Transcript
Safety Data Sheet according to (EC) No 1907/2006 - ISO 11014-1 Page 1 of 6 sds no. : 153623 V002.0
Loctite 382
Revision: 17.05.2010 printing date: 22.06.2010
1. Identification of the substance/preparation and of the company/undertaking Trade name: Loctite 382 Intended use: Cyanoacrylate Company name: Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.:
+44 1606 593933 +44 1606 863762
E-mail address of person responsible for Safety Data Sheet:
[email protected]
Emergency information: 24 Hours Emergency Tel: +44 (0)1442 278497
2. Hazards identification R36/37/38 Irritating to eyes, respiratory system and skin.
3. Composition / information on ingredients General chemical description: Cyanoacrylate Adhesive Declaration of ingredients according to (EC) No 1907/2006: Hazardous components CAS-No. Ethyl 2-cyanoacrylate 7085-85-0 Phthalic anhydride 85-44-9
EINECS ELINCS 230-391-5
content
Classification
> 80 - < 100 %
Xi - Irritant; R36/37/38
201-607-5
> 0,1 - < 1 %
Xi - Irritant; R37/38, R41 Xn - Harmful; R22 R42/43
For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available.
4. First aid measures
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Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water. Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn. Burns should be treated normally after the adhesive has been removed from the skin. If lips are accidentally stuck together apply warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action. Eye contact: If the eye is bonded closed, release eyelashes with warm water by covering with wet pad. Cyanoacrylate will bond to eye protein and will cause periods of weeping which will help to debond the adhesive. Keep eye covered until debonding is complete, usually within 1-3 days. Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage. Ingestion: Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly separate the solidified product from the mouth (several hours).
5. Fire fighting measures Suitable extinguishing media: foam, extinguishing powder, carbon dioxide. fine water spray Special protection equipment for firefighters: Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA). Hazardous combustion products: Oxides of carbon, oxides of nitrogen, irritating organic vapors.
6. Accidental release measures Personal precautions: Ensure adequate ventilation. Environmental precautions: Do not let product enter drains. Clean-up methods: Do not use cloths for mopping up. Flood with water to complete polymerization and scrape off the floor. Cured material can be disposed of as non-hazardous waste.
7. Handling and storage Handling: Ventilation (low level) is recommended when using large volumes Use of dispensing equipment is recommended to minimise the risk of skin or eye contact Storage: For optimum shelf life store in original containers under refrigerated conditions at 2 - 8°C (35.6 - 46.4 °F)
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8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Basis UK EH40 WELs Ingredient ETHYL CYANOACRYLATE 7085-85-0 PHTHALIC ANHYDRIDE 85-44-9 PHTHALIC ANHYDRIDE 85-44-9
ppm 0,3
mg/m3 1,5
Type Short Term Exposure Limit (STEL): Short Term Exposure Limit (STEL): Time Weighted Average (TWA).
12 4
Category
Remarks EH40 WEL EH40 WEL EH40 WEL
Respiratory protection: Ensure adequate ventilation. Hand protection: The use of chemical resistant gloves such as Nitrile are recommended. Polyethylene or polypropylene gloves are recommended when using large volumes. Do not use PVC, rubber or nylon gloves. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear protective glasses. General protection and hygiene measures: Good industrial hygiene practices should be observed.
9. Physical and chemical properties General characteristics: Appearance
Liquid colourless irritating
Odor:
Phys./chem. properties: Boiling point Vapor pressure Density (20 °C (68 °F)) Solubility (qualitative) (Solvent: Water) Solubility (qualitative) (Solvent: Acetone) VOC content (1999/13/EC)
> 149 °C (> 300.2 °F) 0,3 mbar 1,1 g/cm3 Polymerises in presence of water. Soluble <3%
10. Stability and reactivity Conditions to avoid: Stable under normal conditions of storage and use. Materials to avoid: Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and alcohols.
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11. Toxicological information Oral toxicity: Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth. Inhalative toxicity: Irritating to respiratory system Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals In dry atmosphere with < 50% humidity, vapours may irritate the eyes and respiratory system Skin irritation: Irritating to the skin. Bonds skin in seconds. Considered to be of low toxicity: acute dermal LD50 (rabbit)>2000mg/kg Due to polymerisation at the skin surface allergic reaction is unlikely to occur Eye irritation: Irritating to eyes. Liquid product will bond eyelids. In a dry atmosphere (RH<50%) vapours may cause irritation and lachrymatory effect
12. Ecological information Mobility: Cured adhesives are immobile. General ecological information: Biological and Chemical Oxygen Demands (BOD and COD) are insignificant. Do not empty into drains / surface water / ground water.
13. Disposal considerations Product disposal: Cured adhesive: Dispose of as water insoluble non-toxic solid chemical in authorised landfill or incinerate under controlled conditions. Dispose of in accordance with local and national regulations. Contribution of this product to waste is very insignificant in comparison to article in which it is used Waste code(EWC ): 08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Disposal must be made according to official regulations.
14. Transport information Road transport ADR: Not dangerous goods Railroad transport RID: Not dangerous goods Inland water transport ADN: Not dangerous goods Marine transport IMDG: Not dangerous goods
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Air transport IATA: Class: 9 Packaging group: Packaging instructions (passenger) 906 Packaging instructions (cargo) 906 UN no.: 3334 Label: 9 Proper shipping name: Aviation regulated liquid, n.o.s. (Cyanoacrylate ester) Primary packs containing less than 500ml are unregulated by this mode of transport and may be shipped unrestricted.
15. Regulations - classification and identification Indication of danger: Xi - Irritant
Risk phrases: R36/37/38 Irritating to eyes, respiratory system and skin. Safety phrases: S23 Do not breathe vapour. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Additional labeling: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Contains Phthalic anhydride. May produce an allergic reaction.
16. Other information The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet are as follows: R22 Harmful if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R42/43 May cause sensitization by inhalation and skin contact. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.
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Safety Data Sheet according to (EC) No 1907/2006 - ISO 11014-1 Page 1 of 6 sds no. : 179508 V004.0
Loctite 7455
Revision: 20.05.2010 printing date: 22.06.2010
1. Identification of the substance/preparation and of the company/undertaking Trade name: Loctite 7455 Intended use: Primer Company name: Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.:
+44 1606 593933 +44 1606 863762
E-mail address of person responsible for Safety Data Sheet:
[email protected]
Emergency information: 24 Hours Emergency Tel: +44 (0)1442 278497
2. Hazards identification The aerosol container is under pressure. Do not expose to high temperatures. R12 Extremely flammable. R38 Irritating to skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness.
3. Composition / information on ingredients General chemical description: Primer Declaration of ingredients according to (EC) No 1907/2006: Hazardous components CAS-No. n-Heptane 142-82-5
EINECS ELINCS 205-563-8
content
Classification
80 - 100 %
Propane 74-98-6 Benzenamine, N,N,4-trimethyl99-97-8
200-827-9
10 - 20 %
N - Dangerous for the environment; R50, R53 Xi - Irritant; R38 R67 F - Highly flammable; R11 Xn - Harmful; R65 F+ - Extremely flammable; R12
202-805-4
0,1 -
1 %
T - Toxic; R23/24/25 R52, R53 R33
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For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available.
4. First aid measures Inhalation: Move to fresh air. Seek medical advice. Skin contact: Rinse with running water and soap. Seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Seek medical advice.
5. Fire fighting measures Combustion behaviour: Solvent containing flammable product. In case of fire toxic gases are released. Suitable extinguishing media: foam, extinguishing powder, carbon dioxide. Special protection equipment for firefighters: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Hazardous combustion products: Oxides of carbon, oxides of nitrogen, irritating organic vapors. Additional information: In case of fire, keep containers cool with water spray.
6. Accidental release measures Personal precautions: Avoid skin and eye contact. Remove sources of ignition. Ensure adequate ventilation. Environmental precautions: Do not let product enter drains. Clean-up methods: Wipe up using absorbent material Store in a partly filled, closed container until disposal.
7. Handling and storage Handling: Avoid skin and eye contact. Keep away from sources of ignition - no smoking. Vapours should be extracted to avoid inhalation. Storage: Store in a cool, dry place. Do not store near sources of heat or ignition, or reactive materials.
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8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Basis UK EH40 WELs Ingredient N-HEPTANE 142-82-5 N-HEPTANE 142-82-5 PROPANE 74-98-6
ppm 500
mg/m3
500
2.085
Type Time Weighted Average (TWA). Time Weighted Average (TWA).
Category
Remarks EH40 WEL
Indicative
ECTLV
Included in the regulation but with no data values. See regulation for further details.
EH40 WEL
Respiratory protection: Do not inhale vapors and fumes. Use only in well-ventilated areas. Hand protection: The use of chemical resistant gloves such as Nitrile are recommended. In circumstances where there is a potential for prolonged or repeated skin contact, the use of disposable gloves (polyethylene, natural rubber or equivalent ester-resistant material) is recommended. Eye protection: Wear protective glasses. Skin protection: Suitable protective clothing General protection and hygiene measures: Good industrial hygiene practices should be observed.
9. Physical and chemical properties General characteristics: Appearance
Liquid colourless Aliphatic
Odor:
Phys./chem. properties: pH-value Boiling point Flash point Vapor pressure Density () Solubility (qualitative) (Solvent: Water) VOC content (1999/13/EC)
not applicable 96 - 98 °C (204.8 - 208.4 °F) Not applicable to aerosols. 46,7 mbar 0,68 g/cm3 Not miscible 100 %
10. Stability and reactivity Conditions to avoid: Stable under normal conditions of storage and use.
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Materials to avoid: Strong oxidizing agents.
11. Toxicological information Oral toxicity: Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary oedema. Inhalative toxicity: May cause headache and dizziness. Skin irritation: The product is irritant to skin and mucous membranes. Eye irritation: Prolonged or repeated contact may cause eye irritation.
12. Ecological information Ecotoxicity: Hazardous components CAS-No. n-Heptane 142-82-5 n-Heptane 142-82-5 Benzenamine, N,N,4-trimethyl99-97-8
Species Ide, silver or golden orfe (Leuciscus idus) Water flea (Daphnia magna)
Fathead minnow (Pimephales promelas)
Exposure Value time type 48 h LC 50 48 h EC 50
96 h
LC 50
Value 220 mg/l 1,5 mg/l
46 mg/l
General ecological information: Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Do not empty into drains / surface water / ground water.
13. Disposal considerations Product disposal: Dispose of according to regulations. Waste code(EWC ): 140603 Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Disposal must be made according to official regulations.
14. Transport information Road transport ADR: Class: Packaging group: Classification code: Hazard ident. number: UN no.: Label: Technical name: Tunnelcode: Additional substance property:
2 5F 1950 2.1 AEROSOLS (D) Environmentally Hazardous
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Railroad transport RID: Class: Packaging group: Classification code: Hazard ident. number: UN no.: Label: Technical name: Tunnelcode: Additional substance property:
2 5F 1950 2.2 AEROSOLS Environmentally Hazardous
Inland water transport ADN: Class: Packaging group: Classification code: Hazard ident. number: UN no.: Label: Technical name: Additional substance property:
2 5F 1950 2.1 AEROSOLS Environmentally Hazardous
Marine transport IMDG: Class: Packaging group: UN no.: Label: EmS: Seawater pollutant: Proper shipping name:
2.1 1950 2.1 F-D ,S-U Marine pollutant AEROSOLS (n-Heptane)
Air transport IATA: Class: Packaging group: Packaging instructions (passenger) Packaging instructions (cargo) UN no.: Label: Proper shipping name:
2.1 203 203 1950 2.1 Aerosols, flammable
15. Regulations - classification and identification Indication of danger: N - Dangerous for the environment
Contains n-Heptane
Xi - Irritant
F+ - Extremely flammable
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Risk phrases: R12 Extremely flammable. R38 Irritating to skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S23 Do not breathe spray. S28 After contact with skin, wash immediately with plenty of water and soap. S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
Additional labeling: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children
16. Other information The labelling of the product is indicated in Section 15. The full text of the R-phrases indicted by codes in this safety data sheet are as follows: R11 Highly flammable. R12 Extremely flammable. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R33 Danger of cumulative effects. R38 Irritating to skin. R50 Very toxic to aquatic organisms. R52 Harmful to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness.
Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.
