Transcript
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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 10.02.2010
Revision: 24.04.2008
1 Identification of substance: · Product details: · Trade name: VITA CEREC Propellant · Article number: ECPN · Application of the substance / product Auxiliary for manufacture of dental prothesis · Manufacturer/Supplier: VITA Zahnfabrik H. Rauter GmbH & Co. KG Postfach 1338 D 79704 Bad Säckingen e-mail:
[email protected] · Information in case of emergency: Tel.: ++49-(0)761-19240
Tel.: 07761/562-0 Fax: 07761/562299
2 Hazards identification · Hazard description: F+ Extremely flammable · Information concerning to particular hazards to man and environment Warning! Pressurized container. R 12 Extremely flammable. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Buildup of explosive mixtures possible without sufficient ventilation. Keep out of the reach of children
3 Composition/information on ingredients · Chemical characterization: · CAS No. Description: 75-28-5 isobutane · Identification number(s): · EINECS Number: 200-857-2 · Index number: 601-004-01-8
4 First aid measures · After inhalation Supply fresh air; consult doctor in case of complaints. · After skin contact Generally the product does not irritate the skin. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing If symptoms persist consult doctor.
5 Fire fighting measures · Suitable extinguishing agents CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. (Contd. on page 2) GB
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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 10.02.2010
Revision: 24.04.2008
Trade name: VITA CEREC Propellant (Contd. of page 1)
· For safety reasons unsuitable extinguishing agents Water with full jet. · Protective equipment: No special measures required.
6 Accidental release measures · Person-related safety precautions: Ensure adequate ventilation · Measures for environmental protection: No special measures required. · Measures for cleaning/collecting: Ensure adequate ventilation.
7 Handling and storage · Handling · Information for safe handling: Open and handle receptacle with care. · Information about fire - and explosion protection: Do not spray onto a naked flame or any incandescent material. Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric lights. Do not pierce or burn, even after use. · Storage · Requirements to be met by storerooms and receptacles: Store in a cool place with good ventilation · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep receptacle tightly sealed. Do not seal receptacle gas tight. Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight.
8 Exposure controls and personal protection gear · Additional information about design of technical facilities: No further data; see item 7. · Ingredients with limit values that require monitoring at the workplace: Not required. · Additional information: The lists valid during the making were used as basis. · Personal protective equipment · General protective and hygienic measures Wash hands before breaks and at the end of work. · Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: Protective gloves. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. · Material of gloves Nitrile rubber, NBR e.g. Dermatril P, KCL Nr. 743 The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Penetration time of glove material e.g. KCL Dermatril P 30 min The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 3) GB
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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 10.02.2010
Revision: 24.04.2008
Trade name: VITA CEREC Propellant (Contd. of page 2)
· Eye protection: Tightly sealed goggles.
9 Physical and chemical properties: · General Information Form: Colour: Odour:
Aerosol Colourless Nearly odourless
· Change in condition Melting point/Melting range: -159.4°C Boiling point/Boiling range: -11°C · Flash point:
-60°C
· Ignition temperature:
460°C
· Danger of explosion:
In use, may form flammable/explosive vapour-air mixture.
· Explosion limits: Lower: Upper:
1.8 Vol % 8.5 Vol %
· Vapour pressure at 20°C:
3000 hPa
· Density at 20°C:
0.549 g/cm³
· Solubility in / Miscibility with 0.049 g/l Water at 20°C: 0.0 % Organic solvents:
10 Stability and reactivity · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Dangerous reactions No dangerous reactions known · Dangerous decomposition products: No dangerous decomposition products known
11 Toxicological information · Acute toxicity: · Primary irritant effect: · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known.
12 Ecological information: · General notes: Generally not hazardous for water. GB
(Contd. on page 4)
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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 10.02.2010
Revision: 24.04.2008
Trade name: VITA CEREC Propellant (Contd. of page 3)
13 Disposal considerations · Product: · Recommendation Disposal must be made according to official regulations. · European waste catalogue 15 01 04 metallic packaging 15 01 10 packaging containing residues of or contaminated by dangerous substances · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations.
14 Transport information · Land transport ADR/RID (cross-border)
2 5F Gases. · ADR/RID class: · Danger code (Kemler): 23 1950 · UN-Number: · Packaging group: 2.1 · Hazard label · Description of goods: 1950 AEROSOLS · Maritime transport IMDG:
2.1 · IMDG Class: 1950 · UN Number: 2.1 · Label · Packaging group: F-D,S-U · EMS Number: No · Marine pollutant: · Proper shipping name: AEROSOLS · Air transport ICAO-TI and IATA-DGR:
2.1 · ICAO/IATA Class: 1950 · UN/ID Number: 2.1 · Label · Packaging group: · Proper shipping name: AEROSOLS, flammable GB
(Contd. on page 5)
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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 10.02.2010
Revision: 24.04.2008
Trade name: VITA CEREC Propellant (Contd. of page 4)
15 Regulations · Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials · Code letter and hazard designation of product: F+ Extremely flammable · Risk phrases: 12 Extremely flammable. · Safety phrases: 2 Keep out of the reach of children. 9 Keep container in a well-ventilated place. 16 Keep away from sources of ignition - No smoking. · Special labelling of certain preparations: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Buildup of explosive mixtures possible without sufficient ventilation. Keep out of the reach of children · National regulations · Waterhazard class: Generally not hazardous for water.
16 Other information: This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. GB
