray
Liu02
Wil80
9.5f
SgrB2共N兲
SEST 15 m
Num98
9.2f 0.5
unidentified
Pea96
225109.881共50兲
g⫺CH3 CH2 OH
13共6,*兲⫺12共6,*兲 vt ⫽1⫺1
6.9f
SgrB2共N兲
SEST 15 m
Num98
Pea96
225130.505共50兲
g⫺CH3 CH2 OH unidentified
13共8,*兲⫺12共8,*兲 vt ⫽0⫺0
10.1f
Sgr B2共N兲
SEST 15 m
Num98
Pea96
SgrB2共N兲
SEST 15 m
Num98
225153.689*共6兲
SO2
225170.614 共50兲
6.9f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Pea96
225202.572*共10兲
g⫺CH3 CH2 OH CH3 OCH3
13共2,12兲⫺13共1,13兲 13共7,*兲⫺12共7,*兲 vt ⫽0⫺0
9.6f 6.3
24共4,21兲⫺24共3,22兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
225204.001*共8兲
CH3 OCH3
24共4,21兲⫺24共3,22兲 EE
SgrB2共N兲
SEST 15 m
Num98
Gro98
225139.
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
12.1fb
MICROWAVE TRANSITIONS
263
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
b
Sgr B2共N兲
6共3,3兲⫺6共2,4兲
2.1f
SgrB2共M兲
CH3 CHO
15共3,13兲⫺15共2,14兲 A⫹⫺ vt ⫽1
6.6f
SgrB2共N兲
SEST 15 m
Num98
2.8f
SgrB2共M兲
SEST 15 m
Num98
225227.
unidentified t⫺CH3 CH2 OH CH3 CH2 CN
225258.
g⫺CH3 CH2 OH unidentified
225267.
unidentified
225297.
g⫺CH3 CH2 OH unidentified
13共5,*兲⫺12共5,*兲 vt ⫽1⫺1
SgrB2共N兲
SEST 15 m
Num98
7.5f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
4.7f
SgrB2共N兲
SEST 15 m
Num98
3.1f
SgrB2共N兲
SEST 15 m
Num98
9.2f
SgrB2共N兲
SEST 15 m
Num98
10.3f
SgrB2共N兲
SEST 15 m
Num98
6.7f 0.8
Kle96
Pea96
Pea96
CH3 CH2 CN
12共3,9兲⫺11共2,10兲
5.6f
SgrB2共N兲
SEST 15 m
Num98
CH3 CH2 CN
23共2,22兲⫺22共1,21兲
5.8f
SgrB2共N兲
SEST 15 m
Num98
225354.566*共5兲
CH2 CHCN
3共3,0兲⫺3共2,1兲
3.4f
SgrB2共N兲
SEST 15 m
Num98
225371.927*共5兲
CH2 CHCN
3共3,1兲⫺3共2,2兲
4.9f
SgrB2共N兲
SEST 15 m
Num98
225399.733共50兲
g⫺CH3 CH2 OH
13共5,9兲⫺12共5,8兲 vt ⫽0⫺0
4.2f
SgrB2共N兲
SEST 15 m
Num98
Pea96
225404.089共50兲
g⫺CH3 CH2 OH CH2 CHCN
13共5,8兲⫺12共5,7兲 vt ⫽0⫺0
8.3f
SgrB2共N兲
SEST 15 m
Num98
Pea96
5共3,3兲⫺5共2,4兲
SgrB2共N兲
SEST 15 m
Num98
19⫺18
8.3f 0.7
OriMC⫺1
OVRO 10.4 m
Sut85
6共3,4兲⫺6共2,5兲
4.3f
SgrB2共N兲
SEST 15 m
Num98
Dub80
225448.096*共4兲
OC34S CH2 CHCN
225468.366*共22兲
c⫺C2 H4 O
5共4,2兲⫺4共3,1兲
0.49f
NGC6334F
SEST 15 m
Num98a
225476.638*共17兲
12共1,12兲⫺11共0,11兲
2.3f
SgrB2共M兲
SEST 15 m
Num98
225508.841*共4兲
OS18O CH2 CHCN
7共3,5兲⫺7共2,6兲
4.0f
SgrB2共N兲
SEST 15 m
Num98
225511.27*共20兲
CH3 CHO
12共3,9兲⫺11共3,8兲 E vt ⫽2
SgrB2共N兲
SEST 15 m
Num98
Kle96
225512.54*共1兲 225513.43*共16兲
HCOOH CH3 CHO
10共3,7兲⫺9共3,6兲 12共1,12兲⫺11共1,11兲 A⫹⫹ vt ⫽2
4.1fb 0.4
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Wil80 Kle96
225554.55* 共14兲
CH2 NH
1共1,1兲⫺0共0,0兲
OriMC⫺1 SgrB2共N兲
NRAO 12 m SEST 15 m
Dic97a Num98
225583.
unidentified
b
0.22 4.0f 3.1f
SgrB2共N兲
SEST 15 m
Num98
b
OriMC⫺1
MMWO 4.9 m
Woo84
Gro98
12共1,12兲⫺11共0,11兲 EE
0.7b
OriMC⫺1
MMWO 4.9 m
Woo84
Gro98
CH3 OCH3
12共1,12兲⫺11共0,11兲 AA
b
OriMC⫺1
MMWO 4.9 m
Woo84
Gro98
CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO CH2 DCN
19共3,17兲⫺18共3,16兲 E 19共3,17兲⫺18共3,16兲 A 26共9,18兲⫺26共8,19兲 E 26共9,18兲⫺26共8,19兲 A 13共5,*兲⫺12共5,*兲
OriMC⫺1 OriMC⫺1 OriMC⫺1 OMC⫺IRc2 G34.3
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m IRAM 30 m IRAM 30 m
Sut85 Sut85 Sut85 Jac90 Ger92a
Oes99 Oes99 Oes99 Oes99
225723.787*共8兲
H2 CO CH2 DCN
3共1,2兲⫺2共1,1兲 13共3,11兲⫺12共3,10兲
0.2f
OriMC⫺1 G34.3
MMWO 4.9 m IRAM 30 m
Eva79 Ger92a
225724.071*共8兲
CH2 DCN
13共3,10兲⫺12共3,9兲
0.2f
G34.3
IRAM 30 m
Ger92a
225726.557*共9兲
CH2 DCN
13共2,12兲⫺12共2,11兲
0.5f 1.9
G34.3
IRAM 30 m
Ger92a
OMC⫺IRc2 SgrB2共N兲
IRAM 30 m SEST 15 m
Jac90 Num98
OMC⫺IRc2 OMC⫺IRc2 G34.3
IRAM 30 m IRAM 30 m IRAM 30 m
Jac90 Jac90 Ger92a
OMC⫺IRc2 OMC⫺IRc2 OMC⫺IRc2 SgrB2共N兲
IRAM 30 m IRAM 30 m IRAM 30 m SEST 15 m
Jac90 Jac90 Jac90 Num98
OMC⫺IRc2 OMC⫺IRc2 SgrB2共M兲
IRAM 30 m IRAM 30 m SEST 15 m
Jac90 Jac90 Num98
225591.
unidentified
225598.770*共6兲
CH3 OCH3
12共1,12兲⫺11共0,11兲 EA⫹AE
225599.120*共6兲
CH3 OCH3
225599.469*共6兲 225608.778*共17兲
225697.773*共10兲
U
225744.8
unidentified
U
225751.
unidentified
U U
225756.3 225767.4 225781.517*共9兲
unidentified unidentified CH2 DCN
U U
225784.6 225803.1 225824.33*共6兲 225835.938*共8兲
unidentified unidentified HCOOH
225840.8 225850.8 225851. 225853.841共60兲
g⫺CH3 CH2 OH unidentified unidentified unidentified
1.1 1.3 1.0 2.3 0.5f 5.0
5.6f 2.3 0.8 13共2,11兲⫺12共2,10兲
31共3,28兲⫺31共3,29兲 5共3,3兲⫺5共2,3兲 vt ⫽1⫺0
3⫺2
0.7f 0.6 1.3 1.8 5.7f 0.7 1.4 3.9f 1.9
225896.720 共38兲 225900.736*共34兲 225915.8 225928.598*共35兲
D15NC HDO CH3 OCHO unidentified CH3 OCHO
3共1,2兲⫺2共2,1兲 6共6,0兲⫺5共5,0兲 E
2.3 0.14 0.7
6共6,1兲⫺5共5,0兲 A
0.4b
225928.613*共35兲
CH3 OCHO
6共6,0兲⫺5共5,1兲 A
b
U
225934.6 225937.239*共24兲
unidentified
U U
225944.6 226035.6 226043.182*共23兲
U
Telescope
225317.145*共14兲
225618.712*共17兲 225625.063*共48兲 225648.715*共32兲 225659.841*共14兲
U U U
17共2,15兲⫺16共3,14兲 25共4,21兲⫺24共4,20兲 13共6,*兲⫺12共6,*兲 vt ⫽0⫺0
Source
225307.834*共16兲
225413.628共7兲
U
Gro98
24共4,21兲⫺24共3,22兲 AA
225408.671*共5兲
U
Num98 Num98
CH3 OCH3 CH2 CHCN
225278.851共50兲 U
SEST 15 m SEST 15 m
225205.429*共10兲
225236.120*共9兲 225248.812 共50兲 U
Lab. Ref.
225206.505*共5兲
225229.253*共25兲
U
Astr. Ref.
Quantum numbers
225220.246*共90兲 U
T r 共K兲/T a 共K兲
Formula
226043.182*共23兲
0.9
OS18O unidentified unidentified
14共2,13兲⫺14共1,14兲
c⫺C2 H4 O
7共1,6兲⫺6共2,5兲
c⫺C2 H4 O
7共1,6兲⫺6共2,5兲
4.8f 0.6 1.0 0.62f 1.1
Wil80 JPL01
OMC⫺IRc2
IRAM 30 m
Jac90
Pea76
OriMC⫺1 W3共H2O兲 OMC⫺IRc2 OriMC⫺1
OVRO 10.4 m JCMT 15 m IRAM 30 m OVRO 10.4 m
Sut85 Hel97 Jac90 Sut85
DeL71 Oes99
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
OMC⫺IRc2 SgrB2共M兲
IRAM 30 m SEST 15 m
Jac90 Num98
OMC⫺IRc2 OMC⫺IRc2 NGC6334F
IRAM 30 m IRAM 30 m SEST 15 m
Jac90 Jac90 Num98a
OMC⫺IRc2
IRAM 30 m
Jac90
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
264
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Formula
226058.4 226072.144*共23兲
unidentified
226072.144*共23兲 226077.705*共60兲 226090.2 226094. 226094.011*共9兲
c⫺C2 H4 O CH3 OCHO unidentified unidentified N2 O
226125.616*共56兲
CH3 OCHO
U
226217.
unidentified
U
226233.4 226256.83*共5兲 226264.653*共23兲 226300.010*共8兲 226332.519*共20兲 226341.919*共20兲
CN
226346.124*共8兲
U U
U
Source
Telescope
Astr. Ref.
0.7 7共2,6兲⫺6共1,5兲
0.90f
OMC⫺IRc2 NGC6334F
IRAM 30 m SEST 15 m
Jac90 Num98a
c⫺C2 H4 O
Lab. Ref.
7共2,6兲⫺6共1,5兲
1.7
OMC⫺IRc2
IRAM 30 m
Jac90
10共3,7兲⫺9共1,8兲 E
0.6 2.0 0.9
OMC⫺IRc2 OMC⫺IRc2 OMC⫺IRc2 SgrB2共N兲
IRAM 30 m IRAM 30 m IRAM 30 m SEST 15 m
Jac90 Jac90 Jac90 Num98
JPL01
OMC⫺IRc2 SgrB2共N兲
IRAM 30 m SEST 15 m
Jac90 Num98
JPL01
SgrB2共N兲 OriMC⫺1
SEST 15 m OVRO 10.4 m
Dic01 Sut85
9⫺8
6.6f
10共3,7兲⫺9共1,8兲 A
0.9
unidentified CH2 CHCN
24共2,23兲⫺23共2,22兲
4.2f 0.06 0.2
g⫺CH3 CH2 OH
21共4,18兲⫺21共3,18兲 vt ⫽1⫺0
SO2 CN
14共3,11兲⫺14共2,12兲
SgrB2共N兲
SEST 15 m
Num98
JPL01
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Woo82
0.3
OriMC⫺1
OVRO 10.4 m
Sut85
Woo82
CH3 OCH3
2⫺1 J⫽3/2⫺3/2 F⫽5/2⫺3/2 14共1,13兲⫺13共2,12兲 AA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
226346.948*共6兲
CH3 OCH3
14共1,13兲⫺13共2,12兲 EE
1.6b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
226347.772*共8兲
CH3 OCH3
14共1,13兲⫺13共2,12兲 AE⫹EA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
226359.987*共20兲
CN
2⫺1 J⫽3/2⫺3/2 F⫽5/2⫺5/2
1.2
OriMC⫺1
OVRO 10.4 m
Sut85
Woo82
226384. 226435.502*共32兲
unidentified CH3 OCHO
0.5 25共9,16兲⫺25共8,17兲 A
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
226454.11*共12兲
HC13CCN CH3 OCHO
25⫺24
16.6f
SgrB2共N兲
SEST 15 m
Num98
Laf78
25共9,16兲⫺25共8,17兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
HCC13CN CH3 CHO
25⫺24
10.7f
SgrB2共N兲
SEST 15 m
Num98
Laf78
226487.236*共11兲
13共0,13兲⫺12共⫺1,12兲E
5.5f
SgrB2共N兲
SEST 15 m
Num98
Kle96
226491.335*共14兲
CH3 OCH3
22共1,21兲⫺22共0,22兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
226495.523*共12兲
CH3 OCH3
22共1,21兲⫺22共0,22兲 EE
3.2fb
SgrB2共N兲
SEST 15 m
Num98
Gro98
226499.711*共16兲
CH3 OCH3
22共1,21兲⫺22共0,22兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
226508.274*共11兲
SO2
41共5,37兲⫺40共6,34兲
7.5f
SgrB2共M兲
SEST 15 m
Num98
226538.674共50兲
CH3 OD
5共0,5兲⫺4共0,4兲 A
4.6f
OriMC⫺1
IRAM 30 m
Mau88
226548.65*共23兲
CH2 NH
6共1,5兲⫺6共0,6兲
SgrB2共N兲
SEST 15 m
Num98
226551.624*共8兲 226592.732*共8兲 226616.520*共20兲
CH3 CHO CH3 CHO CN
12共0,12兲⫺11共0,11兲 E 12共0,12兲⫺11共0,11兲 A⫹⫹ 2⫺1 J⫽3/2⫺1/2 F⫽1/2⫺3/2
32.6f 0.3 0.2 0.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Kle96 Kle96 Ska83
226632.176*共20兲
CN
2⫺1 J⫽3/2⫺1/2 F⫽3/2⫺3/2
1.4
OriMC⫺1
OVRO 10.4 m
Sut85
Ska83
226659.543*共20兲
CN
2⫺1 J⫽3/2⫺1/2 F⫽5/2⫺3/2
4.3
OriMC⫺1
OVRO 10.4 m
Sut85
Ska83
226663.685*共20兲
CN
2⫺1 J⫽3/2⫺1/2 F⫽1/2⫺1/2
1.5
OriMC⫺1
OVRO 10.4 m
Sut85
Ska83
226679.341*共20兲
CN
1.9
OriMC⫺1
OVRO 10.4 m
Sut85
Ska83
226706.601 共50兲
CH3 OD
2⫺1 J⫽3/2⫺1/2 F⫽3/2⫺1/2 5共2,4兲⫺4共2,3兲 A⫺
OriMC⫺1
IRAM 30 m
Mau88
And88
226713.028*共17兲
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
20共2,19兲⫺19共2,18兲 A 5共⫺4,2兲⫺4共⫺4,1兲E
0.5
226738.864 共50兲
CH3 OCHO CH3 OCHO CH3 OD
3.7f 0.9
OriMC⫺1 OriMC⫺1
OVRO 10.4 m IRAM 30 m
Sut85 Mau88
Oes99 And88
226773.152*共17兲 226778.764*共20兲 226818.36共5兲
CH3 OCHO CH3 OCHO CH2 DOH
20共1,19兲⫺19共1,18兲E 20共1,19兲⫺19共1,18兲A 5共1,4兲⫺4共1,3兲
OriMC⫺1 OriMC⫺1 OriMC⫺1⫺6⬙
OVRO 10.4 m OVRO 10.4 m IRAM 30 m
Sut85 Sut85 Jac92
Oes99 Oes99 Jac93
226856.825*共17兲
CH3 OCHO CH3 OCHO
20共2,19兲⫺19共1,18兲 E 20共2,19兲⫺19共1,18兲 A
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Woo82
Oes99 Oes99 Ska83
226476.082*共49兲
226718.748*共20兲
2⫺1 J⫽3/2⫺3/2 F⫽3/2⫺5/2
20共2,19兲⫺19共2,18兲 E
3.5fb
1.4f 0.9 1.0 1.6f
CN
2⫺1 J⫽5/2⫺3/2 F⫽5/2⫺3/2
b
226874.764*共20兲
CN
2⫺1 J⫽5/2⫺3/2 F⫽7/2⫺5/2
8.0b
OriMC⫺1
OVRO 10.4 m
Woo82
Ska83
226875.896*共20兲
CN
2⫺1 J⫽5/2⫺3/2 F⫽3/2⫺1/2
b
OriMC⫺1
OVRO 10.4 m
Woo82
Ska83
226887.399*共20兲
CN
2⫺1 J⫽5/2⫺3/2 F⫽3/2⫺3/2
1.0
OriMC⫺1
OVRO 10.4 m
Woo82
Ska83
226892.151*共20兲
CN
1.0
OriMC⫺1
OVRO 10.4 m
Woo82
Ska83
226922.584 共50兲
CH3 OD
2⫺1 J⫽5/2⫺3/2 F⫽5/2⫺5/2 5共⫺2,4兲⫺4共⫺2,3兲 E
1.0f
OriMC⫺1
IRAM 30 m
Mau88
And88
226942.830共50兲
CH3 OD
5共3,3兲4共3,2兲 A⫹
1.2f
OriMC⫺1
IRAM 30 m
Mau88
And88
227004.78*共13兲
Si13CC CH3 OCHO CH3 OCHO
10共2,9兲⫺9共2,8兲
IRC⫹10216
IRAM 30 m
Cer91b
19共2,17兲⫺18共2,16兲 E 19共2,17兲⫺18共2,16兲 A
0.7f 1.0 1.2
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
12共3,9兲⫺12共2,10兲
0.7
OriMC⫺1
OVRO 10.4 m
Sut85
SgrB2共N兲
SEST 15 m
Num98
227019.516*共17兲 227028.100*共20兲 227031.878*共12兲 227078.
34
SO2
unidentified
0.5 0.6
And88
OriMC⫺1 OriMC⫺1 OriMC⫺1
226862.239*共20兲 226874.183*共20兲
Oes99 Oes99
CH3 OH
21共1,20兲⫺21共0,21兲 E
3.3f 0.9
OriMC⫺1
OVRO 10.4 m
Sut85
4共3,2兲⫺3共2,1兲
7.9f
SgrB2共N兲
SEST 15 m
Num98
227258.988*共14兲
c⫺C3 H2 CH3 CHO
12共0,12兲⫺11共0,11兲 E vt ⫽1
2.4f
SgrB2共N兲
SEST 15 m
Num98
Kle96
227295.629共50兲
CH3 SH
9共0兲⫺8共0兲 E
12.2f
SgrB2共N兲
SEST 15 m
Num98
Sas86
227300.606*共50兲
13C34S
5⫺4
12.2fb
SgrB2共N兲
SEST 15 m
Num98
0.1
CRL618
IRAM 30 m
Cer89a
227094.60*共15兲 227169.142*共5兲
U
T r 共K兲/T a 共K兲
4.7f 5.8 0.3
226467.745*共43兲
U
Quantum numbers
227318.
unidentified
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Xu_97
MICROWAVE TRANSITIONS
265
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 227326.392共50兲 U
U
U
227344.
Quantum numbers
CH3 SH
9共0兲⫺8共0兲 A⫹⫹
unidentified
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
9.3f
SgrB2共N兲
SEST 15 m
Num98
Sas86
7.5f 3.5
SgrB2共N兲
SEST 15 m
Num98
8.5f
OriMC⫺1 SgrB2共N兲
OVRO10.4m SEST 15 m
Sut85 Num98
Sas86 Sas86
227418.909*共7兲 227531.445共50兲
HCCCN CH3 SH
25⫺24 9共2兲⫺8共2兲 A⫺⫺
227539.453共50兲
CH3 SH
9共5兲⫺8共5兲 A⫹⫹
4.9fb
SgrB2共N兲
SEST 15 m
Num98
227539.453共50兲
CH3 SH
9共5兲⫺8共5兲 A⫺⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
227543.5*共5兲
CH3 NH2
10共⫺2兲⫺10共1兲 Aa⫺⫹
4.9f
SgrB2共N兲
SEST 15 m
Num98
Num98
227543.749共50兲
CH3 SH
9共⫺5兲⫺8共⫺5兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
227548.144 共50兲
CH3 SH
9共5兲⫺8共5兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
227560.932*共20兲
CH3 OCHO
21共1,21兲⫺20共1,20兲 E
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
227561.731*共20兲
CH3 OCHO
21共0,21兲⫺20共0,20兲 E
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
227562.032*共21兲
CH3 OCHO
21共1,21兲⫺20共1,20兲 A
2.1b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
227562.828*共21兲
CH3 OCHO
21共0,21兲⫺20共0,20兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
227594.789 共50兲
CH3 SH
9共3兲⫺8共3兲 E
6.3fb
SgrB2共N兲
SEST 15 m
Num98
Sas86
227595.057共50兲
CH3 SH
9共3兲⫺8共3兲 A⫹⫹
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
227597.280 共50兲
CH3 SH
9共⫺3兲⫺8共⫺3兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
227598.158 共50兲
CH3 SH
9共3兲⫺8共3兲 A⫺⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
227605.645*共6兲
NH2 CHO
11共0,11兲⫺10共0,10兲
16.4f
SgrB2共N兲
SEST 15 m
Num98
13.6f
SgrB2共N兲
SEST 15 m
Num98
13.7fb
SgrB2共N兲
SEST 15 m
Num98
Sas86
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
2.7f
SgrB2共N兲
SEST 15 m
Num98
1.8f
SgrB2共N兲
SEST 15 m
Num98
3.4f 0.5
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
0.5b
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
b
OriMC⫺1
OVRO 10.4 m
Sut85
0.5 4.0f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
227625.
unidentified
227663.745共50兲
CH3 SH
9共⫺2兲⫺8共⫺2兲 E
227669.824共50兲
CH3 SH
9共2兲⫺8共2兲 E
227706.657*共4兲
CH2 CHCN
15共3,13兲⫺15共2,14兲
227729.
unidentified g⫺CH3 CH2 OH CH3 CH2 CN HCCCN
3共2,2兲⫺2共1,2兲 vt ⫽1⫺0
227897.52* 共11兲 227906.61*共9兲
CH3 OH CH2 CHCN CH2 CHCN
16共1,16兲⫺15共2,13兲 A⫹ 24共7,*兲⫺23共7,*兲 24共6,19兲⫺23共6,18兲
227906.64*共9兲
CH2 CHCN
24共6,18兲⫺23共6,17兲
227918.54* 共13兲
CH2 CHCN
24共8,*兲⫺23共8,*兲
227938.
unidentified
227960.07*共15兲
CH2 CHCN
24共9,*兲⫺23共9,*兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
227965.97*共7兲
CH2 CHCN
24共5,20兲⫺23共5,19兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
227967.52*共7兲
CH2 CHCN
24共5,19兲⫺23共5,18兲
OriMC⫺1
OVRO 10.4 m
Sut85
227977.074*共68兲 227994.509*共40兲
HCCCN CH3 OCHO
25⫺24 v7 ⫽1 ᐉ⫽1 e 24共9,15兲⫺24共8,16兲 E
0.5b 0.7
OriMC⫺1
OVRO 10.4 m
Sut85
Laf78
7.4f
SgrB2共N兲
SEST 15 m
Num98
Oes99 Num98
227760.743*共7兲 227780.978*共10兲 227793.19* 共63兲 227814.651*共47兲
U
Formula
25共3,22兲⫺24共3,21兲 25⫺24 v6 ⫽1 ᐉ⫽1 e
14.9f 1.4 0.5
JPL01 Laf78 Xu_97
CH3 NH2
8共2兲⫺8共1兲 Ea
7.4f
SgrB2共N兲
SEST 15 m
Num98
228017.369*共5兲
CH2 CHCN
24共10,*兲⫺23共10,*兲
14.9f
SgrB2共N兲
SEST 15 m
Num98
228029.050共50兲
g⫺CH3 CH2 OH CH3 OCHO
13共3,10兲⫺12共3,9兲 vt ⫽0⫺0
6.8f
SgrB2共N兲
SEST 15 m
Num98
Pea96
228057.846*共48兲
31共4,27兲⫺31共3,28兲 A
19.4f
SgrB2共N兲
SEST 15 m
Num98
Oes99
228087.272*共5兲
CH2 CHCN
24共11,*兲⫺23共11,*兲
b
Sgr B2共N兲
SEST 15 m
Num98
CH2 CHCN CH2 CHCN unidentified
24共3,22兲⫺23共3,21兲 24共4,21兲⫺23共4,20兲
0.4 0.5
U
228090.48*共5兲 228104.55*共6兲 228114.
21.9f
OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
U
228148.
unidentified
15.9f
SgrB2共N兲
SEST 15 m
Num98
228160.312*共3兲
CH2 CHCN
24共4,20兲⫺23共4,19兲
20.7f
SgrB2共N兲
SEST 15 m
Num98
228168.235*共7兲
CH2 CHCN
24共12,*兲⫺23共12,*兲
12.0f
SgrB2共N兲
SEST 15 m
Num98
228201.34*共9兲
CH2 CHCN
24共7,*兲⫺23共7,*兲 v15 ⫽1
10.4fb
SgrB2共N兲
SEST 15 m
Num98
228203.20*共8兲
CH2 CHCN
24共6,*兲⫺23共6,*兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
228210.
unidentified
7.8f
SgrB2共N兲
SEST 15 m
Num98
228229.12*共11兲
CH2 CHCN
24共8,*兲⫺23共8,*兲 v15 ⫽1
7.7f
SgrB2共N兲
SEST 15 m
Num98
228254.01*共7兲
CH2 CHCN
24共5,20兲⫺23共5,19兲 v15 ⫽1
8.7fb
SgrB2共N兲
SEST 15 m
Num98
228255.35*共7兲
CH2 CHCN
24共5,19兲⫺23共5,18兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
228259.152*共8兲
CH2 CHCN
24共13,*兲⫺23共13,*兲
9.3f
SgrB2共N兲
SEST 15 m
Num98
228277.35*共13兲
CH2 CHCNr
24共9,*兲⫺23共9,*兲 v15 ⫽1
228302.988*共68兲 228336.474*共4兲
HCCCN CH2 CHCN
25⫺24 v7 ⫽1 ᐉ⫽1 f 16共3,14兲⫺16共2,15兲
11.7f 0.8
228341.26*共15兲
CH2 CHCN
228359.264*共11兲
CH2 CHCN
228376.92*共6兲
227998.2*共5兲
U
SgrB2共N兲
SEST 15 m
Num98
14.4f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
24共10,*兲⫺23共10,*兲 v15 ⫽1
14.5f
SgrB2共N兲
SEST 15 m
Num98
24共14,*兲⫺23共14,*兲
13.7f
SgrB2共N兲
SEST 15 m
Num98
CH2 CHCN
24共3,22兲⫺23共3,21兲 v15 ⫽1
11.0fb
Sgr B2共N兲
SEST 15 m
Num98
228382.77*共6兲
CH2 CHCN
24共4,21兲⫺23共4,20兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
228418.10* 共17兲
CH2 CHCN
24共11,*兲⫺23共11,*兲 v15 ⫽1
8.1f
SgrB2共N兲
SEST 15 m
Num98
228432.46*共6兲
CH2 CHCN
24共4,20兲⫺23共4,19兲 v15 ⫽1
9.9f
SgrB2共N兲
SEST 15 m
Num98
Laf78
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
266
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
228483.144*共10兲 228506.17* 共19兲
CH3 CH2 CN CH2 CHCN
25共2,23兲⫺24共2,22兲 24共12,*兲⫺23共12,*兲 v15 ⫽1
228544.07*共1兲 228554.323*共16兲
HCOOH CH2 CHCN
10共2,8兲⫺9共2,7兲 24共7,*兲⫺23共7,*兲 v11 ⫽1
228567.080*共16兲
CH2 CHCN
24共8,*兲⫺23共8,*兲 v11 ⫽1
228572.530*共15兲
CH2 CHCN
24共6,19兲⫺23共6,18兲 v11 ⫽1
228572.562*共15兲
CH2 CHCN
24共6,18兲⫺23共6,17兲 v11 ⫽1
228585.100*共2兲
CH2 CHCN
24共16,8兲⫺23共16,7兲
228585.100*共2兲
CH2 CHCNr CH2 CHCN
24共9,*兲⫺23共9,*兲 v11 ⫽1
228617.52*共11兲
CH3 CHO
16共3,14兲⫺16共2,15兲 A⫹⫺ vt ⫽1
7.3f
228628.792*共20兲
CH3 OCHO
18共5,13兲⫺17共5,12兲 E
1.2
228600.629*共19兲
U
U
U
U
U
228639.
unidentified
228643.101*共15兲
CH2 CHCN
24共5,20兲⫺23共5,19兲 v11 ⫽1
228644.871*共15兲
CH2 CHCN
24共5,19兲⫺23共5,18兲 v11 ⫽1
228651.391*共21兲 228658.140*共50兲
CH3 OCHO CH3 COOH
18共5,13兲⫺17共5,12兲 A 21共*,21兲⫺20共*,20兲 E
228664.910*共51兲
CH3 OCHO
39共9,31兲⫺39共8,32兲 A
228690.
unidentified
228691.770*共50兲
CH3 COOH
21共*,21兲⫺20共*,20兲 A
228711.497*共25兲
CH2 CHCN
24共11,*兲⫺23共11,*兲 v11 ⫽1
Source
Telescope
Astr. Ref.
0.9
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
11.9f
SgrB2共N兲
SEST 15 m
Num98
11.0fb
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
6.2fb
SgrB2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
9.9f
SgrB2共N兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
Kle96
OVRO 10.4 m BIMA Array
Sut85 Rem02
Oes99
0.79e
OriMC⫺1 W51e2
10.8fb
9.3f 0.4 9.9f
Lab. Ref.
Wil80
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
1.2 1.29e
OriMC⫺1 W51e2
OVRO 10.4 m BIMA Array
Sut85 Rem02
Oes99 Ily00
8.2f
SgrB2共N兲
SEST 15 m
Num98
Oes99
0.60e
W51e2
BIMA Array
Rem02
1.18e
W51e2
BIMA Array
Rem02
7.7f
SgrB2共N兲
SEST 15 m
Num98
Ily00
228729.780共50兲
CH3 SH
9共1兲⫺8共1兲E
6.4f
SgrB2共N兲
SEST 15 m
Num98
228769.585*共15兲
CH2 CHCN
24共3,22兲⫺23共3,21兲 v11 ⫽1
6.8f
SgrB2共N兲
SEST 15 m
Num98
228784.156*共32兲
CH2 CHCN
24共12,*兲⫺23共12,*兲 v11 ⫽1
5.8f
SgrB2共N兲
SEST 15 m
Num98
228795.024*共15兲
CH2 CHCN
24共4,21兲⫺23共4,20兲 v11 ⫽1
11.1f
SgrB2共N兲
SEST 15 m
Num98
228797.449*共24兲
CH3 CH2 CN
0.3
228821.74* 共15兲
HCCCN
14共2,12兲⫺13共1,13兲 25⫺24 v7 ⫽0 ᐉ⫽0
16.8f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Laf78
228858.41*共11兲
HCCCN
25⫺24 v7 ⫽2 ᐉ⫽2 e
31.6f
SgrB2共N兲
SEST 15 m
Num98
Laf78
228897.81*共16兲
HCCCN
25⫺24 v7 ⫽2 ᐉ⫽2 f
SgrB2共N兲
SEST 15 m
Num98
Laf78
228910.492*共7兲 228921.
DNC unidentified
3⫺2
23.1f 0.23 2.2f
OriMC⫺1 SgrB2共N兲
MMWO 4.9 m SEST 15 m
Lor84b Num98
228958.200*共56兲
CH2 CHCN
24共14,*兲⫺23共14,*兲 v11 ⫽1
228975.
unidentified
229058.385*共75兲
CH2 CHCN
229079.981*共4兲 229086.99*共5兲 229128.901*共43兲
4.9f
SgrB2共N兲
SEST 15 m
Num98
8.6f
SgrB2共N兲
SEST 15 m
Num98
24共15,*兲⫺23共15,*兲 v11 ⫽1
9.1f
SgrB2共N兲
SEST 15 m
Num98
CH2 CHCN
17共3,15兲⫺17共2,16兲
SgrB2共N兲
SEST 15 m
Num98
CH2 CHCN NH2 CHO
24共3,21兲⫺23共3,20兲 24共2,22兲⫺24共2,23兲
8.8f 0.3 5.8f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Sas86
229203.10*共16兲
H13CCCN
26⫺25
20.7f
SgrB2共N兲
SEST 15 m
Num98
Laf78
229224.133*共29兲
CH3 OCHO
23共9,14兲⫺23共8,15兲 A
5.9f
SgrB2共N兲
SEST 15 m
Num98
Oes99
229235.
unidentified
229259.200*共32兲
CH3 OCHO
23共9,14兲⫺23共8,15兲 E
229265.168*共10兲 229300.18*共6兲
CH3 CH2 CN CH2 CHCN
26共2,25兲⫺25共2,24兲 24共3,21兲⫺23共3,20兲 v15 ⫽1
5.0f
SgrB2共N兲
SEST 15 m
Num98
2.8b 0.7
OriMC⫺1
JCMT 15 m
Gre91
OriMC⫺1
OVRO 10.4 m
Sut85 Num98
Oes99
SEST 15 m
10共2,9兲⫺9共2,8兲
5.1f n.r.
SgrB2共N兲
SiC2 CH3 NH2
IRC⫹10216
IRAM 30 m
Cer91b
Cer91b
4共⫺2兲⫺4共1兲 Ea
6.8f
SgrB2共N兲
SEST 15 m
Num98
Num98
229320.057*共35兲
CH3 OCHO
23共9,15兲⫺23共8,16兲 E
JCMT 15 m
Gre91
Oes99
11共5,7兲⫺12共4,8兲 23共9,15兲⫺23共8,16兲 A 18共3,15兲⫺17共3,14兲 E
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m JCMT 15 m OVRO 10.4 m
Sut85 Gre91 Sut85
Oes99 Oes99
18共3,15兲⫺17共3,14兲 A 16共1,15兲⫺15共2,14兲 A⫺⫺
1.3
229429.075*共36兲
SO2 CH3 OCHO CH3 OCHO CH3 OCHO CH3 CHO
1.5b 1.9 0.8 1.2
OriMC⫺1
229347.629*共6兲 229388.813*共29兲 229405.001*共20兲 229420.343*共20兲
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Kle96
229432.106*共10兲
CH3 CHO
11共⫺1,11兲⫺12共0,10兲 E
6.5fb
SgrB2共N兲
SEST 15 m
Num98
Kle96
229453.5*共5兲
CH3 NH2
7共⫺2兲⫺7共1兲 Es
2.2f
SgrB2共N兲
SEST 15 m
Num98
Num98
6.5f 0.3
229304.7共10兲 229310.8*共5兲
U
24共16,9兲⫺23共16,8兲
T r 共K兲/T a 共K兲
29
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
SgrB2共M兲
SEST 15 m
Num98
5.0b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m JCMT 15 m
Sut85 Gre91
Xu_97 Oes99
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
0.2 19.3fb
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
4.1f
SgrB2共N兲
SEST 15 m
Num98
229468.
unidentified
229474.005*共28兲 229491.130*共18兲
CH3 OCHO
20共3,17兲⫺19共4,16兲 E
t⫺CH3 CH2 OH CH3 OCHO NH2 CHO
17共5,12兲⫺17共4,13兲 20共3,17兲⫺19共4,16兲 A 2共2,0兲⫺1共1,1兲
229545.283*共10兲
SO2
13共2,12兲⫺13共1,13兲 v2 ⫽1
11.7f
229589.073*共24兲
15共4,11兲⫺16共3,13兲 E 19共3,17兲⫺18共2,16兲 E
1.3
229590.456*共17兲
CH3 OH CH3 OCHO
229595.036*共21兲
CH3 OCHO
19共3,17兲⫺18共2,16兲 A
229647.75*共9兲 229647.843*共4兲
CH2 CHCN CH2 CHCN
25共1,25兲⫺24共1,24兲 25共1,25兲⫺24共1,24兲
229711.260*共9兲
NH2 CHO
10共2,9兲⫺10共1,10兲
229504.723*共32兲 229533.060*共7兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
8.9f 0.3 2.1f
MICROWAVE TRANSITIONS
267
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
229758.811*共15兲 229775.029*共10兲
CH3 OH CH3 CHO
8共⫺1,8兲⫺7共0,7兲 E 11共1,11兲⫺10共0,10兲 A⫹⫹
229802. 229857.618*共8兲
U
229864.221*共46兲 229893.
Source
Telescope
Astr. Ref.
Lab. Ref.
10.0f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Xu_97 Kle96
3.4f 1.1
SgrB2共N兲
SEST 15 m
Num98
4共2,2兲⫺3共1,3兲
OriMC⫺1
OVRO 10.4 m
Sut85
19共5,15兲⫺20共4,16兲 A⫹
0.4
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Xu_97
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Xu_97
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Xu_97
3.2f
unidentified 34
SO2 CH3 OH unidentified
10.6
19共5,14兲⫺20共4,17兲 A⫺
U
229991.
CH3 OH Unidentified
8.7f 0.5
CH3 OH unidentified
3共⫺2,2兲⫺4共⫺1,4兲 E
U
230027.002*共13兲 230074.
2.4f 5.1
230092.78*共7兲
CH2 CHCN
25共1,25兲⫺24共1,24兲 v15 ⫽1
230093.
unidentified
230106.215*共16兲
CH2 CHCN
230140.140*共10兲 230141.425*共8兲
229939.180*共46兲
U
U U
8.5f
SgrB2共N兲
SEST 15 m
Num98
3.2f
SgrB2共N兲
SEST 15 m
Num98
25共1,25兲⫺24共1,24兲 v11 ⫽1
12.0f
SgrB2共N兲
SEST 15 m
Num98
CH3 OCH3
25共4,22兲⫺25共3,23兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
CH3 OCH3
25共4,22兲⫺25共3,23兲 EE
6.2fb
SgrB2共N兲
SEST 15 m
Num98
Gro98
230142.710*共14兲
CH3 OCH3
25共4,22兲⫺25共3,23兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
230159.
unidentified
4.4f
SgrB2共N兲
SEST 15 m
Num98
3.2f
SgrB2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
SgrB2共N兲
SEST 15 m
Num98
Gro98
230175.
unidentified
230232.166*共14兲
CH3 OCH3
17共2,15兲⫺16共3,14兲 AA
230233.749*共8兲
CH3 OCH3
17共2,15兲⫺16共3,14兲 EE
230235.333*共10兲
CH3 OCH3
17共2,15兲⫺16共3,14兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
230293.862*共29兲
CH3 OCHO
22共9,13兲⫺22共8,14兲 A
3.8f
SgrB2共N兲
SEST 15 m
Num98
Oes99
230301.924*共7兲
CH3 CHO
12共2,11兲⫺11共2,10兲 A⫺⫺
11.7f
SgrB2共N兲
SEST 15 m
Num98
Kle96
230315.788*共7兲
CH3 CHO
12共⫺2,11兲⫺11共⫺2,10兲 E
SgrB2共N兲
SEST 15 m
Num98
Kle96
230317.500*共10兲
O13CS CH3 OH CH3 CHO
19⫺18
15.7f 0.5
OriMC⫺1
OVRO 10.4 m
Sut85
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
OriMC⫺1 IRC⫹10216
OVRO10.4m IRAM 30 m
Sut85 Cer91b
NRAO 11 m OVRO 10.4 m SEST 15 m
Phi77 Sut85 Num98
JPL01 JPL01
230368.199*共89兲 230395.155*共14兲 U
230468. 230512.7*共11兲
unidentified
230538.000共1兲 230738.48*共8兲 230793.506*共13兲
CO CH2 CHCN
230793.506*共13兲 230793.905*共30兲
30
SiC2
22共4,18兲⫺21共5,17兲 E 12共2,11兲⫺11共2,10兲 A⫺⫺ vt ⫽1 10共4,6兲⫺9共4,5兲
20.4fb
0.2 4.1f 0.4 n.r. 70. 0.4
g⫺CH3 CH2 OH
2⫺1 25共0,25兲⫺24共0,24兲 6共5,1兲⫺5共4,1兲 vt ⫽0⫺1
3.3fb
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
g⫺CH3 CH2 OH
6共5,2兲⫺5共4,2兲 vt ⫽0⫺1
b
Sgr B2共N兲
SEST 15 m
Num98
AlF
7⫺6
7.20f
IRC⫹10216
IRAM 30 m
Gue95
230808.374*共4兲
CH2 CHCN
24共1,24兲⫺23共0,23兲
2.9f
SgrB2共N兲
SEST 15 m
Num98
230841.38*共6兲
CH2 CHCN
24共1,23兲⫺23共1,22兲 v15 ⫽1
3.0f
SgrB2共N兲
SEST 15 m
Num98
U
230879.
unidentified
3.2f
SgrB2共N兲
SEST 15 m
Num98
U
230894.
unidentified
3.2f
SgrB2共N兲
SEST 15 m
Num98
16共5,11兲⫺16共4,12兲
4.3f
SgrB2共N兲
SEST 15 m
Num98
230965.245*共5兲
t⫺CH3 CH2 OH SO2
37共10,28兲⫺38共9,29兲
2.5f
SgrB2共M兲
SEST 15 m
Num98
230991.377*共15兲
t⫺CH3 CH2 OH
14共0,14兲⫺13共1,13兲
4.4f
SgrB2共N兲
SEST 15 m
Num98
231060.991*共2兲
OCS CH2 CHCN
19⫺18 24共1,23兲⫺23共1,22兲 v11 ⫽1
0.80
231101.164*共16兲
7.8f
OriMC⫺1 SgrB2共N兲
FCRAO 14 m SEST 15 m
Sch84 Num98
231145.708*共16兲
CH2 CHCN
25共0,25兲⫺24共0,24兲 v11 ⫽1
7.1f
SgrB2共N兲
SEST 15 m
Num98
231187.598*共25兲
CH3 OCHO
21共9,13兲⫺21共8,14兲 E
3.7f
SgrB2共N兲
SEST 15 m
Num98
Oes99
231199.267*共28兲
CH3 OCHO CH3 OCHO
21共9,12兲⫺21共8,13兲 A 21共9,12兲⫺21共8,13兲 E
0.3
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Oes99
13 CS CH3 OCHO
5⫺4
0.7
OriMC⫺1
MMWO 4.9 m
Mun84a
231231.996*共37兲
29共4,26兲⫺29共3,27兲 A
6.5b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
231231.996*共37兲
CH3 OCHO
29共4,26兲⫺29共3,27兲 E
OriMC⫺1
JCMT 15 m
Gre91
Oes99
231239.071*共28兲 231266.0 231281.150*共15兲 231310.439*共10兲
CH3 OCHO unidentified CH3 OH
21共9,13兲⫺21共8,14兲 A
CH3 CH2 CN
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m JCMT 15 m MMWO 4.9 m OVRO 10.4 m
Sut85 Gre91 Mun84a Sut85
Oes99
10共2,9兲⫺9共3,6兲 A⫺ 26共1,25兲⫺25共1,24兲
2.0b 0.4 1.2 0.4
231312.305*共11兲
CH3 CH2 CN
27共0,27兲⫺26共1,26兲
0.9b
OriMC⫺1
OVRO 10.4 m
Sut85
231313.238*共14兲
CH3 CH2 CN
24共2,23兲⫺23共1,22兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
231321.635 共50兲
N 2 D⫹ CH3 CHO
3⫺2
0.17
rhoOphB2
MMWO 4.9 m
Lor85
Sas81
12共5,8兲⫺11共5,7兲 A⫹⫹
2.1fb
SgrB2共N兲
SEST 15 m
Num98
Kle96
231329.790*共7兲
CH3 CHO
12共5,7兲⫺11共5,6兲 A⫺⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Kle96
231342.0 231363.289*共7兲
unidentified CH3 CHO
1.0 12共⫺5,7兲⫺11共⫺5,6兲 E
3.0f
OriMC⫺1 SgrB2共N兲
JCMT 15 m SEST 15 m
Gre91 Num98
Kle96
231369.834*共8兲
CH3 CHO
12共5,8兲⫺11共5,7兲 E
SgrB2共N兲
SEST 15 m
Num98
Kle96
231410.259*共15兲 231414.485*共42兲 231456.738*共7兲
D2 CO CH3 OCHO CH3 CHO
4共0,4兲⫺3共0,3兲 35共10,25兲⫺35共9,26兲 A 12共4,9兲⫺11共4,8兲 A⫺⫺
2.1f 0.12 0.5
OriMC⫺1 OriMC⫺1 SgrB2共N兲
NRAO 12 m JCMT 15 m SEST 15 m
Tur90a Gre91 Num98
Oes99 Kle96
230953.787*共17兲
231199.267*共28兲 231220.768*共48兲
U
231329.636*共7兲
U
Xu_97 Kle96
b
3.1f
JPL01
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
268
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Astr. Ref.
Lab. Ref. Kle96
12共4,8兲⫺11共4,7兲 A⫹⫹
2.4f
SgrB2共N兲
SEST 15 m
Num98
12共4,8兲⫺11共4,7兲 E
SgrB2共N兲
SEST 15 m
Num98
Kle96
231505.59*共1兲 231506.297*共7兲
HCOOH CH3 CHO
10共1,9兲⫺9共1,8兲 12共⫺4,9兲⫺11共⫺4,8兲 E
2.2f 0.8
OriMC⫺1 SgrB2共M兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Wil80 Kle96
231558.513*共22兲
t⫺CH3 CH2 OH
21共5,17兲⫺21共4,18兲
1.5fb
SgrB2共N兲
SEST 15 m
Num98
231560.877*共21兲
20共5,16兲⫺20共4,17兲
b
Sgr B2共N兲
SEST 15 m
Num98
231595.269*共7兲
t⫺CH3 CH2 OH CH3 CHO
12共3,10兲⫺11共3,9兲 A⫹⫹
6.0f
SgrB2共N兲
SEST 15 m
Num98
Kle96
231657.892*共82兲
CH3 OCHO
27共3,25兲⫺27共2,26兲 A
2.4f
SgrB2共N兲
SEST 15 m
Num98
Oes99
231668.733共50兲
g⫺CH3 CH2 OH
14共1,14兲⫺13共1,13兲 vt ⫽0⫺0
2.6f
SgrB2共N兲
SEST 15 m
Num98
Pea96
18
CH3 OH
5共⫺1,5兲⫺4共⫺1,4兲 E
4.9f
SgrB2共N兲
SEST 15 m
Num98
Hos96
231737.593*共20兲
t⫺CH3 CH2 OH CH3 CHO
19共5,15兲⫺19共4,16兲
4.9f
SgrB2共N兲
SEST 15 m
Num98
231748.722*共7兲
12共⫺3,10兲⫺11共⫺3,9兲 E
6.2f
SgrB2共N兲
SEST 15 m
Num98
231756.783*共4兲
CH2 CHCN
26共0,26兲⫺25共1,25兲
4.1f
SgrB2共N兲
SEST 15 m
Num98
CH3 18OH
5共0,5兲⫺4共0,4兲 A⫹⫹
4.2f
SgrB2共N兲
SEST 15 m
Num98
3.0f
SgrB2共N兲
SEST 15 m
Num98 Num98
231765.
unidentified
Hos96
t⫺CH3 CH2 OH
22共5,18兲⫺22共4,19兲
10.0f
SgrB2共N兲
SEST 15 m
CH3 18OH
5共2,4兲⫺4共2,3兲 A⫺⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Hos96
231802.70*共7兲
CH3 18OH unidentified
5共3,2兲⫺4共3,1兲 E
4.4fb
SgrB2共N兲
SEST 15 m
Num98
Hos96
5.1f
SgrB2共N兲
SEST 15 m
Num98
CH3 18OH NH2 CHO
5共1,4兲⫺4共1,3兲 E
8.5f
SgrB2共N兲
SEST 15 m
Num98
17共1,16兲⫺17共0,17兲
8.5f
SgrB2共N兲
SEST 15 m
Num98
231843.6*共5兲
CH3 NH2
9共⫺2兲⫺9共1兲 Aa⫺⫹
17.5f
SgrB2共N兲
SEST 15 m
Num98
Num98
231847.575*共7兲
CH3 CHO
12共3,9兲⫺11共3,8兲 E
4.8f
SgrB2共M兲
SEST 15 m
Num98
Kle96
231854.217*共11兲
CH3 CH2 CN
1.1
231864.68*共4兲
CH3 18OH unidentified
27共1,27兲⫺26共1,26兲 5共2,3兲⫺4共2,2兲 E
6.3f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Hos96
4.1f
SgrB2共N兲
SEST 15 m
Num98 Num98
231815.
231884.
Hos96
231924.246*共14兲
CH3 C15N
13共2兲⫺12共2兲
4.1f
SgrB2共N兲
SEST 15 m
231937.396*共15兲
CH3 C15N CH3 OCHO
13共1兲⫺12共1兲
b
Sgr B2共N兲
SEST 15 m
Num98
20共9,12兲⫺20共8,13兲 E
4.2f
SgrB2共N兲
SEST 15 m
Num98
13共0兲⫺12共0兲
4.2fb 0.3
SgrB2共N兲
SEST 15 m
Num98
0.4b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m NRAO 12 m
Sut85 Tur88b
Oes99
b
OriMC⫺1
OVRO 10.4 m
Tur87b
Kle96
1.0
NRAO 12 m SEST 15 m
Tur87b Num98
Oes99
231952.27*共5兲 231966.913*共28兲
CH3 C15N CH2 CHCN CH3 OCHO
24共2,22兲⫺23共2,21兲 20共9,11兲⫺20共8,12兲 A
231968.385*共7兲
CH3 CHO
12共3,9兲⫺11共3,8兲 A⫺⫺
231975. 231980.516*共14兲
unidentified SO2
14共3,11兲⫺14共2,12兲 v2 ⫽1
13.2f
OriMC⫺1 SgrB2共M兲
231987.779*共6兲
CH3 OCH3
13共0,13兲⫺12共1,12兲 AA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
231987.856*共6兲
CH3 OCH3
13共0,13兲⫺12共1,12兲 EE
3.2b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
231987.933*共6兲
CH3 OCH3
13共0,13兲⫺12共1,12兲 AE⫹EA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
231990.414*共11兲
CH3 CH2 CN CH3 NH2
27共0,27兲⫺26共0,26兲
1.1
OriMC⫺1
OVRO 10.4 m
Sut85
5共2兲⫺5共1兲 Es
5.0f 0.2
232004.2*共5兲 U
232008. 232034.630*共19兲
U
232041. 232075.864*共16兲 232077.197*共27兲 232107. 232125.120*共23兲
unidentified t⫺CH3 CH2 OH unidentified t⫺CH3 CH2 OH
unidentified
U
232163. 232164.355*共21兲
unidentified
Tur87b Num98
8.8f
OriMC⫺1 SgrB2共N兲
NRAO12m SEST 15 m
Tur87b Num98
6.1f
13共6兲⫺12共6兲
8.8f
SgrB2共N兲
SEST 15 m
Num98
8.9f
SgrB2共N兲
SEST 15 m
Num98
13共5兲⫺12共5兲
7.3f
SgrB2共N兲
SEST 15 m
Num98
24共2,22兲⫺23共2,21兲 v15 ⫽1
5.1f
SgrB2共N兲
SEST 15 m
Num98
13.5f 0.8
SgrB2共N兲
SEST 15 m
Num98
OVRO 10.4 m SEST 15 m
Sut85 Num98
13
232157.
Num98
0.2
CH3 CN
U
SEST 15 m NRAO12 m SEST 15 m
共U234831兲 15共5,10兲⫺15共4,11兲
13
232131.86*共7兲
SgrB2共N兲 OriMC⫺1 SgrB2共N兲
18共5,14兲⫺18共4,15兲
unidentified CH3 CN CH2 CHCN
13
CH3 CN
13共4兲⫺12共4兲
8.9f
OriMC⫺1 SgrB2共N兲
232194.888*共21兲
13
13共3兲⫺12共3兲
0.7
OriMC⫺1
OVRO 10.4 m
Sut85
232216.706*共21兲
13
CH3 CN
13共2兲⫺12共2兲
0.5
OriMC⫺1
OVRO 10.4 m
Sut85
232229.801*共22兲
13
CH3 CN
13共1兲⫺12共1兲
0.5
OriMC⫺1
OVRO 10.4 m
Sut85
232234.166*共22兲
13
13共0兲⫺12共0兲
0.6
OriMC⫺1
OVRO 10.4 m
Sut85
SgrB2共N兲
SEST 15 m
Num98
5共6兲⫺4共5兲
14.4f 0.3
OriMC⫺1
OVRO 10.4 m
Sut85
11共2,10兲⫺10共2,9兲
16.4f
SgrB2共N兲
SEST 15 m
Num98
232262. 232265.878*共56兲 232273.628*共7兲
U
Kle96
231801.15*共5兲
231941.783*共15兲
U
3.3f
231735.994*共34兲
231938.592*共25兲
U
Telescope
CH3 CHO
231828.544*共27兲
U
Source
CH3 CHO
231826.68*共4兲
U
T r 共K兲/T a 共K兲
231467.499*共7兲
231790.000*共23兲
U
Quantum numbers
231484.373*共7兲
231758.66*共4兲 U
Formula
CH3 CN
CH3 CN unidentified S18O NH2 CHO
Num98
4.3f
SgrB2共N兲
SEST 15 m
Num98
23共5,19兲⫺23共4,20兲
4.4f
SgrB2共N兲
SEST 15 m
Num98
232328.051*共56兲
t⫺CH3 CH2 OH HCCCHO
22共2,21兲⫺22共1,22兲
2.8f
SgrB2共N兲
SEST 15 m
Num98
232343.860*共71兲
CH3 CHO
12共3,10兲⫺11共3,9兲 A⫹⫹ vt ⫽2
3.1fb
SgrB2共N兲
SEST 15 m
Num98
Kle96
232347.41*共24兲
CH3 CHO
12共1,11兲⫺11共1,10兲 E vt ⫽2
b
Sgr B2共N兲
SEST 15 m
Num98
Kle96
232305. 232318.469*共27兲
unidentified
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
269
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Telescope
Astr. Ref.
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Sut85
SgrB2共N兲
SEST 15 m
Num98
Quantum numbers
T r 共K兲/T a 共K兲
Source
5.9f 3.9 3.0f
U
232364.
unidentified CH3 OH unidentified
10共2,8兲⫺9共3,7兲 A⫹
U
232418.571*共16兲 232478. 232491.366共50兲
g⫺CH3 CH2 OH CH3 CH2 CN
14共0,14兲⫺13共0,13兲 vt ⫽0⫺0
5.9f
SgrB2共N兲
SEST 15 m
Num98
27共1,27兲⫺26共0,26兲
9.0f
SgrB2共N兲
SEST 15 m
Num98
SiC2
10共2,9兲⫺9共2,8兲
n.r. 2.3f
IRC⫹10216 SgrB2共N兲
IRAM 30 m SEST 15 m
Cer91b Num98
232532.326*共11兲 232534.078*共43兲 U
U
232566.
CH3 CHO
12共3,9兲⫺11共3,8兲 A⫺⫺ vt ⫽1
3.3f
SgrB2共N兲
SEST 15 m
Num98
Kle96
19共9,11兲⫺19共8,12兲 E
3.3f
SgrB2共N兲
SEST 15 m
Num98
Oes99
2.7f
SgrB2共N兲
SEST 15 m
Num98
g⫺CH3 CH2 OH CH3 OCHO
14共1,14兲⫺13共0,13兲 vt ⫽1⫺1
2.9f
SgrB2共N兲
SEST 15 m
Num98
Pea96
19共9,10兲⫺19共8,11兲 A
3.9fb
SgrB2共N兲
SEST 15 m
Num98
Oes99
232625.203*共25兲
CH3 OCHO
19共9,11兲⫺19共8,12兲 A
Oes99
232635.
unidentified
232588.
unidentified
NH2 CHO
Sgr B2共N兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
2.7f
SgrB2共N兲
SEST 15 m
Num98
unidentified
1.5f
SgrB2共N兲
SEST 15 m
Num98
U
232679.
unidentified
1.5f
SgrB2共N兲
SEST 15 m
Num98
2.8f
VYCMa
IRAM 30 m
Men89
3.1f
SgrB2共N兲
SEST 15 m
Num98 Num98
H2 O
232686.70共5兲 232714.
unidentified
232728.
unidentified
232735.750*共34兲
13
232740.086*共36兲
13
232751.
unidentified
232783.591*共33兲 U
232790.038*共10兲 232836.
CH3 OH CH3 CH2 CN unidentified
U
232866.
unidentified
U
232883.
unidentified
232928.552*共15兲 232945.835*共19兲 232962.337*共10兲
U
U
t⫺CH3 CH2 OH CH3 OH CH3 CH2 CN
1.6f
SgrB2共N兲
SEST 15 m
14共1兲⫺13共1兲
b
Sgr B2共N兲
SEST 15 m
Num98
14共0兲⫺13共0兲
1.6fb
SgrB2共N兲
SEST 15 m
Num98
18共3,16兲⫺17共4,13兲 A⫹ 26共3,24兲⫺25共3,23兲
3.7f 1.4 1.1
SgrB2共N兲
SEST 15 m
Num98
1.3f
OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
2.5f
SgrB2共N兲
SEST 15 m
Num98
2.0f
SgrB2共N兲
SEST 15 m
Num98
14共5,9兲⫺14共4,10兲
12.0f
SgrB2共N兲
SEST 15 m
Num98
10共⫺3,8兲⫺11共⫺2,10兲 E 26共10,*兲⫺25共10,*兲
3.0
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
b
CH3 CH2 CN
26共9,*兲⫺25共9,*兲
OVRO 10.4 m
CH3 CH2 CN CH3 CH2 CN
26共11,*兲⫺25共11,*兲
1.2b 0.8
OriMC⫺1
232975.519*共11兲 232998.747*共10兲
OriMC⫺1
OVRO 10.4 m
Sut85
26共8,*兲⫺25共8,*兲
1.1b
OriMC⫺1
OVRO 10.4 m
Sut85
233002.694*共12兲
CH3 CH2 CN
26共12,*兲⫺25共12,*兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
233041.083*共12兲 233069.310*共9兲
CH3 CH2 CN CH3 CH2 CN
26共13,*兲⫺25共13,*兲
0.4
OriMC⫺1
OVRO 10.4 m
Sut85
1.0
233069.371*共9兲
CH3 CH2 CN
26共7,20兲⫺25共7,19兲 26共7,19兲⫺25共7,18兲
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
b
233082.338*共53兲
CH3 OCHO
22共4,18兲⫺21共5,17兲 A
12.0f
SgrB2共N兲
SEST 15 m
Num98
233088.868*共13兲
CH3 CH2 CN
26共14,*兲⫺25共14,*兲
0.5
OVRO 10.4 m SEST 15 m
Sut85 Num98
Bel87a
Xu_97
Xu_97
Oes99
233104.
unidentified
1.6f
OriMC⫺1 SgrB2共N兲
233122.063*共24兲
CH3 OCHO
18共9,10兲⫺18共8,11兲 E
0.9f
SgrB2共N兲
SEST 15 m
Num98
Oes99
233140.770*共28兲
CH3 OCHO
18共9,9兲⫺18共8,10兲 E
SgrB2共N兲
SEST 15 m
Num98
Oes99
233144.815*共13兲 233155.
CH3 CH2 CN unidentified
26共15,*兲⫺25共15,*兲
6.6f 0.4
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
233182.649*共43兲
CH3 OCHO
19共18,*兲⫺18共18,*兲 E
3.4f
SgrB2共N兲
SEST 15 m
Num98
233205.049*共9兲
CH3 CH2 CN
26共6,21兲⫺25共6,20兲
1.5b
OriMC⫺1
OVRO 10.4 m
Sut85
233207.322*共9兲
CH3 CH2 CN
26共6,20兲⫺25共6,19兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
233208.054*共14兲
CH3 CH2 CN
26共16,*兲⫺25共16,*兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
233212.742*共17兲
CH3 OCHO
19共4,15兲⫺18共4,14兲 E
SgrB2共N兲
SEST 15 m
Num98
Oes99
233222.161*共45兲
CH3 OCHO
19共17,3兲⫺18共17,2兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
233226.782*共17兲
19共4,16兲⫺18共4,15兲 A 19共16,*兲⫺18共16,*兲 A
1.1
233246.776*共32兲
CH3 OCHO CH3 OCHO
5.1fb
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Oes99
233255.951*共35兲
CH3 OCHO
19共16,3兲⫺18共16,2兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
233268.593*共37兲
CH3 OCHO
19共16,4兲⫺18共16,3兲 E
1.2f
SgrB2共N兲
SEST 15 m
Num98
Oes99
233277.959*共15兲
CH3 CH2 CN
26共17,*兲⫺25共17,*兲
3.7f
SgrB2共N兲
SEST 15 m
Num98
10共5,5兲⫺11共4,8兲
3.6f
SgrB2共M兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Oes99 Kle96
34
SO2
5.3f
233300.
unidentified
233310.095*共28兲 233331.186*共32兲
CH3 OCHO CH3 OCHO
19共15,*兲⫺18共15,*兲 A 19共15,5兲⫺18共15,4兲 E
CH3 CHO
7共3,4兲⫺7共2,5兲 E
233341.700*共15兲 U
CH3 CCH
5共5,0兲⫺6共4,3兲 v2 ⫽1
232967.585*共10兲
233296.403*共9兲 U
CH3 CCH
20共6,15兲⫺21共5,16兲
b
3.0f
232672.
232653.277*共74兲
U
Cer91b
CH3 OCHO
U
U
Pea96
232579.320*共24兲
232617.144*共25兲
U
Xu_97
232576.449*共13兲
232596.554共50兲
U
unidentified
Lab. Ref.
233348.
unidentified
233354.062*共16兲
CH3 CH2 CN CH3 NH2
233367.2*共5兲
18.6fb
3.0f 0.4 1.8f 3.8f
SgrB2共N兲
SEST 15 m
Num98
1.9f
SgrB2共M兲
SEST 15 m
Num98
26共18,*兲⫺25共18,*兲
13.3f
SgrB2共N兲
SEST 15 m
Num98
7共⫺2兲⫺7共1兲 As⫺⫹
4.6f
SgrB2共N兲
SEST 15 m
Num98
Oes99
Num98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
270
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Formula
233384.
unidentified
233394.627*共25兲 233396.592*共29兲
CH3 CCHO CH3 OCHO
Quantum numbers 19共14,*兲⫺18共14,*兲 A 19共14,5兲⫺18共14,4兲 E
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
SgrB2共N兲
SEST 15 m
Num98
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
6.9f 0.4
233406.633*共4兲
CH2 CHCN
21共3,19兲⫺21共2,20兲
5.4f
SgrB2共N兲
SEST 15 m
Num98
233414.421*共28兲
CH3 OCHO
19共14,6兲⫺18共14,5兲 E
4.1f
SgrB2共N兲
SEST 15 m
Num98
233443.092*共9兲
CH3 CH2 CN
26共5,22兲⫺25共5,21兲
0.7 13.1f
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
6.8f
SgrB2共N兲
SEST 15 m
Num98
17.4fb
SgrB2共N兲
SEST 15 m
Num98
U
233456.
unidentified
U
233472.
unidentified
233488.839*共24兲
NH2 CHO
11共8,3兲⫺10共8,2兲
233488.839*共24兲
NH2 CHO
11共8,4兲⫺10共8,3兲
b
Sgr B2共N兲
SEST 15 m
Num98
233492.634*共30兲
NH2 CHO
11共9,2兲⫺10共9,1兲
b
Sgr B2共N兲
SEST 15 m
Num98
233492.634*共30兲
NH2 CHO
11共9,3兲⫺10共9,2兲
b
Sgr B2共N兲
SEST 15 m
Num98
233498.016*共19兲
NH2 CHO
11共7,4兲⫺10共7,3兲
SgrB2共N兲
SEST 15 m
Num98
233498.016*共19兲
NH2 CHO
11共7,5兲⫺10共7,4兲
233498.299*共9兲 233504.883*共28兲
CH3 CH2 CN CH3 OCHO
26共5,21兲⫺25共5,20兲 19共13,6兲⫺18共13,5兲 E
233505.489*共37兲
NH2 CHO
11共10,1兲⫺10共10,0兲
27.1fb b
Sgr B2共N兲
SEST 15 m
Num98
0.8 b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
Oes99
NH2 CHO
11共10,2兲⫺10共10,1兲
b
Sgr B2共N兲
SEST 15 m
Num98
233506.658*共24兲 233523.507*共20兲 233524.618*共24兲
CH3 OCHO CH3 CH2 CN CH3 OCHO NH2 CHO
19共13,*兲⫺18共13,*兲 A 26共20,*兲⫺25共20,*兲
0.8 0.5
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Oes99
19共13,7兲⫺18共13,6兲 E 11共6,6兲⫺10共6,5兲
0.4
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
35.0fb
NH2 CHO
11共6,5兲⫺10共6,4兲
b
Sgr B2共N兲
SEST 15 m
Num98
U
233542.
unidentified
17.5f
SgrB2共N兲
SEST 15 m
Num98
U
233552.
unidentified
12.6f
SgrB2共N兲
SEST 15 m
Num98
U
233561.
unidentified
6.6f
SgrB2共N兲
SEST 15 m
Num98
233527.748*共15兲
13共5,8兲⫺13共4,9兲
10.6f
SgrB2共N兲
SEST 15 m
Num98
233594.395*共11兲
t⫺CH3 CH2 OH NH2 CHO
11共5,7兲⫺10共5,6兲
40.1fb
SgrB2共N兲
SEST 15 m
Num98
233594.533*共11兲
NH2 CHO
11共5,6兲⫺10共5,5兲
b
Sgr B2共N兲
SEST 15 m
Num98
10.0f
SgrB2共N兲
SEST 15 m
Num98
233571.082*共14兲
U
Oes99 Oes99
233505.489*共37兲
233527.747*共15兲
U
Lab. Ref.
233612.
unidentified
14.0f
SgrB2共N兲
SEST 15 m
Num98
0.4b
OriMC⫺1
OVRO 10.4 m
Sut85
17共9,9兲⫺17共8,10兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
25共5,20兲⫺25共4,21兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
233622.
unidentified
233627.079*共24兲
CH3 OCHO
17共9,8兲⫺17共8,9兲 A
233628.394*共24兲
CH3 OCHO
233631.654*共14兲
CH3 OCH3
Oes99
233632.284*共10兲
CH3 OCH3
25共5,20兲⫺25共4,21兲 EE
7.2fb
SgrB2共N兲
SEST 15 m
Num98
Gro98
233632.912*共16兲
CH3 OCH3
25共5,20兲⫺25共4,21兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
233649.811*共25兲
19共12,7兲⫺18共12,6兲 E 26共4,23兲⫺25共4,22兲 19共12,*兲⫺18共12,*兲 A 19共12,8兲⫺18共12,7兲 E
0.5 1.1 1.1 0.3 7.6f
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Sut85 Sut85 Num98
Oes99
233654.072*共10兲 233655.310*共21兲 233670.944*共21兲 233698.
CH3 OCHO CH3 CH2 CN CH3 OCHO CH3 OCHO unidentified
233724.934*共9兲
SO2
16共1,15兲⫺15共2,14兲 v2 ⫽1
7.9f
SgrB2共M兲
SEST 15 m
Num98
233734.694*共9兲
NH2 CHO
11共4,8兲⫺10共4,7兲
26.5f
SgrB2共N兲
SEST 15 m
Num98
233745.594*共9兲
NH2 CHO
11共4,7兲⫺10共4,6兲
20.2f
SgrB2共N兲
SEST 15 m
Num98
233753.910*共20兲 233777.515*共21兲 233795.799*共32兲 233827.515*共18兲
CH3 OCHO CH3 OCHO CH3 OH CH3 CH2 CN
18共4,14兲⫺17共4,13兲 E 18共4,14兲⫺17共4,13兲 A 18共3,15兲⫺17共4,14兲 A⫺ 8共4,5兲⫺7共3,4兲
0.8 0.8 1.0 9.9fb
OriMC⫺1 OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Sut85 Num98
233842.851*共18兲
CH3 CH2 CN
8共4,4兲⫺7共3,5兲
SgrB2共N兲
SEST 15 m
Num98
233845.126*共24兲 233854.263*共21兲 233867.128*共20兲 233896.552*共8兲
CH3 OCHO CH3 OCHO CH3 OCHO NH2 CHO
19共11,8兲⫺18共11,7兲 E 19共11,*兲⫺18共11,*兲 A 19共11,9兲⫺18共11,8兲 E
13.7fb 0.5 0.7 0.4
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
11共3,9兲⫺10共3,8兲
22.9f
SgrB2共N兲
SEST 15 m
Num98
U
233916.
unidentified
6.6f
SgrB2共N兲
SEST 15 m
Num98
U
233945.
unidentified
19.4f
SgrB2共N兲
SEST 15 m
Num98
U
Oes99 Oes99 Oes99
OS18O
24共2,22兲⫺24共1,23兲
5.5f
SgrB2共M兲
SEST 15 m
Num98
233951.264*共14兲
t⫺CH3 CH2 OH CH3 OCHO
13共5,9兲⫺13共4,10兲
2.5f
SgrB2共M兲
SEST 15 m
Num98
16共9,8兲⫺16共8,9兲 E
3.4f
SgrB2共N兲
SEST 15 m
Num98
8.0f
SgrB2共N兲
SEST 15 m
Num98
16共9,7兲⫺16共8,8兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
5共1,5兲⫺4共1,4兲 A⫹
0.76b
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97 Oes99
233968.
unidentified
234011.357*共24兲
CH3 OCHO
234011.614*共8兲
U
Oes99 Oes99 Xu_97
233949.985*共34兲
233958.904*共24兲 U
Oes99 Oes99
13
234011.838*共24兲
CH3 OH CH3 OCHO
234033.
unidentified
234051.178*共13兲 234112.250*共21兲
t⫺CH3 CH2 OH CH3 OCHO
16共9,8兲⫺16共8,9兲 A
12共5,7兲⫺12共4,8兲 19共10,9兲⫺18共10,8兲 E
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
OriMC⫺1
OVRO 10.4 m
Sut85
4.6f
SgrB2共N兲
SEST 15 m
Num98
4.1f 0.3
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
Oes99
MICROWAVE TRANSITIONS
271
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
Quantum numbers
Source
Telescope
Astr. Ref.
Lab. Ref.
234124.880*共20兲
CH3 OCHO
19共10,10兲⫺18共10,9兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
CH3 OCHO
19共10,9兲⫺18共10,8兲 A
0.6b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
234134.590*共20兲
CH3 OCHO SO2 CH3 CHO
0.6 1.6 5.4f
OriMC⫺1 OriMC⫺1 SgrB2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
Oes99
234187.054*共19兲 234198.322*共16兲
19共10,10兲⫺18共10,9兲 E 28共3,25兲⫺28共2,26兲 4共3,1兲⫺4共2,2兲E
1.8f
SgrB2共N兲
SEST 15 m
Num98
234220.
unidentified
Kle96
234231.584*共4兲
CH3 CH2 CN
42共6,36兲⫺42共5,37兲
2.1f
SgrB2共N兲
SEST 15 m
Num98
234255.270*共13兲
12共5,8兲⫺12共4,9兲
7.8f
SgrB2共N兲
SEST 15 m
Num98
234273.001*共24兲
t⫺CH3 CH2 OH CH3 OCHO
15共9,7兲⫺15共8,9兲 E
4.5f
SgrB2共N兲
SEST 15 m
Num98
Oes99
234281.184*共21兲
CH3 OCH3
28共3,26兲⫺27共4,23兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
9.7bf
SgrB2共N兲
SEST 15 m
Num98
Gro98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
0.6
OVRO 10.4 m SEST 15 m
Sut85 Num98
JPL01
234282.346*共20兲
CH3 OCH3
28共3,26兲⫺27共4,23兲 EE
234283.508*共20兲
CH3 OCH3
28共3,26兲⫺27共4,23兲 AE⫹EA
234291. 234315.482*共8兲
unidentified NH2 CHO
11共3,8兲⫺10共3,7兲
17.1f
OriMC⫺1 SgrB2共N兲
234328.779*共24兲
CH3 OCHO
15共9,*兲⫺15共8,*兲 A
8.3f
SgrB2共N兲
SEST 15 m
Num98
Oes99
CH3 CHO
19共2,17兲⫺19共1,18兲 A⫹⫺ vt ⫽2
3.9f
SgrB2共N兲
SEST 15 m
Num98
Kle96
16.2f
SgrB2共N兲
SEST 15 m
Num98
234357.
unidentified
U
234380.
unidentified CH3 CHO unidentified
6共⫺3,4兲⫺6共⫺2,5兲 E
U
234385.736*共14兲 234390. 234401.335*共87兲
CH3 CHO
234406.456*共13兲
t⫺CH3 CH2 OH SO2 CH3 CH2 CN
18共⫺2,17兲⫺18共⫺1,18兲 E 11共5,6兲⫺11共4,7兲
234421.567*共6兲 234423.951*共10兲
2.5f 12.0 2.5f 12.0
16共6,10兲⫺17共5,13兲
8.1f 1.5
26共4,22兲⫺25共4,21兲
b
SgrB2共M兲
SEST 15 m
Num98
Sgr B2共N兲 SgrB2共M兲
SEST 15 m SEST 15 m
Num98 Num98
Kle96
Sgr B2共N兲 SgrB2共N兲
SEST 15 m SEST 15 m
Num98 Num98
Kle96
OriMC⫺1
OVRO 10.4 m
Sut85
OriMC⫺1
OVRO 10.4 m
Sut85
AlF
7⫺6
IRAM 30 m
Gue95
Gue95
CH3 CHO CH3 OCHO CH3 OCHO
7共⫺3,5兲⫺7共⫺2,6兲 E 19共9,10兲⫺18共9,9兲 E
0.29f 12.0 0.6
IRC⫹10216
234486.196*共14兲 234486.388*共20兲 234502.250*共20兲
Sgr B2共N兲 OriMC⫺1
SEST 15 m OVRO 10.4 m
Num98 Sut85
Kle96 Oes99
19共9,11兲⫺18共9,10兲 A
1.1b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
234502.441*共20兲
CH3 OCHO
19共9,10兲⫺18共9,9兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
234508.552*共17兲 234512.0共15兲
CH3 OCHO unidentified
19共9,11兲⫺18共9,10兲 E
0.6
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
0.2f
IRC⫹10216
IRAM 30 m
Gue95
234529.290*共24兲
CH3 OCHO
14共9,6兲⫺14共8,7兲 E
9.9f
SgrB2共N兲
SEST 15 m
Num98
SiC2
10共8,*兲⫺9共8,*兲
16.0f
IRC⫹10216
IRAM 30 m
Gue95
14共9,5兲⫺14共8,6兲 E
2.8f
SgrB2共N兲
SEST 15 m
Num98
Oes99
9共1,9兲⫺8共0,8兲 E vt ⫽1
1.8f
SgrB2共N兲
SEST 15 m
Num98
Xu_97
234433.1*共5兲
U
T r 共K兲/T a 共K兲
234124.885*共20兲
234338.2*共23兲 U
Formula
234533.9*共1兲 234550.208*共14兲 234560.936*共27兲
CH3 OCHO 13
CH3 OH
Oes99
U
234578.
unidentified
2.0f
SgrB2共N兲
SEST 15 m
Num98
U
234592.
unidentified
4.1f
SgrB2共N兲
SEST 15 m
Num98
234631.323*共27兲
CH3 CH2 CN
36共3,33兲⫺35共4,32兲
1.4f
SgrB2共N兲
SEST 15 m
Num98
234666.157*共14兲
t⫺CH3 CH2 OH CH3 OH CH3 OH
10共5,5兲⫺10共4,6兲
SgrB2共N兲
SEST 15 m
Num98
4共2,3兲⫺5共1,4兲A⫺ 5共⫺4,2兲⫺6共⫺3,4兲 E
4.3f 2.6 1.2
10共5,6兲⫺10共4,7兲
5.2f
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
Xu_97 Xu_97
234726.538*共16兲
t⫺CH3 CH2 OH CH3 OCHO
OriMC⫺1 OriMC⫺1 SgrB2共N兲
20共4,17兲⫺19共3,16兲 E
2.7f
SgrB2共N兲
SEST 15 m
Num98
Oes99
234735.557*共25兲
CH3 OCHO
13共9,5兲⫺13共8,6兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
234737.458*共29兲
CH3 OCHO
9共5,5兲⫺8共4,4兲 A
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
234739.082*共17兲 234758.793*共23兲
CH3 OCHO
20共2,18兲⫺19共3,17兲 A 6共3,4兲⫺5共2,3兲
0.5 1.8
OriMC⫺1 OriMC⫺1
OVRO 10.4 m NRAO 12 m
Sut85 Tur87b
Oes99
8共⫺3,6兲⫺8共⫺2,7兲 E
234683.451*共17兲 234698.467*共21兲 234714.797*共14兲
U
U
234781.701*共14兲
t⫺CH3 CH2 OH CH3 CHO
234783.367*共28兲
CH3 OCHO
234784.006*共35兲 234795.450*共8兲
0.70b
OriMC⫺1
NRAO 12 m
Tur87b
Kle96
9共5,4兲⫺8共4,4兲 E
b
OriMC⫺1
NRAO 12 m
Tur87b
Oes99
CH3 OCHO
9共5,5兲⫺8共4,5兲 E
b
OriMC⫺1
NRAO 12 m
Tur87b
Oes99
CH3 CHO
12共2,10兲⫺11共2,9兲 E
b
OriMC⫺1
NRAO 12 m
Tur87b
Kle96
234797.130*共28兲
CH3 OCHO
13共9,4兲⫺13共8,5兲 A
0.90b
OriMC⫺1
NRAO 12 m
Tur87b
Oes99
234797.144*共28兲
CH3 OCHO
13共9,5兲⫺13共8,6兲 A
234812.988*共15兲 234825.875*共8兲 234831. 234842.780*共13兲 234852.866*共15兲
SiS CH3 CHO
13⫺12 v⫽1 12共2,10兲⫺11共2,9兲 A⫹⫹
unidentified CH3 CHO
共U232041兲 6共3,3兲⫺6共2,4兲 A
t⫺CH3 CH2 OH
9共5,4兲⫺8共4,5兲
234859. 234873.877*共15兲
9共5,5兲⫺9共4,6兲
NRAO 12 m
Tur87b
Oes99
NRAO 12 m NRAO 12 m
Tur87a Tur87b
Kle96
0.2 0.2
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Tur87b Tur87b
Kle96
0.7
OriMC⫺1
NRAO 12 m
Tur87b
2.6f
SgrB2共N兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1 SgrB2共N兲
NRAO 12 m NRAO 12 m SEST 15 m
Tur87b Tur87b Num98
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Tur87b Tur87b
234916.770*共29兲 234930.
t⫺CH3 CH2 OH CH3 CH2 CN CH3 OCHO unidentified
14共3,12兲⫺13共2,11兲 9共5,4兲⫺8共4,5兲 A
3.7f 0.2 0.4
234935.69共10兲 234955.295*共10兲
PN HNCS
5⫺4 20共1,19兲⫺10共1,18兲
2.6f 0.400 0.3
234882.481*共17兲 U
unidentified
OriMC⫺1 IRC⫹10216 OriMC⫺1
b
0.060 0.2
Oes99 Wys72
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
272
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
Formula
Quantum numbers 12共9,3兲⫺12共8,4兲 A
b
OriMC⫺1
NRAO 12 m
Tur87b
Oes99
12共9,4兲⫺12共8,5兲 A
0.3b
OriMC⫺1
NRAO 12 m
Tur87b
Oes99
234984.050*共16兲
t⫺CH3 CH2 OH
8共5,3兲⫺8共4,4兲
3.0f
SgrB2共N兲
SEST 15 m
Num98
234992.183*共16兲
t⫺CH3 CH2 OH unidentified
8共5,4兲⫺8共4,5兲
3.8f
SgrB2共N兲
SEST 15 m
Num98
SgrB2共N兲
SEST 15 m
Num98
235029.886*共20兲 235046.506*共17兲 235051.295*共17兲
CH3 OCHO CH3 OCHO CH3 OCHO
19共8,11兲⫺18共8,10兲 E 19共8,12兲⫺18共8,11兲 A 19共8,12兲⫺18共8,11兲 E
2.2f 1.2 0.6
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Oes99 Oes99 Oes99
235051.402*共17兲
CH3 OCHO t⫺CH3 CH2 OH
6.7fb
OriMC⫺1 SgrB2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
235073.313*共18兲
19共8,11兲⫺18共8,10兲 A 7共5,2兲⫺7共4,3兲
235076.038*共18兲
t⫺CH3 CH2 OH unidentified
7共5,3兲⫺7共4,4兲
235105.060*共26兲
c⫺C2 H4 O
235105.093*共26兲
c⫺C2 H4 O HOCO⫹
11共2,10兲⫺10共2,9兲
235002.
235085.
Num98
SEST 15 m
Num98
8共0,8兲⫺7共1,7兲
0.27b
Sgr B2共N兲
SEST 15 m
Dic97
8共1,8兲⫺7共0,7兲
b
Sgr B2共N兲
SEST 15 m
Dic97
1.8fb
SgrB2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
9.3fb
SgrB2共N兲
SEST 15 m
Num98
6共5,2兲⫺6共4,1兲
b
Sgr B2共N兲
SEST 15 m
Num98
4共2,2兲⫺3共1,3兲
1.0 5.5fb
OriMC⫺1 SgrB2共N兲
MMWO 4.9 m SEST 15 m
Lor84a Num98
b
Sgr B2共N兲
SEST 15 m
Num98
5.0f
SgrB2共N兲
SEST 15 m
Num98
11共2,9兲⫺10共2,8兲 6共5,1兲⫺6共4,2兲
235131.372*共20兲
t⫺CH3 CH2 OH
235151.704*共7兲 235166.771*共21兲
SO2 t⫺CH3 CH2 OH
5共5,0兲⫺5共4,1兲
235166.771*共21兲
t⫺CH3 CH2 OH
5共5,1兲⫺5共4,2兲
235190.393*共42兲
11共0,11兲⫺10共0,10兲 12共1,11兲⫺11共1,10兲 A⫺⫺ vt ⫽1
1.3f 0.7
unidentified
9共9,0兲⫺9共8,1兲 A
235337.1*共5兲
CH3 NH2
14共6兲⫺15共5兲 As⫺⫹
235337.2*共5兲
CH3 NH2
14共⫺6兲⫺15共⫺5兲 As⫺⫺
235340.5*共22兲
CH3 CHO
17共2,15兲⫺17共1,16兲 A⫹⫺ vt ⫽1
235371.060*共17兲
13
5共⫺2,3兲⫺4共⫺2,2兲 E vt ⫽1
13
5共2,3兲⫺4共2,2兲 A⫹⫹ vt ⫽1
235374.768*共13兲 235375.249*共70兲
CH3 OH CH3 OH
CH3 OCHO
SgrB2共N兲
SEST 15 m
Num98
Kle96
11.6f
OriMC⫺1 SgrB2共N兲
OVRO10.4m SEST 15 m
Sut85 Num98
Oes99
1.8f
SgrB2共N兲
SEST 15 m
Num98
2.2fb
SgrB2共N兲
SEST 15 m
Num98
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
Num98
2.2f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
b
Sgr B2共N兲
SEST 15 m
Num98
Xu_97 Xu_97
b
Sgr B2共N兲
SEST 15 m
Num98
11共3,8兲⫺10共2,9兲 A
4.2f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
5共2,4兲⫺4共2,3兲 A⫺⫺ vt ⫽1
4.3fb
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
235378.019*共13兲
13
235421.373*共29兲
13
5共⫺1,4兲⫺4共⫺1,3兲 E vt ⫽1
2.2f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
235450.959*共31兲
13
5共0,5兲⫺4共0,4兲 A⫹⫹ vt ⫽1
3.8f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
7.3f
Sgr B2共N兲
SEST 15 m
Num98
12.6f
Sgr B2共N兲
SEST 15 m
Num98
6.3f
Sgr B2共N兲
SEST 15 m
Num98
235483. 235509.39* 共14兲 235524. 235532.357*共54兲
CH3 OH CH3 OH CH3 OH
unidentified 26⫺25
HC13CCN unidentified
26⫺25
HCC13CN
235541.
unidentified
235549.
unidentified
235563.82*共6兲
CH2 CHCN
235613.029*共14兲
13
25共2,24兲⫺24共2,23兲 5共1,4兲⫺4共1,3兲 A⫺⫺ vt ⫽1
Laf78
4.6f
Sgr B2共N兲
SEST 15 m
Num98
3.2f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
3.1f 0.3
Sgr B2共N兲
SEST 15 m
Num98
5.0f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
5.3f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
Xu_97
235629.949*共89兲
CH3 OH CH3 CHO
235713.323*共12兲
CH3 OCH3
235714.475*共10兲
CH3 OCH3
26共4,22兲⫺26共3,24兲 EE
4.4fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
235715.627*共14兲
CH3 OCH3
26共4,22兲⫺26共3,24兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
235731.
unidentified
3.0f
Sgr B2共M兲
SEST 15 m
Num98
8共⫺2兲⫺8共1兲 Aa
7.8f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
M17SW
CSO 10.4 m
Lat93
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla84 Bla84
Oes99 Oes99
235734.9*共5兲
18共2,17兲⫺18共1,18兲 A⫺⫹ 26共4,22兲⫺26共3,24兲 AE⫹EA
CH3 NH2
Num98
235784.
unidentified
235789.641 共30兲
CO⫹ unidentified
3/2,2⫺1/2,1
8.2f 0.1
CH3 OCHO CH3 OCHO
19共7,13兲⫺18共7,12兲 A 19共7,13兲⫺18共7,12兲 E
6.4f 0.54 0.48
13 CH3 OH CH3 OCHO unidentified
5共0,5兲⫺4共0,4兲 E
0.60
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
235887.063*共20兲 235904.
19共7,12兲⫺18共7,11兲 E
0.54
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla84 Num98
Oes99
235917.
unidentified
235800. 235844.542*共17兲 235865.878*共17兲 235881.179*共8兲
U
SEST 15 m
SgrB2共N兲
HOCO⫹
235300.
U
Sgr B2共N兲
t⫺CH3 CH2 OH
U
U
b
2.4f
235119.827*共46兲
unidentified CH3 OCHO
U
b
1.2
235131.372*共20兲
235261. 235263.319*共40兲
U
Lab. Ref.
CH3 OCHO
235217.832*共17兲
U
Astr. Ref.
CH3 OCHO
U
U
Telescope
234963.018*共29兲
HOCO⫹ CH3 CHO
U
Source
234963.022*共29兲
235114.260*共46兲
U
T r 共K兲/T a 共K兲
235927.489*共9兲 235932.376*共17兲 235938.210*共8兲
235961.331*共18兲
5.1f 0.59
Sgr B2共N兲
SEST 15 m
Num98
5共2,4兲⫺4共1,3兲
OriMC⫺1
OVRO 10.4 m
Bla84
19共7,12兲⫺18共7,11兲 A 5共⫺1,5兲⫺4共⫺1,4兲 E
0.47 0.68
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla84 Bla84
SO2
10共3,7兲⫺10共2,8兲
0.71
OriMC⫺1
OVRO 10.4 m
Bla84
CH3OH SiS
5共0,5兲⫺4共0,4兲 A⫹
0.71
OriMC⫺1
OVRO 10.4 m
Bla84
13⫺12
0.39
IRC⫹10216
MMWO 4.9 m
Sah84
34
SO2 CH3 OCHO 13
CH3 OH
235951.915*共10兲 235960.390*共8兲
4.0f
34 13
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Sas81b
Oes99 Xu_97
Xu_97
MICROWAVE TRANSITIONS
273
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
0.25b
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
5共4,1兲⫺4共4,0兲 A⫹
b
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
235978.630*共9兲
13
5共⫺4,2兲⫺4共⫺4,1兲 E
0.12
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
14共1,14兲⫺13共0,13兲
22.8f
Sgr B2共N兲
SEST 15 m
Num98
5共4,1兲⫺4共4,0兲 E
b
OriMC⫺1
OVRO 10.4 m
Bla84
12共1,11兲⫺11共1,10兲 E
15.5f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
CH3 OH CH3 OH
t⫺CH3 CH2 OH
235994.432*共10兲
13
235996.202*共8兲
CH3 CHO
235997.100*共8兲
13
5共3,3兲⫺4共3,2兲 A⫹
0.72b
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
235997.431*共8兲
13
5共3,2兲⫺4共3,1兲 A⫺
OVRO 10.4 m
Bla84
Xu_97
13
5共3,2兲⫺4共3,1兲 E
0.72b 0.35
OriMC⫺1
236006.170*共8兲
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
236008.434*共7兲
13
5共2,4兲⫺4共2,3兲 A⫺
0.65
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
236016.581*共8兲
13
5共⫺3,3兲⫺4共⫺3,2兲 E
0.36
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
236041.416*共8兲
13
Xu_97
CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH
236049.136*共8兲
CH3 OH CH3 CHO
236049.534*共7兲
13
236062.064*共8兲
13
CH3 OH CH3 OH CO⫹
13
CH3 OH
236102.128*共14兲
D2 CO
236146.424*共18兲
t⫺CH3 CH2 OH CH2 CHCN
5共1,4兲⫺5共1,3兲 E
0.56
OriMC⫺1
OVRO 10.4 m
Bla84
14.8f 0.41
Sgr B2共N兲
SEST 15 m
Num98
Kle96
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
M17SW
NRAO 12 m
Lat93
Sas81b Xu_97
5共2,3兲⫺4共2,2兲 A⫹ 5共⫺2,4兲⫺2共⫺2,3兲 E 3/2,2⫺1/2,1
0.92b
OriMC⫺1
OVRO 10.4 m
Bla84
4共2,2兲⫺3共2,1兲 15共1,14兲⫺14共2,13兲
0.53 6.8f
IRAS16293⫺2422 Sgr B2共N兲
IRAM 30 m SEST 15 m
Cec98 Num98
25共2,24兲⫺24共2,23兲 v11 ⫽1
25.4f
Sgr B2共N兲
SEST 15 m
Num98
13.5f 1.1
Sgr B2共N兲
SEST 15 m
Num98
11.3f 0.18
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor81a Num98
IRC⫹10216
IRAM 30 m
Cer89
5.7f
Sgr B2共M兲
SEST 15 m
Num98
236216.685*共7兲 236229.170*共17兲
SO2 CH3 CH2 CN
16共1,15兲⫺15共2,14兲 31共2,29兲⫺30共3,28兲
SiC
3⌸ 2 6⫺5e, f 20共7,13兲⫺21共6,16兲
SO2
b
0.1
5共2,3兲⫺4共2,2兲 E
unidentified
34
Xu_97
12共1,11兲⫺11共1,10兲 A⫺⫺
236184.
Cer89
6共3,3兲⫺5共2,4兲
7.9f
Sgr B2共N兲
SEST 15 m
Num98
11共0,11兲⫺10共1,10兲 A⫹⫹
15.2f 0.9 0.7
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
236365.562*共17兲 236407.9*共5兲
CH3 OH CH3 OCHO CH3 OCHO CH3 NH2
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
Oes99 Oes99 Num98
236452.297*共57兲 236512.780*共8兲 236524.8*共14兲
SO HCCCN HCCCN
1共2兲⫺2共1兲 26⫺25 26⫺25 v5 ⫽1 ᐉ⫽1 e
8.1f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m MMWO 4.9 m SEST 15 m
Sut85 Lor81 Num98
Laf78
2.4f
Sgr B2共N兲
SEST 15 m
Num98
8.3f
Sgr B2共N兲
SEST 15 m
Num98
23.6f 0.4 1.1 0.6 0.6 0.6 0.8
Sgr B2共N兲
SEST 15 m
Num98
Laf78
OVRO 10.4 m MMWO 4.9 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Lor84a Sut85 Sut85 Sut85 Sut85 Num98
Wil80
11.6f
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
236299.039*共22兲 236353.064*共39兲 236355.911*共16兲
t⫺CH3 CH2 OH 13
236553.
unidentified
236642.
unidentified
20共3,18兲⫺19共3,17兲 E 20共3,18兲⫺19共3,17兲 A 6共⫺2兲⫺6共1兲 As
HCCCN
26⫺25 v5 ⫽1 ᐉ⫽1 f
236717.20*共1兲 236726.33* 共27兲 236743.645*共17兲 236759.683*共17兲 236800.513*共17兲 236810.327*共17兲 236844.005*共25兲
HCOOH H2 CS CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO NH2 CHO
11共1,11兲⫺10共1,10兲 7共1,7兲⫺6共1,6兲 19共5,15兲⫺18共5,14兲 E 19共5,15兲⫺18共5,14兲 A 19共6,14兲⫺18共6,13兲 E 19共6,14兲⫺18共6,13兲 A 24共3,21兲⫺24共2,22兲
236852.
unidentified
236653.4*共14兲
10.1f 0.4 0.8
Oes99 Oes99 Oes99 Oes99
4.3f
Sgr B2共N兲
SEST 15 m
Num98
236902.16* 共72兲
HCCCN
26⫺25 v6 ⫽1 ᐉ⫽1 e
15.1f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
236936.168*共29兲
14共1,13兲⫺13共2,12兲 A⫺ 50共5,46兲⫺50共4,47兲
2.3
236974.518*共6兲
CH3 OH CH3 CH2 CN
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Xu_97 JPL01
236977. 237046.080*共8兲
unidentified CH3 OCH3
7共2,5兲⫺6共1,6兲 AE
b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Gro98
237046.094*共8兲
CH3 OCH3
7共2,5兲⫺6共1,6兲 EA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
237048.836*共6兲
CH3 OCH3
7共2,5兲⫺6共1,6兲 EE
1.5b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
237051.586*共10兲
CH3 OCH3
7共2,5兲⫺6共1,6兲 AA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
237068.819*共7兲
SO2
237093.183*共79兲 237095.785*共23兲
HCCCN NH2 CHO
12共3,9兲⫺12共2,10兲 26⫺25 v7 ⫽1 ᐉ⫽1 e 23共3,20兲⫺23共2,21兲
0.9 0.8
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m OVRO 10.4 m SEST 15 m
Lei84a Sut85 Num98
Laf78
237129.23* 共19兲
CH3 OH CH3 NH2
22共1,21兲⫺22共0,22兲 E 2共⫺2兲⫺2共⫺1兲 Ea
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Xu_97 Num98
SiC2
10共4,7兲⫺9共4,6兲 25共8,18兲⫺26共7,19兲
IRC⫹10216 OriMC⫺1
IRAM 30 m JCMT 15 m
Cer91b Gre91
Cer91b
5.5f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
Sgr B2共N兲
SEST 15 m
Num98
Gro98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
0.4
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
237144.4*共5兲 237150.052*共30兲 237169.107*共25兲 U
Lab. Ref.
5共4,2兲⫺4共4,1兲 A⫺
CH3 OH
236287.610 共18兲 236295.657*共17兲
U
Astr. Ref.
13
236159.906*共16兲
U
Telescope
13
236062.854*共8兲
U
Source
235971.104*共9兲
236062.553 共20兲
U
T r 共K兲/T a 共K兲
235971.105*共9兲
235983.358*共16兲
U
Quantum numbers
34
SO2
237170.451*共10兲
CH3 CH2 CN
237216.
unidentified
237260.103*共12兲
CH3 OCH3
25共3,23兲⫺25共2,24兲 AE⫹EA
237262.593*共10兲
CH3 OCH3
25共3,23兲⫺25共2,24兲 EE
237265.082*共14兲
CH3 OCH3
25共3,23兲⫺25共2,24兲 AA
237266.959*共20兲
CH3 OCHO
21共1,20兲⫺20共2,19兲 A
26共3,23兲⫺25共3,22兲
6.3f 0.9
16.7f 0.7 3.7f n.r. b
0.9
10.0fb
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
274
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
OVRO 10.4 m
Sut85
Dub80
JCMT 15 m OVRO 10.4 m
Gre91 Sut85
Oes99
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
1.1
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
IRC⫹10216 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
IRAM 30 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Cer91b Sut85 Sut85 Num98
Cer91b Oes99 Oes99 Oes99
T r 共K兲/T a 共K兲
Source
Telescope
OC34S unidentified CH3 OCHO CH3 OCHO
20⫺19
0.5
OriMC⫺1
237288.0 237297.478*共16兲 237306.018*共17兲
20共2,18兲⫺19共2,17兲 E
2.0 0.8
OriMC⫺1 OriMC⫺1
20共2,18兲⫺19共2,17兲 A
1.1b
237309.515*共17兲
CH3 OCHO
21共2,20兲⫺20共2,19兲 E
237315.140*共20兲 237331.347*共29兲
21共2,20兲⫺20共2,19兲 A
237344.881*共17兲 237350.434*共20兲 237360.893*共11兲
CH3 OCHO SiC2 CH3 OCHO CH3 OCHO CH3 CH2 CN
10共4,7兲⫺9共4,6兲 21共1,20兲⫺20共1,19兲 E 21共1,20兲⫺20共1,19兲 A 28共1,27兲⫺27共2,26兲
n.r. 0.8 0.7
237393.188*共17兲
CH3 OCHO
21共2,20兲⫺20共1,19兲 E
237397.105*共4兲
CH2 CHCN
25共7,*兲⫺24共7,*兲
237398.615*共20兲
CH3 OCHO
21共2,20兲⫺20共1,19兲 A
237405.190*共10兲 237412.012*共4兲
CH3 CH2 CN CH2 CHCN
26共2,24兲⫺25共2,23兲 25共6,20兲⫺24共6,19兲
237412.053*共4兲
CH2 CHCN
25共6,19兲⫺24共6,18兲
237415.524*共4兲
CH2 CHCN
25共8,*兲⫺24共8,*兲
237432.049*共79兲 237456.25* 共19兲 237476.064*共13兲 237482.77*共9兲
HCCCN CH2 CHCN CH3 CH2 CN CH2 CHCN
26⫺25 v7 ⫽1 ᐉ⫽1 f 25共9,*兲⫺24共9,*兲 25共2,24兲⫺24共1,23兲 25共5,21兲⫺24共5,20兲
237485.01*共9兲
CH2 CHCN
25共5,20兲⫺24共5,19兲
237514.258*共5兲
CH2 CHCN
25共10,*兲⫺24共10,*兲 28共2,25兲⫺28共2,26兲
237521.048*共31兲 U
Lab. Ref.
Quantum numbers
237273.631共8兲 U
Astr. Ref.
Formula
34
SO2
237545.
unidentified
237585.809*共6兲
CH2 CHCN
25共11,*兲⫺24共11,*兲
237591.40*共6兲
CH2 CHCN
6.1f 2.1b
OriMC⫺1
JCMT 15 m
Gre91
26.6f
Sgr B2共N兲
SEST 15 m
Num98
b
OriMC⫺1
JCMT 15 m
Gre91
0.7
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
b
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
0.7 0.2 0.7
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m JCMT 15 m OVRO 10.4 m
Sut85 Sut85 Gre91 Sut85
b
OriMC⫺1
OVRO 10.4 m
Sut85
17.4f
Sgr B2共N兲
SEST 15 m
Num98
11.4f
Sgr B2共M兲
SEST 15 m
Num98
6.1f
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
0.4 8.4f
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
23.1fb
0.3b
Oes99
Laf78
237602.217*共38兲
SO2
25共3,23兲⫺24共3,22兲 28共3,25兲⫺28共2,26兲 v2 ⫽1
237618.821*共8兲
CH3 OCH3
9共2,8兲⫺8共1,7兲 EA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
237618.826*共8兲
CH3 OCH3
9共2,8兲⫺8共1,7兲 AE
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
237620.888*共6兲
CH3 OCH3
9共2,8兲⫺8共1,7兲 EE
0.9b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
237622.953*共8兲
CH3 OCH3
9共2,8兲⫺8共1,7兲 AA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
237638.109*共3兲
CH2 CHCN
25共4,22兲⫺24共4,21兲
11.1fb
Sgr B2共N兲
SEST 15 m
Num98
237669.176*共7兲
CH2 CHCN
25共12,*兲⫺24共12,*兲
8.9f
Sgr B2共N兲
SEST 15 m
Num98
237700.302*共13兲
11共3,8兲⫺11共2,9兲
9.8f 0.3
Sgr B2共M兲
SEST 15 m
Num98
237711.89*共7兲 237738.35* 共13兲
OS18O CH2 CHCN CH2 CHCN
3.9f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
25共4,21兲⫺24共4,20兲 25共8,*兲⫺24共8,*兲 v15 ⫽1
237751.
unidentified
6.6f
Sgr B2共N兲
SEST 15 m
Num98
237763.118*共9兲
CH2 CHCN
25共13,*兲⫺24共13,*兲
3.4f
Sgr B2共N兲
SEST 15 m
Num98
237781.47*共8兲
CH2 CHCN
25共5,21兲⫺24共5,20兲 v15 ⫽1
7.2fb
Sgr B2共N兲
SEST 15 m
Num98
237783.41*共8兲
CH2 CHCN
25共5,20兲⫺24共5,19兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
237786.32* 共16兲
CH2 CHCN
25共9,*兲⫺24共9,*兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
237807.577*共17兲 237829.829*共17兲 237851.858*共10兲 237859.71*共7兲 237866.789*共12兲
CH3 OCHO CH3 OCHO CH3 CH2 CN C4 H CH2 CHCN
19共6,13兲⫺18共6,12兲 E 19共6,13兲⫺18共6,12兲 A 27共2,26兲⫺26共2,25兲 51/2⫺49/2 25共14,11兲⫺24共14,10兲
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m MMWO 4.9 m SEST 15 m
Sut85 Sut85 Sut85 Lor84a Num98
237866.789*共12兲
CH2 CHCN
25共14,12兲⫺24共14,11兲
Sgr B2共N兲
237896.673*共7兲
NH2 CHO
11共2,9兲⫺10共2,8兲
237898.03*共7兲 237910.384*共6兲
C4 H NH2 CHO
237926.37*共7兲 237930.08* 共21兲 237968.08* 共17兲
HCCCN
26⫺25 v7 ⫽2 ᐉ⫽0
0.5 0.6 0.4 0.053 5.3fb
Oes99 Oes99
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
49/2⫺47/2
17.1f 0.055
IRC⫹10216
MMWO 4.9 m
Lor84a
10共1,10兲⫺9共0,9兲
3.3f
Sgr B2共N兲
SEST 15 m
Num98
CH2 CHCN
25共4,22兲⫺24共4,21兲 v15 ⫽1
3.6fb
Sgr B2共N兲
SEST 15 m
Num98
CH2 CHCN
25共11,*兲⫺24共11,*兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
Laf78
5共1,4兲⫺4共1,3兲 A⫺
14.6f 0.84
OriMC⫺1
OVRO 10.4 m
Bla84
Xu_97
26⫺25 v7 ⫽2 ᐉ⫽2 e
18.2f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
18.2f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
238053.90* 共19兲
H CCCN HCCCN
27⫺26 26⫺25 v7 ⫽2 ᐉ⫽2 f
8.7f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
238082.086*共16兲
CH2 CHCN
25共7,*兲⫺24共7,*兲 v11 ⫽1
10.5fb
Sgr B2共N兲
SEST 15 m
Num98
238091.646*共17兲
CH2 CHCN
25共8,*兲⫺24共8,*兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
238106.875*共16兲
CH2 CHCN
25共6,20兲⫺24共6,19兲 v11 ⫽1
9.9fb
Sgr B2共N兲
SEST 15 m
Num98
238106.927*共16兲
CH2 CHCN
25共6,19兲⫺24共6,18兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
238118.052*共32兲
CH3 OCHO
7共6,2兲⫺6共5,2兲 E
7.3f
Sgr B2共N兲
SEST 15 m
Num98
238124.055*共19兲
CH2 CHCN
25共9,*兲⫺24共9,*兲 v11 ⫽1
7.3f
Sgr B2共N兲
SEST 15 m
Num98
238155.883*共20兲
CH3 OCHO
22共1,22兲⫺21共1,21兲 E
b
OriMC⫺1
OVRO 10.4 m
Sut85
237983.445*共8兲 238009.67* 共13兲 238015.68* 共19兲
13
CH3 OH HCCCN 13
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
Oes99
Oes99
MICROWAVE TRANSITIONS
275
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
238156.319*共20兲
CH3 OCHO
22共0,22兲⫺21共0,21兲 E
2.7b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
238156.907*共21兲
CH3 OCHO
22共1,22兲⫺21共1,21兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
238157.342*共21兲
CH3 OCHO
22共0,22兲⫺21共0,21兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
238166.359*共10兲
SO2
17共3,15兲⫺18共0,18兲
9.8f
Sgr B2共M兲
SEST 15 m
Num98
238173.402*共21兲
CH2 CHCN
25共10,*兲⫺24共10,*兲 v11 ⫽1
6.7f
Sgr B2共N兲
SEST 15 m
Num98
238182.
unidentified
3.8f
Sgr B2共N兲
SEST 15 m
Num98
238189.997*共15兲
CH2 CHCN
25共5,21兲⫺24共5,20兲 v11 ⫽1
6.9fb
Sgr B2共N兲
SEST 15 m
Num98
238190.083*共34兲
CH3 OCHO
7共6,2兲⫺6共5,1兲 A
0.2b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
238190.244*共34兲
CH3 OCHO
7共6,1兲⫺6共5,2兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
238192.700*共15兲
CH2 CHCN
25共5,20兲⫺24共5,19兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
238236.388*共25兲
CH2 CHCN
25共11,*兲⫺24共11,*兲 v11 ⫽1
7.0f
Sgr B2共N兲
SEST 15 m
Num98
238296.827*共15兲
CH2 CHCN
25共3,23兲⫺24共3,22兲 v11 ⫽1
Sgr B2共N兲
SEST 15 m
Num98
238301.574 共15兲
CP
5⫺4 J⫽9/2⫺7/2 F⫽5⫺4
3.6f 0.040
IRC⫹10216
IRAM 30 m
Gue90
Sai89
238304.519 共10兲
CP
0.040
IRC⫹10216
IRAM 30 m
Gue90
Sai89
238306.335*共28兲
NH2 CHO
5⫺4 J⫽9/2⫺7/2 F⫽4⫺3 25共3,22兲⫺25共2,23兲
4.0f
Sgr B2共N兲
SEST 15 m
Num98
238316.004*共5兲
NH2 CN
12共1,12兲⫺11共1,11兲
5.0f
Sgr B2共N兲
SEST 15 m
Num98
238359.342*共15兲
CH2 CHCN
25共4,22兲⫺24共4,21兲 v11 ⫽1
7.2f
Sgr B2共N兲
SEST 15 m
Num98
238396.151*共42兲
CH2 CHCN
25共13,*兲⫺24共13,*兲 v11 ⫽1
10.1f
Sgr B2共N兲
SEST 15 m
Num98
238444.515*共15兲
CH2 CHCN
25共4,21兲⫺24共4,20兲 v11 ⫽1
9.6f
Sgr B2共N兲
SEST 15 m
Num98
238457.
unidentified
8.3f
Sgr B2共N兲
SEST 15 m
Num98
238478.230*共21兲
CH3 CN
13共12兲⫺12共12兲
6.5f
Sgr B2共N兲
SEST 15 m
Num98
238490.890*共57兲
CH2 CHCN
25共14,*兲⫺24共14,*兲 v11 ⫽1
6.0f
Sgr B2共N兲
SEST 15 m
Num98
238532.389*共10兲
NH2 CHO
11共2,10兲⫺11共1,11兲
8.3f
Sgr B2共N兲
SEST 15 m
Num98
U
238554.
unidentified
5.3f
Sgr B2共N兲
SEST 15 m
Num98
U
238559.
unidentified
3.0f
Sgr B2共N兲
SEST 15 m
Num98
6共1,5兲⫺5共0,5兲 vt ⫽1⫺0
3.0f
Sgr B2共N兲
SEST 15 m
Num98
13共11兲⫺12共11兲
6.0f
Sgr B2共N兲
SEST 15 m
Num98
6.3f
Sgr B2共N兲
SEST 15 m
Num98
5.2f
Sgr B2共N兲
SEST 15 m
Num98
12.5f
Sgr B2共N兲
SEST 15 m
Num98 Num98
238568.317*共8兲 238583.173*共18兲 U
U
238602.
unidentified
238616.830*共45兲
CH3 OCHO
238632.
unidentified
38共10,29兲⫺38共9,30兲 E
t⫺CH3 CH2 OH CH3 CN
27共5,23兲⫺27共4,24兲
11.4f
Sgr B2共N兲
SEST 15 m
238679.131*共14兲
13共10兲⫺12共10兲
13.1f
Sgr B2共N兲
SEST 15 m
Num98
238683.403*共14兲
33 SO2
5共2,4兲⫺4共1,3兲
8.2f
Sgr B2共M兲
SEST 15 m
Num98
238690.178*共4兲
CH2 CHCN
25共1,25兲⫺24共0,24兲
6.0f
Sgr B2共N兲
SEST 15 m
Num98
238697.744*共8兲
SO2
4共2,2兲⫺3共1,3兲 v2 ⫽1
6.0f
Sgr B2共M兲
SEST 15 m
Num98
238701.794*共23兲
t⫺CH3 CH2 OH CH2 CHCN CH2 CHCN
11共2,10兲⫺10共1,9兲
7.6f 0.2
Sgr B2共N兲
SEST 15 m
Num98
26共1,26兲⫺25共1,25兲 26共1,26兲⫺25共1,25兲
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
238667.995*共61兲
238726.70* 共12兲 238726.816*共4兲 238766.067*共12兲 U
g⫺CH3 CH2 OH CH3 CN
21.8f
JPL01
Oes99
CH3 CN unidentified
13共9兲⫺12共9兲
238778. 238796.22*共7兲 238826.5*共5兲
CH2 CHCN CH2 CHCN
25共3,22兲⫺24共3,21兲 25共17,*兲⫺24共17,*兲 v11 ⫽1
6.9f
238843.944*共9兲
CH3 CN
238854.779*共24兲
13共8兲⫺12共8兲 13共6兲⫺12共6兲
15.6f
238855.959共8兲
CH3 13CN CP
5⫺4 J⫽11/2⫺9/2 F⫽6⫺5
0.050
IRC⫹10216
IRAM 30 m
Gue90
Sai89
238856.932共4兲
CP
5⫺4 J⫽11/2⫺9/2 F⫽5⫺4
0.050
IRC⫹10216
IRAM 30 m
Gue90
Sai89
0.4 9.9f 0.2 0.6
U
238870.
unidentified
11.8f
Sgr B2共N兲
SEST 15 m
Num98
U
238889.
unidentified
13.1f
Sgr B2共N兲
SEST 15 m
Num98
238899.927*共22兲
NH2 CHO
22共3,19兲⫺22共2,20兲
19.3f
Sgr B2共N兲
SEST 15 m
Num98
238905.106*共16兲
CH3 13CN CH3 CN CH3 OCHO
13共5兲⫺12共5兲
19.3f
Sgr B2共N兲
SEST 15 m
Num98
13共7兲⫺12共7兲 20共3,18兲⫺19共2,17兲 E 13共4兲⫺12共4兲
0.7 0.3
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
238912.733*共7兲 238926.851*共16兲 238946.311*共11兲
U
JPL01
238972.405*共5兲 238992.491*共7兲
CH3 13CN CH3 CN SO2
239001.290*共9兲 239015.042*共10兲
Oes99
13共6兲⫺12共6兲
18.8f 0.31
OriMC⫺1
MMWO 4.9 m
Lor84
CH3 13CN
21共7,15兲⫺22共6,16兲 12共2兲⫺11共2兲
⬍0.12 0.3
OriMC⫺1 OriMC⫺1
MMWO 4.9 m OVRO 10.4 m
Lor84 Sut85
CH3 13CN CH3 OCH3
0.5b
OriMC⫺1
OVRO 10.4 m
Sut85
239019.614*共12兲
24共5,19兲⫺24共4,20兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
239019.616*共12兲
CH3 OCH3
24共5,19兲⫺24共4,20兲 EA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
239019.627*共11兲
12共0兲⫺11共0兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
239020.533*共12兲
CH3 13CN CH3 OCH3
24共5,19兲⫺24共4,20兲 EE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
239021.452*共12兲
CH3 OCH3
24共5,19兲⫺24共4,20兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
239022.937*共4兲 239046.0
CH3 CN unidentified
13共5兲⫺12共5兲
0.33 1.3
OriMC⫺1 OriMC⫺1
MMWO 4.9 m JCMT 15 m
Lor84 Gre91
12共1兲⫺11共1兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
276
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
CH3 CN CH3 CN CH3 CN
13共4兲⫺12共4兲 13共3兲⫺12共3兲 13共2兲⫺12共2兲
0.39 0.68 0.54
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Lor84 Lor84 Lor84
S18O CH3 CN CH3 CN unidentified
6共6兲⫺5共5兲
0.13
W3共IRS5兲
JCMT 15 m
Hel97
239133.317*共4兲 239137.920*共4兲 239168.
13共1兲⫺12共1兲 13共0兲⫺12共0兲
0.73 0.83
MMWO 4.9 m MMWO 4.9 m SEST 15 m
Lor84 Lor84 Num98
239179.278*共5兲 239192.03*共9兲
CH3 CCH CH2 CHCN
14共4兲⫺13共4兲
6.7f 0.16
OriMC⫺1 OriMC⫺1 Sgr B2共N兲 OriMC⫺1
MMWO 4.9 m
Lor84a
26共1,26兲⫺25共1,25兲 v15 ⫽1
6.5f
Sgr B2共N兲
SEST 15 m
Num98
239198.13*共8兲
CH2 CHCN
25共1,24兲⫺24共1,23兲 v15 ⫽1
7.1f
Sgr B2共N兲
SEST 15 m
Num98
239199.653*共16兲
CH2 CHCN
26共1,26兲⫺25共1,25兲 v11 ⫽1
10.4f
Sgr B2共N兲
SEST 15 m
Num98
239211.212*共3兲 239234.032*共2兲 239247.727*共2兲 239252.292*共2兲 239278.548*共42兲
CH3 CCH CH3 CCH CH3 CCH CH3 CCH CH3 OCHO
14共3兲⫺13共3兲 14共2兲⫺13共2兲 14共1兲⫺13共1兲 14共0兲⫺13共0兲 37共10,28兲⫺37共9,29兲 E
0.24 0.19 0.36 0.37 4.0fb
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m SEST 15 m
Lor84a Lor84a Lor84a Lor84a Num98
239282.
unidentified
4.5f
Sgr B2共N兲
SEST 15 m
Num98
239305.848*共50兲
CH3 COOH
22共*,22兲⫺21共*,21兲 E
b
W51e2
BIMA Array
Rem02
Ily00
239309.40* 共20兲
CH3 CN
13共12兲⫺12共12兲 v8 ⫽1 ᐉ⫽⫹1
0.95be
W51e2
BIMA Array
Rem02
Bou80
2.83e
W51e2
BIMA Array
Rem02
8.5f
Sgr B2共M兲
SEST 15 m
Num98
b
W51e2
BIMA Array
Rem02
5.03be
W51e2
BIMA Array
Rem02
239064.309*共3兲 239096.504*共3兲 239119.510*共4兲 239128.550*共16兲
U
U
U
U
239321.
unidentified
239336.054*共17兲 239338.771*共50兲
OS18O CH3 COOH
239344.
unidentified NH2 CN
12共2,11兲⫺11共2,10兲 v⫽1
3.8f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
CH3 NH2
4共⫺2兲⫺4共⫺1兲 Ea
7.2f
Sgr B2共N兲
SEST 15 m
Num98
Num98
239444.4*共5兲
CH3 NH2
3共2兲⫺3共1兲 Ea
4.3f
Sgr B2共N兲
SEST 15 m
Num98
Num98
239475.04* 共12兲
CH3 CN
13共8兲⫺12共8兲 v8 ⫽1 ᐉ⫽⫺1
12.4f
Sgr B2共N兲
SEST 15 m
Num98
239478.079 共50兲
g⫺CH3 CH2 OH CH3 CN
14共2,13兲⫺13共2,12兲 vt ⫽0⫺0
12.3f
Sgr B2共N兲
SEST 15 m
Num98
13共10兲⫺12共10兲 v8 ⫽1 ᐉ⫽1
6.7f
Sgr B2共N兲
SEST 15 m
Num98
g⫺CH3 CH2 OH CH3 CN
14共2,13兲⫺13共2,12兲 vt ⫽1⫺1
8.7f
Sgr B2共N兲
SEST 15 m
Num98
13共7兲⫺12共7兲 v8 ⫽1 ᐉ⫽⫺1
8.7f
Sgr B2共N兲
SEST 15 m
Num98
239554.22* 共12兲
Pea96
18
21⫺20
6.0f
Sgr B2共N兲
SEST 15 m
Num98
239570.48* 共12兲
CH3 CN
13共9兲⫺12共9兲 v8 ⫽1 ᐉ⫽1
5.2fb
Sgr B2共N兲
SEST 15 m
Num98
239609.95* 共10兲
32共5,28兲⫺32共3,29兲 A 13共6兲⫺12共6兲 v8 ⫽1 ᐉ⫽⫺1
0.9 b
OMC⫺IRc2 Sgr B2共N兲
IRAM 30 m SEST 15 m
Jac90 Num98
Plu84
239624.07* 共11兲
CH3 OCHO CH3 CN
239627.16* 共12兲 239639.45* 共10兲 239650.8 239651.
CH3 CN CH3 CN unidentified unidentified
13共1兲⫺12共1兲 v8 ⫽1 ᐉ⫽1 13共8兲⫺12共8兲 v8 ⫽1 ᐉ⫽1
0.4 0.8 0.8
OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2
OVRO 10.4 m IRAM 30 m IRAM 30 m
Sut85 Jac90 Jac90
Bou80 Bou80
239674.0 239682.806*共10兲 239684.57* 共10兲 239699.25* 共10兲 239708.28* 共11兲
unidentified CH3 CH2 CN CH3 CN CH3 CN
OCS
9.5f
Sgr B2共N兲
SEST 15 m
Num98
27共1,26兲⫺26共1,25兲 13共5兲⫺12共5兲 v8 ⫽1 ᐉ⫽⫺1 13共7兲⫺12共7兲 v8 ⫽1 ᐉ⫽1
0.6 0.7 7.2 1.6
OMC⫺IRc2 OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2
IRAM 30 m OVRO 10.4 m IRAM 30 m IRAM 30 m
Jac90 Sut85 Jac90 Jac90
Bou80 Bou80
26共0,26兲⫺25共0,25兲 16共7,10兲⫺17共6,11兲 A⫹ 16共7,9兲⫺17共6,12兲 A⫺ 13共4兲⫺12共4兲 v8 ⫽1 ᐉ⫽1 5共1,5兲⫺4共1,4兲 A⫹ 13共3兲⫺12共3兲 v8 ⫽1 ᐉ⫽⫺1
0.1 0.6 0.6 2.2 7.4 0.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 OMC⫺IRc2 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m IRAM 30 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85 Jac90 Sut85 Sut85
Xu_97 Xu_97 Bou80 Xu_97 Bou80
13共5兲⫺12共5兲 v8 ⫽1 ᐉ⫽1 12共4,8兲⫺11共4,7兲
0.2 0.4b
OriMC⫺1 OMC⫺IRc2
OVRO 10.4 m IRAM 30 m
Sut85 Jac90
Bou80 JPL01
b
239805.275*共5兲
CH2 CHCN CH3 OH CH3 OH CH3 CN CH3 OH CH3 CN CH3 CN NH2 CN
239805.275*共5兲
NH2 CN
12共4,9兲⫺11共4,8兲
OMC⫺IRc2
IRAM 30 m
Jac90
JPL01
239808.91* 共12兲 239816.08*共5兲
CH3 CN CH2 CHCN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN unidentified
13共2兲⫺12共2兲 v8 ⫽1 ᐉ⫽⫺1
0.6
OriMC⫺1
OVRO 10.4 m
Sut85
Bou80
25共1,24兲⫺24共1,23兲 13共4兲⫺12共4兲 v8 ⫽1 ᐉ⫽1 13共1兲⫺12共1兲 v8 ⫽1 ᐉ⫽⫺1 13共0兲⫺12共0兲 v8 ⫽1 ᐉ⫽1 13共3兲⫺12共3兲 v8 ⫽1 ᐉ⫽1 13共2兲⫺12共2兲 v8 ⫽1 ᐉ⫽1
0.5 0.8 0.5 0.5 0.7 0.4
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO OVRO OVRO OVRO OVRO OVRO
Sut85 Sut85 Sut85 Sut85 Sut85 Sut85
Bou80 Bou80 Bou80 Bou80 Bou80
SEST 15 m
Num98
28共0,28兲⫺27共1,27兲 12共2,10兲⫺11共2,9兲 44共8,36兲⫺44共7,37兲 E 39共8,32兲⫺39共7,33兲 A
9.0f 1.8 0.16 0.6 0.8
Sgr B2共N兲
CH3 CH2 CN NH2 CN CH3 OCHO CH3 OCHO
OMC⫺IRc2 OriMC⫺1 OMC⫺IRc2 OMC⫺IRc2
IRAM 30 m NRAO 12 m IRAM 30 m IRAM 30 m
Jac90 Tur85 Jac90 Jac90
CH3 CH2 CN NH2 CHO unidentified
23共4,20兲⫺23共2,21兲
0.6
OMC⫺IRc2
IRAM 30 m
Jac90
11共1,11兲⫺10共1,9兲
2.1 1.2
OMC⫺IRc2 OMC⫺IRc2
IRAM 30 m IRAM 30 m
Jac90 Jac90
239824.78* 共12兲 239829.96* 共13兲 239836.06* 共18兲 239850.01* 共14兲 239871.67* 共29兲 239879. 239887.277*共11兲 239908.860*共3兲 239927.456*共77兲 239935.347*共45兲 239945.202*共23兲
U
Pea96
239562.032*共8兲
239731.344*共33兲 239731.344*共33兲 239735.65* 共10兲 239746.220*共6兲 239777.19* 共11兲 239791.76* 共11兲
U
Ily00
239389.842*共4兲
239551.366 共50兲
U
22共*,22兲⫺21共*,21兲 A
Oes99
239427.5*共5兲
239492.33* 共14兲
U U
13共1,13兲⫺12共0,12兲
Lab. Ref.
239951.786*共7兲 239960.7
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m
JPL01 Oes99 Oes99
MICROWAVE TRANSITIONS
277
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U U
U
U
U
U U
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
239971.0 239974.426*共75兲
unidentified CH3 OCHO
0.4 44共8,36兲⫺44共7,37兲 A
OMC⫺IRc2 Sgr B2共N兲
IRAM 30 m SEST 15 m
Jac90 Num98
Oes99
239977.5 239984.730*共40兲
unidentified 共CH3 兲2 CO
4.5f 2.0
24共0,24兲⫺23共1,23兲 AE
b
OMC⫺IRc2 Ori⫺IRc2
IRAM 30 m IRAM 30 m
Jac90 Jac90
Vac86
239984.779*共40兲
共CH3 兲2 CO
24共0,24兲⫺23共1,23兲 EA
0.9b
Ori⫺IRc2
IRAM 30 m
Jac90
Vac86
239988.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
239991.110*共28兲
共CH3 兲2 CO 共CH3 兲2 CO unidentified CH3 OCHO CH3 OCHO unidentified
7.0f 1.4 0.5 0.4 1.0 0.15 0.5 n.r.
Ori⫺IRc2 Ori⫺IRc2 OMC⫺IRc2 OriMC⫺1 W3共H2O兲 OMC⫺IRc2 IRC⫹10216
IRAM 30 m IRAM 30 m IRAM 30 m OVRO 10.4 m JCMT 15 m IRAM 30 m IRAM 30 m
Jac90 Jac90 Jac90 Sut85 Hel97 Jac90 Cer91b
2.7f
OriMC⫺1 OMC⫺IRc2 IRAS16293⫺2422 OriMC⫺1 Sgr B2共N兲
NRAO 12 m IRAM 30 m JCMT 15 m OVRO 10.4 m SEST 15 m
Tur85 Jac90 Bla94 Sut85 Num98
239997.382*共42兲 240008.6 240021.129*共20兲 240034.638*共20兲 240045.3 240050.1共15兲 240057.476*共11兲 240079.1 240086. 240089.83*共12兲 240110.199*共41兲
10共2,8兲⫺9共2,7兲 11共5,7兲⫺12共4,8兲 v2 ⫽1
13共1兲⫺12共1兲 v8 ⫽1 ᐉ⫽1 27共2,25兲⫺27共1,26兲
0.28 0.5 0.09 0.6
Oes99 Oes99 Cer91b
Bou80
240130.311*共16兲
26共0,26兲⫺25共0,25兲 v11 ⫽1
7.3f
Sgr B2共N兲
SEST 15 m
Num98
240130.645*共4兲
NH2 CN
12共3,10兲⫺11共3,9兲
7.4fb
Sgr B2共N兲
SEST 15 m
Num98
JPL01
240132.690*共4兲
NH2 CN
12共3,9兲⫺11共3,8兲
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
240185.612*共97兲 240224.61*共8兲
CH2 CO CH2 CHCN
12共1,12兲⫺11共1,11兲 26共0,26兲⫺25共0,25兲 v15 ⫽1
0.5
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
240241.502*共17兲 240266.26* 共28兲 240319.342*共12兲 240331.43* 共16兲
CH3 OH H2 CS CH3 CH2 CN H2 CS
5共3,2兲⫺6共2,4兲 E 7共0,7兲⫺6共0,6兲 28共1,28兲⫺27共1,27兲 7共4,3兲⫺6共4,2兲
0.55 0.55 0.16
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO MMWO MMWO MMWO
Lor84a Lor84a Lor84a Lor84a
240331.43* 共16兲
H2 CS
7共4,4兲⫺6共4,3兲
0.07b
OriMC⫺1
MMWO 4.9 m
Lor84a
8.7f 0.16
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor84a Lor84a
240362. 240392.29* 共18兲
U
SiC2
SO2 unidentified unidentified CH3 CN
19共3,16兲⫺18共3,15兲 E 19共3,16兲⫺18共3,15兲 A
Vac86 Vac86
t⫺CH3 CH2 OH CH2 CHCN
240381.28* 共23兲
U
30
24共0,24兲⫺23共1,23兲 EE 24共0,24兲⫺23共1,23兲 AA
unidentified H2 CS H2 CS
7共2,6兲⫺6共2,5兲 7共3,5兲⫺6共3,4兲
13.5f
b
0.38b
4.9 4.9 4.9 4.9
m m m m
Xu_97
240392.96* 共18兲
H2 CS
7共3,4兲⫺6共3,3兲
b
OriMC⫺1
MMWO 4.9 m
Lor84a
240400.827*共50兲
CH3 OCHO
41共9,33兲⫺41共8,34兲 A
4.9fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
240408.987*共50兲
CH3 OCHO
41共9,33兲⫺41共8,34兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
240417.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
240429.189*共12兲 240435.181*共16兲
CH3 CH2 CN CH2 CHCN
9.5f 0.12 10.7f
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84a Num98
240443.
unidentified
12.0f
Sgr B2共N兲
SEST 15 m
Num98
7.6f
Sgr B2共N兲
SEST 15 m
Num98
3.2f 0.11
Sgr B2共N兲
SEST 15 m
Num98
4.0f
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84a Num98
240454.85共5兲
CH3 OH
28共0,28兲⫺27共0,27兲 25共1,24兲⫺24共1,23兲 v11 ⫽1 5共1,5兲⫺4共1,4兲 A⫹⫹ vt ⫽2
U
240471.
unidentified
U U
240473.4 240500.
unidentified unidentified
U
240516.
unidentified
6.1f
Sgr B2共N兲
SEST 15 m
Num98
U
240525.
unidentified
5.2f 0.16
Sgr B2共N兲
SEST 15 m
Num98
6.2f
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84a Num98
4.9f
Sgr B2共M兲
SEST 15 m
Num98
240548.29* 共23兲 240608.704*共26兲 240612.350*共12兲
H2 CS CH3 CHO 33
7共2,5兲⫺6共2,4兲 12共1,12兲⫺11共0,11兲 A⫹⫹ vt ⫽1 10共3,7兲⫺10共2,8兲
Her84
Kle96
U
240627.
SO2 unidentified
4.1f
Sgr B2共N兲
SEST 15 m
Num98
U
240636.
unidentified
8.4f
Sgr B2共N兲
SEST 15 m
Num98
U
240717.
unidentified
9.0f
Sgr B2共N兲
SEST 15 m
Num98
U
240729.
unidentified
5.2f
Sgr B2共N兲
SEST 15 m
Num98
U
240740.
unidentified
5.9f
Sgr B2共N兲
SEST 15 m
Num98
U
240749.
unidentified
3.2f
Sgr B2共N兲
SEST 15 m
Num98
U
240757.91共5兲
CH3 OH
5共2,3兲⫺4共2,2兲 A⫹⫹ vt ⫽2
b
Sgr B2共N兲
SEST 15 m
Num98
Her84
240757.91共5兲
CH3 OH
5共2,4兲⫺4共2,3兲 A⫺⫺ vt ⫽2
4.8b
Sgr B2共N兲
SEST 15 m
Num98
Her84
U
240776.
unidentified
2.5f
Sgr B2共N兲
SEST 15 m
Num98
U
240799.
unidentified
1.6f
Sgr B2共N兲
SEST 15 m
Num98
U
240807.
unidentified
1.9f
Sgr B2共N兲
SEST 15 m
Num98
14共1,13兲⫺13共1,12兲 vt ⫽0⫺0
6.6f
Sgr B2共N兲
SEST 15 m
Num98
240861.254*共12兲
g⫺CH3 CH2 OH CH3 CH2 CN
28共1,28兲⫺27共0,27兲
Sgr B2共N兲
SEST 15 m
Num98
240875.735*共16兲 240916.2
HNCO CH3 OH
11共1,11兲⫺10共1,10兲 5共3,3兲⫺4共3,2兲 A⫹⫹ vt ⫽2
6.3f 1.0 0.14b
OriMC⫺1 W3共H2O兲
OVRO 10.4 m JCMT 15 m
Sut85 Hel97
Xu_97
240916.2
CH3 OH
5共3,3兲⫺4共3,2兲 A⫺⫺ vt ⫽2
b
W3共H2O兲
JCMT 15 m
Hel97
Xu_97
240929.
unidentified
8.3f
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
240838.909*共17兲
U
240932.018 共20兲
CH3 OH
5共4,1兲⫺4共4,0兲 A⫹⫹ vt ⫽2
JPL01
And90
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
278
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
240932.018 共20兲
CH3 OH
5共4,2兲⫺4共4,1兲 A⫺⫺ vt ⫽2
b
Sgr B2共N兲
SEST 15 m
Num98
And90
240936.73共5兲
CH3 OH
5共⫺2,3兲⫺4共⫺2,2兲 E vt ⫽2
b
Sgr B2共N兲
SEST 15 m
Num98
Her84
240938.94共5兲
CH3 OH
5共0,5兲⫺4共0,4兲 A⫹⫹ vt ⫽2
Sgr B2共N兲
SEST 15 m
Num98
Her84
240942.788*共7兲 240948.303 共20兲
SO2 CH3 OH
18共1,17兲⫺18共0,18兲 5共3,3兲⫺4共3,2兲 E vt ⫽2
b
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lei84 Num98
And90
240952.07共5兲
CH3 OH
5共2,4兲⫺4共2,3兲 E vt ⫽2
10.5f
Sgr B2共N兲
SEST 15 m
Num98
Her84
240958.8
CH3 OH
5共⫺1,5兲⫺4共⫺1,4兲 E vt ⫽2
W3共H2O兲
JCMT 15 m
Hel97
Xu_97
CH3 OH CH3 OCH3 CH3 OCH3
5共1,5兲⫺4共1,4兲 A⫹ vt ⫽1
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Gro98 Gro98
240960.559*共9兲 240978.250*共16兲 240982.770*共8兲
5共3,3兲⫺4共2,2兲 EA 5共3,3兲⫺4共2,2兲 AE
10.3fb 0.8
0.24b 0.9 0.2
240985.067*共8兲
CH3 OCH3
5共3,3兲⫺4共2,2兲 EE
1.0b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
240989.973*共10兲
CH3 OCH3
0.7 0.83
OriMC⫺1 OriMC⫺2
OVRO 10.4 m MMWO 4.9 m
Sut85 Sne84
Gro98
241016.113*共18兲
5共3,3兲⫺4共2,2兲 AA 5⫺4
U
241113.
C34S unidentified
U
241130.
unidentified
4.6f
Sgr B2共N兲
SEST 15 m
Num98
5.8f
Sgr B2共N兲
SEST 15 m
Num98
5.8f 0.2 0.7
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Wil80 Xu_97
5共3,3兲⫺4共3,2兲 E vt ⫽1 5共4,1兲⫺4共4,0兲 A⫹ vt ⫽1
0.8 b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Xu_97 Xu_97
241142.68* 共10兲
CH3 OH
22共⫺6,16兲⫺23共⫺5,18兲 E
241146.20*共1兲 241159.144*共10兲 241166.564*共11兲
11共0,11兲⫺10共0,10兲 5共4,2兲4共4,1兲 E vt ⫽1
241178.426*共14兲
HCOOH CH3 OH CH3 OH CH3 OH
241178.426*共14兲
CH3 OH
5共4,2兲⫺4共4,1兲 A⫺ vt ⫽1
1.3b
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
241179.862*共9兲
CH3 OH
5共⫺3,2兲⫺4共⫺3,1兲 E vt ⫽1
b
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
241184.167*共11兲 241187.417*共9兲 241192.851*共9兲 241196.427*共10兲
CH3 OH CH3 OH CH3 OH CH3 OH
5共⫺4,1兲⫺4共⫺4,0兲 E vt ⫽1 5共⫺2,3兲⫺4共⫺2,2兲 E vt ⫽1 5共2,3兲4共2,2兲 A⫹ vt ⫽1 5共2,4兲⫺4共2,3兲 A⫺ vt ⫽1
1.1 1.4 1.9 2.1b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO OVRO OVRO OVRO
m m m m
Sut85 Sut85 Sut85 Sut85
Xu_97 Xu_97 Xu_97 Xu_97
241198.262*共10兲
CH3 OH
5共3,3兲⫺4共3,2兲 A⫹ vt ⫽1
b
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
241198.269*共10兲
CH3 OH
5共3,2兲⫺4共3,1兲 A⫺ vt ⫽1
b
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
241203.710*共10兲
CH3 OH
5共1,5兲⫺4共1,4兲 E vt ⫽1
b
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
241206.039*共9兲 241210.733*共11兲
CH3 OH CH3 OH
5共0,5兲⫺4共0,4兲 E vt ⫽1 5共2,4兲⫺4共2,,3兲 E vt ⫽1
2.8 1.2b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Xu_97 Xu_97
241238.108*共14兲
CH3 OH CH3 OH unidentified
5共⫺1,4兲⫺4共⫺1,3兲 E vt ⫽1 5共0,5兲⫺4共0,4兲 A⫹ vt ⫽1
0.7 0.4 7.5f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
Xu_97 Xu_97
U
241267.822*共20兲 241289.
U
241327.
unidentified
6.0f
Sgr B2共N兲
SEST 15 m
Num98
241345.3
CH2 CN
12共0,12兲⫺11共0,11兲 25/2⫺23/2
4.1f
Sgr B2共N兲
SEST 15 m
Num98
Num98
241353.3
CH2 CN
12共3兲⫺11共3兲 25/2⫺23/2
2.9f
Sgr B2共N兲
SEST 15 m
Num98
Num98
241364.12共5兲
CH3 OH
5共1,4兲⫺4共1,3兲 A⫺⫺ vt ⫽2
2.9f
Sgr B2共N兲
SEST 15 m
Num98
Her84
241365.35*共6兲
19共3,17兲⫺20共0,20兲 12共3兲⫺11共3兲 27/2⫺25/2
2.1
241381.5
CH2 CHCN CH2 CN
OMC⫺IRc2 Sgr B2共N兲
IRAM 30 m SEST 15 m
Jac90 Num98
Num98
241386.2
CH2 CN
12共2,11兲⫺11共2,10兲 25/2⫺23/2
5.0fb
Sgr B2共N兲
SEST 15 m
Num98
Num98
241391.4
CH2 CN
12共2,11兲⫺11共2,10兲 27/2⫺25/2
b
Sgr B2共N兲
SEST 15 m
Num98
Num98
10共0,10兲⫺9共1,9兲 28共2,26兲⫺28共2,27兲 A
1.7
241436.182*共77兲
HCO CH3 OCHO
OMC⫺IRc2 OMC⫺IRc2
IRAM 30 m IRAM 30 m
Jac90 Jac90
Bla84a Oes99
241437.060*共77兲
CH3 OCHO
28共2,26兲⫺28共1,27兲 A
241441.265*共10兲 241464.034*共77兲 241478.582*共4兲
CH3 OH CH3 OCHO NH2 CN
5共1,4兲4共1,3兲 A⫺ vt ⫽1 28共3,26兲⫺28共2,27兲 A 12共1,11兲⫺11共1,10兲
2.6b 1.5 1.0
241492.5
CH2 CN
12共2,10兲⫺11共2,9兲 25/2⫺23/2
241501.7*共5兲
CH3 NH2
5共⫺2兲⫺5共⫺1兲 Ea 16共1,15兲⫺15共2,14兲
241420.880 共20兲
241509.053*共9兲 241523.801*共8兲 241528.320*共14兲
U
34
SO2 CH3 OCH3 CH3 OCH3
b
b
10.4 10.4 10.4 10.4
OMC⫺IRc2
IRAM 30 m
Jac90
Oes99
6.8f
OriMC⫺1 OMC⫺IRc2 Sgr B2共N兲
OVRO 10.4 m IRAM 30 m SEST 15 m
Sut85 Jac90 Num98
Xu_97 Oes99 JPL01
9.2f
Sgr B2共N兲
SEST 15 m
Num98
Num98
11.8f
Sgr B2共N兲
SEST 15 m
Num98
Num98
0.9
OriMC⫺1
OVRO 10.4 m
Sut85
5共3,2兲⫺4共2,3兲 AE 5共3,2兲⫺4共2,3兲 EA
0.9 b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Gro98 Gro98
241528.710*共8兲
CH3 OCH3
5共3,2兲⫺4共2,3兲 EE
1.7b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
241531.009*共10兲
CH3 OCH3
5共3,2兲⫺4共2,3兲 AA
b
OriMC⫺1
OVRO 10.4 m
Sut85
Gro98
241534. 241561.550 共37兲 241581.488*共39兲
unidentified HDO NH2 CHO
2共1,1兲⫺2共1,2兲 21共2,19兲⫺20共3,18兲
0.4 1.0
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m MMWO 4.9 m SEST 15 m
Eri84b Bec82 Num98
DeL71
241590.12* 共18兲
CH3 OH
25共3,22兲⫺25共2,23兲 A⫺⫹
SEST 15 m
Num98
Xu_97
SO2 CH3 CH2 CN
5共2,4兲⫺4共1,3兲
7.5f 1.4
Sgr B2共N兲
241615.779*共7兲 241625.870*共10兲
OriMC⫺1
MMWO 4.9 m
Lor84e
27共3,25兲⫺26共3,24兲
22.9f
Sgr B2共N兲
SEST 15 m
Num98
241635.798*共16兲
CH3 OCH3
21共3,18兲⫺20共4,17兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
241635.798*共16兲
CH3 OCH3
21共3,18兲⫺20共4,17兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
241637.321*共12兲
CH3 OCH3
21共3,18兲⫺20共4,17兲 EE
0.54b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
241637.321*共12兲
CH3 OCH3
21共3,18兲⫺20共4,17兲 EE
6.1fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
7.0f
MICROWAVE TRANSITIONS
279
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
241638.824*共14兲
CH3 OCH3
21共3,18兲⫺20共4,17兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
241638.844*共14兲
CH3 OCH3
21共3,18兲⫺20共4,17兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
241638.846*共14兲
CH3 OCH3
21共3,18兲⫺20共4,17兲 EA
CH3 OH unidentified
5共0,5兲⫺4共0,4兲 E
U
241700.168*共6兲 241719.
U
241732.
unidentified
241737.567*共3兲
CH2 CHCN
241739.9 241767.247*共6兲 241774.037*共10兲 241791.367*共6兲 241806.521*共5兲
unidentified CH3 OH HNCO CH3 OH CH3 OH
241806.521*共5兲
CH3 OH
5共4,2兲⫺4共4,1兲 A⫺
241813.248*共5兲 241829.629*共6兲 241832.716*共5兲
CH3 OH CH3 OH CH3 OH
5共⫺4,2兲⫺4共⫺4,1兲 E 5共4,1兲⫺4共4,0兲 E 5共3,3兲⫺4共3,2兲 A⫹
241833.104*共5兲
CH3 OH
5共3,2兲⫺4共3,1兲 A⫺
241842.287*共6兲
CH3 OH
5共2,4兲⫺4共2,3兲 A⫺
241843.608*共5兲
CH3 OH
241852.299*共5兲
U
U
W3共H2O兲
JCMT 15 m
Hel97
Gro98
MMWO 4.9 m SEST 15 m
Lor84 Num98
Xu_97
9.1f
OriMC⫺1 Sgr B2共NW兲
9.5f
Sgr B2共N兲
SEST 15 m
Num98
20.7f 2.5 1.8 3.1 1.8
Sgr B2共N兲
SEST 15 m
Num98
OMC⫺IRc2 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
IRAM 30 m MMWO 4.9 m OVRO 10.4 m MMWO 4.9 m MMWO 4.9 m
Jac90 Lor84 Sut85 Lor84 Lor84
Xu_97 Xu_97
OriMC⫺1
MMWO 4.9 m
Lor84
Xu_97
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Lor84 Lor84 Lor84
Xu_97 Xu_97 Xu_97
1.6b
OriMC⫺1
MMWO 4.9 m
Lor84
Xu_97
b
OriMC⫺1
MMWO 4.9 m
Lor84
Xu_97
5共3,2兲⫺4共3,1兲 E
1.7b
OriMC⫺1
MMWO 4.9 m
Lor84
Xu_97
241879.038*共6兲 241887.678*共6兲 241904.158*共5兲
CH3 OH CH3 OH CH3 OH CH3 OH
5共⫺3,3兲⫺4共⫺3,2兲 E 5共1,4兲⫺4共1,3兲 E 5共2,3兲⫺4共2,2兲 A⫹ 5共⫺2,4兲⫺4共⫺2,3兲 E
0.9 1.4 1.2
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO MMWO MMWO MMWO
m m m m
Lor84 Lor84 Lor84 Lor81a
Xu_97 Xu_97 Xu_97 Xu_97
241904.643*共6兲
CH3 OH
5共2,3兲⫺4共2,2兲 E
OriMC⫺1
MMWO 4.9 m
Lor81a
Xu_97
241922.546*共11兲 241932.175*共11兲
CH3 CH2 CN CH3 CH2 CN
27共10,*兲⫺26共10,*兲 27共9,*兲⫺26共9,*兲
1.2b 0.9 1.3b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
241933.160*共12兲
CH3 CH2 CN
27共11,*兲⫺26共11,*兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
241946.245*共6兲
CH3 OCH3
13共1,13兲⫺12共0,12兲 AE⫹EA
b
OriMC⫺1
MMWO 4.9 m
Lor81a
Gro98
241946.537*共6兲
CH3 OCH3
13共1,13兲⫺12共0,12兲 EE
0.5b
OriMC⫺1
MMWO 4.9 m
Lor81a
Gro98
241946.830*共6兲
CH3 OCH3
13共1,13兲⫺12共0,12兲 AA
b
OriMC⫺1
MMWO 4.9 m
Lor81a
Gro98
241959.049*共12兲 241970.442*共10兲 241980.
CH3 CH2 CN CH3 CH2 CN unidentified
27共12,*兲⫺26共12,*兲 27共6,*兲⫺26共6,*兲
0.7 0.8
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
OriMC⫺1
OVRO 10.4 m
Sut85
8.5f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
241985.446*共9兲 U
U
241997.101*共13兲 242017.
U
b
0.8b 0.7 ⬍0.7
b
SO2 CH3 CH2 CN unidentified
8共3,5兲⫺8共2,5兲
14.9f 1.4
27共13,*兲⫺26共13,*兲
0.5
34
4.9 4.9 4.9 4.9
242045.285*共13兲
CH3 CH2 CN
27共14,*兲⫺26共14,*兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
CH3 CH2 CN
27共7,21兲⫺26共7,20兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
242052.583*共10兲
CH3 CH2 CN
27共7,20兲⫺26共7,19兲
0.8b
OriMC⫺1
OVRO 10.4 m
Sut85
242068.665*共21兲
NH2 CHO
21共3,18兲⫺21共2,19兲
15.8fb
Sgr B2共N兲
SEST 15 m
Num98
242073.408*共19兲
NH2 CHO
16共1,15兲⫺15共2,14兲
242102.219*共14兲 242106.023*共10兲
CH3 CH2 CN CH3 CHO
27共15,*兲⫺26共15,*兲 13共⫺1,13兲⫺12共⫺1,12兲 E
242118.143*共10兲
CH3 CHO
13共1,13兲⫺12共1,12兲 A⫹⫹
242143.
unidentified
Xu_97
b
Sgr B2共N兲
SEST 15 m
Num98
0.8 31.9f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Kle96
15.1f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
4.7f
Sgr B2共N兲
SEST 15 m
Num98 Num98
242159.201*共4兲
CH2 CHCN
10共2,8兲⫺9共1,9兲
SEST 15 m
CH3 CH2 CN
27共16,*兲⫺26共16,*兲
11.0f 0.2
Sgr B2共N兲
242166.935*共14兲 242175.455 共50兲
OriMC⫺1
OVRO 10.4 m
Sut85
14共11,3兲⫺13共11,2兲 vt ⫽1⫺1
18.1f
Sgr B2共N兲
SEST 15 m
Num98
242206.974*共10兲
g⫺CH3 CH2 OH CH3 CH2 CN
27共6,22兲⫺26共6,21兲
1.3b
OriMC⫺1
OVRO 10.4 m
Sut85
242210.413*共10兲
CH3 CH2 CN
27共6,21兲⫺26共6,20兲
b
OriMC⫺1
OVRO 10.4 m
Sut85
g⫺CH3 CH2 OH
13共3,10兲⫺13共2,12兲 vt ⫽1⫺0
b
Sgr B2共N兲
SEST 15 m
Num98
Pea96
242221.277 共50兲
g⫺CH3 CH2 OH
14共9,5兲⫺13共9,4兲 vt ⫽1⫺1
9.2fb
Sgr B2共N兲
SEST 15 m
Num98
Pea96
242221.277 共50兲
g⫺CH3 CH2 OH
14共9,6兲⫺13共9,5兲 vt ⫽1⫺1
b
Sgr B2共N兲
SEST 15 m
Num98
Pea96
5.6f
Sgr B2共N兲
SEST 15 m
Num98
242229.
unidentified
242238.732*共14兲
CH3 CH2 CN
27共17,*兲⫺26共17,*兲
27.5f
Sgr B2共N兲
SEST 15 m
Num98
CH3 NH2
6共⫺2兲⫺6共1兲 Aa⫺⫹
13.2f
Sgr B2共N兲
SEST 15 m
Num98
6.8f
Sgr B2共N兲
SEST 15 m
Num98
242262.9*共5兲 U
5共⫺1,5兲⫺4共⫺1,4兲 E 11共0,11兲⫺10共0,10兲 5共0,5兲⫺4共0,4兲 A⫹ 5共4,1兲⫺4共4,0兲 A⫹
242052.483*共10兲
242215,792 共50兲
U
25共2,23兲⫺24共2,22兲
b
1.7
242283.
unidentified
242309.307*共49兲
CH2 CO
12共4,9兲⫺11共4,8兲
6.0fb
Sgr B2共N兲
SEST 15 m
Num98
242309.308*共49兲
CH2 CO
12共4,8兲⫺11共4,7兲
b
Sgr B2共N兲
SEST 15 m
Num98
242317.090*共15兲
CH3 CH2 CN
27共18,*兲⫺26共18,*兲
24.4f
Sgr B2共N兲
SEST 15 m
Num98
242349.842 共50兲
g⫺CH3 CH2 OH
14共7,*兲⫺13共7,*兲 vt ⫽1⫺1
6.3f
Sgr B2共N兲
SEST 15 m
Num98
15.7f
Sgr B2共N兲
SEST 15 m
Num98
16.2f 0.5
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
242360. 242373.176*共20兲 242375.38* 共22兲 242398.458*共37兲
unidentified 13
CH3 OH CH2 CO CH2 CO
4共2,3兲⫺5共1,4兲 A⫺⫺ 12共0,12兲⫺11共0,11兲 12共3,10兲⫺11共3,9兲
0.6b
Pea96
Num98
Pea96
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
280
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
b
OriMC⫺1
OVRO 10.4 m
0.2
OriMC⫺1
OVRO 10.4 m
Sut85
O13CS CH3 OH CH3 CH2 CN CH3 OH unidentified
19⫺18
0.14
IRAS16293⫺2422
JCMT 15 m
Bla94
14共⫺1,14兲⫺13共⫺2,12兲 E 27共5,23兲⫺26共5,22兲 24共3,21兲⫺24共2,22兲 A⫺⫹
3.3 0.9 0.7
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Sut85 Num98
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Num98
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
242446.125*共20兲 242470.399*共10兲 242491.31* 共15兲 242512.
Pea96
Num98
Pea96
5.3f
Sgr B2共N兲
SEST 15 m
Num98
g⫺CH3 CH2 OH unidentified
14共3,12兲⫺13共3,11兲 vt ⫽1⫺1
3.7f
Sgr B2共N兲
SEST 15 m
Num98
242778.
2.8f
Sgr B2共N兲
SEST 15 m
Num98
242839.
unidentified
8.7f
Sgr B2共N兲
SEST 15 m
Num98
5.8f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
19共5,14兲⫺18共5,13兲 E 12共3,9兲⫺12共2,10兲 v2 ⫽1
1.1
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Oes99 Bog81 Bog81
CH3 OCHO
19共5,14兲⫺18共5,13兲 A
5.3f 1.1
C33S
5⫺4 13/2⫺11/2⫹11/2⫺9/2
1.5b
C33S
5⫺4 9/2⫺7/2⫹7/2⫺5/2
OriMC⫺1
OVRO 10.4 m
Sut85
7.7f
IRC⫹10216 Sgr B2共M兲
NRAO 12 m SEST 15 m
Hig00 Num98
5.1f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
7共5兲⫺6共5兲
4.6f 0.4
OriMC⫺1
OVRO 10.4 m
Sut85
Sgr B2共N兲
SEST 15 m
Num98
SO2
5共4,2兲⫺6共3,3兲
5.1f 1.4
OriMC⫺1
OVRO 10.4 m
Sut85
g⫺CH3 CH2 OH
14共4,11兲⫺13共4,10兲 vt ⫽0⫺0
2.3f
Sgr B2共N兲
SEST 15 m
Num98
1.8f 0.067 0.08
Sgr B2共N兲
SEST 15 m
Num98
IRC⫹10216 IRC⫹10216
NRAO 12 m NRAO 12 m
Tur87 Hig00
Cer89
Sgr B2共N兲
SEST 15 m
Num98
Kle96
MMWO 4.9 m SEST 15 m
Lor84a Num98
242970. 242997.786*共11兲
unidentified SO2
19共3,17兲⫺20共0,20兲
243013.996*共33兲
NH2 CHO
8共4,4兲⫺9共3,7兲
243020.
unidentified
243039.339*共56兲
S18O unidentified
243156.
Pea96
14共3,12兲⫺13共3,11兲 vt ⫽0⫺0
b
0.011
unidentified
243160.707*共28兲 243176.934共8兲
CS SiC
243178.657*共18兲
CH3 CHO
3⌸ 1 J⫽6⫺5 e 13共1,13兲⫺12共1,12兲 E vt ⫽1
5⫺4 v⫽1
243218.034*共2兲 243245.401*共10兲
OCS SO2
20⫺19 26共8,18兲⫺27共7,21兲
15.7f
OriMC⫺1 Sgr B2共M兲
7.1f 0.67
Pea96
243374.788*共48兲
OS18O
19共1,18兲⫺19共0,19兲
5.1f
Sgr B2共M兲
SEST 15 m
Num98
243397.555*共50兲
CH3 OH
18共6,13兲⫺19共5,14兲 A⫺
b
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
243397.816*共50兲
CH3 OH
18共6,12兲⫺19共5,15兲 A⫹
OriMC⫺1
OVRO 10.4 m
Sut85
Xu_97
243413.43* 共12兲 243450.
CH3 OH unidentified
23共3,20兲⫺23共2,21兲 A⫺⫹
1.6b 0.9
OVRO 10.4 m SEST 15 m
Sut85 Num98
Xu_97
14.7f
OriMC⫺1 Sgr B2共N兲
243490.
unidentified
3.3f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
243521.023*共7兲
NH2 CHO
12共1,12兲⫺11共1,11兲
243522.660*共10兲 243556.853*共26兲
SO2
14共0,14兲⫺13共1,13兲 v2 ⫽1
21.1f 0.6
t⫺CH3 CH2 OH CH3 OCHO
8共2,6兲⫺7共1,7兲
5.3f
34共10,25兲⫺34共9,26兲 A
2.1f
Sgr B2共N兲
SEST 15 m
Num98
3.8f 0.9
Sgr B2共M兲
SEST 15 m
Num98
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Gro98
23共5,18兲⫺23共4,19兲 EE
5.2fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
23共5,18兲⫺23共4,19兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
1.1 4.1f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
8.4f
Sgr B2共N兲
SEST 15 m
Num98
4.3f
Sgr B2共N兲
SEST 15 m
Num98
unidentified
5.1f
Sgr B2共N兲
SEST 15 m
Num98
unidentified
Sgr B2共NW兲
SEST 15 m
Num98
5共1,4兲⫺4共1,3兲 A⫺ 18共1,17兲⫺18共0,18兲
1.4f 8.1 0.4
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85
Xu_97
13共6,7兲⫺13共5,8兲
3.4f
Sgr B2共M兲
SEST 15 m
Num98
Bog86
14共3,12兲⫺14共2,13兲 A⫹⫺
5.5f 0.91
Sgr B2共N兲
SEST 15 m
Num98
Kle96
OriMC⫺1
MMWO 4.9 m
Lor85
3.7f
Sgr B2共N兲
SEST 15 m
Num98
243589.
unidentified
243643.235*共10兲 243738.713*共12兲
CH3 CH2 CN CH3 OCH3
27共4,23兲⫺26共4,22兲 23共5,18兲⫺23共4,19兲 AE⫹EA
243739.900*共8兲
CH3 OCH3
243741.087*共14兲
CH3 OCH3
243747. 243766.
unidentified unidentified
243823.055*共13兲
CH3 CH2 CN
U
243839.
unidentified
U
243848.
U
243869.
U
Num98
SEST 15 m
9共4,6兲⫺8共3,5兲
243564.632*共35兲
U U
SEST 15 m
Sgr B2共N兲
14共5,9兲⫺13共5,8兲 vt ⫽1⫺1
243087.650*共6兲 243120.317 共50兲
Pea96
Sgr B2共N兲
g⫺CH3 CH2 OH CH3 CH2 CN
243053.
Xu_97
b
14共5,10兲⫺13共5,9兲 vt ⫽1⫺1
242693.030 共50兲
242913.72共10兲
Xu_97
8.1fb
CH3 CH2 CN
g⫺CH3 CH2 OH CH3 OCHO SO2
Lab. Ref.
7.1f 1.1 1.0
g⫺CH3 CH2 OH
242896.022*共21兲 242913.72共10兲
U
g⫺CH3 CH2 OH HNCO
12共2,10兲⫺11共2,9兲 27共5,22兲⫺26共5,21兲 14共6,*兲⫺13共6,*兲 vt ⫽0⫺0
242685.010 共50兲
242872.861*共11兲
U
CH2 CO CH3 CH2 CN
11.0f 0.4 0.7
11共1,10兲⫺10共1,9兲 27共4,24兲⫺26共4,23兲
242871.513*共20兲
U
Sut85
12共3,9兲⫺11共3,8兲
242870.574*共3兲
U
Astr. Ref.
12共2,11兲⫺11共2,10兲
242770.099 共50兲
U
Telescope
CH2 CO
242753.807*共18兲
U
Source
CH2 CO
242639.717*共16兲 242664.690*共10兲
U
T r 共K兲/T a 共K兲
242398.956*共37兲
242547.326*共10兲 242625.693 共50兲
U
Quantum numbers
242424.606*共46兲 242435.425*共11兲
242536.214*共47兲
U
Formula
243915.811*共6兲 243935.965*共11兲
CH3 OH
243966.283*共25兲 243975.379*共14兲
c⫺H13CCCH CH3 CHO
244047.80* 共27兲 244133.
H2 CS unidentified
34
SO2
26共2,25兲⫺25共1,24兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
7共1,6兲⫺6共1,5兲
Oes99
MICROWAVE TRANSITIONS
281
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
U
244142.
Source
Telescope
Astr. Ref.
5.6f
Sgr B2共N兲
SEST 15 m
Num98
6共⫺2兲⫺6共⫺1兲 Ea
3.9f
Sgr B2共N兲
SEST 15 m
Num98
244222.170*共11兲
c⫺C3 H2
3共2,1兲⫺2共1,2兲
Sgr B2共N兲
SEST 15 m
Num98
244254.205*共7兲 244284.
SO2 unidentified
14共0,14兲⫺13共1,13兲
2.2f 1.5
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor85 Num98
244330.987*共98兲
CH3 OH CH3 OH unidentified HNO SO2
22共,19兲⫺22共2,20兲 A⫺⫹ 9共1,9兲⫺8共0,8兲 E vt ⫽1
OVRO 10.4 m OVRO 10.4 m NRAO 12 m NRAO 12 m SEST 15 m
Sut85 Sut85 Ziu94a Ziu94a Num98
unidentified
Num98
33
244392.329*共26兲
SO2 CH3 CH2 CN
244440.
unidentified
244481.515*共10兲
3共0,3兲⫺2共0,2兲 18共1,17兲⫺18共0,18兲 v2 ⫽1
11.7f
OriMC⫺1 OriMC⫺1 OriMC⫺1 NGC2024 Sgr B2共M兲
14共0,14兲⫺13共1,13兲
11.9f
Sgr B2共M兲
SEST 15 m
15共2,13兲⫺14共1,14兲
4.2f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共M兲
SEST 15 m
Num98
14共0,14兲⫺13共1,13兲
3.3f 1.4
OriMC⫺1
OVRO 10.4 m
Sut85
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
244503.902*共14兲
CH3 OCH3
23共2,22兲⫺23共1,23兲 EA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
244508.305*共12兲
CH3 OCH3
23共2,22兲⫺23共1,23兲 EE
0.89b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
244512.709*共16兲
CH3 OCH3
23共2,22兲⫺23共1,23兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
244564.33* 共16兲
HC13CCN CH3 OCHO
27⫺26
8.9f 1.3
Sgr B2共N兲
SEST 15 m
Num98
Laf78
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Laf78
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99 Pea96
12.4f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Kle96
7.3f
Sgr B2共N兲
SEST 15 m
Num98
15.2f
Sgr B2共N兲
SEST 15 m
Num98
6.3f
Sgr B2共N兲
SEST 15 m
Num98
22.0f 0.5
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Sut85
2.5f
Sgr B2共N兲
SEST 15 m
Num98
5.9f 5.5
Sgr B2共N兲
SEST 15 m
Num98
2.3f
OriMC⫺2 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Sne84 Num98
244712.079*共96兲 244789.253*共10兲 244799. 244832.183*共10兲 244843.
34
SO2
HCC13CN CH3 OCHO g⫺CH3 CH2 OH CH2 CO CH3 CHO
20共4,17兲⫺19共4,16兲 E 27⫺26 20共4,17兲⫺19共4,16兲 A 14共1,13兲⫺13共1,12兲 vt ⫽1⫺1 12共1,11兲⫺11共1,10兲 13共0,13兲⫺12共0,12兲 E
unidentified CH3 CHO
13共0,13兲⫺12共0,12兲 A⫹⫹
unidentified
244854.209*共9兲
NH2 CHO
13共0,13兲⫺12共1,12兲
244857.39*共7兲 244878.
CH2 CHCN unidentified
26共2,25兲⫺25共2,24兲
U
244885.
unidentified CS unidentified
5⫺4
U
244935.560*共10兲 244993.
SO2
5共2,4兲⫺4共1,3兲 v2 ⫽1
245002.766*共8兲
Sgr B2共M兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
14共3,11兲⫺13共2,12兲
6.1f
Sgr B2共N兲
SEST 15 m
Num98
27共3,25兲⫺27共2,26兲
2.8f
Sgr B2共N兲
SEST 15 m
Num98
unidentified
5.4f
Sgr B2共N兲
SEST 15 m
Num98
unidentified
3.9f 0.40
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共M兲
NRAO 12 m SEST 15 m
Dic97a Num98
OriMC⫺1
OVRO 10.4 m
Sut85
Sgr B2共N兲
SEST 15 m
Num98
3.6f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
26共2,25兲⫺25共2,24兲 v15 ⫽1
3.5f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
6共3,3兲⫺6共2,4兲
8.3f 0.9
OriMC⫺1
OVRO 10.4 m
Sut85
14共3,11兲⫺13共3,10兲 vt ⫽1⫺1
6.1f
Sgr B2共N兲
SEST 15 m
Num98
26共3,23兲⫺25共4,22兲
1.7
OVRO 10.4 m SEST 15 m
Sut85 Num98
245023.654*共17兲
CH3 CH2 CN
245056.920*共4兲
CH2 CHCN
U
245084.
U
245092.
245178.721*共11兲 245200. 245223.465*共80兲 U
U
245233.
12共5,7兲⫺12共4,8兲
34
SO2
15共2,14兲⫺15共1,15兲
5.6f 0.8
21共3,18兲⫺22共2,19兲 A⫺⫹
2.7f 1.3
unidentified CH3 OH unidentified CH2 CHCN 34
SO2
g⫺CH3 CH2 OH SO2
Kle96
Bog86
Xu_97
Pea96
245352.
unidentified
7.9f
OriMC⫺1 Sgr B2共N兲
245393.804*共32兲
CH3 OCHO
33共0,24兲⫺33共9,25兲 E
4.9f
Sgr B2共N兲
SEST 15 m
Num98
245447.195*共42兲
CH3 OCHO
20共19,*兲⫺19共19,*兲 A
2.9f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
CH3 NH2
10共5兲⫺11共4兲 Aa⫹⫹
5.0fb
Sgr B2共N兲
SEST 15 m
Num98
Num98
245457.1*共5兲
Oes99
CH3 NH2
10共⫺5兲⫺11共⫺4兲 Aa⫺⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Num98
245465.735*共43兲
CH3 OCHO
20共19,1兲⫺19共19,0兲 E
7.9fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
245468.370*共58兲
CH3 OCHO
20共19,2兲⫺19共19,1兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
245491.831*共40兲
CH3 OCHO
20共18,2兲⫺19共18,1兲 E
3.7fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
245498.273*共48兲
CH3 OCHO
20共18,3兲⫺19共18,2兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
245515.
unidentified
⫺1.7f
Sgr B2共NW兲
SEST 15 m
Num98
⫺1.1f
245458.2*共5兲
U
c⫺H13CCCH
unidentified
245339.279*共9兲
U
4共1,4兲⫺3共1,3兲
245267. 245327.139 共50兲
U
CH2 NH
245251.34*共8兲
245302.235*共8兲
2.5f 0.8
6.2f
unidentified
245125.79* 共20兲 245141.329*共25兲
10.5f 1.1
5.0f
245015.
U
Xu_97 Xu_97
23共2,22兲⫺23共1,23兲 AE
244633.950 共50兲
U
Num98
CH3 OCH3
244594.036*共17兲
U
3.2f 1.1 1.2 0.08 0.020
Lab. Ref.
244503.902*共14兲
244580.313*共16兲 244588.094*共63兲
U
T r 共K兲/T a 共K兲
CH3 NH2
244388.894*共12兲
U
Quantum numbers
244152.0*共5兲
244338.004*共15兲 U244353. 244364.019*共70兲 244386.671*共13兲
U
Formula
245527.
unidentified
Sgr B2共NW兲
SEST 15 m
Num98
245530.284*共35兲
CH3 OCHO
20共17,3兲⫺19共17,2兲 E
4.9f
Sgr B2共N兲
SEST 15 m
Num98
245532.794*共15兲
D2 CO
4共1,3兲⫺3共1,2兲
0.27
IRAS16293⫺2422
IRAM 30 m
Cec98
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
282
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
Sgr B2共N兲
SEST 15 m
Num98
Oes99
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m MMWO 4.9 m OVRO 10.4 m SEST 15 m
Sut85 Lor81 Sut85 Num98
245540.308*共37兲
CH3 OCHO
20共17,4兲⫺19共17,3兲 E
245563.410*共7兲 245606.311*共9兲 245651.199*共24兲 245710.
SO2 HCCCN CH3 OCHO unidentified
10共3,7兲⫺10共2,8兲 27⫺26 20共15,*兲⫺19共15,*兲 A
6.5f 7.8 0.7 0.6
245752.239*共24兲 245753.993*共28兲
CH3 OCHO CH3 OCHO
20共14,*兲⫺19共14,*兲 A
5.1f 0.7
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
20共14,6兲⫺19共14,5兲 E
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
245772.630*共24兲 245782.
CH3 OCHO unidentified
20共14,7兲⫺19共14,6兲 E
0.5
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
245821.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
245883.062*共25兲 245885.201*共21兲 245903.654*共21兲 245993.
CH3 OCHO CH3 OCHO CH3 OCHO unidentified
20共13,7兲⫺19共13,7兲 E 20共13,*兲⫺19共13,*兲 A 20共13,8兲⫺19共13,7兲 E
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Sut85 Num98
246010.80* 共82兲
HCCCN
27⫺26 v6 ⫽1 ᐉ⫽1 e
Sgr B2共N兲
SEST 15 m
Num98
Laf78
246054.775*共24兲 246060.791*共20兲 246074.914*共65兲 246105.97*共1兲
CH3 OCHO CH3 OCHO CH3 OH HCOOH
20共12,8兲⫺19共12,7兲 E 20共12,*兲⫺19共12,*兲 A 20共3,17兲⫺20共2,18兲 A⫺⫹ 11共2,10兲⫺10共2,9兲
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Oes99 Oes99 Xu_97 Wil80
U
246109.
unidentified
246119.348*共12兲 U
246126.
OS18O unidentified
U
246143.
U U
U
U U
U
U
U
U
6.4f 3.9f 0.2 0.8 0.2 8.6f 7.2f 0.5 0.8 1.6 8.3f
Sgr B2共N兲
SEST 15 m
Num98
4.7f
Sgr B2共M兲
SEST 15 m
Num98
3.6f
Sgr B2共M兲
SEST 15 m
Num98
4.2f
Sgr B2共N兲
SEST 15 m
Num98
unidentified
1.8f
Sgr B2共N兲
SEST 15 m
Num98
246170.
unidentified
5.6f
Sgr B2共N兲
SEST 15 m
Num98
246187.
unidentified
9.8f
Sgr B2共N兲
SEST 15 m
Num98
8共3,5兲⫺8共2,6兲
Oes99 Oes99 Oes99
246201.40* 共94兲
HCCCN
27⫺26 v6 ⫽1 ᐉ⫽1 f
14.4f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
246208.942*共91兲
HCCCN
27⫺26 v7 ⫽1 ᐉ⫽1 e
22.7f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
2.1f 0.9 0.4 1.3 0.4
Sgr B2共N兲
SEST 15 m
Num98
3.7f
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Sut85 Sut85 Sut85 Sut85 Num98
4.2f
Num98
246232.
unidentified
246268.741*共10兲 246285.300*共21兲 246295.106*共20兲 246308.197*共20兲 246330.689*共16兲
CH3 CH2 CN CH3 OCHO CH3 OCHO CH3 OCHO CH3 CHO
246355.
unidentified
27共2,25兲⫺26共2,24兲 20共11,9兲⫺19共11,8兲 E 20共11,*兲⫺19共11,*兲 A 20共11,10兲⫺19共11,9兲 E 15共3,13兲⫺15共2,14兲 A⫹⫺
Oes99 Oes99 Oes99 Kle96
Sgr B2共N兲
SEST 15 m
246389.273*共20兲
NH2 CHO
20共3,17兲⫺20共2,18兲
7.9f
Sgr B2共N兲
SEST 15 m
Num98
246404.604*共67兲
SO
2共3兲⫺3共2兲
9.0f
Sgr B2共M兲
SEST 15 m
Num98
COL01
246414.762 共50兲
g⫺CH3 CH2 OH CH3 CH2 CN unidentified
14共3,11兲⫺13共3,10兲 vt ⫽0⫺0
Sgr B2共N兲
SEST 15 m
Num98
Pea96
28共2,27兲⫺27共2,26兲
6.3f 0.6 5.5f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
8共3,5兲⫺8共2,6兲
9.8f
246421.915*共11兲 246448. 246455.765*共11兲
Sgr B2共M兲
SEST 15 m
Num98
U
246459.
unidentified
7.6f
Sgr B2共N兲
SEST 15 m
Num98
U
246488.
unidentified
3.3f
Sgr B2共N兲
SEST 15 m
Num98
U
246495.
unidentified
2.4f
Sgr B2共N兲
SEST 15 m
Num98
U
Oes99
33
SO2
246522.43* 共66兲
CH3 OD
8共0,8兲⫺7共1,7兲 A⫹⫹
3.6f
Sgr B2共N兲
SEST 15 m
Num98
And88
246524.586*共16兲
13共2,12兲⫺12共1,12兲 vt ⫽0⫺1
SEST 15 m
Num98
JPL01
27共3,24兲⫺26共3,23兲 27⫺26 v7 ⫽1 ᐉ⫽1 f 20共10,10兲⫺19共10,9兲 E
3.6f 0.6 1.1 0.7
Sgr B2共N兲
246548.703*共10兲 246560.749*共91兲 246599.935*共20兲 246613.385*共20兲
g⫺CH3 CH2 OH CH3 CH2 CN HCCCN CH3 OCHO CH3 OCHO
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Sut85 Sut85 Sut85
Laf78 Oes99
20共10,11兲⫺19共10,10兲 A
1.1b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
246613.400*共20兲
CH3 OCHO
20共10,10兲⫺19共10,9兲 A
b
OriMC⫺1
OVRO 10.4 m
Sut85
Oes99
246623.159*共17兲 246645.
CH3 OCHO unidentified
20共10,11兲⫺19共10,10兲 E
0.8
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
Oes99
246663.403*共32兲
34 SO CH2 CHCN
246678.431*共4兲 246686.115*共8兲
5共6兲⫺4共5兲
5.6f 2.9
26共1,26兲⫺25共0,25兲
3.5f
4共3,1兲⫺4共2,2兲
OriMC⫺1
OVRO 10.4 m
Sut85
Sgr B2共N兲
SEST 15 m
Num98
0.3
OriMC⫺1
OVRO 10.4 m
Sut85
246697.454*共16兲
CH3 OCH3
27共4,24兲⫺26共5,21兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
246697.903*共16兲
CH3 OCH3
27共4,24兲⫺26共5,21兲 EE
7.6fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
246698.352*共16兲
CH3 OCH3
27共4,24兲⫺26共5,21兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
U
246764.
unidentified
4.2f
Sgr B2共N兲
SEST 15 m
Num98
U
246790.
unidentified
6.9f
Sgr B2共N兲
SEST 15 m
Num98
U
246799.
unidentified
7.7f
Sgr B2共N兲
SEST 15 m
Num98
U
246807.
unidentified
3.8f
Sgr B2共N兲
SEST 15 m
Num98
U
246816.
unidentified
9.4f
Sgr B2共N兲
SEST 15 m
Num98
246827.92* 共21兲
H13CCCN unidentified
10.1f
Sgr B2共N兲
SEST 15 m
Num98
8.3f
Sgr B2共N兲
SEST 15 m
Num98
U
246839.
34
SO2
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
28⫺27
Laf78
MICROWAVE TRANSITIONS
283
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
Astr. Ref.
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor85 Lor85
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor85 Num98
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Sut85 Num98
T r 共K兲/T a 共K兲
Source
5.4f 0.30 0.18 0.1
Lab. Ref.
246851.
unidentified 19共3,16兲⫺19共2,17兲 A⫺⫹ 19共4,15兲⫺18共4,14兲 E
246912.406*共4兲
CH3 OH CH3 OCHO CH2 CHCN CH2 CHCN
246914.657*共20兲 246918.442*共4兲
CH3 OCHO CH2 CHCN
19共4,15兲⫺18共4,14兲 A 26共6,21兲⫺25共6,20兲
246918.505*共4兲
CH2 CHCN
26共6,20兲⫺25共6,19兲
b
Sgr B2共N兲
SEST 15 m
Num98
CH3 NH2
2共2兲⫺2共⫺1兲 As⫹⫺
Sgr B2共N兲
SEST 15 m
Num98
246924.681*共11兲 246945.776*共45兲 246952.14* 共23兲 247001.71* 共11兲
HDCO CH3 OCHO CH2 CHCN CH2 CHCN
4共1,4兲⫺3共1,3兲 10共5,6兲⫺9共4,6兲 E 26共9,*兲⫺25共9,*兲 26共5,22兲⫺25共5,21兲
5.1f 0.40 0.16 0.6
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m OVRO 10.4 m OVRO 10.4 m
Lor85 Lor85 Sut85 Bla86
247004.92* 共11兲
CH2 CHCN
26共5,21兲⫺25共5,20兲
b
OriMC⫺1
OVRO 10.4 m
Bla86
247010.671*共5兲
CH2 CHCN
26共10,*兲⫺25共10,*兲
b
Sgr B2共N兲
SEST 15 m
Num98
247040.570*共20兲 247044.108*共16兲 247053.496*共17兲 247057.273*共17兲
CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO
20共9,11兲⫺19共9,10兲 E 21共3,19兲⫺20共3,18兲 E 21共3,19兲⫺20共3,18兲 A
0.6 1.1 1.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86 Bla86
Oes99 Oes99 Oes99
20共9,12兲⫺19共9,11兲 A
1.2b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
247057.751*共17兲
CH3 OCHO
20共9,11兲⫺19共9,10兲 A
b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
247063.586*共17兲 247081.8*共5兲
CH3 OCHO CH3 NH2
20共9,12兲⫺19共9,11兲 E
0.5
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
4共⫺2兲⫺4共1兲 Aa⫺⫹
15.4f
Sgr B2共N兲
SEST 15 m
Num98
Num98
Num98
26共7,*兲⫺25共7,*兲 26共8,*兲⫺25共8,*兲
27.4fb 1.2
0.2b
Xu_97 Oes99
Oes99
Num98 Plu87
247083.717*共6兲
CH2 CHCN
26共11,*兲⫺25共11,*兲
b
Sgr B2共N兲
SEST 15 m
247086.93*共8兲 247113.16* 共20兲
CH2 CHCN HCCCN
26共3,24兲⫺25共3,23兲 27⫺26 v7 ⫽2 ᐉ⫽0
0.2
OriMC⫺1
OVRO 10.4 m
Bla86
5.5f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
247124.165*共29兲
CH3 OCHO
10共5,5兲⫺9共4,6兲 A
3.1f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
247127.386*共8兲
34 SO2 CH3 OH CH2 CHCN
3共3,1兲⫺3共2,2兲
4.0f
Sgr B2共M兲
SEST 15 m
Num98
16共2,14兲⫺15共3,12兲 E 26共12,*兲⫺25共12,*兲
1.6 b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
247161.994*共33兲 247169.371*共7兲
Xu_97
247169.842*共15兲
SO2
31共9,23兲⫺32共8,24兲
8.8f
Sgr B2共M兲
SEST 15 m
Num98
247173.939*共4兲
CH2 CHCN
26共4,23兲⫺25共4,22兲
8.9fb
Sgr B2共N兲
SEST 15 m
Num98
247210.01* 共22兲
HCCCN
27⫺26 v7 ⫽2 ᐉ⫽2 f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
247228.737*共17兲 247247.54* 共16兲
CH3 OH CH2 CHCN
4共2,2兲⫺5共1,5兲 A⫹
12.3f 3.9
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
26共8,*兲⫺25共8,*兲 v15 ⫽1
3.5f
Sgr B2共N兲
SEST 15 m
Num98
247261.771*共12兲
CH3 OCH3
26共3,24兲⫺26共2,25兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
247264.269*共10兲
CH3 OCH3
26共3,24兲⫺26共2,25兲 EE
5.1fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
247266.246*共9兲
CH2 CHCN
26共13,*兲⫺25共13,*兲
b
Sgr B2共N兲
SEST 15 m
Num98
247266.767*共16兲
CH3 OCH3
26共3,24兲⫺26共2,25兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
247270.64*共9兲
26共4,22兲⫺25共4,21兲 26共5,22兲⫺25共5,21兲 v15 ⫽1
0.3
247310.92*共9兲
CH2 CHCN CH2 CHCN
3.6fb
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
247313.68*共9兲
CH2 CHCN
26共5,21兲⫺25共5,20兲 v15 ⫽1
247327.
unidentified
247360.73*共22兲
CH2 CHCN
Gro98
b
Sgr B2共N兲
SEST 15 m
Num98
4.4f
Sgr B2共N兲
SEST 15 m
Num98
26共10,*兲⫺25共10,*兲 v15 ⫽1
1.6f
Sgr B2共N兲
SEST 15 m
Num98
CH3 NH2
7共⫺2兲⫺7共⫺1兲 Ea
1.6f
Sgr B2共N兲
SEST 15 m
Num98
Num98
247368.523*共32兲
CH3 OCHO
31共10,21兲⫺31共7,24兲 E
5.0f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
247390.697*共7兲
NH2 CHO
12共0,12兲⫺11共0,11兲
Sgr B2共N兲
SEST 15 m
Num98
247440.294*共8兲
5共3,3兲⫺5共2,4兲
15.4f 0.7
OriMC⫺1
OVRO 10.4 m
Bla86
4.3f
Sgr B2共N兲
SEST 15 m
Num98
0.6 6.3f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
247362.5*共5兲
U
247460.
34 SO2 unidentified
U
247469. 247472.24*共8兲
unidentified CH2 CHCN
26共4,23兲⫺25共4,22兲 v15 ⫽1
247490.140*共16兲
U
Telescope
Quantum numbers
246873.503*共53兲 246891.590*共17兲 246896.87* 共16兲
246924.3*共5兲
U
Formula
CH2 CHCN
26共15,*兲⫺25共15,*兲
4.1f
Sgr B2共N兲
SEST 15 m
Num98
247514.12*共1兲
HCOOH
11共2,10兲⫺10共2,9兲
2.7f
Sgr B2共N兲
SEST 15 m
Num98
Wil80
247525.867*共32兲
CH3 CHO
14共0,14兲⫺13共1,13兲 E vt ⫽1
2.6f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
247558.67*共8兲
CH2 CHCN
26共4,22兲⫺25共4,21兲 v15 ⫽1
7.3f
Sgr B2共N兲
SEST 15 m
Num98
247563.
unidentified
10.1f 1.1 0.4
Sgr B2共M兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
247611.037*共43兲
CH3 OH
18共3,15兲⫺18共2,16兲 A⫺⫹
U
247630. 247633.635*共7兲
unidentified NH2 CHO
3共2,2兲⫺2共1,1兲
U
247636. 247642.490*共16兲
unidentified CH2 CHCN
26共6,21兲⫺25共6,20兲 v11 ⫽1
247642.570*共16兲
CH2 CHCN
26共6,20兲⫺25共6,19兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
247647.276*共19兲
CH2 CHCN
26共9,*兲⫺25共9,*兲 v11 ⫽1
6.0fb
Sgr B2共N兲
SEST 15 m
Num98
247656.861*共16兲
CH3 OCHO CH3 OCHO CH3 OCHO
21共2,19兲⫺20共2,18兲 E 21共2,19兲⫺20共2,18兲 A 20共8,12兲⫺19共8,11兲 E
1.4 1.2 0.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86 Bla86
247665.389*共17兲 247682.634*共17兲
7.0f 0.4
Xu_97
Oes99 Oes99 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
284
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86
Oes99 Oes99
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99
10.9fb
Source
247696.638*共22兲
CH2 CHCN
26共10,*兲⫺24共10,*兲 v11 ⫽1
247697.214*共17兲 247704.315*共17兲 247707.983*共17兲
20共8,13兲⫺19共8,12兲 A 20共8,13兲⫺19共8,12兲 E
9.0f 0.7 0.8
20共8,12兲⫺19共8,11兲 A 26共5,22兲⫺25共5,21兲 v11 ⫽1
1.1
247739.262*共15兲
CH3 OCHO CH3 OCHO CH3 OCHO CH2 CHCN
Lab. Ref.
247741.
unidentified
6.3f
Sgr B2共M兲
SEST 15 m
Num98
247743.109*共15兲
CH2 CHCN
26共5,21兲⫺25共5,20兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
247754.80* 共35兲
CH2 CHCN
26共14,*兲⫺25共14,*兲 v15 ⫽1
4.4f
Sgr B2共N兲
SEST 15 m
Num98
247760.692*共26兲
CH2 CHCN
26共11,*兲⫺24共11,*兲 v11 ⫽1
5.2f
Sgr B2共N兲
SEST 15 m
Num98
247770.686*共10兲
CH3 OCH3
22共5,17兲⫺22共4,18兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
247770.692*共10兲
CH3 OCH3
22共5,17兲⫺22共4,18兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
247772.121*共8兲
CH3 OCH3
22共5,17兲⫺22共4,18兲 EE
3.7fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
247773.554*共14兲
CH3 OCH3
22共5,17兲⫺22共4,18兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
247798.55* 共15兲 247818.061*共15兲
CH2 CHCN CH2 CHCN
27共1,27兲⫺26共1,26兲 26共3,24兲⫺25共3,23兲 v11 ⫽1
0.3 4.1f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
247835.
unidentified
5.6f
Sgr B2共M兲
SEST 15 m
Num98
247837.228*共33兲
CH2 CHCN
26共12,*兲⫺24共12,*兲 v11 ⫽1
9.2f
Sgr B2共N兲
SEST 15 m
Num98
247840.224*共75兲
12共⫺2,10兲⫺13共⫺3,10兲 E vt ⫽1 22共1,21兲⫺21共2,20兲 E
1.0
247873.934*共17兲
CH3 OH CH3 OCHO
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Xu_97 Oes99
247879.552*共17兲
CH3 OCHO
22共1,21兲⫺21共2,20兲 A
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
247901.631*共17兲
CH3 OCHO CH3 OCHO
22共2,21兲⫺21共2,20兲 E 22共2,21兲⫺21共2,20兲 A 15共0,15兲⫺14共1,14兲
0.7 0.6
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Oes99 Oes99
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99
Sgr B2共N兲
SEST 15 m
Num98
4.6f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99 Pea96 Oes99
t⫺CH3 CH2 OH CH3 OCHO CH2 CHCN
22共1,21兲⫺21共1,20兲 E 26共13,*兲⫺24共13,*兲 v11 ⫽1
247926.084*共15兲
CH2 CHCN
26共4,23兲⫺25共4,22兲 v11 ⫽1
247927.733*共17兲 247943.406 共50兲
CH3 OCHO
22共1,21兲⫺21共1,20兲 A 15共1,15兲⫺14共1,14兲 vt ⫽0⫺0
10.0fb
6.4f 0.6 b
16.6fb 0.5
247949.938*共17兲
g⫺CH3 CH2 OH CH3 OCHO
22共2,21兲⫺21共1,20兲 A
6.1fb
Sgr B2共N兲
SEST 15 m
Num98
247955.350*共17兲
CH3 OCHO
22共2,21兲⫺21共1,20兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
247967.093*共25兲
CH3 OH
23共1,22兲⫺23共0.23兲 E
4.3f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
248022.693*共59兲
CH2 CHCN
26共14,*兲⫺24共14,*兲 v11 ⫽1
4.2f
Sgr B2共N兲
SEST 15 m
Num98
248042.561*共11兲
CH3 CH2 CN
28共1,27兲⫺27共1,26兲
17.0f
Sgr B2共N兲
SEST 15 m
Num98
248057.387*共8兲
SO2
6.1
248143.406*共12兲
g⫺CH3 CH2 OH
15共2,14兲⫺15共1,15兲 7共5,2兲⫺6共4,2兲 vt ⫽0⫺1
2.0fb
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
JPL01
248143.906*共12兲
g⫺CH3 CH2 OH
7共5,3兲⫺6共4,3兲 vt ⫽0⫺1
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
248178.548*共5兲
g⫺CH3 CH2 OH
15共1,15兲⫺14共1,14兲 vt ⫽1⫺1
8.2f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
2.6f
Sgr B2共N兲
SEST 15 m
Num98
248213.
unidentified
248245.7*共5兲
CH2 CHCN
26共16,*兲⫺24共16,*兲 v11 ⫽1
2.7f
Sgr B2共N兲
SEST 15 m
Num98
248282.480*共36兲
17共3,14兲⫺17共2,15兲 A⫺⫹ 43共11,33兲⫺42共12,30兲 A
2.2
248317.032*共56兲
CH3 OH CH3 OCHO
3.6f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
248326.
unidentified
3.0f
Sgr B2共N兲
SEST 15 m
Num98
248355.6*共5兲
CH2 CHCN
3.4f 0.9
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
34.3f
Sgr B2共N兲
SEST 15 m
Num98
5.1f 0.6
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
248364.764*共8兲 U
Sgr B2共N兲
T r 共K兲/T a 共K兲
247922.241*共17兲 247924.864*共43兲
U
Astr. Ref.
Quantum numbers
247907.169*共17兲 247911.869*共16兲
U
Telescope
Formula
26共6,*兲⫺25共6,*兲 v11 ⫽2 7共3,5兲⫺7共2,6兲
34
SO2
248392.
unidentified
248419.925*共4兲
CH3 CH2 CN
39共6,34兲⫺39共5,35兲
248436.921*共8兲 248463.614 共50兲
SO2
13共3,11兲⫺14共0,14兲
g⫺CH3 CH2 OH
14共2,12兲⫺13共2,11兲 vt ⫽0⫺0
248481.
unidentified
8.3f
Sgr B2共N兲
SEST 15 m
Num98
3.7f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97 Oes99
JPL01 Pea96
U
248500.
unidentified
1.1f
Sgr B2共M兲
SEST 15 m
Num98
U
248520.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
CH2 CHCN unidentified
26共3,23兲⫺25共3,22兲
U
248528.95* 共78兲 248547.
3.6f 0.4 10.8f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
248577.119 共50兲
g⫺CH3 CH2 OH
15共0,15兲⫺14共0,14兲 vt ⫽0⫺0
8.5f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
20共7,14兲⫺19共7,13兲 A
1.4f 1.0
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
20共7,14兲⫺19共7,13兲 E
1.0
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99
18.1f
OriMC⫺1 Sgr B2共N兲
U
248608.
unidentified
248617.441*共17兲 248633.613*共21兲
CH3 OCHO CH3 OCHO
U
248640.
unidentified
U
248653.
unidentified
3.5f
Sgr B2共M兲
SEST 15 m
Num98
248666.5*共4兲
CH2 CHCN
26共4,23兲⫺25共4,22兲 v11 ⫽2
3.0f
Sgr B2共N兲
SEST 15 m
Num98
248677.200*共4兲
CH2 CHCN
27共0,27兲⫺26共0,26兲
5.8f
Sgr B2共N兲
SEST 15 m
Num98
248687.
unidentified
7.0f
Sgr B2共N兲
SEST 15 m
Num98
38.4f
Sgr B2共M兲
SEST 15 m
Num98
10.0f
Sgr B2共N兲
SEST 15 m
Num98
U
248698.688*共12兲 U
248727.
34
SO2
13共1,13兲⫺12共0,12兲
unidentified
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Pea96
MICROWAVE TRANSITIONS
285
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Source
Telescope
Astr. Ref.
Lab. Ref.
CH3 OCHO
20共7,13兲⫺19共7,12兲 E
7.7fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
CH3 OCHO
23共1,23兲⫺22共1,22兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
248749.839*共20兲
CH3 OCHO
23共0,23兲⫺22共0,22兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
248771.523*共15兲
OS18O CH3 CH2 CN
15共0,15兲⫺14共1,14兲
10.8fb
Sgr B2共M兲
SEST 15 m
Num98
29共1,29兲⫺28共1,28兲
14.1f
Sgr B2共N兲
SEST 15 m
Num98
6共3,3兲⫺6共2,4兲
b
Sgr B2共M兲
SEST 15 m
Num98
18
248786.821*共17兲
OS O CH3 OCHO
20共7,13兲⫺19共7,12兲 A
5.1f
Sgr B2共N兲
SEST 15 m
Num98
248830.823*共7兲
SO2
10共5,5兲⫺11共4,8兲
38.8f
Sgr B2共M兲
SEST 15 m
Num98
248840.3*共5兲 248869.418*共12兲 248885.479*共30兲 248946.
CH3 NH2
3共⫺2兲⫺3共1兲 Aa⫺⫹
7.1f
Sgr B2共N兲
SEST 15 m
Num98
CH3 CH2 CN
29共0,29兲⫺28共0,28兲
27.0f
Sgr B2共N兲
SEST 15 m
Num98
CH3 OH
16共3,13兲⫺16共2,14兲 A⫺⫹
25.2f
Sgr B2共N兲
SEST 15 m
Num98
2.5f
Sgr B2共N兲
SEST 15 m
Num98
unidentified
248992.483*共28兲
CH3 OCHO
248997.
unidentified
248999.2*共5兲 249024.531*共42兲
CH3 NH2 CH3 OCHO
249030.981*共16兲
CH3 OCHO
249047.435*共17兲 249054.409*共5兲
31共10,22兲⫺31共9,23兲 E
Sgr B2共N兲
SEST 15 m
Num98
SEST 15 m
Num98
3共⫺2兲⫺3共⫺1兲 Es
5.4f
Sgr B2共N兲
SEST 15 m
Num98
Num98
33共4,29兲⫺33共3,30兲 A
3.8f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
20共5,16兲⫺19共5,15兲 E
7.6f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
CH3 OCHO
20共5,16兲⫺19共5,15兲 A
14.7f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
c⫺C3 H2
5共2,3兲⫺4共3,2兲
13.6f
Sgr B2共N兲
SEST 15 m
Num98
34 SO2 CH2 CHCN
30共4,26兲⫺30共3,27兲
14.6f
Sgr B2共M兲
SEST 15 m
Num98
249107.186*共4兲
26共1,25兲⫺25共1,24兲
18.8f
Sgr B2共N兲
SEST 15 m
Num98
249121.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
IRAS16293⫺2422
JCMT 15 m
Bla94
249133.047*共9兲
OC34S
21⫺20
11.4f 0.16
249142.279*共5兲
g⫺CH3 CH2 OH CH3 CH2 CN
15共0,15兲⫺14共0,14兲 vt ⫽0⫺1
3.8f
Sgr B2共N兲
SEST 15 m
Num98
37共6,32兲⫺37共5,33兲
7.3f
Sgr B2共N兲
SEST 15 m
Num98
5共6兲⫺4共5兲
249162.745*共20兲
16.0f
Sgr B2共M兲
SEST 15 m
Num98
249167.
unidentified
6.2f
Sgr B2共N兲
SEST 15 m
Num98
U
249174.
unidentified
7.0f
Sgr B2共N兲
SEST 15 m
Num98
249184.736*共16兲
CH3 CH2 CN
33共6,27兲⫺33共5,28兲
8.2f
Sgr B2共N兲
SEST 15 m
Num98
249192.864*共24兲
CH3 OH
16共⫺3,14兲⫺15共⫺4,12兲 E
6.5f
Sgr B2共N兲
SEST 15 m
Num98
249213.175*共12兲
CH3 CH2 CN
29共1,29兲⫺28共0,28兲
10.3f
Sgr B2共N兲
SEST 15 m
Num98
249247.
unidentified
U
Xu_97
Sgr B2共M兲
U
U
Num98
8.6f
249158.549*共20兲
U
Oes99
13.2f
249099.227*共45兲
U
T r 共K兲/T a 共K兲
248744.628*共24兲
248784.368*共12兲
U
Quantum numbers
248749.602*共20兲
248781.110*共12兲
U
Formula
33
SO
Oes99
JPL01
Xu_97
1.8f
Sgr B2共N兲
SEST 15 m
Num98
249323.932*共9兲
CH3 CHO
13共2,12兲⫺12共2,11兲 A⫺⫺
0.89fb
NGC6334F
SEST 15 m
Num98a
Kle96
249326.631*共9兲
CH3 CHO
13共⫺2,12兲⫺12共⫺2,11兲 E
b
NGC6334F
SEST 15 m
Num98a
Kle96
3.9f
Sgr B2共N兲
SEST 15 m
Num98
249365.
unidentified
249397.
unidentified
4.9f
Sgr B2共N兲
SEST 15 m
Num98
249404.737*共16兲
CH2 CHCN
26共3,23兲⫺25共3,22兲 v11 ⫽1
7.9f
Sgr B2共N兲
SEST 15 m
Num98
249419.904*共26兲
CH3 OH
15共3,12兲⫺15共2,13兲 A⫺⫹
23.8f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
249443.402*共50兲
CH3 OH
7共4,4兲⫺8共3,5兲 A⫺
16.9f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
249451.885*共19兲
CH3 OH
7共4,3兲⫺8共3,6兲 A⫹
20.0f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
249491.128*共4兲
CH3 CH2 CN
49共6,44兲⫺49共5,45兲
6.8f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
249519.28*共8兲
CH2 CHCN
26共1,25兲⫺25共1,24兲 v15 ⫽1
9.1f
Sgr B2共N兲
SEST 15 m
Num98
249542.8*共7兲
CH2 CHCN
27共0,27兲⫺26共0,26兲 v11 ⫽2
3.2f
Sgr B2共N兲
SEST 15 m
Num98
249561.244*共19兲
CH3 CH2 CN
36共6,31兲⫺36共5,32兲
6.4f
Sgr B2共N兲
SEST 15 m
Num98
249578.094*共16兲
CH3 OCHO
20共6,15兲⫺19共6,14兲 E
12.5f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
249591.732*共17兲
CH3 OCHO
20共6,15兲⫺19共6,14兲 A
5.1f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
249603.922*共42兲
CH3 OCHO
33共5,29兲⫺33共4,30兲 A
Sgr B2共N兲
SEST 15 m
Num98
Oes99
249623.885*共22兲
c⫺C2 H4 O
5共5,0兲⫺4共4,1兲
2.6f 0.30
Sgr B2共N兲
SEST 15 m
Dic97
5.6f
Sgr B2共M兲
SEST 15 m
Num98
U
249658.
unidentified
5.7f
Sgr B2共N兲
SEST 15 m
Num98
U
249682.
unidentified
4.2f
Sgr B2共N兲
SEST 15 m
Num98
U
249692.
unidentified
3.4f
Sgr B2共N兲
SEST 15 m
Num98
249729.829*共16兲
CH2 CHCN
26共1,25兲⫺25共1,24兲 v11 ⫽1
8.3f
Sgr B2共N兲
SEST 15 m
Num98
249773.360*共15兲
CH3C15N
14共1兲⫺13共1兲
b
Sgr B2共N兲
SEST 15 m
Num98
249778.080*共15兲
CH3C15N CH3 OH unidentified
14共0兲⫺13共0兲
5.0fb
Sgr B2共N兲
SEST 15 m
Num98
14共3,11兲⫺14共2,12兲 A⫺⫹
3.6 3.1f
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
4.0f
Sgr B2共M兲
SEST 15 m
Num98
b
OriMC⫺1
OVRO 10.4 m
Bla86
14共6兲⫺13共6兲
8.3f
Sgr B2共N兲
SEST 15 m
Num98
15共1,14兲⫺14共2,13兲 EE
1.1b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
4.5f
Sgr B2共N兲
SEST 15 m
Num98
249650.186*共11兲
249887.427*共23兲 U
249903. 249907.901*共17兲 249923.816*共8兲 249923.860*共27兲 249924.463*共6兲 249925.110*共8兲 249973.273*共18兲
33
33
SO2
SO2
CH3 OCH3 13
CH3 CN CH3 OCH3 CH3 OCH3 CH3 CH2 CN
6共3,3兲⫺6共2,4兲
13共1,13兲⫺12共0,12兲 15共1,14兲⫺14共2,13兲 AA
15共1,14兲⫺14共2,13兲 AE⫹EA 35共6,30兲⫺35共5,31兲
Xu_97
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
286
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
14共5兲⫺13共5兲
4.5f
Sgr B2共N兲
SEST 15 m
Num98
250005.87* 共13兲
CH3 OCHO
27共1,26兲⫺27共1,27兲 A
2.4fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
250005.90* 共13兲
CH3 OCHO
27共1,26兲⫺27共0,27兲 A
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
250007.45* 共13兲
CH3 OCHO
27共2,26兲⫺27共1,27兲 A
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
3.6f
Sgr B2共N兲
SEST 15 m
Num98
249975.454*共22兲
250017.695*共20兲
13
CH3 CN
14共4兲⫺13共4兲
13
CH3 CN
U
250027.
unidentified
3.5f
Sgr B2共N兲
SEST 15 m
Num98
U
250038.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
250050.567*共20兲
13
14共3兲⫺13共3兲
2.9f 0.6
250074.057*共20兲
13
14共2兲⫺13共2兲
0.5
OriMC⫺1
OVRO 10.4 m
Bla86
250088.154*共21兲
13
14共1兲⫺13共1兲
0.3
OriMC⫺1
OVRO 10.4 m
Bla86
250092.854*共21兲
13
14共0兲⫺13共0兲
0.4
OriMC⫺1
OVRO 10.4 m
Bla86
7共1,6兲⫺7共0,7兲 20共3,17兲⫺19共3,16兲 E
0.22 1.0
OriMC⫺1 OriMC⫺1
NRAO 12 m OVRO 10.4 m
Dic97a Bla86
20共3,17兲⫺19共3,16兲 A 13共3,10兲⫺13共2,11兲 A⫺⫹
0.9 4.2 8.8f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
250161.68* 共30兲 250246.522*共17兲 250258.391*共17兲 U
250291.130*共20兲 250312.
U
CH3 CN CH3 CN
CH3 CN CH2 NH CH3 OCHO CH3 OCHO CH3 OH unidentified
4共3,2兲⫺4共2,3兲
250325. 250332.7*共4兲
CH2 CHCN
250345.
unidentified
3.9f
Sgr B2共M兲
SEST 15 m
Num98
8.2f
Sgr B2共N兲
SEST 15 m
Num98
26共1,25兲⫺25共1,24兲 v11 ⫽2
4.1f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99 Oes99 Xu_97
9共3,7兲⫺9共2,8兲
250364.474*共12兲
SO2 CH3 CH2 CN
6.2f 0.9
27共2,26兲⫺26共1,25兲
9.2f
Sgr B2共N兲
SEST 15 m
Num98
250386.497*共18兲
CH3 CH2 CN
34共6,29兲⫺34共5,30兲
4.3f
Sgr B2共N兲
SEST 15 m
Num98
250410.974*共32兲
CH3 OCHO
8共6,2兲⫺7共5,2兲 E
4.7f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
250436.845*共4兲
NO
39.7fb
Sgr B2共N兲
SEST 15 m
Num98
Win94
250440.337*共10兲
CH3 CH2 CN
250440.656*共4兲
250358.379*共9兲
34
J, F⫽5/2,7/2⫺3/2,5/2 e 28共3,26兲⫺27共3,25兲
2⌸
1/2
1.7w
OriMC⫺1
OVRO 10.4 m
Bla86
NO
2⌸
1/2
J, F⫽5/2,5/2⫺3/2,3/2 e
b
Sgr B2共N兲
SEST 15 m
Num98
Win94
250448.528*共4兲
NO
2⌸
1/2
J, F⫽5/2,3/2⫺3/2,1/2 e
9.4f
Sgr B2共N兲
SEST 15 m
Num98
Win94
250475.422*共4兲
NO
2⌸
1/2
J, F⫽5/2,3/2⫺3/2,3/2 e
10.7f
Sgr B2共N兲
SEST 15 m
Num98
Win94
250482.941共4兲
NO
2⌸
1/2
J, F⫽5/2,5/2⫺3/2,3/2 e 12共2,11兲⫺11共1,10兲
0.3
OriMC⫺1
OVRO 10.4 m
Bla86
Win94
9.9f 5.8
Sgr B2共N兲
SEST 15 m
Num98
5.6fb
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Xu_97 Kle96
250491.595*共23兲 250507.016*共22兲 250524.485*共11兲
t⫺CH3 CH2 OH CH3 OH CH3 CHO
11共0,11兲⫺10共1,10兲 A⫹ 13共7,6兲⫺12共7,5兲 A⫺⫺
250524.485*共11兲
CH3 CHO
13共7,7兲⫺12共7,6兲 A⫹⫹
b
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250550.131*共11兲
CH3 CHO
13共7,7兲⫺12共7,6兲 E
3.7f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250559.093*共10兲
CH3 CHO
13共6,8兲⫺12共6,7兲 A⫺⫺
3.1fb
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250559.097*共10兲
CH3 CHO
13共6,7兲⫺12共6,6兲 A⫹⫹
b
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250569.506*共15兲
CH3 CHO
13共⫺6,7兲⫺12共⫺6,6兲 E
2.2f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250635.144*共18兲
12共3,9兲⫺12共2,10兲 A⫺⫹ 13共⫺5,8兲⫺12共⫺5,7兲 E
5.9
250673.675*共9兲
CH3 OH CH3 CHO
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Xu_97 Kle96
250680.124*共9兲
CH3 CHO
13共5,9兲⫺12共5,8兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250699.6*共5兲
CH3 NH2
8共0兲⫺7共1兲 As⫹⫹
3.4f
Sgr B2共N兲
SEST 15 m
Num98
Num98
250708.244*共4兲
NO
Sgr B2共N兲
SEST 15 m
Num98
Win94
CH3 CHO
2⌸ 1/2 J, F⫽5/2,5/2⫺3/2,5/2 f 13共⫺3,10兲⫺12共⫺3,9兲 E vt ⫽1
3.5f
250738.126*共15兲
2.6f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250767.453*共12兲
OS18O
6共3,4兲⫺6共2,5兲
3.4f
Sgr B2共M兲
SEST 15 m
Num98
250796.426*共4兲
NO
2⌸
1/2
J, F⫽5/2,7/2⫺3/2,5/2 f
22.7f
Sgr B2共N兲
SEST 15 m
Num98
Win94
250815.612*共4兲
NO
2⌸
1/2
J, F⫽5/2,5/2⫺3/2,3/2 f
24.2fb
Sgr B2共N兲
SEST 15 m
Num98
Win94
250816.932*共4兲
NO
2⌸
1/2
b
Sgr B2共N兲
SEST 15 m
Num98
Win94
250829.155*共8兲
CH3 CHO
3.2f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250853.155*共8兲
CH3 CHO
13共⫺4,10兲⫺12共⫺4,9兲 E
8.7f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250882.744*共12兲
CH3 CH2 CN
28共10,*兲⫺27共10,*兲
16.6f
Sgr B2共N兲
SEST 15 m
Num98
250890.447*共12兲
CH3 CH2 CN
28共11,*兲⫺27共11,*兲
8.2f
Sgr B2共N兲
SEST 15 m
Num98
250897.226*共11兲
CH3 CH2 CN
28共9,*兲⫺27共9,*兲
7.1f
Sgr B2共N兲
SEST 15 m
Num98
250924.342*共16兲
CH3 OH
11共3,8兲⫺11共2,9兲 A⫺⫹
50.1f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
250934.551*共9兲
CH3 CHO
13共3,11兲⫺12共3,10兲 A⫹⫹
10.5f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
250943.266*共11兲
CH3 CH2 CN
28共8,21兲⫺27共8,20兲
8.2fb
Sgr B2共N兲
SEST 15 m
Num98
250943.270*共11兲
CH3 CH2 CN
28共8,20兲⫺27共8,19兲
b
Sgr B2共N兲
SEST 15 m
Num98
250952.303*共13兲
CH3 CH2 CN
28共13,*兲⫺27共13,*兲
4.7f
Sgr B2共N兲
SEST 15 m
Num98
22⫺21
4.0f
Sgr B2共N兲
SEST 15 m
Num98
250992.
OCS unidentified
4.1f
Sgr B2共N兲
SEST 15 m
Num98
251000.725*共14兲
CH3 CH2 CN
28共14,*兲⫺27共14,*兲
3.9f
Sgr B2共N兲
SEST 15 m
Num98
251023.365*共39兲
t⫺CH3 CH2 OH CH3 CH2 CN
27共3,25兲⫺27共2,26兲
6.6f
Sgr B2共N兲
SEST 15 m
Num98
28共7,22兲⫺27共7,21兲
11.4fb
Sgr B2共N兲
SEST 15 m
Num98
250965.460*共8兲 U
CH3 CN
OS18O unidentified
250315.134*共12兲 U
Lab. Ref.
251037.791*共11兲
J, F⫽5/2,3/2⫺3/2,1/2 f 13共4,9兲⫺12共4,8兲 E
18
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
12.5fb
MICROWAVE TRANSITIONS
287
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
251037.952*共11兲
CH3 CH2 CN
28共7,21兲⫺27共7,20兲
b
Sgr B2共N兲
SEST 15 m
Num98
251058.517*共14兲
CH3 CH2 CN
28共15,*兲⫺27共15,*兲
3.8f
Sgr B2共N兲
SEST 15 m
Num98
251078.966*共37兲
CH3 CH2CN
41共2,40兲⫺41共1,41兲
5.9f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
251081.305*共37兲
CH3 OCHO
31共4,28兲⫺31共3,29兲 E
5.9f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
251138.714*共42兲
CH3 OCHO
29共2,27兲⫺29共1,28兲 E
4.3f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
251140.801*共10兲
CH3 OCH3
21共5,16兲⫺21共4,17兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
251140.817*共10兲
CH3 OCH3
21共5,16兲⫺21共4,17兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
251142.466*共8兲
CH3 OCH3
21共5,16兲⫺21共4,17兲 EE
4.2fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
251144.122*共10兲
CH3 OCH3
21共5,16兲⫺21共4,17兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
251164.056*共14兲
CH3 OH
10共3,7兲⫺10共2,8兲 A⫺⫹
41.7f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
251192.333 共50兲
CH3 SH
10共⫺1兲⫺9共⫺1兲 E
251199.655*共8兲 251210.575*共7兲 251212.967*共9兲 251264.443*共17兲
SO2 SO2 AlNC CH3 OCHO
13共1,13兲⫺12共0,12兲 8共3,5兲⫺8共2,6兲 21⫺20 20共6,14兲⫺19共6,13兲 E
251271.329*共15兲
CH3 CH2 CN
30共6,24兲⫺30共5,25兲
251285.732*共20兲
CH3 OCHO
251301.712*共23兲
t⫺CH3 CH2 OH
251314.348*共44兲 251314.354*共44兲 251332. 251359.841*共13兲 U
Formula
251375. 251421.22* 共18兲 251428.534*共9兲
Sgr B2共N兲
SEST 15 m
Num98
Sas86
6.3f
IRAS16293⫺2422 IRAS16293⫺2422 IRC⫹10216 Sgr B2共N兲
JCMT 15 m JCMT 15 m IRAM 30 m SEST 15 m
Bla94 Bla94 Ziu02 Num98
Oes99
10.1f
Sgr B2共N兲
SEST 15 m
Num98
20共6,14兲⫺19共6,13兲 A
8.0f
Sgr B2共N兲
SEST 15 m
Num98
7共3,5兲⫺6共2,4兲
5.3f
Sgr B2共N兲
SEST 15 m
Num98
c⫺C3 H2
7共0,7兲⫺6共1,6兲
12.9fb
c⫺C3 H2
7共1,7兲⫺6共2,6兲
unidentified CH3 OH
9共3,6兲⫺9共2,7兲 A⫺⫹
unidentified CH2 NH SO2
6共0,6兲⫺5共1,5兲 10共3,7兲⫺10共2,8兲 v2 ⫽1
10.7f 1.09 0.63 0.005
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
18.2f
Sgr B2共N兲
SEST 15 m
Num98
39.4f
Sgr B2共N兲
SEST 15 m
Num98
6.9f 0.46
Sgr B2共N兲
SEST 15 m
Num98
3.6f
OriMC⫺1 Sgr B2共N兲
NRAO 12 m SEST 15 m
Dic97a Num98
Oes99
Xu_97
251450.167*共11兲
SO2
13共1,13兲⫺12共0,12兲 v2 ⫽1
8.6f
Sgr B2共M兲
SEST 15 m
Num98
251489.283*共9兲
CH3 CHO
13共3,10兲⫺12共3,9兲 A⫺⫺
9.3f
Sgr B2共N兲
SEST 15 m
Num98
251501.407*共10兲
CH3 CH2 CN
28共5,24兲⫺27共5,23兲
11.4f
Sgr B2共N兲
SEST 15 m
Num98
251505.966*共4兲
CH2 CHCN
26共2,24兲⫺25共2,23兲
11.8f
Sgr B2共N兲
SEST 15 m
Num98
251517.269*共13兲
CH3 OH
8共3,5兲⫺8共2,6兲 A⫺⫹
31.5f
Sgr B2共N兲
SEST 15 m
Num98
251527.309*共14兲
c⫺C3 H2
6共2,5兲⫺5共1,4兲
8.1f
Sgr B2共N兲
SEST 15 m
Num98
251566.475*共16兲
t⫺CH3 CH2 OH CH3 OCH3
15共1,15兲⫺14共0,14兲
6.7f
Sgr B2共N兲
SEST 15 m
Num98
251581.691*共8兲
10共2,9兲⫺9共1,8兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
251583.634*共6兲
CH3 OCH3
10共2,9兲⫺9共1,8兲 EE
3.6fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
251585.576*共6兲
CH3 OCH3
10共2,9兲⫺9共1,8兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
251607.120*共10兲
CH3 CH2 CN
28共5,23兲⫺27共5,22兲
9.6f
Sgr B2共N兲
SEST 15 m
Num98
251641.754*共13兲
CH3 OH
7共3,4兲⫺7共2,5兲 A⫺⫹
32.3f
Sgr B2共N兲
SEST 15 m
Num98
251661.030*共18兲
CH3 CH2 CN
10共4,7兲⫺9共3,6兲
5.5f
Sgr B2共N兲
SEST 15 m
Num98
251668.849*共10兲
CH3 CH2 CN
28共4,25兲⫺27共4,24兲
6.1f
Sgr B2共N兲
SEST 15 m
Num98
251714.06*共8兲
CH2 CHCN
26共2,24兲⫺25共2,23兲 v15 ⫽1
2.8f
Sgr B2共N兲
SEST 15 m
Num98
CH3 OH
6共3,3兲⫺6共2,4兲 A⫺⫹ 32共4,28兲⫺32共3,29兲
2.0
OriMC⫺1 Sgr B2共M兲
MMWO 4.9 m SEST 15 m
Cle84 Num98
Xu_97 Xu_97
251738.411*共13兲 251758.357*共47兲 251811.936*共14兲 251825.816*共16兲 251866.511*共15兲
34
SO2 CH3 OH
U
251890.868*共14兲 251895.703*共13兲 251900.439*共15兲 251905.720*共16兲 251917.057*共16兲 251923.671*共12兲 251953. 251984.802*共12兲
SO CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH unidentified CH3 OH
U
252025.
unidentified
5共3,2兲⫺5共2,3兲 A⫺⫹
11.4f 1.2
OriMC⫺1
MMWO 4.9 m
Cle84
52.1f
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m SEST 15 m
Cle84 Cle84 Cle84 Cle84 Cle84 Cle84 Cle84 Cle84 Cle84 Num98
7.6f
Sgr B2共N兲
SEST 15 m
Num98
5共6兲⫺4共5兲 4共3,1兲⫺4共2,2兲 A⫺⫹ 5共3,3兲⫺5共2,4兲 A⫹⫺ 6共3,4兲⫺6共2,5兲 A⫹⫺ 4共3,2兲⫺4共2,3兲 A⫹⫺ 3共3,0兲⫺3共2,1兲 A⫺⫹ 3共3,1兲⫺3共2,2兲 A⫹⫺ 7共3,5兲⫺7共2,6兲 A⫹⫺
3.3 1.5 1.8 2.1 1.7 1.0 1.1 1.8 1.2
8共3,6兲⫺8共2,7兲 A⫹⫺
Kle96
Xu_97
Xu_97
Xu_97 Xu_97 Xu_97 Xu_97 Xu_97 Xu_97 Xu_97 Xu_97
252090.369*共13兲
CH3 OH
9共3,7兲⫺9共2,8兲 A⫹⫺
54.4f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
252107.954*共75兲
CH3 OCHO
31共7,24兲⫺30共8,23兲 A
9.6f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
U
252133.
unidentified
3.6f
Sgr B2共N兲
SEST 15 m
Num98
U
252154.
unidentified
10.9f
Sgr B2共N兲
SEST 15 m
Num98
U
252182.
unidentified
5.9f
Sgr B2共N兲
SEST 15 m
Num98
U
252192.
unidentified
7.6f
Sgr B2共N兲
SEST 15 m
Num98
55.9f
Sgr B2共N兲
SEST 15 m
Num98
252252.807*共14兲
CH3 OH
10共3,8兲⫺10共2,9兲 A⫹⫺
U
252280.
unidentified
2.7f
Sgr B2共N兲
SEST 15 m
Num98
U
252328.
unidentified
2.7f
Sgr B2共N兲
SEST 15 m
Num98
U
252354.
unidentified
4.6f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
288
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
252360.863*共16兲
CH3 OCH3
28共2,26兲⫺28共1,27兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
CH3 OCH3
28共2,26兲⫺28共1,27兲 EE
7.1fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
252366.391*共16兲
CH3 OCH3
28共2,26兲⫺28共1,27兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
252395.180*共7兲
NH2 CHO
3共2,1兲⫺2共1,2兲
6.3f
Sgr B2共N兲
SEST 15 m
Num98
252440.
unidentified
8.9f
Sgr B2共N兲
SEST 15 m
Num98
252464.159 共50兲
CH3 SH
10共0兲⫺9共0兲 E
6.7f
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252485.631*共15兲
CH3 OH
11共3,9兲⫺11共2,10兲 A⫹⫺
30.1f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
252508.348 共50兲
CH3 SH
10共0兲⫺9共0兲 A⫹⫹
7.3f
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252563.945*共12兲
SO2
32共4,28兲⫺31共5,27兲
19.9f
Sgr B2共M兲
SEST 15 m
Num98
252582.442*共15兲
CH3 CH2 CN
28共6,23兲⫺28共5,24兲
7.6f
Sgr B2共N兲
SEST 15 m
Num98
7共3,5兲⫺7共2,6兲
2.6f
Sgr B2共M兲
SEST 15 m
Num98
252591.691*共11兲
33
252615.371*共10兲
34
SO2
9共5,5兲⫺10共4,6兲
7.7f
Sgr B2共M兲
SEST 15 m
Num98
15共2,14兲⫺15共1,15兲 v2 ⫽1
6.8f
Sgr B2共M兲
SEST 15 m
Num98
Sgr B2共M兲
SEST 15 m
Num98
CH3 OH
12共3,10兲⫺12共2,11兲 A⫹⫺
2.1f 4.1
OriMC⫺1
OVRO 10.4 m
Bla86
9共3,7兲⫺9共2,8兲
4.6f
Sgr B2共M兲
SEST 15 m
Num98
252841.551 共50兲
OS18O CH3 SH
10共4兲⫺9共4兲 A⫹⫹
14.3fb
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252841.551 共50兲
CH3 SH
10共4兲⫺9共4兲 A⫺⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252844.091 共50兲
CH3 SH
10共4兲⫺9共4兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252848.436 共50兲
CH3 SH
10共⫺4兲⫺9共⫺4兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252871.368*共14兲
CH3 CH2 CN
27共6,22兲⫺27共5,23兲
13.3f
Sgr B2共N兲
SEST 15 m
Num98
252878.153 共50兲
CH3 SH
10共3兲⫺9共3兲 A⫹⫹
10.7fb
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252880.499 共50兲
CH3 SH
10共3兲⫺9共3兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252882.567 共50兲
CH3 SH
10共⫺3兲⫺9共⫺3兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252882.612 共50兲
CH3 SH
10共3兲⫺9共3兲 A⫺⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Sas86
252896.054*共11兲 252908.6*共5兲
CH3 CH2 CN CH3 NH2
28共4,24兲⫺27共4,23兲
0.7
OriMC⫺1
OVRO 10.4 m
Bla86
252926.
unidentified
252764. 252803.346*共17兲 252814.801*共12兲
U
Quantum numbers
252363.627*共14兲
252731.049*共13兲 U
Formula
252942.
SO2
SO2 unidentified
6共2兲⫺6共⫺1兲 Ea
unidentified
8.1f
Sgr B2共N兲
SEST 15 m
Num98
8.8f
Sgr B2共N兲
SEST 15 m
Num98
7.9f
Sgr B2共N兲
SEST 15 m
Num98
11.6fb
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
252951.131*共25兲
t⫺CH3 CH2 OH
4共4,1兲⫺3共3,0兲
252952.070*共25兲
4共4,0兲⫺3共3,1兲
252966.930*共14兲
t⫺CH3 CH2 OH CH3 CH2 CN
26共6,20兲⫺26共5,21兲
8.4f
Sgr B2共N兲
SEST 15 m
Num98
252967.333 共50兲
CH3 SH
10共⫺2兲⫺9共⫺2兲 E
8.4f
Sgr B2共N兲
SEST 15 m
Num98
10.5f
Sgr B2共N兲
SEST 15 m
Num98
252976. 252984.032 共50兲
unidentified CH3 SH
10.3f
Sgr B2共N兲
SEST 15 m
Num98
unidentified
2.8f
Sgr B2共N兲
SEST 15 m
Num98
253078.
unidentified
7.1f
Sgr B2共N兲
SEST 15 m
Num98
253115.
unidentified
5.3f
Sgr B2共N兲
SEST 15 m
Num98
U
253058.
U U
10共2兲⫺9共2兲 E
253124.169 共50兲
CH3 SH
10共2兲⫺9共2兲 A⫹⫹
5.8f
Sgr B2共N兲
SEST 15 m
Num98
253134.792*共14兲
CH3 CH2 CN
26共6,21兲⫺26共5,22兲
8.1f
Sgr B2共N兲
SEST 15 m
Num98
253165.778*共8兲
NH2 CHO
12共2,11兲⫺11共2,10兲
22.6f 3.0
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
3.1
OVRO 10.4 m SEST 15 m
Bla86 Num98
253207.034*共16兲
6共6兲⫺5共5兲
34
253221.340*共19兲 253257.907*共14兲
SO CH3 OH CH3 CH2 CN
13共3,11兲⫺13共2,12兲 A⫹⫺ 25共6,19兲⫺25共5,20兲
9.8f
OriMC⫺1 Sgr B2共N兲
253266.009*共19兲
CH3 CH2 CN
5共5,1兲⫺4共4,0兲
8.5fb
Sgr B2共N兲
SEST 15 m
Num98
253266.010*共19兲
CH3 CH2 CN
5共5,0兲⫺4共4,1兲
b
Sgr B2共N兲
SEST 15 m
Num98
U
253308.
unidentified
5.1f
Sgr B2共N兲
SEST 15 m
Num98
U
253352.
unidentified
11.3f
Sgr B2共N兲
SEST 15 m
Num98
U
253362.
unidentified
10.1f
Sgr B2共N兲
SEST 15 m
Num98
253372.836*共14兲
CH3 CH2 CN
25共6,20兲⫺25共5,21兲
9.4f
Sgr B2共N兲
SEST 15 m
Num98
253392.037*共40兲
CH3 OCHO
28共10,18兲⫺28共9,19兲 E
6.5f
Sgr B2共N兲
SEST 15 m
Num98
253401.
unidentified
9.1f
Sgr B2共N兲
SEST 15 m
Num98
253423.
unidentified
253497.404*共18兲 253508.682*共14兲
OS18O CH3 CH2 CN
253537.
unidentified
U U
U
U
14共1,14兲⫺13共0,13兲 24共6,18兲⫺24共5,19兲
253545.519*共10兲
NH2 CHO
253570.406*共20兲
NS
2⌸
253570.735*共20兲
NS
2⌸
253572.148共7兲
NS
2⌸
253586.052*共14兲
CH3 CH2 CN
253594.
unidentified
253605.972*共20兲
NS
8共2,7兲⫺8共0,8兲
2⌸
4.2f
Sgr B2共N兲
SEST 15 m
Num98
5.1f
Sgr B2共M兲
SEST 15 m
Num98
3.5f
Sgr B2共N兲
SEST 15 m
Num98
7.0f
Sgr B2共N兲
SEST 15 m
Num98
7.4f
Sgr B2共N兲
SEST 15 m
Num98
56.6fb
Sgr B2共N兲
SEST 15 m
Xu_97
Num98
Sas86
Sas86
Sas86
Xu_97
Oes99
1/2
J, F⫽5.5,6.5⫺4.5,5.5 e
Num98
Lee95
1/2
J, F⫽5.5,5.5⫺4.5,4.5 e
b
Sgr B2共N兲
SEST 15 m
Num98
Lee95
J, F⫽5.5,4.5⫺4.5,3.5 e 24共6,19兲⫺24共5,21兲
b
Sgr B2共N兲
SEST 15 m
Num98
Lee95
9.0f
Sgr B2共N兲
SEST 15 m
Num98
4.7f
Sgr B2共N兲
SEST 15 m
Num98
J, F⫽5.5,4.5⫺4.5,4.5 e
11.4fb
Sgr B2共N兲
SEST 15 m
Num98
1/2
1/2
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Lee95
MICROWAVE TRANSITIONS
289
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
253610.002共3兲 253619.61* 共18兲 U
253629.
2
⌸
1/2
J, F⫽5.5,5.5⫺4.5,5.5 e 28⫺27
HC13CCN unidentified
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
b
Sgr B2共N兲
SEST 15 m
Num98
Lee95
11.4f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
6.0f
Sgr B2共N兲
SEST 15 m
Num98
HCC13CN CH3 OCHO
28⫺27
18.7f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
253660.115*共48兲
28共10,19兲⫺28共9,20兲 E
7.3f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
253683.707*共7兲
NH2 CHO
11共1,11兲⫺10共0,10兲
Num98
253643.580*共72兲
SEST 15 m
6⫺5 v⫽2
25.4f 4.0
Sgr B2共N兲 VYCMa
IRAM 30 m
Cer92
253717.539*共50兲
SiO CH3 OCHO
28共10,18兲⫺28共9,20兲 E
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
253718.237*共40兲
CH3 OCHO
23共4,19兲⫺22共5,18兲 E
9.3fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
253724.193*共14兲
CH3 CH2 CN
23共6,17兲⫺23共5,18兲
5.5f
Sgr B2共N兲
SEST 15 m
Num98
253755.783*共22兲
CH3 OH CH3 OCHO
14共3,12兲⫺14共2,13兲 A⫹⫺ 23共4,19兲⫺22共5,18兲 A
0.73 6.0f
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84b Num98
Xu_97 Oes99 Num98
253703.23* 共14兲
253766.948*共48兲
29
CH3 NH2
6共⫺2兲⫺6共⫺1兲 Es
6.2f
Sgr B2共N兲
SEST 15 m
Num98
253775.338*共14兲
CH3 CH2 CN
23共6,18兲⫺23共5,19兲
4.7f
Sgr B2共N兲
SEST 15 m
Num98
253768.2*共5兲
U
NS
Quantum numbers
253802.
unidentified
3.4f
Sgr B2共N兲
SEST 15 m
Num98
253825.381*共5兲
CH2 CHCN
3共3,1兲⫺2共2,0兲
2.8fb
Sgr B2共N兲
SEST 15 m
Num98
253828.873*共5兲
CH2 CHCN
3共3,0兲⫺2共2,1兲
b
Sgr B2共N兲
SEST 15 m
Num98
253904.677*共10兲
CH3 OCH3
20共5,15兲⫺20共4,16兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
253904.710*共10兲
CH3 OCH3
20共5,15兲⫺20共4,16兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
253906.554*共8兲
CH3 OCH3
20共5,15兲⫺20共4,16兲 EE
Sgr B2共N兲
SEST 15 m
Num98
Gro98
253908.413*共12兲
CH3 OCH3
20共5,15兲⫺20共4,16兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
253908.706*共14兲
CH3 CH2CN
22共6,16兲⫺22共5,17兲
16.3f
Sgr B2共N兲
SEST 15 m
Num98
253936.313*共10兲
34 SO2 CH3 CH2 CN
11共3,9兲⫺11共2,10兲
29.6f
Sgr B2共M兲
SEST 15 m
Num98
22共6,17兲⫺22共5,18兲
14.1f
Sgr B2共N兲
SEST 15 m
Num98
253956.546*共7兲
SO2
15共6,10兲⫺16共5,11兲
40.9f
Sgr B2共M兲
SEST 15 m
Num98
253968.393共4兲
NS
2⌸
1/2
J, F⫽5.5,6.5⫺4.5,5.5 f
57.1fb
Sgr B2共N兲
SEST 15 m
Num98
Lee95
253970.581共3兲
NS
2⌸
1/2
J, F⫽5.5,4.5⫺4.5,3.5 f
b
Sgr B2共N兲
SEST 15 m
Num98
Lee95
253970.581共3兲
NS
2⌸
1/2
J, F⫽5.5,5.5⫺4.5,4.5 f 2共0,2兲⫺1共⫺1,1兲 E 4共⫺1兲⫺3共0兲 Ea
b
Sgr B2共N兲
SEST 15 m
Num98
Lee95
0.95
MMWO 4.9 m SEST 15 m
Lor84 Num98
Xu_97 Num98
253941.855*共14兲
254015.367*共15兲
CH3 OH CH3 NH2
16.5fb
5.0f
OriMC⫺1 Sgr B2共N兲
U
254063.
unidentified
6.0f
Sgr B2共N兲
SEST 15 m
Num98
U
254080.
unidentified
11.7f
Sgr B2共N兲
SEST 15 m
Num98
254103.175*共19兲 254137.467*共4兲
SiS CH2 CHCN
IRC⫹10216 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Sah84 Num98 Lor84b
254055.8*共5兲
254216.29* 共14兲
11.1f 0.6
OriMC⫺1
MMWO 4.9 m
c⫺C2 H4 O
8共1,7兲⫺7共2,6兲
0.57
Sgr B2共N兲
SEST 15 m
Dic97
254235.701*共25兲
c⫺C2 H4 O
8共2,7兲⫺7共1,6兲
1.06f
NGC6334F
SEST 15 m
Num98a
30
SiO
6⫺5 v⫽0
0.85
254231.776*共25兲
254277.654*共44兲
28共4,24兲⫺28共3,25兲
b
W3共IRS5兲
JCMT 15 m
Hel97
254280.527*共7兲
SO2
6共3,3兲⫺6共2,4兲
b
W3共IRS5兲
JCMT 15 m
Hel97
254283.326*共12兲
SO2
24共2,22兲⫺24共1,23兲
2.09b
W3共IRS5兲
JCMT 15 m
Hel97
254311.091*共14兲
CH3 CH2 CN
19共6,13兲⫺19共5,14兲
11.1f
Sgr B2共N兲
SEST 15 m
Num98
254318.956*共14兲
CH3 CH2 CN
254321.787*共20兲 254384.040*共22兲
34
SO2
13
CH3 OH
254423.511*共25兲 254481.340*共15兲
t⫺CH3 CH2 OH CH3 OH CH3 CH2 CN
254483.861*共15兲
CH3 CH2 CN
254509.349*共20兲 254510.013*共11兲
19共6,14兲⫺19共5,15兲
12.3f
Sgr B2共N兲
SEST 15 m
Num98
4共2,2兲⫺5共1,5兲 A⫹⫹
12.3f
Sgr B2共N兲
SEST 15 m
Num98
7共3,4兲⫺6共2,5兲
Sgr B2共N兲
SEST 15 m
Num98
15共3,13兲⫺15共2,14兲 A⫹⫺
4.7f 3.0
OriMC⫺1
OVRO 10.4 m
Bla86
17共6,11兲⫺17共5,12兲
5.2fb
Sgr B2共N兲
SEST 15 m
Num98
17共6,12兲⫺17共5,13兲
Num98
b
Sgr B2共N兲
SEST 15 m
10共3,7兲⫺10共2,8兲 A⫺⫹
5.6f
Sgr B2共N兲
SEST 15 m
Num98
SO2
9共3,7兲⫺9共2,8兲
7.7f
Sgr B2共M兲
SEST 15 m
Num98
SO2
14共6,8兲⫺15共5,11兲
13
CH3 OH 33
7.7f
Sgr B2共M兲
SEST 15 m
Num98
5.1f
Sgr B2共N兲
SEST 15 m
Num98
16共6,10兲⫺16共5,11兲
5.7fb
Sgr B2共N兲
SEST 15 m
Num98
CH3 CH2 CN
16共6,11兲⫺16共5,12兲
b
Sgr B2共N兲
SEST 15 m
Num98
CH2 CHCN
27共2,26兲⫺26共2,25兲 v15 ⫽1
6.0f
Sgr B2共N兲
SEST 15 m
Num98
21⫺20
6.0f
Sgr B2共N兲
SEST 15 m
Num98
254573.610*共80兲 254586.635*共77兲
O13CS SO NH2 CHO
8共9兲⫺8共8兲 19共6,14兲⫺20共5,15兲
0.39
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84 Num98
254633.218*共16兲
CH3 CH2 CN
14共6,8兲⫺14共5,9兲
6.9fb
Sgr B2共N兲
SEST 15 m
Num98
254633.597*共16兲
CH3 CH2 CN
14共6,9兲⫺14共5,10兲
b
Sgr B2共N兲
SEST 15 m
Num98
254663.179*共16兲
CH3 CH2 CN
13共6,7兲⫺13共5,8兲
8.5fb
Sgr B2共N兲
SEST 15 m
Num98
254663.359*共16兲
CH3 CH2 CN
13共6,8兲⫺13共5,9兲
b
Sgr B2共N兲
SEST 15 m
Num98
254685.07* 共18兲
CH2 NH
4共0,4兲⫺3共0,3兲
Sgr B2共N兲
SEST 15 m
Num98
254699.490*共10兲
HCCCN
28⫺27
36.4f 5.0
OriMC⫺1
OVRO 10.4 m
Bla86
254516.763*共13兲 U
14⫺13 27共2,26兲⫺26共2,25兲
34
254536.
unidentified
254543.911*共15兲
CH3 CH2 CN
254545.347*共15兲 254551.67*共8兲 254552.727*共13兲
10.0f
Xu_97
Xu_97
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
290
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Source
Telescope
Astr. Ref.
21.8fb
CH3 CH2 CN
10共6,4兲⫺10共5,5兲
Sgr B2共N兲
SEST 15 m
Num98
10共6,5兲⫺10共5,6兲
b
Sgr B2共N兲
SEST 15 m
Num98
254716.683*共18兲
CH3 CH2 CN
9共6,3兲⫺9共5,4兲
b
Sgr B2共N兲
SEST 15 m
Num98
254716.687*共18兲
CH3 CH2 CN
9共6,4兲⫺9共5,5兲
b
Sgr B2共N兲
SEST 15 m
Num98
254717.373*共18兲
CH3 CH2 CN
6共6,*兲⫺6共5,*兲
b
Sgr B2共N兲
SEST 15 m
Num98
254719.098*共18兲
CH3 CH2 CN
7共6,*兲⫺7共5,*兲
b
Sgr B2共N兲
SEST 15 m
Num98
254719.127*共18兲
CH3 CH2 CN
8共6,*兲⫺8共5,*兲
b
Sgr B2共N兲
SEST 15 m
Num98
254726.974*共31兲
NH2 CHO
12共9,3兲⫺11共9,2兲
8.1fb
Sgr B2共N兲
SEST 15 m
Num98
254726.974*共31兲
NH2 CHO
12共9,4兲⫺11共9,3兲
b
Sgr B2共N兲
SEST 15 m
Num98
254727.263*共25兲
NH2 CHO
12共8,4兲⫺11共8,3兲
b
Sgr B2共N兲
SEST 15 m
Num98
254727.263*共25兲
NH2 CHO
12共8,5兲⫺11共8,4兲
b
Sgr B2共N兲
SEST 15 m
Num98
254743.791*共20兲
NH2 CHO
12共7,5兲⫺11共7,4兲
Sgr B2共N兲
SEST 15 m
Num98
254743.791*共20兲
NH2 CHO
12共7,6兲⫺11共7,5兲
Sgr B2共N兲
SEST 15 m
Num98
254786.398*共16兲
NH2 CHO
12共6,7兲⫺11共6,6兲
Sgr B2共N兲
SEST 15 m
Num98
254786.401*共16兲
NH2 CHO
12共6,6兲⫺11共6,5兲
b
Sgr B2共N兲
SEST 15 m
Num98
254827.143*共10兲
CH3 CHO
13共2,11兲⫺12共2,10兲 E
Sgr B2共M兲
SEST 15 m
Num98
Kle96
254841.836*共19兲
13
8共3,5兲⫺8共2,6兲 A⫺⫹
6.2f 0.7
OriMC⫺1
OVRO 10.4 m
Sut88
Xu_97 Kle96
14.0fb b
10.0fb
254850.487*共10兲
CH3 OH CH3 CHO
13共2,11兲⫺12共2,10兲 A⫹⫹
6.8f
Sgr B2共M兲
SEST 15 m
Num98
254876.293*共12兲
NH2 CHO
12共5,8兲⫺11共5,7兲
20.3fb
Sgr B2共N兲
SEST 15 m
Num98
254876.610*共12兲
NH2 CHO
Num98
254959.414*共16兲
13
254976.352*共11兲 254976.353*共11兲
CH3 OH CH3 CH2 CN CH3 CH2 CN
254977.935 共20兲
SO⫹
254987.648*共6兲
b
Sgr B2共N兲
SEST 15 m
7共3,4兲⫺7共2,5兲 A⫺⫹
12共5,7兲⫺11共5,6兲
1.2
OriMC⫺1
OVRO 10.4 m
Bla86
29共2,28兲⫺28共2,27兲 29共2,28兲⫺28共2,27兲
1.5
OVRO 10.4 m SEST 15 m
Bla86 Num98
29.9f
OriMC⫺1 Sgr B2共N兲
15.4f
Sgr B2共M兲
SEST 15 m
Num98
13.9f
Sgr B2共M兲
SEST 15 m
Num98
255002.604*共18兲
c⫺C3 H2 CH3 CH2 CN
1/2 J⫽11/2⫺9/2 5共3,3兲⫺4共2,2兲
17共3,15兲⫺16共2,14兲
5.6f
Sgr B2共N兲
SEST 15 m
Num98
255016.04* 共10兲
CH2 NH
8共3,5兲⫺9共2,8兲
Sgr B2共N兲
SEST 15 m
Num98
255050.260 共59兲 255050.985*共16兲
HDO
5共2,3兲⫺4共3,2兲 6共3,3兲⫺6共2,4兲 A⫺⫹
7.5f 2.1 n.r.
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86
13
2⌸
Ama91
DeL71 Xu_97
255058.504*共10兲
12共4,9兲⫺11共4,8兲
21.4f
Sgr B2共N兲
SEST 15 m
Num98
255071.237*共11兲
CH3 CH2 CN
28共2,26兲⫺27共2,25兲
11.7f
Sgr B2共N兲
SEST 15 m
Num98
255078.883*共10兲
NH2 CHO
12共4,8兲⫺11共4,7兲
15.1f
Sgr B2共N兲
SEST 15 m
Num98
255119.11* 共92兲
HCCCN
28⫺27 v6 ⫽1 ᐉ⫽1 e
Sgr B2共N兲
SEST 15 m
Num98
Laf78
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
Num98
255158.
255184.
13
5共3,2兲⫺5共2,3兲 A⫺⫹
22.8f 1.7
SEST 15 m
4共3,1兲⫺4共2,2兲 A⫺⫹
4.3f 1.2
Sgr B2共N兲
13
OriMC⫺1
OVRO 10.4 m
Bla86
10.7f
Sgr B2共N兲
SEST 15 m
Num98
CH3 OH unidentified CH3 OH unidentified
Xu_97
255192.391*共16兲
13
5共3,3兲⫺5共2,4兲 A⫹⫺
b
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
255193.491*共16兲
13
6共3,4兲⫺6共2,5兲 A⫹⫺
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
255203.725*共18兲
13
4共3,2兲⫺4共2,3兲 A⫹⫺
1.8b 1.3
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
255210.596*共20兲
13
3共3,0兲⫺3共2,1兲 A⫺⫹
0.6
OriMC⫺1
OVRO 10.4 m
Sut88
Xu_97
255214.890*共16兲
13
CH3 OH
7共3,5兲⫺7共2,6兲 A⫹⫺
1.0
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
255220.861*共20兲
13 CH3 OH NH2 CHO
3共3,1兲⫺3共2,2兲 A⫹⫺
0.9
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
12共3,10兲⫺11共3,9兲
22.3f
Sgr B2共N兲
SEST 15 m
Num98
CH3 OH unidentified
16共3,14兲⫺16共2,15兲 A⫹⫺
3.8
255256.
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
255264.930*共17兲
CH3 CH2 CN
Num98
255265.639*共19兲 255316.5*共11兲 255324.34* 共11兲 255353.237 共20兲 255355.916*共23兲
CH3 OH CH3 OH CH3 OH CH3 OH
13
6.3f 15共3,12兲⫺14共2,13兲
Sgr B2共N兲
SEST 15 m
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
20.8f 1.0
Sgr B2共N兲
SEST 15 m
Num98
Laf78
OriMC⫺1
OVRO 10.4 m
Bla86
Laf78
⌸1/2 J⫽11/2⫺9/2 f 9共3,7兲⫺9共2,8兲 A⫹⫺
0.13
Sgr B2共N兲
NRAO 12 m
Tur94a
Ama91
1.0
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
6.5
OVRO 10.4 m SEST 15 m
Bla86 Num98
Kle96 Num98
28⫺27 v6 ⫽1 ᐉ⫽1 f
HCCCN
28⫺27 v7 ⫽1 ᐉ⫽1 e
SO⫹ 13
2
255374.453*共2兲 255384.756*共10兲
CH3 OH OCS CH3 CHO
21⫺20 13共1,12兲⫺12共1,11兲 A⫺⫺
12.0f
OriMC⫺1 Sgr B2共N兲
255444.1*共5兲
CH3 NH2
9共⫺2兲⫺9共⫺1兲 Ea
9.6f
Sgr B2共N兲
SEST 15 m
Num98
255456.
unidentified
4.8f
Sgr B2共N兲
SEST 15 m
Num98
U
255466.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
6⫺5 v⫽1
3.1f 4.0
VYCMa
IRAM 30 m
Cer92
3⫺2
1.0
OriMC⫺1
OVRO 10.4 m
Bla86
Sgr B2共N兲
SEST 15 m
Num98
10共3,8兲⫺10共2,9兲 A⫹⫺
2.8f 0.8
OriMC⫺1
OVRO 10.4 m
Bla86
Sgr B2共N兲
SEST 15 m
Num98
4共3,1兲⫺4共2,2兲
3.7f 7.4
OriMC⫺1
OVRO 10.4 m
Bla86
255478.30* 共12兲 255479.389 共10兲 255487. 255496.963*共30兲 255520. 255553.294*共7兲
29
SiO
HC18O⫹ unidentified 13
CH3 OH
Xu_97
10.5f 1.4
8共3,6兲⫺8共2,7兲 A⫹⫺
CH3 OH HCCCN
U
U
Xu_97
CH3 OH NH2 CHO
255241.905*共29兲
U
Lab. Ref.
CH3 CH2 CN
255225.630*共9兲 U
T r 共K兲/T a 共K兲
254710.892*共17兲
255172.998*共18兲 U
Quantum numbers
254710.904*共17兲
255120.895*共16兲 U
Formula
unidentified SO2
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Plu83
Xu_97
MICROWAVE TRANSITIONS
291
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
HOCO⫹ unidentified
12共1,12兲⫺11共1,11兲
255595.391*共32兲
SO2
255596.896共6兲
NS
255600.379共3兲 255602.964共3兲
255564.159*共57兲 U
U
255573.
255633. 255639.83* 共24兲 255689.08* 共11兲 255701.008*共38兲
U
U255729.
U
U
U U
SEST 15 m
Num98
SEST 15 m
Num98
51共7,45兲⫺50共8,42兲
0.4v
OriMC⫺1
OVRO 10.4 m
Bla86
2
⌸3/2 J, F⫽5.5,6.5⫺4.5,5.5
18.8fb
Sgr B2共N兲
SEST 15 m
Num98
Lee95
NS
2
⌸3/2 J, F⫽5.5,5.5⫺4.5,4.5
b
Sgr B2共N兲
SEST 15 m
Num98
Lee95
NS
2
⌸3/2 J, F⫽5.5,4.5⫺4.5,3.5
b
Sgr B2共N兲
SEST 15 m
Num98
Lee95
14.4f
Sgr B2共N兲
SEST 15 m
Num98
33
SO
HCCCN 13
CH3 OH
29⫺28
5.2f
Sgr B2共N兲
SEST 15 m
Num98
6共6兲⫺5共5兲
8.7f 1.1
Sgr B2共M兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
Laf78
8.9f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
3.3f 1.0
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
1.0
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99
W51 Sgr B2共N兲
NRAO 12 m SEST 15 m
Dic97a Num98
Sgr B2共M兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1
OVRO 10.4 m BTL 7 m
Bla86 Tha81
28⫺27 v7 ⫽1 ᐉ⫽1 f 11共3,9兲⫺11共2,10兲 A⫹⫺
unidentified
255818.387*共19兲
SO2
21共4,18兲⫺20共4,17兲 A 44共6,38兲⫺43共7,37兲
255840.21* 共29兲 255871.810*共9兲
CH2 NH NH2 CHO
4共2,3兲⫺3共2,2兲 12共3,9兲⫺11共3,8兲
34
SO2
CH3 CH2 CN SO2 13
CH3 OH CH3 NH2
21共4,18兲⫺20共4,17兲 E
19共7,13兲⫺20共6,14兲 28共3,25兲⫺27共3,24兲 3共3,1兲⫺3共2,2兲
2.4f 0.03 17.9f 2.3f 0.9 ⬎3.
Laf78
12共3,10兲⫺12共2,11兲 A⫹⫺
0.5
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
4共2兲⫺4共⫺1兲 Aa⫹⫺
Sgr B2共N兲
SEST 15 m
Num98
Num98
6⫺5
W3共IRS5兲
JCMT 15 m
Hel97
256049.474*共28兲
HCS⫹ CH3 OCHO
10.3f 0.16
26共10,16兲⫺26共9,17兲 A
5.3f
Sgr B2共N兲
SEST 15 m
Num98
256060.154*共30兲
CH3 CHO
18共3,18兲⫺18共2,17兲 A⫹⫺
5.3f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
256071.124*共32兲
CH3 OCHO
26共10,16兲⫺26共9,17兲 E
5.1f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
256081.
unidentified
5.1f
Sgr B2共N兲
SEST 15 m
Num98
256091.96* 共23兲
6.9f
Sgr B2共N兲
SEST 15 m
Num98
256135.123*共10兲
OS17O CH3 OCH3
19共5,14兲⫺19共4,15兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
256135.190*共10兲
CH3 OCH3
19共5,14兲⫺19共4,15兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
256137.199*共6兲
CH3 OCH3
19共5,14兲⫺19共4,15兲 EE
Sgr B2共N兲
SEST 15 m
Num98
Gro98
256139.241*共12兲
CH3 OCH3
19共5,14兲⫺19共4,15兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
256160.781*共11兲
CH3 CCH
15共6兲⫺14共6兲
3.8f
Sgr B2共M兲
SEST 15 m
Num98
256165.7*共43兲
CH2 NH
4共3,2兲⫺3共3,1兲
12.0f
Sgr B2共N兲
SEST 15 m
Num98
256176.71* 共43兲
CH2 NH
4共3,1兲⫺3共3,0兲
8.0f
Sgr B2共N兲
SEST 15 m
Num98
256206.216*共3兲
15共2,14兲⫺14共2,13兲 vt ⫽0⫺0
5.6f
Sgr B2共N兲
SEST 15 m
Num98
256214.468*共8兲
g⫺CH3 CH2 OH CH3 CCH
15共5兲⫺14共5兲
Sgr B2共N兲
SEST 15 m
Num98
256228.765*共35兲 256246.937*共7兲 256258.423*共5兲
CH3 OH SO2 CH3 CCH
17共3,15兲⫺17共2,16兲 A⫹⫺ 5共3,3兲⫺5共2,4兲 15共4兲⫺14共4兲
6.8f 1.7 1.2
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m MMWO 4.9 m SEST 15 m
Bla86 Lor84b Num98
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84b Num98
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m SEST 15 m
Lor84b Lor84b Lor84b Num98
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
256027.111*共22兲
U
Lab. Ref.
Sgr B2共N兲
CH3 OCHO CH3 OCHO
255999.5*共5兲
Astr. Ref.
Sgr B2共N兲
H13CCCN
255892.271*共19兲
Telescope
5.4f
255776.135*共16兲 255789.443*共16兲
255906.479*共11兲 255958.037*共7兲 255981.193*共50兲
Source
1.7f
unidentified
255651.323*共16兲
T r 共K兲/T a 共K兲
256274.
15共0,15兲⫺14共1,14兲
unidentified
11.4fb
1540f 11.0f 0.3
256292.627*共4兲 256310.77* 共17兲
CH3 CCH HCCCN
15共3兲⫺14共3兲 28⫺27 v7 ⫽2 ᐉ⫽2 e
16.6f
256317.069*共3兲
CH3 CCH CH3 CCH CH3 CCH
15共2兲⫺14共2兲 15共1兲⫺14共1兲 15共0兲⫺14共0兲
0.3 0.4 0.4 8.9f 1.0
256331.737*共3兲 256336.627*共3兲 256351.
unidentified
256366.14* 共25兲
HCCCN
28⫺27 v7 ⫽2 ᐉ⫽2 f
256395.934*共11兲 256397.423*共5兲
CH3 CH2 CN CH2 CHCN
29共1,28兲⫺28共1,27兲 27共7,*兲⫺26共7,*兲
256409.07* 共29兲 256425.85* 共16兲
CH2 CHCN CH2 CHCN
27共8,*兲⫺26共8,*兲 27共6,22兲⫺26共6,21兲
256425.95* 共16兲
CH2 CHCN
27共6,21兲⫺26共6,20兲
256447.75* 共28兲 256506.569*共5兲
CH2 CHCN CH2 CHCN
27共9,*兲⫺26共9,*兲 27共10,*兲⫺26共10,*兲
256522.86* 共13兲 256527.36* 共13兲 256566.278*共43兲
CH2 CHCN CH2 CHCN
10.2f 0.8 0.5
6.5f
27共5,23兲⫺26共5,22兲 27共5,22兲⫺26共5,21兲 12共0,12兲⫺11共0,11兲
256576.351*共4兲
HOCO⫹ CH2 CHCN
256580.971*共6兲
CH2 CHCN
27共11,*兲⫺26共11,*兲
256585.558*共11兲 256622.
HDCO unidentified
4共0,4兲⫺3共0,3兲
256632.
unidentified
256668.790*共7兲
CH2 CHCN
256671.783*共21兲
13
CH3 OH
27共3,25兲⫺26共3,24兲
27共12,*兲⫺26共12,*兲 9共0,9兲⫺8共1,7兲 E
17.9f 0.7
OriMC⫺1
OVRO 10.4 m
Bla86
0.7b
OriMC⫺1
OVRO 10.4 m
Bla86
b
OriMC⫺1
OVRO 10.4 m
Bla86
0.4
OriMC⫺1
OVRO 10.4 m
Bla86
Sgr B2共N兲
SEST 15 m
Num98
5.6f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
21.4fb
Sgr B2共N兲
SEST 15 m
Num98
b
Sgr B2共N兲
SEST 15 m
Num98
0.54 3.7f
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor85 Num98
3.2f
Sgr B2共N兲
SEST 15 m
Num98
8.5f 0.5
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
JPL01
Xu_97
Laf78
Laf78
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
292
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
256711.75* 共11兲 256725.
CH2 CHCN unidentified
27共4,24兲⫺26共4,23兲
0.3 4.4f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
256736.68* 共16兲
CH2 CHCN
27共7,*兲⫺26共7,*兲 v15 ⫽1
4.2f
Sgr B2共N兲
SEST 15 m
Num98
256756.33* 共13兲
CH2 CHCN
27共6,22兲⫺26共6,21兲 v15 ⫽1
7.6fb
Sgr B2共N兲
SEST 15 m
Num98
256756.41* 共13兲
CH2 CHCN
27共6,21兲⫺26共6,20兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
256756.68* 共19兲
CH2 CHCN
27共8,*兲⫺26共8,*兲 v15 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
256768.502*共9兲
CH2 CHCN
27共13,*兲⫺26共13,*兲
8.5f
Sgr B2共N兲
SEST 15 m
Num98
256785.415*共37兲
CH3 OCHO
36共6,31兲⫺36共5,32兲 A
3.5f
Sgr B2共N兲
SEST 15 m
Num98
256803.26* 共23兲
CH2 CHCN
27共9,*兲⫺26共9,*兲 v15 ⫽1
9.7f
Sgr B2共N兲
SEST 15 m
Num98
CH3 CN
14共12兲⫺13共12兲
3.7f
Sgr B2共N兲
SEST 15 m
Num98
5.5f 0.3
Sgr B2共N兲
SEST 15 m
Num98
8.4fb
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
b
256817.173*共22兲 U
256826.
unidentified
256837.22* 共11兲 256842.41* 共10兲
CH2 CHCN CH2 CHCN
27共4,23兲⫺26共4,22兲 27共5,23兲⫺26共5,22兲 v15 ⫽1
256846.29* 共10兲
CH2 CHCN
27共5,22兲⫺26共5,21兲 v15 ⫽1
256863.936*共5兲
CH2 CHCN
28共1,28兲⫺27共1,27兲
256877.810*共30兲
SO SiO CH2 CHCN
6⫺5 v⫽2 27共3,25兲⫺26共3,24兲 v15 ⫽1
256952.01* 共30兲
CH2 CHCN
27共11,*兲⫺26共11,*兲 v15 ⫽1
256957.
unidentified
256966.892*共13兲 256999.700*共17兲
CH3 CH2 CN CH2 CHCN
256898.37* 共14兲 256904.30*共8兲
U
U
30共0,30兲⫺29共1,29兲 27共15,*兲⫺26共15,*兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
MMWO 4.9 m
Lor84
3.5 5.9f
VYCMa Sgr B2共N兲
IRAM 30 m SEST 15 m
Cer93 Num98
1.9f
Sgr B2共N兲
SEST 15 m
Num98
4.2f 0.2
Sgr B2共N兲
SEST 15 m
Num98
8.8f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
5.8f
Sgr B2共N兲
SEST 15 m
Num98
4.7f 0.3
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
257015.
unidentified
257020.20*共9兲
CH2 CHCN
27共4,24兲⫺26共4,23兲 v15 ⫽1
257033.461*共15兲 257048.570*共10兲
CH3 CN CH3 OCH3
14共10兲⫺13共10兲 18共2,16兲⫺17共3,15兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
257049.891*共10兲
CH3 OCH3
18共2,16兲⫺17共3,15兲 EE
7.4fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
257051.212*共12兲
CH3 OCH3
18共2,16兲⫺17共3,15兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
257060.879*共18兲
t⫺CH3 CH2 OH CH3 OCHO
16共1,15兲⫺15共2,14兲
5.2f
Sgr B2共N兲
SEST 15 m
Num98
22共2,20兲⫺21共3,19兲 A
9.8f
Sgr B2共N兲
SEST 15 m
Num98
7共3,5兲⫺7共2,6兲 28共2,27兲⫺27共1,26兲
7.9
257103.583*共13兲
SO2 CH3 CH2 CN
OriMC⫺1 OriMC⫺1
OVRO 10.4 m JCMT 15 m
Bla86 Gre91
257106.443*共12兲
CH3 CH2 CN
30共1,29兲⫺29共2,28兲
b
OriMC⫺1
JCMT 15 m
Gre91
257112.54* 共28兲
CH2 NH
4共2,2兲⫺3共2,1兲
21.6f
Sgr B2共N兲
SEST 15 m
Num98
257127.054*共12兲
CH3 CN CH2 CHCN
14共9兲⫺13共9兲 27共4,23兲⫺26共4,22兲 v15 ⫽1
0.6
257132.25*共9兲
7.9f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
257139.308*共17兲
CH2 CHCN
27共7,*兲⫺26共7,*兲 v11 ⫽1
7.9fb
Sgr B2共N兲
SEST 15 m
Num98
257141.092*共18兲
CH2 CHCN
27共8,*兲⫺26共8,*兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
257158.535*共36兲
14共7兲⫺13共7兲
2.7f
Sgr B2共N兲
SEST 15 m
Num98
257170.283*共20兲
CH3 13CN CH2 CHCN
27共9,*兲⫺26共9,*兲 v11 ⫽1
3.5f
Sgr B2共N兲
SEST 15 m
Num98
257179.423*共16兲
CH2 CHCN
27共6,22兲⫺26共6,21兲 v11 ⫽1
3.3fb
Sgr B2共N兲
SEST 15 m
Num98
257179.544*共16兲
CH2 CHCN
27共6,21兲⫺26共6,20兲 v11 ⫽1
b
Sgr B2共N兲
SEST 15 m
Num98
257188.0 257210.896*共10兲 257222.517*共26兲
unidentified CH3 CN
3.5 0.6
JCMT 15 m OVRO 10.4 m SEST 15 m
Gre91 Bla86 Num98
OVRO OVRO OVRO OVRO
257074.938*共16兲 257099.956*共7兲
U
7共6兲⫺6共5兲
34
Sgr B2共N兲
11.5f 0.79
Lab. Ref.
257226.577*共20兲 257239.863*共13兲 257252.661*共21兲 257255.06* 共14兲 257276.699*共17兲
CH3 13CN CH3 OCHO CH3 CH2 CN CH3 OCHO 29
SiO
7.7f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
20共5,15兲⫺19共5,14兲 E 30共1,30兲⫺29共1,29兲 20共5,15兲⫺19共5,14兲 A 6⫺5 v⫽0
0.8 0.4 0.9 1.6
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
14共5兲⫺13共5兲
13.5f 1.0
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
14共8兲⫺13共8兲 14共6兲⫺13共6兲
CH3 13CN CH3 CN CH2 CHCN
14共7兲⫺13共7兲 27共5,23兲⫺26共5,22兲 v11 ⫽1
257296.354*共16兲
CH2 CHCN
27共5,22兲⫺26共5,21兲 v11 ⫽1
257310.649*共13兲
CH3 CH2 CN
257321.060*共11兲
CH3 13CN CH3 CN
30共0,30兲⫺29共0,29兲 14共4兲⫺13共4兲
257284.953*共7兲 257290.955*共16兲
b
12.9fb
10.4 10.4 10.4 10.4
m m m m
Bla86 Bla86 Bla86 Bla86
b
Sgr B2共N兲
SEST 15 m
Num98
0.8
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
14共6兲⫺13共6兲
8.0f 1.8
14共3兲⫺13共3兲
1.5f
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
257365.580*共16兲
CH3 13CN CH2 CHCN
28共1,28兲⫺27共1,27兲 v11 ⫽1
10.5f
Sgr B2共N兲
SEST 15 m
Num98
257369.72* 共12兲
CH2 CHCN
28共1,28兲⫺27共1,27兲 v15 ⫽1
Sgr B2共N兲
SEST 15 m
Num98
257380.249*共10兲
CH3 13CN
14共2兲⫺13共2兲
10.5f 0.3
OriMC⫺1
OVRO 10.4 m
Bla86
257395.055*共11兲
CH3 13CN
14共1兲⫺13共1兲
b
Sgr B2共M兲
SEST 15 m
Num98
257399.900*共11兲
CH3 13CN CH3 OH
14共0兲⫺13共0兲
10.7fb
Sgr B2共M兲
SEST 15 m
Num98
257402.182*共43兲
18共3,16兲⫺18共2,17兲 A⫹⫺
OriMC⫺1
OVRO 10.4 m
Bla86
257403.598*共4兲 257420.292*共25兲
CH3 CN SO2
14共5兲⫺13共5兲 24共2,22兲⫺24共1,23兲 v2 ⫽1
2.8b 0.5 0.4
OriMC⫺1 OriMC⫺1
MMWO 4.9 m OVRO 10.4 m
Lor84 Bla86
257349.196*共6兲 257355.581*共9兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Oes99
Oes99 Oes99
Xu_97
MICROWAVE TRANSITIONS
293
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 257448.139*共4兲 257466.843*共44兲
U
U
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
CH3 CN
14共4兲⫺13共4兲 29共9,21兲⫺30共8,22兲
0.5 0.17
OriMC⫺1 W3共H2O兲
MMWO 4.9 m JCMT 15 m
Lor84 Hel97
14共3兲⫺13共3兲
1.1
OriMC⫺1
MMWO 4.9 m
Lor84
14共2兲⫺13共2兲 14共1兲⫺13共1兲 14共0兲⫺13共0兲 27共14,*兲⫺26共14,*兲 v11 ⫽1
0.85 1.15 1.2
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m SEST 15 m
Lor84 Lor84 Lor84 Num98
34
257522.432*共4兲 257527.387*共4兲 257553.574*共60兲
SO2 CH3 CN CH3 CN CH3 CN CH3 CN CH2 CHCN
257583.620*共13兲 257612.026*共14兲
CH3 CH2 CN CH3 OCH3
27共3,25兲⫺27共2,26兲 AE⫹EA
257614.538*共12兲
CH3 OCH3
27共3,25兲⫺27共2,26兲 EE
257617.049*共16兲
CH3 OCH3
27共3,25兲⫺27共2,26兲 AA
257629.
unidentified
257482.800*共4兲 257507.567*共4兲
U
Formula
30共1,30兲⫺29共0,29兲
3.6f 0.3
Lab. Ref.
OriMC⫺1
OVRO 10.4 m
Bla86
Sgr B2共N兲
SEST 15 m
Num98
Gro98
Sgr B2共N兲
SEST 15 m
Num98
Gro98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
7.6f
Sgr B2共N兲
SEST 15 m
Num98
b
10.3fb
257639.553*共16兲
CH2 CHCN
27共4,23兲⫺26共4,22兲 v11 ⫽1
7.0f
Sgr B2共N兲
SEST 15 m
Num98
257646.01* 共19兲
28共0,28兲⫺27共0,27兲 27共15,*兲⫺26共15,*兲 v11 ⫽1
0.5
257664.49*共8兲
CH2 CHCN CH2 CHCN
2.0f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
257677.
unidentified
SEST 15 m
Num98
257699.464*共16兲 257738.
CH3 OCHO CH3 OCHO unidentified
22共3,20兲⫺21共3,19兲 E 22共3,20兲⫺21共3,19兲 A
3.3f 1.4 0.9
Sgr B2共N兲
257690.313*共16兲
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
257748.718*共10兲 257790.430*共29兲
HDCO CH3 OCHO
4共2,3兲⫺3共2,2兲 21共18,*兲⫺20共18,*兲 A
5.0f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99
257821.499*共12兲
NO
2
⌸3/2 J, F⫽5/2,3/2⫺3/2,3/2 e
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
257822.086 共40兲
NO
2
⌸3/2 J, F⫽5/2,7/2⫺3/2,5/2 e
3.7fb
Sgr B2共N兲
SEST 15 m
Num98
JPL01
257824.695*共12兲
NO
2
⌸3/2 J, F⫽5/2,3/2⫺3/2,3/2 f
2.5fb
Sgr B2共N兲
SEST 15 m
Num98
JPL01
257825.025 共40兲
NO
2
⌸3/2 J, F⫽5/2,7/2⫺3/2,5/2 f
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
257852.746 共20兲
NO
2
4.7fb
Sgr B2共N兲
SEST 15 m
Num98
JPL01
257854.467*共29兲
CH3 OCHO
⌸3/2 J, F⫽5/2,5/2⫺3/2,3/2 e 21共17,4兲⫺20共17,3兲 E
1.8b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
257855.289 共20兲
NO
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
257865.047*共34兲
CH3 OCHO
21共17,5兲⫺20共17,4兲 E
1.9b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
257890.00* 共15兲
CH3 CN
14共8兲⫺13共8兲 v8 ⫽1 ᐉ⫽⫺1
3.1f
Sgr B2共N兲
SEST 15 m
Num98
257911.060*共10兲
CH3 OCH3
18共5,13兲⫺18共4,14兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
257911.198*共10兲
CH3 OCH3
18共5,13兲⫺18共4,14兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
257913.330*共6兲
CH3 OCH3
18共5,13兲⫺18共4,14兲 EE
8.5fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
257915.532*共10兲
CH3 OCH3
18共5,13兲⫺18共4,14兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
6.1f 0.3
Sgr B2共M兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Sgr B2共N兲
SEST 15 m
Num98
b
OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m
Gre91 Gre91
b
Sgr B2共N兲
SEST 15 m
Num98
1.1 0.3
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Bou80
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Oes99 Oes99
257957.216*共12兲 257975.01*共1兲 257975.22* 共14兲
33
SO2
2
⌸3/2 J, F⫽5/2,5/2⫺3/2,3/2 f
11共3,9兲⫺11共2,10兲
HCOOH CH3 CN
12共1,12兲⫺11共1,11兲 14共7兲⫺13共7兲 v8 ⫽1 ᐉ⫽⫺1
257993.28* 共14兲
CH3 CN
14共9兲⫺13共9兲 v8 ⫽1 ᐉ⫽1
258001.726*共21兲 258007.205*共25兲
CH3 OCHO CH3 OCHO
21共15,*兲⫺20共15,*兲 A 21共15,6兲⫺20共15,5兲 E
1.6f 0.6
5.2f 2.7f 2.6
Oes99 Oes99
Wil80
Oes99 Oes99
258050.40* 共14兲
CH3 CN
14共6兲⫺13共6兲 v8 ⫽1 ᐉ⫽⫺1
258054.14* 共15兲 258070.958*共9兲 258072.433*共25兲
CH3 CN HDCO CH3 OCHO
14共1兲⫺13共1兲 v8 ⫽1 ᐉ⫽1 4共3,2兲⫺3共3,1兲 24共10,15兲⫺24共9,16兲 A
258081.010*共16兲 258089.525*共16兲 258099.753*共16兲
CH3 OCHO CH3 OCHO CH2 CHCN
22共2,20兲⫺21共2,19兲 E 22共2,20兲⫺21共2,19兲 A 28共0,28兲⫺27共0,27兲 v11 ⫽1
5.6f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
258115.48* 共14兲
CH3 CN
14共5兲⫺13共5兲 v8 ⫽1 ᐉ⫽⫺1
7.0f
Sgr B2共N兲
SEST 15 m
Num98
258121.149*共20兲
CH3 OCHO
21共14,*兲⫺20共14,*兲 A
1.0b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
258122.655*共24兲
CH3 OCHO
21共14,7兲⫺20共14,6兲 E
b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
258132.27* 共14兲
CH3 CN
14共7兲⫺13共7兲 v8 ⫽1 ᐉ⫽1
5.4f
Sgr B2共N兲
SEST 15 m
Num98
258142.069*共21兲
CH3 OCHO
21共14,8兲⫺20共14,7兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
258152.528*共70兲
CH3 OCHO
11共5,7兲⫺10共4,6兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
258157.005*共11兲
HC15N CH3 CN
3⫺2
5.2
OriMC⫺1
OVRO 10.4 m
Bla86
14共4兲⫺13共4兲 v8 ⫽1 ᐉ⫽⫺1
10.6f
Sgr B2共N兲
SEST 15 m
Num98
14共6兲⫺13共5兲 v8 ⫽1 ᐉ⫽1 14共3兲⫺13共3兲 v8 ⫽1 ᐉ⫽⫺1
0.3
258214.98* 共15兲
CH3 CN CH3 CN
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
258232.10* 共14兲
CH3 CN
14共5兲⫺13共5兲 v8 ⫽1 ᐉ⫽1
Sgr B2共N兲
SEST 15 m
Num98
258255.893*共13兲 258267.94* 共14兲
SO CH3 CN
6共6兲⫺5共5兲 14共4兲⫺13共4兲 v8 ⫽1 ᐉ⫽1
20.8f
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Cle84 Num98
258271.07* 共16兲
CH3 CN
14共1兲⫺13共1兲 v8 ⫽1 ᐉ⫽⫺1
b
Sgr B2共N兲
SEST 15 m
Num98
258274.868*共24兲
CH3 OCHO
21共13,8兲⫺20共13,7兲 E
b
W3共H2O兲
JCMT 15 m
Hel97
258276.18* 共23兲
CH3 CN
14共0兲⫺13共0兲 v8 ⫽1 ᐉ⫽⫹⫺1
Sgr B2共N兲
SEST 15 m
Num98
258277.399*共20兲 258277.399*共20兲
CH3 OCHO CH3 OCHO
21共13,8兲⫺20共13,7兲 A
258170.39* 共14兲 258186.99* 共13兲
21共13,9兲⫺20共13,8兲 A
5.8f 1.2 1.1
6.4f 12.6f 4.0
12.2fb 0.10 b
Oes99
Bou80
Oes99
W3共H2O兲
JCMT 15 m
Hel97
Oes99
W3共H2O兲
JCMT 15 m
Hel97
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
294
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Telescope
Astr. Ref.
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Sgr B2共NW兲
SEST 15 m
Num98
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Quantum numbers
T r 共K兲/T a 共K兲
Source
8.5f 1.1
258285.663*共4兲
CH2 CHCN
27共3,24兲⫺26共3,23兲
258295.60* 共18兲 258306.213*共28兲
CH3 CN CH3 OCHO
14共3兲⫺13共3兲 v8 ⫽1 ᐉ⫽1 11共5,7兲⫺10共4,6兲 A
258315.
unidentified
5.1f 0.9f 0.7
14共2兲⫺13共2兲 v8 ⫽1 ᐉ⫽1 5共2兲⫺5共⫺1兲 Aa⫹⫺
258360.05*共7兲
CH2 CHCN
258388.697*共31兲 258431.5*共6兲
SO2 CH2 CHCN
27共1,26兲⫺26共1,25兲 32共4,28兲⫺32共3,29兲 27共4,23兲⫺26共4,22兲 v11 ⫽2
3.0f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
258475.068*共17兲
CH3 OCHO
23共1,22兲⫺22共2,21兲 E
5.4fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
258476.407*共21兲
CH3 OCHO CH3 OCHO
21共12,9兲⫺20共12,8兲 E 23共1,22兲⫺22共2,21兲 A
0.9
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99 Oes99
21共12,*兲⫺20共12,*兲 A
1.0
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
258496.308*共17兲 258499.265*共17兲 258502.765*共17兲 258508.193*共17兲 258518.547*共17兲
CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO
23共2,22兲⫺22共2,21兲 E 23共2,22兲⫺22共2,21兲 A 21共12,10兲⫺20共12,9兲 E 23共1,22兲⫺22共1,21兲 E 23共1,22兲⫺22共1,21兲 A 23共2,22兲⫺22共1,21兲 E
1.0 1.1 0.8 1.0 1.0 2.0fb
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Bla86 Bla86 Bla86 Num98
Oes99 Oes99 Oes99 Oes99 Oes99 Oes99
258523.925*共17兲
CH3 OCHO
23共2,22兲⫺22共1,21兲A
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
258548.817*共6兲
CH3 OCH3
14共1,14兲⫺13共0,13兲AE⫹EA
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
258549.061*共6兲
CH3 OCH3
14共1,14兲⫺13共0,13兲EE
3.2b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
258549.305*共6兲
CH3 OCH3
14共1,14兲⫺13共0,13兲AA
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
258552.40* 共15兲
CH3 CN
14共1兲⫺13共1兲v8 ⫽1ᐉ⫽1
0.6b
OriMC⫺1
OVRO 10.4 m
Bla86
Bou80
258480.576*共17兲 258482.960*共20兲 258490.850*共17兲
5.9f 0.6 1.5
b
U
258568.
unidentified
5.2f
Sgr B2共N兲
SEST 15 m
Num98
U
258579.
unidentified
5.4f
Sgr B2共N兲
SEST 15 m
Num98
U
258608.
unidentified
2.8f
Sgr B2共N兲
SEST 15 m
Num98
U
258618.
unidentified
2.7f
Sgr B2共N兲
SEST 15 m
Num98
U
258636.348*共14兲
NH2 CHO
13共2,12兲⫺13共1,13兲
2.5f
Sgr B2共N兲
SEST 15 m
Num98
258666.921*共8兲
SO2
20共7,13兲⫺21共6,16兲
0.7 3.2f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98 Num98
258676.
unidentified
258698.
unidentified
258707.36* 共12兲 U
U
SiO
Bou80 Num98
3.5f
Sgr B2共N兲
SEST 15 m
6⫺5 v⫽1
41.7e
RLeo
OVRO 10.4 m
Jew87
Sgr B2共M兲
SEST 15 m
Num98
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Bla86 Num98
Oes99 Oes99 Xu_97
258737.
unidentified
258746.170*共20兲 258756.662*共17兲
21共11,10兲⫺20共11,9兲 E
258769.910*共17兲 258780.405*共52兲 258793.
CH3 OCHO CH3 OCHO CH3 OCHO CH3 OH unidentified
3.6f 0.5
21共11,*兲⫺20共11,*兲 A 21共11,11兲⫺20共11,10兲 E 19共3,17兲⫺19共2,18兲 A⫹⫺
0.7 0.4 1.8 6.1f
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共N兲
258803.81*共9兲
CH2 CHCN
27共1,26兲⫺26共1,25兲 v15 ⫽1
5.3f
Sgr B2共N兲
SEST 15 m
Num98
258847.857*共29兲
CH3 OCHO
23共10,13兲⫺23共9,14兲 E
5.9f
Sgr B2共N兲
SEST 15 m
Num98
258859.125*共25兲
CH3 OCHO
23共10,13兲⫺23共9,14兲 A
3.5f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
CH3 NH2
7共2兲⫺7共⫺1兲 As⫹⫺
3.5f
Sgr B2共N兲
SEST 15 m
Num98
Num98
3.8f
Sgr B2共N兲
SEST 15 m
Num98
7共2,5兲⫺6共1.6兲
4.0f
Sgr B2共N兲
SEST 15 m
Num98
258859.8*共5兲 U
Bou80 Oes99
CH3 CN CH3 NH2
258320.39* 共25兲 258350.7*共5兲
U
Lab. Ref.
258864. 258874.744*共62兲
unidentified HCCCHO
U
258908.
unidentified
7.5f
Sgr B2共N兲
SEST 15 m
Num98
U
258917.
unidentified
6.7f
Sgr B2共N兲
SEST 15 m
Num98
U
258926.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
9共3,7兲⫺9共2,8兲 3⫺2
7.6f 0.9 2.3
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor84b Lor84b
4共2,2兲⫺3共2,1兲
0.18
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84b Num98 Num98
258942.188*共7兲 259011.799*共11兲
SO2
Oes99
U
259034.772*共10兲 259067.
H13CN HDCO unidentified
U
259078.
unidentified
SEST 15 m
CH3 OCHO CH3 OCHO
21共10,11兲⫺20共10,10兲 E
9.3f 0.6
Sgr B2共N兲
259113.888*共17兲 259128.159*共17兲
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
21共10,12兲⫺20共10,11兲 A
b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
259128.200*共17兲
CH3 OCHO
21共10,11兲⫺20共10,10兲 A
OVRO 10.4 m
Bla86
Oes99
CH3 OCHO CH2 CHCN
21共10,12兲⫺20共10,11兲 E
1.1b 0.3
OriMC⫺1
259137.936*共17兲 259210.110*共16兲
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
Sgr B2共N兲
SEST 15 m
Num98
259232.728*共11兲 259263.
CH3 CH2 CN unidentified
29共3,27兲⫺28共3,26兲
10.0f 0.7
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
259273.51* 共13兲
CH3 OH
17共2,16兲⫺16共1,15兲 A⫺⫹ vt ⫽1 7共6兲⫺6共5兲
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Xu_97
22.8f
U
259281.753*共20兲
33
5.0f
27共3,24兲⫺26共3,23兲 v11 ⫽1
12.0f 1.0
259309.492*共10兲
SO CH3 OCH3
17共5,12兲⫺17共4,13兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
259309.777*共10兲
CH3 OCH3
17共5,12兲⫺17共4,13兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
259311.964*共6兲
CH3 OCH3
17共5,12兲⫺17共4,13兲 EE
Sgr B2共N兲
SEST 15 m
Num98
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
14.7fb
MICROWAVE TRANSITIONS
295
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
259314.293*共10兲
CH3 OCH3
17共5,12兲⫺17共4,13兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
259342.052*共20兲
CH3 OCHO
24共1,24兲⫺23共1,23兲 E
2.0b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
259342.180*共20兲
CH3 OCHO
24共0,24兲⫺23共0,23兲 E
b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
259342.924*共21兲
CH3 OCHO
24共1,24兲⫺23共1,23兲 A
b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
259343.052*共21兲
CH3 OCHO
24共0,24兲⫺23共0,23兲 A
b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
259354.
unidentified
8.4f
Sgr B2共N兲
SEST 15 m
Num98
259367.
unidentified
9.2f
Sgr B2共N兲
SEST 15 m
Num98
259376.189*共28兲
CH3 OCHO
11共5,6兲⫺10共4,7兲 A
3.7f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
259390.543 共20兲
NH2 CN
13共2,11兲⫺12共2,10兲 v⫽1
3.9f 0.8
Sgr B2共N兲
SEST 15 m
Num98
JPL01
U U
259398.0 259405.
unidentified unidentified
8.3f
OriMC⫺1 Sgr B2共N兲
JCMT 15 m SEST 15 m
Gre91 Num98
U
259428.
unidentified
3.4f
Sgr B2共N兲
SEST 15 m
Num98
U
259438.
unidentified
3.5f
Sgr B2共N兲
SEST 15 m
Num98
13.1f
Sgr B2共N兲
SEST 15 m
15共11,*兲⫺14共11,*兲 vt ⫽1⫺1
Num98
JPL01
259484.844*共10兲
g⫺CH3 CH2 OH CH3 OCH3
6共3,4兲⫺5共2,3兲 EA
0.7b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
259486.608*共8兲
CH3 OCH3
6共3,4兲⫺5共2,3兲 AE
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
259489.720*共6兲 259493.733*共10兲 259499.905*共17兲 259521.773*共20兲 259539.240*共6兲
CH3 OCH3 CH3 OCH3 CH3 OCHO CH3 OCHO
6共3,4兲⫺5共2,3兲 EE 6共3,4兲⫺5共2,3兲 AA 20共4,16兲⫺19共4,15兲 E 20共4,16兲⫺19共4,15兲 A
1.3 0.6 0.8 1.0
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO OVRO OVRO OVRO
Bla86 Bla86 Bla86 Bla86
Gro98 Gro98 Oes99 Oes99
g⫺CH3 CH2 OH
15共9,*兲⫺14共9,*兲 vt ⫽1⫺1
JPL01
259478.284*共12兲
U
259571.
7.8f
Sgr B2共N兲
SEST 15 m
Num98
5.6f
Sgr B2共N兲
SEST 15 m
Num98
CH3 OH
24共1,23兲⫺24共0,24兲 E
6.3f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
259599.421*共30兲
30共4,26兲⫺30共3,27兲 22共5,18兲⫺22共4,19兲 EA
1.5
259615.913*共10兲
SO2 CH3 OCH3
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Gro98
259615.920*共10兲
CH3 OCH3
22共5,18兲⫺22共4,19兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
13共3,11兲⫺13共2,12兲
1.0
OriMC⫺1
OVRO 10.4 m
Bla86
259617.356*共8兲
SO2 CH3 OCH3
22共5,18兲⫺22共4,19兲 EE
13.7fb
259618.796*共12兲
CH3 OCH3
22共5,18兲⫺22共4,19兲 AA
259629.214*共17兲 259646.576*共17兲
CH3 OCHO CH3 OCHO
21共9,12兲⫺20共9,11兲 E 21共9,13兲⫺20共9,12兲 A
259647.711*共17兲
CH3 OCHO
259653.009*共16兲
CH3 OCHO
259669.
unidentified
259688.856*共10兲
CH3 OCH3
23共5,19兲⫺23共4,20兲 AE⫹EA
259690.082*共8兲
CH3 OCH3
23共5,19兲⫺23共4,20兲 EE
259691.308*共14兲
CH3 OCH3
23共5,19兲⫺23共4,20兲 AA
259697.808*共15兲 259725.15* 共12兲
g⫺CH3 CH2 OH CH3 OCHO
259725.16* 共12兲
CH3 OCHO
259726.03* 共12兲
34
Sgr B2共N兲
SEST 15 m
Num98
Gro98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
0.6 0.8b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86
Oes99 Oes99
21共9,12兲⫺20共9,11兲 A
b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
21共9,13兲⫺20共9,12兲 E
0.5
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99
10.8f
OriMC⫺1 Sgr B2共N兲
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
9.4fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
15共7,9兲⫺14共7,8兲 vt ⫽1⫺1
4.1fb
Sgr B2共N兲
SEST 15 m
Num98
JPL01
28共1,27兲⫺28共1,28兲 A
1.4b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
28共1,27兲⫺28共0,28兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
CH3 OCHO
28共2,27兲⫺28共1,28兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
259730.510*共8兲
CH3 OCH3
21共5,17兲⫺21共4,18兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
259730.526*共8兲
CH3 OCH3
21共5,17兲⫺21共4,18兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
259732.167*共8兲
CH3 OCH3
21共5,17兲⫺21共4,18兲 EE
Sgr B2共N兲
SEST 15 m
Num98
Gro98
259733.816*共12兲
CH3 OCH3
21共5,17兲⫺21共4,18兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
259744.274*共15兲
g⫺CH3 CH2 OH
13共1,12兲⫺12共2,10兲 vt ⫽1⫺0
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
259749.366*共17兲
g⫺CH3 CH2 OH
18共4,15兲⫺18共2,16兲 vt ⫽1⫺1
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
259750.828*共11兲
g⫺CH3 CH2 OH
15共11,*兲⫺14共11,*兲 vt ⫽0⫺0
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
259753.256*共14兲
g⫺CH3 CH2 OH
15共12,*兲⫺14共12,*兲 vt ⫽0⫺0
b
Sgr B2共N兲
SEST 15 m
Num98
JPL01
259757.134*共14兲
g⫺CH3 CH2 OH
15共10,5兲⫺14共10,4兲 vt ⫽0⫺0
17.0fb
Sgr B2共N兲
SEST 15 m
Num98
JPL01
259775.917*共6兲
g⫺CH3 CH2 OH
15共9,*兲⫺14共9,*兲 vt ⫽0⫺0
1.5f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
259814.446 共50兲
g⫺CH3 CH2 OH CH3 CH2 CN
15共8,*兲⫺14共8,*兲 vt ⫽0⫺0
1.4f 1.0
Sgr B2共N兲
SEST 15 m
Num98
Pea96
OriMC⫺1
OVRO 10.4 m
Bla86
NH2 CN
13共0,13兲⫺12共0,12兲
SEST 15 m
Num98
JPL01
29共11,*兲⫺28共11,*兲 15共6,*兲⫺14共6,*兲 vt ⫽1⫺1
4.7f 0.9
Sgr B2共M兲
CH3 CH2 CN
11.3f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Pea96
29共9,*兲⫺28共9,*兲 29共12,*兲⫺28共12,*兲
0.9 0.6 10.7f 0.5 1.0
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 W3共H2O兲
OVRO 10.4 m JCMT 15 m
Bla86 Hel97
259842.927*共13兲 259847.139 共20兲 259847.361*共13兲 259852.277 共50兲
29共10,*兲⫺28共10,*兲
259869.887*共14兲 259878.
g⫺CH3 CH2 OH CH3 CH2 CN CH3 CH2 CN unidentified
259906.654*共14兲 259917.261*共12兲 259942.467*共11兲
CH3 CH2 CN CH3 CH2 CN NH2 CHO
29共13,*兲⫺28共13,*兲 29共8,*兲⫺28共8,*兲
259955.149*共14兲 259982.558*共10兲
CH3 CH2 CN CH3 OCH3
29共14,*兲⫺28共14,*兲 20共5,16兲⫺20共4,17兲 EA
259862.749*共12兲 U
m m m m
259581.21* 共32兲
259617.201*共12兲
U
unidentified
10.4 10.4 10.4 10.4
12共2,9兲⫺11共2,10兲
12.4fb
4.9f 0.4 b
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
296
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
259982.591*共10兲
CH3 OCH3
20共5,16兲⫺20共4,17兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
CH3 OCH3
20共5,16兲⫺20共4,17兲 EE
0.20b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
259986.278*共12兲
CH3 OCH3
20共5,16兲⫺20共4,17兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
259986.566*共14兲
13
0.8
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
2共1,1兲⫺1共0,1兲 E
260003.398*共12兲
CH3 OH CH3 OCH3
24共5,20兲⫺24共4,21兲 EA⫹AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260004.406*共10兲
CH3 OCH3
24共5,20兲⫺24共4,21兲 EE
8.7fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260005.413*共14兲
CH3 OCH3
24共5,20兲⫺24共4,21兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260013.666*共14兲
29共15,*兲⫺28共15,*兲 29共7,23兲⫺28共7,22兲
0.5
260025.314*共11兲
CH3 CH2 CN CH3 CH2 CN
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86
260025.569*共11兲
CH3 CH2 CN
29共7,23兲⫺28共7,22兲
b
OriMC⫺1
OVRO 10.4 m
Bla86
260036.
unidentified
10.5f
Sgr B2共N兲
SEST 15 m
Num98
260060.33共10兲 260081.013*共14兲 260090.165 共50兲
g⫺CH3 CH2 OH HCO CH3 CH2 CN
15共3,13兲⫺14共3,12兲 vt ⫽1⫺1 3共0,3兲⫺2共0,2兲7/2⫺5/2 F⫽4⫺3 29共16,*兲⫺28共16,*兲 15共1,14兲⫺14共1,13兲 vt ⫽0⫺0
0.8b
5.9fb 0.09
Sgr B2共N兲
SEST 15 m
Num98
JPL01
OriMC⫺2
MMWO 4.9 m
Sny85a
Bla84a
0.3 7.0f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Pea96
6.1f
Sgr B2共N兲
SEST 15 m
Num98
260097.
g⫺CH3 CH2 OH unidentified
260107.590 共50兲
g⫺CH3 CH2 OH
15共5,11兲⫺14共5,10兲 vt ⫽1⫺1
6.1f
Sgr B2共N兲
SEST 15 m
Num98
Pea96
5.2f
Sgr B2共N兲
SEST 15 m
Num98
Pea96
29共17,*兲⫺28共17,*兲 12共2,10兲⫺11共2,9兲
0.4
260189.078*共9兲
g⫺CH3 CH2 OH CH3 CH2 CN NH2 CHO
15共5,10兲⫺14共5,9兲 vt ⫽1⫺1
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
260191.76* 共12兲 260204.
CH2 CO unidentified
13共1,13兲⫺12共1,12兲
6.1f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
260221.653*共11兲
CH3 CH2 CN
29共6,24兲⫺28共6,23兲
0.9b
OriMC⫺1
OVRO 10.4 m
Bla86
260229.157*共11兲
CH3 CH2 CN
29共6,23兲⫺28共6,22兲
b
OriMC⫺1
OVRO 10.4 m
Bla86
260244.481*共17兲 260249.723*共3兲
CH3 OCHO
21共3,18兲⫺20共3,17兲 E
0.8
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
15共5,11兲⫺14共5,10兲 vt ⫽0⫺0
5.3f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
260255.151*共17兲
g⫺CH3 CH2 OH CH3 OCHO
21共3,18兲⫺20共3,17兲 A
OVRO 10.4 m
Bla86
Oes99
H13CO⫹
3⫺2
2.1b 0.95
OriMC⫺1
260255.48* 共10兲
OriMC⫺1
MMWO 4.9 m
Woo84a
260266.089*共3兲
g⫺CH3 CH2 OH CH3 NH2
15共5,10兲⫺14共5,9兲 vt ⫽0⫺0
11.2f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
10共⫺2兲⫺10共⫺1兲 Ea
4.8f
Sgr B2共N兲
SEST 15 m
Num98
Num98
260122.690 共50兲 260156.326*共14兲
U
Quantum numbers
259984.426*共8兲
260046.626*共3兲
U
Formula
260292.7*共5兲
14.1f 0.6
U
260300.
unidentified
8.2f
Sgr B2共N兲
SEST 15 m
Num98
U
260310.
unidentified
Sgr B2共N兲
SEST 15 m
Num98
U U
260314.0 260319.
unidentified unidentified
7.7f 1.9
OriMC⫺1 Sgr B2共N兲
JCMT 15 m SEST 15 m
Gre91 Num98
260326.965*共21兲
U
OriMC⫺1
OVRO 10.4 m
Bla86
260327.155*共10兲
CH3 OCH3
19共5,15兲⫺19共4,16兲 EA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
260327.223*共10兲
CH3 OCH3
19共5,15兲⫺19共4,16兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
260329.239*共6兲
CH3 OCH3
19共5,15兲⫺19共4,16兲 EE
0.17b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
260331.289*共10兲
CH3 OCH3
19共5,15兲⫺19共4,16兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
260381.697*共65兲
CH3 OH
20共3,18兲⫺20共2,19兲 A⫹⫺
1.8b
OriMC⫺1
OVRO 10.4 m
Bla86
Xu_97
260384.263*共17兲
CH3 OCHO
21共8,13兲⫺20共8,12兲 E
1.6b
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
260392.767*共17兲
21共8,14兲⫺20共8,13兲 A 16共5,11兲⫺16共4,12兲 AE
1.0
260400.557*共10兲
CH3 OCHO CH3 OCH3
b
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99 Gro98
260401.150*共10兲
CH3 OCH3
16共5,11兲⫺16共4,12兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260403.260*共6兲
CH3 OCH3
16共5,11兲⫺16共4,12兲 EE
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260404.003*共16兲 260405.664*共10兲
CH3 OCHO CH3 OCH3
21共8,14兲⫺20共8,13兲 E 16共5,11兲⫺16共4,12兲 AA
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99 Gro98
260415.357*共17兲 260424.406*共18兲
CH3 OCHO CH3 CH2 CN
21共8,13兲⫺20共8,12兲 A
0.7
OriMC⫺1
OVRO 10.4 m
Bla86
Oes99
29共20,*兲⫺28共20,*兲
Sgr B2共N兲
SEST 15 m
Num98
260437.683*共3兲
g⫺CH3 CH2 OH unidentified
7共1,6兲⫺6共0,6兲 vt ⫽1⫺0
8.7f 5.9
Sgr B2共N兲
SEST 15 m
Num98
JPL01
1.2
g⫺CH3 CH2 OH
15共4,12兲⫺14共4,11兲 vt ⫽1⫺1
11.0f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
JPL01
17共2,16兲⫺17共1,17兲
8.4f
Sgr B2共M兲
SEST 15 m
Num98
6⫺5 v⫽0 29共5,25兲⫺28共5,24兲
2.9 35.8f
OriMC⫺1 Sgr B2共N兲
MMWO 4.9 m SEST 15 m
Lor84b Num98
260440. 260457.651*共3兲 260479.408*共33兲
SO2
18
19.3fb 1.8 b
260518.08* 共14兲 260535.671*共11兲
OS O SiO CH3 CH2 CN
260541.147*共18兲
CH3 CH2 CN
11共4,8兲⫺10共3,7兲
13.7f
Sgr B2共N兲
SEST 15 m
Num98
260544.027*共14兲
CH3 CHO
14共1,14兲⫺13共1,13兲 A⫹⫹
13.7f
Sgr B2共N兲
SEST 15 m
Num98
4.6f
Sgr B2共N兲
SEST 15 m
Num98
1.3 18.1f
OriMC⫺1 Sgr B2共N兲
JCMT 15 m SEST 15 m
Gre91 Num98
7.1f
Sgr B2共N兲
SEST 15 m
Num98
U
260568.
U
260578.0 260591.325*共3兲
U
34
24共2,22兲⫺24共1,23兲
5.8f 1.0
unidentified unidentified
Kle96
g⫺CH3 CH2 OH unidentified
15共4,12兲⫺14共4,11兲 vt ⫽0⫺0
260616.079*共12兲
CH3 OCH3
25共5,21兲⫺25共4,22兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260616.867*共10兲
CH3 OCH3
25共5,21兲⫺25共4,22兲 EE
5.3fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260617.654*共14兲
CH3 OCH3
25共5,21兲⫺25共4,22兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260605.
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
JPL01
MICROWAVE TRANSITIONS
297
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
U
U U
U
U
Telescope
Astr. Ref.
Lab. Ref.
unidentified
3.7f
Sgr B2共N兲
SEST 15 m
Num98
29共22,*兲⫺28共22,*兲
3.8f
Sgr B2共N兲
SEST 15 m
Num98
260664.778*共11兲
CH3 CH2 CN
29共4,26兲⫺28共4,25兲
0.9b
OriMC⫺1
OVRO 10.4 m
Bla86
260667.109*共18兲
CH3 CH2 CN
11共4,7兲⫺10共3,6兲
b
OriMC⫺1
OVRO 10.4 m
Bla86
260679.047*共11兲
29共5,24兲⫺28共5,23兲 20共10,10兲⫺20共9,11兲 A
0.8
260682.044*共24兲
CH3 CH2 CN CH3 OCHO
3.2b
OriMC⫺1 OriMC⫺1
OVRO 10.4 m JCMT 15 m
Bla86 Gre91
Oes99
260682.797*共24兲
CH3 OCHO
20共10,11兲⫺20共9,12兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
260693.997*共14兲
CH3 CHO
13共1,13兲⫺12共0,12兲 A⫹⫹
9.7f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
260725.469*共10兲
CH3 OCH3
18共5,14兲⫺18共4,15兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260725.607*共10兲
CH3 OCH3
18共5,14兲⫺18共4,15兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260727.785*共6兲
CH3 OCH3
18共5,14兲⫺18共4,15兲 EE
9.1fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260730.032*共10兲
CH3 OCH3
18共5,14兲⫺18共4,15兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
260758.391*共6兲 260761.508*共10兲
CH3 OCH3 CH3 OCH3
6共3,3兲⫺5共2,4兲 EE
1.9
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
6共3,3兲⫺5共2,4兲 AA
1.5
OVRO 10.4 m SEST 15 m
Bla86 Num98
Gro98
5.2f
OriMC⫺1 Sgr B2共N兲
15共4,11兲⫺14共4,10兲 vt ⫽1⫺1
5.7f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
6.5f
Sgr B2共N兲
SEST 15 m
Num98
260771.
260815.
unidentified g⫺CH3 CH2 OH unidentified
260825.741*共18兲
CH3 CH2 CN
24共11,*兲⫺25共10,*兲
4.8f
Sgr B2共N兲
SEST 15 m
Num98
260826.541*共25兲
CH3 CHO
14共1,14兲⫺13共1,13兲 A⫹⫹ vt ⫽1
4.8f
Sgr B2共N兲
SEST 15 m
Num98
8.2f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
260895.
unidentified
260920.
unidentified
4.7f
Sgr B2共N兲
SEST 15 m
Num98
260934.986*共42兲
CH3 OCHO
30共3,28兲⫺30共2,29兲 E
2.7f
Sgr B2共N兲
SEST 15 m
Num98
Oes99
CH3 NH2
11共1兲⫺10共2兲 Aa⫹⫺
6.4f
Sgr B2共N兲
SEST 15 m
Num98
Num98
260960.976*共3兲
g⫺CH3 CH2 OH
15共4,11兲⫺14共4,10兲 vt ⫽0⫺0
SEST 15 m
Num98
JPL01
OC34S unidentified
22⫺21
6.4f 0.12
Sgr B2共N兲
260991.818*共11兲
IRAS16293⫺2422
JCMT 15 m
Bla94
4.0f
Sgr B2共N兲
SEST 15 m
Num98
261024.4*共5兲
CH3 NH2
4共1兲⫺3共0兲 Es
3.4f
Sgr B2共N兲
SEST 15 m
Num98
Num98
261061.615 共62兲
CH3 OH
21共⫺4,18兲⫺20共⫺5,15兲 E
0.5
OVRO 10.4 m SEST 15 m
Bla86 Num98
Xu_97
3.8f
OriMC⫺1 Sgr B2共M兲
Num98
261010.
261066.
unidentified
261073.299*共19兲
CH3 CH2 CN
18共3,16兲⫺17共2,15兲
3.9f
Sgr B2共N兲
SEST 15 m
261084.089*共24兲
CH3 OCHO
19共10,10兲⫺19共9,11兲 E
6.6f
Sgr B2共N兲
SEST 15 m
Num98
261091.126*共28兲
SO2
27共4,24兲⫺28共1,27兲
6.4f
Sgr B2共M兲
SEST 15 m
Num98
261095.760*共28兲
CH3 OCHO
19共10,9兲⫺19共9,10兲 E
261102.
unidentified
261145.225*共10兲
CH3 OCH3
261145.510*共10兲
CH3 OCH3
261147.820*共6兲 261148.888*共16兲
2.0f
Sgr B2共N兲
SEST 15 m
Num98
Sgr B2共N兲
SEST 15 m
Num98
17共5,13兲⫺17共4,14兲 EA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
17共5,13兲⫺17共4,14兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
CH3 OCH3
17共5,13兲⫺17共4,14兲 EE
0.23b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
CH3 OCHO CH3 OCH3
21共5,17兲⫺20共5,16兲 E 17共5,13兲⫺17共4,14兲 AA
1.4 b
OriMC⫺1 W3共H2O兲
OVRO 10.4 m JCMT 15 m
Bla86 Hel97
Oes99 Gro98
3⫺2
1.8
OriMC⫺1
JCMT 15 m
Gre91
21共5,17兲⫺20共5,16兲 A
1.2 2.0 7.1f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m JCMT 15 m SEST 15 m
Bla86 Gre91 Num98
3.1f
Sgr B2共M兲
SEST 15 m
Num98
3.5f 1.5 0.8
Sgr B2共N兲
SEST 15 m
Num98
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
U
261220.0*共5兲
HC17O⫹ CH3 OCHO unidentified CH3 NH2
U
261221.
unidentified
261234.
unidentified
261248.127*共8兲 261250.503*共12兲 261254.679*共1兲
CH3 OCH3 CH3 OCH3 CH2 CHCN
261263.39* 共10兲 261286.241*共4兲 261307.039*共5兲 261327.439*共8兲
Oes99
2.7f
261165.451*共17兲 261206.0
261164.920*共10兲
U
Source
CH3 CH2 CN
261150.272*共10兲
U
T r 共K兲/T a 共K兲
260624.
260960.5*共5兲
U
Quantum numbers
260634.556*共28兲
260796.805*共3兲 U
Formula
4共1兲⫺3共0兲 Aa⫹⫹
15共5,10兲⫺15共4,11兲 EE 15共5,10兲⫺15共4,11兲 AA 27共2,25兲⫺26共2,24兲
Oes99
Oes99 Num98
Gro98 Gro98
HN C
3⫺2
2.4f 0.2
OriMC⫺1
MMWO 4.9 m
Lor84b
g⫺CH3 CH2 OH CH2 CHCN
15共1,14兲⫺14共1,13兲 vt ⫽1⫺1
2.9f
Sgr B2共N兲
SEST 15 m
Num98
29共0,29兲⫺28共1,28兲
2.1f
Sgr B2共N兲
SEST 15 m
Num98
NH2 CHO
12共1,11兲⫺11共1,10兲
15.0f
Sgr B2共N兲
SEST 15 m
Num98
3.7f
Sgr B2共N兲
SEST 15 m
Num98
3.3fb 0.9 1.3
Sgr B2共N兲
SEST 15 m
Num98
Num98
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Oes99 Oes99
13
JPL01
261410.
unidentified
261420.5
CH2 CN
13共0,13兲⫺12共0,12兲 29/2⫺27/2
CH3 OCHO CH3 OCHO CH2 CHCN
21共7,15兲⫺20共7,14兲 A 21共7,15兲⫺20共7,14兲 E 27共2,25兲⫺26共2,24兲 v15 ⫽1
3.5f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
261495.1
CH2 CN
13共2,12兲⫺12共2,11兲 27/2⫺25/2
b
Sgr B2共N兲
SEST 15 m
Num98
Num98
261497.6
CH2 CN
13共2,12兲⫺12共2,11兲 29/2⫺27/2
6.4f
Sgr B2共N兲
SEST 15 m
Num98
Num98
261560.815*共10兲
CH3 OCH3
16共5,12兲⫺16共4,13兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
261561.409*共10兲
CH3 OCH3
16共5,12兲⫺16共4,13兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
CH3 NH2
8共0兲⫺7共1兲 Aa⫹⫹
9.6f
Sgr B2共N兲
SEST 15 m
Num98
Num98
261433.787*共17兲 261436.691*共20兲 261479.60*共9兲
261562.5*共5兲 261563.798*共6兲
CH3 OCH3
16共5,12兲⫺16共4,13兲 EE
9.6 fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
261566.486*共10兲
CH3 OCH3
16共5,12兲⫺16共4,13兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
298
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
Formula
Quantum numbers
Source
Telescope
Astr. Ref.
Lab. Ref.
261584.228*共12兲
CH3 OCH3
26共5,22兲⫺26共4,23兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
261584.796*共10兲
CH3 OCH3
26共5,22兲⫺26共4,23兲 EE
3.5fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
261585.364*共16兲
CH3 OCH3
26共5,22兲⫺26共4,23兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
261594.362 共20兲
NH2 CN
13共1,12兲⫺12共1,11兲
3.7f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
261631.9
5.7f
CH2 CN
13共2,11兲⫺12共2,10兲
261649.31* 共16兲
SiN
6⫺5 J⫽11/2⫺9/2 F⫽13/2⫺11/2
261650.25* 共16兲
SiN
6⫺5 J⫽11/2⫺9/2 F⫽11/2⫺9/2
261651.10* 共16兲
SiN
261704.420*共28兲 261715.504*共21兲 261746.608*共17兲 261759.
CH3 OH CH3 OCHO CH3 OCHO unidentified
6⫺5 J⫽11/2⫺9/2 F⫽9/2⫺7/2 12共6,7兲⫺13共5,9兲 E 21共7,14兲⫺20共7,13兲 E 21共7,14兲⫺20共7,13兲 A
261805.736*共8兲 261843.756*共18兲 261897.640*共10兲
CH3 OH SO CH3 OCH3
2共1,1兲⫺1共0,1兲 E 7共6兲⫺6共5兲 14共5,9兲⫺14共4,10兲 EE
261899.788*共12兲
CH3 OCH3
14共5,9兲⫺14共4,10兲 AA
261956.633*共8兲 261959.638*共10兲 262004.26共5兲
CH3 OCH3 CH3 OCH3 C2 H
15共5,11兲⫺15共4,12兲 EE 15共5,11兲⫺15共4,12兲 AA
262064.99共5兲
C2 HC
262067.46共5兲 262078.89* 共30兲
Sgr B2共N兲
SEST 15 m
Num98
Num98
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
0.03b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
0.9 1.1 1.1
OriMC⫺1 OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86 Bla86
Xu_97 Oes99 Oes99
3.2f 1.0 4.2
Sgr B2共N兲
SEST 15 m
Num98
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Lor85 Lor85 Lor85
Xu_97
0.23b
OriMC⫺1 OriMC⫺1 OriMC⫺1
b
OriMC⫺1
MMWO 4.9 m
Lor85
Gro98
3⫺2 J⫽7/2⫺5/2 F⫽4⫺3
0.28 1.1 3.5
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m OVRO 10.4 m MMWO 4.9 m
Lor85 Bla86 Ziu82
Gro98 Gro98 Ziu82
3⫺2 J⫽5/2⫺3/2 F⫽3⫺2
2.8
OriMC⫺1
MMWO 4.9 m
Ziu82
Ziu82
C2 H
3⫺2 J⫽5/2⫺3/2 F⫽2⫺1
2.4
OriMC⫺1
MMWO 4.9 m
Ziu82
Ziu82
C2 H
0.8
OriMC⫺1
OVRO 10.4 m
Bla86
2.5fb
Sgr B2共N兲
SEST 15 m
Num98
Oes99
b
Sgr B2共N兲
SEST 15 m
Num98
Oes99
0.4
OVRO 10.4 m SEST 15 m
Bla86 Num98
Wil80
1.5f
OriMC⫺1 Sgr B2共N兲
2.4f
Sgr B2共M兲
SEST 15 m
Num98
4.7f
Sgr B2共N兲
SEST 15 m
Num98
Gro98
262088.177*共21兲
CH3 OCHO
3⫺2 J⫽5/2⫺3/2 F⫽2⫺2 16共10,6兲⫺16共9,7兲 A
262088.188*共21兲
CH3 OCHO
16共10,6兲⫺16共9,7兲 A
262103.48*共1兲 262108.
HCOOH unidentified
12共0,12兲⫺11共0,11兲
262144.895*共8兲
SO2
262154.300*共22兲
5共3,3兲⫺5共2,4兲 v 2 ⫽1 13共2,12兲⫺12共1,11兲
262154.74* 共16兲
t⫺CH3 CH2 OH SiN
6⫺5 J⫽13/2⫺11/2 F⫽15/2⫺13/2
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
262155.54* 共16兲
SiN
6⫺5 J⫽13/2⫺11/2 F⫽13/2⫺11/2
0.03b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
262156.08* 共16兲
SiN
6⫺5 J⫽13/2⫺11/2 F⫽11/2⫺9/2
b
IRC⫹10216
NRAO 12 m
Tur92
Tur92
262172.531*共16兲
CH2 CHCN
10.5f
Sgr B2共N兲
SEST 15 m
Num98
262183.751*共11兲
CH3 CH2 CN C2 H
27共2,25兲⫺26共2,24兲 v 11 ⫽1 29共4,25兲⫺28共4,24兲
0.7 ⬍0.8
OriMC⫺1 OriMC⫺1
OVRO 10.4 m OVRO 10.4 m
Bla86 Bla86
b
OriMC⫺1
JCMT 15 m
Gre91
2.4b 1.3 1.7
OriMC⫺1
JCMT 15 m
Gre91
OVRO 10.4 m MMWO 4.9 m SEST 15 m
Bla86 Eri84a Num98
262208.61* 共30兲 262222.858*共19兲
CH3 CH2 CN
3⫺2 J⫽5/2⫺3/2 F⫽3⫺3 6共5,1兲⫺5共4,2兲
262222.858*共19兲
CH3 CH2 CN
6共5,2兲⫺5共4,1兲
CH3 OH SO2 unidentified
21共3,19兲⫺21共2,20兲 A⫹⫺ 11共3,9兲⫺11共2,10兲
U
262224.203*共80兲 262256.893*共7兲 262273.
U
262292.
unidentified
262308.633*共16兲
CH3 OCH3
262311.019*共10兲 262313.161*共8兲
U
T r 共K兲/T a 共K兲
5.9f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
Xu_97
7.3f
Sgr B2共N兲
SEST 15 m
Num98
14共5,10兲⫺14共4,11兲 EA
0.8 b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
CH3 OCH3
14共5,10兲⫺14共4,11兲 AE
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
262316.664*共12兲 262324.873*共16兲 262333.967*共7兲
CH3 OCH3 CH3 OCH3 CH3 OCHO SO2
14共5,10兲⫺14共4,11兲 EE 14共5,10兲⫺14共4,11兲 AA 21共6,16兲⫺20共6,15兲 E 4共4,0兲⫺5共3,5兲
1.0 0.9 1.2
OVRO 10.4 m OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Bla86 Num98
Gro98 Gro98 Oes99
10.6f
OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共M兲
262340.570*共17兲
CH3 OCHO
21共6,16兲⫺20共6,15兲 A
1.0
unidentified
4.5f
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Oes99
262351. 262359.
unidentified
3.8f
Sgr B2共N兲
SEST 15 m
Num98
23⫺22
5.8f
Sgr B2共N兲
SEST 15 m
Num98
262384.537*共12兲
OCS CH3 OCH3
13共5,9兲⫺13共4,9兲 EE
5.4f
Sgr B2共N兲
SEST 15 m
Num98
Gro98
262393.101*共24兲
CH3 OCH3
13共5,8兲⫺13共4,9兲 EA
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
262393.520*共12兲
CH3 OCH3
13共5,8兲⫺13共4,9兲 EE
1.3b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
262395.128*共12兲
CH3 OCH3
13共5,8兲⫺13共4,9兲 AA
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
U
262462.
unidentified
4.2f
Sgr B2共N兲
SEST 15 m
Num98
U
262473.
unidentified
8.7f
Sgr B2共N兲
SEST 15 m
Num98
262487.490*共25兲
CH3 OCHO
3.4f
Sgr B2共N兲
SEST 15 m
Num98
262498.
unidentified
3.9f
Sgr B2共N兲
SEST 15 m
Num98
262518.
unidentified
U
262368.291*共8兲
U U
18
14共10,*兲⫺14共9,*兲 A
5.4f
Sgr B2共N兲
SEST 15 m
Num98
262524.897*共21兲
SO2
28共2,26兲⫺29共1,29兲
3.5f
Sgr B2共M兲
SEST 15 m
Num98
262547.77* 共28兲
CH2 CO CH2 CO
13共0,13兲⫺12共0,12兲 13共3,11兲⫺12共3,10兲
0.5
OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
262597.391*共37兲
CH2 CO
13共3,10兲⫺12共3,9兲
b
Sgr B2共N兲
SEST 15 m
Num98
262599.761*共29兲
CH3 OCHO
9共6,4兲⫺8共5,4兲 E
2.1f
Sgr B2共M兲
SEST 15 m
Num98
262618.909*共52兲
CH2 CO
13共2,12兲⫺12共2,11兲
0.6
OriMC⫺1
JCMT 15 m
Gre91
262596.643*共36兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
9.4fb
Oes99
Oes99
MICROWAVE TRANSITIONS
299
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
262625.453*共12兲 262629.746*共12兲 262673.14* 共21兲
CH3 OCH3 CH3 OCH3
13共5,9兲⫺13共4,10兲 EE 13共5,9兲⫺13共4,10兲 AA 29⫺28
1.6 0.6 9.8f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Gro98 Gro98 Laf78
262698.703*共82兲
HCC13CN CH3 OCH3
29⫺28
12.0f
Sgr B2共N兲
SEST 15 m
Num98
Laf78
12共5,7兲⫺12,4,6兲 EE
1.3b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
1.3b
OriMC⫺1
OVRO 10.4 m
Bla86
b
OriMC⫺1
OVRO 10.4 m
262768.962*共14兲 262769.484*共20兲
HNCO
12共1,12兲⫺11共1,11兲
262769.870*共14兲
CH3 OCH3
12共5,7兲⫺12,4,6兲 AA
Bla86
Gro98
262774.015*共6兲
CH3 OCH3
8共2,6兲⫺7共1,7兲 EE
0.7b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
262776.841*共10兲
CH3 OCH3
8共2,6兲⫺7共1,7兲 AA
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
262890.225*共14兲 262895.447*共12兲 262897.564*共12兲
CH3 OCH3 CH3 OCH3 CH3 OCH3
12共5,8兲⫺11共4,9兲 EE 12共5,8兲⫺11共4,9兲 AA 12共5,7兲⫺12共4,9兲 EE
0.5 0.5 3.6f
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Gro98 Gro98 Gro98
262913.026*共23兲
13
7共4,4兲⫺8共3,5兲 A⫺⫺
262920.316*共23兲
13
3.4fb
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
7共4,3兲⫺8共3,6兲 A⫹⫹
b
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
262960.100*共13兲
CH3 OH CH3 CHO
14共0,14兲⫺13共0,13兲 E
7.5f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
262964.187*共12兲
CH3 OCH3
27共5,23兲⫺27共4,24兲 AE⫹EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
262964.540*共10兲
CH3 OCH3
27共5,23兲⫺27共4,24兲 EE
7.5fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
262964.893*共16兲
CH3 OCH3
27共5,23兲⫺27共4,24兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
262969.693*共11兲 262981.36* 共10兲
SO2
1.4
CH3 18OH
25共8,18兲⫺26共7,19兲 5共3,3兲⫺5共2,4兲 A⫹⫺
b
OriMC⫺1 Sgr B2共N兲
JCMT 15 m SEST 15 m
Gre91 Num98
Hos96
262987.36*共8兲
CH3 18OH
4共3,2兲⫺4共2,3兲 A⫹⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Hos96
262988.27* 共13兲
CH3 18OH
6共3,4兲⫺6共2,5兲 A⫹⫺
6.7fb
Sgr B2共N兲
SEST 15 m
Num98
Hos96
262990.043*共83兲
CH3 18OH SO2
3共3,0兲⫺3共2,1兲 A⫹⫺
b
Sgr B2共N兲
SEST 15 m
Num98
Hos96
7.0f
Sgr B2共M兲
SEST 15 m
Num98
263003.988*共13兲
CH3 CHO
7.0f
Sgr B2共N兲
SEST 15 m
Num98
Kle96
263035.285*共32兲
CH3 OCH3
11共5,7兲⫺11共4,7兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263042.827*共16兲
CH3 OCH3
11共5,7兲⫺11共4,7兲 EE
2.2fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263049.967*共16兲
CH3 OCH3
11共5,6兲⫺11共4,7兲 EE
1.1b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
263050.431*共14兲
CH3 OCH3
11共5,6兲⫺11共4,7兲 AA
b
OriMC⫺1
OVRO 10.4 m
Bla86
Gro98
263065. 263107.922*共16兲 263113.378*共20兲
unidentified CH3 OCH3
11共5,7兲⫺11共4,8兲 EE
0.9 0.3
OriMC⫺1 OriMC⫺1 Sgr B2共N兲
OVRO 10.4 m OVRO 10.4 m SEST 15 m
Bla86 Bla86 Num98
Gro98 Xu_97
OriMC⫺1 Sgr B2共M兲
OVRO 10.4 m SEST 15 m
Bla86 Num98
Gro98
6.0f
13
5共2,3兲⫺4共1,3兲 E
12.2f 1.2
263216.431*共16兲
CH3 OH CH3 OCH3 SO2
263249.833*共16兲
CH3 OCH3
10共5,6兲⫺10共4,6兲 EE
3.7fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263251.079*共12兲
CH3 OCH3
10共5,5兲⫺10共4,6兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263255.648*共24兲
CH3 OCH3
10共5,5兲⫺10共4,6兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263257.114*共14兲
CH3 OCH3
10共5,5兲⫺10共4,6兲 EE
5.8fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263257.613*共24兲
CH3 OCH3
10共5,5兲⫺10共4,6兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263280.881*共12兲
CH3 OCH3
10共5,6兲⫺10共4,7兲 AE
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263281.379*共14兲
CH3 OCH3
10共5,6兲⫺10共4,7兲 EE
6.5fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263287.414*共14兲
CH3 OCH3
10共5,6兲⫺10共4,7兲 AA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263288.660*共16兲
CH3 OCH3
10共5,5兲⫺10共4,7兲 EE
8.7fb
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263290.855*共40兲
CH3 OCH3
10共5,5兲⫺10共4,7兲 EA
b
Sgr B2共N兲
SEST 15 m
Num98
Gro98
263306.048*共38兲
13
3.3f
Sgr B2共N兲
SEST 15 m
Num98
Xu_97
263113.799*共14兲
U
CH3 OH
7共3,5兲⫺7共2,6兲 v 2 ⫽1 14共0,14兲⫺13共0,13兲 A⫹⫹
262999.769*共8兲
U
HC13CCN
11共5,7兲⫺11共4,8兲 AA 45共5,41兲⫺44共6,38兲
CH3 OH unidentified
11共2,10兲⫺10共3,7兲 A⫺⫺
4.6f
Sgr B2共N兲
SEST 15 m
Num98
OS18O CH3 NH2
14共3,12兲⫺14共2,13兲
3.5f
Sgr B2共M兲
SEST 15 m
Num98
8共0兲⫺7共1兲 Es
5.1f
Sgr B2共N兲
SEST 15 m
Num98
Num98
263399.160*共20兲
CH3 OCH3
9共5,5兲⫺9共4,5兲 EE
4.2b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263401.095*共14兲
CH3 OCH3
9共5,4兲⫺9共4,5兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263403.663*共24兲
CH3 OCH3
9共5,4兲⫺9共4,5兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263403.702*共4兲
CH2 CHCN
28共2,27兲⫺27共2,26兲
29.2f
Sgr B2共N兲
SEST 15 m
Num98
263406.626*共14兲
CH3 OCH3
9共5,4兲⫺9共4,5兲 EE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263407.803*共16兲
CH3 OCH3
9共5,4兲⫺9共4,5兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263411.382*共16兲
CH3 OCH3
9共5,5兲⫺9共4,6兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263413.950*共14兲
CH3 OCH3
9共5,5兲⫺9共4,6兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263415.126*共14兲
CH3 OCH3
9共5,5兲⫺9共4,6兲 EE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263420.657*共16兲
CH3 OCH3
9共5,5兲⫺9共4,6兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263330. 263377.225*共14兲 263378.3*共5兲
263436.115*共48兲
34
34共4,30兲⫺34共4,31兲
1.1
OriMC⫺1
JCMT 15 m
Gre91
263439.621*共13兲
33
13共3,11兲⫺13共2,12兲
11.4f
Sgr B2共M兲
SEST 15 m
Num98
15共3,12兲⫺14共3,11兲 v t ⫽1⫺1 8共5,3兲⫺8共4,4兲 AE
1.7f
Sgr B2共N兲
SEST 15 m
Num98
JPL01
263507.112*共14兲
g⫺CH3 CH2 OH CH3 OCH3
4.8b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263507.414*共24兲
CH3 OCH3
8共5,3兲⫺8共4,4兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263511.479*共12兲
CH3 OCH3
8共5,3兲⫺8共4,4兲 EE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263472.358*共3兲
SO2 SO2
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
300
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U U
Formula
Quantum numbers
Telescope
Astr. Ref.
Lab. Ref.
263511.779*共18兲
CH3 OCH3
8共5,4兲⫺8共4,5兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
CH3 OCH3
8共5,4兲⫺8共4,5兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263513.976*共16兲
CH3 OCH3
8共5,3兲⫺8共4,4兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263514.578*共14兲
CH3 OCH3
8共5,4兲⫺8共4,5兲 EE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263516.236*共12兲
30共2,29兲⫺29共2,29兲 8共5,4兲⫺8共4,5兲 AA
5.7
263518.946*共14兲
CH3 CH2 CN CH3 OCH3
OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m
Gre91 Gre91
Gro98
263542.225*共9兲
NH2 CHO
13共1,13兲⫺12共1,12兲
Sgr B2共N兲
SEST 15 m
Num98
263543.959*共21兲 263578.388*共24兲
SO2 CH3 OCH3
30共3,27兲⫺30共2,28兲
16.2f 5.4
OriMC⫺1
JCMT 15 m
Gre91
7共5,2兲⫺7共4,3兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263579.441*共14兲
CH3 OCH3
7共5,2兲⫺7共4,3兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263581.155*共14兲
CH3 OCH3
7共5,3兲⫺7共4,4兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263582.259*共16兲
CH3 OCH3
7共5,3兲⫺7共4,4兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263582.803*共12兲
CH3 OCH3
7共5,2兲⫺7共4,3兲 EE
6.0b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263584.846*共14兲
CH3 OCH3
7共5,3兲⫺7共4,4兲 EE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263586.494*共16兲
CH3 OCH3
7共5,2兲⫺7共4,3兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263588.158*共16兲
CH3 OCH3
7共5,3兲⫺7共4,4兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263624.890*共24兲
CH3 OCH3
6共5,1兲⫺6共4,2兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263626.601*共14兲
CH3 OCH3
6共5,1兲⫺6共4,2兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263627.056*共14兲
CH3 OCH3
6共5,2兲⫺6共4,3兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263628.767*共16兲
CH3 OCH3
6共5,2兲⫺6共4,3兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263629.417*共14兲
CH3 OCH3
6共5,1兲⫺6共4,2兲 EE
3.7b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263631.363*共14兲
CH3 OCH3
6共5,2兲⫺6共4,3兲 EE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263633.724*共16兲
CH3 OCH3
6共5,1兲⫺6共4,2兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263634.179*共16兲
CH3 OCH3
6共5,2兲⫺6共4,3兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263653.326*共24兲
CH3 OCH3
5共5,0兲⫺5共4,1兲 EA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263655.248*共16兲
CH3 OCH3
5共5,0兲⫺5共4,1兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263655.339*共16兲
CH3 OCH3
5共5,1兲⫺5共4,2兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263657.260*共16兲
CH3 OCH3
5共5,1兲⫺5共4,2兲 AE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263657.923*共14兲
CH3 OCH3
5共5,0兲⫺5共4,1兲 EE
1.8b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263659.890*共14兲
CH3 OCH3
5共5,1兲⫺5共4,2兲 EE
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263662.424*共14兲
CH3 OCH3
5共5,0兲⫺5共4,1兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263662.565*共14兲
CH3 OCH3
5共5,1兲⫺5共4,2兲 AA
b
OriMC⫺1
JCMT 15 m
Gre91
Gro98
263744.0 263748.630*共13兲 263749.414*共31兲 263792.304*共11兲 263810.807*共14兲 264270.108*共19兲 264330. 264439.36* 共12兲
unidentified HNCO AlF HCCCN CH3 CH2 CN H2 CO unidentified HCCCN
12共0,12兲⫺11共0,11兲 8⫺7 29⫺28 29共2,27兲⫺28共2,26兲 10共1,9兲⫺10共1,10兲
2.8 0.3 0.027 0.6 1.9 1.0 1.0
JCMT 15 m MMWO 4.9 m NRAO 12 m MMWO 4.9 m JCMT 15 m NRAO 12 m NRAO 12 m JCMT 15 m
Gre91 Arm84 Hig01 Arm84 Gre91 Ziu86 Ziu86 Gre91
Laf78
264451.38* 共27兲
H13CCCN
b
29⫺28 v 7 ⫽1 ᐉ⫽1 e 30⫺29
3.6b
OriMC⫺1 OriMC⫺1 CRL2688 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
b
OriMC⫺1
JCMT 15 m
Gre91
12共1,11兲⫺11共1,10兲 30共1,29兲⫺29共1,28兲
6.7 4.0 3.9
OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m JCMT 15 m
Gre91 Gre91 Gre91
Win76
34
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT JCMT JCMT JCMT JCMT JCMT
m m m m m m
Gre91 Gre91 Gre91 Gre91 Gre91 Gre91
Oes99
6共1,5兲⫺5共2,3兲 E 34共4,30兲⫺34共3,31兲 26共4,22兲⫺26共2,23兲
1.7 2.0 2.6 5.6 3.2 n.r.
34
7共2,6兲⫺6共1,5兲
1.3
OriMC⫺1
JCMT 15 m
Gre91
4共4,1兲⫺3共3,0兲
3.1 0.16 0.8 0.21
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT 15 m MMWO 4.9 m NRAO 12 m MMWO 4.9 m
Gre91 Lor84a Ziu86 Lor84a
0.8 1.5
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Ziu86 Ziu86
20. 8.6 2.5 8.0 3.5 1.1
Hale 5m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m
Hug79 Gre91 Gre91 Gre91 Gre91 Gre91 Gre91
Mak02
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
1.7 0.20
OriMC⫺1 OriMC⫺1
MMWO 4.9 m NRAO 12 m
Joh84 Tur90
Xu_97 JPL01
264693.665*共20兲
HNCO
264747.883*共12兲 264817.01* 共12兲
CH3 CH2 CN HCCCN
265024.851*共20兲
CH3 OCHO
265176.0 265200.0 265289.616*共15兲 265481.962*共31兲 265488.699*共41兲
unidentified unidentified CH3 OH SO2 SO2
29⫺28 v 7 ⫽1 ᐉ⫽1 f 21共6,15兲⫺20共6,14兲 A
SO2
U U U
265630.0 265698. 265700. 265759.484*共6兲
U
265760. 265852.709*共10兲
c⫺C3 H2 unidentified HCN
265886.436*共4兲 266084.0 266161.070 共25兲 266334.469*共20兲 266386.0 266613.0 266832.197*共16兲
HCN unidentified HDO CH3 CH2 CN unidentified unidentified CH3 OCHO
22共4,19兲⫺21共4,18兲 A
266838.123*共15兲 266943.323*共5兲
CH3 OH SO2
5共2,3兲⫺4共1,3兲 E 30共9,21兲⫺31共8,24兲
U U
Source
263512.082*共14兲
265554.040*共11兲
U
T r 共K兲/T a 共K兲
unidentified unidentified unidentified
3⫺2 v 2 ⫽1 ᐉ⫽1 e 3⫺2 2共2,0兲⫺3共1,3兲 8共8,*兲⫺9共7,*兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
15 15 15 15 15 15
Laf78
Xu_97
Mak02
DeL71
Oes99
MICROWAVE TRANSITIONS
301
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
266951.661*共23兲 267109.142*共4兲
CH3 CH2 CN HCN
14共4,12兲⫺15共2,13兲
1.8 0.2
OriMC⫺1 IRC⫹10216
JCMT 15 m IRAM 30 m
Gre91 Luc89
Mak02
267120.101*共4兲
HCN
0.5
IRC⫹10216
IRAM 30 m
Luc89
Mak02
267197.774*共85兲 267199.282*共10兲
SO HCN
3⫺2 v 2 ⫽2 ᐉ⫽2 e 3共4兲⫺4共3兲
6.3 1.5
OriMC⫺1 OriMC⫺1
JCMT 15 m NRAO 12 m
Gre91 Ziu86
Mak02
267242.195*共27兲
29
0.1b
IRC⫹10216
NRAO 12 m
Ziu86
OriMC⫺1
NRAO 12 m
Tur87
9共0,9兲⫺8共1,7兲 E 22⫺21 13共3,11兲⫺13共2,12兲 3⫺2
0.17b 2.8 1.8 r r 12.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT 15 m UKIRT 3.8 m MMWO 4.9 m MMWO 4.9 m Hale 5 m
Gre91 Den84 Lor84b Lor84b Hug79
13
15共8兲⫺14共8兲
4.1 1.5
OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m
Gre91 Gre91
12共5,8兲⫺12共4,8兲 L 15共7兲⫺14共7兲
2.6
13
b
OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m
Gre91 Gre91
28共4,24兲⫺28共3,25兲
4.9b
OriMC⫺1
JCMT 15 m
Gre91
15共4兲⫺14共4兲
2.3b
OriMC⫺1
JCMT 15 m
Gre91
b
OriMC⫺1
JCMT 15 m
Gre91
24共5,20兲⫺23共6,18兲 E
1.0
OriMC⫺1
JCMT 15 m
Gre91
1.0
OriMC⫺1
JCMT 15 m
Gre91
SiS HCN
267243.195*共5兲 U
U
267360.0 267403.394*共15兲 267530.216*共2兲 267537.437*共8兲 267557.633*共60兲 267620.0 267638.833*共44兲 267642.78共10兲 267704.059*共34兲
unidentified CH3 OH OCS SO2 HCO⫹ unidentified CH3 CN NH2 D CH3 CN
267719.808*共28兲 267869.822*共19兲 267871.059*共15兲
U U
U U
34
SO2 CH3 OH
3⫺2 v2 ⫽2 ᐉ⫽0
15共3,13兲⫺15共2,14兲
Mak02 Xu_97
13
15共3兲⫺14共3兲
267945.291*共20兲
13
15共1兲⫺14共0兲
b
OriMC⫺1
JCMT 15 m
Gre91
267950.325*共20兲
13
15共0兲⫺14共0兲
OriMC⫺1
JCMT 15 m
Gre91
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 Sgr B2共OH兲
JCMT 15 m JCMT 15 m NRAO 12 m NRAO 12 m NRAO 12 m
Gre91 Gre91 App97 App97 Ziu95a
Bla83
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m JCMT 15 m JCMT 15 m
App97 App97 Gre91 Gre91
Oes99 Oes99
CH3 CN CH3 CN
Xu_97
HOC⫹ unidentified unidentified CH3 OCHO CH3 OCHO
3⫺2
1.0b 2.7 3.9 0.02 0.02 0.062
23共2,21兲⫺22共2,20兲 E 23共2,21兲⫺22共2,20兲 A
0.02 0.02 1.3 0.8
H2 C18O CH3 CH2 CN
4共1,4兲⫺3共1,3兲
0.64
OriMC⫺1
MMWO 4.9 m
Man90
268803.090*共13兲
30共10,*兲⫺29共10,*兲
2.8b
OriMC⫺1
JCMT 15 m
Gre91
268803.888*共13兲
CH3 CH2 CN
30共11,*兲⫺29共11,*兲
b
OriMC⫺1
JCMT 15 m
Gre91
268824.320*共14兲
CH3 CH2 CN
30共12,*兲⫺29共12,*兲
3.8b
OriMC⫺1
JCMT 15 m
Gre91
268828.759*共13兲
CH3 CH2 CN
30共9,*兲⫺29共9,*兲
b
OriMC⫺1
JCMT 15 m
Gre91
268860.124*共15兲 268892.467*共13兲
CH3 CH2 CN CH3 CH2 CN
30共13,*兲⫺29共13,*兲
2.8
OriMC⫺1
JCMT 15 m
Gre91
30共8,23兲⫺29共8,22兲
4.0b
OriMC⫺1
JCMT 15 m
Gre91
268892.477*共13兲
CH3 CH2 CN
30共8,22兲⫺29共8,21兲
b
OriMC⫺1
JCMT 15 m
Gre91
268908.520*共15兲 268967.624*共15兲
CH3 CH2 CN CH3 CH2 CN CH3 CH2 CN
30共14,*兲⫺29共14,*兲
2.8
OriMC⫺1
JCMT 15 m
Gre91
30共15,*兲⫺29共15,*兲 30共7,24兲⫺29共7,23兲
1.0 3.3b
OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m
Gre91 Gre91
269015.530*共12兲
CH3 CH2 CN
30共7,23兲⫺29共7,22兲
b
OriMC⫺1
JCMT 15 m
Gre91
269036.117*共14兲 269078.016*共17兲
CH3 CH2 CN CH3 OCHO
30共16,*兲⫺29共16,*兲
0.5
OriMC⫺1
JCMT 15 m
Gre91
24共2,23兲⫺23共2,22兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269083.401*共17兲
CH3 OCHO
24共2,23兲⫺23共2,22兲 A
1.8b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269084.854*共17兲
CH3 OCHO
24共1,23兲⫺23共1,22兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269090.220*共17兲
CH3 OCHO
24共1,23兲⫺23共1,22兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269156. 269933.102*共21兲
unidentified CH3 OCHO
0.5 25共0,25兲⫺24共1,24兲 E
b
OriMC⫺1 OriMC⫺1
NRAO 12 m JCMT 15 m
Ziu91a Gre91
Oes99
269933.182*共21兲
CH3 OCHO
25共1,25兲⫺24共1,24兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269933.252*共21兲
CH3 OCHO
25共0,25兲⫺24共0,24兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269933.332*共21兲
CH3 OCHO
25共1,25兲⫺24共0,24兲 E
4.3b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269933.899*共21兲
CH3 OCHO
25共0,25兲⫺24共1,24兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269933.979*共21兲
CH3 OCHO
25共1,25兲⫺24共1,24兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269934.048*共21兲
CH3 OCHO
25共0,25兲⫺24共0,24兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
269934.128*共21兲
CH3 OCHO
25共1,25兲⫺24共0,24兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
270013.753*共43兲
22共21,*兲⫺21共21,*兲 A 22共14,*兲⫺21共14,*兲 A
1.5
270501.929*共17兲
CH3 OCHO CH3 OCHO
1.7b
OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m
Gre91 Gre91
Oes99 Oes99
270503.152*共21兲
CH3 OCHO
22共14,8兲⫺21共14,7兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
270520.90* 共42兲 270598.0 270664.0 270681.011*共21兲
H2 CS unidentified unidentified CH3 OCHO
8共1,8兲⫺7共1,7兲
3.6 3.2 4.7
22共13,9兲⫺21共13,8兲 E
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT JCMT JCMT JCMT
m m m m
Gre91 Gre91 Gre91 Gre91
Oes99
270683.963*共17兲
CH3 OCHO
22共13,*兲⫺21共13,*兲 A
1.9b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
268168.331*共7兲 268435. 268445. 268451.09共5兲 268463. 268475. 268552.675*共16兲 268561.162*共16兲 268745.769*共12兲
269015.133*共12兲
U
CH3 CN
3⫺2 v 2 ⫽1 ᐉ⫽1 f 15⫺14
267887.64* 共12兲 267905.031*共18兲
268002.524*共12兲 U U
SO2 13
3⫺2 v 2 ⫽2 ᐉ⫽2 f
CH3 CN CH3 CH2 CN SO2 unidentified unidentified
30共3,28兲⫺29共3,27兲 9共5,5兲⫺10共4,6兲
15 15 15 15
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
302
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
271228.929*共20兲
CH3 OCHO
22共11,11兲⫺21共11,10兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
CH3 OCHO
22共11,12兲⫺21共11,11兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
271240.119*共17兲
CH3 OCHO
22共11,11兲⫺21共11,10兲 A
OriMC⫺1
JCMT 15 m
Gre91
Oes99
271253.451*共17兲 271312.0 271410.221*共15兲
CH3 OCHO unidentified
22共11,11兲⫺21共11,10兲 E
2.1b 1.5 1.8 2.3
OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m JCMT 15 m
Gre91 Gre91 Gre91
Oes99
Oes99
17共2,16兲⫺17共1,17兲
271505.919*共17兲
34 SO2 CH3 OCHO
21共5,16兲⫺20共5,15兲 E
b
OriMC⫺1
JCMT 15 m
Gre91
271506.602*共12兲
CH3 CH2 CN
30共4,26兲⫺29共4,25兲
b
OriMC⫺1
JCMT 15 m
Gre91
271524.741*共17兲
CH3 OCHO
21共4,17兲⫺20共4,16兲 E
271528.993*共8兲
SO2
7共2,6兲⫺6共1,5兲
271532.859*共21兲
CH3 OCHO
271544.794*共17兲
CH3 OCHO
271981.131*共12兲 272028.0 272204. 272243.013*共20兲 272254.817*共17兲 272272.437*共17兲 272275.002*共17兲 272279.286*共16兲 272849.944*共12兲
HNC unidentified unidentified SiS CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO
3⫺2
15⫺14 22共9,13兲⫺21共9,12兲 E 22共9,14兲⫺21共9,13兲 A 22共9,13兲⫺21共9,12兲 A 22共9,14兲⫺21共9,13兲 E
OC34S CH3 OCHO HCCCN CH3 OCHO
23⫺22
1.7
OriMC⫺1
JCMT 15 m
Gre91
23共3,20兲⫺22共4,19兲E 30⫺29 23共3,20兲⫺22共4,19兲A
2.4 0.8
OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT 15 m MMWO 4.9 m JCMT 15 m
Gre91 Lor81 Gre91
4共1,4兲⫺3共1,3兲
1.20
OriMC⫺1
MMWO 4.9 m
Man90
15共3,13兲⫺15共2,14兲 15共6兲⫺14共6兲 15共5兲⫺14共5兲 15共4兲⫺14共4兲
1.7 0.47 0.39 0.42
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO MMWO MMWO MMWO
4.9 4.9 4.9 4.9
m m m m
Lor84c Lor84 Lor84 Lor84
15共3兲⫺14共3兲 15共2兲⫺14共2兲 15共1兲⫺14共1兲 15共0兲⫺14共0兲 9共⫺1,9兲⫺8共0,8兲 E
0.96 0.83 1.17 1.24 1.0 1.5
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO MMWO MMWO MMWO MMWO MMWO
4.9 4.9 4.9 4.9 4.9 4.9
m m m m m m
Lor84 Lor84 Lor84 Lor84 Lor84c Lor84c
8共1,7兲⫺7共1,6兲 3⫺2
0.8 0.9
OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m
Lor84f Lor84g
4共1,4兲⫺3共1,3兲 15共1,15兲⫺14共0,14兲 6⫺5 9共⫺3,7兲⫺10共⫺2,9兲E 31⫺30 6共2,4兲⫺5共1,5兲 20共1,19兲⫺20共0,20兲 4共0,4兲⫺3共0,3兲
1.4 1.0 0.10 0.8 0.8 1.6 0.7 0.50
rhoOphB OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m NRAO 12 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Lor83 Lor84c Tur87b Lor81 Lor81 Lor81 Lor84f Man90
22共2,20兲⫺21共3,19兲 4⫺3
0.10 0.36 0.22 ⬍1.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 p⫺Oph
MMWO MMWO MMWO MMWO
Man90 Lor85 Lor85 Lor82
274762.114*共7兲 275240.168*共10兲 275724.719*共6兲 275782.988*共5兲 275830.694*共4兲 275867.819*共4兲 275894.347*共4兲 275910.268*共4兲 275915.575*共4兲 278263. 278304.575*共15兲 278886.56* 共42兲 279511.732*共77兲 281526.918*共13兲 281762.581*共10兲 281914.13共10兲 281956.537*共19兲 281976.781*共13兲 282036.546*共8兲 282292.801*共8兲 283441.874*共7兲 286293.697*共12兲 U
Quantum numbers
271240.112*共17兲
272864.400*共17兲 272884.738*共12兲 272885.543*共20兲
U
Formula
H2 13CO SO2 CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN unidentified CH3 OH H2 CS N 2 H⫹ H2 CO SO2 PN CH3 OH HCCCN SO2 SO2 H2 13CO H2 C18O
b
OriMC⫺1
JCMT 15 m
Gre91
2.7b
OriMC⫺1
JCMT 15 m
Gre91
21共5,16兲⫺20共5,15兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
21共4,17兲⫺20共4,16兲 A
b
OriMC⫺1
JCMT 15 m
Gre91
Oes99
OriMC⫺1 OriMC⫺1 OriMC⫺1 IRC⫹10216 Ori⫺KL共N兲 Ori⫺KL共N兲 Ori⫺KL共N兲 Ori⫺KL共N兲
Hale 5 m JCMT 15 m NRAO 12 m MMWO 4.9 m NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m
Hug79 Gre91 Ziu91a Sah84 Ziu91a Ziu91a Ziu91a Ziu91a
4共1,3兲⫺3共1,2兲
10. 1.7 0.3 0.48 0.9 0.9 0.9 0.9
b
4.9 4.9 4.9 4.9
m m m m
Oes99
Oes99 Laf78 Oes99
Xu_97
Wys72 Xu_97
286342.45 286416.298*共9兲 288143.911*共29兲
unidentified SO2
289209.098*共22兲
C34S DCN CH3 OH CH3 OH
6⫺5
0.8
OriMC⫺1
MMWO 4.9 m
Lor85
289644.920*共4兲 289939.386*共7兲 290307.294*共6兲
4⫺3 6共0,6兲⫺5共0,5兲 E 6共⫺2,5兲⫺5⫺2,4兲 E
1.65 2.1
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Gre85 Pla82 Man90
Xu_97 Xu_97
290307.738*共7兲
CH3 OH
6共2,4兲⫺5共2,3兲 E
OriMC⫺1
MMWO 4.9 m
Man90
Xu_97
290380.702*共22兲 290479.902*共4兲 290496.515*共4兲 290502.053*共4兲 290562.252*共36兲
SiS CH3 CCH CH3 CCH CH3 CCH
16⫺15 17共2兲⫺16共2兲 17共1兲⫺16共1兲 17共0兲⫺16共0兲
MMWO MMWO MMWO MMWO
Sah84 Lor84b Lor84b Lor84b
6共7兲⫺5共6兲
0.4
OriMC⫺1
MMWO 4.9 m
Lor84b
290623.410*共13兲 291237.769*共12兲 291380.454*共13兲
H2 CO H2 CO H2 CO
4共0,4兲⫺3共0,3兲 4共2,3兲⫺3共2,2兲 4共3,2兲⫺3共3,1兲
3.8 2.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Lor84b Lor84a Lor84a
291384.373*共13兲
H2 CO
4共3,1兲⫺3共3,0兲
291782.262*共33兲 291839.649*共3兲 291948.071*共12兲 292412.248*共6兲
CS OCS H2 CO CH3 OCH3
6⫺5 v⫽1 24⫺23 4共2,2兲⫺3共2,1兲 16共1,16兲⫺15共0,15兲 AE⫹EA
0.027 0.53 1.9
292412.420*共6兲
CH3 OCH3
16共1,16兲⫺15共0,15兲 EE
0.36b
DCO⫹
34
SO
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
4.0b b
0.22 0.14 0.32 0.3
2.3b b
b
IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1
4.9 4.9 4.9 4.9
m m m m
OriMC⫺1
MMWO 4.9 m
Lor84a
IRC⫹10216 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m MMWO 4.9 m MMWO 4.9 m MMWO 4.9 m
Hig00 Lor84b Lor84a Woo85
Gro98
OriMC⫺1
MMWO 4.9 m
Woo85
Gro98
MICROWAVE TRANSITIONS
303
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Lab. Ref.
b
OriMC⫺1
MMWO 4.9 m
Woo85
Gro98
1.00
OriMC⫺1
MMWO 4.9 m
Man90
OriMC⫺1 OriMC⫺2 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO MMWO MMWO MMWO MMWO MMWO
Lor84b Sne84 Lor84a Lor84a Lor84a Eri84
292412.592*共6兲
CH3 OCH3
16共1,16兲⫺15共0,15兲 AA 4共1,3兲⫺3共1,2兲
293464.203*共17兲 293912.097*共13兲 294098.885*共6兲 294161.016*共5兲 294211.885*共4兲 298576.283*共9兲 299703.88* 共16兲
H2 13CO CH3 OH CS CH3 CN CH3 CN CH3 CN SO2 SiO
3共2,1兲⫺4共1,4兲 A⫹ 6⫺5 16共6兲⫺15共6兲 16共5兲⫺15共5兲 16共4兲⫺15共4兲 9共2,8兲⫺8共1,7兲 7⫺6 v⫽2
0.95 3.3 0.29 0.16 0.29 2.0
300836.631*共13兲 301286.193*共14兲 301814.37* 共15兲
H2 CO SO SiO
4共1,3兲⫺3共1,2兲 7共7兲⫺6共6兲 7⫺6 v⫽1
303926.88* 共16兲 303993.256*共3兲 304077.914*共19兲 304122.6 304208.324*共13兲 304306.2*共6兲
SiO OCS SO unidentified CH3 OH H2 CS H2 CS
7⫺6 v⫽0 25⫺24 8共7兲⫺7共6兲
34
SO2
6.4 e 3.9 2.7
4.9 4.9 4.9 4.9 4.9 4.9
m m m m m m
RAqr
JCMT 15 m
Gra95
OriMC⫺1 OriMC⫺1 RAqr
MMWO 4.9 m MMWO 4.9 m JCMT 15 m
Lor86 Lor86 Gra95
2共1,1兲⫺2共0,2兲 A⫺⫹
22.0 e 8. 3.3 13. 0.4 7.2
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO NRAO
m m m m m
Hol86 Hol86 Hol86 Woo86 Hol86
9共1,9兲⫺8共1,8兲 9共1,9兲⫺8共1,8兲 3共3,1兲⫺2共2,0兲
2.0 6.0 0.7
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m CSO 10.4 m NRAO 12 m
Hol86 Phi92 Hol86
12 12 12 12 12
Xu_97
Xu_97
304371.281*共8兲
CH3 OCH3
14共2,13兲⫺13共1,12兲 AE⫹EA
b
OriMC⫺1
NRAO 12 m
Hol86
Gro98
304372.642*共6兲
CH3 OCH3
14共2,13兲⫺13共1,12兲 EE
1.6b
OriMC⫺1
NRAO 12 m
Hol86
Gro98
304374.003*共8兲
CH3 OCH3
14共2,13兲⫺13共1,12兲 AA
b
OriMC⫺1
NRAO 12 m
Hol86
Gro98
307165.911*共13兲 307165.911*共13兲
CH3 CHO CH3 OH
4共1,3兲⫺4共0,4兲 A⫺⫹
0.6
Barnard1
CSO 10.4 m
Lis02
Kle96
4共1,3兲⫺4共0,4兲 A⫺⫹ 1共1兲 ⫺ ⫺2共1兲 ⫹
6.6 0.6
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Hol86 Hol86
Xu_97 Plu85
13
4共1,3兲⫺4共0,4兲 A⫺⫹
0.5 1.0
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Woo86 Woo86
Xu_97
13
4共1,3兲⫺4共0,4兲 A⫹⫹
4.0
OriMC⫺1
CSO 10.4 m
Phi92
Xu_97
2共2兲⫺2共1兲
Barnard1 Barnard1
CSO 10.4 m CSO 10.4 m
Lis02 Lis02
307205.4 307311.413*共20兲 307311.431*共20兲 309502.468*共57兲 309908.111*共1兲
H3 O⫹ unidentified CH3 OH CH3 OH SO ND3
1共0兲 a⫺0共0兲 s F⫽1⫺1
0.24 0.7
309909.338*共1兲
ND3
1共0兲a⫺0共0兲 s F⫽2⫺1
1.3
Barnard1
CSO 10.4 m
Lis02
309911.179*共1兲
ND3
0.3
Barnard1
CSO 10.4 m
Lis02
310193.059*共8兲 317250.336*共11兲
CH3 CHO SO2 CH3 OH H2 O CH2 NH CH3 OH HDCO
1共0兲a⫺0共0兲 s F⫽0⫺1 3共1,2兲⫺2共0,2兲 E
0.5
Barnard1
CSO 10.4 m
Lis02
17共7,11兲⫺18共6,12兲 8共1,7兲⫺8共0,8兲 A⫺⫹ 10共2,9兲⫺9共3,6兲 5共2,3兲⫺4共2,2兲 9共1,8兲⫺9共0,9兲 A⫺⫹ 5共4,1兲⫺4共4,0兲
0.71 6.0 3.0 1.1 5.5
W3共IRS5兲 W51 W51 OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT 15 m CSO 10.4 m CSO 10.4 m CSO 10.4 m CSO 10.4 m CSO 10.4 m
Hel97 Men90 Men90 Men90a Men90a Men90a
1.0b 0.5 1.0
OriMC⫺1
CSO 10.4 m
Men90a
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Men90a Men90a
318318.934*共18兲 321225.64共24兲 322161.6*共4兲 322239.480*共20兲 322496.309*共9兲 322496.309*共9兲
HDCO
5共4,2兲⫺4共4,1兲
322521.684*共20兲 322530.0*共7兲 322965.17共5兲
CH3 OCHO CH2 CHCN
25共6,19兲⫺24共6,18兲 A 38共4,35兲⫺38共3,36兲
325152.919 共27兲 329330.546*共5兲 330035.9 330191.143*共11兲
H2 18O H2 O C18O unidentified 34
1.0b
Kle96 Xu_97 DeL72a Xu_97
Oes99
5共1,5兲⫺4共2,2兲
0.5
OriMC⫺1
CSO 10.4 m
Men90a
DeL72
5共1,5兲⫺4共2,2兲 3⫺2
2.2 15.3
OriMC⫺1 Ori⫺bar⌬␣⫽⫹20⬙
CSO 10.4 m JCMT 15 m
Men90a Hog95
DeL72a
8共2,60_7共1,7兲
0.7 0.7
G34.3⫹0.15 G34.3⫹0.15
JCMT 15 m JCMT 15 m
Mac96 Mac96
JCMT 15 m JCMT 15 m JCMT 15 m
Mac96 Mac96 Mac96
Xu_97
330355.780*共52兲 330371.935*共5兲 330405.459*共8兲
SO2 CH3 OH CH2 CHCN CH3 OCH3
20共3,17兲⫺19共4,16兲 A⫺⫺ 11共3,8兲⫺10共2,9兲 16共2,15兲⫺15共1,14兲 EA⫹AE
0.8 0.7 b
G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15
330406.505*共6兲
CH3 OCH3
16共2,15兲⫺15共1,14兲 EE
0.7b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
330407.552*共8兲
CH3 OCH3
16共2,15兲⫺15共1,14兲 AA
b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
330459.651*共28兲 330587.960*共4兲
NH2 CHO
19共1,18兲⫺18共2,17兲
0.7
G34.3⫹0.15
JCMT 15 m
Mac96
330667.759*共24兲
U
Astr. Ref.
293126.507*共7兲
307192.41共5兲
U
Telescope
Quantum numbers
304306.20* 共61兲 304332.022*共11兲
U
Source
T r 共K兲/T a 共K兲
Formula
13
CO
34
3⫺2
16.03
OriMC⫺1
NRAO 12 m
Jew89
21共2,20兲⫺21共1,21兲
7.3f
Sgr B2共M兲
CSO 10.4 m
Sut91
8共⫺3,6兲⫺9共⫺2,8兲 E
7.8f 1.59 1.23
Sgr B2共M兲
CSO 10.4 m
Sut91
OriMC⫺1 OriMC⫺1 Sgr B2共M兲
NRAO 12 m NRAO 12 m CSO 10.4 m
Jew89 Jew89 Sut91
IRC⫹10216
CSO 10.4 m
Gro94
IRC⫹10216
CSO 10.4 m
Gro94
330793.977*共19兲
SO2 CH3 OH
330797. 330842.781*共7兲 330848.8*共 兲
unidentified CH3 CN HNCO
18共6兲⫺17共6兲 15共1,14兲⫺14共1,13兲
330870.463*共45兲
SiC2
14共6,9兲⫺13共6,8兲
330874.450*共46兲
SiC2
14共6,8兲⫺13共6,7兲
330912.624*共5兲 330969.806*共5兲 331014.305*共5兲
CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN
18共5兲⫺17共5兲 18共4兲⫺17共4兲
0.88 1.38
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
18共3兲⫺17共3兲 18共2兲⫺17共2兲 18共1兲⫺17共1兲
1.38 1.60 1.64
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m NRAO 12 m
Jew89 Jew89 Jew89
331046.103*共5兲 331065.186*共5兲
17.2f 6.4 bf b
Gro98
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
304
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
331071.548*共5兲 331220.395*共29兲 331469.442*共17兲 331502.333*共24兲 331580.171*共11兲
CH3 CN CH3 OH CH3 OCHO CH3 OH SO2
18共0兲⫺17共0兲 16共⫺1,16兲⫺15共⫺2,14兲 E 28共3,25兲⫺27共3,24兲 A 11共1,10兲⫺11共0,11兲 A⫺⫹
1.77 0.8 0.5 1.99
OriMC⫺1 G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1
NRAO 12 m JCMT 15 m JCMT 15 m NRAO 12 m
Jew89 Mac96 Mac96 Jew89
Xu_97 Oes99 Xu_97
332015.78* 共10兲
CH3 CN
17共0兲⫺16共0兲 v8 ⫽1 ᐉ⫽⫺1
332017.77* 共10兲
CH3 CN
17共⫺1兲⫺16共⫺1兲 v8 ⫽1 ᐉ⫽⫹1
332091.412*共12兲
SO2
21共2,20兲⫺21共1,21兲 23共3,21兲⫺23共1,22兲
332173.585*共33兲
U
U
4共3,1兲⫺3共2,2兲 35共6,30兲⫺34共6,29兲
CSO 10.4 m
Sut91
OriMC⫺1
NRAO 12 m
Jew89
Wlo88
b
OriMC⫺1
NRAO 12 m
Jew89
Wlo88
1.92 13.6f 3.02 0.6
OriMC⫺1 Sgr B2共M兲
NRAO 12 m CSO 10.4 m
Jew89 Sut91
OriMC⫺1 G34.3⫹0.15
NRAO 12 m JCMT 15 m
Jew89 Mac96 Gro94
SO2 CH2 CHCN
19⫺18
5.1f
IRC⫹10216
CSO 10.4 m
332572.83* 共29兲
CH2 NH
5共1,4兲⫺4共1,3兲
13.5f
Sgr B2共M兲
CSO 10.4 m
Sut91
332575.690*共24兲
CH3 OCHO
30共1,29兲⫺29共1,28兲 A
0.64b
OriMC⫺1
NRAO 12 m
Jew89
332575.959*共24兲
CH3 OCHO
30共2,29兲⫺29共2,28兲 A
b
OriMC⫺1
NRAO 12 m
Jew89
Oes99
332780.945*共50兲
NH2 D
1共0,1兲⫺0共0,0兲 F⫽0⫺1 o
b
L134N
IRAM 30 m
Tin00
JPL01
332781.796*共50兲
NH2 D
1共0,1兲⫺0共0,0兲 F⫽2⫺1 o
0.4b
L134N
IRAM 30 m
Tin00
JPL01
332782.363*共50兲
NH2 D
1共0,1兲⫺0共0,0兲 F⫽1⫺1 o
b
L134N
IRAM 30 m
Tin00
JPL01
332821.560*共50兲
NH2 D
1共0,1兲⫺0共0,0兲 F⫽0⫺1 p
b
L1689N
CSO 10.4 m
Sha01
JPL01
332822.415*共50兲
NH2 D
1共0,1兲⫺0共0,0兲 F⫽2⫺1 p
0.4b
L1689N
CSO 10.4 m
Sha01
JPL01
332822.985*共50兲
NH2 D
1共0,1兲⫺0共0,0兲 F⫽1⫺1 p
b
L1689N
CSO 10.4 m
Sha01
JPL01
332836.235*共21兲
34
Sgr B2共M兲
CSO 10.4 m
Sut91
G34.3⫹0.15
JCMT 15 m
Mac96
JCMT 15 m JCMT 15 m JCMT 15 m CSO 10.4 m
Mac96 Mac96 Mac96 Gro94
30
SiS
SO2
16共4,12兲⫺16共3,13兲
2.8f 0.5
Oes99
13 CH3 OH unidentified unidentified HDS SiC2
7共1,6兲⫺6共1,5兲 A⫺⫺
333118.5 333162.1 333278.60* 共16兲 333386.048*共52兲
2共0,2兲⫺1共1,1兲 14共4,11兲⫺13共4,10兲
11.0f
G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15 IRC⫹10216
333419.207*共17兲
CH3 OCHO
27共12,16兲⫺26共12,15兲 A
0.6b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
333419.220*共17兲
CH3 OCHO
27共12,15兲⫺26共12,14兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
333438.1 333449.021*共25兲
unidentified CH3 OCHO
0.6 31共1,31兲⫺30共1,30兲 E
b
G34.3⫹0.15 G34.3⫹0.15
JCMT 15 m JCMT 15 m
Mac96 Mac96
Oes99
333449.023*共25兲
CH3 OCHO
31共0,31兲⫺30共0,30兲 E
0.9b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
333449.382*共37兲
CH3 OCHO
31共0,31兲⫺30共0,30兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
333449.384*共37兲
CH3 OCHO
31共1,31兲⫺30共1,30兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
0.4 0.5 0.3
Xu_97
Hel73
7共8兲⫺6共7兲
2.18
OriMC⫺1
NRAO 12 m
Jew89
334017.024*共20兲 334031.604*共17兲
SO CH3 OCHO CH3 OCHO
27共11,16兲⫺26共11,15兲 E 27共11,17兲⫺26共11,16兲 A
4.2 4.3b
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
Oes99 Oes99
334031.907*共17兲
CH3 OCHO
27共11,16兲⫺26共11,15兲 A
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Oes99
334044.338*共17兲 334109.090*共25兲 334265.8*共 兲 334426.561*共13兲 334456.9 334483.460*共9兲 334620.7
CH3 OCHO CH3 OCHO HCOOH CH3 OH unidentified NH2 CHO CH3 OH
27共11,17兲⫺26共11,16兲 E 15共6,10兲⫺14共5,9兲 A 15共2,14兲⫺14共2,13兲 3共0,3兲⫺2共1,2兲 E vt ⫽1
2.2 1.2 2.5 6.5 0.5 2.2
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共CR兲 W3共H2O兲
JCMT JCMT JCMT JCMT JCMT JCMT JCMT
m m m m m m m
Sut95 Sut95 Sut95 Sut95 Mac96 Sut95 Hel97
Oes99 Oes99 Sut95 Xu_97
334673.328*共10兲 334709.932*共17兲
SO2 NH2 CHO CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO unidentified
8共2,6兲⫺7共1,7兲
NRAO 12 m
Jew89
JCMT JCMT JCMT JCMT JCMT JCMT JCMT
Mac96 Sut95 Sut95 Sut95 Sut95 Mac96 Sut95
333900.981*共40兲
U
SO2
Sgr B2共M兲
1.22b
29.1f
332505.226*共9兲 332533.155*共7兲 332550.294*共65兲
333114.787*共9兲 U U
34
11共6,6兲⫺12共5,7兲
334850.962*共20兲 334867.021*共16兲 334872.802*共16兲 334877.659*共17兲 334893.0 334929.49* 共61兲 335092.20* 共49兲 335096.786*共13兲 335109.135*共17兲 335125.05* 共20兲
34
8共2,7兲⫺7共1,6兲 22共3兲⫺22共2兲 E vt ⫽2 17共0,17兲⫺16共1,16兲 27共10,17兲⫺26共10,16兲 E 27共10,18兲⫺26共10,17兲 A 27共10,17兲⫺26共10,16兲 A 27共10,18兲⫺26共10,17兲 E
0.37b 3.25 0.6 3.1 2.2 3.0 3.3 0.6 2.0
OriMC⫺1 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共SP兲
15 15 15 15 15 15 15 15 15 15 15 15 15 15
m m m m m m m
H13CCCN
37⫺36
HC13CCN HDCO CCCS
37⫺36
0.4
OriMC⫺1共CR兲
JCMT 15 m
Sut95
5共1,4兲⫺4共1,3兲 58⫺57 37⫺36
4.9 1.8 0.4
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
HCC13CN SO2
20共4,16兲⫺20共3,17兲 v2 ⫽1
Xu_97
Oes99 Oes99 Oes99 Oes99
Sgr B2共M兲
CSO 10.4 m
Sut91
CH3 OH CH3 OCHO CH3 OCHO CH3 CH2CN SiC2
2共2,1兲⫺3共1,2兲 A⫺ 28共4,24兲⫺26共5,23兲 E
1.98 0.9
OriMC⫺1 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m
Jew89 Sut95
Xu_97 Oes99
28共4,24兲⫺26共5,23兲 A 34共3,32兲⫺33共2,31兲 14共4,10兲⫺13共4,9兲
0.6 0.6
JCMT 15 m JCMT 15 m CSO 10.4 m
Sut95 Sut95 Gro94
Oes99
335321.262*共22兲 335341.931*共77兲
CH3 CH2 CN
9共6,*兲⫺8共5,*兲
13.0f 1.9
OriMC⫺1共CR兲 OriMC⫺1共CR兲 IRC⫹10216 OriMC⫺1共CR兲
JCMT 15 m
Sut95
Si34S
19⫺18
9.6f
IRC⫹10216
CSO 10.4 m
Gro94
335395.50共3兲 335402.700*共25兲
HDO CH3 OCHO
3共3,1兲⫺4共2,2兲 15共6,9兲⫺14共5,10兲 A
0.52 1.8
OriMC⫺1 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m
Jew89 Sut95
335128.523*共34兲 335133.686*共17兲 335158.094*共20兲 335183.323*共20兲 335226.854*共20兲 335289.690*共47兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
DeL71 Oes99
MICROWAVE TRANSITIONS
305
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
33546.53共10兲 335559. 335560.207*共40兲 335582.022*共7兲 335773.132*共48兲 335815.938*共21兲
U
U
Source
Telescope
Astr. Ref.
Lab. Ref.
NHD2 unidentified
1共1,1兲⫺0共0,0兲O⫺共a兲
OriMC⫺1 OriMC⫺1 OriMC⫺1共CR兲
NRAO 12 m NRAO 12 m JCMT 15 m
Tur90a Jew89 Sut95
DeL75
12共1,11兲⫺12共0,12兲 A⫺⫹
0.015 0.71 4.4
7共1,7兲⫺6共1,6兲 A⫹ 29共5,25兲⫺30共2,28兲 5共1,5兲⫺4共1,4兲
3.37 0.28 2.6
OriMC⫺1 W3共IRS5兲 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m JCMT 15 m
Jew89 Hel97 Sut95
Xu_97
26共5,22兲⫺26共4,21兲 A 26共5,22兲⫺26共4,21兲 E
OriMC⫺1共CR兲 OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m
Sut95 Sut95 Mac96 Sut95 Sut95 Sut95 Jew89 Sut95
Oes99 Oes99
27共9,19兲⫺26共9,18兲 A 27共9,19兲⫺26共9,18兲 E 27共9,18兲⫺26共9,17兲 E 23共3,21兲⫺23共2,22兲 27共9,18兲⫺26共9,17兲 A
1.6 1.1 0.6 3.6 3.1 3.0 2.17 2.3
13
CH3 OH CH3 OH SO2
Xu_97
336351.347*共17兲 336352.205*共87兲 336354.806*共20兲 336368.188*共17兲 336373.824*共20兲 336438.219*共36兲
1.6 3.8 0.62 5.5 3.5 3.9
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Jew89 Sut95 Sut95 Sut95
14共7,7兲⫺15共6,10兲 A⫺⫺
4.6b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
336438.219*共36兲
CH3 OH
14共7,8兲⫺15共6,9兲 A⫹⫹
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
336520.085*共21兲 336553.75* 共12兲
HCCCN SO
37⫺36 10共11兲⫺10共10兲
NRAO 12 m CSO 10.4 m
Jew89 Sut91
336614.038*共18兲 336638.0 336669.515*共13兲
CH3 OH CH3 CH2 CN unidentified SO2
7共1,7兲⫺6共1,6兲 A⫹⫹ vt ⫽2 20共4,17兲⫺19共3,16兲
16.2f 2.1 1.4 1.3
OriMC⫺1 Sgr B2共M兲
16共7,9兲⫺17共6,12兲
19.9f
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 Sgr B2共M兲
JCMT 15 m JCMT 15 m JCMT 15 m CSO 10.4 m
Sut95 Sut95 Sut95 Sut91
336760.698*共21兲
SO2
20共1,19兲⫺19共2,18兲 v2 ⫽1
336808.457*共8兲 336865.153*共26兲 336887.2 336889.203*共20兲 336918.151*共20兲 337029.5*共 兲
CH2 CHCN CH3 OH unidentified CH3 OCHO CH3 OCHO CH3 OH
37共0,37兲⫺36共1,36兲 12共1,11兲⫺12共0,12兲 A⫺⫹ 26共6,20兲⫺25共6,19兲 E 26共6,20兲⫺25共6,19兲 A 7共2,5兲⫺6共2,4兲 A⫹⫹ vt ⫽2
10.2f 0.9 3.47 0.7 4.4 4.4
CH3 OH
7共2,6兲⫺6共2,5兲 A⫺⫺ vt ⫽2
CH2 CHCN CH2 CHCN
36共2,35兲⫺35共2,34兲 35共3,32兲⫺34共3,31兲 3⫺2
1.3b 1.47
7共5,2兲⫺6共5,1兲 A⫺⫺ vt ⫽2
1.0b b
兲
兲
337039.739*共7兲 337050.913*共7兲 337061.123*共4兲
1.09
Oes99 Oes99 Oes99 Oes99 Oes99 Oes99 Oes99 Oes99
Xu_97
Sgr B2共M兲
CSO 10.4 m
Sut91
1.3b
OriMC⫺1共CR兲 OriMC⫺1 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Jew89 Mac96 Sut95 Sut95 Sut95
Oes99 Oes99 Xu_97
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
1.4
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
OriMC⫺1
NRAO 12 m
Jew89
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
Xu_97
337098.5*共
兲
C17O CH3 OH
337098.5*共
兲
CH3 OH
7共5,3兲⫺6共5,2兲 A⫹⫹ vt ⫽2
337113.8*共 兲 337135.858*共18兲
CH3 OH CH3 OH
7共1,7兲⫺6共1,6兲 E vt ⫽2
1.1
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
3共3,0兲⫺4共2,2兲 E
0.76 0.4 1.2 0.63 1.3
NRAO 12 m JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m
Jew89 Mac96 Sut95 Jew89 Sut95 Sut95
Xu_97
1.1b
OriMC⫺1 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲
Xu_97 Xu_97 Xu_97
U
337149.8 337159.4*共 337167.
兲
U
337175.2*共 337186.6*共 337198.4*共
兲 兲
unidentified CH3 OH unidentified CH3 OH CH3 OH
7共⫺4,3兲⫺6共⫺4,2兲 E vt ⫽2 7共0,7兲⫺6共0,6兲 E vt ⫽2
兲
CH3 OH
7共⫺5,3兲⫺6共⫺5,2兲 E vt ⫽2
1.8b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
7共8兲⫺6共7兲
9.6f
Sgr B2共M兲
CSO 10.4 m
Sut91
0.97
337199.730*共24兲
33
SO
7共6,1兲⫺6共6,0兲 E vt ⫽2
Xu_97
337201. 337252.3*共
兲
unidentified CH3 OH
7共3,4兲⫺6共3,3兲 A⫺⫺ vt ⫽2
b
OriMC⫺1 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m
Jew89 Sut95
Xu_97
337252.3*共
兲
CH3 OH
7共3,5兲⫺6共3,4兲 A⫹⫹ vt ⫽2
3.7b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
337273.6*共
兲
CH3 OH
7共4,3兲⫺6共4,2兲 A⫹⫹ vt ⫽2
4.3b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
337273.6*共
兲
CH3 OH
7共4,4兲⫺6共4,3兲 A⫺⫺ vt ⫽2
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
337278.9*共 337284.4*共
兲 兲
CH3 OH CH3 OH
7共⫺2,5兲⫺6共⫺2,4兲 E vt ⫽2 7共0,7兲⫺6共0,6兲 A vt ⫽2
3.7 5.2b
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
Xu_97 Xu_97
337296.0*共
兲
CH3 OH CH3 OH NH2 CHO CH3 OH CH3 OH
7共3,5兲⫺6共3,4兲 E vt ⫽2 7共1,7兲⫺6共1,6兲 A⫹⫹ vt ⫽1 19共2,18兲⫺19共1,19兲 7共2,6兲⫺6共2,5兲 E vt ⫽2 7共⫺1,6兲⫺6共⫺1,5兲 E vt ⫽2
3.0 7.1 0.88 3.5 4.1
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Jew89 Sut95 Sut95
Xu_97 Xu_97
337297.483*共11兲 337300.924*共34兲 337302.9*共 兲 337312.3*共 兲 337323.531*共41兲
U
T r 共K兲/T a 共K兲
16共2,15兲⫺15共2,14兲 27共6,22兲⫺26共6,21兲 E 29共4,25兲⫺29共3,26兲 26共5,21兲⫺25共5,20兲 E 27共6,22兲⫺26共6,21兲 A 26共5,21兲⫺25共5,20兲 A
337029.5*共
U
Quantum numbers
H2 C18O CH3 OCHO CH3 OCHO unidentified CH3 OCHO CH3 OCHO CH3 OCHO SO2 CH3 OCHO NH2 CHO CH3 OCHO NH2 CHO CH3 OCHO CH3 OCHO CH3 OCHO CH3 OH
335827.922*共34兲 335839.494*共32兲 335964.9 336028.154*共16兲 336032.505*共24兲 336086.111*共25兲 336089.210*共20兲 336111.318*共16兲 336135.519*共15兲
336605.8*共 U
Formula
337344.3*共4兲 337347.559*共19兲 337353. 337396.498*共27兲 337420.484*共16兲
t⫺CH3 CH2 OH
20共7,14兲⫺20共6,15兲
0.4
G34.3⫹0.15
JCMT 15 m
Mil95
HCCCN CH3 CH2 CN unidentified
37⫺36 v7 ⫽1 ᐉ⫽1 e 38共3,36兲⫺37共3,35兲
2.6 3.0 0.72 1.89
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m NRAO 12 m NRAO 12 m
Sut95 Sut95 Jew89 Jew89
b
OriMC⫺1共CR兲
JCMT 15 m
Sot95
C34S CH3 OCH3
7⫺6 21共2,19兲⫺20共3,18兲 AA
Xu_97 Xu_97
Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
306
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Source
Telescope
Astr. Ref.
Lab. Ref.
4.6b
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
b
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
0.6 2.5 0.6 4.0 1.7 2.2
G34.3⫹0.15 OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT JCMT JCMT JCMT JCMT JCMT
15 15 15 15 15 15
m m m m m m
Mac96 Sut95 Mac96 Sut95 Sut95 Sut95
1.6 1.0 4.1 5.8 5.6b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT JCMT JCMT JCMT JCMT
15 15 15 15 15
m m m m m
Sut95 Sut95 Sut95 Sut95 Sut95
Xu_97 Sut95 Oes99 Xu_97 Xu_97
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
OriMC⫺1
NRAO 12 m
Jew89
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1
JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m
Sut95 Sut95 Sut95 Sut95 Sut95 Sut95 Jew89
Xu_97 Sut95 Xu_97 Xu_97 Xu_97 Xu_97 Xu_97
CH3 OCH3
21共2,19兲⫺20共3,18兲 EE
CH3 OCH3
21共2,19兲⫺20共3,18兲 AE⫹EA
337445.858*共18兲 337461.6 337463.624*共17兲 337473.1 337489.669*共16兲 337490.378*共29兲
NH2 CN CH3 CH2 CN unidentified CH3 OH unidentified CH3 OCHO CH3 OH
17共1,17兲⫺16共1,16兲 vt ⫽1 37共4,33兲⫺36共4,32兲
337490.5*共 兲 337503.489*共16兲 337519.117*共13兲 337545.987*共18兲
HCOOH CH3 OCHO CH3 OH CH3 OH
7共⫺6,2兲⫺6共⫺6,1兲 E vt ⫽1 15共7,*兲⫺14共7,*兲 27共8,20兲⫺26共8,19兲 A 7共3,5兲⫺6共3,4兲 E vt ⫽1 7共5,2兲⫺6共5,1兲 A⫺⫺ vt ⫽1
337545.987*共18兲
CH3 OH
7共5,3兲⫺6共5,2兲 A⫹⫹ vt ⫽1
兲
7共6,1兲⫺6共6,0兲 A⫹⫹ vt ⫽1 27共8,20兲⫺26共8,19兲 E
8共8兲⫺7共7兲
34
1.92
337581.604*共13兲 337589.9*共 兲 337605.276*共11兲 337610.627*共11兲 337625.745*共11兲 337635.750*共11兲 337642.484*共12兲
SO CH3 OH HCOOH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH
7共4,4兲⫺6共4,3兲 E vt ⫽1 15共6,*兲⫺14共6,*兲 7共⫺2,5兲⫺6共⫺2,4兲 E vt ⫽1 7共⫺3,4兲⫺6共⫺3,3兲 E vt ⫽1 7共2,5兲⫺6共2,4兲 A⫹⫹ vt ⫽1 7共2,6兲⫺6共2,5兲 A⫺⫺ vt ⫽1 7共1,7兲⫺6共1,6兲 E vt ⫽1
337643.921*共11兲
CH3 OH
7共0,7兲⫺6共0,6兲 E vt ⫽1
337646.021*共13兲 337648.188*共24兲 337655.174*共13兲
CH3 OH CH3 OH CH3 OH
7共⫺4,3兲⫺6共⫺4,2兲 E vt ⫽1 7共⫺5,3兲⫺6共⫺5,2兲 E vt ⫽1 7共3,5兲⫺6共3,4兲 A⫹⫹ vt ⫽1
337655.211*共13兲
CH3 OH
7共3,4兲⫺6共3,3兲 A⫺⫺ vt ⫽1
337655.211*共18兲
CH3 OH
7共4,4兲⫺6共4,3兲 A⫺⫺ vt ⫽1
337671.194*共14兲 337685.218*共14兲 337685.594*共18兲
CH3 OH CH3 OH CH3 OH
7共2,6兲⫺6共2,5兲 E vt ⫽1 7共5,2兲⫺6共5,1兲 E vt ⫽1 7共4,4兲⫺6共4,2兲 A⫹⫹ vt ⫽1
337707.520*共18兲 337722.348*共12兲
CH3 OH CH3 OCH3
7共⫺1,6兲⫺6共⫺1,5兲 E vt ⫽1
5.4b 6.6
OriMC⫺1共CR兲
7共4,4兲⫺6共3,3兲 EE
0.12b
W3共H2O兲
337722.348*共12兲
CH3 OCH3
7共4,4兲⫺6共3,3兲 EE
6.1b
OriMC⫺1共CR兲
337722.995*共10兲
CH3 OCH3
7共4,4兲⫺6共3,3兲 AE
b
337722.995*共10兲
CH3 OCH3
7共4,4兲⫺6共3,3兲 AE
b
337726.967*共40兲
t⫺CH3 CH2 OH CH3 OCH3
19共7,12兲⫺19共6,13兲
0.4
337730.742*共12兲
7共4,4兲⫺6共3,3兲 AA
b
337730.742*共12兲
CH3 OCH3
7共4,4兲⫺6共3,3兲 AA
b
337731.850*共12兲
CH3 OCH3
7共4,3兲⫺6共3,3兲 EA
b
337731.850*共17兲
CH3 OCH3
7共4,3兲⫺6共3,3兲 EA
8.1b
337732.186*共12兲
CH3 OCH3
7共4,3兲⫺6共3,3兲 EE
b
337732.186*共12兲
CH3 OCH3
7共4,3兲⫺6共3,3兲 EE
0.26b
337748.771*共26兲
CH3 OH CH3 OCH3
7共0,7兲⫺6共0,6兲 A⫹⫹ vt ⫽1 7共4,4兲⫺6共3,4兲 EA
7.0
337770.614*共16兲 337770.614*共17兲 337778.025*共10兲
CH3 OCH3 CH3 OCH3
337778.025*共10兲 337779.470*共10兲 337779.470*共10兲 337785.1*共
兲
337787.216*共12兲 337787.8*共
兲
337787.863*共14兲
U U
T r 共K兲/T a 共K兲
337421.032*共12兲
337580.162*共20兲
U U U
Quantum numbers
337421.580*共14兲 337427.8*共 U
Formula
3.5 2.0 5.5 8.9 9.4 10.9 b
Oes99
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
8.5b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
Xu_97 Xu_97 Xu_97
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
6.7 2.3
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
Xu_97 Xu_97 Xu_97
JCMT 15 m
Sut95
Xu_97
JCMT 15 m
Hel97
Gro98
JCMT 15 m
Sot95
Gro98
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
W3共H2O兲
JCMT 15 m
Hel97
Gro98
G34.3⫹0.15
JCMT 15 m
Mil95
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
W3共H2O兲
JCMT 15 m
Hel97
Gro98
W3共H2O兲
JCMT 15 m
Hel97
Gro98
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
W3共H2O兲
JCMT 15 m
Hel97
Gro98
b
OriMC⫺1共CR兲 W3共H2O兲
JCMT 15 m JCMT 15 m
Sut95 Hel97
Xu_97 Gro98
7共4,4兲⫺6共3,4兲 EA
2.3
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
7共4,4兲⫺6共3,4兲 EE
0.47b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
CH3 OCH3
7共4,4兲⫺6共3,4兲 EE
7.3b
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
CH3 OCH3
7共4,3兲⫺6共3,4兲 AE
b
OriMC⫺1共CR兲
JCMT 15 m
Sot95
Gro98
CH3 OCH3
7共4,3兲⫺6共3,4兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
HCOOH
15共5,11兲⫺14共5,10兲
9.0b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Sut95
CH3 OCH3
7共4,3兲⫺6共3,4兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Sut95
W3共H2O兲
JCMT 15 m
Hel97
Gro98
W3共H2O兲
JCMT 15 m
Hel97
Gro98
JCMT JCMT JCMT JCMT JCMT JCMT
m m m m m m
Sut95 Sut95 Mac96 Sut95 Mac96 Sut95
Oes99
G34.3⫹0.15 W3共H2O兲
JCMT 15 m JCMT 15 m
Mac96 Hel97
Xu_97 Xu_97
1.05b 4.5 1.9
HCOOH
15共5,10兲⫺14共5,9兲
b
CH3 OCH3
7共4,3兲⫺6共3,4兲 EE
0.39b
337790.076*共24兲
CH3 OCH3
7共4,3兲⫺6共3,4兲 EA
337811.639*共50兲 337824.9*共4兲 337829.1 337839.3 337844.4 337877.5*共 兲
CH3 OCHO HCCCN unidentified unidentified unidentified CH3 OH
44共6,39兲⫺44共5,40兲 A 37⫺36 v7 ⫽1 ᐉ⫽1 f
1.1 2.3 0.5 1.6 0.4
7共1,6兲⫺6共1,5兲 A vt ⫽2
337892.524*共27兲 337938.089*共67兲 337969.434*共12兲
SO2 CH3 OH
21共2,20兲⫺21共1,21兲 v2 ⫽1 20共⫺6,14兲⫺21共⫺5,16兲 E
2.1b 0.4 0.28
CH3 OH
7共1,6兲⫺6共1,5兲 A⫺⫺ vt ⫽1
8.4
OriMC⫺1共CR兲
JCMT 15 m
Sut95
10共1,10兲⫺9共1,9兲
0.9 0.86 1.78
G34.3⫹0.15 OriMC⫺1 OriMC⫺1
JCMT 15 m NRAO 12 m NRAO 12 m
Mac96 Jew89 Jew89
337969.6 337973. 338081.1*共9兲
Xu_97
unidentified unidentified H2 CS
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共CR兲
15 15 15 15 15 15
Xu_97
MICROWAVE TRANSITIONS
307
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Source
Telescope
Astr. Ref. Mil95
t⫺CH3 CH2 OH
18共7,11兲⫺18共6,12兲
0.5
G34.3⫹0.15
JCMT 15 m
18共7,12兲⫺18共6,13兲
0.5
G34.3⫹0.15
JCMT 15 m
Mil95
7共0,7兲⫺6共0,6兲 E 37共3,34兲⫺36共3,33兲
4.48
OriMC⫺1 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m
Jew89 Sut95
Xu_97
OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲 Sgr B2共M兲
JCMT 15 m NRAO 12 m JCMT 15 m CSO 10.4 m
Sut95 Jew89 Sut95 Sut91
Sut95
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
OriMC⫺1 Sgr B2共M兲
NRAO 12 m CSO 10.4 m
Jew89 Sut91
338143.7*共 兲 338147. 338201.8*共 兲 338204.003*共7兲
338320.348*共19兲
HCOOH unidentified HCOOH c⫺C3 H2 CH2 CHCN HCOOH CH2 CHCN SO2 34
15共4,12兲⫺14共4,11兲 15共3,13兲⫺14共3,12兲 5共5,1兲⫺4共4,0兲 37共1,37兲⫺36共0,36兲 15共4,11兲⫺14共4,10兲 35共2,33兲⫺34共2,32兲 18共4,14兲⫺18共3,15兲 13共2,12兲⫺12共1,11兲
338355.823*共16兲 338396.331*共16兲 338404.593*共9兲
SO2 CH3 OCHO CH3 OH CH3 OCHO CH3 OCHO CH3 OH
7共⫺1,7兲⫺6共⫺1,6兲 E 27共8,19兲⫺26共8,18兲 A 27共7,21兲⫺26共7,20兲 E 7共6,2兲⫺6共6,1兲 E
338408.718*共7兲
CH3 OH
7共0,7兲⫺6共0,6兲 A⫹
338414.117*共16兲 338430.981*共10兲 338442.367*共11兲
CH3 OCHO CH3 OH CH3 OH
27共7,21兲⫺26共7,20兲 A 7共⫺6,1兲⫺6共⫺6,0兲 E 7共6,1兲⫺6共6,0兲 A⫹
338442.367*共11兲
CH3 OH
7共6,2兲⫺6共6,1兲 A⫺ 19⫺18
338338.014*共16兲 338344.605*共7兲
338447.318*共36兲
29
27共8,19兲⫺26共8,18兲 E
3.1b 1.0 0.67 0.7 5.3f 0.9 1.4 1.0b 3.42 16.4f 4.6 4.23 4.6 3.7 4.52b
Sut95
Sut95
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Oes99
OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1
NRAO 12 m JCMT 15 m JCMT 15 m NRAO 12 m
Jew89 Sut95 Sut95 Jew89
Xu_97 Oes99 Oes99 Xu_97
b
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
1.2 0.80
OriMC⫺1 OriMC⫺1 OriMC⫺1
MMWO 4.9 m NRAO 12 m NRAO 12 m
Lor85 Jew89 Jew89
Oes99 Xu_97 Xu_97
b
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
13.5f
IRC⫹10216
CSO 10.4 m
Gro94
1.08b
SiS CH2 CHCN
37共0,37兲⫺36共0,36兲
2.0b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
338475.217*共8兲 338486.322*共8兲
CH3 OH CH3 OH CH3 OH
7共⫺5,2兲⫺6共⫺5,1兲 E 7共5,3兲⫺6共5,2兲 E 7共5,2兲⫺6共5,1兲 A⫺
1.72 1.80 2.12b
OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m NRAO 12 m
Jew89 Jew89 Jew89
Xu_97 Xu_97 Xu_97
338486.322*共8兲
CH3 OH
7共5,3兲⫺6共5,2兲 A⫹
b
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
338504.056*共7兲
7共⫺4,4兲⫺6共⫺4,3兲 E 7共4,4兲⫺6共4,3兲 A⫺
3.05
338512.627*共7兲
CH3 OH CH3 OH
4.13b
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
Xu_97 Xu_97
338512.639*共7兲
CH3 OH
7共4,3兲⫺6共4,2兲 A⫹
b
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
338512.856*共7兲
CH3 OH
7共2,6兲⫺6共2,5兲 A⫺
b
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
338530.256*共7兲 338540.824*共7兲
CH3 OH CH3 OH
7共4,3兲⫺6共4,2兲 E 7共3,5兲⫺6共3,4兲 A⫹
1.98 4.75b
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
Xu_97 Xu_97
338543.149*共7兲
CH3 OH
7共3,4兲⫺6共3,3兲 A⫺
b
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
338559.963*共7兲 338583.223*共7兲 338611.816*共12兲 338614.953*共7兲
7共⫺3,5兲⫺6共⫺3,4兲 E 7共3,4兲⫺6共3,3兲 E 20共4,19兲⫺19共2,18兲
3.05 4.05 0.73
OriMC⫺1 OriMC⫺1 IRAS16293⫺2422
NRAO 12 m NRAO 12 m JCMT 15 m
Jew89 Jew89 Bla94
Xu_97 Xu_97
338639.807*共7兲 338708.8 338721.694*共7兲
CH3 OH CH3 OH SO2 CH3 OH CH3 OH unidentified CH3 OH
7共1,6兲⫺6共1,5兲 E 7共2,5兲⫺6共2,4兲 A⫹
7.75 3.82 0.6 5.08b
NRAO 12 m NRAO 12 m JCMT 15 m NRAO 12 m
Jew89 Jew89 Mac96 Jew89
Xu_97 Xu_97
7共2,5兲⫺6共2,4兲 E
OriMC⫺1 OriMC⫺1 G34.3⫹0.15 OriMC⫺1
Xu_97
338722.914*共5兲
CH3 OH
7共⫺2,6兲⫺6共⫺2,5兲 E
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
0.7
G34.3⫹0.15
JCMT 15 m
Mac96
13共0,13兲⫺12共1,12兲 A⫹
1.3 3.2
G34.3⫹0.15 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Mac96 Sut95
14共4,10兲⫺14共3,11兲
0.8 2.8 0.53
G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1
JCMT 15 m JCMT 15 m NRAO 12 m
Mac96 Sut95 Jew89
0.1b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
IRC⫹10216
CSO 10.4 m
Gro94
1.3b
G34.3⫹0.15 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Mac96 Sut95
b
338447.690*共8兲 338456.521*共7兲
U
338747.0
unidentified
U
338759.8 338759.948*共50兲
unidentified
338771.4 338773.0 338785.692*共17兲
13
CH3 OH unidentified unidentified 34
SO2
338788.813*共19兲
CH3 CH2 CN
U
338821.
unidentified
U
338843.4 338886.171*共26兲
t⫺CH3 CH2 OH
15共7,8兲⫺15共6,9兲
338887.356*共26兲
39共1,38兲⫺38共2,37兲
t⫺CH3 CH2 OH
15共7,9兲⫺15共6,10兲
30
SiO
b
33f
unidentified
338929.56*共18兲
U
Lab. Ref.
t⫺CH3 CH2 OH CH3 OH CH3 CH2 CN
338305.976*共15兲
U U
T r 共K兲/T a 共K兲
338099.107*共35兲
338213.505*共8兲 338248.7*共兲 338278.149*共7兲
U
Quantum numbers
338109.733*共35兲 338124.498*共7兲 338142.834*共18兲 U
Formula
0.8
OriMC⫺1共CR兲
JCMT 15 m
Sut95
8⫺7 v⫽0
1.07
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
339061.026*共25兲
t⫺CH3 CH2 OH
14共7,7兲⫺14共6,8兲
0.6b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
339061.537*共25兲
t⫺CH3 CH2 OH CH3 OCHO unidentified SO2 CH3 OCHO CH3 OCHO CH3 OCHO
14共7,8兲⫺14共6,9兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
1.1 1.4 0.09
OriMC⫺1共CR兲 OriMC⫺1共CR兲 W3共IRS5兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Hel97
Oes99
1.5 1.5 1.0
JCMT JCMT JCMT JCMT
m m m m
Sut95 Sut95 Sut95 Sut95
Oes99 Oes99 Oes99
0.8b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
2.7
OriMC⫺1共CR兲
JCMT 15 m
Sut95
339129.374*共25兲 339137.1 339149.160*共33兲 339152.730*共28兲 339185.942*共25兲 339196.327*共25兲 339201.539*共26兲 339201.745*共26兲 339309.002*共14兲
13共7,7兲⫺12共6,7兲 E 37共4,34兲⫺38共1,37兲
t⫺CH3 CH2 OH
13共7,6兲⫺12共6,6兲 E 13共7,7兲⫺12共6,7兲 A 13共7,6兲⫺12共6,6兲 A 13共7,6兲⫺13共6,7兲
t⫺CH3 CH2 OH
13共7,7兲⫺13共6,8兲
13
CH3 CN
19共3兲⫺18共3兲
15 15 15 15
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
308
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
339312.559*共27兲
t⫺CH3 CH2 OH
12共7,5兲⫺12共6,6兲
2.4b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
339312.635*共27兲
t⫺CH3 CH2 OH
12共7,6兲⫺12共6,7兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
19共2兲⫺18共2兲
1.4
OriMC⫺1共CR兲
JCMT 15 m
Sut95
3共3兲⫺3共2兲 28⫺27
1.90 0.6
OriMC⫺1 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m
Jew89 Sut95 Sut95
339340.824*共15兲 339341.502*共62兲 339353.782*共35兲
CH3 CN SO
O13CS
339359.923*共17兲
13
19共1兲⫺18共1兲
1.4
OriMC⫺1共CR兲
JCMT 15 m
339366.290*共17兲
13
19共0兲⫺18共0兲
1.6
OriMC⫺1共CR兲
JCMT 15 m
Sut95
1.0b
OriMC⫺1共CR兲
JCMT 15 m
Sut95 Sut95
CH3 CN CH3 CN
339398.498*共29兲
t⫺CH3 CH2 OH
11共7,4兲⫺11共6,5兲
339398.524*共29兲
t⫺CH3 CH2 OH
11共7,5兲⫺11共6,6兲
339446.779*共30兲
CN
339459.994*共30兲
b
OriMC⫺1共CR兲
JCMT 15 m
3⫺2 J⫽5/2⫺5/2 F⫽3/2⫺3/2
0.6
OriMC⫺1共ER兲
JCMT 15 m
Sut95
CN
3⫺2 J⫽5/2⫺5/2 F⫽3/2⫺5/2
0.2b
OriMC⫺1共ER兲
JCMT 15 m
Sut95
339462.679*共30兲
CN
OriMC⫺1共ER兲
JCMT 15 m
Sut95
t⫺CH3 CH2 OH
3⫺2 J⫽5/2⫺5/2 F⫽5/2⫺3/2 10共7,3兲⫺10共6,4兲
b
339463.379*共31兲
0.5b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
339463.387*共31兲
t⫺CH3 CH2 OH
10共7,4兲⫺10共6,5兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
339475.894*共30兲
CN
1.3
OriMC⫺1共ER兲
JCMT 15 m
Sut95
339491.485*共8兲
CH3 OCH3
3⫺2 J⫽5/2⫺5/2 F⫽5/2⫺5/2 19共1,18兲⫺18共2,17兲 AA
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Gro98
339491.549*共6兲
CH3 OCH3
19共1,18兲⫺18共2,17兲 EE
8.5b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Gro98
339491.613*共4兲
CH3 OCH3
19共1,18兲⫺18共2,17兲 AE⫹EA
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Gro98
339493.281*共30兲
CN
3⫺2 J⫽5/2⫺5/2 F⫽5/2⫺7/2
0.3
OriMC⫺1共ER兲
JCMT 15 m
Sut95
339499.303*共30兲
CN
OriMC⫺1共ER兲
JCMT 15 m
Sut95
t⫺CH3 CH2 OH
3⫺2 J⫽5/2⫺5/2 F⫽7/2⫺5/2 9共7,2兲⫺9共6,3兲
0.3
339510.854*共34兲
0.5b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
339510.856*共34兲
t⫺CH3 CH2 OH CN
Sut95
339516.690*共30兲 339544.224*共37兲
t⫺CH3 CH2 OH
3⫺2 J⫽5/2⫺5/2 F⫽7/2⫺7/2 8共7,1兲⫺8共6,2兲
339544.225*共37兲
t⫺CH3 CH2 OH
339566.451*共41兲
t⫺CH3 CH2 OH NH2 CHO NH2 CHO NH2 CHO 34 SO CH3 CH2 CN
9共8兲⫺8共7兲
339894.686*共20兲
39共2,38兲⫺38共2,37兲
339902.430*共19兲
NH2 CHO
16共6,11兲⫺15共6,10兲
0.60b
339902.509*共19兲
NH2 CHO
16共6,10兲⫺15共6,9兲
339910.922*共43兲
33
19⫺18 v⫽0
3.0f
339968.188*共19兲
Si S CH3 CH2 CN
38共2,36兲⫺37共2,35兲
339978.945*共26兲
t⫺CH3 CH2 OH
9共4,6兲⫺8共3,5兲
3.7b 2.6
339978.945*共26兲
t⫺CH3 CH2 OH CN
9共4,6兲⫺8共3,5兲
2.6
339686.037*共30兲 339715.156*共25兲 339779.493*共22兲 339857.266*共38兲
339992.258*共50兲
9共7,3兲⫺9共6,4兲
b
OriMC⫺1共CR兲
JCMT 15 m
2.4
OriMC⫺1共ER兲
JCMT 15 m
Sut95
1.4b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
8共7,2兲⫺8共6,3兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
7共7,*兲⫺7共6,*兲
0.4
OriMC⫺1共CR兲
JCMT 15 m
Sut95
16共9,*兲⫺15共9,*兲 16共8,*兲⫺15共8,*兲 16共7,*兲⫺15共7,*兲
1.0 1.0 1.1
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
3.29
OriMC⫺1
NRAO 12 m
Jew89
2.7b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
OriMC⫺1
NRAO 12 m
Jew89
OriMC⫺1
NRAO 12 m
Jew89
IRC⫹10216
CSO 10.4 m
Gro94
OriMC⫺1共CR兲
JCMT 15 m
Sut95
OriMC⫺1共CR兲
JCMT 15 m
Sut95
OriMC⫺1共CR兲
JCMT 15 m
Sut95
W3共H2O兲
JCMT 15 m
Hel97
b
340008.097 共50兲
CN
3⫺2 J⫽5/2⫺3/2 F⫽5/2⫺5/2
2.23b n.r.
Sgr B2共M兲
CSO 10.4 m
Sut91
Ska83
340019.605 共50兲
CN
3⫺2 J⫽5/2⫺3/2 F⫽3/2⫺3/2
n.r.
Sgr B2共M兲
CSO 10.4 m
Sut91
Ska83
340031.567*共40兲
CN
3⫺2 J⫽5/2⫺3/2 F⫽7/2⫺5/2
1.6b
OriMC⫺1
MMWO 4.9 m
Lor85
Ska83
340035.281*共50兲
CN
3⫺2 J⫽5/2⫺3/2 F⫽3/2⫺1/2
b
OriMC⫺1
MMWO 4.9 m
Lor85
Ska83
340035.525*共50兲
CN
b
OriMC⫺1
MMWO 4.9 m
Lor85
Ska83
340047.924*共7兲
CH2 CHCN
3⫺2 J⫽5/2⫺3/2 F⫽5/2⫺3/2 36共1,35兲⫺35共1,34兲
OriMC⫺1共CR兲
JCMT 15 m
Sut95
340052.600*共18兲
C33S CH2 CHCN unidentified NH2 CHO NH2 CHO CH3 OH CH3 CH2 CN
IRAS16293⫺2422
CSO 10.4 m
Bla94
16共5,12兲⫺15共5,11兲 16共5,11兲⫺15共5,10兲 2共2,0_⫺3共1,3兲 A⫹ 39共1,38兲⫺38共1,37兲
3.9b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m
Sut95 Sut95 Sut95 Sut95 Jew89 Sut95
340151.218*共21兲
CH3 CH2 CN
35共3,33兲⫺34共2,32兲
0.3b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
340189.267*共26兲
t⫺CH3 CH2 OH
6共5,2兲⫺5共4,1兲
7.1bf
Sgr B2共M兲
CSO 10.4 m
Sut91
340189.420*共26兲
t⫺CH3 CH2 OH CH2 CO
b
Sgr B2共M兲
CSO 10.4 m
Sut91
17共1,17兲⫺16共1,16兲
7.1f 0.29
Sgr B2共M兲
CSO 10.4 m
Sut91
IRC⫹10216
JCMT 15 m
Ave94
OriMC⫺1共CR兲 OriMC⫺1
JCMT 15 m MMWO 4.9 m
Sut95 Lor85
Sut95 Ska83 Ska83
340058.548*共8兲 U
13
Lab. Ref.
340114.7 340133.036*共17兲 340137.638*共17兲 340141.288*共17兲 340149.089*共20兲
340192.54* 共29兲 340200.122*共9兲
3⫺2 J⫽5/2⫺3/2 F⫽3/2⫺5/2
7⫺6 31共2,30兲⫺30共1,29兲
6共5,1兲⫺5共4,2兲
4⫺3
15
1.1b 0.38 1.4 2.2 1.1 1.1 1.47
Xu_97
340229.0*共 兲 340247.625*共50兲
HC N HCOOH CN
15共3,12兲⫺14共3,11兲
1.7
3⫺2 J⫽7/2⫺5/2 F⫽7/2⫺5/2
3.1b
340247.874*共50兲
CN
3⫺2 J⫽7/2⫺5/2 F⫽9/2⫺7/2
b
OriMC⫺1
MMWO 4.9 m
Lor85
340248.573*共50兲
CN
3⫺2 J⫽7/2⫺5/2 F⫽5/2⫺3/2
b
OriMC⫺1
MMWO 4.9 m
Lor85
Ska83
340261.818 共50兲
CN
3⫺2 J⫽7/2⫺7/2 F⫽5/2⫺5/2
n.r.
Sgr B2共M兲
CSO 10.4 m
Sut91
Ska83
340265.025 共50兲
CN
Sgr B2共M兲
CSO 10.4 m
Sut91
Ska83
SO2
3⫺2 J⫽7/2⫺7/2 F⫽7/2⫺7/2 28共2,26兲⫺28共1,27兲
n.r.
340316.416*共18兲
1.07
OriMC⫺1
NRAO 12 m
Jew89
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
309
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
340353.85* 共25兲 340393.660*共40兲
CH2 NH CH3 OH
3共1,3兲⫺2共0,2兲 16共6,10兲⫺17共5,13兲 A⫹⫹
n.r.
Sgr B2共M兲 OriMC⫺1共CR兲
CSO 10.4 m JCMT 15 m
Sut91 Sut95
Xu_97
340393.660*共40兲
CH3 OH
16共6,11兲⫺17共5,12兲 A⫺⫺
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Xu_97
340398.042*共39兲 340420.397*共26兲
CS
7⫺6 v⫽1 9共4,5兲⫺8共3,6兲
7.0b 0.18 1.4
IRAS16293⫺2422 OriMC⫺1共CR兲
CSO 10.4 m JCMT 15 m
Bla94 Sut95
2.5 0.4 2.0 2.23 1.8 0.08 2.9
OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲 IRC⫹10216 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m NRAO 12 m JCMT 15 m
Sut95 Mac96 Sut95 Jew89 Sut95 Hig00 Sut95
0.72 2.7 1.0
OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m JCMT 15 m JCMT 15 m
Jew89 Sut95 Sut95 Sut95
OriMC⫺1共CR兲
JCMT 15 m
Sut95
JCMT 15 m JCMT 15 m
Sut95 Sut95
Gro98
340432.606*共22兲 340436.9 340440.034*共22兲 340449.267*共5兲 340452.120*共23兲 340463. 340483.114*共21兲 340489.609*共16兲
t⫺CH3 CH2 OH CH3 CH2 CN unidentified CH3 CH2 CN OCS CH3 CH2 CN unidentified CH3 CH2 CN NH2 CHO
340492.935*共23兲 340534.378*共16兲 340534.544*共6兲
CH3 CH2 CN NH2 CHO CH2 CHCN
340551.252*共23兲 340575.950*共21兲
38共9,*兲⫺37共9,*兲 10共3,7兲⫺9共2,8兲 AE
2.5
340609.234*共8兲
CH3 CH2 CN CH3 CH2 CN CH3 OCH3
b
OriMC⫺1共CR兲 OriMC⫺1共CR兲
340609.311*共8兲
CH3 OCH3
10共3,7兲⫺9共2,8兲 EA
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Gro98
340612.609*共6兲 340615.944*共8兲
CH3 OCH3 CH3 OCH3
10共3,7兲⫺9共2,8兲 EE
0.79
OriMC⫺1
NRAO 12 m
Jew89
Gro98
0.79
NRAO 12 m CSO 10.4 m
Jew89 Sut91
340683.989*共16兲 340690.738*共16兲 340714.350*共17兲 340741.966*共17兲 340742.711*共20兲
HC18O⫹ CH3 OH NH2 CHO SO CH3 OCHO CH3 CH2 CN
OriMC⫺1 Sgr B2共M兲
Gro98
340630.71* 共60兲
10共3,7兲⫺9共2,8兲 AA 4⫺3
JCMT 15 m JCMT 15 m MMWO 4.9 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Lor85 Sut95 Sut95
Xu_97
3.0b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲
340743.063*共20兲
CH3 CH2 CN
38共8,30兲⫺37共8,29兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
340754.702*共17兲
CH3 OCHO
28共5,24兲⫺27共5,23兲 A 8共8兲⫺7共7兲
4.0 5.8
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
38共4,35兲⫺37共4,34兲
0.91 1.6 1.9
OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m JCMT 15 m
Jew89 Sut95 Sut95
2.0 2.3 0.43 4.1
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m
Sut95 Sut95 Jew89 Sut95
0.7 0.5 0.4 0.5 0.06 1.0
G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15 IRC⫹10216 OriMC⫺1共CR兲 Sgr B2共M兲
JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m CSO 10.4 m
Mac96 Mac96 Mac96 Mac96 Ave94 Sut95 Sut91
340838.645*共20兲 U U
340843. 340918.8 340972.693*共19兲 341025.581*共20兲 U341037.0 U341039. 341131.665*共50兲
U U U U
341132.3 341173.3 341236.1 341242.607*共50兲 341252. 341254.961*共20兲 341275.467*共16兲 341350.204*共25兲 341403.084*共34兲 341410.213*共20兲 341415.641*共7兲
U U
b
33
SO unidentified unidentified CH3 CH2 CN CH3 CH2 CN
38共12,*兲⫺37共12,*兲 38共11,*兲⫺37共11,*兲 28⫺27 38共13,*兲⫺37共13,*兲 38共10,*兲⫺37共10,*兲 16共3,14兲⫺15共3,13兲 38共14,*兲⫺37共14,*兲 16共4,13兲⫺15共4,12兲 17共2,15兲⫺16共1,16兲 38共15,*兲⫺37共15,*兲
11共1,11兲⫺10共0,10兲 E vt ⫽1 16共4,12兲⫺15共4,11兲 7共8兲⫺6共7兲 28共5,24兲⫺27共5,23兲 E 38共8,31兲⫺37共8,30兲
38共7,32兲⫺37共7,31兲
unidentified unidentified 13 CH3 OH unidentified unidentified unidentified HCO unidentified CH3 CH2 CN SO2
HCS
⫹
SO2 CH3 OCHO CH3 OH CH3 OCHO
13共1,12兲⫺13共0,13兲 A⫺⫹
11共0,11兲⫺10共1,10兲 39共2,38兲⫺38共1,37兲 21共8,14兲⫺22共7,15兲
0.2b 0.8
4.9f 8.0 1.6 2.7 4.0
11.9f
Bla84a
0.23
IRAS16293⫺2422
CSO 10.4 m
Bla94
1.6 0.6
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
Oes99
7共1,6兲⫺6共1,5兲 A⫺ 29共3,26兲⫺28共4,25兲 A
2.93 0.6
OriMC⫺1 OriMC⫺1共CR兲
NRAO 12 m JCMT 15 m
Jew89 Sut95
Xu_97 Oes99
IRC⫹10216 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT JCMT JCMT JCMT JCMT
m m m m m
Ave94 Mac96 Sut95 Sut95 Sut95
38共6,33兲⫺37共6,32兲 36共3,34兲⫺35共3,33兲 38共6,32兲⫺37共6,31兲
0.05 0.4 1.9 1.4 2.3
36共5,31兲⫺36共4,32兲
12.5f
Sgr B2共M兲
CSO 10.4 m
Sut91
341678.455*共30兲
CH3 CH2 CN
40共0,40兲⫺39共1,39兲
OriMC⫺1共CR兲
JCMT 15 m
Sut95
341682.468*共7兲 341703.758*共36兲
CH3 CCH CH3 CH2 CN CH3 CH2 CN
20共3兲⫺19共3兲
1.4b 1.5
OriMC⫺1共ER兲
JCMT 15 m
Sut95
3.6
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
OriMC⫺1共ER兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
OriMC⫺1共ER兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
3.7b
OriMC⫺1共ER兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
0.9 1.3
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
40共1,40兲⫺39共1,39兲 40共0,40兲⫺39共0,39兲 20共2兲⫺19共2兲 29共4,26兲⫺28共4,25兲 E 29共4,26兲⫺28共4,25兲 A
341735.881*共36兲
CH3 CCH CH3 OCHO CH3 OCHO CH3 CCH CH3 CH2 CN
341741.021*共7兲 341852.665*共19兲
CH3 CCH CH3 CH2 CN
20共0兲⫺19共0兲 38共5,34兲⫺37共5,33兲
341862.518*共29兲
CH3 OCHO CH3 OCHO
27共5,23兲⫺26共4,22兲 A 27共5,23兲⫺26共4,22兲 E
341870.166*共28兲
Xu_97
40共4,36兲⫺40共3,37兲 29共3,26兲⫺28共4,25兲 E
unidentified unidentified CH3 CH2 CN CH2 CHCN CH3 CH2 CN SO2
341710.690*共36兲
Oes99
8⫺7
341421.312*共20兲 341425. 341467.1 341468.680*共19兲 341563.758*共7兲 341603.214*共19兲 341673.947*共46兲
341714.993*共7兲 341722.194*共20兲 341732.276*共20兲 341734.513*共7兲
Oes99
20共1兲⫺19共1兲 40共1,40兲⫺39共0,39兲
3.1b 1.7 4.8 2.5 2.6 0.4b 2.8
15 15 15 15 15
Oes99 Oes99
Oes99 Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
310
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
341882.010*共8兲
CH2 CHCN
36共8,28兲⫺35共8,27兲
1.6b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
341882.012*共8兲
CH2 CHCN
36共8,29兲⫺35共8,28兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
341894.224*共8兲
CH2 CHCN CH3 OCHO CH2 CHCN
36共9,*兲⫺35共9,*兲 29共3,26兲⫺28共3,25兲 E 36共7,30兲⫺35共7,29兲
1.3 3.1 4.1b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
341917.909*共20兲 341924.241*共7兲 341924.300*共7兲
CH2 CHCN
36共7,29兲⫺35共7,28兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
341927.201*共18兲
CH3 CH2 CN
20共4,16兲⫺19共3,17兲
OriMC⫺1共CR兲
JCMT 15 m
Sut95
341927.482*共20兲 341944.154*共8兲 342052.935*共7兲
CH3 OCHO CH2 CHCN CH2 CHCN
29共3,26兲⫺28共3,25兲 A 36共10,*兲⫺35共10,*兲 36共6,31兲⫺35共6,30兲
0.3b 1.7 1.0 1.4b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95
342055.212*共7兲
CH2 CHCN
36共6,30兲⫺35共6,29兲
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
34
5共3,3兲⫺4共2,2兲
17.1f
SgrB2共M兲
CSO10.4 m
Sut91
29共4,26兲⫺28共3,25兲 E 20共1,19兲⫺19共2,18兲
0.6
34
342208.848*共12兲 342229.890*共20兲 342231.652*共18兲 U U
Formula
342238.446*共20兲 342288.7 342290.6 342317.552*共7兲 342332.016*共13兲
SO2 CH3 OCHO SO2 CH3 OCHO unidentified unidentified CH2 CHCN 34
Lab. Ref.
Oes99
Oes99
OriMC⫺1共CR兲 SgrB2共M兲
JCMT 15 m CSO 10.4 m
Sut95 Sut91
Oes99
OriMC⫺1共CR兲 OriMC⫺1共CR兲 G34.3⫹0.15 OriMC⫺1共CR兲 OriMC⫺1
JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m
Sut95 Sut95 Mac96 Sut95 Jew89
Oes99
36共5,32兲⫺35共5,31兲 12共4,8兲⫺12共3,9兲
10.3f 0.6 2.3 0.4 2.2 0.83
30共2,28兲⫺29共3,27兲 E 30共2,28兲⫺29共3,27兲 A
1.3 0.4
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
Oes99 Oes99
30共3,28兲⫺29共3,27兲 E 30共2,28兲⫺29共2,27兲 E
1.9 6.4b
OriMC⫺1共CR兲 OriMC⫺1共CR兲
JCMT 15 m JCMT 15 m
Sut95 Sut95
Oes99 Oes99
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Oes99
3.3 0.6 1.1 0.5 0.6 0.48 3.1e 2.3 1.6 1.1 0.27 2.0
JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Sut95 Sut95 Sut95 Jew89 Gra99 Sut95 Sut95 Sut95 Tur90a Sut95 Sut95
Oes99 Oes99
3.1b
OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 VYCMa OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1共CR兲 OriMC⫺1 OriMC⫺1共CR兲 OriMC⫺1共CR兲
Oes99 Oes99
b
OriMC⫺1共CR兲
JCMT 15 m
Sut95
Oes99
0.8
OriMC⫺1共CR兲 OriMC⫺1
JCMT 15 m NRAO 12 m
Sut95 Jew89
Gro98
29共4,26兲⫺28共3,25兲 A
342358.279*共20兲
SO2 CH3 OCHO CH3 OCHO CH3 OCHO CH3 OCHO
342359.441*共21兲
CH3 OCHO
30共3,28兲⫺29共3,27兲 A
342366.269*共21兲 342367.679*共20兲 342375.562*共7兲 342375.627*共21兲 342433.950*共30兲 342435.928*共39兲 342504.35* 共19兲 342506.772*共28兲 342511.025*共18兲 342521.2*共 兲 342522.150*共21兲 342525.278*共32兲 342572.398*共28兲
CH3 OCHO CH3 OCHO CH2 CHCN CH3 OCHO CH3 CH2 CN SO2 SiO CH3 OCHO NH2 CHO HCOOH D2 CO CH3 OCHO CH3 OCHO
30共2,28兲⫺29共2,27兲 A 30共3,28兲⫺29共2,27兲 E 36共5,31兲⫺35共5,30兲 30共3,28兲⫺29共2,27兲 A 40共2,38兲⫺39共3,37兲 23共3,21兲⫺23共2,22兲 v2 ⫽1 8⫺7 v⫽2 11共8,4兲⫺10共7,4兲 E 18共3,16兲⫺18共2,17兲 16共1,16兲⫺15共1,15兲 6共0,6兲⫺5共0,5兲 11共8,3兲⫺10共7,3兲 E 11共8,4兲⫺10共7,3兲 A
342572.412*共28兲
CH3 OCHO
11共8,3兲⫺10共7,4兲 A
342585.469*共7兲 342607.916*共6兲
CH2 CHCN CH3 OCH3
36共4,33兲⫺35共4,32兲 19共0,19兲⫺18共1,18兲 AE⫹EA
342607.987*共6兲
CH3 OCH3
19共0,19兲⫺18共1,18兲 EE
1.13b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
342608.058*共6兲
CH3 OCH3
19共0,19兲⫺18共1,18兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
342651.908*共20兲 342677.583*共20兲 342692.894*共28兲
CH3 CH2 CN CH3 CH2 CN CH3 OCHO
15共5,11兲⫺14共4,10兲 15共5,10兲⫺14共4,11兲 27共13,14兲⫺27共12,15兲 A
1.0 1.3
OriMC⫺1共CR兲 OriMC⫺1共CR兲 G34.3⫹0.15
JCMT 15 m JCMT 15 m JCMT 15 m
Sut95 Sut95 Mac96
Oes99
342692.913*共28兲
CH3 OCHO
27共13,15兲⫺27共12,16兲 A
0.6b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
342729.781*共28兲
CH3 OH
13共1,12兲⫺13共0,13兲 A⫺⫹
OriMC⫺1
NRAO 12 m
Jew89
Xu_97
U U
342731. 342754.0 342761.646*共26兲
unidentified unidentified SO2
4.83b 0.33 1.9
34共3,31兲⫺34共2,32兲
CSO 10.4 m JCMT 15 m CSO 10.4 m
Bla94 Sut95 Sut91
U
342778. 342804.95*共25兲
unidentified SiC2
6.7f 0.4
IRAS16293⫺2422 OriMC⫺1共CR兲 SgrB2共M兲
15共2,14兲⫺14共2,13兲
IRC⫹10216 IRC⫹10216
JCMT 15 m CSO 10.4 m
Ave94 Gro94
342882.866*共16兲 342944.55*共88兲 342980.64* 共18兲
CS H2 CS
7⫺6 10共0,10兲⫺9共0,9兲
26.3f 9.65 0.22
OriMC⫺1 IRAS16293⫺2422
NRAO 12 m CSO 10.4 m
Jew89 Bla94
29 SiO unidentified unidentified NH2 CHO
8⫺7 v⫽0
0.18
IRAS16293⫺2422
CSO 10.4 m
Bla94
16共3,13兲⫺15共3,12兲
0.17 0.20 1.01
IRAS16293⫺2422 IRAS16293⫺2422 OriMC⫺1
CSO 10.4 m CSO 10.4 m NRAO 12 m
Bla94 Bla94 Jew89
9共8兲⫺8共7兲
0.66
W3共IRS5兲
JCMT 15 m
Hel97
19⫺18 v⫽1
0.18 5.1f 0.20
CSO 10.4 m CSO 10.4 m JCMT 15 m JCMT 15 m
Bla94 Gro94 Ave94 Mac96
Oes99
342342.025*共20兲 342350.082*共21兲 342351.425*共20兲
U U
343003. 343058. 343083.099*共16兲 343086.847*共24兲
U U
33
b
b
Oes99
Oes99 Sut95
343087. 343101.001*共24兲 343105. 343147.921*共24兲
SO unidentified SiS unidentified CH3 OCHO
31共1,30兲⫺30共2,29兲 E
b
IRAS16293⫺2422 IRC⫹10216 IRC⫹10216 G34.3⫹0.15
343148.071*共24兲
CH3 OCHO
31共2,30兲⫺30共2,29兲 E
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
343148.192*共24兲
CH3 OCHO
31共1,30兲⫺30共1,29兲 E
1.0b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
343148.341*共24兲
CH3 OCHO
31共2,30兲⫺30共1,29兲 E
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
343152.922*共25兲
CH3 OCHO
31共1,30兲⫺30共2,29兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
311
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
Source
Telescope
Astr. Ref.
Lab. Ref.
CH3 OCHO
31共2,30兲⫺30共2,29兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
CH3 OCHO
31共1,30兲⫺30共1,29兲 A
0.9b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
343153.340*共25兲
CH3 OCHO
31共2,30兲⫺30共1,29兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
343196.972*共17兲 343201.05* 共55兲 343207.58* 共63兲 343313.6 343319.83* 共81兲 343325.672*共16兲
NH2 CHO H2 CS H2 CS unidentified H2 CS
17共1,17兲⫺16共1,16兲 10共5,*兲⫺9共5,*兲 10共4,*兲⫺9共4,*兲
G34.3⫹0.15 OriMC⫺1 G34.3⫹0.15 G34.3⫹0.15 IRAS16293⫺2422 OriMC⫺1
JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m CSO 10.4 m NRAO 12 m
Mac96 Jew89 Mac96 Mac96 Bla94 Jew89
10共2,9兲⫺9共2,8兲 5共1,5兲⫺4共1,4兲
343384.718*共49兲
H2 13CO CH2 CO
0.4 0.98 0.7 0.5 0.25 1.32
17共3,15兲⫺16共3,14兲
0.5b
G34.3⫹0.15
JCMT 15 m
Mac96
343387.610*共53兲
CH2 CO
17共3,14兲⫺16共3,13兲
b
G34.3⫹0.15
JCMT 15 m
Mac96
343407.73* 共73兲 343411.9*共7兲 343411.92* 共73兲 343435.239*共20兲
10共3,8兲⫺9共3,7兲 10共3,7兲⫺9共3,6兲 10共3,7兲⫺9共3,6兲
0.15 0.83 0.98
IRAS16293⫺2422 W3共H2O兲 OriMC⫺1
CSO 10.4 m JCMT 15 m NRAO 12 m
Bla94 Hel97 Jew89
343443.930*共20兲 343693.913*共98兲 343753.325*共8兲
H2 CS H2 CS H2 CS CH3 OCHO CH3 OCHO CH2 CO CH3 OCH3
28共4,24兲⫺27共4,23兲 E 28共4,24兲⫺27共4,23兲 A 17共2,15兲⫺16共2,14兲 17共2,16兲⫺16共1,15兲 AE⫹EA
1.13 0.95 0.4
W3共H2O兲 OriMC⫺1 G34.3⫹0.15 OriMC⫺1
JCMT 15 m NRAO 12 m JCMT 15 m NRAO 12 m
Hel97 Jew89 Mac96 Jew89
Gro98
343754.222*共6兲
CH3 OCH3
17共2,16兲⫺16共1,15兲 EE
0.88b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
343755.118*共8兲
CH3 OCH3
17共2,16兲⫺16共1,15兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
343758.015*共20兲
CH3 OCHO
27共7,20兲⫺26共7,19兲 A
b
OriMC⫺1
NRAO 12 m
Jew89
Oes99
343810.89* 共81兲
H2 CS
343851.130*共51兲
34
SO SO2
10共2,8兲⫺9共2,7兲 2共3兲⫺2共1兲
0.68 0.4
OriMC⫺1 G34.3⫹0.15
NRAO 12 m JCMT 15 m
Jew89 Mac96
Mul01
24共2,22兲⫺23共3,21兲 v2 ⫽1
3.3f
SgrB2共M兲
CSO 10.4 m
Sut91
OC34S CH3 OCHO
0.6
G34.3⫹0.15
JCMT 15 m
Mac96
344029.286*共28兲
32共1,32兲⫺31共1,31兲 E
0.81b
OriMC⫺1
NRAO 12 m
Jew89
Oes99
344029.287*共28兲
CH3 OCHO
32共0,32兲⫺31共0,31兲 E
b
OriMC⫺1
NRAO 12 m
Jew89
Oes99
344029.580*共40兲
CH3 OCHO
32共1,32兲⫺31共1,31兲 A
b
OriMC⫺1
NRAO 12 m
Jew89
Oes99
344029.581*共40兲
CH3 OCHO
32共0,32兲⫺31共0,31兲 A
b
OriMC⫺1
NRAO 12 m
Jew89
Oes99
344109.132*共50兲 344200.122*共9兲
CH3 OH
18共2,16兲⫺17共3,14兲 E
0.9
G34.3⫹0.15
JCMT 15 m
Mac96
Xu_97
4⫺3
37.2f
SgrB2共M兲
CSO 10.4 m
Sut91
0.94
OriMC⫺1
NRAO 12 m
Jew89
0.6 10.93
G34.3⫹0.15 OriMC⫺1 OriMC⫺1
JCMT 15 m NRAO 12 m NRAO 12 m
Mac96 Jew89 Jew89
Gro98 Gro98
HC15N 34
SO2
29⫺28
10共4,6兲⫺10共3,7兲
b
Oes99 Oes99
344288.4 344310.792*共16兲 344357.832*共6兲
unidentified SO CH3 OCH3
8共8兲⫺7共7兲 19共1,19兲⫺18共0,18兲 AE⫹EA
344357.944*共6兲
CH3 OCH3
19共1,19兲⫺18共0,18兲 EE
1.30b
OriMC⫺1
NRAO 12 m
Jew89
344358.056*共6兲
CH3 OCH3
19共1,19兲⫺18共0,18兲 AA
b
OriMC⫺1
NRAO 12 m
Jew89
Gro98
344443.90* 共10兲 344512.169*共8兲
CH3 OH CH3 OCH3
19共1,19兲⫺18共2,16兲 A⫹⫹ 10共3,9兲⫺10共2,8兲 EA
b
G34.3⫹0.15 G34.3⫹0.15
JCMT 15 m JCMT 15 m
Mac96 Mac96
Xu_97 Gro98
344512.211*共8兲
CH3 OCH3
10共3,9兲⫺10共2,8兲 AE
b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
344515.377*共6兲
CH3 OCH3
10共3,9兲⫺10共2,8兲 EE
0.6b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
344515.418*共20兲
CH3 OCHO
28共16,*兲⫺28共16,*兲 A
0.9b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
344518.563*共10兲
CH3 OCH3
10共3,9兲⫺10共2,8兲 AA
b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
344541.313*共21兲
CH3 OCHO
28共16,13兲⫺27共16,12兲 E 19共1,19兲⫺18共0,18兲
W3共H2O兲 OriMC⫺1
JCMT 15 m NRAO 12 m
Hel97 Jew89
Oes99
344581.052*共21兲
34
344807.918*共14兲
34
344906.030*共34兲 344916.36*共17兲 344987.591*共18兲 344998.162*共12兲
SO2
SO2 SiC2 SiO
34
SO2
b
0.7
0.94 0.60
13共4,10兲⫺13共3,11兲
0.50
OriMC⫺1
NRAO 12 m
Jew89
16共0,16兲⫺15共0,15兲
IRC⫹10216
CSO 10.4 m
Gro94
8⫺7 v⫽1 15共4,12兲⫺15共3,13兲
27.1f 0.8 0.60
G34.3⫹0.15 OriMC⫺1
JCMT 15 m NRAO 12 m
Mac96 Jew89
11共4,8兲⫺11共3,9兲
0.60
OriMC⫺1
NRAO 12 m
Jew89
345069.042*共20兲
CH3 OCHO
28共14,14兲⫺28共14,13兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
345128.186*共42兲
CH3 OCH3
35共2,33兲⫺35共1,34兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
345128.186*共42兲
CH3 OCH3
35共2,33兲⫺35共1,34兲 EA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
345130.999*共42兲
CH3 OCH3
35共2,33兲⫺35共1,34兲 EE
0.27b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
345133.811*共42兲
CH3 OCH3
35共2,33兲⫺35共1,34兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
345148.959*共10兲
SO2
5共5,1兲⫺6共4,2兲
7.0f
SgrB2共M兲
CSO 10.4 m
Sut91
345168.663*共10兲
34 SO2 NH2 CHO unidentified unidentified
345181.244*共17兲 345203.4 345226.6 345238.735*共20兲 345285.620*共10兲 U
T r 共K兲/T a 共K兲
343153.070*共25兲
344245.347*共11兲
U U
Quantum numbers
343153.191*共25兲
343923.802*共24兲 343983.267*共27兲
U
Formula
34
SO2
H13CN 34
SO2
8共4,4兲⫺8共3,5兲
8.7f
SgrB2共M兲
CSO 10.4 m
Sut91
17共0,17兲⫺16共0,16兲
0.6 0.5 0.6
4⫺3 v2 ⫽1, ᐉ⫽1 c
6.0f
G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15 IRC⫹10216
JCMT 15 m JCMT 15 m JCMT 15 m CSO 10.4 m
Mac96 Mac96 Mac96 Gro94
9共4,6兲⫺9共3,7兲
6.5f 0.6
SgrB2共M兲
CSO 10.4 m
Sut91
G34.3⫹0.15 OriMC⫺1
JCMT 15 m NRAO 12 m
Mac96 Jew89
OriMC⫺1
NRAO 12 m
Jew89
345291.6 345338.509*共12兲
unidentified SO2
13,共2,12兲⫺12共1,11兲
345339.771*共13兲
H13CN
4⫺3
7.71b b
Pre93
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
312
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
SO2
HCCCN
CSO 10.4 m
Sut91
JCMT 15 m
Mac96
Oes99
G34.3⫹0.15 W3共H2O兲 SgrB2共M兲
JCMT 15 m JCMT 15 m CSO 10.4 m
Mac96 Hel97 Sut91
Oes99 Oes99
G34.3⫹0.15 SgrB2共M兲
JCMT 15 m CSO 10.4 m
Mac96 Sut91
OriMC⫺1 SgrB2共M兲
NRAO12 m CSO 10.4 m
Jew89 Sut91
6共4,2兲⫺6共3,3兲
34
SO2
34
38⫺37 5共4,2兲⫺5共3,3兲
34
4共4,0兲⫺4共3,1兲
34
3⫺2 16共1,15兲⫺15共2,14兲 A⫺ 18共⫺3,16兲⫺17共⫺4,14兲 E 17共4,14兲⫺17共3,15兲
SO2
SO2 CO CH3 OH CH3 OH
346109.992*共68兲
SO2 SiC2
346202.766*共21兲 346204.318*共21兲 346218.2 346220.137共6兲
CH3 OH CH3 OH unidentified NS
346365.300*共56兲
SO2
⌸1/2 J⫽7/2⫺6/2 F⫽8/2⫺7/2 f 34共3,31兲⫺34共2,32兲 v2 ⫽1
346379.186*共24兲
SO2
19共1,19兲⫺18共0,18兲 v2 ⫽1
346508.7 346523.864*共13兲
unidentified SO2
16共4,12兲⫺16共3,13兲
346528.587*共20兲
SO
9共8兲⫺8共7兲
346591.783*共28兲
SO2
18共4,14兲⫺18共3,15兲 v2 ⫽1
346599.97*共29兲 346652.155*共14兲 346674.998*共17兲
CH2 CO SO2 CH3 OCHO
17共1,16兲⫺16共1,15兲 19共1,19兲⫺18共0,18兲 28共11,18兲⫺27共11,17兲 A
346675.661*共17兲
CH3 OCHO
28共11,17兲⫺27共11,16兲 A
346686.2 346725.172 共50兲 346998.54* 共40兲
unidentified HCO
347191. 347330.67*共18兲 347443.1
H13CO⫹ unidentified SiO CH3 OH ⫹
14共2,12兲⫺13共2,11兲 5共4,2兲⫺6共3,3兲 A⫺⫺ 5共4,1兲⫺6共3,4兲 A⫺⫺ 2
4共0,4兲⫺3共0,3兲 4⫺3 8⫺7 v⫽0 19共3兲⫺19共2兲 E vt ⫽2
0.5 0.19 6.0f 0.4 9.0f 1.95 35.0f
SgrB2共M兲
CSO 10.4 m
Sut91
OriMC⫺1 OriMC⫺1 G34.3⫹0.15 SgrB2共M兲
NRAO 12 m NRAO 12 m JCMT 15 m CSO 10.4 m
Jew89 Jew89 Mac96 Sut91
IRC⫹10216
CSO 10.4 m
Gro94
1.2b
G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15
JCMT JCMT JCMT JCMT
m m m m
Mac96 Mac96 Mac96 Mac96
8.6f
SgrB2共M兲
CSO 10.4 m
Sut91
35.0f 70.00 1.80 1.1 6.0f 26.6f 1.3 1.3 1.1
8.6f 0.3 8.73b b
23.1f 0.8 4.82 b
0.3b 0.7 0.7 1.03 0.72 6.81 0.37b 0.51
SO SO2
⌸1/2 J⫽15/2⫺13/2 e 13共2,12兲⫺12共1,11兲 v2 ⫽1
348100.194*共30兲 348117.481*共28兲
CH3 OH
11共0,11兲⫺10共1,9兲E
19.9f 0.4
19共4,16兲⫺19共3,17兲
348202.6 348262.00* 共22兲 348269. 348330.5 348340.49* 共10兲
unidentified HCOOD unidentified unidentified
347991.839*共17兲
U U
SgrB2共M兲 G34.3⫹0.15
28共13,*兲⫺27共13,*兲 A 28共13,16兲⫺27共13,15兲 E 7共4,4兲⫺7共3,5兲
34
345609.022*共23兲 345651.290*共11兲
347740.011 共20兲
U
7.1f 0.4
26共9,17兲⫺27共8,20兲 28共13,15兲⫺27共13,14兲 E
345795.990*共1兲 345903.965*共37兲 345919.191*共34兲 345929.294*共23兲
U
Telescope
SO2
345678.784*共11兲
U
Source
CH3 OCHO CH3 OCHO CH3 OCHO unidentified
34
SO2
348387.835*共13兲 348518.39* 共14兲 348532.18* 共86兲 348637.059*共8兲 348909.527*共20兲
HN13C SO2 HNO H2 CS CH2 CHCN CH3 OCHO
348911.426*共15兲 348915.019*共16兲
CH3 CN CH3 OCHO
349024.995*共12兲
Lab. Ref.
T r 共K兲/T a 共K兲
345449.068*共25兲
345544.4 345553.090*共10兲
Astr. Ref.
Quantum numbers
345461.052*共24兲 345466.990*共20兲 345486.661*共20兲 345519.655*共10兲 U
Formula
2
16共8,8兲⫺15共8,7兲
4⫺3
15 15 15 15
Xu_97 Xu_97
Xu_97 Xu_97 Lee95
SgrB2共M兲
CSO 10.4 m
Sut91
G34.3⫹0.15 OriMC⫺1
JCMT 15 m NRAO 12 m
Mac96 Jew89
OriMC⫺1
NRAO 12 m
Jew89
SgrB2共M兲
CSO 10.4 m
Sut91
G34.3⫹0.15 OriMC⫺1 G34.3⫹0.15
JCMT 15 m NRAO 12 m JCMT 15 m
Mac96 Jew89 Mac96
Oes99
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1
JCMT 15 m JCMT 15 m NRAO 12 m
Mac96 Mac96 Jew89
Bla84a
OriMC⫺1 OriMC⫺1 W3共H2O兲
NRAO 12 m NRAO 12 m JCMT 15 m
Jew89 Jew89 Hel97
Xu_97
W3共IRS5兲
JCMT 15 m
Hel97
Ama91
SgrB2共M兲
CSO 10.4 m
Sut91
G34.3⫹0.15
JCMT 15 m
Mac96
1.32
OriMC⫺1
NRAO 12 m
Jew89
0.3 0.5 0.97 0.5
G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1 G34.3⫹0.15 SgrB2共M兲
JCMT 15 m JCMT 15 m NRAO 12 m JCMT 15 m CSO10.4 m
Mac96 Mac96 Jew89 Mac96 Sut91
Xu_97
Wil80
24共2,22兲⫺23共3,21兲
33.9f 4.13
OriMC⫺1
NRAO 12 m
Jew89
1共1,1兲⫺2共0,2兲 10共1,9兲⫺9共1,8兲 38共1,38兲⫺37共1,37兲
0.6 3.38 0.6
G34.3⫹0.15 OriMC⫺1 G34.3⫹0.15
JCMT 15 m NRAO 12 m JCMT 15 m
Mac96 Jew89 Mac96
28共9,20兲⫺27共9,19兲 E
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
19共9兲⫺18共9兲 28共9,20兲⫺27共9,19兲 A
1.50
OriMC⫺1 G34.3⫹0.15
NRAO 12 m JCMT 15 m
Jew89 Mac96
Oes99
CH3 CN CH3 OH
19共8兲⫺18共8兲 14共1,13兲⫺14共0,14兲 A⫺⫹
1.03
NRAO 12 m NRAO 12 m
Jew89 Jew89
Xu_97
349125.310*共9兲 349212.331*共7兲 349286.022*共5兲 349337.741*共13兲
CH3 CN CH3 CN CH3 CN
19共7兲⫺18共7兲 19共6兲⫺18共6兲 19共5兲⫺18共5兲
3.52b 0.5 0.71 0.79
OriMC⫺1 OriMC⫺1 G34.3⫹0.15 OriMC⫺1 OriMC⫺1
JCMT 15 m NRAO 12 m NRAO 12 m
Mac96 Jew89 Jew89
C2 H
4⫺3 J⫽9/2⫺7/2 F⫽5⫺4
1.2b
M17
MMWO 4.9 m
Lor85
Mul00
349339.067*共16兲
C2 H
b
M17
MMWO 4.9 m
Lor85
Mul00
349346.356*共5兲 349393.307*共5兲
CH3 CN CH3 CN
4⫺3 J⫽9/2⫺7/2 F⫽4⫺3 19共4兲⫺18共4兲 19共3兲⫺18共3兲
1.27 3.38b
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
349399.342*共14兲
C2 H
4⫺3 J⫽7/2⫺5/2 F⫽4⫺3
1.0b
M17
MMWO 4.9 m
Lor85
Mul00
349400.692*共14兲
C2 H
4⫺3 J⫽7/2⫺5/2 F⫽3⫺2
b
M17
MMWO 4.9 m
Lor85
Mul00
349426.856*共5兲 349446.992*共5兲
CH3 CN CH3 CN
19共2兲⫺18共2兲 19共1兲⫺18共1兲
2.10b
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
349453.704*共5兲
CH3 CN
19共0兲⫺18共0兲
b
OriMC⫺1
NRAO 12 m
Jew89
349783.325*共45兲
SO2 CH3 OCH3
46共5,41兲⫺46共4,42兲 10共1,10兲⫺11共2,9兲 EA
W3共IRS5兲 G34.3⫹0.15
JCMT 15 m JCMT 15 m
Hel97 Mac96
349106.954*共31兲
349802.991*共10兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
0.7b
1.50
0.25 b
Gro98
MICROWAVE TRANSITIONS
313
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
Formula
Quantum numbers 10共1,10兲⫺11共2,9兲 AE
b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
10共1,10兲⫺11共2,9兲 EE
0.7b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
349809.338*共12兲
CH3 OCH3
10共1,10兲⫺11共2,9兲 AA
b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
349891.2 349995.4 350035.613*共69兲
unidentified unidentified
0.6 0.5
G34.3⫹0.15 G34.3⫹0.15 IRC⫹10216
JCMT 15 m JCMT 15 m CSO10.4m
Mac96 Mac96 Gro94
G34.3⫹0.15
JCMT 15 m
Mac96
Xu_97
OriMC⫺1 G34.3⫹0.15 IRC⫹10216
NRAO 12 m JCMT 15 m CSO10.4m
Jew89 Mac96 Gro94
Gro94
G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1
JCMT 15 m JCMT 15 m NRAO 12 m
Mac96 Mac96 Jew89
JPL01 Wlo88
OriMC⫺1
NRAO 12 m
Jew89
Wlo88
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1 OriMC⫺1 G34.3⫹0.15 Ori⫺bar⌬␣⫽⫹20⬙
NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m JCMT 15 m JCMT 15 m NRAO 12 m NRAO 12 m JCMT 15 m CSO 10.4 m
Jew89 Jew89 Jew89 Jew89 Mac96 Mac96 Jew89 Jew89 Mac96 Hog95
Wlo88
OriMC⫺1 Ori⫺bar⌬␣⫽⫹20⬙
NRAO 12 m CSO 10.4 m
Jew89 Hog95
Ori⫺bar⌬␣⫽⫹20⬙
CSO 10.4 m
Hog95
G34.3⫹0.15 OriMC⫺1 SgrB2共M兲
JCMT 15 m NRAO 12 m CSO 10.4 m
Mac96 Jew89 Sut91
G34.3⫹0.15 SgrB2共M兲
JCMT 15 m CSO 10.4 m
Mac96 Sut91
G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1 OriMC⫺1 G34.3⫹0.15 OriMC⫺1 G34.3⫹0.15
JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m NRAO 12 m JCMT 15 m NRAO 12 m JCMT 15 m
Mac96 Mac96 Mac96 Jew89 Jew89 Mac96 Jew89 Mil95 Sut91
SiS
350286.9 350333.34*共5兲 350423.50*共5兲
unidentified HNCO CH3 CN
350423.50*共5兲
U
1共1,1兲⫺0共0,0兲 A⫹⫹
8.4f 0.6 0.78 0.4
15共10,*兲⫺14共10,*兲 16共1,16兲⫺15共1,15兲 18共⫺2兲⫺17共⫺2兲 v8 ⫽1 ᐉ⫽⫹1
1.6f 1.1 0.8 1.02b
CH3 CN
18共2兲⫺17共2兲 v8 ⫽1 ᐉ⫽⫺1
350449.53*共5兲 350515. 350552.23*共5兲 350687.651*共15兲 350804.4 350847.1 350862.718*共12兲 350905.070*共14兲 351015.853*共17兲 351043.525共6兲
CH3 CN unidentified CH3 CN CH3 OH unidentified unidentified SO2 CH3 OH CH3 OCHO NO
18共⫺1兲⫺17共⫺1兲 v8 ⫽1 ᐉ⫽⫹1
351047. 351051.524共6兲
unidentified NO
2
⌸1/2 J, F⫽7/2,7/2⫺5/2,5/2 f
0.30b
NO
2
1.2 7.52
18共2兲⫺17共2兲 v8 ⫽1 ᐉ⫽⫹1 4共0,4兲⫺3共⫺1,3兲 E
10共6,4兲⫺11共5,7兲 1共1,1兲⫺0共0,0兲 A⫹ 28共7,22兲⫺27共7,21兲 A 2
⌸1/2 J, F⫽7/2,9/2⫺5/2,7/2 f
b
1.27 0.95 1.25 5.12 2.5 0.9 2.10 3.33 0.6 0.20 1.98
351236.343*共28兲
CH3 OH
351257.205*共10兲 351289.99* 共10兲
SO2 SO2
⌸1/2 J, F⫽7/2,5/2⫺5/2,3/2 f 9共5,5兲⫺10共4,6兲 E 5共3,3兲⫺4共2,2兲 36共5,31兲⫺36共4,32兲 v2 ⫽1
351420.1 351454.24*共66兲
unidentified CH2 NH
10共1,9兲⫺10共0,10兲
351464.979*共39兲 351539.4 351553.9 351633.4*共5兲 351768.636*共16兲 351822.7 351873.861*共11兲 351917.665*共54兲
OCS unidentified unidentified HNCO H2 CO unidentified SO2 t⫺CH3 CH2 OH
14共4,10兲⫺14共3,11兲 25共3,22兲⫺24共4,21兲
7.6f 0.7 0.7 0.5 2.77 11.31 0.3 6.67 0.3
351965.98* 共24兲
351051.798共6兲
U
20⫺19
30 13
U
U U
29⫺28
16共0,16兲⫺15共0,15兲 5共1,5兲⫺4共1,4兲
b
15.0f 0.4
c⫺C3 H2
9共1,8兲⫺8共2,7兲
4.0bf
SgrB2共M兲
CSO 10.4 m
351965.99*共24兲
c⫺C3 H2
9共2,8兲⫺8共1,7兲
b
Sgr B2共M兲
CSO 10.4 m
Sut91
352005.764*共50兲
HCN
4⫺3 v1 ⫽1
IRC⫹10216
CSO 10.4 m
Gro94
352041. 352082.906*共34兲
unidentified
OriMC⫺1 OriMC⫺1
NRAO 12 m NRAO 12 m
Jew89 Jew89
352087.918*共7兲
HCN
IRC⫹10216
CSO 10.4 m
Gro94
9.1bf
G34.3⫹0.15 OriMC⫺1 G34.3⫹0.15 IRC⫹10216
JCMT 15 m NRAO 12 m JCMT 15 m CSO 10.4 m
Mac96 Jew89 Mac96 Gro94
b
IRC⫹10216
34
SO2
21共4,18兲⫺21共3,19兲 4⫺3 v3 ⫽1
2.6f 1.37 1.46 6.8f 0.4 1.17 0.7
U
352277.8
U
352292.578*共20兲 352405.2 352436.554*共91兲
unidentified CH3 OCHO unidentified SiC2
352436.558*共91兲
SiC2
352505. 352599.562*共5兲 352903. 352925.620*共21兲
unidentified OCS unidentified CH3 OCHO
29⫺28
1.00 2.99 1.20
31共3,29兲⫺30共3,28兲 A
352929.594*共21兲
CH3 OCHO
31共2,29兲⫺30共2,28兲 A
352973.886*共82兲
20⫺19
353660. 353695. 353728.575*共29兲
Si34S unidentified unidentified CH3 OCHO
32共2,31兲⫺31共2,30兲 A
353728.642*共29兲
CH3 OCHO
32共1,31兲⫺31共1,30兲 A
CO⫹ HCN
U U
U U
Lab. Ref.
CH3 OCH3
CH3 OH unidentified unidentified SiC2
U
Astr. Ref.
CH3 OCH3
350149. 350169.9 350280.0*
U
Telescope
349802.993*共10兲
U U
U U
Source
349806.165*共6兲
350103.084*共23兲
U
T r 共K兲/T a 共K兲
353741.26共10兲
30共4,27兲⫺29共4,26兲 A 15共8,8兲⫺14共8,7兲 15共8,7兲⫺14共8,6兲
Wlo88 Xu_97
Xu_97 Oes99
Xu_97
Mak02
Mak02 Oes99
CSO 10.4 m
Gro94
0.97b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
NRAO NRAO NRAO NRAO
m m m m
Jew89 Jew89 Jew89 Jew89
Oes99
b
OriMC⫺1
NRAO 12 m
Jew89
Oes99
17.2f
IRC⫹10216
CSO 10.4 m
Gro94
0.05 0.06 b
IRC⫹10216 IRC⫹10216 G34.3⫹0.15
JCMT 15 m JCMT 15 m JCMT 15 m
Ave94 Ave94 Mac96
0.7b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
3/2,2⫺1/2,1
0.1
M17SW
CSO 10.4 m
Lat93
Sas81b
12 12 12 12
Oes99
4⫺3共0,1,1兲 ᐉ⫽1 f 5共0,5兲⫺4共0,4兲
0.11 0.58
IRC⫹10216 OriMC⫺1
JCMT 15 m NRAO 12 m
Ave94 Jew89
Mak02
353820.616*共54兲
H2 13CO HCN
4⫺3共1,1,0兲 ᐉ⫽1 f
0.08b
IRC⫹10216
JCMT 15 m
Ave94
Mak02
353822.504*共50兲
HCN
4⫺3共0,2,1兲 ᐉ⫽0
b
IRC⫹10216
JCMT 15 m
Ave94
Mak02
353904.226*共50兲
HCN
4⫺3共0,2,1兲 ᐉ⫽0
0.04
IRC⫹10216
JCMT 15 m
Ave94
Mak02
353808.398*共50兲 353811.876*共13兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
314
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers 7/2,3⫺5/2,2
Astr. Ref.
T r 共K兲/T a 共K兲
Source
Telescope
0.18
Ori⫺bar⌬␣⫽⫹20⬙
CSO 10.4 m
Hog95
0.6
G34.3⫹0.15 IRC⫹10216
JCMT 15 m CSO 10.4 m
Mac96 Gro94
JCMT 15 m NRAO 12 m JCMT 15 m JCMT 15 m JCMT 15 m
Mac96 Jew89 Mac96 Mac96 Mac96
Lab. Ref.
U
354122.4 354460.433*共13兲
CO⫹ unidentified HCN
U
354496.8 354505.480*共4兲 354546.5 354576.8 354607.765*共29兲
unidentified HCN unidentified unidentified CH3 OCHO
33共1,33兲⫺32共1,32兲 E
b
G34.3⫹0.15 OriMC⫺1 G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15
354607.766*共29兲
CH3 OCHO
33共0,33兲⫺32共0,32兲 E
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
354607.996*共42兲
CH3 OCHO
33共0,33兲⫺32共0,32兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
354607.996*共42兲
CH3 OCHO
33共1,33兲⫺32共1,32兲 A
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
354610. 354697.462*共24兲 354789.526*共48兲
unidentified HCCCN SiC2
39⫺38 15共6,10兲⫺14共6,9兲
0.8b 1.5 2.0 9.5bf
Sgr B2共N兲 Sgr B2共N兲 IRC⫹10216
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Lis91 Lis91 Gro94
354798.371*共54兲
SiC2
15共6,9兲⫺14共6,8兲
b
IRC⫹10216
CSO 10.4 m
Gro94
354799.992*共22兲
SO2
16共4,12兲⫺16共3,13兲 v2 ⫽1
SgrB2共M兲
CSO 10.4 m
Sut91
354845.0 354898.657*共33兲
unidentified H2 13CO
5共2,4兲⫺4共2,3兲
0.97b
G34.3⫹0.15 W3共IRS5兲
JCMT 15 m JCMT 15 m
Mac96 Hel97
355041.900*共47兲
H2 13CO SO2 SO2
12共1,11兲⫺12共1,12兲
2.29b 7.73
W3共IRS5兲
JCMT 15 m
Hel97
OriMC⫺1
NRAO 12 m
Jew89
G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1
JCMT 15 m JCMT 15 m NRAO 12 m
Mac96 Mac96 Jew89
354014.254*共88兲
U U
U
U
355045.506*共9兲 355154.951*共42兲 355186.463*共18兲 355190.95* 共11兲 355202.66* 共11兲 U
355278.2 355439.87*共20兲
U
355571. 355571.120*共82兲
U
355603.110*共26兲 355759. 355921.70* 共42兲 355921.72* 共42兲
U U
SO2 H2 13CO
4⫺3 v2 ⫽1 ᐉ⫽1 e 4⫺3
12共4,8兲⫺12共3,9兲 32共2,30兲⫺33共1,33兲 17共4,14兲⫺18共1,17兲 5共3,3兲⫺4共3,2兲
62.5f 2.0 17.40 0.3 0.4
4.3f 0.6
0.3 0.4 2.22b
OriMC⫺1
NRAO 12 m
Jew89
1⫺0
0.5 1.39
G34.3⫹0.15 W3共H2O兲
JCMT 15 m JCMT 15 m
Mac96 Hel97
8共9兲⫺7共8兲
1.08 0.24
OriMC⫺1 W3共IRS5兲
NRAO 12 m JCMT 15 m
Jew89 Hel97
1.5 0.90
G34.3⫹0.15 OriMC⫺1 W3共IRS5兲
JCMT 15 m NRAO 12 m JCMT 15 m
Mac96 Jew89 Hel97
H2 13CO unidentified
5共3,2兲⫺4共3,1兲
H15NC unidentified S18O CH3 OH unidentified
13共0,13兲⫺12共1,12兲 A⫹⫹
b
34
34共11,24兲⫺34共10,25兲
b
34
34共11,23兲⫺34共10,26兲
0.52b 0.4 0.4 2.1 3.80 1.26
SO2
355965.98* 共30兲 355990.6 356007.152*共37兲 356009. 356040.573*共14兲 356135.347*共5兲
SO2 CH3 OH unidentified CH3 OH unidentified SO2 HCN
356162.751*共5兲
HCN
4⫺3 v2 ⫽2 ᐉ⫽2 e
356222.390*共39兲
34
25共3,23兲⫺25共2,24兲
SO2
16共3,14兲⫺16共2,15兲 E vt ⫽1 15共1,14兲⫺15共0,15兲 A⫹⫹ 15共7,9兲⫺16共6,10兲 4⫺3 v2 ⫽2 ᐉ⫽2 f
20⫺19
Mak02 Mak02
Oes99
Xu_97
W3共IRS5兲
JCMT 15 m
Hel97
5.2f
G34.3⫹0.15 G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1 OriMC⫺1 IRC⫹10216
JCMT 15 m JCMT 15 m JCMT 15 m NRAO 12 m NRAO 12 m CSO 10.4 m
Mac96 Mac96 Mac96 Jew89 Jew89 Gro94
Mak02
6.3f
IRC⫹10216
CSO 10.4 m
Gro94
Mak02
0.24
W3共IRS5兲
JCMT 15 m
Hel97
20.f
IRC⫹10216
CSO 10.4 m
Gro94
72.f 2.33 0.4
IRC⫹10216
CSO 10.4 m
Gro94
Mak02
OriMC⫺1 G34.3⫹0.15 IRC⫹10216
NRAO 12 m JCMT 15 m CSO 10.4 m
Jew89 Mac96 Gro94
Mak02
G34.3⫹0.15 G34.3⫹0.15
JCMT 15 m JCMT 15 m
Mac96 Mac96
Gro98
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
JCMT 15 m JCMT 15 m
Mac96 Mac96
Gro98
Xu_97 Xu_97
356242.386*共38兲
29
356255.566*共13兲
HCN
U U
356261. 356293.6 356301.176*共6兲
unidentified unidentified HCN
U
356400.8 356575.247*共10兲
unidentified CH3 OCH3
8共4,5兲⫺7共3,4兲 AE
b
356576.016*共10兲
CH3 OCH3
8共4,5兲⫺7共3,4兲 EE
356577.7 356582.855*共10兲
unidentified CH3 OCH3
0.7b 0.7
8共4,5兲⫺7共3,4兲 AA
b
G34.3⫹0.15 G34.3⫹0.15
356586.756*共12兲
CH3 OCH3
8共4,4兲⫺7共3,4兲 EE
0.7b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
356586.896*共20兲
CH3 OCH3
8共4,4兲⫺7共3,4兲 EA
b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
356723. 356734.242*共75兲
unidentified 4⫺3
0.025 17.40
IRC⫹10216 OriMC⫺1
JCMT 15 m NRAO12 m
Ave94 Jew89
10共4,6兲⫺10共3,7兲 10共4,6兲⫺10共3,7兲 4⫺3 共0,3,0兲 ᐉ⫽3 e 10共4,7兲⫺9共3,6兲
0.42 0.80 0.10 0.5
IRAS16293⫺2422 W3共IRS5兲 IRC⫹10216 G34.3⫹0.15
CSO 10.4 m JCMT 15 m JCMT 15 m JCMT 15 m
Bla94 Hel97 Ave94 Mil95
U
U
356755.179*共9兲 356755.179*共9兲 356839.549*共8兲 357067.465*共22兲 357102.195*共22兲 U
SiS
HCO⫹ SO2 SO2 HCN t⫺CH3 CH2 OH 34
SO2
4⫺3 v2 ⫽1 ᐉ⫽1 f
4⫺3 v2 ⫽2 ᐉ⫽0
9.4f 0.5
Mak02
20共0,20兲⫺19共1,19兲
0.61
W3共IRS5兲
JCMT 15 m
Hel97
13共4,10兲⫺13共3,11兲
3.46 0.5 3.21 3.21 b
OriMC⫺1 G34.3⫹0.15 OriMC⫺1 OriMC⫺1 G34.3⫹0.15
NRAO 12 m JCMT 15 m NRAO 12 m NRAO 12 m JCMT 15 m
Jew89 Mac96 Jew89 Jew89 Mac96
Gro98
0.8b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
b
G34.3⫹0.15
JCMT 15 m
Mac96
Gro98
357165.379*共10兲 357215.6 357241.180*共12兲 357387.569*共9兲 357459.417*共8兲
SO2 unidentified SO2 SO2 CH3 OCH3
15共4,12兲⫺15共3,13兲 11共4,8兲⫺11共3,9兲 18共2,17兲⫺17共1,16兲 AE⫹EA
357460.174*共6兲
CH3 OCH3
18共2,17兲⫺17共1,16兲 EE
357460.930*共8兲
CH3 OCH3
18共2,17兲⫺17共1,16兲 AA
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS
315
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
Lab. Ref.
15共4,12兲⫺14共4,11兲
16.6f
IRC⫹10216
CSO10.4m
Gro94
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
357549.768*共20兲
CH3 OCHO
29共14,15兲⫺28共14,14兲 A
0.5b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
357549.768*共20兲
CH3 OCHO
29共14,16兲⫺28共14,15兲 A
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
357581.439*共8兲
SO2
8共4,4兲⫺8共3,5兲 7共2,5兲⫺6共1,5兲 E
0.6 0.7
G34.3⫹0.15 G34.3⫹0.15
JCMT 15 m JCMT 15 m
Mac96 Mac96
Xu_97
2.75
OriMC⫺1 G34.3⫹0.15
NRAO 12 m JCMT 15 m
Jew89 Mil95
0.6b 3.13 2.18 1.83
13
CH3 OH SO2
357671.810*共8兲 357681.234*共29兲
t⫺CH3 CH2 OH
9共4,6兲⫺9共3,7兲 7共5,3兲⫺6共4,2兲
357682.001*共29兲
t⫺CH3 CH2 OH
7共5,2兲⫺6共4,3兲
357892.433*共9兲 357925.838*共9兲 357962.891*共14兲 357995.05* 共23兲
SO2 SO2 SO2 CH3 OH
7共4,4兲⫺7共3,5兲 6共4,2兲⫺6共3,3兲 17共4,14兲⫺17共3,15兲 15共3,13兲⫺15共2,14兲 E vt ⫽1
357995.604*共20兲
CH3 OCHO
29共13,17兲⫺29共13,16兲 A
357995.607*共20兲
CH3 OCHO
29共13,16兲⫺29共13,15兲 A
357995.677*共21兲
CH3 OCHO
28共5,23兲⫺27共5,22兲 E
358013.144*共9兲
SO2 SO2 SO2
5共4,2兲⫺5共3,3兲
34
b
G34.3⫹0.15
JCMT 15 m
Mil95
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 G34.3⫹0.15
NRAO 12 m NRAO 12 m NRAO 12 m JCMT 15 m
Jew89 Jew89 Jew89 Mac96
Xu_97
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
1.2b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
2.35
OriMC⫺1
NRAO 12 m
Jew89
4共4,0兲⫺4共3,1兲
0.7
G34.3⫹0.15
JCMT 15 m
Mac96
20共0,20兲⫺19共1,19兲 23共4,20兲⫺22323221
2.50 0.25
OriMC⫺1 W3共IRS5兲
NRAO 12 m JCMT 15 m
Jew89 Hel97
28共7,21兲⫺27共7,20兲 E 28共7,21兲⫺27共7,20兲 A 10共6,5兲⫺11共5,7兲 E
0.17 0.14 0.49 1.5
JCMT JCMT JCMT JCMT JCMT
m m m m m
Hel97 Hel97 Hel97 Mac96 Mac96
358364.221*共20兲 358392.411*共20兲 358414.688*共32兲 358453.2 358576.600*共17兲
SO2 CH3 OCHO CH3 OCHO CH3 OH unidentified CH3 OCHO
29共12,18兲⫺29共12,17兲 A
b
W3共H2O兲 W3共H2O兲 W3共H2O兲 G34.3⫹0.15 G34.3⫹0.15
358576.669*共17兲
CH3 OCHO
29共12,17兲⫺29共12,16兲 A
1.1b
G34.3⫹0.15
JCMT 15 m
Mac96
Oes99
358605.870*共9兲
CH3 OH
OriMC⫺1 W3共IRS5兲
NRAO 12 m JCMT 15 m
Jew89 Hel97
358728.5 358756.497*共8兲 358790.633*共8兲 358811.119*共8兲
S18O unidentified CH3 CCH CH3 CCH CH3 CCH
3.18 0.21
Xu_97
358645.723*共20兲
4共1,3兲⫺3共0,3兲 E 9共9兲⫺8共8兲 21共3兲⫺20共3兲 21共2兲⫺20共2兲
0.6 0.20 0.15
G34.3⫹0.15 W3共H2O兲 W3共H2O兲
JCMT 15 m JCMT 15 m JCMT 15 m
Mac96 Hel97 Hel97
358816.3 358817.949*共8兲
unidentified CH3 CCH 34
SO2
21共1兲⫺20共1兲
b
0.6
15 15 15 15 15
W3共H2O兲
JCMT 15 m
Hel97
G34.3⫹0.15 W3共H2O兲
JCMT 15 m JCMT 15 m
Mac96 Hel97
0.29b 0.14
W3共IRS5兲
JCMT 15 m
Hel97
0.5 0.8 2.21
G34.3⫹0.15 G34.3⫹0.15 OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m NRAO 12 m NRAO 12 m
Mac96 Mac96 Jew89 Jew89
Gro98
OriMC⫺1
NRAO 12 m
Jew89
Gro98
JCMT 15 m JCMT 15 m JCMT 15 m
Mac96 Mac96 Hel97
Oes99 Xu_97
25共3,23兲⫺25共2,24兲 12共3,10兲⫺11共2,9兲 EE
0.63b
359387.637*共10兲
CH3 OCH3
12共3,10兲⫺11共2,9兲 AA
b
359544.7 359558.004*共17兲 359651.770*共22兲
unidentified CH3 OCHO
29共6,24兲⫺28共6,23兲 A 24共2,22兲⫺23共2,21兲
0.6 0.7 0.30
G34.3⫹0.15 G34.3⫹0.15 W3共IRS5兲
4.80b 3.04 0.22
W3共H2O兲
JCMT 15 m
Hel97
OriMC⫺1 W3共IRS5兲
NRAO 12 m JCMT 15 m
Jew89 Hel97
W3共IRS5兲 W3共H2O兲
JCMT 15 m JCMT 15 m
Hel97 Hel97
JCMT 15 m NRAO 12 m NRAO 12 m NRAO 12 m CSO 10.4 m NRAO 12 m JCMT 15 m
Hel94 Woo91 Woo91 Woo91 Phi92 Woo91 Hel97
SO2 CH3 OH SO2
Oes99
21共0兲⫺20共0兲
unidentified unidentified SO2 CH3 OCH3
34
Oes99 Oes99 Xu_97
15共2,14兲⫺14共1,13兲
358990.3 359004.8 359151.140*共23兲 359384.584*共8兲
359677.68* 共18兲
14共3,12兲⫺14共2,13兲 E vt ⫽1 19共4,16兲⫺19共3,17兲 5⫺4
360848.861*共20兲
DCO⫹ SO2 CH3 OH
361236.467*共25兲 361780.2 361798.7 361835.144*共17兲 361852.279*共19兲 361852.279*共19兲 361863.466*共6兲
CH3 OH unidentified unidentified CH3 OCHO CH3 OH CH3 OH CH3 OCH3
29共9,21兲⫺28共9,20兲 E 8共1,7兲⫺7共2,5兲 E 8共1,7兲⫺7共2,5兲 E 20共1,20兲⫺19共0,19兲 AE
b
W3共IRS5兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 W3共H2O兲
361863.466*共6兲
CH3 OCH3
20共1,20兲⫺19共0,19兲 AE⫹EA
b
OriMC⫺1
CSO 10.4 m
Phi92
Gro98
361863.466*共6兲
CH3 OCH3
20共1,20兲⫺19共0,19兲 EA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
361863.566*共6兲
CH3 OCH3
20共1,20兲⫺19共0,19兲 EE
0.41b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
361863.566*共6兲
CH3 OCH3
20共1,20兲⫺19共0,19兲 EE
0.5b
OriMC⫺1
CSO 10.4 m
Phi92
Gro98
361863.667*共6兲
CH3 OCH3
20共1,20兲⫺19共0,19兲 AA
b
OriMC⫺1
CSO 10.4 m
Phi92
Gro98
361863.667*共8兲
CH3 OCH3
20共1,20兲⫺19共0,19兲 AA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
361871.020*共6兲
CH3 OCH3
11共3,8兲⫺10共2,9兲 AE
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
361871.062*共6兲
CH3 OCH3
11共3,8兲⫺10共2,9兲 EA
b
W3共H2O兲
JCMT 15 m
Hel97
Gro98
361874.319*共6兲
CH3 OCH3
11共3,8兲⫺10共2,9兲 EE
W3共H2O兲
JCMT 15 m
Hel97
Gro98
361874.6 361877.597*共8兲
unidentified CH3 OCH3
1.22b 2.0
OriMC⫺1 W3共H2O兲
NRAO 12 m JCMT 15 m
Woo91 Hel97
Gro98
360290.386*共45兲
U
Astr. Ref.
29共14,15兲⫺28共14,14兲 E
359770.669*共17兲 360169.830*共29兲
U U
Telescope
SiC2
358987.965*共22兲 U U
Source
CH3 OCHO
358347.336*共40兲
U
T r 共K兲/T a 共K兲
357473.425*共68兲
358037.878*共9兲 358215.625*共15兲
U
Quantum numbers
357548.131*共25兲
357657.980*共19兲
U
Formula
34共5,29兲⫺34共4,30兲 11共0,11兲⫺10共1,9兲 E 3共1,2兲⫺4共2,3兲 A⫺⫺
11共3,8兲⫺10共2,9兲 AA
0.64 4.55b n.r. 0.5 0.5 1.0 7.0 17.0
b
Xu_97 Xu_97
Oes99 Xu_97 Gro98
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
316
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U
U
U U
U U U U
Formula
U U U
U
U
Telescope
Astr. Ref.
Lab. Ref.
29共9,20兲⫺28共9,19兲 A 13共3,10兲⫺12共2,11兲 E vt ⫽1 6共3,3兲⫺5共2,4兲
0.5 1.0 10.0 2.0 2.0 2.0 2.0 0.31
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 W3共IRS5兲
NRAO 12 m NRAO 12 m NRAO 12 m NRAO 12 m CSO 10.4 m NRAO 12 m CSO 10.4 m JCMT 15 m
Woo91 Woo91 Woo91 Woo91 Phi92 Woo91 Phi92 Hel97
30共5,26兲⫺29共5,25兲 A 4⫺3 5共0,5兲⫺4共0,4兲 23共2,22兲⫺23共1,23兲
1.0 1.5 1.5 3.0 4.7 0.16
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 W3共IRS5兲
NRAO 12 m NRAO 12 m NRAO 12 m MMWO 4.9 m MMWO 4.9 m JCMT 15 m
Woo91 Woo91 Woo91 Man90 Man90 Hel97
2.36 1.0 1.0 9.94 2.10b
W3共IRS5兲 W3共IRS5兲 W3共IRS5兲 OriMC⫺1 OriMC⫺1
JCMT 15 m JCMT 15 m JCMT 15 m CSO 10.4 m CSO 10.4 m
Hel97 Hel94 Hel94 Man93 Man93
b
OriMC⫺1
CSO 10.4 m
Man93
8.6 8.3
OriMC⫺1 OriMC⫺1 W3共H2O兲
CSO 10.4 m CSO 10.4 m JCMT 15 m
Man93 Man93 Hel97
Xu_97
G34.3⫹15 OriMC⫺1 G34.3⫹15 OriMC⫺1 W3共H2O兲
CSO 10.4 m NRAO 12 m CSO 10.4 m NRAO 12 m JCMT 15 m
Phi92 Woo91 Phi92 Woo91 Hel97
Xu_97
NRAO 12 m JCMT 15 m
Woo91 Hel97
Xu_97
unidentified unidentified DCN CH3 OCHO unidentified CH3 OCHO CH3 OH
362191.5 362211.9 362221.777*共20兲 362630.327*共14兲 362736.010*共16兲 362834.170*共30兲
unidentified unidentified CH3 OCHO HNC H2 CO
363159.246*共21兲
SO2
363890.884*共13兲 363925.816*共14兲 363945.869*共15兲 364103.229*共19兲
SO2 SO2 H2 CO H2 CO
21共4,18兲⫺21共3,19兲 24共1,23兲⫺24共0,24兲 23共2,22兲⫺23共1,23兲 5共2,4兲⫺4共2,3兲 5共4,2兲⫺4共4,1兲
364103.269*共19兲
H2 CO
5共4,1兲⫺4共4,0兲
364275.204*共15兲 364288.914*共15兲 364508.172*共47兲
H2 CO H2 CO CH3 OH
5共3,3兲⫺4共3,2兲 5共3,2兲⫺4共3,1兲 8共3,6兲⫺8共2,9兲 E vt ⫽1
364640. 364642.4 364680. 364681.0 364746.206*共40兲
unidentified unidentified unidentified unidentified CH3 OH
7共3,5兲⫺7共2,6兲 E vt ⫽1
b
364748.952*共5兲 364757.51* 共17兲
OCS CH3 OH
30⫺29 12共6,7兲⫺13共5,8兲 A⫹⫹ vt ⫽1
11.0 0.86b
OriMC⫺1 W3共H2O兲
364757.51* 共17兲
CH3 OH
12共6,7兲⫺13共5,8兲 A⫺⫺ vt ⫽1
b
W3共H2O兲
JCMT 15 m
Hel97
Xu_97
H 3 O⫹
3,2⫺2,2
0.5
OriMC⫺1
NRAO 12 m
Woo91
Bog85
1.0 2.0 1.0 1.0 0.43 1.5 1.0 1.5 1.0 1.0 n.r. 0.055 0.08
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 W3共IRS5兲 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 IC443G N1333
CSO 10.4 m NRAO 12 m NRAO 12 m CSO 10.4 m JCMT 15 m NRAO 12 m CSO 10.4 m NRAO 12 m CSO 10.4 m NRAO 12 m CSO 10.4 m CSO 10.4 m JCMT 15 m
Phi92 Woo91 Woo91 Phi92 Hel97 Woo91 Phi92 Woo91 Phi92 Woo91 Phi92 Tur91a Sta99
Bog84b
3,0⫺2,0
12. 0.3 1.8
OriMC⫺1 G34.3⫹15 OriMC⫺1
KAO 1 m CSO 10.4 m CSO 10.4 m
Phi80 Phi92 Phi92
Bog85
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Phi92 Phi92
Xu_97
OriMC⫺1
CSO 10.4 m
Phi92
Xu_97
IRAS16293⫺2422 RXBoo UHer
CSO 10.4 m HHT 10 m CSO 10.4 m
Bla94 Bie00 Mel93
DeL74
364836. 364836.3 364860.7 364898.282*共39兲 364950.171*共27兲 364954.6 364986.766*共11兲 364990.4 365030.935*共50兲 365037.1 365046.901*共58兲 365363.410*共15兲 372421.34共20兲 380197.372*共25兲 396162. 396272.412 共60兲
U
Source
361893.5 361950.2 362045.759*共8兲 362096.725*共17兲 362101. 362110.620*共16兲 362149.60* 共11兲 362158.223*共13兲
34
SO2
34
SO2
364797.43共10兲 U U U
T r 共K兲/T a 共K兲
Quantum numbers
396358. 396517.309*共23兲
unidentified unidentified unidentified CH3 OH SO2 unidentified CH3 OH unidentified CH3 OH unidentified CH3 OH H2 CO H 2 D⫹ H2 O unidentified
5⫺4 29共9,20兲⫺28共9,19兲 E
6共3,4兲⫺6共2,5兲 E vt ⫽1 25共9,17兲⫺26共8,18兲 5共3,3兲⫺5共2,4兲 E vt ⫽1 4共3,2兲⫺4共2,3兲 E vt ⫽1 3共3,1兲⫺3共2,2兲 E vt ⫽1 5共2,3兲⫺4共2,2兲 1共1,0兲⫺1共1,1兲 4共1,4兲⫺3共2,1兲
H 3 O⫹ unidentified
0.41b 0.6 2.0 0.3 3.5
2共1,2兲⫺1共0,1兲 A⫹⫹
9.0 5.0
398946.209*共15兲
CH3 OH
5共0,5兲⫺4共⫺1,4兲 E
11.0
398989. 434120.31* 共23兲 437346.67共20兲
unidentified SiO H2 O
10⫺9 v⫽0 7共5,3兲⫺6共6,0兲
439150.812共50兲
H2 O
6共4,3兲⫺5共5,0兲
443952.93共12兲 457005.658*共24兲 459487.007*共7兲 459566.153*共7兲 459627.724*共7兲 459671.755*共7兲
LiH CH3 OH CH3 CN CH3 CN CH3 CN CH3 CN
459698.169*共8兲
CH3 CN
459706.974*共8兲
13
CH3 OH
0.15 1.40 340.e
Oes99 Oes99 Xu_97
Oes99
Xu_97
Xu_97 Xu_97 Xu_97
UHer
CSO 10.4 m
Mel93
DeL74
1⫺0 11共2,9兲⫺11共1,11兲 A⫹⫺ 25共5兲⫺25共5兲 25共4兲⫺25共4兲 25共3兲⫺25共3兲
280.e 0.007 1.8 0.69 0.74 1.11
B0218⫹357 W3共OH兲 G34.26⫹0.15 G34.26⫹0.15 G34.26⫹0.15
IRAM 30 m JCMT 15 m HHT 10 m HHT 10 m HHT 10 m
Com98 Hel96 Pan01 Pan01 Pan01
Bel94 Xu_97
25共2兲⫺25共2兲
0.5b
G34.26⫹0.15
HHT 10 m
Pan01
25共1兲⫺25共1兲
0.57b
G34.26⫹0.15
HHT 10 m
Pan01
CH3 CN
25共0兲⫺25共0兲
G34.26⫹0.15
HHT 10 m
Pan01
461040.768*共1兲 461182.45* 共31兲
CO HNCO
4⫺3 21共3,19兲⫺20共3,18兲
1.21b 60. 1.b
OriMC⫺1 OriMC⫺1
KAO 1 m HHT 10 m
Phi80 Zin00
461182.51* 共31兲
HNCO
21共3,18兲⫺20共3,17兲
b
OriMC⫺1
HHT 10 m
Zin00
JPL01
461336.93* 共38兲 461368.88* 共35兲
HNCO HNCO
21共2,20兲⫺20共2,19兲 21共2,19兲⫺20共2,18兲
n.r. 3.
OriMC⫺1 OriMC⫺1
HHT 10 m HHT 10 m
Zin00 Zin00
JPL01 JPL01
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
JPL01
MICROWAVE TRANSITIONS
317
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U
Formula
Quantum numbers
Source
Telescope
Astr. Ref.
Lab. Ref.
461392.564*共32兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺1/21/2⫺1/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
461399.552*共30兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺1/23/2⫺1/2
⫺1.5b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
461449.562*共34兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺1/21/2⫺3/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
461450.67* 共20兲 461456.550*共29兲
HNCO NH2
21共0,21兲⫺20共0,20兲 1共1,0兲⫺1共0,1兲3/2⫺1/21/2⫺3/2
20. ⫺2.0b
OriMC⫺1 Sgr B2共M兲
HHT 10 m CSO 10.4 m
Zin00 vDi93
JPL01 COL01
461465.106*共29兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺1/23/2⫺3/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
461755.942*共33兲 461882.08*共7兲 461907.700*共9兲 461934.421*共3兲 462236.037*共15兲
SO HCOOH OCS CH2 CHCN
25. 2.0 10. 2.0
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
Sch91 Sch91 Sch91 Sch91 Sch91
COL01 JPL01
462241.656*共29兲
SO CH3 OH
13共14兲⫺13共13兲 11共4,7兲⫺11共3,8兲 38⫺37 10共0,10兲⫺9共0,9兲 10共11兲⫺9共10兲 5共⫺5,0兲⫺6共⫺4,3兲 E
20.b
OriMC⫺1
CSO 10.4 m
Sch91
Xu_97
462424.981*共29兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺3/23/2⫺5/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
462433.537*共23兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺3/25/2⫺5/2
⫺9.0b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
462448.723*共28兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺3/21/2⫺3/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
462455.711*共25兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺3/23/2⫺3/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
462464.267*共31兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺3/25/2⫺3/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
462467.171*共28兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺3/21/2⫺1/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
462474.158*共27兲
NH2
1共1,0兲⫺1共0,1兲3/2⫺3/23/2⫺1/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
463011.403*共14兲 463119.共 兲 463198. 463326.224*共45兲 464834.670*共19兲 464924.520 共32兲 464960.5 466245.2共6兲 466367. 469366.331*共34兲
SO2 HNCO unidentified SO2 CH3 OH HDO unidentified NH3 unidentified NH2
12共2,10兲⫺11共1,11兲 21共1,20兲⫺20共1,19兲
6.8 8.4 ⫺2.0 21.8 30. 20. 2.0 1.7 2.0
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO CSO
m m m m m m m m m
Sch92 Sch92 Sch92 Sch92 Sch91 Sch91 Sch91 Sch92 Sch92
1共1,0兲⫺1共0,1兲1/2⫺1/21/2⫺3/2
⫺3.0b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
469383.623*共34兲
NH2
1共1,0兲⫺1共0,1兲1/2⫺1/23/2⫺1/2
b
Sgr B2共M兲
CSO 10.4 m
vDi93
COL01
469440.621*共32兲
NH2 H2 O SiO
1共1,0兲⫺1共0,1兲1/2⫺1/23/2⫺3/2 6共4,2兲⫺5共5,1兲 11⫺10 10⫺9
⫺3.0 69.e 1.0 3.1
Sgr B2共M兲 UHer HH211 Sgr B2共N兲
CSO 10.4 m CSO10.4 m JCMT 15 m CSO 10.4 m
vDi93 Mel93 Nis02 Hau93
COL01 DeL74
10⫺9 7共1,7兲⫺6共1,6兲 1共1,0兲⫺1共0,1兲 1共0兲⫺0共0兲 7⫺6
11.7 1.51 ⫺3.7 3.5 2.9
Sgr B2共N兲 Ori⫺bar⌬␣⫽⫹20⬙ OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m JCMT 15 m PIROG7 60c m KAO 1 m CSO10.4 m
Hau93 Hog95 Tau96 Kee83 Sch01
12共2,10兲⫺11共1,10兲 E 14⫺13v⫽0 24共9,15兲⫺23共8,16兲 12共7,6兲⫺11共6,5兲 EA
3.5 10.6 5.9
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
34
470888.95共19兲 477504.73*共25兲 481915.883*共51兲 489750.952*共37兲 491968.367*共20兲 556936.002 共89兲 572498.15共10兲 607175.1*共10兲
U U
T r 共K兲/T a 共K兲
C34S CS H2 CO H2 O NH3
35共4,32兲⫺35共3,33兲 9共2,7兲⫺9共1,8兲 A⫹⫺ 1共0,1兲⫺0共0,0兲 0共0兲⫺1共0兲 v2 ⫽1
20.b
10.4 10.4 10.4 10.4 10.4
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
m m m m m
JPL01 COL01
Sch92
Xu_97 DeL71 Urb81
DeL74
607215.814*共28兲 607607.79* 共30兲 608021.337* 共6兲 608094.265*共72兲
H13CO⫹ CH3 OH SiO CH3 CH2 CN CH3 OCH3
608096.853*共68兲
CH3 OCH3
12共7,6兲⫺11共6,5兲 EE
5.8b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
608098.248*共68兲
CH3 OCH3
12共7,6兲⫺11共6,5兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
608098.260*共68兲
CH3 OCH3
12共7,5兲⫺11共6,6兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
608099.434*共68兲
CH3 OCH3
12共7,6兲⫺11共6,5兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
608099.446*共68兲
CH3 OCH3
12共7,5兲⫺11共6,6兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
608100.841*共70兲
CH3 OCH3
12共7,5兲⫺11共6,6兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
608102.243*共74兲
CH3 OCH3
12共7,5兲⫺11共6,6兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
608269.3 609131.2 609507.66* 共20兲
unidentified unidentified 7⫺6
5.2 2.1 3.6
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
33共2,32兲⫺32共1,31兲 10共10兲⫺10共9兲 13共6,7兲⫺12共6,6兲 A⫹⫹ vt ⫽1
11.7 17.2 8.0
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Mul01 Xu_97
609558.445*共47兲 609960.050*共53兲 610692.70* 共17兲
HN13C SO2 SO 13
CH3 OH
10.4 10.4 10.4 10.4
JPL01 Gro02
13 CH3 OH CH3 OCH3
13共⫺12,2兲⫺12共⫺12,1兲 E vt ⫽1
8.8
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
610844.451*共28兲
20共3,17兲⫺19共2,18兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
610844.452*共28兲
CH3 OCH3
20共3,17兲⫺19共2,18兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
610847.489*共24兲
CH3 OCH3
20共3,17兲⫺19共2,18兲 EE
5.8b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
610850.525*共32兲
CH3 OCH3
20共3,17兲⫺19共2,18兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
610890.4*共10兲
13
4.3
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
610721.9*共13兲
611267.20共8兲
CH3 OH C2 H
13共⫺11,3兲⫺12共⫺11,2兲 E vt ⫽1 7⫺615/2,13/2⫺13/2,11/2
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
611267.20共8兲
C2 H
7⫺615/2,15/2⫺13/2,13/2
2.2b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
611329.71共8兲
C2 H
7⫺613/2,11/2⫺11/2,9/2
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
611329.71共8兲
C2 H
7⫺613/2,13/2⫺11/2,11/2
3.8b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
318
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
H2 S SO CH3 OH
5共3,2兲⫺5共2,3兲 4共5兲⫺3共2兲 18共2,17兲⫺17共3,14兲 A⫺⫺
13.2 3.7 4.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
JPL01 Mul01 Xu_97
13 CH3 OH CH3 CH2 CN CH3 OCH3
13共⫺1,13兲⫺12共⫺1,12兲 E
2.5
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
612227.427*共5兲 612285.51* 共77兲
35共7,28兲⫺34共6,29兲 30共11,19兲⫺30共10,20兲 AA
5.1 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Gro02
612285.51* 共77兲
CH3 OCH3
30共11,20兲⫺30共10,21兲 AA
2.7b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
612285.81* 共77兲
CH3 OCH3
30共11,19兲⫺30共10,20兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
612286.11* 共77兲
CH3 OCH3
30共11,19兲⫺30共10,20兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
612286.28* 共77兲
CH3 OCH3
30共11,20兲⫺30共10,21兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
612286.58* 共77兲
CH3 OCH3
30共11,19兲⫺30共10,20兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
612286.59* 共77兲
CH3 OCH3
30共11,20兲⫺30共10,21兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
612287.06* 共77兲
CH3 OCH3
30共11,20兲⫺30共10,21兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
612442.747*共27兲 612479.632*共24兲
SO2
n.r. 1.9
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Xu_97
611441.629 共70兲 611552.412*共30兲 611579.832*共55兲 612124.206*共26兲
13
13共4,10兲⫺12共3,9兲 v2 ⫽1 13共0,13兲⫺12共0,12兲 A⫹⫹
612867.63* 共31兲 612892.089*共88兲
2.6
13
28共1,28兲⫺27共1,27兲 13共7,6兲⫺12共7,5兲 A⫺⫺
b
OriMC⫺1 OriMC⫺1
612892.089*共88兲
13
13共7,7兲⫺12共7,6兲 A⫹⫹
1.7b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
612933.657*共32兲
13
13共2,12兲⫺12共2,11兲 A⫺⫺
1.8b 7.8 7.5
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
5.1b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97 Xu_97
CH3 OH HNCO CH3 OH CH3 OH CH3 OH
613076.211*共14兲 613303.946*共34兲
13
8共5,3兲⫺7共4,4兲 13共3,11兲⫺12共3,10兲 A⫹⫹
613334.287*共44兲
13
13共4,10兲⫺12共4,9兲 A⫺⫺
613335.238*共44兲
13
SO2 CH3 OH CH3 OH CH3 OH
14共4,10兲⫺13共3,11兲
CH3 OH
U
U U U U
Sch01
CSO 10.4 m
Sch01
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13
13共3,10兲⫺12共3,9兲 A⫺⫺
13
13共1,12兲⫺12共1,11兲 E
1.9
613611.908*共34兲
13
13共3,10兲⫺12共3,9兲 E
2.4
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
41共3,39兲⫺41共2,40兲 4共⫺2,3兲⫺3共⫺1,3兲 E
2.6 1.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
34共9,26兲⫺33共8,25兲 A
4.0
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
13
13共2,11兲⫺12共2,10兲 E
2.7
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13
42共7,35兲⫺42共6,36兲 13共⫺2,12兲⫺12共⫺2,11兲 E
2.9 3.1
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
28共3,26兲⫺27共3,25兲
2.9b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
CH3 OH CH3 OH SO2
13 CH3 OH CH3 OCHO
CH3 OH SO2
614780.01* 共39兲
CH3 OH HNCO
614780.23* 共39兲
HNCO
28共3,25兲⫺27共3,24兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
614976.38* 共47兲 615052.07* 共43兲 615098.94* 共27兲 615248.689*共5兲 615276.7 615628.825*共50兲 615985.382*共19兲
HNCO HNCO HNCO CH3 CH2 CN unidentified SO2
28共2,27兲⫺27共2,26兲 28共2,26兲⫺27共2,25兲 28共0,28兲⫺27共0,27兲 30共8,23兲⫺29共7,22兲
1.7 2.5 4.5 2.5 6.1 1.7 4.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO
10.4 10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
JPL01 JPL01 JPL01 JPL01
3.7 9.7 n.r. 5.6 3.2 2.7
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO
10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
4共⫺2,3兲⫺3共⫺1,3兲 E
5.7 6.8 7.0
CSO CSO CSO CSO
10.4 10.4 10.4 10.4
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97
616226.3 616322.23* 共61兲 616347.430*共87兲 616472.243*共48兲 616603.6 616638.96* 共13兲
U U
CSO 10.4 m
OriMC⫺1
613522.469*共25兲
614113.666*共69兲 614361.002*共27兲
U
OriMC⫺1
613351.033*共34兲
614018.969*共66兲 614089.934*共25兲
34
b
5.1b 4.1
613676.374*共48兲 613904.956*共23兲
U
13共4,9兲⫺12共4,8兲 A⫹⫹
SO2
613338.136*共30兲
12共9,3兲⫺12共8,6兲 9共5,5兲⫺8共4,4兲
34
SO2 unidentified CH3 OH SO2 SO2 unidentified
20共2,19兲⫺19共3,17兲 E vt ⫽1 34共2,32兲⫺33共3,31兲 v2 ⫽1 29共3,27兲⫺28共2,26兲 9共1,9兲⫺8共1,8兲
Xu_97
616979.845*共15兲 617097.1 617149.5 617180.497*共43兲
H2 13CO CH3 OH unidentified unidentified CH3 CH2 CN
72共2,71兲⫺71共2,70兲
2.9b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
617180.663*共43兲
CH3 CH2 CN
72共1,71兲⫺72共1,70兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
617234.380*共12兲
CH3 CH2 CN
69共12,58兲⫺68共12,57兲
4.9b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
617234.439*共12兲
CH3 CH2 CN
69共12,58兲⫺68共12,57兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
617340.582*共6兲 617346.67* 共30兲 617627.4*共 兲 617919.038*共6兲 618152.108*共43兲 619157.0 619251.217*共94兲 619318.7 619365.2 623071.654*共54兲 623145.8 623193.27* 共25兲
CH3 CH2 CN HNCO CH3 OH CH3 CH2 CN SO2 unidentified SO2 unidentified unidentified CH3 OH
43共6,38兲⫺42共5,37兲 28共1,27兲⫺27共1,26兲 20共⫺7兲⫺20共⫺6兲 E vt ⫽2 41共6,35兲⫺40共5,36兲 34共2,32兲⫺33共3,31兲
8.0 3.3 3.3 6.1 2.4 5.5 n.r. 11.7 9.8 5.9
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO
m m m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
JPL01 JPL01 Sch01 JPL01
Xu_97
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
unidentified CH3 OH
29共3,27兲⫺28共2,26兲 v2 ⫽1
18共2,16兲⫺17共3,15兲 A⫹⫹ 14共⫺7,8兲⫺14共⫺6,9兲 E vt ⫽1
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
6.34 9.2
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
JPL01
MICROWAVE TRANSITIONS
319
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U U U U U U U
623262.2 623296.5 623316.9 623340.9 623363.570*共21兲 623487.1 623516.691*共17兲 623570.7 623644.1 623693.10* 共23兲
U
U
U
U
Telescope
Astr. Ref.
7⫺6 v2 ⫽1 ᐉ⫽1 f
4.8 11.7 9.6 17.3 15.7 10.4 n.r. 19.9 13.4
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
CSO CSO CSO CSO
10.4 10.4 10.4 10.4
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97 JPL01
8共5,3兲⫺7共4,4兲 v2 ⫽1
Lab. Ref.
Mak02
10.3b
623779.824*共32兲 623848.6 624024.403*共29兲
6.6 4.8 5.8
25共12,14兲⫺24共11,14兲 E
2.4b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
624031.728*共28兲
CH3 OCHO
25共12,14兲⫺24共11,13兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
624031.768*共28兲
CH3 OCHO
25共12,13兲⫺24共11,14兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
624072.8 624166.255*共22兲
unidentified CH3 CN
4.7
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
624208.46* 共13兲
OriMC⫺1
CSO10.4m
Sch01
624232.42*共11兲 624263.6 624344.136*共16兲
HCO⫹ CH3 OH unidentified CH3 CN
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
624344.618*共79兲
SO2
OriMC⫺1
CSO 10.4 m
Sch01
624460.9 624498.445*共12兲 624551.7*共5兲
unidentified CH3 CN CH3 OCHO
34共6兲⫺33共6兲 54共5,49兲⫺53共6,48兲 A
4.5b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
JPL01
624551.9*共5兲
CH3 OCHO
54共6,49兲⫺53共6,48兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
624552.1*共5兲
CH3 OCHO
54共5,49兲⫺53共5,48兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
624552.4*共5兲
CH3 OCHO
54共6,49兲⫺53共5,48兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
624629.119*共11兲
CH3 CN
34共5兲⫺33共5兲
16.7b
OriMC⫺1
CSO 10.4 m
Sch01
624680.365*共58兲
CH3 OCHO
16共16,0兲⫺15共15,1兲 A
3.1b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
624680.365*共58兲
CH3 OCHO
16共16,1兲⫺15共15,0兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
624736.106*共11兲
CH3 CN
34共4兲⫺33共4兲
9.7b
OriMC⫺1
CSO 10.4 m
Sch01
9.7b
OriMC⫺1
CSO 10.4 m
Sch01
5.9
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
OriMC⫺1
CSO 10.4 m
Sch01
6.7b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
b
624778.0 624819.363*共12兲
13
CH3 OH
34共8兲⫺33共8兲 7⫺6 21共1,20兲⫺20共2,19兲 A⫺⫺
8.0b 14.3 19.7 4.9
34共7兲⫺33共7兲
16.4b
35共1,35兲⫺34共0,34兲
16.4b 8.5 9.7
3共2,2兲⫺2共1,1兲 A⫺⫺
Oes99
Xu_97
Xu_97
unidentified CH3 CN
34共3兲⫺33共3兲
6.7b
兲
CH3 OH
13共1兲⫺12共1兲 A⫹⫹ vt ⫽2
624878.856*共13兲 624887.539*共37兲
CH3 CN SO2
34共2兲⫺33共2兲 42共4,38兲⫺41共5,37兲
6.7b 6.7
624914.561*共14兲
CH3 CN
34共1兲⫺33共1兲
OriMC⫺1
CSO 10.4 m
Sch01
624926.465*共14兲
CH3 CN
34共0兲⫺33共0兲
16.9b
OriMC⫺1
CSO 10.4 m
Sch01
624932.124*共10兲
CH3 OCH3
16共6,11兲⫺15共5,11兲 EE
16.9b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
624932.402*共18兲
CH3 OCH3
16共6,10兲⫺15共5,11兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
624935.401*共24兲
CH3 OCH3
16共6,10兲⫺15共5,11兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
624935.641*共20兲
CH3 OCH3
16共6,10兲⫺15共5,11兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
624936.218*共22兲
CH3 OCH3
16共6,10兲⫺15共5,11兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
624964.37共10兲
H37Cl
1⫺0 3/2⫺3/2
0.7
OriMC⫺1
CSO 10.4 m
Sal96
DeL71a
624977.82共10兲
H37Cl
1⫺0 5/2⫺3/2
1.4
OriMC⫺1
CSO 10.4 m
Sal96
DeL71a
624988.33共10兲
H37Cl CH3 CH2CN
1⫺0 1/2⫺3/2
1.0
OriMC⫺1
CSO 10.4 m
Sal96
DeL71a
44共6,39兲⫺43共5,38兲
1.7
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
13共9兲⫺12共9兲 A⫹⫹ vt ⫽2 13共11兲⫺12共11兲 E vt ⫽2 13共⫺10兲⫺12共⫺10兲 A⫹⫹ vt ⫽2
4.8 6.0 8.1 5.7 4.6
CSO CSO CSO CSO CSO CSO
m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97
625024.694*共7兲 625063.4 625072.8*共 兲 625155.8*共 兲 625207.6*共 兲 625335.0 625352.52* 共73兲 625352.52* 共73兲 625383.1*共 625434.0*共
U
Source
46共3,43兲⫺46共2,44兲
624838.0*共
U
T r 共K兲/T a 共K兲
9共0,9兲⫺8共1,8兲 E vt ⫽1 72共3,70兲⫺71共3,69兲
624744.289*共26兲 U
unidentified unidentified unidentified unidentified HCN unidentified SO2 unidentified unidentified
Quantum numbers
34 SO2 CH3 OH CH3 CH2 CN unidentified CH3 OCHO
623737.869*共15兲 U
Formula
兲 兲
625510.225*共58兲 625668.1 625749.466*共9兲 625782.413*共38兲 625901.60共10兲
unidentified CH3 OH CH3 OH CH3 OH unidentified CH3 OH
10.4 10.4 10.4 10.4 10.4 10.4
Sch01
24共10,14兲⫺25共9,17兲 A⫹⫹
4.6b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CH3 OH
24共10,15兲⫺25共9,16兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
CH3 OH CH3 OH CH3 OH unidentified CH3 OH CH3 OH
13共10兲⫺12共10兲 A⫹⫹ vt ⫽2
4.6
OriMC⫺1
CSO 10.4 m
Sch01
Sch01
13共⫺1兲⫺12共⫺1兲 E vt ⫽2 13共8,5兲⫺12共8,4兲 A⫹⫹ vt ⫽1
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
Sch01 Xu_97
13共0,13兲⫺12共0,12兲 E 13共3,11兲⫺12共3,10兲 E vt ⫽1
2.2 5.7 4.9 18.1 6.1
Xu_97 Xu_97
10.4 10.4 10.4 10.4 10.4
Sch01 Sch01 Sch01
H35Cl
1⫺0 3/2⫺3/2
4.5
OriMC⫺1
CSO 10.4 m
Sch95
DeL71a
625918.76共10兲
H35Cl
1⫺0 5/2⫺3/2
6.5
OriMC⫺1
CSO 10.4 m
Sch95
DeL71a
625932.01共10兲
H35Cl
1⫺0 1/2⫺3/2
6.0
OriMC⫺1
CSO 10.4 m
Sch95
DeL71a
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
320
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 625971.256*共18兲 626007.723*共23兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
CH3 OH
13共1,13兲⫺12共1,12兲 A⫹⫹ vt ⫽1 10共0,10兲⫺9共⫺1,9兲 E
5.5 5.0
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
13
CH3 OH SO2 SO2
15共4,12兲⫺14共3,11兲
21.1b
OriMC⫺1
CSO 10.4 m
Sch01
626087.297*共20兲
14共4,10兲⫺13共3,11兲
OriMC⫺1
CSO 10.4 m
Sch01
626156.8*共 兲 626185.892*共97兲
CH3 OH CH3 OH
13共10兲⫺12共10兲 E vt ⫽2 13共7,6兲⫺12共7,5兲 E vt ⫽1
21.1b 6.2 3.1b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Sch01 Xu_97
5.4b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
626043.503*共34兲
626185.941*共32兲
34
25共12,14兲⫺26共11,15兲
626192.162*共31兲
34
20共11,9兲⫺21共10,12兲
SO2
13⫺12
8.8
OriMC⫺1
CSO 10.4 m
Sch01
626381.697*共33兲 626397.983*共40兲 626452.169*共21兲 626474.625 共70兲 626476.517*共31兲
13共⫺8,6兲⫺12共⫺8,5兲 E vt ⫽1 13共⫺6,8兲⫺12共⫺6,7兲 E vt ⫽1 13共⫺2,11兲⫺12共⫺2,10兲 E vt ⫽1 7共6,1兲⫺7共5,7兲
2.5 4.2 6.8 13.1
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97 JPL01
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626476.517*共31兲
CH3 OH
13共7,7兲⫺12共7,6兲 A⫹⫹ vt ⫽1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626489.93* 共10兲 626511.037*共28兲
CH3 OH CH3 OH
21共⫺1,21兲⫺20共2,18兲 E
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13共5,8兲⫺12共5,7兲 A⫺⫺ vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
9.4b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13共7,6兲⫺12共7,5兲 A⫺⫺ vt ⫽1
13.1b 8.5
10.4 10.4 10.4 10.4
626511.037*共28兲
CH3 OH
13共5,9兲⫺12共5,8兲 A⫹⫹ vt ⫽1
626555.117*共45兲
CH3 OH
17共0,17兲⫺16共1,15兲 E vt ⫽1
626555.150*共20兲
CH3 OH
13共4,10兲⫺12共4,9兲 E vt ⫽1
13.8b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626608.113*共17兲
CH3 OH
13共⫺3,10兲⫺12共⫺3,9兲 E vt ⫽1
14.2b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626609.821*共17兲
CH3 OH
13共2,11兲⫺12共2,10兲 A⫹⫹ vt ⫽1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626626.362*共18兲
CH3 OH
3共2,2兲⫺2共1,1兲 A⫺⫺
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626639.928*共18兲
CH3 OH
13共0,13兲⫺12共0,12兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626654.090*共17兲 626673.583*共17兲 626724.8 626865.178*共19兲 626879.380*共41兲
CH3 OH CH3 OH unidentified CH3 OH CH3 OH
13共1,13兲⫺12共1,12兲 E vt ⫽1 13共2,12兲⫺12共2,11兲 A⫺⫺ vt ⫽1
18.2 15.3 3.7 8.6
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97 Xu_97
626881.664*共22兲
CH3 OH
13共2,12兲⫺12共2,11兲 E vt ⫽1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
626930.794*共31兲 626945.944*共23兲 626978.722*共54兲
CH3 OH CH3 OH CH3 OCH3
13共⫺1,12兲⫺12共⫺1,11兲 E vt ⫽1 13共⫺4,9兲⫺12共⫺4,8兲 E vt ⫽1 35共0,35兲⫺34共1,34兲 AE
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Gro02
626978.722*共54兲
CH3 OCH3
35共0,35兲⫺34共1,34兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
626978.777*共54兲
CH3 OCH3
35共0,35兲⫺34共1,34兲 EE
4.3b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
626978.833*共54兲
CH3 OCH3
35共0,35兲⫺34共1,34兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
626986.840*共54兲
CH3 OCH3
35共1,35兲⫺34共0,34兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
626986.840*共54兲
CH3 OCH3
35共1,35兲⫺34共0,34兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
626986.894*共54兲
CH3 OCH3
35共1,35兲⫺34共0,34兲 EE
4.3b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
626986.948*共54兲
CH3 OCH3
35共1,35兲⫺34共0,34兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627004.212*共47兲
13共0,13兲⫺12共0,12兲 A⫹⫹ vt ⫽1 13共⫺5,9兲⫺12共⫺5,8兲 E vt ⫽1
8.8
627013.605*共38兲
CH3 OH CH3 OH
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
627016.318*共68兲
CH3 OCH3
13共7,7兲⫺12共6,6兲 EA
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627018.797*共64兲
CH3 OCH3
13共7,7兲⫺12共6,6兲 EE
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627020.168*共66兲
CH3 OCH3
13共7,7兲⫺12共6,6兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627020.204*共66兲
CH3 OCH3
13共7,6兲⫺12共6,7兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627021.259*共64兲
CH3 OCH3
13共7,7兲⫺12共6,6兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627021.294*共64兲
CH3 OCH3
13共7,6兲⫺12共6,7兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627022.665*共66兲
CH3 OCH3
13共7,6兲⫺12共6,7兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627024.054*共70兲
CH3 OCH3
13共7,6兲⫺12共6,7兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
627138.621*共26兲
13
3共2,1兲⫺2共1,2兲 A⫹⫹
6.9
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13共⫺1,13兲⫺12共⫺1,12兲 E 13共1,12兲⫺12共1,11兲 A⫺⫺ vt ⫽1 16共2,14兲⫺15共1,15兲
19.7 8.7
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97
627170.503*共9兲
CH3 OH CH3 OH CH3 OH SO2
13共3,11兲⫺12共3,10兲 A⫹⫹ vt ⫽1 13共8,5兲⫺12共8,4兲 E vt ⫽1
b
26.2b
b
9.0b 9.8 12.0
14.6b b
14.6b
10.4 10.4 10.4 10.4 10.4
14.7b
OriMC⫺1 OriMC⫺1 OriMC⫺1
33共7,27兲⫺33共6,28兲
14.7b
OriMC⫺1
CSO 10.4 m
Sch01
627445.408*共46兲
SO2 CH3 OH
13共4,9兲⫺12共4,8兲 A⫹⫹ vt ⫽1
7.4b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
627445.410*共46兲
CH3 OH
13共4,10兲⫺12共4,9兲 A⫺⫺ vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
627476.1 627529.217*共51兲 627558.440*共9兲 627647.660*共42兲 627715.243*共53兲
unidentified CH3 OH CH3 OH CH3 OH SO2
13共5,8兲⫺12共5,7兲 E vt ⫽1 13共0,13兲⫺12共0,12兲 A⫹⫹ 13共10,4兲⫺12共10,3兲 E 42共2,40兲⫺42共1,41兲
6.1 6.5 23.4 3.0
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
627774.178*共40兲 627809.639*共37兲
CH3 OH CH3 OH
13共⫺10,3兲⫺12共⫺10,2兲 E 13共9,5兲⫺12共9,4兲 E
6.3b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
627814.509*共28兲
CH3 OH
13共⫺9,4兲⫺12共⫺9,3兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
627209.067*共25兲 627331.141*共20兲 627335.271*共87兲
U
SO2
C34S CH3 OH CH3 OH CH3 OH H2 S CH3 OH
626351.502*共94兲
U
34
34
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
2.4b 3.5
10.4 10.4 10.4 10.4 10.4
MICROWAVE TRANSITIONS
321
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
627898.317*共28兲
CH3 OH
13共9,4兲⫺12共9,3兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
627898.317*共28兲
CH3 OH
13共9,5兲⫺12共9,4兲 A⫹⫹
4.7b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
627922.137*共24兲
13共⫺8,5兲⫺12共⫺8,4兲 E 13共8,5兲⫺12共8,4兲 A⫹⫹
6.1
627971.284*共20兲
CH3 OH CH3 OH
6.7b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
627971.284*共20兲
CH3 OH
13共8,6兲⫺12共8,5兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628021.276*共21兲
CH3 OH
13共8,6兲⫺12共8,5兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628039.186*共17兲
CH3 OH
13共7,6兲⫺12共7,5兲 A⫺⫺
7.5b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628039.186*共17兲
CH3 OH
13共7,7兲⫺12共7,6兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628051.884*共10兲 628093.4 628113.718*共16兲
CH3 OH unidentified CH3 OH
13共2,12兲⫺12共2,11兲 A⫹⫹
22.0 2.7
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97
7.8b
OriMC⫺1 OriMC⫺1 OriMC⫺1
Xu_97
628115.613*共17兲
CH3 OH
13共⫺7,6兲⫺12共⫺7,5兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628167.709*共14兲 628187.885*共13兲
CH3 OH CH3 OH
13共6,8兲⫺12共6,7兲 E 13共6,7兲⫺12共6,6兲 A⫹⫹
10.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
628187.885*共13兲
CH3 OH
13共6,8兲⫺12共6,7兲 A⫺⫺
CSO 10.4 m
Sch01
Xu_97
CH3 OH CH3 OH CH3 OH CH3 OH
13共⫺6,7兲⫺12共⫺6,6兲 E 13共5,9兲⫺12共5,8兲 E 13共⫺5,8兲⫺12共⫺5,7兲 E
12.2b 11.5 13.0 17.1
OriMC⫺1
628237.723*共14兲 628251.336*共11兲 628318.246*共11兲 628329.925*共10兲
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
13共⫺4,10兲⫺12共⫺4,9兲 E
17.1b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628338.242*共12兲
CH3 OH
13共5,8兲⫺12共5,7兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628338.242*共12兲
CH3 OH
13共5,9兲⫺12共5,8兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
628341.176*共28兲
U
Formula
34
13共7,7兲⫺12共7,6兲 E
16共2,14兲⫺15共1,15兲
b
628408.882*共10兲 628445.283*共10兲 628469.879*共9兲 628512.151*共10兲
SO2 CH3 OH CH3 OH CH3 OH CH3 OH
13共4,9兲⫺12共4,8兲 E 13共⫺3,11兲⫺12共⫺3,10兲 E 13共3,11兲⫺12共3,10兲 A⫹⫹
17.1b 16.3 17.3 19.9
13共4,10兲⫺12共4,9兲 A⫺⫺
25.1b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628513.330*共10兲
CH3 OH
13共4,9兲⫺12共4,8兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628525.026*共9兲
CH3 OH
13共3,10兲⫺12共3,9兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
628660.07* 共18兲
CH3 OCH3
10共8,3兲⫺9共7,3兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628661.18* 共18兲
CH3 OCH3
10共8,3兲⫺9共7,3兲 EE
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628662.28* 共18兲
CH3 OCH3
10共8,2兲⫺9共7,3兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628662.28* 共18兲
CH3 OCH3
10共8,3兲⫺9共7,2兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628664.24* 共18兲
CH3 OCH3
10共8,2兲⫺9共7,3兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628664.24* 共18兲
CH3 OCH3
10共8,3兲⫺9共7,2兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628665.34* 共18兲
CH3 OCH3
10共8,2兲⫺9共7,2兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628668.40* 共19兲
CH3 OCH3
10共8,2兲⫺9共7,2兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
628696.381*共9兲 628816.121*共9兲 628869.040*共10兲 628889.7 629140.501*共18兲 629321.677*共10兲 629363.8*共兲 629651.808*共9兲 629696.0 629790.563*共24兲 629825.3* 629921.263*共17兲
CH3 OH CH3 OH CH3 OH unidentified CH3 OH CH3 OH CH3 OH CH3 OH
13共1,12兲⫺12共1,11兲 E 13共3,10兲⫺12共3,9兲 E 13共2,11兲⫺12共2,10兲 A⫹⫹
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO
m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
3共2,1兲⫺2共1,2兲 A⫹⫹ 13共2,11兲⫺12共2,10兲 E 17共1兲⫺16共0兲 E vt ⫽2 13共⫺2,12兲⫺12共⫺2,11兲 E
18.8 16.3 16.3 5.4 21.1 19.2 5.3 17.4
71共4,67兲⫺70共4,66兲 5共3,3兲⫺4共2,3兲 E
2.3 2.0 1.5
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
25.7 3.4 4.0 b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97
8.4b
12.9b
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
Xu_97 Xu_97 Sch01 Xu_97
unidentified CH3 CH2 CN CH3 OD CH3 OH
7共1,7兲⫺6共0,6兲 A⫹⫹
630583.01* 共49兲 630951.028*共48兲
unidentified CH3 OH CH3 OH
7共⫺1,6兲⫺8共⫺2,6兲 E vt ⫽1 13共6,4兲⫺12共4,8兲 A⫺⫺
630951.029*共48兲
CH3 OH
13共6,5兲⫺12共4,8兲 A⫹⫹
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
631702.829*共24兲
H2 CO
9共1,9兲⫺8共1,8兲 14共15兲⫺13共14兲
37.1 14.8
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
COL01
9共5,5兲⫺8共4,4兲
25.6
OriMC⫺1
CSO 10.4 m
Sch01
630376.0
631742.131 共50兲
34
SO
10.4 10.4 10.4 10.4
JPL01 Sch01 Xu_97
632193.333*共15兲 632401.43* 共30兲
SO2 CH3 OCHO
51共17,35兲⫺50共17,34兲 A
3.6b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
632401.67* 共30兲
CH3 OCHO
51共17,34兲⫺50共17,33兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
3.0
OriMC⫺1
CSO 10.4 m
Sch01
SO2
29共7,23兲⫺29共6,24兲
CH3 OH HNCO
8共3,6兲⫺7共2,5兲 A⫹⫹
5.2
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
11共1,11兲⫺12共0,12兲 15共15兲⫺14共14兲
6.2 15.0
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 COL01
8共3,5兲⫺7共2,6兲 A⫺⫺
6.7
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
1.9 3.7
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
3.4 4.1
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
632474.710*共74兲 632505.472*共19兲 632571.66* 共14兲 632647.840 共50兲 632771.534*共19兲 U U
632852.2 633023.5
U
633114.6 633147.801*共70兲
34 13
34
SO
13 CH3 OH unidentified unidentified
unidentified 34
SO2
28共7,21兲⫺28共6,22兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
322
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 633293.153 共50兲
U U U U U U U
U
U
U
U
U
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
16共15兲⫺15共14兲
17.1
OriMC⫺1
CSO 10.4 m
Sch01
COL01
13共1,12兲⫺12共1,11兲 A⫺⫺ 4共⫺2,2兲⫺5共⫺3,2兲 E vt ⫽1
23.2 12.9 3.9 3.2 7.2 5.0 4.6 4.6 5.2 5.2
CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO
m m m m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97
633423.069*共10兲 633571.984*共75兲 633674.4 633802.5 633832.8 633860.1 633891.1 633898.3 633907.894*共48兲 633926.9 633952.831*共51兲
34 SO CH3 OH CH3 OH unidentified unidentified unidentified unidentified unidentified unidentified CH3 OCHO unidentified CH3 OCHO
19共15,5兲⫺18共14,5兲 E
7.9b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
633960.580*共45兲
CH3 OCHO
19共15,4兲⫺18共14,5兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
633960.580*共45兲
CH3 OCHO
19共15,5兲⫺18共14,4兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
634081.2 634118.947*共31兲 634454.275*共66兲
unidentified SO2
5.4 n.r. 5.4
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
14.8 6.7 2.8
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
n.r. 4.8 2.9b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
JPL01 JPL01
634510.837*共12兲 634584.6 634634.296*共57兲
34
SO2 HNC unidentified 33
SO2
19共15,4兲⫺18共14,4兲 E
14共4,10兲⫺13共3,11兲 v2 ⫽1 27共7,21兲⫺27共6,22兲 7⫺6 34共7,27兲⫺34共6,28兲
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
Oes99 Oes99
634692.28* 共45兲 634731.65* 共34兲 634766.649*共19兲
SO2 HNCO CH3 CH2 CN
38共1,37兲⫺38共0,38兲 v2 ⫽1 29共1,29兲⫺28共1,28兲 71共13,59兲⫺70共13,58兲
634766.654*共19兲
CH3 CH2 CN
71共13,58兲⫺70共13,57兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
634782.522*共52兲
SO2
11共9,3兲⫺12共8,4兲
634878.9 634898.408*共52兲 635027.6*共6兲
unidentified SO2 CH3 OCHO
31共3,29兲⫺30共2,28兲 55共5,50兲⫺54共6,49兲 A
3.3 9.1 12.9 3.6b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
JPL01
635027.8*共6兲
CH3 OCHO
55共5,50兲⫺54共5,49兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635027.8*共6兲
CH3 OCHO
55共6,50兲⫺54共6,49兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635027.9*共6兲
CH3 OCHO
55共6,50兲⫺54共5,49兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
10共5,5兲⫺9共4,6兲
5.5
OriMC⫺1
CSO 10.4 m
Sch01
26共7,19兲⫺26共6,20兲
4.2 1.9
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
15⫺14 v⫽0
3.5
OriMC⫺1
CSO 10.4 m
Sch01
1.3 1.4 2.5 1.8b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
635051.001*共20兲 U
Formula
34
SO2
10.4 10.4 10.4 10.4
635085.0 635144.278*共61兲
unidentified
635218.10* 共35兲 635295.3 635324.846*共63兲 635389.85* 共22兲 635414.461*共26兲
30 SiO unidentified SO2 CH3 OH CH3 CH2 CN
635414.461*共26兲
CH3 CH2 CN
71共23,49兲⫺70共23,48兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635668.93* 共18兲 635697.60* 共10兲
CH3 OH CH3 CH2 CN
25共4,21兲⫺25共3,21兲 A⫹⫺ 75共0,75兲⫺74共0,74兲
5.1 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 JPL01
635697.60* 共10兲
CH3 CH2 CN
75共1,75兲⫺74共1,74兲
3.3b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635750.578*共34兲
CH3 OCHO
31共10,22兲⫺30共9,21兲 A
1.5b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
635750.8*共6兲
CH3 OCHO
56共4,52兲⫺55共4,51兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635750.8*共6兲
CH3 OCHO
56共4,52兲⫺55共5,51兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635750.8*共6兲
CH3 OCHO
56共5,52兲⫺55共4,51兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635750.8*共6兲
CH3 OCHO
56共5,52兲⫺55共5,51兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635751.2*共3兲
CH3 OCHO
51共15,37兲⫺50共15,36兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
635754.586*共32兲
CH3 OCHO
31共10,22兲⫺30共7,23兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
635871.06* 共15兲 635904.9 635943.85* 共13兲 636011.46* 共12兲 636053.035*共57兲
CH3 OH unidentified CH3 OH CH3 OH
24共4,20兲⫺24共3,21兲 A⫹⫺
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01
Xu_97
24共⫺3,22兲⫺23共⫺4,20兲 E 23共4,19兲⫺23共3,20兲 A⫹⫺
3.8 2.5 1.3 3.5
25共7,19兲⫺25共6,20兲
1.1
OriMC⫺1
CSO 10.4 m
Sch01
636073.895*共28兲
CH3 OCHO
26共12,15兲⫺25共11,14兲 A
1.2b
OriMC⫺1
CSO 10.4 m
Sch01
636073.997*共28兲
CH3 OCHO
26共12,15兲⫺25共11,14兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
636103.69* 共10兲 636159.60*共8兲 636189.302*共61兲
CH3 OH CH3 OH CH3 OH
22共4,18兲⫺24共3,19兲 A⫹⫺ 21共4,17兲⫺21共3,18兲 A⫹⫺ 20共4,16兲⫺20共3,17兲 A⫹⫺
5.6 7.6
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
636190.088*共23兲
CH3 OH
15共4,11兲⫺15共3,12兲 A⫹⫺
16.5b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636190.924*共21兲
CH3 OH
14共4,10兲⫺15共3,11兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636193.270*共26兲
CH3 OH
16共4,12兲⫺16共3,13兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636196.960*共20兲
CH3 OH
13共4,9兲⫺13共3,10兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636198.424*共31兲
CH3 OH
17共4,13兲⫺17共3,14兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636201.292*共48兲
CH3 OH
19共4,15兲⫺19共3,16兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
34
SO2
34
SO2
38共7,31兲⫺38共6,32兲 26共4,22兲⫺26共3,23兲 E 71共23,48兲⫺70共23,47兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
10.4 10.4 10.4 10.4
10.4 10.4 10.4 10.4
m m m m
Xu_97 JPL01
Xu_97 Xu_97 Oes99
MICROWAVE TRANSITIONS
323
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Source
Telescope
Astr. Ref.
Lab. Ref.
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
17.2 16.2
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
8共4,5兲⫺8共3,6兲 A⫺⫹ 7共4,3兲⫺7共3,4兲 A⫹⫺
19.8
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
CH3 OH
7共4,4兲⫺7共3,5兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
CH3 OH
13共4,10兲⫺13共3,11兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636363.115*共21兲
CH3 OH
6共4,2兲⫺6共3,3兲 A⫹⫺
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636365.661*共21兲
CH3 OH
6共4,3兲⫺6共3,4兲 A⫺⫹
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636393.314*共22兲
CH3 OH
5共4,1兲⫺5共3,2兲 A⫹⫺
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636393.830*共22兲
CH3 OH
5共4,2兲⫺5共3,3兲 A⫺⫹
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636413.793*共21兲
CH3 OH
14共4,11兲⫺14共3,12兲 A⫺⫹
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636419.896*共24兲
CH3 OH
4共4,0兲⫺4共3,1兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636420.026*共24兲
CH3 OH
4共4,1兲⫺4共3,2兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636468.335*共14兲
CH3 OCH3
20共5,16兲⫺19共4,15兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
636468.378*共14兲
CH3 OCH3
20共5,16兲⫺19共4,15兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
636470.257*共12兲
CH3 OCH3
20共5,16兲⫺19共4,15兲 EE
6.4b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
636472.158*共14兲
CH3 OCH3
20共5,16兲⫺19共4,15兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
636522.990*共23兲
CH3 OH
15共4,12兲⫺15共3,13兲 A⫺⫹
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
636532.519*共80兲 636677.598*共26兲 636714.07* 共44兲
CS CH3 OH HNCO
13⫺12 16共4,13兲⫺16共3,14兲 A⫺⫹ 29共3,27兲⫺28共3,26兲
2.2b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 JPL01
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
6.7
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Oes99
Quantum numbers
636202.500*共38兲
CH3 OH
18共4,14兲⫺18共3,15兲 A⫹⫺
636208.656*共18兲 636225.884*共18兲 636248.048*共17兲
12共4,8兲⫺12共3,9兲 A⫹⫺ 11共4,7兲⫺11共3,8兲 A⫹⫺ 10共4,6兲⫺10共3,7兲 A⫹⫺ 9共4,5兲⫺9共3,6兲 A⫹⫺
15.8
636274.205*共17兲
CH3 OH CH3 OH CH3 OH CH3 OH
636279.367*共17兲
CH3 OH
10共4,7兲⫺10共3,8兲 A⫺⫹
636280.535*共18兲
CH3 OH
11共4,8兲⫺10共3,9兲 A⫺⫹
636299.453*共18兲
CH3 OH
12共4,9兲⫺12共3,10兲 A⫺⫹
636303.169*共18兲
CH3 OH
8共4,4兲⫺8共3,5兲 A⫹⫺
636311.642*共18兲 636333.605*共19兲
CH3 OH CH3 OH
636337.464*共19兲 636341.725*共19兲
U
U
20.7b
21.3b
20.6b b
20.6b b
19.8b
29.9b 29.9 10.2
HNCO
29共3,26兲⫺28共3,25兲
636886.893*共32兲 636952.080*共58兲
CH3 OH CH3 OCHO
17共4,14兲⫺17共3,15兲 A⫺⫹ 17共16,2兲⫺16共15,2兲 E
2.7b
OriMC⫺1 OriMC⫺1
636953.794*共35兲
CH3 OCHO
31共10,21兲⫺30共9,22兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
636954.752*共53兲
CH3 OCHO
17共16,1兲⫺16共15,2兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
636954.752*共53兲
CH3 OCHO
17共16,2兲⫺16共15,1兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
636999.88* 共48兲 637037.75* 共31兲 637161.182*共39兲 637307.324*共48兲
HNCO HNCO CH3 OH
29共2,27兲⫺28共2,26兲 29共0,29兲⫺28共0,28兲 18共4,15兲⫺18共3,16兲 A⫺⫹ 23共7,17兲⫺23共6,18兲
2.3 7.7 5.6 1.1
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01
JPL01 JPL01 Xu_97
637511.827*共50兲 637684.0*共15兲
CH3 OH
34
SO2
10.4 10.4 10.4 10.4
m m m m
19共4,16兲⫺19共3,17兲 A⫺⫹
5.1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13
11共5,7兲⫺12共4,8兲 A⫺⫺
1.5b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13
CH3 OH
11共5,6兲⫺12共4,9兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
637723.300*共9兲
CH3 CH2 CN
12共12,0兲⫺11共11,1兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
637723.300*共9兲
CH3 CH2 CN
12共12,1兲⫺11共11,0兲
1.7b 2.3
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
OriMC⫺1
CSO 10.4 m
Sch01
38共7,31兲⫺37共6,32兲
4.1 4.1 2.6 2.1
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
10共0,10兲⫺9共⫺1,9兲 E
2.0 16.1
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
2.5 29.0 1.2 1.2
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
41共7,35兲⫺41共6,36兲
2.7
OriMC⫺1
CSO 10.4 m
Sch01
8共3,5兲⫺7共2,6兲 A⫺⫺ 22共4,19兲⫺22共3,20兲 A⫺⫹ 16共7,9兲⫺16共6,10兲
25.9 2.9
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1
CSO 10.4 m
Sch01
637797.437*共43兲
U
21.2b
636714.34* 共44兲
637685.1*共15兲
U
T r 共K兲/T a 共K兲
Formula
637863.7 637951.258*共64兲 638084.3 638119.367*共6兲 638220.4 638279.610*共17兲 638492.967*共82兲 638523.473*共15兲 638586. 638635.265*共35兲 638770.436*共68兲 638817.792*共15兲 639151.50* 共10兲 639646.086*共26兲
CH3 OH
34
SO2
unidentified CH3 OH unidentified CH3 CH2 CN unidentified CH3 OH CH3 OH CH3 OH unidentified 34
SO2
SO2 CH3 OH CH3 OH 34
SO2
22共7,15兲⫺22共6,16兲 20共4,17兲⫺20共3,18兲 A⫺⫹
21共4,18兲⫺21共3,19兲 A⫺⫹ 8共3,6兲⫺7共2,5兲 A⫹⫹ 20共7,13兲⫺20共6,14兲
13.8b
639650.959*共22兲
SO2
15共4,12兲⫺14共3,11兲
639765.60* 共25兲
H2 13CO
9共3,7兲⫺8共3,6兲
13.8b 1.6
15共7,9兲⫺15共6,10兲
1.4
639795.085*共26兲 639942.39* 共13兲 640002.222*共28兲
34
SO2 CH3 OH 34
SO2
10.4 10.4 10.4 10.4
10.4 10.4 10.4 10.4
23共4,20兲⫺23共3,21兲 A⫺⫹
1.3
OriMC⫺1
CSO 10.4 m
Sch01
13共7,7兲⫺13共6,8兲
1.1
OriMC⫺1
CSO 10.4 m
Sch01
640116.709*共32兲
34
11共7,5兲⫺11共6,6兲
2.5
OriMC⫺1
CSO 10.4 m
Sch01
640148.309*共35兲
34
10共7,3兲⫺10共6,4兲
b
OriMC⫺1
CSO 10.4 m
Sch01
SO2 SO2
Xu_97 JPL01 Xu_97 Xu_97 Xu_97
Xu_97 Xu_97
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
324
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U U U U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
640167.091*共37兲
34
9共7,3兲⫺9共6,4兲
b
OriMC⫺1
CSO 10.4 m
Sch01
640175.892*共40兲
34
8共7,1兲⫺6共6,2兲
b
OriMC⫺1
CSO 10.4 m
Sch01
640177.273*共42兲
34
SO2
7共7,1兲⫺7共6,2兲
2.0b
OriMC⫺1
CSO 10.4 m
Sch01
CH3 OH
SO2 SO2
Lab. Ref.
640287.13* 共31兲
13
20共4,16兲⫺20共3,17兲 A⫹⫺
3.8b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640297.03* 共24兲
13
19共4,15兲⫺19共3,16兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640297.33* 共10兲
13
16共4,12兲⫺16共3,13兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640298.21* 共31兲
13
17共4,13兲⫺17共3,14兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640298.99*共8兲
13
15共4,11兲⫺15共3,12兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640299.23* 共18兲
13
18共4,14兲⫺18共3,15兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640304.744*共57兲
13
14共4,10兲⫺14共3,11兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640376.734*共25兲
13
10共4,6兲⫺10共3,7兲 A⫹⫺
1.1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640398.548*共29兲
13
11共4,8兲⫺18共3,9兲 A⫹⫺
2.0b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640403.485*共25兲
13
10共4,7兲⫺10共3,8兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640404.884*共23兲
13
9共4,5兲⫺9共3,6兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640408.779*共35兲
13
12共4,9兲⫺12共3,10兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640419.323*共23兲
13
9共4,6兲⫺9共3,7兲 A⫺⫹
2.1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640435.179*共22兲
13
8共4,4兲⫺8共3,5兲 A⫹⫺
2.6b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640439.119*共44兲
13
13共4,10兲⫺13共3,11兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640442.415*共22兲
13
8共4,5兲⫺8共3,6兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640466.374*共24兲
13
7共4,3兲⫺7共3,4兲 A⫹⫺
2.4b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640469.670*共24兲
13
7共4,4兲⫺7共3,5兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640494.244*共57兲
13
14共4,11兲⫺14共3,12兲 A⫺⫹
3.4b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640497.184*共28兲
13
6共4,2兲⫺6共3,3兲 A⫹⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640498.504*共28兲
13
6共4,3兲⫺6共3,4兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640526.344*共32兲
13
5共4,1兲⫺5共3,2兲 A⫹⫺
2.6b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640526.784*共32兲
13
5共4,2兲⫺5共3,3兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640552.670*共36兲
13
4共4,0兲⫺4共3,1兲 A⫹⫺
2.0b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
640552.780*共36兲
13
4共4,1兲⫺4共3,2兲 A⫺⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97
3共3,0兲1共3兲⫺3共2,2兲0共3兲
0.9 1.6 1.3
18共4,15兲⫺18共3,16兲 A⫺⫹
1.9
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
9共3,7兲⫺8共0,8兲
1.6 1.4 1.6
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
640882.17* 共16兲 640981.1 641056.70* 共12兲 641119.58* 共18兲 641206.557*共19兲 641224.8 641324.38* 共29兲
CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH
CH3 OH CH3 OH unidentified NH2 D 13
CH3 OH SO2 unidentified 34
SO2
24共4,21兲⫺24共3,22兲 A⫺⫹
39共2,38兲⫺39共1,39兲
JPL01
641361.791*共12兲
CH3 OCH3
20共5,15兲⫺19共4,16兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
641361.834*共12兲
CH3 OCH3
20共5,15兲⫺19共4,16兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
641363.653*共12兲
CH3 OCH3
20共5,15兲⫺19共4,16兲 EE
2.2b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
641365.493*共14兲
CH3 OCH3
20共5,15兲⫺19共4,16兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
641825.538*共57兲 641988.73* 共20兲 642136.2
SO2 CH3 OH unidentified
36共0,36兲⫺35共1,35兲 25共4,22兲⫺25共3,23兲 A⫺⫹
642232.005*共60兲 642552.7 642670.879*共18兲 642739.0 642762.1
SO2 unidentified CH3 CN unidentified unidentified
36共7,29兲⫺36共6,30兲
SO2
21共11,11兲⫺22共10,12兲
4.5 1.4 2.0 1.7 1.5 3.7 6.6 2.2 2.9
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO CSO
m m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
15⫺14 v⫽0
2.9
OriMC⫺1
CSO 10.4 m
Sch01
2.6
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
642806.212*共22兲 642807.24* 共35兲 642829.602*共13兲 642832.43* 共47兲 642964.014*共11兲 643074.061*共11兲
35共7兲⫺34共7兲
29
SiO CH3 CN 13
CH3 OH CH3 CN CH3 CN CH3 OCHO CH3 CN CH3 CN CH3 CN
35共6兲⫺34共6兲 22共4,19兲⫺14共3,20兲 A⫺⫹ 35共5兲⫺34共5兲
2.6b 2.0
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
JPL01
Xu_97
35共4兲⫺34共4兲 22共14,9兲⫺21共13,9兲 E 35共3兲⫺34共3兲 35共2兲⫺34共2兲 35共1兲⫺34共1兲
2.4 2.4 1.9 1.8
35共0兲⫺34共0兲 29共11,18兲⫺28共10,18兲 E
4.3
643276.738*共35兲
CH3 CN CH3 OCHO
4.3b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
643282.004*共28兲
CH3 OCHO
29共11,19兲⫺28共10,18兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
643643.050*共18兲
CH3 OCH3
17共6,12兲⫺16共5,11兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643643.755*共20兲
CH3 OCH3
17共6,12兲⫺16共5,11兲 EE
3.3b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643646.062*共20兲
CH3 OCH3
17共6,12兲⫺16共5,11兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643646.749*共30兲
CH3 OCH3
17共6,11兲⫺16共5,11兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643647.520*共18兲
CH3 OCH3
17共6,11兲⫺16共5,11兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643091.069*共42兲 643159.699*共12兲 643220.894*共14兲 643257.621*共15兲 643269.865*共14兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
4.3b
10.4 10.4 10.4 10.4 10.4
Xu_97
Oes99
Oes99
MICROWAVE TRANSITIONS
325
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U U
U
U
U U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
643658.314*共52兲 643690.703*共30兲
SO2 CH3 OCH3
35共2,34兲⫺34共1,33兲 17共6,12兲⫺16共5,12兲 EA
4.0 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Gro02
643692.942*共18兲
CH3 OCH3
17共6,12兲⫺16共5,12兲 EE
3.1b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643694.402*共18兲
CH3 OCH3
17共6,11兲⫺16共5,12兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643696.707*共20兲
CH3 OCH3
17共6,11兲⫺16共5,12兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643696.853*共36兲
CH3 OCH3
17共6,11兲⫺16共5,12兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643697.411*共20兲
CH3 OCH3
17共6,11兲⫺16共5,12兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
643728.4 644185.9 644378.918 共30兲 645254.933 共30兲 645875.924 共30兲 645924.425*共66兲
unidentified unidentified SO SO SO CH3 OCH3
14共15兲⫺13共14兲 15共15兲⫺14共14兲 16共15兲⫺15共14兲 14共7,8兲⫺13共6,7兲 EA
2.3 3.5 33.9 39.6 39.0
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO
m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
COL01 COL01 COL01 Gro02
645926.788*共60兲
CH3 OCH3
14共7,8兲⫺13共6,7兲 EE
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
645928.115*共62兲
CH3 OCH3
14共7,8兲⫺13共6,7兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
645928.211*共62兲
CH3 OCH3
14共7,7兲⫺13共6,8兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
645929.104*共62兲
CH3 OCH3
14共7,8兲⫺13共6,7兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
645929.200*共62兲
CH3 OCH3
14共7,7兲⫺13共6,8兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
645930.527*共62兲
CH3 OCH3
14共7,7兲⫺13共6,8兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
645931.901*共66兲
CH3 OCH3
14共7,7兲⫺13共6,8兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646089.004*共16兲
CH3 OCH3
22共4,18兲⫺21共3,19兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646089.004*共16兲
CH3 OCH3
22共4,18兲⫺21共3,19兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646090.950*共14兲
CH3 OCH3
22共4,18兲⫺21共3,19兲 EE
2.5b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646092.896*共16兲
CH3 OCH3
22共4,18兲⫺21共3,19兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646211.382*共50兲
CH3 OCHO
20共15,6兲⫺19共14,6兲 E
2.3b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
646217.151*共43兲
CH3 OCHO
20共15,5兲⫺19共14,6兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
646217.151*共43兲
CH3 OCHO
20共15,6兲⫺19共14,5兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
646742.0 646762.451*共32兲
unidentified CH3 OCH3
1.9 30共4,27兲⫺29共3,26兲 AA
b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Gro02
646763.066*共26兲
CH3 OCH3
30共4,27兲⫺29共3,26兲 EE
1.9b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646763.681*共30兲
CH3 OCH3
30共4,27兲⫺29共3,26兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646763.681*共30兲
CH3 OCH3
30共4,27兲⫺29共3,26兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
646927.8 647081.739*共25兲 647196.312*共16兲
unidentified H2 CO CH3 OCH3
9共0,9兲⫺8共0,8兲 21共3,18兲⫺20共2,19兲 AE
1.8 21.9 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Gro02
647196.312*共16兲
CH3 OCH3
21共3,18兲⫺20共2,19兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647196.433*共14兲
CH3 OCH3
21共3,18兲⫺20共2,19兲 EE
2.1b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647202.553*共18兲
CH3 OCH3
21共3,18兲⫺20共2,19兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647319.8 647403.947*共74兲 647418.5 647447.624*共42兲
unidentified CH3 OH unidentified CH3 OCH3
12共⫺8,9兲⫺13共⫺7,6兲 E
1.9 3.4 2.8
35共2,33兲⫺34共3,32兲 AE
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
647447.624*共42兲
CH3 OCH3
35共2,33兲⫺34共3,32兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647448.034*共42兲 647448.445*共42兲
CH3 OCH3 CH3 OCH3
35共2,33兲⫺34共3,32兲 EE 35共2,33兲⫺34共3,32兲 AA
5.8c
OriMC⫺1 OriMC⫺1
CSO10.4 m CSO 10.4 m
Sch01 Sch01
Gro02 Gro02
SO2
34共7,27兲⫺34共6,28兲
5.8b 2.7
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1
CSO 10.4 m
Sch01
647448.527*共57兲 647546.759*共86兲
U U
U
33共3,31兲⫺32共2,30兲
b
10.4 10.4 10.4 10.4
Xu_97 Gro02
647610.50* 共17兲
SO2 CH3 OCH3
11共8,4兲⫺10共7,4兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647611.55* 共18兲
CH3 OCH3
11共8,4兲⫺10共7,4兲 EE
8.7b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647612.60* 共18兲
CH3 OCH3
11共8,3兲⫺10共7,4兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647612.60* 共18兲
CH3 OCH3
11共8,4兲⫺10共7,3兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647614.55* 共18兲
CH3 OCH3
11共8,3兲⫺10共7,4兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647614.55* 共18兲
CH3 OCH3
11共8,4兲⫺10共7,3兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647615.60* 共18兲
CH3 OCH3
11共8,3兲⫺10共7,3兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647618.60* 共18兲
CH3 OCH3
11共8,3兲⫺10共7,3兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
647717.214*共36兲 648119.8 648134.0 648324.397*共18兲
SO2 unidentified unidentified CH3 OCHO
15共4,12兲⫺14共3,11兲 v2 ⫽1
n.r.
OriMC⫺1
CSO 10.4 m
Sch01
6.4 5.2 5.8b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Oes99
648334.228*共40兲
CH3 OCHO
32共8,24兲⫺31共7,25兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
648381.517*共59兲
SO2
35共7,29兲⫺35共6,30兲 18共3,15兲⫺17共2,16兲
4.7 4.8
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
38共3,35兲⫺37共4,34兲
2.7 1.7 7.1
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
648737.545*共41兲 U
34
b
10.5b
10.4 10.4 10.4 10.4 10.4 10.4
648787.4 649052.199*共42兲 649104.5
34
SO2
unidentified SO2 unidentified
32共10,22兲⫺31共9,23兲 A
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
326
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
649172.407*共53兲 649225.606*共56兲
CH3 OCHO CH3 OCHO
18共16,2兲⫺17共15,2兲 E 18共16,3兲⫺17共15,3兲 E
3.6 3.2b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Oes99 Oes99
649226.808*共50兲
CH3 OCHO
18共16,2兲⫺17共15,3兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
649226.808*共50兲
CH3 OCHO
18共16,3兲⫺17共15,2兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
649236.244*共60兲 649540.341*共28兲 649915.23*共3兲
43共3,41兲⫺43共2,42兲 14共1,13兲⫺13共2,11兲 E
2.7 10.6
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
650374.186 共70兲 650534.1 650569.388*共6兲 650595.023*共84兲
SO2 CH3 OH NH2 D H2 S unidentified CH3 CH2 CN CH3 CH2 CN
2共0,2兲1共1兲⫺1共0,1兲1共1兲 4共4,1兲⫺4共3,2兲
1.3 15.9 3.0 2.1 2.5b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
JPL01 JPL01
650595.088*共84兲
CH3 CH2 CN
JPL01
650742.556*共13兲
U
33
SO2
U U U U U
U U
76共1,75兲⫺75共1,74兲
JPL01 JPL01
b
OriMC⫺1
CSO 10.4 m
Sch01
16共7,9兲⫺16共6,10兲
4.0
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
COL01 COL01
650956.35* 共35兲 651299.877*共16兲 651306.305*共55兲 651410.117*共53兲 651432.658*共38兲
SiO SO2 SO2 SO2 NO
15⫺14 v⫽0 10共5,5兲⫺9共4,6兲 32共7,25兲⫺32共6,26兲 18共3,15兲⫺17共2,16兲
21.8 32.0 11.3 20.7
J,F⫽6.5,6.5⫺5.5,5.5 e
15.5b
651433.023*共38兲
NO
J,F⫽6.5,7.5⫺5.5,6.5 e
b
OriMC⫺1
CSO 10.4 m
Sch01
651433.558*共38兲
NO
J,F⫽6.5,5.5⫺5.5,4.5 e
b
OriMC⫺1
CSO 10.4 m
Sch01
COL01
651494.023*共60兲 651535.9 651565.99*共5兲 651617.453*共18兲 652534.238*共29兲
SO unidentified DCN CH3 OH CH3 CH2 CN
11共11兲⫺11共10兲
2.0b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
COL01
9⫺8 10共1,9兲⫺9共0,9兲 E 73共13,61兲⫺72共13,60兲
4.7 5.7 5.5 12.0
652534.248*共29兲
CH3 CH2 CN
73共13,60兲⫺72共13,59兲
JPL01
10.4 10.4 10.4 10.4 10.4
10.4 10.4 10.4 10.4 10.4
Xu_97 JPL01
b
OriMC⫺1
CSO 10.4 m
Sch01
16共4,12兲⫺15共3,13兲
6.0
OriMC⫺1
CSO 10.4 m
Sch01
17共⫺1,17兲⫺16共0,16兲 E
3.4 2.4
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
653244.273*共14兲
CH3 OH CH3 OCH3
21共5,17兲⫺20共4,16兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
653244.294*共14兲
CH3 OCH3
21共5,17兲⫺20共4,16兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
653245.995*共12兲
CH3 OCH3
21共5,17兲⫺20共4,16兲 EE
1.1b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
653247.706*共16兲
CH3 OCH3
21共5,17兲⫺20共4,16兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
653320.506*共30兲
CH3 CH2 CN
73共11,63兲⫺72共11,62兲
1.9b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
653323.786*共30兲
CH3 CH2 CN
73共11,62兲⫺72共11,61兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
653535.4 653572.1 653598.0 653711.0 653882.923*共51兲 653931.4 653970.158*共22兲 654030.729*共32兲 654069.929*共22兲
unidentified unidentified unidentified unidentified SO2 unidentified H2 CO CH3 CH2 CN
31共7,25兲⫺31共6,26兲
1.3 1.2 0.9 2.7 5.5 3.2 13.5 2.0 4.9
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO CSO
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
654131.1 654341.801*共43兲 654396.9 654419.987*共33兲
unidentified CH3 OH unidentified
14共1,14兲⫺13共1,12兲 A⫹⫹
2.3 2.1 1.9 3.7
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
10.4 10.4 10.4 10.4
m m m m
Sch01 Sch01 Sch01 Sch01
30共7,23兲⫺30共6,24兲
6.6
OriMC⫺1
CSO 10.4 m
Sch01
652652.805*共38兲 U
34共8,27兲⫺33共7,26兲 76共2,75兲⫺75共2,74兲
10.4 10.4 10.4 10.4 10.4
652930. 653042.584*共12兲
34
SO2
unidentified 13
34
SO2
13
9共2,9兲⫺8共2,8兲 73共10,64兲⫺72共10,63兲 11共5,7兲⫺10共4,6兲 6共3,4兲⫺5共2,4兲 E vt ⫽1
654437.604*共48兲 654465.288*共74兲
CH3 OH SO2 H2 CO
9共7,2兲⫺8共7,1兲
b
OriMC⫺1
CSO 10.4 m
Sch01
654465.288*共74兲
H2 CO
9共7,3兲⫺8共7,2兲
OriMC⫺1
CSO 10.4 m
Sch01
CH3 CH2 CN unidentified H2 CO
40共7,34兲⫺39共6,33兲
U
654519.549*共6兲 654533.4 654838.292*共45兲
3.7b 2.1 2.0
9共6,3兲⫺8共6,2兲
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
H2 CO unidentified H2 CO
9共6,4兲⫺8共6,3兲
3.2
OriMC⫺1
CSO 10.4 m
Sch01
U
654838.292*共45兲 654993.4 655212.140*共34兲
3.1
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
9共5,5兲⫺8共5,4兲
655212.165*共34兲
H2 CO
9共5,4兲⫺8共5,3兲
655444.52* 共15兲 655639.815*共25兲
HNCO H2 CO
10共1,10兲⫺11共0,11兲 9共4,6兲⫺8共4,5兲
655643.733*共25兲
H2 CO
656075.381*共46兲 656164.713*共22兲 656168.882*共29兲 656464.585*共22兲
SO2 H2 CO CH3 OH H2 CO
656549.72*共12兲 656593.14* 共38兲
7.0b b
OriMC⫺1
CSO 10.4 m
Sch01
3.9 7.8b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
9共4,5兲⫺8共4,4兲
b
OriMC⫺1
CSO 10.4 m
Sch01
29共7,23兲⫺29共6,24兲 9共3,7兲⫺8共3,6兲 13共2,11兲⫺12共1,11兲 E
4.0 16.6 16.6
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
SO2
9共3,6兲⫺8共3,5兲 37共1,37兲⫺36共0,36兲
8.5 1.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
HNCO
30共1,30兲⫺29共1,29兲
2.5
OriMC⫺1
CSO 10.4 m
Sch01
34
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
JPL01
Xu_97 Xu_97
JPL01
JPL01
Xu_97
JPL01
MICROWAVE TRANSITIONS
327
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
656656.220*共55兲 656724.0 656760.435*共43兲 656900.677*共24兲
Formula
Quantum numbers
SO2 unidentified SO2
33共3,31兲⫺32共2,30兲
34
SO2 SO2
657222.569*共48兲
U
U
U
m m m m
Sch01 Sch01 Sch01 Sch01
10.4 10.4 10.4 10.4
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1
CSO 10.4 m
Sch01
CH3 OH
14共0,14兲⫺13共0,13兲 E
1.8
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
657455.18* 共24兲
13
14共6,8兲⫺13共6,7兲 A⫹⫹ vt ⫽1
17.3b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
657455.18* 共24兲
13
14共6,9兲⫺13共6,8兲 A⫺⫺ vt ⫽1
Xu_97
657721.9 657885.347*共41兲 657933.8 658006.55共20兲 658031.5 658101.932*共69兲 658217.358*共43兲
CH3 OH CH3 OH
H2 13CO unidentified SO2 unidentified H2 O unidentified CH3 OH 34
b
OriMC⫺1
CSO 10.4 m
Sch01
9共1,8兲⫺8共1,7兲
3.0
OriMC⫺1
CSO 10.4 m
Sch01
27共7,21兲⫺27共6,22兲
2.9 5.4 6.4
OriMC⫺1 OriMC⫺1 OriMC⫺1 VYCMa
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Men95
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
1共1,0兲⫺1共0,1兲 v2 ⫽1 19共2,18兲⫺18共3,15兲 A⫺⫺ 17共4,14兲⫺16共3,13兲
2760e 3.2 3.7 5.2b
10.4 10.4 10.4 10.4
Hel83 Xu_97
658218.51* 共11兲
SO2 SO2 SO2
33共3,31兲⫺32共2,30兲 v2 ⫽1 15共10,6兲⫺16共9,7兲
n.r.
658226.818*共24兲
5.2b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01
658466.639*共42兲
CH3 OCHO
21共15,6兲⫺20共14,7兲 A
3.8b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
658466.639*共42兲
CH3 OCHO
21共15,7兲⫺20共14,6兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
658541.616*共38兲 658553.275*共12兲
SO2
26共7,19兲⫺26共6,20兲 6⫺5
25.0 25.0
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
36共1,35兲⫺35共2,34兲
10.2 6.7
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
1.7b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
JPL01 Xu_97
30共0,30兲⫺29共0,29兲 14共1,13兲⫺13共1,12兲 A⫺⫺ vt ⫽1
2.2 1.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Xu_97
25共7,19兲⫺25共6,20兲 14共0,14兲⫺13共0,13兲 A⫹⫹
3.2 8.5 5.4
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97
37共1,37兲⫺36共0,36兲
9.9 9.9
40共1,39兲⫺40共0,40兲
10.1b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
b
OriMC⫺1
CSO 10.4 m
Sch01
2.7 3.5b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Xu_97
C18O SO2
658714.7 658742.875*共20兲
unidentified
658749.349*共47兲 658928.6 658945.76* 共54兲 658951.694*共35兲
SO2 unidentified HNCO
659188.8 659338.285*共35兲 659390.067*共32兲
33
SO2
13
CH3 OH
HNCO 13
CH3 OH unidentified SO2 13
16共4,12兲⫺15共3,13兲 18共3,15兲⫺17共2,16兲 v2 ⫽1 30共2,28兲⫺29共2,27兲 14共⫺1,14兲⫺13共⫺1,13兲 E
659421.061*共61兲 659495.2 659885.85* 共11兲
CH3 OH SO2 unidentified SO2
659898.524*共33兲
SO2
24共7,17兲⫺24共6,18兲
659989.199*共14兲
CH3 CH2 CN
56共6,51兲⫺55共5,50兲 14共⫺7,7兲⫺13共⫺7,6兲 E
6.9b n.r. 2.6 1.7
10.4 10.4 10.4 10.4
660040.22* 共13兲
13
660044.80* 共12兲
13
14共7,8兲⫺13共7,7兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
660115.139*共97兲
13
14共6,8兲⫺13共6,7兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
660115.139*共97兲
13
14共6,9兲⫺13共6,8兲 A⫹⫹
3.0b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
660458.514*共14兲
CH3 OH CH3 OCH3
21共5,16兲⫺20共4,17兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
660458.536*共14兲
CH3 OCH3
21共5,16兲⫺20共4,17兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
660460.183*共12兲
CH3 OCH3
21共5,16兲⫺20共4,17兲 EE
3.6b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
660461.841*共16兲
CH3 OCH3
21共5,16兲⫺20共4,17兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
660472.672*共30兲
SO2 CH3 CN
23共7,17兲⫺23共6,18兲 36共9兲⫺35共9兲 14共1,13兲⫺13共1,12兲 E
8.6 0.9 3.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97
2.8 2.2
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97
660593.533*共34兲 660673.637*共34兲 U
CSO CSO CSO CSO
13
658973.51* 共34兲 659065.39* 共13兲 U
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
3.8b 3.4
658631.749*共54兲 U
9.9 4.1 7.2 4.2
Lab. Ref.
657404.972*共38兲
657665.25* 共13兲
U
Astr. Ref.
36共1,35兲⫺35共2,34兲
33
48共3,45兲⫺48共2,46兲
Telescope
SO2
657331.618*共42兲
U
28共7,21兲⫺28共6,22兲 6共6,0兲⫺5共5,1兲
Source
T r 共K兲/T a 共K兲
660785.2 660806.420*共26兲
CH3 OH CH3 OH CH3 OH
13
CH3 OH
660811.488*共46兲
13
36共8兲⫺35共8兲 14共3,11兲⫺13共3,10兲 E
2.2b
OriMC⫺1 OriMC⫺1 OriMC⫺1
660866.698*共42兲
13
14共2,12兲⫺13共2,11兲 A⫹⫹
2.7
OriMC⫺1
CSO 10.4 m
Sch01
22共7,15兲⫺22共6,16兲 6⫺5
14.0 64.0
OriMC⫺1 OMC⫺IRc2
CSO 10.4 m JCMT 15 m
Sch01 Gra90 Sch01
660918.280*共27兲 661067.267*共8兲 661157.589*共14兲 661190.803*共22兲 661295.729*共12兲 661314.153*共33兲 661332.436*共25兲 661389.99* 共37兲 661408.829*共12兲 661496.843*共13兲 661510.830*共49兲 661559.736*共14兲
unidentified CH3 CN CH3 OH CH3 OH SO2
13 CO CH3 CN
36共6兲⫺35共6兲
4.7
OriMC⫺1
CSO 10.4 m
13
5共⫺2,4兲⫺4共⫺1,4兲 E
2.8
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
6.2
13
36共6兲⫺35共6兲 14共2,12兲⫺13共2,11兲 E
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
CH3 OH CH3 CN CH3 OH
SO2 HNCO CH3 CN CH3 CN SO2 CH3 CN
21共7,15兲⫺21共6,16兲 30共1,29兲⫺29共1,28兲 36共6兲⫺35共6兲 36共6兲⫺35共6兲 36共2,34兲⫺35共3,33兲 36共6兲⫺35共6兲
7.1b 11.5 2.3 2.8 6.4 6.4 5.7
10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m
JPL01
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
328
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Telescope
Astr. Ref.
CH3 CN
36共6兲⫺35共6兲
b
OriMC⫺1
CSO 10.4 m
Sch01
36共6兲⫺35共6兲
7.3b
OriMC⫺1
CSO 10.4 m
Sch01
661668.232*共23兲
SO2
20共7,13兲⫺20共6,14兲 14共⫺2,13兲⫺13共⫺2,12兲 E
11.9 2.8
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
11共5,7兲⫺10共4,6兲
b
OriMC⫺1
CSO 10.4 m
Sch01
661970.519*共74兲
U
Source
CH3 CN
661962.138*共20兲
U
T r 共K兲/T a 共K兲
661597.481*共15兲
661961.077*共15兲
U
Quantum numbers
661610.065*共16兲 661761.486*共37兲
U
Formula
13
CH3 OH 33
SO2 SO2
34
SO2
19共7,13兲⫺19共6,14兲 38共3,35兲⫺37共4,34兲
Lab. Ref.
Xu_97
OriMC⫺1
CSO 10.4 m
Sch01
b
OriMC⫺1
CSO 10.4 m
Sch01
1.6
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Gro02
11.2b
662087.2 662202.660*共18兲
unidentified SO2
18共7,11兲⫺18共6,12兲
662209.155*共22兲 662295.834*共58兲 662319.165*共30兲
H2 CO CH3 OH CH3 OCH3
9共2,7兲⫺8共2,6兲 16共⫺7,9兲⫺17共⫺6,11兲 E 18共6,13兲⫺17共5,12兲 EA
662320.580*共18兲
CH3 OCH3
18共6,13兲⫺17共5,12兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
662321.570*共16兲
CH3 OCH3
18共6,13兲⫺17共5,12兲 EE
4.5b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
662323.350*共20兲
CH3 OCH3
18共6,13兲⫺17共5,12兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
662404.206*共17兲
SO2
17共7,11兲⫺17共6,12兲
OriMC⫺1
CSO 10.4 m
Sch01
662414.468*共18兲
CH3 OCH3
18共6,12兲⫺17共5,13兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
662415.883*共28兲
CH3 OCH3
18共6,12兲⫺17共5,13兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
662416.247*共16兲
CH3 OCH3
18共6,12兲⫺17共5,13兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
662417.234*共20兲
CH3 OCH3
18共6,12兲⫺17共5,13兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
662566.840*共15兲
SO2
662697.531*共14兲 662799.378*共14兲 662876.878*共14兲 662933.488*共14兲 662972.711*共15兲
SO2 SO2 SO2 SO2 SO2
16共7,9兲⫺16共6,10兲 15共7,9兲⫺15共6,10兲 14共7,7兲⫺14共6,8兲 13共7,7兲⫺13共6,8兲 12共7,5兲⫺12共6,6兲
17.0 12.7 12.5 14.1 17.2
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
SO2
11共7,5兲⫺11共6,6兲 10共7,5兲⫺10共6,4兲
20.8
662997.653*共16兲
20.9b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
20.1b 20.1 2.2
15.7b
10.4 10.4 10.4 10.4 10.4
663011.199*共17兲
SO2
9共7,3兲⫺9共6,4兲
b
OriMC⫺1
CSO 10.4 m
Sch01
663014.271*共19兲
SO2
7共7,1兲⫺7共6,2兲
b
OriMC⫺1
CSO 10.4 m
Sch01
663015.955*共18兲
SO2
8共7,1兲⫺8共6,2兲
OriMC⫺1
CSO 10.4 m
Sch01
663639.1 663951.174*共8兲
unidentified CH3 CH2 CN
20共11,9兲⫺19共10,10兲
2.5b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01
663951.174*共9兲
CH3 CH2 CN
20共11,10兲⫺19共10,9兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
664404.656*共29兲 664449.276*共58兲
SO2 CH3 OCHO
20共3,17兲⫺20共0,20兲 17共17,0兲⫺16共16,1兲 A
4.8 6.5b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Oes99
664449.276*共58兲
CH3 OCHO
17共17,1兲⫺16共16,0兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
664456.345*共64兲
CH3 OCHO
17共17,1兲⫺16共16,1兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
664682.800*共9兲
CH3 CH2CN
15共12,3兲⫺14共11,4兲
3.3b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
664682.800*共9兲
CH3 CH2CN
15共12,4兲⫺14共11,3兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
664760.274*共70兲 664780.9 664815.519*共62兲
SO2 unidentified CH3 OCH3
44共2,42兲⫺44共1,43兲
2.6 3.5
15共7,9兲⫺14共6,8兲 EA
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Gro02
664817.757*共56兲
CH3 OCH3
15共7,9兲⫺14共6,8兲 EE
6.7b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
664818.998*共58兲
CH3 OCH3
15共7,9兲⫺14共6,8兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
664819.240*共58兲
CH3 OCH3
15共7,8兲⫺14共6,9兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
664819.880*共58兲
CH3 OCH3
15共7,9兲⫺14共6,8兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
664820.112*共58兲
CH3 OCH3
15共7,8兲⫺14共6,9兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
664821.363*共58兲
CH3 OCH3
15共7,8兲⫺14共6,9兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
664822.720*共62兲
CH3 OCH3
15共7,8兲⫺14共6,9兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
665203.684*共23兲
SO2
25共12,14兲⫺26共11,15兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
665246.825*共25兲
SO2
16共4,12兲⫺15共3,13兲
20.4b
OriMC⫺1
CSO 10.4 m
Sch01
665393.738 共70兲
H2 S CH3 OH CH3 OCHO CH3 OCHO unidentified
4共2,2兲⫺4共1,3兲 5共⫺2,4兲⫺4共⫺1,4兲 E 56共7,49兲⫺55共7,48兲 A 55共9,47兲⫺54共9,46兲 A
8.6 19.6 2.3 3.0 3.4
CSO CSO CSO CSO CSO CSO
m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
JPL01 Xu_97 JPL01 JPL01
20.9b 2.2
6共6,0兲⫺5共5,1兲
5.3b
666417.650*共15兲
33 SO2 CH3 CH2 CN
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
20共15,5兲⫺20共14,6兲
2.0b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666417.650*共15兲
CH3 CH2 CN
20共15,6兲⫺20共14,7兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666441.8*共11兲
CH3 OCHO
58共5,53兲⫺57共6,52兲 A
5.2b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666441.8*共11兲
CH3 OCHO
58共6,53兲⫺57共6,52兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666441.9*共11兲
CH3 OCHO
58共5,53兲⫺57共5,52兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666441.9*共11兲
CH3 OCHO
58共6,53兲⫺57共5,52兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666517.656*共15兲
CH3 CH2 CN
22共15,7兲⫺22共14,8兲
2.0b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666517.656*共15兲
CH3 CH2 CN
22共15,8兲⫺22共14,9兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
665442.393*共15兲 665509.0*共12兲 665568.7*共11兲 665814.5 666382.012*共15兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
10.4 10.4 10.4 10.4 10.4 10.4
MICROWAVE TRANSITIONS
329
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
666550.75* 共17兲
CH3 OCH3
12共8,4兲⫺11共7,5兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
CH3 OCH3
12共8,5兲⫺11共7,4兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
666556.82* 共17兲
CH3 OCH3
12共8,5兲⫺11共7,4兲 EE
5.3b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
666557.81* 共17兲
CH3 OCH3
12共8,4兲⫺11共7,5兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
666557.81* 共17兲
CH3 OCH3
12共8,5兲⫺11共7,4兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
666559.76* 共17兲
CH3 OCH3
12共8,4兲⫺11共7,5兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
666559.76* 共17兲
CH3 OCH3
12共8,5兲⫺11共7,4兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
666563.69* 共18兲
CH3 OCH3
12共8,4兲⫺11共7,5兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
666623.499*共14兲
CH3 CH2 CN
24共15,10兲⫺24共14,11兲
1.7b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
666623.499*共14兲
CH3 CH2 CN
24共15,9兲⫺24共14,10兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
8共1,8兲⫺7共0,7兲 A⫹⫹
4.7
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
666821.3 666907.496*共14兲
CH3 OH unidentified CH3 CH2 CN
2.5 29共15,14兲⫺29共14,15兲
3.0b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01
666907.496*共14兲
CH3 CH2 CN
29共15,15兲⫺29共14,16兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
667026.135*共14兲
CH3 CH2 CN
31共15,16兲⫺31共14,17兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
667026.135*共14兲
CH3 CH2 CN
31共15,17兲⫺31共14,18兲
3.5b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
667146.786*共36兲
CH3 OH
10共5,6兲⫺11共4,7兲 A⫹⫹
7.5b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13
667147.451*共36兲
CH3 OH
10共5,5兲⫺11共4,8兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
667471.065*共37兲 667498.072*共31兲 667717.693*共12兲
CH3 OCHO CH3 OH CH3 CH2 CN
24共14,10兲⫺23共13,10兲 E 6共4,2兲⫺7共3,4兲 E 43共15,28兲⫺43共14,29兲
4.8 6.7 2.0b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Oes99 Xu_97 JPL01
667717.693*共12兲
CH3 CH2 CN
43共15,29兲⫺43共14,30兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
667948.102*共11兲
CH3 CH2 CN
48共15,33兲⫺48共14,34兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
667948.102*共11兲
CH3 CH2 CN
48共15,33兲⫺48共14,34兲
2.7b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
668077.63* 共39兲
CH3 OCH3
9共9,0兲⫺8共8,1兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668077.63* 共39兲
CH3 OCH3
9共9,1兲⫺8共8,0兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668078.44* 共39兲
CH3 OCH3
9共9,1兲⫺8共8,1兲 EE
5.8b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668079.25* 共39兲
CH3 OCH3
9共9,1兲⫺8共8,1兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668081.85* 共39兲
CH3 OCH3
9共9,0兲⫺8共8,0兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668082.66* 共39兲
CH3 OCH3
9共9,0兲⫺8共8,1兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668082.66* 共39兲
CH3 OCH3
9共9,1兲⫺8共8,0兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668086.07* 共40兲
CH3 OCH3
9共9,0兲⫺8共8,0兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
668116.889*共58兲
18共0,18兲⫺17共1,16兲 E 22共5,18兲⫺21共4,17兲 EA
4.8
669407.635*共16兲
CH3 OH CH3 OCH3
b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Gro02
669407.646*共16兲
CH3 OCH3
22共5,18兲⫺21共4,17兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669408.150*共14兲
CH3 OCH3
22共5,18兲⫺21共4,17兲 EE
2.1b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669409.660*共18兲
CH3 OCH3
22共5,18兲⫺21共4,17兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669490.5*共11兲
CH3 OCH3
36共12,25兲⫺36共11,26兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669491.0*共11兲
CH3 OCH3
36共12,24兲⫺36共11,25兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669491.0*共11兲
CH3 OCH3
36共12,25兲⫺36共11,26兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669491.5*共11兲
CH3 OCH3
36共12,25兲⫺36共11,26兲 EE
2.7b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669491.6*共11兲
CH3 OCH3
36共12,24兲⫺36共11,25兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669492.1*共11兲
CH3 OCH3
36共12,24兲⫺36共11,25兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669492.6*共11兲
CH3 OCH3
36共12,24兲⫺36共11,25兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
669492.6*共11兲
CH3 OCH3
36共12,25兲⫺36共11,26兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670011.3 670096.4*共12兲
unidentified CH3 OCH3
2.4 34共12,23兲⫺34共11,24兲 EA
b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Gro02
670097.0*共12兲
CH3 OCH3
34共12,22兲⫺34共11,23兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670097.0*共12兲
CH3 OCH3
34共12,23兲⫺34共11,24兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670097.1*共12兲
CH3 OCH3
34共12,23兲⫺34共11,24兲 EE
5.5b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670097.6*共12兲
CH3 OCH3
34共12,22兲⫺34共11,23兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670097.7*共12兲
CH3 OCH3
34共12,22兲⫺34共11,23兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670097.8*共12兲
CH3 OCH3
34共12,22兲⫺34共11,23兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670097.8*共12兲
CH3 OCH3
34共12,23兲⫺34共11,24兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
670365.886*共17兲 670422.699*共13兲 670499.623*共6兲
SO2 CH3 OH CH3 CH2 CN
11共5,7兲⫺10共4,6兲 14共1,14兲⫺13共1,13兲 A⫹⫹ 31共9,23兲⫺30共8,22兲
17.8 9.7 2.6b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 JPL01
670499.648*共6兲
CH3 CH2 CN
670756.616*共24兲 U U U
Quantum numbers
666555.83* 共17兲
666706.044*共24兲 U
Formula
13
31共9,22兲⫺30共8,23兲 4共2,3兲⫺3共1,2兲 A⫺⫺
670852.2 670894.5 671408.4 671480.79*共10兲
CH3 OH unidentified unidentified unidentified CH3 OH
18共8,10兲⫺19共7,13兲 A⫹⫹
671480.79*共10兲
CH3 OH
18共8,11兲⫺19共7,12兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
3.1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
5.3 3.3 3.1 4.1b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
10.4 10.4 10.4 10.4
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
330
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
U
671716.8 671912.639*共16兲 672184.351*共27兲
13
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
10共0,10兲⫺9共1,9兲 E vt ⫽1 11共0,11兲⫺10共⫺1,10兲 E
1.7 2.2 1.7
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97
2.9 1.9 13.5 6.2 b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97 Gro02
672360.692*共67兲 672447.3 672564.481*共27兲 672902.595*共31兲 672903.763*共18兲
unidentified SO2 CH3 OH CH3 OCH3
17共4,14兲⫺16共3,13兲 17共⫺1,17兲⫺16共0,16兲 E 23共4,19兲⫺22共3,20兲 AE
672903.763*共18兲
CH3 OCH3
23共4,19兲⫺22共3,20兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
672905.587*共16兲
CH3 OCH3
23共4,19兲⫺22共3,20兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
672907.411*共18兲
CH3 OCH3
23共4,19兲⫺22共3,20兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
673072.1 673101.436*共25兲
unidentified
4.0 5.0
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
673415.979*共10兲 673559.9 673675.449*共40兲
CH3 OH unidentified CH3 OH
8.8 2.5
14共6,9兲⫺13共6,8兲 A⫺⫺ vt ⫽1
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97
673676.690*共48兲
CH3 OH
14共3,12兲⫺13共3,11兲 E vt ⫽1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
673712.993*共50兲 673746.070*共18兲
CH3 OCHO CH3 OH CH3 OH
20共16,4兲⫺19共15,4兲 E
4.3b 2.7
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
9.9
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Sch01
19共2,17兲⫺18共3,16兲 A⫹⫹
12共5,7兲⫺11共4,8兲
34
SO2
14共0,14兲⫺13共0,13兲 E
3.8b
673991.85* 共12兲
34
38共0,38兲⫺37共1,37兲
6.6b
OriMC⫺1
CSO 10.4 m
Sch01
673997.113*共92兲
34
35共3,33兲⫺34共2,32兲
b
OriMC⫺1
CSO 10.4 m
Sch01
兲
674016.903*共23兲 674143.586*共37兲
SO2 SO2
4共2,3兲⫺3共1,2兲 A⫺⫺ 14共⫺4兲⫺13共⫺4兲 E vt ⫽2
b
10.4 10.4 10.4 10.4 10.4
OriMC⫺1 OriMC⫺1
674009.290*共12兲
Xu_97
Xu_97
C17O CH3 OH
6⫺5
6.6
OriMC⫺1
CSO 10.4 m
Sch01
14共1,14兲⫺13共1,13兲 A⫹⫹ vt ⫽1
6.6b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
14共⫺7,8兲⫺13共⫺7,7兲 E vt ⫽1 14共⫺2兲⫺13共⫺2兲 E vt ⫽2
1.8 1.7b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Sch01
674162.1*共
兲
CH3 OH CH3 OH
674162.4*共
兲
CH3 OH
14共4兲⫺13共4兲 A⫺⫺ vt ⫽2
b
OriMC⫺1
CSO 10.4 m
Sch01
Sch01
674196.5*共
兲
CH3 OH
14共0兲⫺13共0兲 A⫹⫹ vt ⫽2
1.4b
OriMC⫺1
CSO 10.4 m
Sch01
Sch01
674201.8*共
兲
CH3 OH
14共3兲⫺13共3兲 E vt ⫽2
b
OriMC⫺1
CSO 10.4 m
Sch01
Sch01
CH3 OH unidentified
14共⫺1兲⫺13共⫺1兲 E vt ⫽2
1.2 2.0 3.9
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Sch01
14共⫺2,12兲⫺13共⫺2,11兲 E vt ⫽1 14共7,7兲⫺13共7,6兲 A⫺⫺ vt ⫽1
3.2 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
1.4b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
674254.4*共 兲 674284.5 674473.75* 共12兲
14⫺13
674513.023*共26兲 674597.336*共36兲
C34S CH3 OH CH3 OH
674597.336*共36兲
CH3 OH
14共7,8兲⫺13共7,7兲 A⫹⫹ vt ⫽1
674617.103*共33兲
CH3 OH
14共5,10兲⫺13共5,9兲 A⫹⫹ vt ⫽1
674617.103*共33兲
CH3 OH
14共5,9兲⫺13共5,8兲 A⫺⫺ vt ⫽1
2.5b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
674659.227*共24兲
CH3 OH
14共4,11兲⫺13共4,10兲 E vt ⫽1
3.8b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
11共3,9兲⫺10共0,10兲
3.8b
OriMC⫺1
CSO 10.4 m
Sch01
674710.166*共22兲
SO2 CH3 OH
14共2,12兲⫺13共2,11兲 A⫹⫹ vt ⫽1
4.0b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
674717.329*共21兲
CH3 OH
14共⫺3,11兲⫺13共⫺3,10兲 E vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
674743.033*共23兲
14共0,14兲⫺13共0,13兲 E vt ⫽1 14共1,14兲⫺13共1,13兲 E vt ⫽1
6.4
674762.330*共23兲
CH3 OH CH3 OH
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
674791.038*共22兲
CH3 OH
14共2,13兲⫺13共2,12兲 A⫺⫺ vt ⫽1
CSO 10.4 m
Sch01
Xu_97
9共1,8兲⫺8共1,7兲
OriMC⫺1
CSO 10.4 m
Sch01
17.1
675034.787*共23兲
H2 CO CH3 OH CH3 OH
6.6b 16.2
OriMC⫺1
674809.776*共24兲 674990.446*共19兲
3.5b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
675049.360*共27兲
CH3 OH
14共2,13兲⫺13共2,12兲 E vt ⫽1
3.7b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
675097.889*共36兲
CH3 OH CH3 OH
14共⫺1,13兲⫺13共⫺1,12兲 E vt ⫽1 14共⫺1,14兲⫺13共⫺1,13兲 E
4.5 12.9b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
3共3,0兲⫺2共2,0兲 E
12.9b
674667.793*共28兲
675134.556*共10兲 675134.994*共32兲
34
8共1,8兲⫺7共0,7兲 A⫹⫹ 14共3,12兲⫺13共3,11兲 A⫹⫹ vt ⫽1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
14共0,14兲⫺13共0,13兲 A⫹⫹ vt ⫽1 14共⫺5,10兲⫺13共⫺5,9兲 E vt ⫽1 17共16兲⫺16共15兲
4.3 2.9 6.6
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Mul01
14共1,13兲⫺13共1,12兲 A⫺⫺ vt ⫽1 4共2,2兲⫺3共1,3兲 A⫹⫹
4.6
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 JPL01 Xu_97
CH3 OH
CH3 OH
14共⫺4,10兲⫺13共⫺4,9兲 E
675176.196*共53兲 675232.847*共44兲 675312.868 共50兲
CH3 OH CH3 OH
675555.336*共24兲
34 SO CH3 OH 13
7.5b
b
13
675145.256*共29兲
675347.374*共32兲
U
unidentified CH3 OH
Quantum numbers
CH3 OH CH3 OH
673969.6*共
U
Formula
4.6b 8.8 2.3
675612.646*共10兲 675654.3*共13兲 675773.382*共20兲
CH3 OH CH3 OH CH3 OCHO CH3 OH
8.8b
OriMC⫺1 OriMC⫺1 OriMC⫺1
675779.760*共56兲
CH3 OH
14共4,11兲⫺13共4,19兲 A⫺⫺ vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
675779.771*共56兲
CH3 OH
14共4,10兲⫺13共4,9兲 A⫹⫹ vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
675888.668*共62兲
CH3 OH CH3 OH unidentified
14共5,9兲⫺13共5,8兲 E vt ⫽1 14共⫺10,4兲⫺13共⫺10,3兲 E
5.6 3.7 3.7 5.5b
CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97
7共6,2兲⫺6共5,1兲
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
675959.046*共37兲 675984.0 676010.725*共23兲
14共0,14兲⫺13共0,13兲 E 56共8,48兲⫺55共9,47兲 A 3共3,0兲⫺2共2,0兲 E
34
SO2
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
10.4 10.4 10.4 10.4
m m m m
MICROWAVE TRANSITIONS
331
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
U
U
U U U U U
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
676015.716*共38兲 676021.454*共53兲 676031.965*共27兲 676112.113*共29兲
CH3 OH SO2 CH3 OH CH3 OCHO
14共9,6兲⫺13共9,5兲 E 22共7,15兲⫺22共6,16兲 v2 ⫽1 14共⫺9,5兲⫺13共⫺9,4兲 E 27共13,15兲⫺26共12,14兲 A
5.5 n.r. 4.8
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97
4.2b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
10.4 10.4 10.4 10.4
Xu_97 Oes99
676112.121*共29兲
CH3 OCHO
27共13,14兲⫺26共12,15兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
676120.180*共27兲
CH3 OH
14共9,5兲⫺13共9,4兲 A⫺⫺
3.1b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676120.180*共27兲
CH3 OH
14共9,6兲⫺13共9,5兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676138.986*共25兲 676205.311*共21兲
CH3 OH CH3 OH
14共⫺8,6兲⫺13共⫺8,5兲 E 14共8,6兲⫺13共8,5兲 A⫺⫺
4.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
676205.311*共21兲
CH3 OH
14共8,7兲⫺13共8,6兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676215.016*共11兲
CH3 OH
14共2,13兲⫺13共2,12兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676250.436*共21兲 676269.636*共19兲
CH3 OH CH3 OH
14共8,7兲⫺13共8,8兲 E 14共7,7兲⫺13共7,6兲 A⫺⫺
4.7 7.3b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
676269.636*共19兲
CH3 OH
14共7,8兲⫺13共7,7兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676349.551*共17兲 676361.695*共17兲
CH3 OH CH3 OH
14共⫺7,7兲⫺13共⫺7,6兲 E 14共7,8兲⫺13共7,7兲 E
6.6 6.9b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
676416.064*共15兲
CH3 OH
14共6,9兲⫺13共6,8兲 E
10.6b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676425.685*共15兲
CH3 OH
14共6,8兲⫺13共6,7兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676425.685*共15兲
CH3 OH
14共6,9兲⫺13共6,8兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676484.356*共16兲
SO2
6共6,0兲⫺5共5,1兲
20.0b
OriMC⫺1
CSO 10.4 m
Sch01
676494.608*共13兲
CH3 OH
14共5,10兲⫺13共5,9兲 E
20.0b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676496.553*共15兲
CH3 OH
14共⫺6,8兲⫺13共⫺6,7兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676499.322*共63兲
CH3 OH
19共0,19兲⫺18共1,18兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676585.326*共11兲
CH3 OH
14共⫺4,11兲⫺13共⫺4,10兲 E
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676591.277*共13兲
CH3 OH
14共⫺5,9兲⫺13共⫺5,8兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676604.244*共13兲
CH3 OH
14共5,10兲⫺13共5,9兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676604.250*共13兲
CH3 OH
14共5,9兲⫺13共5,8兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
676677.658*共12兲 676712.384*共11兲 676749.459*共10兲 676823.527*共11兲
CH3 OH CH3 OH CH3 OH CH3 OH
14共5,10兲⫺13共5,9兲 E 14共⫺3,12兲⫺13共⫺4,11兲 E 14共3,12兲⫺13共3,11兲 A⫹⫹
9.1 10.0 13.2
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
14共4,10兲⫺13共4,9兲 A⫹⫹
14.9b
676829.563*共10兲
CH3 OH
14共3,11兲⫺13共3,10兲 A⫺⫺
676926.632*共64兲 677012.842*共11兲
SO2 CH3 OH unidentified CH3 OH CH3 OH unidentified CH3 OH
677112.4 677190.542*共10兲 677233.266*共11兲 677273.0 677417.5*共 兲 677509.53* 共38兲
30
14.5b
11.1b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
38共0,38兲⫺37共1,37兲
7.7
OriMC⫺1
CSO 10.4 m
Sch01
14共1,13兲⫺13共1,12兲 E
18共1兲⫺17共0兲 E vt ⫽2
12.2 2.8 12.1 12.1 3.6 3.5
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO
m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
15⫺14 v⫽0
3.5
OriMC⫺1
CSO 10.4 m
Sch01
3.6 14.1 n.r. 2.9 n.r.
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
10.4 10.4 10.4 10.4 10.4
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
3.4 2.9 n.r. 6.7 12.5
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO
10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97
14共3,11兲⫺13共3,10兲 E 14共2,12兲⫺13共2,11兲 A⫹⫹
10.4 10.4 10.4 10.4 10.4 10.4
Xu_97 Xu_97 Xu_97 Sch01
678005.984*共32兲 678054.630*共40兲 678128.276*共57兲 678237.50*共15兲 678252.591*共11兲
SiO unidentified CH3 OH SO2 unidentified SO2 SO2 CH3 OCHO SO2 SO2 HNCO CH3 OH
678358.0 678417.7 678452.00* 共42兲 678546.9 678676. 678710.4 678785.460*共17兲 679341.014*共52兲
unidentified unidentified HNCO unidentified unidentified unidentified CH3 OH CH3 OH
4共2,2兲⫺3共1,3兲 A⫹⫹ 9共6,4兲⫺10共5,5兲 A⫺⫺
679341.015*共52兲
CH3 OH
9共6,3兲⫺10共5,6兲A⫹⫹
9.5b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
679392.977*共6兲
CH3 CH2 CN
32共9,24兲⫺31共8,23兲
3.4b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
679393.020*共6兲
CH3 CH2 CN
32共9,23兲⫺31共8,24兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
679482.315*共15兲 679554.483*共23兲
CH3 CN
37共6兲⫺36共6兲
3.6
OriMC⫺1
CSO 10.4 m
Sch01
13 CH3 OH CH3 OCHO
9共3,7兲⫺8共2,6兲A⫹⫹
6.6
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
679683.926*共34兲
25共14,11兲⫺24共13,12兲A
2.2b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
679683.926*共34兲
CH3 OCHO
25共14,12兲⫺24共13,11兲A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
679683.962*共37兲
CH3 OCHO
25共14,12兲⫺24共13,12兲E
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
677567.6 677709.778*共11兲 677885.802*共33兲 677919.9 677961.696*共35兲 677984.726*共13兲
14共2,12兲⫺13共2,11兲 E 14共7,7兲⫺14共6,8兲 v2 ⫽1 13共7,7兲⫺13共6,6兲 v2 ⫽1 41共2,40兲⫺41共1,41兲 32共11,21兲⫺31共10,22兲 A 11共7,5兲⫺11共6,6兲 v2 ⫽1 37共2,36兲⫺36共1,35兲 9共1,9兲⫺10共0,10兲 14共⫺2,13兲⫺13共⫺2,12兲 E
31共1,31兲⫺30共1,30兲
12.5b 2.0 4.3 1.7 3.6 6.1 3.3 21.8
Xu_97
Oes99
JPL01 Xu_97
JPL01
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
332
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued
U
Frequency 共Unc.兲 共MHz兲
Formula
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
679740.320*共13兲 679760.8 679790.951*共16兲
CH3 CN unidentified CH3 OCH3
37共4兲⫺36共4兲
4.5 3.7
22共5,17兲⫺21共4,18兲AE
b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Gro02
679790.962*共16兲
CH3 OCH3
22共5,17兲⫺21共4,18兲EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
679792.422*共14兲
CH3 OCH3
22共5,17兲⫺21共4,18兲EE
4.4b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
679793.837*共18兲
CH3 OCH3
22共5,17兲⫺21共4,18兲AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
679830.703*共14兲 679895.289*共15兲 679934.051*共16兲
CH3 CN CH3 CN CH3 CN
37共3兲⫺36共3兲 37共2兲⫺36共2兲 37共1兲⫺36共1兲
4.7 5.7 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
679946.974*共17兲
CH3 CN
37共0兲⫺36共0兲
7.7b
OriMC⫺1
CSO 10.4 m
Sch01
9共3,6兲⫺8共2,7兲A⫺⫺
9.2b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
6⫺5 J,F⫽11/2,11/2⫺9/2,11/2
0.41
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
4.4 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01
0.41b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
2.9 2.4
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
JPL01 JPL01 JPL01
680000.110*共22兲
13
CH3 OH
680026.757*共38兲 U
680247.8 680264.1共3兲
unidentified CN
6⫺5 J,F⫽11/2,11/2⫺9/2,9/2
680264.1共3兲
CN
6⫺5 J,F⫽11/2,13/2⫺9/2,11/2
680264.1共3兲
CN
680480.820*共77兲 680506.930*共77兲 680575.04* 共54兲
CH3 CH2 CN CH3 CH2 CN HNCO
6⫺5 J,F⫽11/2,9/2⫺9/2,7/2 78共4,75兲⫺77共4,74兲 78共3,75兲⫺77共3,74兲 31共3,29兲⫺30共3,28兲
680575.42* 共54兲
HNCO
31共3,28兲⫺30共3,27兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
680787.00* 共64兲 680800.48* 共14兲
HNCO CH3 OH
31共2,30兲⫺30共2,29兲 22共1,21兲⫺21共2,20兲 A⫺⫺
8.1
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Xu_97
680841.350*共6兲
CH3 CH2 CN
680889.64* 共59兲 680906.12* 共38兲 680923.690*共22兲
HNCO HNCO CH3 OCH3
43共7,36兲⫺42共6,37兲 31共2,29兲⫺30共2,28兲 31共0,31兲⫺30共0,30兲 19共6,14兲⫺18共5,13兲 EA
2.4 4.2 7.9 b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
JPL01 JPL01 JPL01 Gro02
680924.383*共18兲
CH3 OCH3
19共6,14兲⫺18共5,13兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
680925.462*共14兲
CH3 OCH3
19共6,14兲⫺18共5,13兲 EE
7.2b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
680926.899*共20兲
CH3 OCH3
19共6,14兲⫺18共5,13兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
680967.554*共50兲
CH3 OCHO
3.5 2.8
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Oes99
681089.871*共18兲
SO2 CH3 OCH3
36共10,27兲⫺35共9,26兲 A 12共5,7兲⫺11共4,8兲 19共6,13兲⫺18共5,14兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
681090.564*共22兲
CH3 OCH3
19共6,13兲⫺18共5,14兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
681091.304*共16兲 681092.379*共20兲
CH3 OCH3 CH3 OCH3
19共6,13兲⫺18共5,14兲 EE 19共6,13兲⫺18共5,14兲 AA
5.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Gro02 Gro02
681674.029*共59兲
SO2
681789.670*共78兲 681913.128*共8兲
CH3 OH CH3 CH2 CN
35共3,33兲⫺34共2,32兲 3共⫺2,1兲⫺4共⫺3,1兲 E vt ⫽1 22共11,11兲⫺21共10,12兲
7.8 14.2 1.5b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 JPL01
681913.128*共8兲
CH3 CH2 CN
22共11,12兲⫺21共10,11兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
681946.108*共59兲
CH3 CH2 CN CH3 OH unidentified
76共9,68兲⫺75共9,67兲 14共1,13兲⫺13共1,12兲 A⫺⫺
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01
JPL01 Xu_97
26共2,24兲⫺25共3,22兲 E
3.5 20.2 3.0 4.4
681012.756*共15兲
U
681989.818*共11兲 682092.3 682370.93* 共97兲
U U
33
13
CH3 OH
1.0b
8.1b
b
10.4 10.4 10.4 10.4
10.4 10.4 10.4 10.4
m m m m
Xu_97
16⫺15
0.9
OriMC⫺1
CSO10.4m
Sch01
682583.747*共61兲 682901.025*共42兲 682938.629*共37兲
HCS⫹ CH3 CH2 CN CH3 OCHO CH3 OCHO
76共9,69兲⫺75共9,68兲 23共15,8兲⫺22共14,8兲 E 23共15,8兲⫺22共14,9兲 E
3.5 1.7 2.2b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
JPL01 Oes99 Oes99
682938.629*共37兲
CH3 OCHO
23共15,9兲⫺22共14,8兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
682938.890*共43兲
CH3 OCHO
23共15,9兲⫺22共14,9兲 E
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
683170.8 683407.59* 共41兲 683476.8 683510.6 683686.228*共58兲
unidentified HNCO unidentified unidentified CH3 OCH3
2.8 3.6 4.4 4.6
16共7,10兲⫺15共6,9兲 EA
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
683688.326*共54兲
CH3 OCH3
16共7,10兲⫺15共6,9兲 EE
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
683689.409*共54兲
CH3 OCH3
16共7,10兲⫺15共6,9兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
683689.972*共54兲
CH3 OCH3
16共7,9兲⫺15共6,10兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
683690.176*共54兲
CH3 OCH3
16共7,10兲⫺15共6,9兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
683690.740*共54兲
CH3 OCH3
16共7,9兲⫺15共6,10兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
683691.823*共54兲
CH3 OCH3
16共7,9兲⫺15共6,10兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
683693.153*共58兲
CH3 OCH3
16共7,9兲⫺15共6,10兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
683749.819*共21兲
CH3 OH
12共⫺2,11兲⫺11共1,10兲 E
6.2b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
683761.077*共37兲
CH3 OCHO
30共12,18兲⫺29共11,18兲 E
3.9b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
683770.816*共28兲
CH3 OCHO
30共12,19兲⫺29共11,18兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
683773.681*共28兲
CH3 OCHO
30共12,18兲⫺29共11,19兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
683961.110*共16兲
CH3 CH2 CN
80共1,79兲⫺79共1,78兲
2.0
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
682436.0*共4兲
U
CN
31共1,30兲⫺30共1,29兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
b
11.1b
10.4 10.4 10.4 10.4 10.4
JPL01
Gro02
MICROWAVE TRANSITIONS
333
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U U
684261.68* 共16兲 684296.1 684430.0 684677.95* 共12兲
Formula
Quantum numbers
CH3 OH unidentified unidentified
25共⫺3,23兲⫺24共⫺4,21兲 E
6.1 3.9 6.6 4.9
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97
10.4 10.4 10.4 10.4
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
684839.646*共18兲
CH3 OCH3
23共5,19兲⫺22共4,18兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
684840.937*共16兲
CH3 OCH3
23共5,19兲⫺22共4,18兲 EE
4.4b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
684842.231*共18兲
CH3 OCH3
23共5,19兲⫺22共4,18兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
684928.743*共81兲
45共3,43兲⫺45共2,44兲 22共3,19兲⫺21共2,20兲 AE
3.7
685336.603*共18兲
SO2 CH3 OCH3
b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Gro02
685336.603*共18兲
CH3 OCH3
22共3,19兲⫺21共2,20兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685339.833*共16兲
CH3 OCH3
22共3,19兲⫺21共2,20兲 EE
1.9b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685343.063*共20兲
CH3 OCH3
22共3,19兲⫺21共2,20兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685436.00* 共10兲 685494.47* 共16兲
CS CH3 OCH3
14⫺13 13共8,6兲⫺12共7,6兲 EA
25.0 b
OriMC⫺1 OriMC⫺1
JCMT 15 m CSO 10.4 m
Har95 Sch01
Gro02
685495.40* 共16兲
CH3 OCH3
13共8,6兲⫺12共7,6兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685496.33* 共16兲
CH3 OCH3
13共8,5兲⫺12共7,6兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685496.33* 共16兲
CH3 OCH3
13共8,6兲⫺12共7,5兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685498.27* 共16兲
CH3 OCH3
13共8,5兲⫺12共7,6兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685498.27* 共16兲
CH3 OCH3
13共8,6兲⫺12共7,5兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685499.20* 共16兲
CH3 OCH3
13共8,5兲⫺12共7,5兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685502.07* 共16兲
CH3 OCH3
13共8,5兲⫺12共7,5兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685505.010*共19兲
CH3 OH CH3 OH
11共0,11兲⫺10共⫺1,10兲 E 11共0,11兲⫺10共⫺1,10兲 E
18.0
OriMC⫺1 OriMC⫺1
JCMT 15 m CSO 10.4 m
Har95 Sch01
Xu_97 Xu_97
29
SiO
16⫺15 v⫽0
19.8b 2.5
OriMC⫺1
CSO 10.4 m
Sch01
3.8b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
JPL01 Oes99 Oes99
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
19共4,16兲⫺18共3,15兲
3.6
OriMC⫺1
CSO 10.4 m
Sch01
9共3,7兲⫺8共2,6兲 A⫹⫹
21.9
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
24.5 b
OriMC⫺1 OriMC⫺1
JCMT 15 m CSO 10.4 m
Har95 Sch01
Xu_97 Gro02
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
685976.069*共48兲 686019.616*共43兲
CH3 CH2 CN CH3 OCHO CH3 OCHO
38共8,30兲⫺37共7,31兲 21共16,5兲⫺20共15,5兲 E 21共16,5兲⫺20共15,6兲 E
3.0 3.8
686019.616*共43兲
CH3 OCHO
21共16,6兲⫺20共15,5兲 E
686022.823*共50兲
CH3 OCHO
21共16,6兲⫺20共15,6兲 E
686678.926*共53兲 686731.459*共15兲 686731.459*共15兲
34
SO2 CH3 OH CH3 OH
687035.02* 共38兲
CH3 OCH3
9共3,7兲⫺8共2,6兲 A⫹⫹ 10共9,1兲⫺9共8,2兲 AA
687035.02* 共38兲
CH3 OCH3
10共9,2兲⫺9共8,1兲 AA
687035.84* 共38兲
CH3 OCH3
10共9,2兲⫺9共8,2兲 EE
687036.65* 共38兲
CH3 OCH3
10共9,2兲⫺9共8,2兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
687038.15* 共38兲
CH3 OCH3
10共9,1兲⫺9共8,1兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
687039.97* 共38兲
CH3 OCH3
10共9,1兲⫺9共8,1兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
687039.97* 共38兲
CH3 OCH3
10共9,2兲⫺9共8,2兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
687043.28* 共38兲
CH3 OCH3
10共9,1兲⫺9共8,1兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
687224.558*共15兲
CH3 OH CH3 OH H2 S H2 S SO unidentified unidentified unidentified unidentified SO
9共3,6兲⫺8共2,7兲 A⫺⫺ 9共3,6兲⫺8共2,7兲 A⫺⫺ 2共0,2兲⫺1共1,1兲 2共0,2兲⫺1共1,1兲 15共16兲⫺14共15兲
23.9 26.9 20.3 14.9 35.1 5.1 4.8 3.0 3.1 40.6 11.1
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m JCMT 15 m CSO 10.4 m JCMT 15 m JCMT 15 m CSO 10.4 m CSO 10.4 m CSO 10.4 m CSO 10.4 m JCMT 15 m JCMT 15 m
Sch01 Har95 Sch01 Har95 Har95 Sch01 Sch01 Sch01 Sch01 Har95 Har95
Xu_97 Xu_97 JPL01 Hel73 COL01
687224.558*共15兲 687303.468 共70兲 687303.84* 共52兲 687457.694 共30兲 687544.7 687580.7 687696.7 687718.3 688204.630 共30兲 688273.83* 共11兲 688611.746*共31兲 688735.700 共30兲 689070. 689120.170 共70兲 689233.781*共28兲 689289.6 689438.686*共18兲 689438.686*共18兲 689522.618*共21兲 690465.163*共13兲 690552.089*共15兲 690629.327*共44兲
U
Lab. Ref.
23共5,19兲⫺22共4,18兲 EA
685611.201*共6兲
U
Astr. Ref.
H2 13CO CH3 OCH3
685505.010*共19兲
U
Telescope
684839.641*共18兲
685603.25* 共38兲
U U U U
10共1,10兲⫺9共1,9兲
Source
T r 共K兲/T a 共K兲
690672.9 691473.076*共1兲
HC15N 13
CH3 OH SO unidentified H2 S SO2 unidentified SO2 SO2 SO2 SO2 H13CN 13
CH3 OH unidentified CO
16共16兲⫺15共15兲 8⫺7
12.4b
COL01
11共1,10兲⫺10共0,10兲 E
2.5
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
17共16兲⫺16共15兲
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
JCMT 15 m CSO 10.4 m CSO 10.4 m CSO 10.4 m CSO 10.4 m CSO 10.4 m JCMT 15 m CSO 10.4 m CSO 10.4 m
Har95 Sch01 Sch01 Sch01 Sch01 Sch01 Har95 Sch01 Sch01
COL01
12共5,7兲⫺11共4,8兲 12共5,7兲⫺11共4,8兲 11共3,9兲⫺10共0,10兲 52共8,44兲⫺52共7,45兲
54.1 7.1 5.9 n.r. 2.3 19.3 20.2 2.7 1.7
8⫺7
16.3
OriMC⫺1
JCMT 15 m
Har95
14共2,12兲⫺13共1,12兲 E
3.7
OriMC⫺1
CSO 10.4 m
Sch01
4.3 100.
OriMC⫺1 OriMC⫺1
CSO 10.4 m IRTF 3 m
Sch01 Gol81a
9共7,2兲⫺9共6,3兲 6共6,0兲⫺5共5,1兲 v2 ⫽1
6⫺5
JPL01
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
334
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U U U U U
U U U U
Telescope
Astr. Ref.
Lab. Ref.
CH3 CH2 CN
18共12,6兲⫺17共11,7兲
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
18共12,7兲⫺17共11,6兲
12.0b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
691815.729*共37兲
26共14,12兲⫺25共13,12兲 E 26共14,13兲⫺25共13,12兲 A
1.6
691842.216*共32兲
CH3 OCHO CH3 OCHO
2.8b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Oes99 Oes99
691842.217*共32兲
CH3 OCHO
26共14,12兲⫺25共13,13兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
691844.853*共37兲
CH3 OCHO
26共14,13兲⫺25共13,13兲 A
b
OriMC⫺1
CSO 10.4 m
Sch01
Oes99
13共5,9兲⫺12共4,8兲
2.3
OriMC⫺1
CSO 10.4 m
Sch01
5共3,2兲⫺4共4,1兲
1.3
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
12共12兲⫺12共11兲 39共1,39兲⫺38共0,38兲 v2 ⫽1 18共4,14兲⫺17共3,15兲
2.5 4.0 3.2 n.r. 5.6
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
COL01
8⫺7
3.1 14.0
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO10.4m
Sch01 Sch01
38共1,37兲⫺37共2,36兲 16⫺15 v⫽0 39共1,39兲⫺38共0,38兲
5.3 12.1 6.8 6.8 4.7
8共6,2兲⫺7共5,3兲
7.1b 2.1 22.8 2.1 1.4
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m JCMT 15 m CSO 10.4 m CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Har95 Sch01 Sch01 Sch01 Sch01
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO
m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01
OriMC⫺1
CSO 10.4 m
Sch01
2.1 3.5 9.5 1.5 1.9 1.5 2.1 2.5 1.7 2.6 5.6 2.9 3.7 6.6 5.7 7.5
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO
m m m m m m m m m m m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 JPL01
692674.4 692726.2 693270.259*共67兲 693420.43* 共21兲 693468.986*共48兲 693790.3 693876.6*共20兲 694138.233*共59兲 694294.16* 共34兲 694494.068*共68兲 694726.2 695067.1 695119.253*共22兲 695525.3 695632.506*共15兲 695773.7 696258. 696527.111*共26兲
34
SO2
H2 18O unidentified unidentified SO SO2 34 SO2 unidentified
H13CO⫹ SO2 SiO SO2 unidentified unidentified 34
SO2
unidentified SO2 unidentified unidentified SO2
7共6,2兲⫺6共5,1兲
13共10,4兲⫺14共9,5兲 8⫺7
13
b
2.8b 2.8
10.4 10.4 10.4 10.4 10.4
10.4 10.4 10.4 10.4 10.4
JPL01
HN C CH3 CN unidentified CH3 OH CH3 CN unidentified CH3 CN unidentified CH3 CN unidentified unidentified CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN CH3 OH C2 H
38共0兲⫺37共0兲 13共5,8兲⫺14共4,11兲 E vt ⫽1 8⫺717/2,15/2⫺15/2,13/2
6.0 1.9 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
698544.78共15兲
C2 H
8⫺717/2,17/2⫺15/2,15/2
2.2b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
698607.46共10兲
C2 H
8⫺715/2,13/2⫺13/2,11/2
3.1b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
698607.46共10兲
C2 H
8⫺715/2,15/2⫺13/2,13/2
3.1b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
698787.600*共7兲
CH3 CH2 CN
29共10,19兲⫺28共9,20兲
0.8b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
698787.600*共7兲
CH3 CH2 CN
29共10,20兲⫺28共9,19兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
698931.092*共30兲 699071.6 699430.994*共18兲
CH3 OH unidentified CH3 OCH3
3共1,2兲⫺2共2,1兲 A⫺⫺ vt ⫽1
2.6 3.5 b
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97
24共5,20兲⫺23共4,19兲 EA
OriMC⫺1 OriMC⫺1 OriMC⫺1
699430.997*共18兲
CH3 OCH3
24共5,20兲⫺23共4,19兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699432.054*共18兲 699433.113*共20兲
CH3 OCH3 CH3 OCH3
24共5,20兲⫺23共4,19兲 EE 24共5,20兲⫺23共4,19兲 AA
3.3 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Gro02 Gro02
699436.952*共20兲
CH3 OCH3
20共6,15兲⫺19共5,14兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699437.264*共18兲
CH3 OCH3
20共6,15兲⫺19共5,14兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699438.309*共14兲
CH3 OCH3
20共6,15兲⫺19共5,14兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699439.512*共20兲
CH3 OCH3
20共6,15兲⫺19共5,14兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699452.811*共18兲
CH3 OCH3
23共5,18兲⫺22共4,19兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699452.816*共18兲
CH3 OCH3
23共5,18兲⫺22共4,19兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699454.075*共16兲
CH3 OCH3
23共5,18兲⫺22共4,19兲 EE
2.5b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699454.843*共18兲
CH3 OCH3
23共5,18兲⫺22共4,19兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699719.558*共18兲
CH3 OCH3
20共6,14兲⫺19共5,15兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699719.870*共18兲
CH3 OCH3
20共6,14兲⫺19共5,15兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
696958.879*共50兲 697061.3 697146.279*共29兲 697209.301*共39兲 697297.5 697433.636*共30兲 697500.6 697631.792*共22兲 697660.7 697761.5 697803.689*共16兲 697949.259*共13兲 698068.441*共13兲 698161.189*共15兲 698227.464*共16兲 698267.239*共17兲 698280.500*共18兲 698494.86* 共24兲 698544.78共15兲
U
Source
CH3 CH2 CN
696534.36* 共25兲 U
T r 共K兲/T a 共K兲
691649.326*共9兲
692079.14共60兲
U
Quantum numbers
691649.326*共9兲
691991.776*共28兲
U U
Formula
38共10兲⫺37共10兲 15共1,14兲⫺14共2,12兲 E 38共9兲⫺37共9兲 38共8兲⫺37共8兲 38共7兲⫺37共7兲
38共6兲⫺37共6兲 38共5兲⫺37共5兲 38共4兲⫺37共4兲 38共3兲⫺37共3兲 38共2兲⫺37共2兲 38共1兲⫺37共1兲
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
Xu_97
Gro02
MICROWAVE TRANSITIONS
335
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
699720.755*共14兲
CH3 OCH3
20共6,14兲⫺19共5,15兲 EE
1.7b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699721.795*共20兲
CH3 OCH3
20共6,14兲⫺19共5,15兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
699828.892*共24兲
SO2
699874.85* 共18兲
n.r. 3.4
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
700308.15* 共47兲 700312.979*共25兲
H2 13CO HNCO SO2
12共5,7兲⫺11共4,8兲 v2 ⫽1 10共0,10兲⫺9共0,9兲 32共1,32兲⫺31共1,31兲 18共11,7兲⫺19共10,10兲
3.1 3.1b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 JPL01
700638.908*共9兲
CH3 CH2 CN
19共12,7兲⫺18共11,8兲
1.9b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
700638.908*共9兲
CH3 CH2 CN
19共12,8兲⫺18共11,7兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
700950.33* 共16兲 701022.039*共44兲
HNCO
8共1,8兲⫺9共0,9兲 15共1,15兲⫺14共1,14兲 A⫹⫹
2.4 1.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Xu_97
11共1,10兲⫺10共0,10兲 E
22.6b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
10共1,10兲⫺9共1,9兲 18共⫺1,18兲⫺17共0,17兲 E
22.6
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
23.7b 5.2
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1
CSO 10.4 m
Sch01
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
13
701366.722*共20兲
CH3 OH CH3 OH
701370.474*共27兲
H2 CO
702069.89* 共15兲
13
CH3 OH
23.7b
702103.748*共32兲
SO2
19共4,16兲⫺18共3,15兲
702293.419*共55兲 702417.399*共41兲
SO2 CH3 OH NH2 D HNCO
7共3,5兲⫺6共2,5兲 E vt ⫽1 4共2,3兲1共5兲⫺3共3,1兲0共4兲 32共3,30兲⫺31共3,29兲
3.3 1.3 2.6b
OriMC⫺1 OriMC⫺1 OriMC⫺1
46共2,44兲⫺46共1,45兲
702479.99* 共15兲 702501.79* 共60兲 702501.98* 共42兲
38共2,36兲⫺37共3,35兲
Xu_97 JPL01 JPL01
SO2 HNCO
2.6b
OriMC⫺1
CSO 10.4 m
Sch01
702502.23* 共60兲
32共3,29兲⫺31共3,28兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
702532.848*共56兲
CH3 OCH3
17共7,11兲⫺16共6,10兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702534.763*共50兲
CH3 OCH3
17共7,11兲⫺16共6,10兲 EE
5.2b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702535.583*共50兲
CH3 OCH3
17共7,11兲⫺16共6,10兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702536.230*共50兲
CH3 OCH3
17共7,11兲⫺16共6,10兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702536.822*共50兲
CH3 OCH3
17共7,10兲⫺16共6,11兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702537.469*共50兲
CH3 OCH3
17共7,10兲⫺16共6,11兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702538.288*共50兲
CH3 OCH3
17共7,10兲⫺16共6,11兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702539.557*共54兲
CH3 OCH3
17共7,10兲⫺16共6,11兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
702718.58* 共71兲 702831.45* 共65兲
HNCO HNCO
32共2,31兲⫺31共2,30兲 32共2,30兲⫺31共2,29兲
3.0 4.9b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 JPL01
702835.47* 共42兲
HNCO
32共0,32兲⫺31共0,31兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
702895.676*共34兲 703889.646*共51兲
SO2
18共4,14兲⫺18共1,17兲
5.8
OriMC⫺1
CSO 10.4 m
Sch01
CH3 OH SO2 CH3 OH CH3 OCH3
15共0,15兲⫺14共0,14兲 E
1.9
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
704270.307*共29兲 704288.757*共86兲 704424.67* 共16兲
16共4,12兲⫺16共1,15兲 20共2,19兲⫺19共3,16兲 A⫺⫺ 14共8,7兲⫺13共7,7兲 EA
3.5 5.2 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Gro02
704425.53* 共16兲
CH3 OCH3
14共8,7兲⫺13共7,7兲 EE
5.9b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
704426.40* 共16兲
CH3 OCH3
14共8,6兲⫺13共7,7兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
704426.40* 共16兲
CH3 OCH3
14共8,7兲⫺13共7,6兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
704428.32* 共16兲
CH3 OCH3
14共8,7兲⫺13共7,6兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
704428.33* 共16兲
CH3 OCH3
14共8,6兲⫺13共7,7兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
704429.19* 共16兲
CH3 OCH3
14共8,6兲⫺13共7,6兲 EE
7.4b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
704431.98* 共16兲
CH3 OCH3
14共8,6兲⫺13共7,6兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
1.9
OriMC⫺1
CSO 10.4 m
Sch01
34
13
SO2
8共6,2兲⫺7共5,3兲
CH3 OH
15共7,8兲⫺14共7,7兲 E vt ⫽1
2.7
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
14共2,12兲⫺13共1,12兲 E
12.4
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
32共1,31兲⫺31共1,30兲 15共2,14兲⫺14共2,13兲 A⫺⫺ vt ⫽1
2.4 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Xu_97
18共4,14兲⫺17共3,15兲 15共⫺1,15兲⫺14共⫺1,14兲 E
25.3 2.9
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
11共9,2兲⫺10共8,3兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
704638.105*共14兲 704919.7*共11兲 705182.279*共31兲 705422.36* 共45兲 705464.91* 共11兲
33 13
CH3 OH HNCO 13
CH3 OH SO2
705672.104*共30兲 705724.979*共47兲
U
Quantum numbers
13
705990.15* 共37兲
CH3 OH CH3 OCH3
705990.15* 共37兲
CH3 OCH3
11共9,3兲⫺10共8,2兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
705990.97* 共37兲
CH3 OCH3
11共9,3兲⫺10共8,3兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
705991.79* 共37兲
CH3 OCH3
11共9,3兲⫺10共8,3兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
705994.19* 共37兲
CH3 OCH3
11共9,2兲⫺10共8,2兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
705995.01* 共38兲
CH3 OCH3
11共9,2兲⫺10共8,3兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
705995.01* 共38兲
CH3 OCH3
11共9,3兲⫺10共8,2兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
705998.22* 共38兲
CH3 OCH3
11共9,2兲⫺10共8,2兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
706082.965*共59兲 706256.332*共42兲
CH3 OH
15共7,9兲⫺16共6,11兲 E
2.4
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
13
CH3 OH SO2 unidentified
15共0,15兲⫺14共0,14兲 A⫹⫹
4.3
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
40共3,37兲⫺39共4,36兲
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97
706923.442*共54兲
13
15共2,14兲⫺14共2,13兲 A⫺⫺
3.2 5.7 2.6
707114.45* 共16兲
13
15共7,9兲⫺14共7,8兲 E
1.2
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707168.426*共12兲
13
15共6,10兲⫺14共6,9兲 E
2.0b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
706411.753*共48兲 706631.8
CH3 OH CH3 OH CH3 OH
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
336
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U U U
U
U U U U U U
Astr. Ref.
Lab. Ref.
15共6,10兲⫺14共6,9兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
15共6,9兲⫺14共6,8兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707245.448*共97兲
13
15共5,11兲⫺14共5,10兲 E
1.3
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707342.923*共74兲
13
15共⫺4,12兲⫺14共⫺4,11兲 E
1.9
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707368.092*共99兲
13
15共5,10兲⫺14共5,9兲 A⫹⫹
3.6b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707368.102*共99兲
13
15共5,10兲⫺14共5,9兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707443.637*共78兲
13
15共4,11兲⫺14共4,10兲 E
1.7
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707478.304*共62兲
13
15共⫺3,13兲⫺14共⫺3,12兲 E
1.9
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707518.662*共58兲
13
15共3,13兲⫺14共3,12兲 A⫹⫹
1.9
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707604.031*共75兲
13
15共4,12兲⫺14共4,11兲 A⫺⫺
3.8b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707609.667*共75兲
13
15共4,11兲⫺14共4,10兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
707615.417*共59兲
13
15共3,12兲⫺14共3,11兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97 JPL01
CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH
707727.944*共7兲
CH3 CH2 CN
30共10,20兲⫺29共9,21兲
1.8b
OriMC⫺1
CSO 10.4 m
Sch01
707727.944*共7兲
CH3 CH2 CN
30共10,21兲⫺29共9,20兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
2.6
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
15共1,14兲⫺14共1,13兲 E
707812.226*共45兲
13
708010.448*共59兲
13
15共3,12兲⫺14共3,11兲 E
2.4
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
708055.354*共54兲
13
15共2,13兲⫺14共2,12兲 A⫹⫹
2.3
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
10共2,9兲⫺9共2,8兲
2.8 4.1
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
13共5,9兲⫺12共4,8兲 3共1,2兲⫺3共0,3兲
26.6 23.9
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01
6共⫺2,5兲⫺5共⫺1,5兲 E
4.1
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
3.7 13.4
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Mak02 Xu_97
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
10.4 10.4 10.4 10.4
m m m m
Sch01 Sch01 Sch01 Sch01
4.5b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
10.4 10.4 10.4 10.4
m m m m
Sch01 Sch01 Sch01 Sch01
4.5b
OriMC⫺1
CSO 10.4 m
Sch01
708216.1 708269.32* 共20兲
708654.2 708785.861*共24兲 708811.374*共78兲 708877.004*共4兲 708979.327*共40兲 709006.3 709201.735*共48兲 709308.3 709466.2 709510.736*共62兲 710385.894*共25兲
CH3 OH CH3 OH
CH3 OH unidentified H2 13CO SO2 H2 S 13
CH3 OH unidentified HCN CH3 OH
8⫺7 v2 ⫽1 ᐉ⫽1 e 19共0,19兲⫺18共1,17兲 E
HCN SO2 unidentified
8⫺7 20共4,16兲⫺20共1,19兲
13 CH3 OH unidentified unidentified SO2
15共⫺2,14兲⫺14共⫺2,13兲 E
13
CH3 OH
710386.96* 共65兲
H2 13CO
710393.82* 共65兲
H2 13CO 34
SO2
SO2
37共3,35兲⫺36共2,34兲 9共1,9兲⫺8共0,8兲 A⫹⫹ 10共4,7兲⫺9共4,6兲 10共4,6兲⫺9共4,5兲
16.3b 48.7 4.5 4.1 1.9 6.7 5.1 5.7
b
OriMC⫺1
CSO 10.4 m
Sch01
21共4,18兲⫺20共3,17兲
3.8
OriMC⫺1
CSO 10.4 m
Sch01
14共4,10兲⫺14共1,13兲
3.4
OriMC⫺1
CSO 10.4 m
Sch01
Mak02
Xu_97
Xu_97
14共5,9兲⫺13共4,10兲
5.2
OriMC⫺1
CSO 10.4 m
Sch01
711302.032*共19兲
SO2 CH3 CH2 CN
18共16,2兲⫺18共15,3兲
1.7b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
711302.032*共19兲
CH3 CH2 CN
18共16,3兲⫺18共15,4兲
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
711316.9 711416.38* 共31兲
unidentified
1.7 3.6
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
712527. 712747. 712808.013*共44兲 712825.714*共62兲 713341.37* 共16兲
U U
Telescope
13
712010.528*共72兲 712372.048*共25兲
U
Source
13
710918.690*共25兲 711020.908*共32兲
U U
T r 共K兲/T a 共K兲
707173.34* 共13兲
710572.657*共64兲
U
Quantum numbers
707173.34* 共13兲
708392.421*共20兲 708470.430 共70兲 708546.213*共22兲 U
Formula
34
H2 13CO SO2 HCN
10共3,7兲⫺9共3,6兲 40共0,40兲⫺39共1,39兲 8⫺7 v2 ⫽1 ᐉ⫽1 f
7.2
OriMC⫺1
CSO 10.4 m
Sch01
15共1,14兲⫺14共1,13兲 A⫺⫺
11.6 2.6 4.0 2.9
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
39共2,38兲⫺38共1,37兲
6.3
OriMC⫺1
CSO 10.4 m
Sch01
8⫺7
24.7
OriMC⫺1
CSO10.4m
Sch01
9共6,4兲⫺8共5,3兲
3.6 2.7
OriMC⫺1 OriMC⫺1
CSO10.4m CSO 10.4 m
Sch01 Sch01
2.0 3.2
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
JPL01
unidentified unidentified 13
CH3 OH SO2
HCO⫹
10.4 10.4 10.4 10.4
Mak02
Xu_97
713409.6 714223.757*共22兲
unidentified
714375.3 714455.9 714505.5*共16兲
unidentified unidentified NS
J,F⫽31/2,31/2⫺29/2,29/2 e
2.8b
OriMC⫺1 OriMC⫺1 OriMC⫺1
714505.6*共16兲
NS
J,F⫽31/2,29/2⫺29/2,25/2 e
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
714505.6*共16兲
NS
J,F⫽31/2,33/2⫺29/2,31/2 e
b
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
2.8 1.3 7.9 4.4 5.2 3.9 5.2 2.9 3.7 3.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
714617.5 714747.08*共6兲 714779.476*共15兲 714971.8 714984.0 715195.9 715237.95* 共42兲 715407.1 715446.0 715767.2
34
SO2
Unidentified NH2 D SO2 unidentified unidentified unidentified CH3 OH unidentified unidentified unidentified
3共0,3兲0共4兲⫺2共1,1兲1共3兲 8共6,2兲⫺7共5,3兲
9共⫺1,8兲⫺8共2,7兲 E vt ⫽1
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m m m m m
JPL01
Xu_97
MICROWAVE TRANSITIONS
337
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲 U
716121.622*共17兲 716167.5 716194.543 共50兲 716270.891*共14兲 716393.103*共14兲 716488.208*共15兲 716556.167*共17兲 716596.954*共18兲 716860.67*共5兲 716938.368*共28兲
U
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
CH3 CN unidentified
39共6兲⫺38共6兲
34 SO CH3 CN CH3 CN CH3 CN CH3 CN CH3 CN NH2 D H2 CO
16共17兲⫺15共16兲
3.7 5.1 4.7
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
COL01
39共5兲⫺38共5兲 39共4兲⫺38共4兲 39共3兲⫺38共3兲 39共2兲⫺38共2兲 39共1兲⫺38共1兲 2共1,1兲1共3兲⫺1共1,0兲1共2兲
4.0 3.1 5.2 1.7 4.4 1.3
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO
m m m m m m
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
JPL01
10共0,10兲⫺9共0,9兲
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
COL01
10.4 10.4 10.4 10.4 10.4 10.4
18共17兲⫺17共16兲
717837.274*共18兲
34 SO CH3 OCH3
18.1 3.1 9.7
21共6,16兲⫺20共5,15兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
717837.408*共18兲
CH3 OCH3
21共6,16兲⫺20共5,15兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
717839.358*共16兲
CH3 OCH3
21共6,16兲⫺20共5,15兲 EE
1.8b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
717839.376*共20兲
CH3 OCH3
21共6,16兲⫺20共5,15兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
718158.806*共15兲
CH3 OH
718209.190*共41兲
16.3 2.7
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
718304.947*共18兲
13 CH3 OH CH3 OCH3
15共1,15兲⫺14共1,14兲 A⫹⫹ 4共⫺4,1兲⫺3共⫺3,1兲 E 21共6,15兲⫺20共5,16兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
718305.082*共18兲
CH3 OCH3
21共6,15兲⫺20共5,16兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
718305.956*共16兲
CH3 OCH3
21共6,15兲⫺20共5,16兲 EE
4.9b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
718306.898*共20兲
CH3 OCH3
21共6,15兲⫺20共5,16兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
718436.178*共25兲 718764.144*共38兲
CH3 OH
4共⫺4,1兲⫺3共⫺3,1兲 E 21共4,18兲⫺20共3,17兲
17.5
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97
3.0b
OriMC⫺1 OriMC⫺1
718771.450*共28兲
SO2
13共5,9兲⫺12共4,8兲 v2 ⫽1 20共3,17兲⫺19共2,18兲
n.r. 1.9
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
16共13,3兲⫺15共12,4兲
2.3b 1.7
OriMC⫺1
CSO 10.4 m
Sch01
OriMC⫺1
CSO 10.4 m
Sch01
JPL01 Xu_97
717308.3 717334.402 共50兲
718830.574*共51兲
U
Formula
unidentified
33
SO2
34
719178.410*共10兲
SO2 CH3 CH2 CN
719462.614*共26兲 719664.775*共20兲
SO2 CH3 OH
719790.03* 共41兲
720812.0*共 兲 721010.717*共12兲 721351.258*共52兲
30 SiO unidentified CH3 OH CH3 OH SO2 CH3 OH CH3 OH CH3 OCH3
721352.872*共46兲
CH3 OCH3
18共7,12兲⫺17共6,11兲 EE
721353.361*共46兲
CH3 OCH3
721353.881*共46兲
17共11,7兲⫺18共10,8兲
JPL01
9共1,9兲⫺8共0,8兲 A⫹⫹ 15⫺14 v⫽0
12.7 3.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
11共0,11兲⫺10共1,10兲 E vt ⫽1 5共2,4兲⫺4共1,3兲 A⫺⫺
2.7 2.5 6.5
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97
13.2 2.1 11.0 b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Sch01 Xu_97 Gro02
2.3b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
18共7,12兲⫺17共6,11兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
CH3 OCH3
18共7,12兲⫺17共6,11兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
721355.948*共46兲
CH3 OCH3
18共7,11兲⫺17共6,12兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
721356.467*共46兲
CH3 OCH3
18共7,11兲⫺17共6,12兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
721356.956*共48兲
CH3 OCH3
18共7,11兲⫺17共6,12兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
721358.051*共50兲
CH3 OCH3
18共7,11兲⫺17共6,12兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
721522.342*共59兲 721541.230*共51兲
CH3 OH CH3 OH
15共3,13兲⫺14共3,12兲 E vt ⫽1 15共6,10兲⫺14共6,9兲 A⫺⫺ vt ⫽1
1.2 2.5b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
721541.230*共51兲
CH3 OH
15共6,9兲⫺14共6,8兲 A⫹⫹ vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
721792.693*共82兲 722039.105*共29兲 722075.4*共 兲
CH3 OH CH3 OH CH3 OH HNCO
20共2,18兲⫺19共3,17兲 A⫹⫹ 15共1,15兲⫺14共1,14兲 A⫹⫹ vt ⫽1
2.6 1.5
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
15共6兲⫺14共6兲 E vt ⫽2 33共1,33兲⫺32共1,32兲 4共3,1兲⫺3共2,1兲 E
0.9 3.4 2.7
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Sch01 JPL01 Xu_97
CH3 OH
15共⫺2,13兲⫺14共⫺2,12兲 E vt ⫽1
2.7
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
C34S CH3 OH
15⫺14
8.1
OriMC⫺1
CSO 10.4 m
Sch01
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97
719948.0 720069.340*共18兲 720441.548*共18兲 720723.670*共33兲
722161.50* 共51兲 722316.438*共30兲 722545.711*共33兲 722582.97* 共14兲
13
CH3 OH
20共3,17兲⫺19共2,18兲 15共1兲⫺14共1兲 A⫹⫹ vt ⫽2 15共0,15兲⫺14共0,14兲 E 18共7,12兲⫺17共6,11兲 EA
10.4 10.4 10.4 10.4
722602.147*共41兲 722615.905*共25兲 722703.936*共39兲
SO2 CH3 OH
15共⫺8,8兲⫺14共⫺8,7兲 E vt ⫽1 18共2,16兲⫺17共1,17兲 15共5,10兲⫺14共5,9兲 A⫺⫺ vt ⫽1
7.7 9.4 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
722703.936*共39兲
CH3 OH
15共5,11兲⫺14共5,10兲 A⫹⫹ vt ⫽1
2.7b
OriMC⫺1
CSO 10.4 m
Sch01
722704.97* 共20兲
SO2
22共12,10兲⫺23共11,13兲
OriMC⫺1
CSO 10.4 m
Sch01
JPL01
722742.811*共30兲 722789.490*共29兲 722805.033*共27兲
CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH CH3 OH
15共4,12兲⫺14共4,11兲 E vt ⫽1 15共2,13兲⫺14共2,12兲 A⫹⫹ vt ⫽1
2.7b 1.7 2.3
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
Xu_97 Xu_97
3.8 2.7 3.2 2.1 8.0
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97 Xu_97 Xu_97 Xu_97
722823.979*共30兲 722849.297*共29兲 722888.917*共28兲 723040.392*共12兲 723193.004*共29兲
15共⫺3,12兲⫺14共⫺3,11兲 E vt ⫽1 15共0,15兲⫺14共0,14兲 E vt ⫽1 15共1,15兲⫺14共1,14兲 E vt ⫽1 15共2,14兲⫺14共2,13兲 A⫺⫺ vt ⫽1 15共⫺1,15兲⫺14共⫺1,14兲 E 15共3,13兲⫺14共3,12兲 A⫹⫹ vt ⫽1
5.0b
10.4 10.4 10.4 10.4 10.4 10.4
m m m m m m
Xu_97
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
338
FRANK J. LOVAS TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
U
U
Quantum numbers
T r 共K兲/T a 共K兲
Source
Telescope
Astr. Ref.
Lab. Ref.
723194.756*共30兲
CH3 OH
15共3,12兲⫺14共3,11兲 A⫺⫺ vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
723204.977*共33兲
CH3 OH
15共2,14兲⫺14共3,13兲 E vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
723251.959*共42兲 723279.970*共35兲 723334.995*共60兲
CH3 OH CH3 OH CH3 OH
15共⫺1,14兲⫺14共⫺1,13兲 E vt ⫽1 18共⫺1,18兲⫺17共0,17兲 E 15共0,15兲⫺14共0,14兲 A⫹⫹ vt ⫽1
1.9 5.3 6.1b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
723338.273*共36兲
CH3 OH
15共⫺4,11兲⫺14共⫺4,10兲 E vt ⫽1
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
723344.48* 共15兲
CH3 OCH3
15共8,8兲⫺14共7,8兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723345.28* 共15兲
CH3 OCH3
15共8,8兲⫺14共7,8兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723346.07* 共15兲
CH3 OCH3
15共8,8兲⫺14共7,7兲AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723346.08* 共15兲
CH3 OCH3
15共8,7兲⫺14共7,8兲AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723347.99* 共15兲
CH3 OCH3
15共8,7兲⫺14共7,8兲AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723347.99* 共15兲
CH3 OCH3
15共8,8兲⫺14共7,7兲AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723348.79* 共15兲
CH3 OCH3
15共8,7兲⫺14共7,7兲EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723351.50* 共16兲
CH3 OCH3
15共8,7兲⫺14共7,7兲EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
723582.73* 共17兲 723619.288*共12兲 723866.6 724121.610*共19兲 724153.938*共35兲
7共1,7兲⫺8共0,8兲 15共0,15兲⫺14共0,14兲A⫹⫹
1.7 7.5 1.5 8.9
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
JPL01 Xu_97
724345.382*共13兲 724482.235*共21兲
HNCO CH3 OH unidentified CH3 OH CH3 OH CH3 OH CH3 OH
15共⫺10,5兲⫺14共⫺10,4兲 E 15共2,14兲⫺14共2,13兲 A⫺⫺ 15共7,8兲⫺14共7,7兲 A⫺⫺
1.9 2.6 b
OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m CSO 10.4 m
Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
724482.235*共21兲
CH3 OH
15共7,9兲⫺14共7,8兲 A⫹⫹
4.7b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
724506.193*共46兲 724565.107*共19兲 724594.444*共20兲 724644.726*共17兲
SO2 CH3 OH CH3 OH CH3 OH
22共4,18兲⫺22共1,21兲 15共⫺7,8兲⫺14共⫺7,7兲 E 15共7,9兲⫺14共7,8兲 E 15共6,10兲⫺14共6,9兲 A⫺⫺
4.5 7.0 4.5
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
Sch01 Sch01 Sch01 Sch01
Xu_97 Xu_97 Xu_97
724644.736*共17兲
CH3 OH
15共6,9兲⫺14共6,8兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
724647.37* 共78兲 724648.350*共18兲
HNCO CH3 OH
33共2,32兲⫺32共2,31兲 15共6,10兲⫺14共6,9兲 E
6.5 b
OriMC⫺1 OriMC⫺1
CSO 10.4 m CSO 10.4 m
Sch01 Sch01
JPL01 Xu_97
724719.257*共15兲 724740.442*共17兲
CH3 OH CH3 OH
724761.45* 共37兲 724823.472*共13兲 724851.142*共15兲
4共3,1兲⫺3共2,1兲 E
6.5b
10.4 10.4 10.4 10.4
10.4 10.4 10.4 10.4
m m m m
Xu_97
15共5,11兲⫺14共5,10兲 E
4.6
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
HNCO CH3 OH CH3 OH
15共⫺6,9兲⫺14共⫺6,8兲 E 33共0,33兲⫺32共0,32兲 15共⫺4,12兲⫺14共⫺4,11兲 E 15共⫺5,10兲⫺14共⫺5,9兲 E
3.9 4.3 4.9 5.7b
OriMC⫺1 OriMC⫺1 OriMC⫺1 OriMC⫺1
CSO CSO CSO CSO
m m m m
Sch01 Sch01 Sch01 Sch01
Xu_97 JPL01 Xu_97 Xu_97
724855.173*共15兲
CH3 OH
15共5,11兲⫺14共5,10兲 A⫹⫹
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
724855.185*共15兲
CH3 OH
15共5,10兲⫺14共5,9兲 A⫺⫺
b
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
724942.05* 共36兲
CH3 OCH3
12共9,3兲⫺11共8,4兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724942.05* 共36兲
CH3 OCH3
12共9,4兲⫺11共8,3兲 AA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724942.88* 共36兲
CH3 OCH3
12共9,4兲⫺11共8,4兲 EE
5.9b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724943.70* 共36兲
CH3 OCH3
12共9,4兲⫺11共8,4兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724945.98* 共36兲
CH3 OCH3
12共9,3兲⫺11共8,3兲 EE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724946.81* 共36兲
CH3 OCH3
12共9,3兲⫺11共8,4兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724946.81* 共36兲
CH3 OCH3
12共9,4兲⫺11共8,3兲 AE
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724949.91* 共36兲
CH3 OCH3
12共9,3兲⫺11共8,3兲 EA
b
OriMC⫺1
CSO 10.4 m
Sch01
Gro02
724962.880*共13兲 725013.110*共12兲
CH3 OH CH3 OH H2 O SO2 HCN HCN unidentified
15共⫺3,13兲⫺14共⫺3,12兲 E
5.8
OriMC⫺1
CSO 10.4 m
Sch01
Xu_97
15共3,13兲⫺14共3,12兲 A⫹⫹ 2共1,1兲⫺2共0,2兲 7共7,1兲⫺6共6,0兲 9⫺8 v2 ⫽1 ᐉ⫽1 e 9⫺8
6.2 0.002 7.2 11.0 55. 9. 13.2
OriMC⫺1 IRAS10214⫹4724 OriMC⫺1 GL2591 OriMC⫺1 OriMC⫺1 OriIRc2
CSO 10.4 m IRAM 30 m IRTF 3 m JCMT 15 m IRTF 3 m IRTF 3 m UKIRT 3.8 m
Sch01 Enc93 Stu89 Boo01 Stu88 Stu89 Jaf92
Xu_97 DeL74
IRC⫹10216
CSO 10.4 m
Sch00
OriMC⫺1 OriMC⫺1 OriIRc2
IRTF 3 m IRTF 3 m CSO 10.4 m
Sch85a Stu89 Par01
JPL01
752033.23共49兲 796982.613*共19兲 797330.308*共26兲 797433.263*共4兲 802270. 802458.40* 共21兲 804751.188*共50兲
U
Formula
HCO⫹ HCN
9⫺8 9⫺8 共0,4,0兲 ᐉ⫽0
1400e 110. 3.5 1.0
Mak02 Mak02
Mak02
806651.801*共1兲 809583. 848869.35* 共10兲
CO unidentified
848961.73* 共50兲
HDO
2共1,2兲⫺1共1,1兲
5.0
OriIRc2
CSO 10.4 m
Par01
Mes84
885970.689*共10兲 890443.998*共43兲 893638.71* 共50兲 991329.295*共12兲
HCN CH3 OH HDO
10⫺9 6共6,1兲⫺6共5,2兲 E 1共1,1兲⫺0共0,0兲 9⫺8
15.0 n.r. 4.0 3.0
OriIRc2 OriIRc2 OriIRc2 W3共IRS5兲
CSO 10.4 m CSO 10.4 m CSO 10.4 m KAO 1 m
Par01 Par01 Par01 Bor91
Mak02 Xu_97 Mes84
1036912.385*(1) 1267014.482*(1) 1370085.3共 兲 1381995.102*共2兲 1611793.508*共3兲
33
SO2
7⫺6
10.4 10.4 10.4 10.4
21共9,13兲⫺21共8,14兲
13
CO CO
9⫺8
17.5
W3共IRS5兲
KAO 1 m
Bor91
CO
11⫺10
65.
OriMC⫺1
KAO 1 m
Ros89
H2 D⫹ CO CO
1共0,1兲⫺0共0,0兲
⫺0.5
OriMC⫺1
KAO 1 m
Bor93
12⫺11 14⫺13
65. n.r.
OriMC⫺1 M17
KAO 1 m KAO 1 m
Ros89 Har87
J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
Bor93
MICROWAVE TRANSITIONS
339
TABLE 4. Recommended rest frequencies for observed interstellar molecular lines—Continued Frequency 共Unc.兲 共MHz兲
Formula
1646398.143共39兲
H2 18O
2共2,1兲⫺2共1,2兲
1655833.9共15兲
1共1兲⫺⫺1共1兲⫹
1834746.874*共35兲
H 3 O⫹ OH
2
⌸1/2 J⫽3/2⫺1/2 F⫽2⫺⫺1⫹
1837816.342*共35兲
OH
2
1841345.512*共3兲
CO
1956018.137*共4兲 1968595.39共10兲 1979726.375*共47兲
Telescope
Astr. Ref.
Lab. Ref.
OriMC⫺1
KAO 1 m
Tim96
Mat99
SgrB2共M兲
ISO 0.6 m
Goi01
Ver89
2.2aa
SgrAWest
KAO 1 m
Gen85
Var93
⌸1/2 J⫽3/2⫺1/2 F⫽2⫹⫺1⫺
2.3aa
SgrAWest
KAO 1 m
Gen85
Var93
16⫺15
2.6aa
SgrAWest
KAO 1 m
Gen85
CO
17⫺16
KAO 1 m
Sta82
J⫽3⫺2 v2 ⫽1⫺0 ᐉ⫽1⫺0 18⫺17
0.7q ⫺1.5
OriMC⫺1
C3
Sgr B2共M兲
KAO 1 m
Gie01
2.3e
OriMC⫺1
KAO 1 m
Gen90
0.85q n.r. n.r.
OriMC⫺1
KAO 1 m
Wat80
SgrB2共MN兲 Sgr B2共M兲
ISO 0.6 m KAO 1 m
Neu97 Sto81
Jen87 Var93 Var93
13
Quantum numbers
CO
2413917.113*共5兲
CO
21⫺20
2463428.11共21兲 2509948.662*共30兲
HF OH
2⫺1 2
⌸3/2 J⫽5/2⫺3/2 F⫽3⫹⫺2⫺
2514316.386*共30兲
OH
2
2528172.068*(5) 2972100.*共99兲
CO
⌸3/2 J⫽5/2⫺3/2 F⫽3⫺⫺2⫹ 22⫺21
H 3 O⫹
3097909.377*共6兲
H 3 O⫹ CO
3438364.643*共7兲
CO
2980725.*共99兲
T r 共K兲/T a 共K兲 14f n.r.
Source
Gie01
n.r.
Sgr B2共M兲
KAO 1 m
Sto81
OriMC⫺1
KAO1 m
Wat80
2共0兲⫺⫺1共0兲⫹
1.4q n.r.
SgrB2共M兲
I SO 0.6 m
Goi01
Goi01
2共1兲⫺⫺1共1兲⫹
n.r.
SgrB2共M兲
ISO 0.6 m
Goi01
Goi01
27⫺26
0.43q
OriMC⫺1
KAO 1 m
Sto81a
30⫺29
0.16q
OriMC⫺1
KAO 1 m
Sto81a
a
The asterisk共*兲 following a rest frequency indicates that the frequency is a calculated value. The symbol n.r., in the intensity column, means that the intensity was not reported. Abreviations: LSB ⫽ lower sideband and USB ⫽ upper sideband. b Blended with adjacent transitions, see astronomical reference. c Line⫺to⫺continuum ratio共T L/T c 兲 ⫽ 0.0095. d Blended with a recombination line. e In flux units共f.u.兲. 1 fu ⫽ 10 ⫺26 W m⫺2 Hz⫺1 ⫽ Jansky共Jy兲. f Integrated intensity, 兰T a ␦ v , 共K km s⫺1 兲. g Beam brightness temperature. h Assignment questionable. i Intensity varies with time. j Astronomical reference shows partially resolved hyperfine structure. k Blended with CH3 13 CN. l Peak line radiation temperature. m Only the strongest of several velocity components is listed. n Reported as unidentified in astronomical reference. o The acetaldehyde and formamide lines were observed in different sidebands and are blended in this observation. p The frequency for this unidentified line reported by Clark et al. 共1979兲 was in error. The correct frequency is 93.780 GHz as shown here. q Units are 10 ⫺16 W/cm2 . r Blended with HCO⫹ J⫽3⫺2. s Originally attributed to NH2 CHO, however this assignment seems inconsistent with other observations.共Cum86兲 t Assignment from Cum84. u Not observed in Orion survey by Sutton et al. 共Sut85兲. v This line may be blended with NS J⫽ 11/2⫺9/2. w This line may be blended with NO J⫽ 5/2⫺3/2. x Confirmed in Tur90. y Although this line is reported in a table of Lor84, it is not apparent in Fig. 2 of this reference. z The J⫽ 54⫺53 of HC5 N is calculated at 143764.97共10兲 MHz. aa Units are 10 ⫺4 erg s⫺1 cm⫺2 sr⫺1 .
6. References to Tables Ada41 A’H83 Aka74 Ala02 All78 Ama91 And77 And87 And88 And90
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340 And94 App97 App99 App99a App00 Arm84 Arm84a Aud94 Ave76 Ave94 Bac90 Bal70 Bal70a Bar71 Bar75 Bar77 Bar89 Bea78 Bec82 Bel70 Bel71 Bel82 Bel83 Bel83a Bel83b Bel85 Bel87 Bel87a Bel91 Bel92a Bel92b Bel93 Bel93a Bel93b Bel94 Bel97 Bel98 Bel99 Ben01 Ber89 Bes83 Bie00 Bla84 Bla84a Bla86 Bla94 Bog81 Bog81a Bog84
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J. Phys. Chem. Ref. Data, Vol. 33, No. 1, 2004
MICROWAVE TRANSITIONS Bog84a Bog84b Bog85 Bog86 Bog91 Boo01 Bor91 Bor93 Bou80 Bre95 Bro75 Bro76 Bro77 Bro78 Bro80 Bro81 Bro84 Bro85 Buh70 Buh74 Buj81 But01 Car70 Cas95 Cec98 Cer84 Cer86 Cer86a Cer86b Cer87 Cer87a Cer87b Cer87c Cer88 Cer89 Cer89a Cer90 Cer91 Cer91a Cer91b Cer91c Cer92 Cer93 Cer96 Cer97 Cer00
341
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342 Cer01 Cer01a Cha80 Che68 Che69 Chu75 Chu77 Chu80 Chu83 Chu86 Cla74 Cla76 Cla77 Cla78 Cla79 Cla81 Cle83 Cle84 Clo64 Coh82 COL01 Com85 Com87 Com96 Com98 Cox89 Cre77 Cum80 Cum86 Cup68 Dav74 DeL69 DeL71 DeL71a DeL72 DeL72a DeL74 DeL75 Den84 Des75 deZ71 Dic76 Dic97 Dic97a Dic01 Dij71 Dix77 Doh74 Dor01
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MICROWAVE TRANSITIONS Gue´00 Gui84 Hal01 Har87 Har95 Has89 Hau93 Hel73 Hel83 Hel94 Hel96 Hel97 Hen83a Hen85 Hen87 Her84 Her85 Her88 Heu73 Hig00 Hig01 Ho77 Hoc75 Hog95 Hol76 Hol76a Hol77 Hol80 Hol80a Hol81 Hol83 Hol83a Hol86 Hol89 Hol91 Hol95 Hol00 Hol02 Hos96 How94 Hug79 Hui71 Hut80 Ike01 Ily01
Irv81 Irv83
345
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Irv90 Jac88 Jac90 Jac93 Jaf92 Jef70 Jef71 Jen79 Jen82 Jen87 Jew84 Jew87 Jew89 Joh72 Joh76 Joh76a Joh77 Joh84 JPL01 Jus96 Kah84 Kah88 Kai74 Kai75 Kai87 Kak75 Kal02 Kau80 Kaw92 Kaw92a Kaw93 Kaw94 Kaw95 Kea93 Kee83 Kil90 Kim00 Kle91 Kle96 Koj80
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MICROWAVE TRANSITIONS McG77 McG94 McG97 McK40 Mee75 Meh85 Meh96 Meh97 Mel93 Men85 Men86 Men86a Men88 Men89 Men90 Men90a Men91 Men95 Mer82 Mes84 Mey91 Mia95 Mia98 Mik89 Mil87 Mil95 Min90 Min91 Min93 Min97 Mor73 Mor75 Mor76 Mor77 Mor85 Mul00 Mul01 Mun84 Mun84a Neu97 Nis02 Nor87 Num98 Num98a Nys78 Oes99 Ohi88 Ohi89
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MICROWAVE TRANSITIONS Ryd77 Ryd80 Sah84 Sai72 Sai83 Sai87 Sai89 Sal94 Sal94a Sal96 Sas81 Sas81b Sas86 Sav02 Say76 Sca78 Sch81 Sch82 Sch83 Sch84 Sch85 Sch85a Sch86 Sch90 Sch91 Sch91a Sch92 Sch95 Sch00 Sch01 Sco78 Sha01 Sin73 Ska83 Sly92 Sly93 Sne77 Sne81 Sne84 Sne84a Sny69 Sny71 Sny71a Sny72 Sny74 Sny74a Sny75 Sny75a
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353
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