Transcript
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Revision
30.11.2010 23.02.2009
Lederpflegeschaum A 001 986 59 71 12
! 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Name of product
Lederpflegeschaum
Distributor
Daimler AG D-70546 Stuttgart Germany E-Mail
[email protected]
Advice Phone +49 (0)711 17-97390 Fax +49 (0)711 17-94831 Emergency advice Phone +49 (0)711 17-0
Recommended intended purpose(s) cleaner
! 2. HAZARDS IDENTIFICATION ! Classification F+; R12 Xi; R36 R-phrases 12 18 36
Extremely flammable. In use, may form flammable/explosive vapour-air mixture. Irritating to eyes.
! Special hazards information for humans and environment Keep away from sources of ignition - do not smoke. Container under pressure. Protect from direct sunlight and temperatures above 50°C. Do not spray into flames or onto glowing objects.
! 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization Propellant containing mixture of active substances ! Hazardous ingredients CAS No
EC No
Name
[%]
Classification
67-63-0 112-34-5 141-43-5
200-661-7 203-961-6 205-483-3
propan-2-ol 2-(2-butoxyethoxy)ethanol 2-aminoethanol Tensid, nichtionisch Alkanes, C11-15-isoNonionic surfactant Orange, sweet, ext. corrosion-inhibiting mixture
2,5 - 10 < 2,5 < 2,5 2,5 - 10 2,5 - 10 2,5 - 10 < 2,5 < 2,5
F R11; Xi R36; R67 Xi R36 Xn R20/21/22; C R34 Xi R41 Xn 65-66 Xn R22; Xi R41 R10; Xi R38; Xn R65 Xi R36/38
90622-58-5 8028-48-6
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Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Revision
30.11.2010 23.02.2009
Lederpflegeschaum A 001 986 59 71 12
4. FIRST AID MEASURES General information Special measures do not occur In case of inhalation Ensure of fresh air. In the event of symptoms refer for medical treatment. In case of skin contact In case of contact with skin wash off immediately with soap and water. Apply protective barrier cream. In case of eye contact In case of contact with eyes rinse with plenty of water carefully. In the event of persistent symptoms seek medical treatment. In case of ingestion Do not induce vomiting. Call for a doctor immediately. Do not administer any drinks.
5. FIRE-FIGHTING MEASURES Suitable extinguishing media Foam Dry fire-extinguishing substance Carbon dioxide water mist Extinguishing media which must not be used for safety reasons water Special protective equipment for fire-fighters Special measures do not occur
6. ACCIDENTAL RELEASE MEASURES Personal precautions Ensure adequate ventilation. Use personal protective clothing. Keep away unprotected persons Environmental precautions Do not discharge into the drains/surface waters/groundwater. Methods for cleaning up Take up with absorbent material (e.g. sand, sawdust, general-purpose binder). After taking up the material dispose according to regulation. Additional Information Hazardous substances are not released
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Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Revision
30.11.2010 23.02.2009
Lederpflegeschaum A 001 986 59 71 12
! 7. HANDLING AND STORAGE Advice on safe handling Provide for appropriate ventilation/aspiration at the work station ! Advice on protection against fire and explosion Keep away from sources of ignition - No smoking Take precautionary measures against static discharges. Do not direct spray towards any flame or incandescent object. Requirements for storage rooms and vessels Adhere to the administrative regulations ruling the storage of pressurised gas containers. Further information on storage conditions Keep container tightly closed. Storage temperature may not exceed 50°C (=122°F). Protect from sun. Keep in a cool place.
! 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Indicative occupational exposure limit values (91/322/EEC, 2000/39/EC or 2006/15/EC) CAS No
Name
Code
[mg/m3]
[ppm]
Remark
141-43-5
2-aminoethanol 2-(2-butoxyethoxy)ethanol
2,5 7,6 67,5 101,2
1 3 10 15
skin
112-34-5
8 hours Short-term 8 hours Short-term
Respiratory protection If ventilation insufficient, wear respiratory protection. ! Eye protection Safety glasses recommended during transfer Hygiene measures Keep away from food and drink. Wash hands before breaks and after work.
! 9. PHYSICAL AND CHEMICAL PROPERTIES Form aerosol
Colour yellowish
Odour characteristic
Important health, safety and environmental information Value
Temperature
pH value in delivery state
10,2
20 °C
Flash point
-30 °C
Autoignition
at
Method
Remark
DIN 19260
DIN 51755 The product is not self-igniting.
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Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Revision
30.11.2010 23.02.2009
Lederpflegeschaum A 001 986 59 71 12
Density
Value
Temperature
0,978 g/cm3
20 °C
at
Method
Remark
DIN 51757 soluble
Solubility in water Explosive properties The product is not explosive
10. STABILITY AND REACTIVITY Conditions to avoid No hazardous reactions known. Hazardous decomposition products No hazardous decomposition products known. Thermal decomposition Remark
No decomposition if used as directed.
11. TOXICOLOGICAL INFORMATION Acute toxicity/Irritability/Sensitization Value/Validation
Irritability skin
non-irritant
Irritability eye
irritant
Skin sensitization
non-sensitizing
Species
Method
Remark
12. ECOLOGICAL INFORMATION General regulation Ecological dates are not available. Do not allow uncontrolled leakage of product into the environment.
! 13. DISPOSAL CONSIDERATIONS Waste code No. 07 06 04*
Name of waste other organic solvents, washing liquids and mother liquors
Wastes marked with an asterisk are considered to be hazardous waste pursuant to Directive 91/689/EEC on hazardous waste. ! Recommendations for the product Remove in accordance with local official regulations. Recommendations for packaging Disposal in accordance with local regulations. Page 4/6
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Revision
30.11.2010 23.02.2009
Lederpflegeschaum A 001 986 59 71 12 Recommended cleansing agent Water, with cleaning agents if necessary.
! 14. TRANSPORT INFORMATION Land and inland navigation transport ADR/RID UN 1950 AEROSOLS, 2.1, (D), Classification code: 5F Transport as "limited quantity" in compliance with chapter 3.4 ADR ! Marine transport IMDG UN 1950 AEROSOLS, 2.1 Air transport ICAO/IATA-DGR UN 1950 Aerosols, flammable, 2.1
15. REGULATORY INFORMATION Remarks for classification The product is classified and labelled in accordance with EC directives/German regulations on dangerous substances. Classification Extremely flammable F+ Irritant Xi
R-phrases 12 18 36 S-phrases 16 2 23.4 26 51 56
Extremely flammable. In use, may form flammable/explosive vapour-air mixture. Irritating to eyes. Keep away from sources of ignition - No smoking. Keep out of the reach of children. Do not breathe spray. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Use only in well-ventilated areas. Dispose of this material and its container to hazardous or special waste collection point.
Special labelling for certain preparations Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. VOC standard VOC content
31,5 %
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Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Revision
30.11.2010 23.02.2009
Lederpflegeschaum A 001 986 59 71 12
16. OTHER INFORMATION Wording of the R-phrases specified in chapter 3 (not the classification of the formulation!) R 10 Flammable. R 11 Highly flammable. R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 22 Harmful if swallowed. R 34 Causes burns. R 36 Irritating to eyes. R 36/38 Irritating to eyes and skin. R 38 Irritating to skin. R 41 Risk of serious damage to eyes. R 65 Harmful: may cause lung damage if swallowed. R 66 Repeated exposure may cause skin dryness or cracking. R 67 Vapours may cause drowsiness and dizziness.
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