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Sheet Metal Msds Safety

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Sheet Metal MSDS Commercial Sheet Metal MSDS Trade Name 3M Silicone Lubricant 440 Tape Alum/Grey 55-010 Breeze Eggshell Latex-White ABC Super 90 Dry Chemical All Season Windshield Washer Fluid Argon Black Spray Paint Can Dry Absorbent Cantesco Premium Anti-Spatter Concentrate Carbon and Alloy Steels Duro Dyne Solvent Based Adhesive Emery Cloth Medium Grit Fantastik Original All Purpose Cleaner Hardcast Foil Grip 1403-181BFX Hardcast Duct Seal 321 Industrial Hydraulic Oil Linacoustic RC Duct Liner Lubriplate Wheel Bearing Grease Microlite XG Mineral Wool Insulation Oil Based Floor Sweep Powdered Chalk Propane PROtack Water Based Duct Liner Adhesive SPRAYON Zinc Rich Cold Galvanizing Compound Unfaced Fiber Glass Insulation United Duct Sealer Water Based Used Oil UVEX Clear Lens Cleaner Vulkem 801 Gray-5 Gal Xirtec 5 GRY Low Voc Cement for PVC Pipe Xylene Manufacturer 3M Tremco General Paint Strike First Corporation Recochem Airgas Inc. The Fastners Group Absorbent Products Cantesco Various Manufacturers Duro Dyne 3M S.C. Johnson Carlisle Carlisle Boss Lubricants Johns Manville Lubriplate Lubricants Johns Manville Roxul Floor Sweep Starrett Superior Propane Ductmate Industries The Sherwin-Williams Company Johns Manville McGill AirSeal Various Manufacturers Uvex Tremco IPS Corporation Imperial Oil Page # 2 10 16 19 23 31 37 42 45 51 53 57 68 76 81 87 89 96 102 108 115 116 125 127 129 135 141 146 156 157 164 166 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 Material Safety Data Sheet Copyright, 2013, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Silicone Lubricant MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 07/12/13 Supercedes Date: 08/04/10 Document Group: 05-6937-6 Product Use: Limitations on Use: Intended Use: Sale and use severely restricted due to high VOC in CT, DE, ME, MD, NH, NJ, NY, PA, RI, VA, DC, in CA per R-1168. Industrial use SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt ISOBUTANE HEPTANE POLY(DIMETHYLSILOXANE) 75-28-5 142-82-5 63148-62-9 70 - 80 15 - 25 3- 7 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: in aerosol, transparent, very slight odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects. May cause frostbite. 3.2 POTENTIAL HEALTH EFFECTS _________________________________________________________________________________________________ Page 1 of 8 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 Eye Contact: Frostbite: Signs/symptoms may include intense pain, clouding of the cornea, redness, swelling, and blindness. Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Frostbite: Signs/symptoms may include intense pain, discoloration of skin, and tissue destruction. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Flash Point Flammable Limits(LEL) Flammable Limits(UEL) No Data Available -50 ºF [Test Method: Tagliabue Closed Cup] [Details: CONDITIONS: Propellant] Approximately 1.5 % volume Approximately 8 % volume 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). _________________________________________________________________________________________________ Page 2 of 8 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing _________________________________________________________________________________________________ Page 3 of 8 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Use with functioning spray booth or local exhaust. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits and/or control spray or mist. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields . 8.2.2 Skin Protection Not applicable. Wear insulated gloves to protect against frostbite. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable. 8.3 EXPOSURE GUIDELINES Ingredient HEPTANE HEPTANE HEPTANE ISOBUTANE Authority Type Limit ACGIH ACGIH OSHA ACGIH TWA STEL TWA STEL 400 ppm 500 ppm 2000 mg/m3 1000 ppm Additional Information SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) _________________________________________________________________________________________________ Page 4 of 8 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Flammable Limits(LEL) Flammable Limits(UEL) Boiling Point Density Vapor Density in aerosol, transparent, very slight odor Liquid No Data Available -50 ºF [Test Method: Tagliabue Closed Cup] [Details: CONDITIONS: Propellant] Approximately 1.5 % volume Approximately 8 % volume No Data Available 0.64 g/ml 2.97 [Ref Std: AIR=1] Specific Gravity pH Melting point 0.640 [Ref Std: WATER=1] Not Applicable No Data Available Solubility in Water Evaporation rate Hazardous Air Pollutants Volatile Organic Compounds Nil 1.90 [Ref Std: WATER=1] 0 % weight [Test Method: Calculated] Approximately 565 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: low solids less exempts] <=5.06 lb/gal [Test Method: calculated SCAQMD rule 443.1] [Details: low solids less exempts] No Data Available Approximately 95 % weight <=94.7 % [Test Method: calculated per CARB title 2] Not Applicable 0% Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Volatile Organic Compounds Kow - Oct/Water partition coef Percent volatile VOC Less H2O & Exempt Solvents Viscosity Solids Content SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat 10.2 Materials to avoid Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide Carbon dioxide During Combustion During Combustion _________________________________________________________________________________________________ Page 5 of 8 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Dispose of empty product containers in a sanitary landfill. RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 62-4678-0930-7, 62-4678-0931-5, 62-4678-4930-3, 62-4678-4935-2, 78-8033-2219-3 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. _________________________________________________________________________________________________ Page 6 of 8 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 0 Aerosol Storage Code: 3 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product use information was modified. Section 16: Disclaimer (second paragraph) was modified. Section 10: Hazardous decomposition or by-products table was modified. Section 8: Respiratory protection - recommended respirators information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 14: Transportation legal text was modified. Section 15: Inventories information was modified. Section 9: Density information was modified. Section 9: Vapor density value was modified. Section 9: Boiling point information was modified. Section 5: Flammable limits (UE) information was modified. Section 5: Flammable limits (LEL) information was modified. Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified. Section 9: Property description for required properties was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 9: Melting point information was modified. Section 9: Solubility in water text was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 9: Flash point information was modified. Section 9: Flammable limits (LEL) information was modified. Section 9: Flammable limits (UEL) information was modified. Section 9: Autoignition temperature information was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 6: 6.2. Environmental precautions heading was modified. Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was modified. Section 16: Web address was added. Section 1: Address was added. Copyright was added. Company logo was added. Telephone header was added. Company Telephone was added. Section 1: Emergency phone information was added. _________________________________________________________________________________________________ Page 7 of 8 MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13 Section 1: Emergency phone information was deleted. Company Logo was deleted. Copyright was deleted. Section 16: Web address heading was deleted. Section 1: Address line 1 was deleted. Section 1: Address line 2 was deleted. Section 8: Respiratory protection - recommended respirators punctuation was deleted. Section 15: TSCA section 12[b] text was deleted. Section 15: TSCA section 12[b] information was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com _________________________________________________________________________________________________ Page 8 of 8 SECTI ON 1 - PROD UCT I N FORM ATI ON Pr odu ct I de n t ifie r : 55- 010 BREEZE EGGSHELL LATEX- WHI TE Pr odu ct Use : Prot ect ive Coat ing M a n u fa ct u r e r 's N a m e : General Paint Corp. Su pplie r 's N a m e : General Paint Corp. St r e e t Addr e ss: 950 Ray m ur Ave St r e e t Addr e ss: 950 Ray m ur Ave Cit y: Vancouver Pr ovin ce : BC Cit y: Vancouver Pr ovin ce : BC Post a l Code : V6A 3L5 Em e r ge n cy Ph on e : ( 604) 253- 4022 Post a l Code : V6A 3L5 Em e r ge n cy Ph on e : ( 604) 253- 4022 SECTI ON 2 - H AZARD OUS I N GRED I EN TS H a za r dou s I n gr e die n t s( Spe cific) % CAS N u m be r LD 5 0 of I n gr e die n t ( Spe cify spe cie s,r out e ) LC 5 0 of I n gr e die n t ( Spe cify spe cie s) TI TANI UM DI OXI DE 14 - 16 13463- 67- 7 NOT AVAI LABLE NOT AVAI LABLE PROPYLENE GLYCOL 2.29 - 2.31 57- 55- 6 20000 MG/ KG( ORAL, RAT) NOT AVAI LABLE SECTI ON 3 - PH YSI CAL D ATA Coa t in g VOC( gm / l) : 128 Odou r Th r e sh old( ppm ) : Not Available Ph ysica l St a t e : Liquid Odou r a n d Appe a r a n ce : liquid wit h a slight am m onia sm ell Spe cific Gr a vit y: 1.31 Va por D e n sit y( a ir = 1 ) : Va por Not Available Pr e ssur e ( m m H g) : Not Available Eva por a t ion Ra t e : Not Available Boilin g Poin t ( º C ) : Great er t han 100° C Fr e e z in g Poin t ( º C ) : Less t han 0° C Coe fficie n t of W a t e r / Oil D ist r ibu t ion : Not Available pH : 8.5- 9.5 SECTI ON 4 - FI RE AN D EXPLOSI ON D ATA Fla m m a bilit y:No I f ye s, Un de r w h ich Con dit ion s?Not Applicable M e a n s of Ex t in ct ion : Alcohol foam , Carbon dioxide, Dry chem ical powder, Polym er foam Fla sh poin t a n d M e t h od: " Not Applicable Uppe r Fla m m a ble Lt ( % by Volu m e ) :Not Applicable Low e r Fla m m a ble Lt ( % by Volu m e ) :Not Applicable Au t oign it ion Te m pe r a t u r e : Not Applicable Ex plosion D a t a - Se n sit ivit y t o Ex plosion D a t a - Se n sit ivit y t o I m pa ct : No St a t ic disch a r ge s: No H a za r dou s Com bu st ion Pdt s:carbon m onoxide, carbon dioxide, acrid, irrit ant fum es ( com ponent s not specified) , calcium oxide, aldehydes, nit rogen oxides, sulfur oxides, m agnesium oxide, am m onium nit rat e, nit rogen, nit rogen dioxide SECTI ON 5 - REACTI VI TY D ATA Ch e m ica l St a bilit y:St able I f Ye s, Un de r w h ich Con dit ion s?Not Applicable I n com pa t ibilit y w it h ot h e r su bst a n ce s:Yes I f ye s, w h ich on e s? St rong Acids St rong Oxidizing agent s St rong Bases Re a ct ivit y, a n d u n de r w h a t con dit ion s?heat , ignit ion sources, nit ric acid, dichlorohydrant ion, heat , sparks, or ot her ignit ion sources, generat ion of dust , t em perat ur es above 320° c H a za r dou s D e com posit ion Pr odu ct s:oxides of nit rogen, acet aldehyde, acet ic acid, am m onia, carbon dioxide, aldehydes, hydrogen SECTI ON 6 - TOXI COLOGI CAL PROPERTI ES Rou t e of Ent r y Sk in Con t a ct : Yes Absor pt ion : Yes Eye Cont a ct : Yes I n h a la t ion : Yes I n ge st ion : Yes Effe ct s t o Acu t e e x posu r e t o Pr odu ct : I nsufficient Dat a Effe ct s t o Ch r on ic e x posu r e t o Pr odu ct : PROPYLENE GLYCOL has been known t o cause LACTI C ACI DOSI S. Ex posu r e Lim it s ( Va lu e ,Un it s,By) TI TANI UM DI OXI DE: 10 m g/ m 3 ACGI H PROPYLENE GLYCOL: 10 m g/ m 3 AI HA I r r it a n cy ( if ye s, e x pla in ) Se n sit iz a t ion ( if ye s, e x pla in ) Ca r cin oge n icit y ( if ye s, e x pla in ) TI TANI UM DI OXI DE is possibly carcinogenic t o hum ans( 2B) by I ARC. Re pr odu ct ive Tox icit y ( if ye s, e x pla in ) Te r a t oge n icit y ( if ye s, e x pla in ) M u t a ge n icit y ( if ye s, e x pla in ) Syn e r gist ic Pr odu ct s ( if ye s, e x pla in ) SECTI ON 7 - PREVEN TI VE M EASURES Pe r son a l Pr ot e ct ive Glove s: No Re spir a t or : Equ ipm e n t Yes Eye : No Foot w e a r : No Clot h in g: No Ot h e r : No I f ch e ck e d, spe cify t ype : Respirat or: NI OSH APPROVED En gin e e r in g con t r ols ( spe cify su ch a s ve nt ila t ion, e n close d pr oce ss) : Use m echanical vent ilat ion t o reduce ex posure, ground all equipm ent and avoid exposure t o open flam es or sparks. Le a k a n d Spill Pr oce du r e : Wear adequat e prot ect ive equipm ent and elim inat e all ignit ion sources. Cont ain spill wit h absorbant m at erial and place in a suit able covered and labeled cont ainer for disposal. W a st e D isposa l: Check wit h Federal, Provincial and local governm ent regulat ions and requirem ent s for disposal. H a n dlin g Pr oce du r e s a n d Equ ipm e n t : Use in a well vent ilat ed area. Do not use wit h incom pat ible subst ances and keep away from heat and all ignit ion sources. Use grounded and non- sparking equipm ent only. St or a ge Re qu ir e m e n t s: St ore in a cool, well vent ilat ed area out of direct sunlight . St ore away from heat and all ignit ion sources. St orage facilit y should be m anufact ured out of fire resist ant m at erials. Spe cia l Sh ippin g I n for m a t ion : None Required SECTI ON 8 - FI RST AI D M EASURES I n h a la t ion : Rem ove t o fresh air. Get m edical help if t here is any breat hing difficult y. I n ge st ion : Do not induce vom it ing unless direct ed by a physician. I f conscious and alert , give t wo glasses of wat er. Seek m edical at t ent ion im m ediat ely. Sk in Con t a ct : Rem ove Cont am inat ed clot hing ( including shoes) and wash before reuse. Flush wit h large am ount s of soap and wat er. I f irrit at ion persist s, seek m edical at t ent ion. Eye Cont a ct : Flush eyes wit h large am ount s of lukewarm wat er for 20 m inut es, while holding eyelids open or unt il irrit at ion subsides. I f irrit at ion persist , get m edical at t ent ion. SECTI ON 9 - PREPARATI ON I N FORM ATI ON Pr e pa r e d by: General Paint Technical Dept Ph on e : ( 604) 253- 3131 Pr e pa r a t ion D a t e : Jul 03, 2012 MATERIAL SAFETY DATA SHEET SECTION: 1 PAGE 1 OF 4 DATE PREPARED: REVISED: MANUFACTURER: PRODUCT IDENTIFICATION Strike First Corporation c/o Steel Fire Equipment 150 Superior Blvd. Mississuaga, ON L5T 2L2 Phone: 1-905-564-1500 ABC SUPER 90 DRY CHEMICAL Multi-Purpose Dry Chemical Fire Extinguisher JUNE 01/06 April 2/2012 EMERGENCY PHONE: Canutec: 1-613-996-6666 SECTION: 2 HAZARDOUS INGREDIENTS % *ACGIH *OSHA CHEMICAL NAME CAS # mg/m3 W/W TLV mg/m3 STEL PEL STEL IDLH Mono Ammonium Phosphate Mica Attaclay Silicone Oil Calcium Carbonate Silica Yellow Pigment 7722-76-1 12001-26-2 8031-18-3 63148-57-2 471-34-1 112926-00-8 5468-75-7 95* <3 <3 <1 <1 <1 <1 NE NE NE NE NE NE NE NE NE NE NE NE 3 NE NE NE 2 NE 3 NE NE NE 6 NE NE NE NE NE NE NE OTHER NE NE NE NE NE NE *ACGIH TLV for particulars, not otherwise classified = 10; OSHA PEL for particulars not otherwise regulated, Total dust =15 Respirable fraction 5. NE = Not established SECTION :3 PHYSICAL DATA BOILING POINT VAPOR PRESSURE VAPOR DENSITY SOLUBILITY IN WATER SPECIFIC GRAVITY PERCENT VOLATILE BY VOLUME EVAPORATION RATE pH: (10% solution) APPEARANCE & COLOR Not applicable Not applicable Not applicable Not soluble. Water repellent coating. Approximately 0.88 Not applicable Not applicable Approximately 9-10 This material is a finely divided yellow powder. MATERIAL SAFETY DATA SHEET PAGE 2 OF 4 MANUFACTURER: Strike First Corporation PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER SECTION: 4 FIRE AND EXPLOSION DATA FLASH POINT FLAMMABLE LIMITS EXTINGUISHING MEDIA SPECIAL FIREFIGHTING PROCEDURES SECTION: 5 Not applicable Lower (LEL) Not applicable Upper (LEL) Not applicable None This product is a fire extinguishing agent. Incipient fire responders should wear eye protection. Structural fire fighters must wear Self-Contained Breathing Apparatus and full protective equipment. HEALTH HAZARD DATA THRESHOLD LIMIT VALUE OSHA PEL *ACGIH TLV for particulars, Not otherwise classified = 10 For particulars not otherwise regulated; Total Dust =15, Respirable Fraction 5. EFFECTS OF OVEREXPOSURE Acute This extinguishing material presents only a slight risk of causing acute health effects. If such effects occur, they will be in the form of mild irritation of the skin, nose, or throat and moderate irritation of the eyes. If ingested, this product may cause an upset stomach. Chronic This product is not known to cause chronic illnesses or diseases. EMERGENCY FIRST-AID PROCEDURES SKIN EXPOSURE If spilled on skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. If reddening or irritation occurs, victim and rescuers must seek immediate medical attention. EYE EXPOSURE If chemical is splashed in eyes, open victim's eyes while under gentle running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. MATERIAL SAFETY DATA SHEET PAGE 3 OF 4 MANUFACTURER: Strike First Corporation PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER SECTION: 5 EMERGENCY FIRST-AID PROCEDURES INHALATION SECTION: 6 If chemical is inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. If reddening or irritation occurs, victim and rescuers must seek immediate medical attention. REACTIVITY DATA STABILITY INCOMPATIBILITY Stable Strong acids. Reacts violently with lithium. HAZARDOUS Carbon monoxide and carbon dioxide DECOMPOSITION PRODUCT HAZARDOUS POLYMERIZATION SECTION: 7 Will not occur SPILL OR LEAK PROCEDURES SMALL SPILLS Sweep up the spilled solid and place all spill residue in a double plastic bag and seal. LARGE SPILLS If it is determined that exposure guidelines for nuisance particulates - 10 mg/m3 (total particulates) or 5 mg/m3 (respirable particulates) is exceeded use Level C: triple gloves (rubber gloves with nitrile gloves, over latex gloves), chemically resistant suit and boots, hard hat, and air purifying respirator with a HEPA filter. Sweep or vacuum. Dispose of in accordance with Federal, Provincial and local hazardous waste disposal regulations. MATERIAL SAFETY DATA SHEET PAGE 4 OF 4 MANUFACTURER: Strike First Corporation PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER SECTION: 8 SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION VENTILATION PROTECTIVE GLOVES EYE PROTECTION OTHER PROTECTIVE EQUIPMENT: SECTION: 9 Respiratory protection is not expected to be needed. Maintain airborne contaminant concentrations below guidelines for nuisance particulates: (see Section 5) Use with adequate ventilation. Use a mechanical fan or vent area to outside. Wear rubber gloves for routine industrial use. Safety glasses. Use body protection appropriate for task. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE All employees who handle this material should be trained to handle it safety. Avoid breathing dusts generated by this product. Avoid getting chemicals ON YOU or IN YOU. OTHER PRECAUTIONS: None SECTION: 10 TRANSPORTATION Hazard Class or Division: Fire Extinguisher, Class 2.2 UN 1044 For additional information contact Strike First Corporation No harm to the environment is expected from this preparation Fire extinguishers are designed and produced for the specific purpose of providing a safe and efficient safety tool to be used only in the fighting of fires. Improper or careless use may cause severe bodily injury and/or property damage. Contents are under pressure which is necessary to deliver the contained extinguishing agent to the fire source. - Contents under pressure. Do not puncture, incinerate or discharge into another person's face. - Do not store at high temperatures above 120 degrees Farenheit or 49 degrees Celcius. - Keep away from children. - Avoid inhaling the extinguishing agent. Avoid inhaling smoke and fumes - all fires release toxic substances that are hamful. DO NOT remain in a closed area after use: evacuate the area immediately and ventilate thoroughly before re-entering. - Although extinguishing agents are non toxic when used properly, contact with them may cause irritation to eyes, nose, throat and other allergic symptoms. Material Safety Data Sheet WHMIS (Pictograms) WHMIS (Classification) Personal protective equipment Class B-2: Flammable liquid Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). Section 1. Product and Company Identification Product name / Trade name Windshield Washer -45°C PC purple All Season Windshield Washer Associated Product’s Item Code WIP-35404PC 15-408H52 Synonym Not available. CAS # Mixture. Chemical family Not available. Validation date 04/05/2011. Apr. 05 2011 Chemical formula Not available. Print date 04/05/2011. Apr. 05 2011 Manufacturer/Supplier Recochem Inc. 850 Montee de Liesse Montreal, Quebec 514-341-3550 Material uses In case of emergency Recochem Inc. Communications and Regulatory Affairs Department (905) 878-5544 Consumer products: Windshield de-icing fluid. Section 2. Hazards identification Emergency Overview WARNING! NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED. No known significant effects or critical hazards. Avoid prolonged contact with eyes, skin and clothing. Potential Acute Health Effects See section 11 for more detailed information on health effects and symptoms. Extremely hazardous by the following route of exposure: of ingestion. Hazardous by the following route of exposure: of inhalation. Slightly hazardous by the following route of exposure: of skin contact (irritant, permeator), of eye contact (irritant). Non-sensitizer to skin. Severe over-exposure can result in death. Note to Physician Acute exposure to methanol, either through ingestion or breathing high airborne concentrations can result in symptoms appearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited to CNS, eyes and gastrointestinal tract. Because of the initial CNS’s effects of headache, vertigo, lethargy and confusion, there may be an impression of ethanol intoxication. Blurred vision, decreased acuity and photophobia are common complaints. Treatment with ipecac or lavage is indicated in any patient presenting within two hours of ingestion. A profound metabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more accurate measure of severity than serum methanol levels. Treatment protocols are available from most major hospitals and early collaboration with appropriate hospitals is recommended. Section 3. Composition, information on ingredients Canada Name Methanol CAS number 67-56-1 Conc. (% w/w) 40 - 50 There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Continued on next page Apr. 05 2011 Validated on 04/05/2011. Windshield Washer -45°C PC All Season Windshield Washer purple Page: 2/8 Section 4. First aid measures Eye contact Immediately flush eyes with plenty of water for at least 20 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if symptoms occur. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Ingestion Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if symptoms occur. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. See section 2 Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Notes to physician Section 5. Fire-fighting measures Products of combustion No specific data. Fire-fighting media and instructions Use an extinguishing agent suitable for the surrounding fire. Fire Hazards Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source of ignition and flash back. When heated to decomposition, it emits acrid smoke and irritating fumes. Explosion Hazards Highly flammable liquid and vapor. Section 6. Accidental release measures Small spill and leak Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill and leak Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Note: see section 1 for emergency contact information and section 13 for waste disposal. Continued on next page Apr. 05 2011 Validated on 04/05/2011. Windshield Washer -45°C PC All Season Windshield Washer purple Page: 3/8 Section 7. Handling and Storage Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Handling Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Storage Section 8. Exposure controls/personal protection Engineering controls No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Personal protection Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Recommended: splash goggles Body Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Hands Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hours (breakthrough time): nitrile rubber United States Product name Methanol Continued on next page Exposure limits ACGIH TLV (United States, 1/2008). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 262 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 328 mg/m³ 15 minute(s). OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s). NIOSH REL (United States, 6/2008). Absorbed through skin. TWA: 200 ppm 10 hour(s). TWA: 260 mg/m³ 10 hour(s). Apr. 05 2011 Validated on 04/05/2011. Page: 4/8 Windshield Washer -45°C PC All Season Windshield Washer purple STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s). OSHA PEL (United States, 11/2006). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). OSHA (United States, 2003). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). Canada Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations Methanol US ACGIH 1/2008 AB 6/2008 BC 6/2008 ON 6/2008 QC 6/2008 200 200 200 200 200 250 250 250 250 250 - [1] [1] [1] [1] [1] 262 262 260 262 - 328 328 325 328 - - - [1]Absorbed through skin. Section 9. Physical and chemical properties Physical State and Appearance Liquid. Odour Alcohol. [Slight] Molecular weight Not available. Taste Not available. pH 8 to 11 Colour Purple. Boiling/condensation point Not available. Volatility Not available. Melting/freezing point Not available. Evaporation rate 2.1 compared to Butyl acetate. Relative density 0.9 to 0.97 Odour Threshold Not available. Vapor pressure <12.8 kPa (<96 mm Hg) Viscosity Not available. Vapour Density <1.11 [Air = 1] Solubility Soluble in water. VOC content Not available. Other Properties Not available. The product is: May be combustible at high temperature. Auto-ignition temperature 385°C (725°F) Flash point Closed cup: 28°C (82.4°F) [Tagliabue.] Flammable limits Lower: 6% Upper: 36% Fire hazards in the presence of various substances Slightly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and heat. Non-flammable in the presence of the following materials or conditions: shocks and mechanical impacts. Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source of ignition and flash back. When heated to decomposition, it emits acrid smoke and irritating fumes. Continued on next page Apr. 05 2011 Validated on 04/05/2011. Page: 5/8 Windshield Washer -45°C PC All Season Windshield Washer purple Section 10. Stability and reactivity Stability The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Conditions of instability Not available. Slightly reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. Incompatibility with various substances Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should not be produced. products Section 11. Toxicological Information Canada Acute toxicity Product/ingredient name Methanol Conclusion/Summary Chronic toxicity Conclusion/Summary Carcinogenicity Conclusion/Summary Classification Product/ingredient name Methanol Mutagenicity Conclusion/Summary Teratogenicity Conclusion/Summary Reproductive Toxicity Conclusion/Summary Continued on next page Result LC50 Inhalation Gas. LD50 Dermal LD50 Dermal LD50 Oral LD50 Oral Not available. Species Rat Rabbit Rabbit Rat Rat Dose 64000 ppm 15800 mg/kg 15840 mg/kg 5600 mg/kg 5600 mg/kg Exposure 4 hours - Not available. May be fatal or cause blindness if swallowed. ACGIH A5 : Not available. : Not available. : Not available. IARC 4 EPA - NIOSH - NTP - OSHA None. Apr. 05 2011 Validated on 04/05/2011. Windshield Washer -45°C PC All Season Windshield Washer purple Page: 6/8 Section 12. Ecological information For accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggested instructions. Ecotoxicity Canada Aquatic ecotoxicity Product/ingredient name Methanol Conclusion/Summary Biodegradability Conclusion/Summary : No known significant effects or critical hazards. Result Species Acute LC50 2500000 ug/L Marine water Crustaceans - Crangon crangon Adult Acute LC50 3289 to 4395 mg/L Fresh Daphnia - Daphnia magna water Neonate - <24 hours Acute LC50 >100000 ug/L Fresh water Fish - Pimephales promelas Juvenile (Fledgling, Hatchling, Weanling) - 0.2 to 0.5 g : Not available. Exposure 48 hours 48 hours 96 hours : Not available. Section 13. Disposal considerations Waste information The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Section 14. Transport information Canada TDG Classification No placard (handling and hazard label) required. Class Subsidiary class Not applicable. Proper Shipping Name (Canada) TDG UN number Packing Group Windshield washer antifreeze, Alcohol exempt. Special provisions In containers of 450L or less, this product meets the requirements for exemption under TDG regulation special provisions, part 1, section 1.36b: Class 3, Flammable liquids: Alcohol Exemption. Not applicable. Not applicable. Not applicable. Continued on next page Apr. 05 2011 Validated on 04/05/2011. Page: 7/8 Windshield Washer -45°C PC All Season Windshield Washer purple IMDG Classification Class Subsidiary class Class 3: Flammable liquid. Proper Shipping Name IMDG UN number Packing Group Alcohols, n.o.s. (Methanol) Marine pollutant Special provisions Not a pollutant. - UN 1987 III No placard (handling and hazard label) required. Emergency schedules (EmS) 3-06 Remarks In a means of containment of 5 L capacity or less this product is classified as a "Limited Quantity". United States DOT (Classification) Class Class 3: Flammable liquid. Subsidiary class - Proper Shipping Name (United States) DOT UN number Packing Group Alcohols, n.o.s. (Methanol) Special provisions In containers of 5 L (5Kg) capacity or less this product is classified as a "Consumer Commodity" under DOT regulations. International Air Transport Association (IATA) For air shipment classification and associated regulations, please refer to the latest edition of IATA Dangerous Goods Regulations. UN 1987 III Section 15. Regulatory information WHMIS Classification (Canada) Canada Domestic Substances List (DSL) Status Class B-2: Flammable liquid Class D-1B: Material causing immediate and serious toxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). This product and/ or all of its components are on the DSL. HCS Classification (U.S.A.) Not regulated. U.S.A. Regulatory Lists This product and/ or all of its components are on the TSCA inventory list. Continued on next page Apr. 05 2011 Validated on 04/05/2011. Hazardous Material Information System (U.S.A.) Health Flammability Reactivity Personal protection Windshield Washer -45°C PC All Season Windshield Washer purple 2 National Fire Protection 3 Health Association 0 (U.S.A.) B Page: 8/8 Flammability 3 2 0 Reactivity Specific hazard Section 16. Other information Printed 04/05/2011. Apr. 05 2011 Apr. 05 2011 Validated and verified by Compliance and Technical Information Manager on 04/05/2011 ph.# 905-878-5544. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. MSDS are available at www.recochem.com Material Safety Data Sheet Argon Section 1. Chemical product and company identification Product name Supplier : Argon : AIRGAS INC., on behalf of its subsidiaries 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 Product use Synonym MSDS # Date of Preparation/Revision In case of emergency : : : : Synthetic/Analytical chemistry. argon, compressed; Cryogenic Liquid Argon, Liquid Argon 001004 5/6/2013. : 1-866-734-3438 Section 2. Hazards identification Physical state Emergency overview : Gas. [COLORLESS, ODORLESS INERT GAS OR LIQUID] : WARNING! GAS: CONTENTS UNDER PRESURE. Do not puncture or incinerate container. Can cause rapid suffocation. May cause severe frostbite. LIQUID: Extremely cold liquid and gas under pressure. Can cause rapid suffocation. May cause severe frostbite. Do not puncture or incinerate container. Contact with rapidly expanding gases or liquids can cause frostbite. : Inhalation Routes of entry Potential acute health effects Eyes : Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenic liquid can cause frostbite and cryogenic burns. Skin : Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenic liquid can cause frostbite and cryogenic burns. Inhalation : Acts as a simple asphyxiant. Ingestion Medical conditions aggravated by overexposure : Ingestion is not a normal route of exposure for gases. Contact with cryogenic liquid can cause frostbite and cryogenic burns. : Acute or chronic respiratory conditions may be aggravated by overexposure to this gas. See toxicological information (Section 11) Section 3. Composition, Information on Ingredients Name Argon Build 1.1 CAS number 7440-37-1 % Volume 100 Exposure limits Oxygen Depletion [Asphyxiant] Page: 1/6 Argon Section 4. First aid measures No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact : None expected. Frostbite : Try to warm up the frozen tissues and seek medical attention. Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Ingestion : As this product is a gas, refer to the inhalation section. Section 5. Fire-fighting measures Flammability of the product Products of combustion Fire-fighting media and instructions Special protective equipment for fire-fighters : Non-flammable. : No specific data. : Use an extinguishing agent suitable for the surrounding fire. Apply water from a safe distance to cool container and protect surrounding area. If involved in fire, shut off flow immediately if it can be done without risk. Contains gas under pressure. In a fire or if heated, a pressure increase will occur and the container may burst or explode. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (section 8). Shut off gas supply if this can be done safely. Isolate area until gas has dispersed. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Immediately contact emergency personnel. Stop leak if without risk. Note: see section 1 for emergency contact information and section 13 for waste disposal. Methods for cleaning up Section 7. Handling and storage Handling : High pressure gas. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Never allow any unprotected part of the body to touch uninsulated pipes or vessels that contain cryogenic liquids. Prevent entrapment of liquid in closed systems or piping without pressure relief devices. Some materials may become brittle at low temperatures and will easily fracture. Storage : Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). For additional information concerning storage and handling refer to Compressed Gas Association pamphlets P-1 Safe Handling of Compressed Gases in Containers and P12 Safe Handling of Cryogenic Liquids available from the Compressed Gas Association, Inc. Build 1.1 Page: 2/6 Argon Section 8. Exposure controls/personal protection Engineering controls Personal protection Eyes Skin Respiratory Hands Personal protection in case of a large spill Product name argon : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. When working with cryogenic liquids, wear a full face shield. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93 : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Insulated gloves suitable for low temperatures : Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of the product. Oxygen Depletion [Asphyxiant] Consult local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Molecular weight Molecular formula Boiling/condensation point Melting/freezing point Critical temperature Vapor density Specific Volume (ft 3/lb) Gas Density (lb/ft 3) : : : : : : : : 39.95 g/mole Ar -185.7°C (-302.3°F) -189.2°C (-308.6°F) -122.4°C (-188.3°F) 1.38 (Air = 1). Liquid Density@BP: 87 lb/ft3 (1393 kg/m3) 9.70874 0.103 Section 10. Stability and reactivity Stability and reactivity Hazardous decomposition products : The product is stable. : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Toxicity data Other toxic effects on humans : No specific information is available in our database regarding the other toxic effects of this material to humans. Specific effects Carcinogenic effects Mutagenic effects Reproduction toxicity : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. Build 1.1 Page: 3/6 Argon Section 12. Ecological information Aquatic ecotoxicity Not available. Environmental fate Environmental hazards Toxicity to the environment : Not available. : No known significant effects or critical hazards. : Not available. Section 13. Disposal considerations Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory information UN number Proper shipping name Class Packing group DOT Classification UN1006 ARGON, COMPRESSED 2.2 Not applicable (gas). UN1951 Argon, refrigerated liquid Label Additional information Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 75 kg Cargo aircraft Quantity limitation: 150 kg TDG Classification UN1006 ARGON, COMPRESSED UN1951 Argon, refrigerated liquid 2.2 Not applicable (gas). Explosive Limit and Limited Quantity Index 0.125 Passenger Carrying Road or Rail Index 75 Special provisions 42 Mexico Classification UN1006 ARGON, COMPRESSED UN1951 Argon, refrigerated liquid 2.2 Not applicable (gas). - “Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product.” Build 1.1 Page: 4/6 Argon Section 15. Regulatory information United States U.S. Federal regulations : TSCA 8(a) IUR: argon United States inventory (TSCA 8b): This material is listed or exempted. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: argon SARA 311/312 MSDS distribution - chemical inventory - hazard identification: argon: Sudden release of pressure Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. State regulations Canada WHMIS (Canada) Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. : Connecticut Carcinogen Reporting: This material is not listed. Connecticut Hazardous Material Survey: This material is not listed. Florida substances: This material is not listed. Illinois Chemical Safety Act: This material is not listed. Illinois Toxic Substances Disclosure to Employee Act: This material is not listed. Louisiana Reporting: This material is not listed. Louisiana Spill: This material is not listed. Massachusetts Spill: This material is not listed. Massachusetts Substances: This material is listed. Michigan Critical Material: This material is not listed. Minnesota Hazardous Substances: This material is not listed. New Jersey Hazardous Substances: This material is listed. New Jersey Spill: This material is not listed. New Jersey Toxic Catastrophe Prevention Act: This material is not listed. New York Acutely Hazardous Substances: This material is not listed. New York Toxic Chemical Release Reporting: This material is not listed. Pennsylvania RTK Hazardous Substances: This material is listed. Rhode Island Hazardous Substances: This material is not listed. : Class A: Compressed gas. CEPA Toxic substances: This material is not listed. Canadian ARET: This material is not listed. Canadian NPRI: This material is not listed. Alberta Designated Substances: This material is not listed. Ontario Designated Substances: This material is not listed. Quebec Designated Substances: This material is not listed. Section 16. Other information United States Label requirements Canada Label requirements Build 1.1 : GAS: CONTENTS UNDER PRESURE. Do not puncture or incinerate container. Can cause rapid suffocation. May cause severe frostbite. LIQUID: Extremely cold liquid and gas under pressure. Can cause rapid suffocation. May cause severe frostbite. : Class A: Compressed gas. Page: 5/6 Argon Hazardous Material Information System (U.S.A.) : Health 0 Flammability 0 Physical hazards 0 liquid: National Fire Protection Association (U.S.A.) Health 3 Fire hazard 0 Reactivity 0 Personal protection C : Health 0 0 SA Flammability 0 Instability Special liquid: Flammability 0 Health 3 SA 0 Instability Special Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Build 1.1 Page: 6/6 MATERIAL SAFETY DATA SHEET E119 02 00 DATE OF PREPARATION Feb 3, 2012 SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION PRODUCT NUMBER E119 PRODUCT NAME Spray Paint, Flat Black MANUFACTURER'S NAME Mfd. for: J2 PRODUCTS 54 Audia Court, Unit 2A Concord, ON L4K 3N4 Telephone Numbers and Websites Product Information (905) 699-9410 Regulatory Information (216) 566-2902 Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 *for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident) SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS % by Weight 14 13 16 36 3 7 1 0.4 CAS Number 74-98-6 106-97-8 108-88-3 67-64-1 763-69-9 14807-96-6 471-34-1 1333-86-4 Ingredient Units Propane ACGIH TLV 2500 OSHA PEL 1000 Butane ACGIH TLV 800 OSHA PEL 800 Toluene ACGIH TLV 20 OSHA PEL 100 OSHA PEL 150 Acetone ACGIH TLV 500 ACGIH TLV 750 OSHA PEL 1000 Ethyl 3-Ethoxypropionate ACGIH TLV OSHA PEL Talc ACGIH TLV 2 OSHA PEL 2 Calcium Carbonate ACGIH TLV 10 OSHA PEL 15 OSHA PEL 5 Carbon Black ACGIH TLV 3.5 OSHA PEL 3.5 Vapor Pressure PPM PPM 760 mm PPM PPM 760 mm PPM ppm (Skin) ppm (Skin) STEL 22 mm PPM PPM STEL PPM 180 mm Not Available Not Available 1.11 mm mg/m3 as Resp. Dust mg/m3 as Resp. Dust mg/m3 as Dust mg/m3 Total Dust mg/m3 Respirable Fraction MG/M3 MG/M3 SECTION 3 — HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. HMIS Codes Health 2* Flammability 3 Reactivity 0 page 1 of 5 E119 May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems: the liver the urinary system the cardiovascular system the reproductive system SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. SECTION 4 — FIRST AID MEASURES EYES: SKIN: INHALATION: INGESTION: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If affected, remove from exposure. Restore breathing. Keep warm and quiet. Do not induce vomiting. Get medical attention immediately. SECTION 5 — FIRE FIGHTING MEASURES FLASH POINT LEL UEL EXTINGUISHING MEDIA Propellant < 0 °F 1.0 12.8 Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. SECTION 6 — ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. SECTION 7 — HANDLING AND STORAGE STORAGE CATEGORY Not Available PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children. SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. page 2 of 5 E119 RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES 768 g/l PRODUCT WEIGHT 6.41 lb/gal SPECIFIC GRAVITY 0.77 <-18 - 172 °C BOILING POINT <0 - 342 °F MELTING POINT Not Available VOLATILE VOLUME 92% EVAPORATION RATE Faster than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. pH 7.0 VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) Volatile Weight 47.26% Less Water and Federally Exempt Solvents SECTION 10 — STABILITY AND REACTIVITY STABILITY — Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur SECTION 11 — TOXICOLOGICAL INFORMATION CHRONIC HEALTH HAZARDS Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. page 3 of 5 E119 TOXICOLOGY DATA CAS No. 74-98-6 106-97-8 108-88-3 67-64-1 763-69-9 14807-96-6 471-34-1 1333-86-4 Ingredient Name Propane LC50 RAT LD50 RAT 4HR Not Available Not Available LC50 RAT LD50 RAT 4HR Not Available Not Available LC50 RAT LD50 RAT 4HR 4000 ppm 5000 mg/kg RAT RAT 4HR Not Available 5800 mg/kg RAT RAT 4HR Not Available 5000 mg/kg RAT RAT 4HR Not Available Not Available RAT RAT 4HR Not Available Not Available RAT RAT 4HR Not Available Not Available Butane Toluene Acetone LC50 LD50 Ethyl 3-Ethoxypropionate LC50 LD50 Talc LC50 LD50 Calcium Carbonate LC50 LD50 Carbon Black LC50 LD50 SECTION 12 — ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. SECTION 13 — DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SECTION 14 — TRANSPORT INFORMATION Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126) Canada (TDG) May be classed as Consumer Commodity, ORM-D UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126) IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D) IATA/ICAO UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY SECTION 15 — REGULATORY INFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/COMPOUND % by WT 108-88-3 Toluene 16 TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. % Element page 4 of 5 E119 SECTION 16 — OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. page 5 of 5 MATERIAL SAFETY DATA SHEET 1 Of 3 Abbreviations used on this Material Safety Data Sheet: N/av. = Not available, N/ap. = Not applicable, ppm = parts per million, TLV = Threshold Limit Value. NFPA Hazard Rating: 4-Extreme, 3-High, 2-Moderate, 1-Slight, 0-None, X-Blank SECTION I - PRODUCT IDENTIFICATION AND USE PRODUCT IDENTIFIER CAN DRY SUPREME ABSORBENT MANUFACTURER'S NAME Absorbent Products Ltd STREET ADDRESS 724 East Sarcee St. CITY/PROVINCE Kamloops, BC POSTAL CODE V2H 1E7 4 - extreme 0 1 EMERGENCY TELEPHONE NUMBER: 3 - high 1 2 - moderate . 1-800-667-0336 1 - slight CHEMICAL NAME: Diatomaceous Earth TRADE NAME: CAN DRY ABSORBENT NFPA HAZARD RATING: 0 - insignificant CHEMICAL FAMILY: Silica Health - 1, Flammability - 0, Reactivity - 1 MATERIAL USE: Industrial Absorbent SECTION II - HAZARDOUS INGREDIENTS OF MATERIAL HAZARDOUS INGREDIENTS % CAS NUMBER OR OSHA PEL LD50/ /LC 50 UN NUMBER OR (ACGIH TLV) SPECIES AND ROUTE NA NUMBER Naturally Occuring Diatomaceous Earth 100% 61790-53-2 see below N/av. <1% 14808-60-7 see below N/av. (Typical Analysis = 67% Silicon Dioxide) Free Crystalline Silica or Silica, quartz For sampling silica dusts refer to NIOSH Analytical Method 7500 or OSHA method ID 142 SECTION III - PHYSICAL DATA FOR MATERIAL PHYSICAL STATE solid ODOR AND APPEARANCE No odor, Buff / grey granules VAPOR PRESSURE (mm Hg) N/ap. DENSITY (20 degrees Celcius) 35lb\cu. ft. +/- 5 VAPOR DENSITY (Air = 1) N/ap. SOLUBILITY IN WATER Insoluble, forms SPECIFIC GRAVITY (Water=1) 2.0 FREEZING POINT N/ap. BOILING POINT N/ap. colloidal suspension pH 5.5 - 6.5 slightly acidic in water SECTION IV - FIRE AND EXPLOSION DATA FLAMMABILITY (IF YES, UNDER WHICH CONDITIONS?) YES NO X MEANS OF EXTINCTION N/ap. SPECIAL PROCEDURES N/ap. FLASHPOINT AND METHOD N/ap. UPPER FLAMMABILITY LIMIT (% BY VOLUME) N/ap. AUTOIGNITION TEMPERATURE N/ap. LOWER FLAMMABILITY LIMIT (% BY VOLUME) N/ap. HAZARDOUS COMBUSTION PRODUCTS N/ap. SENSITIVITY TO STATIC DISCHARGE No EXPLOSION DATA: SENSITIVITY IMPACT No MATERIAL SAFETY DATA SHEET 2 Of 3 MATERIAL IDENTIFIER: CAN DRY SUPREME ABSORBENT SECTION V - HEALTH HAZARDS Routes of Exposure and Effects: Inhalation: Acute (short term) exposure to dust levels exceeding the PEL may cause irritation of respiratory tract resulting in a dry cough. Chronic (long term) exposure to crystalline free silica contained by airborne diatomaceous earth dust where levels are higher than TLV's may lead to the development of silicosis or other respiratory problems. Persistent dry cough, throat irritation and labored breathing on exertion are symptomatic. exposure may aggravate existing upper respiratory tract diseases such as asthma, bronchitis or emphysema. Eyes: Irritant. Skin: Possible drying results in dermatitis. Ingestion: No adverse effects. Permissible Exposure Limits: OSHA PEL ACGIH OHS (for airborne, nuisance dusts) 8 hr TWA TLV 8 hr TWA OHS STEL Total dust 15 mg/m3 Not detected 4 mg/m3 Respirable dust 5 mg/m Not detected 1.5 mg/m n/a Crystalline quartz (respirable) 0.1 mg/m3 0.1 mg/m3 0.025mg/m3 n/a Diatomaceous earth 3 n/a 3 EFFECTS OF CHRONIC EXPOSURE TO PRODUCT Exposure to quantities of crystalline silica dust, in the forms of quartz, cristobalite or tridymite, may be present in airborne dust. If the concentration levels are in excess of th OSHA Permissible Limit (PEL-TWA 8hrs) of 0.05mg/m3 or the ACGIH Threshold Limit Value (TLV) of 0.05mg/m3, the crystalline silica is a known cause of silicosis, a progressive, sometimes fatal, lung disease. From the International Agency for Research on Cancer (IARC), a 1997 review of "Crystalline Silica Inhaled in the Form of Quart or Cristobalite" coded Monograph 68 concluded that Amorphous Silica is not classifiable to its carcinogenicity to humans (Group 3) SECTION VI - REACTIVITY DATA CHEMICAL STABILITY (IF NO, YES UNDER WHICH CONDITIONS) NO INCOMPATIBILITY WITH OTHER SUBSTANCES YES (IF YES, WHICH ONES) NO X X REACTIVITY, AND UNDER WHAT CONDITIONS N/ap. HAZARDOUS DECOMPOSITION PRODUCTS N/ap. Hydrofluoric acid - silica may react violently SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE PERSONAL PROTECTIVE EQUIPMENT Bureau of Mines or NIOSH approved respirators for protection against pneumoconiosis producing dusts recommended when dust is present. If the dust concentration is less than ten (10) times the Permissible Exposure Limit (PEL) use quarter or half mask respirator with replacement dust filter or single use dust respirator with valve. If dust concentration is greater than ten (10) times and less than one hundred (100) times the PEL use full faceplate respirator with replaceable dust filter; if greater than one hundred (100) and less than two hundred (200) times the PEL use power air purifying (positive pressure) respirator with replaceable filter; if greater than two hundred (200) times the PEL use type C, automatic-air respirator, continuous flow type (positive pressure), with full facepiece, head or helmet. GLOVES (SPECIFY) Not needed under normal conditions of use. RESPIRATOR (SPECIFY) Avoid breathing dust. Use respirators approved NIOSH/OSHA for silica bearing dust. EYE (SPECIFY) Use protective goggles in high dust conditions. FOOTWEAR (SPECIFY) As required on jobsite. MATERIAL SAFETY DATA SHEET 3 Of 3 MATERIAL IDENTIFIER: CAN DRY SUPREME ABSORBENT SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE CONTINUED CLOTHING (SPECIFY) Wear coveralls in high dust conditions. ENGINEERING CONTROLS (SPECIFY, E.G. VENTILATION, ENCLOSED PROCESS) Local - control within recommended TLV/PEL, mechanical filtration to minimize dust. Refer to ACGIH publication "Industrial Ventilation" or similar publications for design of ventilation systems. LEAK AND SPILL PROCEDURE Vacuum clean spillage, wet sweep or wash away. Avoid creating dust. WASTE DISPOSAL Dispose of in accordance with local, state and federal regulations. HANDLING PROCEDURES Avoid creating dust. Repair or properly dispose of broken bags. Use wet process or enclosed handling. STORAGE REQUIREMENTS Store in a dry place to maintain product quality. Keep containers closed and in good condition. Repair damaged containers. SPECIAL SHIPPING INFORMATION None SECTION VIII - FIRST AID MEASURES SPECIFIC MEASURES Inhalation: Remove victim to fresh air. If breathing has stopped, a trained person should perform artificial respiration. Acute inhalation can cause dryness of the nasal passage and congestion of the upper respiratory tract. Ingestion: Do not induce vomiting. Short-term exposure not considered harmful. Drink generous amounts of water to reduce bulk and drying effects. Eye: Wash with generous quantities of water. Consult physician if irritation persists. May cause irritation or inflammation. Skin contact: Remove contaminated clothing. Wash with soap and water until clean. Use moisture renewing lotions if dryness occurs. Not absorbed by the skin. May cause dryness. SECTION IX - DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS DESCRIPTION: None IDENTIFICATION NUMBER: None TECHNICAL NAME: None LABEL(S) REQUIRED: None HAZARDOUS CLASS: None SECTION X - ENVIRONMENTAL DATA EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW INFORMATION This product contains no toxic chemicals subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 (SARA 313 - Toxic Chemical Release Reporting). EPA SARA 311/312 Hazard Classification: This product is considered hazardous under OSHA and SARA Title III, Section 301. Category: Chronic Health. CERCLA Section 103: This product is not subject to CERCLA reporting requirements as it is sold. Refer to CERCLA regulations to determine if used product mixed with other chemicals or materials may be reportable. Many states have more stringent release reporting requirements. Reports spills required under federal, state and local regulations. EPZ Toxic Substance Control Act (TSCA): All of the ingredients are listed on the TSCA Chemical Substances Inventory. DOT Marine Pollutants: This product does not contain Marine Pollutants as defined in 49 CFR 171.8. SECTION XI - PREPARATION DATE OF MSDS PREPARED BY: PHONE NUMBER DATE Quality Control Staff, Absorbent Products Ltd. 1-800-667-0336 May, 2013 All information presented herein is believed to be accurate; however, it is the user's responsibility to determine in advance of need that the information is current and suitable for their circumstances. No warranty or guarantee, expressed or implied is made by Absorbent Products Ltd., as to the information, or as to the safety, toxicity or the effect of this product. 36.0.12 Page 1/6 Safety Data Sheet acc. to OSHA HCS Printing date 10/07/2013 Reviewed on 10/07/2013 1 Identification of the substance/mixture and of the company/undertaking · Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE · Article number: ENVIROSPAT, ES-16-P, ES-16-T, ES-1G, ES-5G, ES-DR, ES-4L, ES-20L · MSDS Number: 00104-CA-EN · UPC bar code(s): 699913-10250, 699913-10255, 699913-10260, 699913-10265, 699913-10270 · Relevant identified uses of the substance: PREVENTS SPATTER BUILD UP IN WELDING APPLICATIONS · Manufacturer/Supplier: WWW.CANTESCO.COM USA ADDRESS : KEMPER SYSTEM AMERICA, INC 1200 NORTH AMERICA DR, WEST SENECA, NY 14224 PH (716) 693-8206 FAX (716) 558-2969 CANADIAN ADDRESS : KEMPER SYSTEM CANADA 13 - 5200 DIXIE ROAD MISSISSAUGA, ON L4W 1E4 PH (905) 624-5463 FAX (905) 624-2840 · Information department: Tel: (716) 558-2971 ext. 228 www.cantesco.com · Emergency telephone number: ChemTrec (800) 424-9300 Canada only: CANUTEC (Call collect) (613) 996-6666 2 Hazards identification · Classification of the substance or mixture: The product is not classified according to the Globally Harmonized System (GHS). · Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of international guidelines. · Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · NFPA ratings (scale 0 - 4): 0 0 0 Health = 0 Fire = 0 Reactivity = 0 CA (Contd. on page 2) 36.0.12 Page 2/6 Safety Data Sheet acc. to OSHA HCS Printing date 10/07/2013 Reviewed on 10/07/2013 Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE (Contd. of page 1) 3 Composition/information on ingredients · Chemical characterization: Mixtures · Description: Mixture of the substances listed below with nonhazardous additions. · Dangerous components: 68412-54-4 Polyoxyethylene (9) nonylphenylether, branched Acute Tox. 3, H301; Skin Irrit. 2, H315; Eye Irrit. 2A, H319 112-80-1 oleic acid, pure Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335 · Additional information: Exact concentrations are being withheld as trade secrets. 1-<3% ≤1% 4 First aid measures · General information: No special measures required. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Generally the product does not irritate the skin. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor. · Most important symptoms and effects, both acute and delayed: No further relevant information available. · Indication of any immediate medical attention and special treatment needed: No further relevant information available. 5 Firefighting measures · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture: No further relevant information available. · Protective equipment: No special measures required. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures: Not required. · Environmental precautions: Dilute with plenty of water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · Reference to other sections: No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling · Precautions for safe handling: No special measures required. · Information about protection against explosions and fires: No special measures required. · Storage · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. (Contd. on page 3) CA 36.0.12 Page 3/6 Safety Data Sheet acc. to OSHA HCS Printing date 10/07/2013 Reviewed on 10/07/2013 Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE (Contd. of page 2) · Further information about storage conditions: None. · Specific end use(s): No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the creation were used as basis. · Personal protective equipment · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. · Breathing equipment: Not required. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Eye protection: Goggles recommended during refilling. 9 Physical and chemical properties · Form: · Color: · Odor: · Odour threshold: Liquid Light beige Mild Not determined. · pH-value at 20 °C: 7 · Change in condition Melting point/Melting range: Boiling point/Boiling range: 0 °C 100 °C · Flash point: Not applicable. · Flammability (solid, gaseous): Not applicable. · Ignition temperature: Decomposition temperature: Not determined. · Auto igniting: Product is not selfigniting. · Danger of explosion: Product does not present an explosion hazard. · Explosion limits Lower: Upper: Not determined. Not determined. · Vapor pressure at 20 °C: 23 hPa · Density at 20 °C: · Relative density: 1 g/cm³ Not determined. (Contd. on page 4) CA 36.0.12 Page 4/6 Safety Data Sheet acc. to OSHA HCS Printing date 10/07/2013 Reviewed on 10/07/2013 Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE (Contd. of page 3) · Vapour density at 20 °C: · Evaporation rate at 20 °C: .610 (AIR=1) 1 (BA=1) · Solubility in / Miscibility with Water: Fully miscible. · Partition coefficient (n-octanol/water): Not determined. · Viscosity: Dynamic: Kinematic: Not determined. Not determined. · Solvent content: Organic solvents: 0.0 % Solids content: · Other information 22.0 % No further relevant information available. 10 Stability and reactivity · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Possibility of hazardous reactions: No dangerous reactions known. · Conditions to avoid: No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information · Information on toxicological effects: · Acute toxicity · Primary irritant effect · on the skin: No irritant effect. · on the eye: No irritating effect. · Sensitization: No sensitizing effects known. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. · Carcinogenic categories · IARC (International Agency for Research on Cancer) 102-71-6 2,2',2''-nitrilotriethanol 3 · NTP (National Toxicology Program) None of the ingredients is listed. 12 Ecological information · Aquatic toxicity: No further relevant information available. · Persistence and degradability: No further relevant information available. · Behavior in environmental systems · Bioaccumulative potential: No further relevant information available. · Mobility in soil: No further relevant information available. (Contd. on page 5) CA 36.0.12 Page 5/6 Safety Data Sheet acc. to OSHA HCS Printing date 10/07/2013 Reviewed on 10/07/2013 Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE (Contd. of page 4) · Other adverse effects: No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Smaller quantities can be disposed of with household waste. · Uncleaned packagings · Recommendation: Place in a sealed container and label as waste. Place in a safe area, and comply with all federal, state, provincial and local regulations for disposal. · Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information · UN-Number · DOT, TDG, ADN, IMDG, IATA Not Available · UN proper shipping name · DOT, TDG, ADN, IMDG, IATA Not Available · Transport hazard class(es) · DOT, TDG, ADN, IMDG, IATA · Class Not Available · Packing group · DOT, TDG, IMDG, IATA Not Available · Environmental hazards: · Marine pollutant: No · Special precautions for user: Not applicable. · Transport in bulk according to Annex II of Not applicable. MARPOL73/78 and the IBC Code: · UN "Model Regulation": - 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. (Contd. on page 6) CA 36.0.12 Page 6/6 Safety Data Sheet acc. to OSHA HCS Printing date 10/07/2013 Reviewed on 10/07/2013 Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE (Contd. of page 5) · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Carcinogenic categories · EPA (Environmental Protection Agency): None of the ingredients is listed. · TLV (Threshold Limit Value established by ACGIH): None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health): None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients is listed. · Canadian substance listings · Canadian Domestic Substances List (DSL): All ingredients are listed. · Canadian Ingredient Disclosure list (limit 0.1%): None of the ingredients is listed. · Canadian Ingredient Disclosure list (limit 1%): 112-80-1 oleic acid, pure 16 Other information This MSDS format meets ANSI Z400.1-1998, OSHA 1910.1200 and WHMIS requirements. Kemper System America, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Product use and conditions of use are beyond the control of Kemper System America, Inc. Warranty of materials is limited to test results of product performance as detailed in certificates of compliance. Interpretation of test results is the responsibility of end-user. No other warranties, expressed or implied, are made. Kemper System America, Inc is an ISO 9001:2008 registered company. · Department issuing MSDS: Product safety department · Contact: Stephen Nowicki · Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association (USA) CA MATERIAL SAFETY DATA SHEET Contractors Steel Company P.O. Box 3364 Livonia, Michigan 48150 (734) 464 4000 / Fax (734) 452 3939 (This product may contain chemicals subject to reporting requirements of section 313, Emergency Planning and Community Right To Know Act of 1986 and of 40CFR72) Revision: March 12, 2013 Section 1 - Product Identification Manufacturers Name: VARIOUS Product Name / Trade Name Carbon and Alloy Steels ( Bar ( Hot rolled- Round, Square, Strip, Flat )( Cold Finished - Round, Square, Flat ) ( Angle - Bar size, Structural )( Channel - Bar, Structural, Junior )( Beam - Standard I, Wide Flange & H, Junior )( Sheet - Hot rolled ) ( Plate - Floor, Abrasion Resisting )( Pipe )( Tubing - Square, Rectangular )( Expanded Metal - Standard, Flattened ) ( Bar size Tees) (Grating - Standard, Bar, Stair tread, Catwalk, Grip strut ) ( Molded Cover Bar ) ( Re rod )( Threaded Rod )( Rail) ( Structural Tees )) Galvanized ( Sheet, Round, Angle, Channel ) Section 2 - Ingredients Components Base Metal Iron (Fe) Alloying Elements Aluminum (Al) CAS# 7439-89-6 balance 7429-90-5 0-.15 Antimony (Sb) Arsenic As) Beryllium (Be) Boron (B) Cadmium (Cd) 7440-36-0 7440-38-2 7440-41-7 7440-42-8 7440-43-9 <1 <1 <1 <1 <1 Calcium (Ca) Carbon (C) Chromium (Cr) Cobalt (Co) Copper (Cu) 1305-78-8 7440-4-0 7440-47-3 7440-48-4 7440-50-8 0-1 .003-.1.1 .01-1 <1 .04-1 Lead Pb) Magnesium (Mg) Manganese (Mn) Molybdenum (Mo) Niobium (Nb) Nickel (Ni) Nitrogen (N) Phosphorus (P) Selenium (Se) Silicon (Si) Sulfur (S) 7439-92-1 7439-95-4 7439-96-5 7439-98-7 7440-03-1 7440-02-0 7727-37-9 7723-14-0 7782-49-2 7440-21-3 7446-09-5 0.-0.9 0-1 0.2-2 0.01-0.8 0-1 0.01-1 <1 0-1 <1 0-3 0-1 Tin (Sn) Titanium (Ti) Tungsten (W) 7723-14-0 7440-32-6 7440-33-7 0-1 0-1 0-1 Vanadium (V) 7440-62-2 0-1 Zinc (Zn) 7440-66-6 0.-.05 % Weight (1) ACGIH TLV (mg/m3) (Threshold limit value) (2) 5 Oxide dust/fume OSHA PEL (mg/m3) (Permissible exposure limit) 10 Oxide dust/fume 10 5 .5 .01 .002 10 .01 .002 2 15 5 .5 .01 .002 15 .005 .0025 5 .5 .02 1 .2 .05 0.2 10 1.5 0.1 0.2 10 5.2 13 2 5 10 0.05 Dust Fume As Antimony as Arsenic (A1 Carcinogen) as Beryllium (A1 Carcinogen) Oxide dust as Cadmium (A2 Carcinogen) Respirable fraction Oxide dust not established Metal as Cobalt (A3 Carcinogen) Dust Fume Dust / Fume (A3 Carcinogen) Not established Elemental Mn and Inorg compounds Insoluble compounds Not established Metal simple Asphyxiant Phosphorus Selenium Dust Sulfur dioxide Sulfur dioxide (STEL) Metal, oxide and organic compounds Not established Insoluble compounds as W Insoluble compounds as W (STEL) Oxide Dust/Fume 1 .1 1 .1 .05 5 15 1 0.1 0.2 15 13 Dust Respirable fraction As Antimony as Arsenic as Beryllium Oxide dust as Cadmium as Cadmium (action level) Oxide dust not established Metal Metal/Dust/Fume Dust Fume Dust / Fume Not established Fume (ceiling) Insoluble compounds Metal and insoluble compounds simple Asphyxiant Phosphorus Selenium Dust Sulfur dioxide 2 Inorganic compounds Not established not Established 0.5 0.1 5 10 Oxide dust (ceiling) Oxide Fume (ceiling) Oxide fume Oxide dust 10 Oxide dust 5 Oxide fume 10 Oxide fume (STEL) (1) % of alloying material varies with grade of material. (2) ACGIH Threshold Limit Value. (NOTE: No OSHA PEL’s or ACGIH TLV’s exist for steel. Various grades of steel will contain different combinations of these elements and/or trace elements.. Section 3 - Physical Data Material is (at normal conditions) Solid Boiling Point (Galvanized) 908o C Appearance and Odor (Carbon) Gray-Black metallic, Odorless (Galvanized) Silver or Bluish white Vapor pressure (mm Hg.)Galvanized 1 mmHg pH N/A Section 4 - Fire and Explosion Data 487o C Solubility in water(% by weight) N/A Melting Point (Base Metal)>2500o F Specific Gravity 420o C (Galvanized) approximately 7 Vapor Density (Air = 1) No information Found (NIF) Percent Volatile by Volume (%) Evaporation Rate NIF N/A Extinguishing Media ( Base Metal) N/A (Galvanized) CO2 Dry Powder extinguisher - Do not use water Special Fire Fighting Procedures Steel products in the solid state present no fire or explosion hazard Unusual Fire and Explosion Hazards Zinc oxide fume Flash Point (method used) Auto ignition (solid zinc in oxygen) 908o C Special fire fighting procedures Self Section 5 - Reactivity Data - contained breathing apparatus Incompatibility (Materials to Avoid) Reacts with strong acids to produce Hydrogen gas Stability Stable (Galvanized)Avoid contact with acids and Alkalis Conditions to avoid N/A Hazardous Decomposition Products Zinc forms zinc oxide fumes at boiling point Metallic dust or fumes may be produced during welding, burning, grinding and machining 6-2hri3.doc Revision 03/12/13 Section 6 - Health Hazard Data Note: Steel products in their natural state do not present an inhalation, ingestion or contact hazard. However, operations such as Burning, Welding, Sawing, Brazing, Grinding and Machining may release fumes and/or dusts which may present health hazards if TLV’s are exceeded. The major exposure hazard is inhalation. Effects of overexposure to fumes and dust are as follows: ACUTE: Excessive inhalation of metallic fumes and dust may result in irritation of eyes, nose, and throat. High concentrations of fumes and dust of ironoxide, manganese, and zinc may result in metal fume fever. Typical symptoms last from 12 to 48 hours and consist of a metallic taste in the mouth, dryness and irritation of the throat, chills and fever CHRONIC: Chronic health effects (including cancer) have been associated with the fumes and dusts of individual component metals, and welding fumes as a general category have been listed by IARC as a carcinogen. See conditions listed opposite the element: Iron (Fe) siderosis, a benign pneumoconiosis, symptoms may include chronic bronchitis, emphysema, and shortness of breath, breathing fumes may result in metal fume fever. Penetration of iron particles into the skin or eye may cause an exogenous or ocular siderosis. Ingestion overexposures may affect the gastrointestinal, nervous, hematopoietic system and the liver Aluminum (Al) breathing fumes may result in metal fume fever Antimony (Sb) breathing fumes may result in metal fume fever Arsenic As) breathing fumes may result in metal fume fever Beryllium (Be) breathing fumes may result in metal fume fever No chronic debilitating symptoms indicated Bismuth no information available Boron (B) breathing fumes may result in metal fume fever, Primary target organs are the lung and kidney. Because of its cumulative nature, chronic cadmium poisoning can cause serious disease which takes many years to develop and may continue to progress despite cessation of exposure. Progression of the disease may not reflect current exposure conditions. It is also capable of causing a painful osteomalacia called “Itai-Itai” in postmenopausal women, and has caused developmental effects and/or reproductive effects in male / female animals. Cadmium is a listed carcinogen. Cadmium (Cd) No information available Calcium (Ca) No chronic debilitating symptoms indicated Carbon (C) breathing fumes may result in metal fume fever. Prolonged and repeated overexposure to dust or fumes may cause skin ulcers, nasal irritation and ulceration, kidney damage and cancer of the respiratory system. Is listed as a carcinogen Chromium (Cr) breathing fumes may result in metal fume fever Cobalt (Co) Dust and fume can irritate the eyes, nose and throat causing coughing, wheezing, nosebleeds, ulcers and metal fume fever. Other effects from repeated inhalation include a metallic or sweet taste, discoloration of skin, teeth or hair, and allergic skin reaction. Copper (Cu) breathing fumes may result in metal fume fever, Lead can accumulate in the body. Consequently, exposure to fumes or dust may produce signs of polyneuritis, diminished vision and peripheral neuropathy, such as tingling and loss of feeling in fingers, arms and legs. Lead is a known reproductive and developmental toxin. It is also associated with central nervous system disorders, anemia, kidney disfunction and neurobehavioral abnormalities. The brain is a major target organ. Lead is a listed carcinogen Lead Pb) breathing fumes may result in metal fume fever Magnesium (Mg) breathing fumes may result in metal fume fever, Bronchitis,and pneumonitis. A variety of neurological symptoms including muscle spasms, gait disturbances, tremors, and psychoses. Manganese (Mn) No information available Molybdenum Mo) No chronic debilitating symptoms indicated Niobium (Nb) breathing fumes may result in metal fume fever, Prolonged and repeated contact may cause sensitization dermatitis. Inhalation has caused lung damage as well as sinus, nasal and lung cancer in lab animals. Nickel is a listed carcinogen. Nickel (Ni) No information available Nitrogen (N) Necrosis of the mandible Phosphorus (P) breathing fumes may result in metal fume fever Selenium (Se) No chronic debilitating symptoms indicated Silicon (Si) (as sulfur dioxide) Edema of the lungs Sulfur (S) breathing fumes may result in metal fume fever Tin (Sn) No information available Titanium (Ti) No information available Tungsten (W) The major target for vanadium pentoxide toxicity is the respiratory tract. Fumes or dust can cause severe eye and respiratory irritation and systemic effects. Emphysema, pneumonia, Chronic bronchitis, green tongue, conjunctivitis, pharyngitis, rhinitis, rales, chronic productive cough, tightness of the chest, and allergic reactions have been reported following overexposure. Vanadium (V) breathing fumes may result in metal fume fever, as vanadium pentoxide - Emphysema, pneumonia Zinc (Zn) Gastrointestinal inflammation reported in animal studies Carcinogen(N.T.P.) N/A Carcinogen(I.A.R.C.) N/A Medical conditions aggravated by exposure: Individuals with chronic respiratory disorders may be adversely affected by any fume or airborne particulate matter exposure Emergency Medical Procedures: Inhalation: Remove to fresh air, if condition continues, consult a physician. Eye Contact: Flush thoroughly with running water to remove particulate, obtain medical attention. Skin Contact: Remove particles by washing thoroughly with soap and water. Seek medical attention if condition persists. Ingestion: If significant amounts of metal are ingested, consult a physician HMIS RATING - Health 0 Flammability 0 Reactivity 0 HMIS HAZARD INDEX - Minimal 0 Slight 1 Moderate 2 Serious 3 Severe 4 Section 7 - Environmental Protection Spill or Leak procedures: Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse. Waste Disposal Method: Used or unused product should be disposed of in accordance with Federal, State and Local disposal or discharge laws. Section 8 - Special Protection Information Respiratory Protection: An appropriate dust/mist/fume respirator should be used to avoid excessive inhalation of particulate. If exposure limits are reached or exceeded, use NIOSH approved equipment. Hands, Arms, and Body: Protective gloves should be worn as required for welding burning or handling operations. Eyes and Face: Face shields or goggles should be worn when grinding or cutting. Face shields should be worn when welding or cutting. Other Clothing and Equipment: As required depending on operations and safety codes In welding, precautions should be taken for airborne contaminants which may originate from components of the welding rod. Arc or Spark generated when welding or burning could be a source of ignition for combustible and flammable materials DISCLAIMER The information in this MSDS was obtained from sources which we believe are reliable, however, the information is provided without any representation or warranty, express or implied, regarding the accuracy or correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use, or disposal of the product. 6-2hri3.doc Revision 03/12/13 HEALTH 2 FLAMMABILITY 3 REACTIVITY 0 SAFETY DATA SHEET Prepared by Duro Dyne December 27, 2013 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade name: Product Identifier: Item #: Supplier Details: Information Phone No: Emergency Phone No: DURO DYNE SOLVENT BASED ADHESIVE RPG-1, RPG-5, RPG-55 5047, 5048, 5049 DURO DYNE CORPORATION 81 Spence Street Bay Shore, NY 11706 800-899-3876 800-424-9300 (CHEMTREC) 2. HAZARD IDENTIFICATION Permissible Exposure Level: Threshold Limit Value: Effects of Acute Overexposure: Eyes: Skin: Breathing: Swallowing: Effects of Chronic Overexposure: 50 ppm 50 ppm Can cause severe irritation, redness, tearing, blurred vision. Prolonged or repeated contact can cause moderate irritation, defatting, dermatitis. Excessive inhalation or vapors can cause nasal and respiratory irritation, central nervous system effects including dizziness, weakness, fatigue, nausea, headache and possible unconsciousness, and even death. Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis, which can be fatal. Prolonged or repeated exposure to N-Hexane may damage peripheral nerve tissue (that of the arms and legs) and result in muscular weakness and loss of sensation in the extremities (Peripheral Neuropathy). Methyl Ethyl Ketone may potentate (shorten time of onset) peripheral neuropathy caused by N-Hexane. Prolonged and repeated inhalation of high levels of mixed isomers of Hexane resulted kidney damage in male rats. The effects observed are the same of those seen in male rats exposed to other hydrocarbons. The mechanism by which these chemicals cause the characteristics kidney toxicity is unique to the male rat and the kidney effects are not expected to occur in man. Overexposure to this material (or its components) has been suggested as a cause of the following effects in Page 1 of 4 2. HAZARD IDENTIFICATION continued humans and may aggravate pre-existing disorders of these organs, central nervous system, and visual impairment. 3. COMPOSITION/INFORMATION ON INGREDIENTS PRINCIPAL HAZARDOUS COMPONENTS Toluene Hexane % BY WEIGHT 12.5% 55.5% CAS# 108-88-3 110-54-3 THRESHOLD LIMIT VALUE 100 ppm 50 ppm These chemicals are subject to the reporting requirements of Section 313 of Sara Title III. OSHA, NTP or IARC does not class the ingredients in this product as carcinogens. All ingredients in this product are on the TSCA Inventory. 4. FIRST AID MEASURES Skin: Eyes: Ingested: Inhalation: Primary Routes of Entry: Effects of Chronic Overexposure: Thoroughly wash exposed area with soap and water. Remove contaminated clothing. Launder contaminated clothing before re-use. Flush with large amounts of water. Lifting upper and lower lids occasionally, Get medical attention. Do not induce vomiting. Keep person warm, quiet and get medical attention. Aspiration of material into the lungs due to vomiting can cause chemical pneumonits, which can be fatal. If affected remove individual to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Keep person warm, quiet and get medical attention. Inhalation, skin contact. Prolonged or repeated exposure to N-Hexane may Damage peripheral nerve tissue(that of the arms and legs) and result in muscular weakness and loss of sensation in the extremities (Peripheral Nauropathy). Methyl Ethyl Ketone may potentate (shorten the time of onset) peripheral neuropathy caused by N-Hexane. Prolonged and repeated inhalation of high levels of mixed isomers of Hexane resulted kidney damage in male rats. The effects observed are the same of those seen in male rats exposed to other hydrocarbons. The mechanism by which these chemicals cause the characteristic kidney toxicity is unique to the male rat and the kidney effects are not expected to occur in man. Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans and may aggravate pre-existing disorders of these organs, central nervous system, and visual impairment. Page 2 of 4 5. FIRE-FIGHTING MEASURES Tag closed cup. <0°F LEL: 1.2% UEL: 6.9% Foam, dry chemical CO2, water fog or spray. Use air supplied breathing equipment for enclosed areas. Avoid breathing of vapor or fumes. Heat may build up pressure in closed containers. Cool with water spray. Flash Point (Test Method): Flammable Limits: Extinguishing Media: Special Fire Fighting Procedures: Unusual Fire & Explosion Hazards: 6. ACCIDENTAL RELEASE MEASURES Remove all ignition sources. Keep people away. Recover liquid. Add absorbent sawdust, etc. Ventilate, wipe up. Place in sealed containers. Spill Response: 7. HANDLING AND STORAGE Hygienic Practices in Handling & Storage: Flammable mixture. Do not store near heat, sparks or open flame. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor or contact with skin. Do not take internally, in an emergency call a physician. Keep out of reach of children. Do not store with strong oxidants like liquid chlorine or concentrated oxygen. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection: Skin Protection: Respiratory Protection (Specific Type): Ventilation Recommended: Other Protection: Splash goggles or safety glasses. Chemical resistant gloves. NIOSH approved dual cartridge respirator with cartridges suitable for organic solvent vapor. Adequate = to outdoors. Eye wash, safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: Specific Gravity (Water = 1): Vapor Pressure (mmHg): Percent Volatile: Vapor Density (Air = 1): Evaporation Rate (N-Butyl Aceate = 1): Solubility in Water: Appearance & Odor: Volatile Organic Content: 150°F .77 180 68% by weight 3 8 Not Soluble. Amber colored syrup, mild odor. 4.43 lbs/gal or 531 grams/liter Page 3 of 4 10. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Incompatibility/Materials to Avoid: Hazardous Polymerization: Conditions to Avoid: Hazardous Decomposition of Products: Stable None Strong oxidants like liquid chlorine. Will not occur. None If burned, fumes could contain oxides of carbon and nitrogen. 11. TOXICOLOGICAL INFORMATION No information available. 12. ECOLOGICAL INFORMATION No information available. 13. DISPOSAL METHOD Waste Disposal Method: Approved site. Obey local, state and federal regulations. 14. TRANSPORT INFORMATION Proper DOT Shipping Name: Adhesive Containing Flammable Liquid,3, PG II. 15. REGULATORY INFORMATION Chemical Family: DOT Hazard Classification: Solvent Based Adhesive UN 133 16. OTHER INFORMATION Warning: This product contains chemicals known to the State of California to cause cancer. Do not store with strong oxidants like liquid chlorine or concentrated oxygen. Hazard Rating: Health: 2 Flammability: 3 Reactivity: 0 April 3, 2012 Date SDS Prepared: THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO BE ACCURATE. BECAUSE SOME OF THE INFORMATION IS DERIVED FROM INFORMATION PROVIDED TO DURO DYNE CORPORATION FROM ITS SUPPLIERS, DURO DYNE CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SINCE THE USE OF THIS INFORMATION AND THE CONDITIONS AND USE OF THIS PRODUCT ARE CONTROLLED BY THE USER, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. THE INFORMATION IS SUPPLIED FOR YOUR INFORMATION AND CONSIDERATION AND DURO DYNE CORPORATION ASSUMES NO RESPONSIBILITY FOR USE OR RELIANCE THEREON. IT IS THE RESPONSIBILITY OF THE USER OF DURO DYNE CORPORATION PRODUCTS TO COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS. Page 4 of 4 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: Issue Date: 25-0157-5 03/11/14 Version Number: Supercedes Date: 1.06 03/22/13 SECTION 1: Identification 1.1. Product identifier 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 1.2. Recommended use and restrictions on use Recommended use Abrasive Product 1.3. Supplier’s details MANUFACTURER: DIVISION: ADDRESS: Telephone: 3M Abrasive Systems Division 3M Center, St. Paul, MN 55144-1000, USA 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200. 2.2. Label elements Signal word Not applicable. Symbols Not applicable. Pictograms Not applicable. Notes to Physician: Not applicable 2.3. Hazards not otherwise classified None. __________________________________________________________________________________________ Page 1 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 48% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient Aluminum Oxide Mineral (non-fibrous) Iron Oxide Mineral Limestone Silica Titanium Dioxide Quartz Silica Cured Resin Cloth Backing C.A.S. No. 1344-28-1 1309-37-1 1317-65-3 7631-86-9 13463-67-7 14808-60-7 Mixture Mixture % by Wt 15 - 30 5 - 15 5 - 15 1- 2 0.5 - 1.5 0.001 - 0.25 2 - 15 15 - 40 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Condition During Combustion During Combustion 5.3. Special protective actions for fire-fighters No unusual fire or explosion hazards are anticipated. __________________________________________________________________________________________ Page 2 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Observe precautions from other sections. 6.2. Environmental precautions Not applicable. 6.3. Methods and material for containment and cleaning up Not applicable. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Combustible dust may form by action of this product on another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential for secondary explosions. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Ingredient Iron Oxide Mineral C.A.S. No. 1309-37-1 Iron Oxide Mineral 1309-37-1 ROUGE 1309-37-1 Limestone 1317-65-3 US Dept of Labor - OSHA Aluminum Oxide Mineral (nonfibrous) 1344-28-1 Aluminum Oxide Mineral (nonfibrous) 1344-28-1 Chemical Manufacturer Rec Guid US Dept of Labor - OSHA Aluminum, insoluble compounds 1344-28-1 Titanium Dioxide Agency Amer Conf of Gov. Indust. Hyg. US Dept of Labor - OSHA US Dept of Labor - OSHA Amer Conf of Gov. Indust. Hyg. 13463-67-7 Amer Conf of Gov. Indust. Hyg. Limit type TWA(respirable fraction):5 mg/m3 Additional Comments TWA(as fume):10 mg/m3 TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 TWA:1 fiber/cc TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 TWA(respirable fraction):1 mg/m3 TWA:10 mg/m3 __________________________________________________________________________________________ Page 3 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse Titanium Dioxide Titanium Dioxide Quartz Silica Quartz Silica 13463-67-7 Chemical Manufacturer Rec Guid 13463-67-7 US Dept of Labor - OSHA 14808-60-7 Amer Conf of Gov. Indust. Hyg. 14808-60-7 US Dept of Labor - OSHA Silica 7631-86-9 SILICA, AMORPHOUS 7631-86-9 Chemical Manufacturer Rec Guid US Dept of Labor - OSHA 03/11/14 TWA(as respirable dust):5 mg/m3 TWA(as total dust):15 mg/m3 TWA(respirable fraction):0.025 mg/m3 TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.) TWA(as respirable dust):3 mg/m3 TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists American Indust. Hygiene Assoc : American Industrial Hygiene Association Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). 8.2.2. Personal protective equipment (PPE) Eye/face protection To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Wear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or sanding. Respiratory protection Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator __________________________________________________________________________________________ Page 4 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Solid General Physical Form: Odor, Color, Grade: Odor threshold pH Melting point Boiling Point Flash Point Evaporation rate Flammability (solid, gas) Flammable Limits(LEL) Flammable Limits(UEL) Vapor Pressure Solid Abrasive Product Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Classified Not Applicable Not Applicable Not Applicable Vapor Density Not Applicable Specific Gravity Solubility In Water Not Applicable Not Applicable Solubility- non-water Not Applicable Partition coefficient: n-octanol/ water Autoignition temperature Decomposition temperature Viscosity Not Applicable Not Applicable Not Applicable Not Applicable SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. __________________________________________________________________________________________ Page 5 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 10.6. Hazardous decomposition products Substance None known. 03/11/14 Condition Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Eye Contact: Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity: Ingredient Quartz Silica SILICA, CRYS AIRRESP Titanium Dioxide C.A.S. No. 14808-60-7 14808-60-7 13463-67-7 Class Description Grp. 1: Carcinogenic to humans Known human carcinogen Grp. 2B: Possible human carc. Regulation International Agency for Research on Cancer National Toxicology Program Carcinogens International Agency for Research on Cancer Additional Information: This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material being abraded must also be considered. This product contains titanium dioxide and quartz (crystalline) silica. Cancer of the lungs has been associated with inhalation of high levels of titanium dioxide in animal studies, and occupational exposure to inhaled quartz silica has been associated with silicosis and lung cancer. No exposure to titanium dioxide or quartz silica is expected during the normal handling and use of this product. Titanium dioxide and quartz silica were not detected when air sampling was conducted during simulated use of similar products containing these substances. Therefore, the health effects associated with titanium dioxide and quartz (crystalline) silica are not expected during the normal use of this product. Toxicological Data __________________________________________________________________________________________ Page 6 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Overall product Aluminum Oxide Mineral (non-fibrous) Aluminum Oxide Mineral (non-fibrous) Limestone Iron Oxide Mineral Route Ingestion Dermal InhalationDust/Mist (4 hours) Ingestion Dermal InhalationDust/Mist (4 hours) Ingestion Dermal Rat Value No data available; calculated ATE > 5,000 mg/kg LD50 estimated to be > 5,000 mg/kg LC50 > 2.3 mg/l Rat Rat Rat LD50 > 5,000 mg/kg LD50 > 2,000 mg/kg LC50 3.0 mg/l Rat Not available Not available Rabbit Rat LD50 6,450 mg/kg LD50 3,100 mg/kg Iron Oxide Mineral Ingestion Silica Silica Dermal InhalationDust/Mist (4 hours) Ingestion Dermal InhalationDust/Mist (4 hours) Ingestion Dermal Ingestion Rat Rabbit Rat LD50 > 5,110 mg/kg LD50 > 10,000 mg/kg LC50 > 6.82 mg/l Rat LD50 > 10,000 mg/kg LD50 estimated to be > 5,000 mg/kg LD50 estimated to be > 5,000 mg/kg Species Rabbit Rabbit Rabbit Rabbit Rabbit Value No significant irritation No significant irritation No significant irritation No significant irritation No significant irritation No significant irritation Species Rabbit Rabbit Rabbit Rabbit Rabbit Value No significant irritation No significant irritation No significant irritation No significant irritation No significant irritation Name Iron Oxide Mineral Species Human Silica Human and animal Human and animal Value Some positive data exist, but the data are not sufficient for classification Not sensitizing Aluminum Oxide Mineral (non-fibrous) Limestone Limestone Silica Titanium Dioxide Titanium Dioxide Titanium Dioxide Quartz Silica Quartz Silica Species LD50 3,700 mg/kg LD50 > 5,000 mg/kg LC50 > 0.691 mg/l ATE = acute toxicity estimate Skin Corrosion/Irritation Name Aluminum Oxide Mineral (non-fibrous) Limestone Iron Oxide Mineral Silica Titanium Dioxide Quartz Silica Serious Eye Damage/Irritation Name Aluminum Oxide Mineral (non-fibrous) Limestone Iron Oxide Mineral Silica Titanium Dioxide Skin Sensitization Titanium Dioxide Not sensitizing Respiratory Sensitization Name Species Value __________________________________________________________________________________________ Page 7 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 Germ Cell Mutagenicity Name Aluminum Oxide Mineral (non-fibrous) Iron Oxide Mineral Silica Titanium Dioxide Titanium Dioxide Quartz Silica Route In Vitro In Vitro In Vitro In Vitro In vivo In Vitro Quartz Silica In vivo Value Not mutagenic Not mutagenic Not mutagenic Not mutagenic Not mutagenic Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Aluminum Oxide Mineral (non-fibrous) Iron Oxide Mineral Route Inhalation Inhalation Species Rat Human Silica Mouse Titanium Dioxide Not Specified Ingestion Titanium Dioxide Quartz Silica Inhalation Inhalation Multiple animal species Rat Human and animal Value Not carcinogenic Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Not carcinogenic Carcinogenic Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Limestone Ingestion Not toxic to development Rat NOAEL 625 mg/kg/day Silica Ingestion Not toxic to female reproduction Rat Silica Ingestion Not toxic to male reproduction Rat Silica Ingestion Not toxic to development Rat NOAEL 509 mg/kg/day NOAEL 497 mg/kg/day NOAEL 1,350 mg/kg/day Exposure Duration premating & during gestation 1 generation 1 generation during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Limestone Inhalation respiratory system All data are negative Rat NOAEL 0.812 mg/l Exposure Duration 90 minutes Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Aluminum Oxide Mineral (non-fibrous) Inhalation pneumoconiosis | pulmonary fibrosis Human NOAEL Not available Limestone Inhalation respiratory system Human NOAEL Not available occupational exposure Iron Oxide Mineral Inhalation pulmonary fibrosis | pneumoconiosis Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for Exposure Duration occupational exposure Human NOAEL Not available occupational exposure __________________________________________________________________________________________ Page 8 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse Silica Inhalation Titanium Dioxide Inhalation respiratory system | silicosis respiratory system Titanium Dioxide Inhalation pulmonary fibrosis Quartz Silica Inhalation silicosis 03/11/14 classification All data are negative Human Some positive data exist, but the data are not sufficient for classification All data are negative Rat Causes damage to organs through prolonged or repeated exposure Human Human NOAEL Not available LOAEL 0.010 mg/l occupational exposure 2 years NOAEL Not available NOAEL Not available occupational exposure occupational exposure Aspiration Hazard Name Value Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. The substrate that was abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product may be placed in a landfill properly designed for industrial waste. EPA Hazardous Waste Number (RCRA): Not regulated SECTION 14: Transport Information Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: Regulatory information __________________________________________________________________________________________ Page 9 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 0 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA). Document Group: Issue Date: 25-0157-5 03/11/14 Version Number: Supercedes Date: 1.06 03/22/13 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available __________________________________________________________________________________________ Page 10 of 11 3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14 directly from 3M 3M USA SDSs are available at www.3M.com __________________________________________________________________________________________ Page 11 of 11 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Use of the Substance/Mixture Company : Hard Surface Cleaner : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) 2315406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666 Emergency Overview Appearance / Odor : yellow / liquid / pleasant Immediate Concerns : Caution CAUSES EYE IRRITATION. Avoid contact with skin, eyes and clothing. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : Causes: Moderate eye irritation Skin : Causes skin irritation. Inhalation : No adverse effects expected when used as directed. Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aggravated Medical Condition : Persons with pre-existing skin disorders may be more susceptible to irritating effects. 2. HAZARDS IDENTIFICATION 1/8 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table: Chemical Name Propylene glycol monobutyl ether Alkyl dimethyl benzyl ammonium chloride Alkyl dimethyl ethyl benzyl ammonium chloride (C1214) CAS-No. 5131-66-8 Weight percent 1.00 - 5.00 68391-01-5 0.10 - 1.00 68956-79-6 0.10 - 1.00 For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Skin contact : Wash off immediately with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash clothing before reuse. Thoroughly clean shoes before reuse. Inhalation : No special requirements Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Specific hazards during firefighting : Container may melt and leak in heat of fire. Further information : Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. 5. FIREFIGHTING MEASURES 2/8 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 Flash point : Note: no data available Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available 6. ACCIDENTAL RELEASE MEASURES Personal precautions : No special precautions required. Environmental precautions : Outside of normal use, avoid release to the environment. Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site. Advice on safe handling : Avoid contact with skin, eyes and clothing. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Advice on protection against fire and explosion : Normal measures for preventive fire protection. : Keep container closed when not in use. Keep in a dry, cool and well-ventilated place. 7. HANDLING AND STORAGE Handling Storage Requirements for storage areas and containers 3/8 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Occupational Exposure Limits Components Ethyl alcohol CAS-No. mg/m3 ppm 64-17-5 - 1,000 ppm Nonstandard units - Basis ACGIH STEL Occupational Exposure Limits Personal protective equipment No personal respiratory protective equipment normally required. Respiratory protection Hand protection : If prolonged or repeated contact is possible: Wear suitable gloves. Safety glasses with side-shields Eye protection Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : yellow Odor : pleasant pH : 11.8 - 12.4 Melting point : no data available Boiling point : no data available Freezing point : no data available 4/8 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 Flash point : no data available Evapouration rate : no data available Auto-ignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : 17.5 mmHg Density : 1.01 g/cm3 similar to water Water solubility : completely soluble Partition coefficient: noctanol/water : Viscosity, dynamic : no data available Relative vapour density : no data available Volatile Organic Compounds Total VOC (wt. %)* : 3% - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations Conditions to avoid : Direct sources of heat. Materials to avoid : Strong acids Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Thermal decomposition : Note: no data available Hazardous reactions : Stable under recommended storage conditions. no data available 10. STABILITY AND REACTIVITY 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 Measured > 5,000 mg/kg 5/8 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 Acute inhalation toxicity : no data available Acute dermal toxicity : LD50 Measured > 5,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : None Anticipated Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects 13. DISPOSAL CONSIDERATIONS Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport  U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport  IMDG: Proper shipping name not regulated 6/8 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 Class: UN/ID No.: Packaging group None. None. None. Air transport  ICAO/IATA: Proper shipping name Class: UN/ID No.: Packaging group not regulated None. None. None. 15. REGULATORY INFORMATION California Prop. 65 : Canada Regulations : This product is not subject to the reporting requirements under California's Proposition 65. This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 0 Reactivity 0 NFPA Ratings Health 2 Fire 0 Reactivity 0 Special - This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information 7/8 Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200 FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER Version 3.0 Print Date 03/15/2013 Revision Date 02/25/2013 MSDS Number 350000004769 This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) 8/8 MATERIAL SAFETY DATA SHEET ______________________________________________________________________________________ 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: DuctSeal 321 Synonyms: Water-Based Mastic Manufacturer/Supplier Carlisle HVAC Products 900 Hensley Lane Wylie, TX 75098 Internet Address: http://www.carlisleHVAC.com Fax Number: (972) 442-0076 Phone Numbers Medical Emergency: CHEMTREC (USA): (800) 424-9300 CHEMTREC (International): MSDS Assistance: (972) 442-6545 Fax On Demand: NA Technical Assistance: (888) 229-2199 Customer Service: (888) 229-0199 ______________________________________________________________________________________ 2. COMPONENT INFORMATION Component CAS No. Percent Range Hazardous in Blend Methanol 67-56-1 0.5 – 3.45 This product is not hazardous according OSHA 29 CFR 1910.1200. Hazards: Flammable/Combustible No Acute No Chronic No Carcinogen No Toxin Toxin Pressure No Reactive No Exposure Limit Target Organ Other 2A. OTHER INGREDIENTS Greater than 3% Component CAS No. Latex Co-polymer 24937-78-8 Calcium Carbonate 1317-65-3 Clay 1332-58-7 Chlorinated Paraffin 63449-39-8 _________________________________________________________________________________ 3. HAZARDS IDENTIFICATION Emergency and Hazards Overview: May cause moderate irritation to eyes. May be harmful if swallowed. Read and understand all health and safety information on the product label and Material Safety Data Sheet before use. Ratings Health 1 Flammability 0 Reactivity 0 Primary Route of Exposure: Skin x Inhalation x Eye x Ingestion x Health Effect Information Eye Contact: May cause eye irritation if wiped or rubbed into eyes. Skin Contact: May cause mild skin irritation on prolonged or repeated contact. Inhalation: Breathing high concentrations of vapors may cause nausea & irritation of nose, throat, & respiratory tract. Respiratory symptoms associated with pre-existing lung disorders may be aggravated by exposure to this material. Ingestion: Ingestion of large quantity may cause initial central nervous system stimulation, followed by depression. DuctSeal 321 Issued: 1 February 2014 Supersedes: 1 March 2011 Page 1 of 6 Medical Conditions Aggravated by Exposure: Prolonged exposure to vapors could aggravate pre-existing disorders in lungs, kidney and liver. 4. FIRST AID INFORMATION Eye Contact: Flush with water for 15 minutes. Get medical attention immediately. Skin Contact: Wipe off and wash skin with soap and water. Promptly remove contaminated clothing and wash before reuse. Inhalation: Remove to fresh air. If breathing has stopped, start artificial respiration. Oxygen may be administered. Consult physician immediately Ingestion: Do not induce vomiting unless directed to do so by a physician. Consult a physician immediately. Notes to Physician: This product contains ethylene glycol, Hexahydro-1, 3,5-triethyl-s-triazine (not in a reportable amount). 5. FIRES AND EXPLOSION INFORMATION Flammable Properties Flash Point: No flash to boiling Flame extension: NA Flammable Limits in Air Upper Percent: NA Lower Percent: NA Auto ignition Temperature: NA Test Method: Closed cup Test Method: NA Test Method: NA NFPA Classification: H 1 F 0 R 0 Extinguishing Media: CO2, foam, dry chemical or water spray. Fire Fighting Measures Special Fire Fighting Procedures and Equipment: Firemen must wear full-face air-supplied masks and full protective clothing. Unusual Fire and Explosion Conditions: This product is not sensitive to physical shock or static discharge. Exposure of closed container to temperatures above the boiling point could cause pressure buildup and container rupture. Hazardous Combustion By-Products: CO, CO2, unburned hydrocarbons, or nitrous oxides. DuctSeal 321 Issued: 1 February 2014 Supersedes: 1 March 2011 Page 2 of 6 ______________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personnel Safeguards: Evacuate non-essential personnel to safe areas. Clean-up responders should wear proper protective clothing and gloves before entering the affected area. Regulatory Notifications: Certain component of this product is defined as hazardous according to U.S. EPA. Spill reporting requirements and reportable quantities vary by region. Consult all applicable state and local regulations. For Canada, observe all precautions noted above. Containment and Clean up: Prevent product from entering drinking water supplies or streams. Observe above precautions, collect liquid with inert, noncombustible material and remove for disposal. 7. HANDLING AND STORAGE INFORMATION Handling: Normal use condition doesn’t produce respirable Silica. However, sanding, grinding, and burning might release respirable Silica. Keep out of reach of children. Launder contaminated clothing. Wash hands with soap and water after use, especially before eating or drinking. Storage: Store in a dry, well ventilated environment away from heat, above 35 deg F and below 110 deg F. Keep containers closed when not in use. Do not pressurize, cut weld or grind containers. Empty Container Warnings Drums: Drums may be reused after wash. Plastic: Plastic containers may be reused after wash. ______________________________________________________________________________________ 8. EXPOSURE CONTROLS / PERSONAL PROTECTION INFORMATION Exposure Limits and Guidelines Component Methanol CAS No. 67-56-1 Exposure Limit 200 ppm OSHA PEL 200 ppm ACGIH TWA, 250 ppm STEL Personal Protective Equipment Eye/Face Protection: Wear safety goggles or face shield. Contact lenses should not be worn. Skin Protection: Use protective rubber gloves (Hycron, neoprene, or nitrile). Respiratory Protection: Provide adequate ventilation to maintain vapors below PEL/TWA. If vapor levels are exceeded, use NIOSH approved respirator, both during and immediately after application, until vapor levels are below limits. Personal Hygiene: Avoid rubbing eyes during handling. Use good personal hygiene practices to avoid incidental ingestion. Engineering Controls / Work Practices Ventilation: Provide local exhaust or area ventilation to maintain concentration of vapors below PEL/TWA. Other: Source of clean water should be available in the work area for flushing eyes and skin. Wash thoroughly with soap and water after use and before eating. DuctSeal 321 Issued: 1 February 2014 Supersedes: 1 March 2011 Page 3 of 6 ______________________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES?? Appearance: Gray Mastic Odor: Typical latex with slight ammonia odor Physical state: Mastic pH: 8.4 – 9.5 DOT Corrosivity: NA Boiling Point: 212ºF Melting Point: NA Specific Gravity: 1.34-1.41 Pour Point: NA Solubility in Water: Miscible with water Octanol / Water Coefficient: Log Kow = NA Vapor Pressure: 17 mm Hg @ 20ºC Vapor Density (air=1): 300 K cps ______________________________________________________________________________________ 10. STABILITY AND REACTIVITY INFORMATION Chemical Stability: Stable Conditions to Avoid: Avoid extreme heat, fire and temperature. Incompatible Materials to Avoid: Avoid strong acids, strong oxidizers. ______________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION (will only print available data) Primary Eye Irritation: Irritating Primary Skin Irritation: NA Acute Dermal Toxicity: Product toxicity has not been determined. Subacute Dermal Toxicity: NA Dermal Sensitization: NA Inhalation Toxicity: Product toxicity has not been determined. Inhalation Sensitization: NA Oral Toxicity: Product toxicity has not been determined. Mutagenicity: NA Carcinogenicity: NA Reproductive Toxicity: Product toxicity has not been determined. Teratogenicity: NA Immunotoxicity: NA Neurotoxicity: NA No other toxicological information available ______________________________________________________________________________________ 12. ECOLOGICAL INFORMATION Aquatic Toxicity: Not known Terrestrial Toxicity: Not known Chemical Fate and Transport: Not known No other ecological information available ______________________________________________________________________________________ 13. DISPOSAL INFORMATION Regulatory Information: Consult all regulations (federal, state, provincial, local etc.) or a qualified waste disposal firm when characterizing waste for disposal. DuctSeal 321 Issued: 1 February 2014 Supersedes: 1 March 2011 Page 4 of 6 Waste Disposal Methods: Recover free liquid. Absorb residue and dispose of according to local, state and Federal EPA regulation. Empty container: may contain explosive vapors. Do Not cut, puncture or weld on or nearby. ______________________________________________________________________________________ 14. TRANSPORTATION INFORMATION U.S. Department of Transportation (DOT) Highway / Rail: Not regulated by DOT International Highway (Transportation of Dangerous Goods-TDG): Not regulated International Ocean (International Maritime Dangerous Goods – IMDG): Not regulated International Air (International Air Transportation Authority – IATA): Not regulated The DOT description is provided to assist in the proper shipping classification of this product and may not be suitable for all shipping descriptions. Other: No other information available ______________________________________________________________________________ 15. REGULATORY INFORMATION Regulatory Lists U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory or exempt from listing on the TSCA Inventory. Sara Section 313: This product contains the following Sara, Title III, Section 313 Chemicals: Chemical CAS Number Percent in Product Methanol 67-56-1 0.5 – 3.45 IARC Group: NA Regulatory Lists Searched This product contains a mixture of one or more components found on the following State List at or above OSHA de minimis quantities Health & Safety: NA Environmental: NA International: NA State: FL, MA, MN, PA, NJ, WA National Inventories: NA SARA 311 / 312 Categories (For the chemicals above) Yes Yes Acute: Chronic: Yes Fire: Pressure: Regulated: No No Reactive: No California Proposition 65 Information: Warning! None in the list Canadian WHMIS Classification Methanol DuctSeal 321 Issued: 1 February 2014 Supersedes: 1 March 2011 Page 5 of 6 Class: Class B2 and D2B This product has been classified in accordance with hazard criteria of the Controlled Products Regulations (CPR). This MSDS contains all the information required by the CPR. Canadian Environmental Protection Act (CEPA) All reportable chemical substance is listed on the Domestic Substances List (DSL) or otherwise complies with CEPA new substance notification requirements. National Pollution Release Inventory (NPRI) This product contains the following chemical subject to the reporting requirements of the CEPA subsection 16(1), NPRI. Chemical CAS Number Percent in Product Methanol 67-56-1 0.5 – 3.45 Other Regulations: No other information available. ______________________________________________________________________________________ 16. OTHER INFORMATION Health and Environmental Label Language All ingredients contained in this product are included on the US EPA Toxic Substances Control Act (TSCA) inventory or exempt from listing on the TSCA inventory. All ingredients contained in this product comply with the requirements of the Canadian Environmental Protection Act (CEPA) and are listed on the Domestic Substance List (DSL) or Non-Domestic Substance List (NDSL) MSDS Revisions Previous Version Date: 1 March 2011 Section Old Information: New Information: Prepared By: R&D Department Date: 1 February 2014 Disclaimer of Warranty: The information contained herein is based upon data and information available to us, and reflects our best professional judgment. This product may be formulated in part with components purchased from other companies. In many instances, especially when proprietary or trade secret materials are used, CCWI Company must rely upon the hazard evaluation of such components submitted by that product’s manufacturer or importer. No warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of such data or information. The results to be obtained from the use thereof, or that any such use does not infringe any patent, since the information contained herein may be applied under conditions of use beyond our control and with which we may be unfamiliar, we do not assume responsibility for the results of such application. This information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the material for his particular use. DuctSeal 321 Issued: 1 February 2014 Supersedes: 1 March 2011 Page 6 of 6 Boss Lubricants: Material Safety Data Sheet Issue Date: January 1, 2012 Product Information Product Trade Name: Boss Industrial Hydraulic Oils Transportation: Emergency Phone Number (CHEMTREC): (800) 424-9300 Chemical Name: Petroleum Oil Blend NFPA Code: Health: 0 Fire: 1 Reactivity: 0 HMIS System: Health: 0 Flamability: 1 Reactivity: 0 1. HAZARDOUS INGREDIENTS This material is not known to contain any chemical listed as a carcinogen or suspected carcinogen by OSHA, IARC or the National Toxiology Program (NIP) at a concentration greater than 0.1%. Contains refined petroleum oil and selected additives. This material is non-carcinogenic as defined by OSHA, IARC, or NIP Ventilation Procedure: Glove protection: Eye protection: Other Protection: 5. PHYSICAL DATA Vapour Pressure: >1mm Hg Specific Gravity: <1.00 @ 15.5 C Water Solubility: Slight Percent Volatile: Not determined Vapour Density: Not determined Evaporation Rate: Not determined Odor: Mild hydrocarbon odor Appearance: Amber liquid. 6. STABILITY Stability: Stable Incompatibility: Oxidizing agents Polymerization: Will not occur Thermal Decomposition: Oxides of carbon, nitrogen, phosphorus, and hydrogen sulfide. 2. FIRE AND EXPLOSION HAZARDS 216- 246 Not determined Not determined CO2 dry chemical: foam: water spray: water fog Special Firefighting Procedures: Cool containers with H2O and remove from fire exposure Unusual fire & Explosion Hazards: Empty containers could contain flammable vapours Flash point, C: Upper Flammable Limit: Lower Flammable Limit: Extinguishing Media: 3. HEALTH HAZARD DATA Normal shop ventilation adequate Oil impervious gloves recommended Not usually required, but goggles recommended None required 7. SPILL OR LEAK PROCEDURES Spill Procedures: Wear chemical splash goggles Wear rubber boots Prevent entry into sewers and waterways. Pickup free liquid for recycle/disposal Absorb small amounts of inert material for disposal Waste Disposal: Disposal should be in compliance with federal, provincial and local laws Oral Toxicity: Minimal hazard. Oral toxicity greater than 5,000 mg/kg Eye Irritation: May be an eye irritant Skin Irritation: Possible redness may result from prolonged exposure. Other: Unknown TLV: 5 mg/m3 as oil mist 8. SPECIAL PRECAUTIONS Special Precautions: Launder contaminated clothing before reuse. Wash skin thoroughly after handling. Avoid prolonged contact Emergency First Aid Procedures: Skin: Eye: Inhalation: Oral: Additional: Wash with soap Flush with large amounts of water. If irritation persists, get medical attention Remove to fresh air. See physician if irritation persists Call physician. Do not induce vomiting None 4. SPECIAL PROTECTION INFORMATION 9. TRANSPORTATION AND LABELING DOT Proper Shipping Name: Not applicable DOT Hazard Class: Not applicable 10. OTHER REGULATORY INFORMATION BOSS INDUSTRIAL HYDRAULIC OILS Boss Lubricants: Material Safety Data Sheet SARA SEC 313 SUPPLIER NOTIFICATIONS This product contains the following toxic chemical, subject to the reporting requirements of sec 313 of the energy planning and community right-to-know act of 1986 and of 40CFR372. CAS# CHEMICAL NAME %WEIGHT Available This information must be included in all MSDS’s that are copied and distributed for this material. The information presented herein has been compiled from sources considered to be dependable, and is accurate to the best of BOSS LUBRICANT’S knowledge; however, BOSS makes no warranty whatsoever, expressed or implied, of merchantability or fitness for the particular purpose, regarding the accuracy of such date or the results to be obtained from the use thereof. BOSS LUBRICANTS assumes no responsibility for injury to recipient or to third persons or for any damage to any property and recipient assumes all such risks. 11. January 1, 2011 Prepared by: Technical Services Boss Lubricants Ltd. 112, 6303 30th street S.E. Calgary, Alberta T2C 1R4 (800) 844-9457 BOSS INDUSTRIAL HYDRAULIC OILS Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free Safety Data Sheet ID: 1077 Section 1 - Product and Company Identification Hazard Label WARNING label Company Information Johns Manville Insulation Systems P.O. Box 5108 Denver, CO 80127 USA Telephone: 303-978-2000 8:00AM-5:00PM M-F Internet Address: http://www.jm.com Emergency: 800-424-9300 (Chemtrec, In English) Trade Names: 800 Series Spin Glas® Board, unfaced 1000 Series Spin Glas® Board Duct Liner PM Blended Blowing Wool Fabrication Board Hullboard (Incombustible) Hullinsul® Fiber Glass Board Incombustible Microlite® Insul-SHIELD® Coated Black Linacoustic® RC Micromat Rx™ Permacote® Linacoustic® (Types:Standard, HP and R-300) Precipitator Spin Glas® Spin Glas® HTB 26 & 23 R Series Microlite® (Plain) Spin Glas® HTB 26 & 23 Use: Lining sheet metal ducts in AC, heating and ventilation systems Section 2 - Hazards Identification Emergency Overview Inhalation of excessive amounts of dust from the product may cause temporary upper respiratory irritation and/or congestion-remove individual to fresh air. In high temperature applications, treatment, curing, or in geographic areas of high heat and humidity, this product may release gases irritating to the eyes, nose and throat. Inhalation Temporary mechanical irritation may occur upon exposure to dust or fibers released from cutting this product. Irritation of the upper respiratory tract, coughing, and congestion may occur in extreme exposures. Severe irritation of the mouth, nose, and throat, as well as signs of central nervous system depression (drowsiness, dizziness, headache), may occur upon inhalation of vapors or gases. Skin Temporary irritation (itching) or redness may occur. Ingestion This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal (digestive) tract. Eyes Temporary irritation (itching) or redness may occur. Ears Temporary irritation (itching) or redness may occur. Primary Routes of Entry (Exposure) Eyes, skin, inhalation (breathing dust and fibers) and ingestion. Target Organs Nose (nasal passages), throat, lungs, skin, eyes Medical Conditions Aggravated by Exposure Pre-existing chronic respiratory, skin, or eye diseases or conditions. Section 3 - Composition/Information on Ingredients CAS # Not Applicable Not Applicable Not Available NA 1333-86-4 Component Continuous Filament Glass Fiber Fiber Glass Wool Urea extended phenol-formaldehyde binder (cured) Acrylic Coating Carbon black, bound (present in black products only) ____________________________________________________________ Page 1 of 7 Issue Date: 01/11/2013 Revision: 1.0002 Percent 0-12 65-85 10-18 0-10 <1 Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free 50-00-0 Safety Data Sheet ID: 1077 Formaldehyde <1 Component Information Formaldehyde may be released by partial hydrolysis of the urea formaldehyde polymer. General Product Description Fibrous glass blankets or boards with glass mat facing or coating. Section 4 - First Aid Measures First Aid: Inhalation If dust is inhaled in excess of exposure limits referenced in section 8 of this safety data sheet, remove individual to fresh air. Drink water to clear throat, and blow nose to remove dust. A saline spray in the nose may help clear any fibers. First Aid: Skin Wash gently with soap and water to remove dust and fibers. Alternatively, fibers can be removed from the skin by use of ordinary masking or wrapping tape. Should irritation persist, seek medical attention. First Aid: Ingestion Rinse mouth with water to remove dust and fibers and drink plenty of water to help reduce irritation. If irritation persists, seek medical attention. First Aid: Eyes Do not rub or scratch eyes. Dust particles may cause the eye to be scratched. Flush eyes with large amounts of water until irritation subsides. If irritation persists, seek medical attention. First Aid: Ears Wash exposed skin with soap and water. If irritation develops in the inner ear, seek medical attention. First Aid: Notes to Physician Dust from the product may cause mechanical irritation of the eyes, skin, and upper respiratory tract. Treat symptomatically. Irritating gases may be released under conditions of high heat or humidity. At high levels, these could cause severe upper respiratory and eye irritation. Formaldehyde gas is a skin and respiratory sensitizer. Treatment should be directed toward removing the source of irritation with symptomatic treatment as necessary. Section 5 - Fire Fighting Measures Flash Point: Not applicable Upper Flammable Limit (UFL): Not applicable Auto Ignition: Not determined Rate of Burning: Not determined Method Used: Not applicable Lower Flammable Limit (LFL): Not applicable Flammability Classification: Not determined General Fire Hazards There is no potential for spontaneous fire or explosion. Inorganic glass fibers are naturally non-combustible and nonflammable. Extinguishing Media Carbon dioxide (CO2), water, water fog, dry chemical. Fire Fighting Equipment/Instructions No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to avoid inhalation of smoke and gases. Section 6 - Accidental Release Measures Clean-Up Procedures Pick up large pieces. Vacuum dusts. If sweeping is necessary, use a dust suppressant such as water. Do not dry sweep dust accumulation. These procedures will help to minimize potential exposures. Section 7 - Handling and Storage Handling Procedures Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in accordance with good industrial hygiene and safety practices. Storage Procedures Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and in original packaging. ____________________________________________________________ Page 2 of 7 Issue Date: 01/11/2013 Revision: 1.0002 Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free Safety Data Sheet ID: 1077 Section 8 - Exposure Controls / Personal Protection The Occupational Safety and Health Administration (OSHA) has not adopted specific occupational exposure standards for fiber glass. Fiber glass is treated as a nuisance dust and is regulated by OSHA as a particulate not otherwise regulated (total dust) shown in CFR 1910.1000 Table Z-3. Respirable fraction 5 mg/m3 Total dust 15 mg/m3 JM has adopted the fiber glass industry voluntary Product Stewardship Program (PSP), formerly the NAIMA-OSHA Health and Safety Partnership Program (HSPP). Under the PSP, JM recommends that exposures be limited to the voluntary concentration of 1 f/cc TWA for fibers longer than 5 microns with a diameter less than 3 microns. This will help minimize potential irritation effects. The PSP also includes the PPE recommendations described below. Formaldehyde (50-00-0) OSHA: 0.75 ppm TWA 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29 CFR 1910.1048) 3 ppm TWA (unless specified in 1910.1048) ACGIH: 0.3 ppm Ceiling Carbon black, bound (present in black products only) (1333-86-4) OSHA: 3.5 mg/m3 TWA 3.5 mg/m3 TWA ACGIH: 3.5 mg/m3 TWA PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Safety glasses with side shields are recommended to keep dust out of the eyes. Personal Protective Equipment: Ears Use ear protection (earplugs, hood, or earmuffs) to prevent airborne dust or fibers from entering the ear, if necessary. Personal Protective Equipment: Skin Leather or cotton gloves should be worn to protect against mechanical abrasion. See also Personal Protective Equipment: General, below. Personal Protective Equipment: Respiratory A NIOSH-approved respirator should be used if ventilation is unavailable, or is inadequate for keeping levels below the applicable exposure limits referenced in Section 8 of this SDS. Ventilation In fixed manufacturing settings, local exhaust ventilation should be provided at areas of cutting, milling or other processing to remove airborne dust and fibers. Personal Protective Equipment: General Wear a cap, a loose-fitting, long-sleeved shirt and long pants to protect skin from irritation. Exposed skin areas should be washed with soap and water after handling or working with fiber glass. Clothing should be washed separately from other clothes, and the washer should be rinsed thoroughly (run empty for a complete wash cycle). This will reduce the chances of fiber glass being transferred to other clothing. Section 9 - Physical & Chemical Properties Appearance: Physical State: Vapor Pressure: Boiling Point: Solubility (H2O): VOC: Fibrous glass blankets or boards with glass mat facing or coating with glass mat facing. Solid Not applicable Not applicable Nil Not determined Odor: Mild resin odor pH: Vapor Density: Melting Point: Specific Gravity: Not applicable Not applicable >704ºC/1300ºF Variable ____________________________________________________________ Page 3 of 7 Issue Date: 01/11/2013 Revision: 1.0002 Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free Safety Data Sheet ID: 1077 Section 10 - Stability & Reactivity Information Stability These products are not reactive. Hazardous Decomposition May form carbon dioxide and carbon monoxide. Hazardous Polymerization Will not occur. Section 11 - Toxicological Information Acute Toxicity A: General Product Information If dust evolves from this product during use it may cause temporary mechanical irritation or scratchiness of the throat and/or itching of the eyes and skin. Exposure to formaldehyde may cause eye and upper respiratory irritation, and possible respiratory or skin sensitization (allergy). If sensitization occurs, subsequent exposures to formaldehyde may worsen asthma or other respiratory problems, and cause allergic-type reactions. B: Component Analysis - LD50/LC50 Formaldehyde (50-00-0) Inhalation LC50 Rat: 0.578 mg/L/4H; Oral LD50 Rat:500 mg/kg Carbon black, bound (present in black products only) (1333-86-4) Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit:>3 g/kg Carcinogenicity A: General Product Information Exposure to formaldehyde has been associated with the development of nasopharyngeal cancer in laboratory animals and humans. Formaldehyde has been classified as a known human carcinogen, Group 1, by the International Agency for Research on Cancer (IARC). OSHA specifically regulates formaldehyde under 29 CFR 1910.1048. B: Component Carcinogenicity Fiber glass wool NTP: Not listed. IARC: Group 3 - Not Classifiable (IARC Monograph 81 [2002] (listed under Man-made mineral fibres), Monograph 43 [1988]) Formaldehyde (50-00-0) ACGIH: A2 - Suspected Human Carcinogen OSHA: 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29 CFR 1910.1048) NTP: Known to Cause Cancer IARC: Group 1 - Known Human Carcinogen Carbon black, bound (present in black products only) (1333-86-4) ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 [in preparation], Monograph 65 [1996]) Chronic Toxicity Continuous Filament Glass Fiber: No chronic health effects are known to be associated with exposure to continuous filament fiber glass. Results from epidemiologic studies have not shown any increases in respiratory disease or cancer. The International Agency for Research on Cancer (IARC) has classified continuous filament fiber glass as a Group 3 substance, not classifiable as to its carcinogenicity to humans. Because of the large diameter of continuous filament fibers, these products are not considered respirable. ____________________________________________________________ Page 4 of 7 Issue Date: 01/11/2013 Revision: 1.0002 Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free Safety Data Sheet ID: 1077 Fiber Glass Wool (non-durable glass fibers): In October 2001, IARC classified fiber glass wool as Group 3, "not classifiable as to its carcinogenicity to humans." The 2001 decision was based on current human and animal research that shows no association between inhalation exposure to dust from fiber glass wool and the development of respiratory disease In 2011, the National Toxicology Program (NTP, a component of the United States Department of Health and Human Services) issued its 12th Report on Carcinogens (Report). The Report makes clear that any glass fibers that have been successfully assessed in an animal study and shown no cancer hazard are NOT among those “certain” fibers and NOT listed in the Report. The glass fibers comprising the products on this MSDS have either been successfully assessed by appropriate animal protocols and / or have modeled Kdis values such that they are considered non-durable and the current human and animal research that shows no association between inhalation exposure to dust from fiber glass wool and the development of respiratory disease is applicable to these fibers. Section 12 - Ecological Information Ecotoxicity A: General Product Information No data available for this product. B: Component Analysis - Ecotoxicity - Aquatic Toxicity Formaldehyde (50-00-0) 96 Hr LC50 Pimephales promelas: 24.1 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 0.10 mg/L [flow-through]; 96 Hr LC50 Brachydanio rerio: 41 mg/L [static] 5 min EC50 Photobacterium phosphoreum: 9.0 mg/L; 15 min EC50 Photobacterium phosphoreum: 7.26 mg/L; 25 min EC50 Photobacterium phosphoreum: 6.81 mg/L; 30 min EC50 Photobacterium phosphoreum: 16.5 mg/L; 1 Hr EC50 Vibrio harveyi: 1.2 mg/L; 5 Hr EC50 Vibrio harveyi: 3.7 mg/L; 72 Hr EC50 Colpoda aspera: 5.39 mg/L 96 Hr EC50 water flea: 20 mg/L; 48 Hr EC50 Daphnia magna: 2 mg/L Carbon black, bound (present in black products only) (1333-86-4) 24 Hr EC50 Daphnia magna: >5600 mg/L Section 13 - Disposal Considerations US EPA Waste Number & Descriptions General Product Information This product is not expected to be a hazardous waste when it is disposed of according to the U.S. Environmental Protection Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Product characterization after use is recommended to ensure proper disposal under federal and/or state requirements. Disposal Instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. Section 14 - Transport Information International Transport Regulations These products are not classified as dangerous goods according to international transport regulations. Section 15 - Regulatory Information US Federal Regulations A: General Product Information SARA 311/312: This product is not classified as hazardous under SARA 311/312. B: Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Formaldehyde (50-00-0) SARA 302: 500 lb TPQ SARA 313: 0.1 % de minimis concentration CERCLA: 100 lb final RQ; 45.4 kg final RQ ____________________________________________________________ Page 5 of 7 Issue Date: 01/11/2013 Revision: 1.0002 Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free Safety Data Sheet ID: 1077 State Regulations A: General Product Information The glass fibers in this product are not known to be regulated. Other state regulations may apply. Check individual state requirements. WARNING: This product contains a substance known to the state of California to cause cancer: Methyl Carbamate (trace) 598-55-0 present in mat facer B: Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component CAS # CA FL MA Fiber Glass Wool (¹related to Glass, fibrous or Not Yes¹ No Yes² dust) (²related to Fibrous glass) Applicable Fiber Glass Wool (¹related to Mineral wool fiber) Not Yes¹ No Yes¹ (²related to Fibrous glass) Applicable Formaldehyde 50-00-0 Yes No Yes Carbon black, bound (present in black products 1333-86-4 Yes No Yes only) MN No NJ Yes² PA Yes² Yes Yes² Yes¹ Yes Yes Yes Yes Yes Yes The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer. A: TSCA Status This product and its components are listed on the TSCA 8(b) inventory. B: Component Analysis - Inventory Component Fiber Glass Wool Fiber Glass Wool Formaldehyde Carbon black, bound (present in black products only) CAS # Not Applicable Not Applicable 50-00-0 1333-86-4 TSCA No Yes Yes Yes DSL No Yes Yes Yes EINECS No Yes Yes Yes International Regulations A: General Product Information These products are considered articles under both U.S. and international product regulations and as such, these products do not require registration or notification on the various country-specific inventories. B: Component Analysis - WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List: Component CAS # Minimum Concentration Fiber Glass Wool Not Applicable 1 % (related to Fibrous glass) Formaldehyde 50-00-0 0.1 % WHMIS Classification Controlled Product Classification: D2A This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. This SDS contains all the information required by the Controlled Products Regulations. Section 16 - Other Information Other Information Prepared for: Johns Manville Insulation Systems P. O. Box 5108 Denver, CO USA 80217-5108 Prepared by: ____________________________________________________________ Page 6 of 7 Issue Date: 01/11/2013 Revision: 1.0002 Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free Safety Data Sheet ID: 1077 Johns Manville Technical Center P.O. Box 625005 Littleton, CO USA 80162-5005 The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial, and local laws. Date 09/30/08 09/3/2011 01/11/2013 MSDS # 1077-1.0000 1077-1.0001 1077-1.0002 Reason New SDS for new product. Regulatory update. Trade name and toxicological update in section 11. End of Sheet 1077 ____________________________________________________________ Page 7 of 7 Issue Date: 01/11/2013 Revision: 1.0002 Material Safety Data Sheet Material Name: Mineral Wool Insulation 1. Identification: 1.1 Product Generic Name: Mineral Wool Insulation 1.2 Product Use: Commercial, Industrial, Residential, and Marine Insulation 1.3 Products: AFB®, CAVITYROCK®, COMFORTBATT®, COMFORTBOARDTM, CONROCK, CURTAINROCK®, DRAINBOARD®, ENERWRAP®, FABROCKTM, FIREWALL®, MONOBOARD®, RHM®, RHT®, ROCKBOARD®, ROCKFILLTM, ROXUL Plus, SAFE®, SAFE’n’SOUND®1, STURDIROCK®, TECHTON 1200®, TECHTON 1200® MARINE, TOPROCK® 1.4 Company Address: ROXUL Inc. 420 Bronte St. S. Suite 105 Milton, Ontario Canada L9T 0H9 1.5 Web Site: www.roxul.com 1.6 If further information is required, please call or fax ROXUL Inc. Telephone: 1-800-265-6878 or 905-878-8474 Fax: 905-878-8077 1. SAFE’n’SOUND® is a registered Trademark used under license by ROXUL Inc. 2. Information on Ingredients: Ingredient Name CAS Number % Mineral Fiber RN 65997-17-3 94-99 Cured Urea Extended Phenolic Formaldehyde Binder 25104-55-6 1-6 3. Hazards Identification: 3.1 Appearance and Odor: Grey, green, brown fibrous batt, blanket, preformed pipe or board. 3.2 Emergency Overview: Acrid smoke may be generated during a fire. Exposure to dust may be irritating to the eyes, nose and throat. 3.3 Potential Health Effects: 3.3.1 Inhalation: Temporary mechanical irritation of the upper respiratory tract (scratchy throat, coughing, congestion) may result from exposures to dusts and fibers in excess of applicable exposure limits. 3.3.2 Skin Contact: Dusts and fibers may cause temporary mechanical irritation (itching) or redness to the skin. 3.3.3 Eye Contact: Dusts and fibers may cause temporary mechanical irritation (itching) or redness to the eyes. 3.3.4 Ingestion: Ingestion of this product is unlikely and not intended under normal conditions of use. Ingestion of this product may cause gastrointestinal irritation. 3.3.5 Existing Medical Conditions: Pre-existing chronic eye, skin and respiratory conditions may temporarily worsen due to exposure to dusts and fibers. Page 1 of 7 Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010 Material Safety Data Sheet Material Name: Mineral Wool Insulation 4. First-Aid Measures: 4.1 Inhalation: If irritation occurs, remove the affected person to fresh air. Drink water, and blow nose, to clear dusts and fibers from throat and nose. If irritation persists, consult a physician. 4.2 Skin: If irritation occurs, do not rub or scratch. Rinse under running water prior to washing with mild soap and water. Use a washcloth to help remove fibers. If irritation persists, consult a physician. 4.3 Eyes: If irritation occurs, flush eyes with plenty of water for at least 15 minutes. Do not rub the eyes. Consult a physician if irritation persists. 4.4 Ingestion: Ingestion of this product is unlikely and not intended under normal conditions of use. If it does occur, rinse mouth with plenty of water to help remove dust and fibers, and drink plenty of water to help reduce potential gastrointestinal irritation. Do not induce vomiting unless directed to do so by a physician. 5. Fire-Fighting Measures: The products are non-combustible and do not pose a fire hazard. However, packaging material may burn. 5.1. Suitable extinguishing media: Water, foam, carbon dioxide or dry powder 5.2 Extinguishing media which must not be used for safety reasons: None 5.3 Combustion products: Carbon dioxide, carbon monoxide and trace gases 5.4 Special protective equipment for fire-fighters: Observe normal fire fighting procedures Flash point: Flash Point Method Used: 5.5 None Not Applicable Upper Flammable Limit (UFL): Not Applicable Lower Flammable Limit: Autoignition: Not Applicable Explosive Properties: Not Applicable Not Applicable 6. Accidental Release Measures: 6.1 Containment Procedures: Pick up large pieces and scoop up dusts and fibers after they have settled out of air. These materials will disperse and settle along the bottom of waterways and ponds. It cannot easily be removed once it is waterborne, but is considered non-hazardous in water. 6.2 Cleanup Procedures: Use OSHA-recommended work practices and protective equipment as described in Section 8 of this Material Safety Data Sheet. Avoid generating airborne dusts and fibers during cleanup. Do not use compressed air. Vacuum dusts and fibers. Place material in an appropriate container for disposal as non-hazardous waste. 6.3 Response Procedures: Isolate area. Keep unnecessary personnel away. If dry methods or compressed air are used to collect dusts and fibers, all personnel in the area should wear OSHA-approved protective equipment (see Section 8 of this Material Safety Data Sheet). Page 2 of 7 Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010 Material Safety Data Sheet Material Name: Mineral Wool Insulation 7. Handling and Storage: 7.1 General Precautions: - 7.2 7.3 Utilize OSHA-recommended work practices and protective equipment when using the products (see Section 8 of this Material Safety Data Sheet). Handling: - Unpack material at application site to avoid unnecessary handling of product. - Keep work areas clean. Avoid unnecessary handling of scrap material and debris by placing such materials in suitable containers, which should be kept as close to the work area as possible. - Ensure good ventilation. Local exhaust ventilation may be required if the method of use produces dust levels which exceed applicable exposure limits (see Section 8 of this Material Safety Data Sheet). - Avoid excessive eye and skin contact with dusts and fibers. - Use recommended cleanup procedures to avoid buildup of dusts and fibers in the work area. Storage: - Keep material in original packaging until it is to be used. - Store material to protect against adverse conditions including precipitation. 8. Exposure Controls/Personal Protection: 8.1 Exposure Guidelines: 8.1.1 General Product Information: Follow all applicable exposure limits. Local regulations may apply. Roxul recommends that users of the products adhere to the OSHA-recommended PEL of 1 f/cc TWA (fibers longer than 5 m with diameters less than 3 m). This recommended PEL, together with recommended work practices and personal protective equipment, were adopted in a Health and Safety Partnership Program (HSPP) agreement in 1999 between OSHA and the North American Insulation Manufacturers Association (NAIMA), of which Roxul is a member. Adherence to the OSHA-recommended PEL, work practices and protective equipment in the HSPP is expected to provide appropriate protection against all inhalation-related health risks that may be associated with exposures to mineral wool fibers (ACGIH 1997; NAIMA 1999; OSHA 1999; National Research Council 2000, IARC 2001), and to minimize eye and skin irritation. 8.1.2 Component Exposure Limits: Page 3 of 7 Source Legal or Recommended Exposure Limit Exposure OSHA 1 f/cc TWA (recommended) Synthetic Vitreous Fibers, > 5 m length, < 3 m diameter ACGIH 1 f/cc TWA (threshold limit value – TLV) Synthetic Vitreous Fibers, > 5 m length, < 3 m diameter OSHA 15 mg/m3 TWA-PEL (total particulate) 5 mg/m3 TWA-PEL (respirable particulate) Inert dust and particulates not otherwise regulated ACGIH 10 mg/m3 TWA-TLV (inhalable particulate) 3 mg/m3 TWA-TLV (respirable particulate) Particulates not otherwise classified, containing no asbestos and <1% crystalline silica Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010 Material Safety Data Sheet Material Name: Mineral Wool Insulation 8.2 8.3 Equipment and Work Practices: Follow OSHA-recommended equipment and work practices. A complete copy of these practices can be obtained from Roxul Inc. (see Section 1 of this Material Safety Data Sheet), and is available on the OSHA website (http://www.osha.gov/SLTC/syntheticmineralfibers). 8.2.1 Follow OSHA-recommended safe handling practices listed in Section 7.2 above. 8.2.2 Where feasible, general dilution ventilation or local exhaust ventilation should be used as necessary to maintain exposures below applicable exposure limits. Dust collection systems should be used in cutting or machining operations and may be needed when using power tools. 8.2.3 Follow OSHA-recommended work practices when fabricating, installing or removing product. Personal Protective Equipment:: 8.3.1 Respiratory: 8.3.1.1 General: In poorly ventilated areas when dusty conditions exist and/or dust levels exceed applicable exposure limits, wear a NIOSH certified dust respirator with an efficiency rating of N95 or higher. Use disposable face masks complying with NIOSH respirator standards, such as a 3M Model 8210 (or 8710) (3M Model 9900 in high humidity environments) or equivalent. For exposures up to five times the established exposure limits use a quarter-mask respirator, rated N95 or higher; and for exposures up to ten times the established exposure limits use a half-mask respirator (e.g. MSA’s DM-11, Racal’s Delta N95, 3M’s 8210), rated N95 or higher. For exposures up to 50 times the established exposure limits use a full-face respirator, rated N99 or higher. 8.3.1.2 Specific Operations: In poorly ventilated areas when dusty conditions exist and/or dust levels exceed applicable exposure limits, wear a NIOSH certified dust respirator with an efficiency rating of N95 or higher, such as a 3M Model 8210 (or 8710) (3M Model 9900 in high humidity environments) or equivalent, when fabricating, installing or removing product. 8.3.2 Skin: Wear loose fitting, long sleeved and long-legged clothing to prevent irritation. A head cover is also recommended, especially when working with material overhead. The use of suitable gloves is also recommended. Skin irritation cannot occur if there is no contact with the skin. Do not tape sleeves or pants at wrists or ankles. Remove fibers from the work clothes, before leaving work to reduce potential skin irritation. If working in a very dusty environment it is advisable to shower and change clothes 8.3.3 Eyes/Face: Wear safety goggles or safety glasses with side shields. 9. Physical and Chemical Properties: 9.1 Appearance: 9.2 State: Solid 9.3 Odor: May have slight resin odour 9.4 Boiling point:: n.a. 9.5 Melting point: Approximately 2150 F (1177 C) 9.6 Vapour pressure: n.a. 9.7 Vapour Density: n.a. 9.8 Specific Gravity: n.a. 9.9 Evaporation Rate: n.a. 9.10 Freezing Point: n.a. 9.11 Viscosity: n.a. 9.12 Solubility: Insoluble (H2O) 9.13 Partition coefficient: n.a. Grey, green fibrous batt or board n.a. = not applicable Page 4 of 7 Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010 Material Safety Data Sheet Material Name: Mineral Wool Insulation 10. Stability and Reactivity: 10.1 Stability: Stable 10.2 Reactivity: Not reactive 10.3 Thermal decomposition products: Primary combustion products of the cured urea extended phenolic formaldehyde binder, when heated above 390 F (200 C), are carbon monoxide, carbon dioxide, ammonia, water and trace amounts of formaldehyde. Other undetermined compounds could be released in trace quantities. Emission usually only occurs during the first heating. The released gases may be irritating to the eyes, nose and throat during initial heat-up. Use appropriate respirators (air supplied) particularly in tightly confined or poorly ventilated areas during initial heat-up. 10.4 Hazardous Polymerization: Will not occur 10.5 Incompatible Materials: This product reacts with hydrofluoric acid. 11. Toxicological Information: 11.1 Acute Toxicity: Coarse fibers and dust from mineral wool products can cause temporary mechanical irritation (itching, redness) of the skin, and of the mucous membranes in the eyes and in the upper respiratory tract (nose and throat). The itching and possible inflammation are a mechanical reaction to dust and coarse fibers (of more than about 5 µm in diameter), and are not damaging in the way chemical irritants may be. They generally abate within a short time after the end of exposure. When products are handled continually, the skin itching generally diminishes. 11.2 Chronic Toxicity: 11.2.1 Summary: In October 2001, IARC completed a re-evaluation of respirable mineral wool fibers and classified them in Group 3 (not classifiable as to their carcinogenicity to humans). A summary of the most important scientific studies appears below: 11.2.2 Human Data: 11.2.2.1 The possible carcinogenic effects of exposure to mineral wool fibers has been evaluated in a number of epidemiological (human) studies. Most of this research, including large long-tem studies of mineral wool production workers in the U.S. and Europe, has been sponsored or supported by the North American and International thermal insulation industries, including Roxul Inc. Published reports of the early results of these studies identified significantly elevated rates of respiratory cancer in several subcohorts of the worker populations under evaluation (e.g., Simonato et al. 1987; Enterline et al. 1987). However, the studies had several methodological limitations, including failure to control for confounding exposures to other possible causes of the elevated cancer risk, including tobacco use and occupational exposures to recognized carcinogens such as asbestos. For these reasons, the authors of these reports did not interpret the results as establishing an association between exposure to mineral wool fibers and an increased risk of cancer. Several of these earlier reports formed part of the basis for IARC’s previous classification of mineral wool fibers in Group 2B (possibly carcinogenic to humans) (IARC 1987). 11.2.2.2 Follow-up studies, including case-control studies designed to exclude the contribution of confounding exposures to the cancer experience of the study populations, found no evidence that mineral wool fibers are associated with an increased cancer risk (Marsh et al. 1996; Wong, et al. 1991; Kjaerheim et al. 2001). In announcing the new Group 3 classification for mineral wool fibers, IARC stated: “Epidemiologic studies published during the 15 years since the previous IARC Monographs review of these fibers in 1988 provide no evidence of increased risks of lung cancer or of mesothelioma (cancer of the lining of the body cavities) from occupational exposures during manufacture of these materials” (IARC 2001). 11.2.3 Animal Data: 11.2.3.1 Several studies of intraperitoneal injection of high doses of mineral wool fibers have produced significant increases in the incidence of mesothelioma (IARC 2002). The intraperitoneal injection studies formed part of the basis for IARC’s previous (IARC 1987) Group 2B classification for mineral wool fibers. Leading scientists agree that intraperitoneal injection studies (i.e., surgical implantation or injection into the chest or abdomen) are the least relevant type of animal study for evaluating Page 5 of 7 Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010 Material Safety Data Sheet Material Name: Mineral Wool Insulation potential human risk for fiber exposures, because such studies bypass the animals’ natural defense mechanisms and involve a type and pattern of exposure (implantation of a high dose early in life) that does not mimic human patterns of exposure (inhalation of much lower doses over a lifetime) (National Research Council 2000). 11.2.3.2 A well-designed long-term inhalation study in rats exposed to mineral wool fibers found no significant increase in lung tumor incidence, and no mesotheliomas (IARC 2002). Likewise, in two intratracheal instillation studies of mineral wool fibers, no significant increase in the incidence of lung tumors or mesotheliomas was found (IARC 2002). Inhalation studies are regarded as the most relevant type of animal data for evaluating potential human risk, and intratracheal instillation studies, while less relevant, are considered valuable for the initial screening of fibrous compounds (National Research Council 2000). Thus, evaluating all the available animal studies in conjunction with the human data, IARC’s most recent review finds “inadequate evidence overall for any cancer risk” from mineral wool fibers (IARC 2001). 11.3 Evaluations of Potential Carcinogenicity: Source Classification Description IARC Group 3 Not Classifiable as a Human Carcinogen ACGIH Group A3 Confirmed Animal Carcinogen with Unknown Relevance to Humans 12. Ecological Information: 12.1 Ecotoxicity: No data available for the products. The products are stable, are not expected to cause harm to animals, plants or fish, and have no other known adverse environmental effects. 12.2 Environmental Fate: No data available for the products. 13. Disposal Considerations: 13.1 US EPA Waste Number & Descriptions: 13.1.1 General Product Information: The products, as supplied, are not expected to be a characteristic hazardous waste under RCRA if discarded. 13.1.2 EPA Waste Numbers: No EPA Waste Numbers are applicable for this product's components. 13.2 Disposal Instructions: Product is not considered a hazardous waste. Dispose of waste material according to Federal, State, Provincial, and Local environmental regulations. 14. Transport Information: 14.1 General: No special precautions. 14.2 US DOT Information: This product is not classified as a hazardous material for transport. 15. Regulatory Information: 15.1 U.S. Regulations: 15.1.1 Toxic Substances Control Act (TSCA): All components in this product are listed, as required, on the US EPA TSCA inventory, or are not required to be listed 15.1.2 CERCLA: Includes mineral fiber emissions from facilities manufacturing or processing glass rock or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less; Statutory RQ = 1 pound (.454 kg); no final RQ is being assigned to the generic or broad class (related to Fine mineral fibers). Page 6 of 7 Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010 Material Safety Data Sheet Material Name: Mineral Wool Insulation 15.1.3 Clean Air Act: Mineral wool fiber appears on the Clean Air Act-1990 Hazardous Air Pollutants List. 15.2 State and Local Regulations: State, Provincial, and Local regulations not identified in this Material Safety Data Sheet may apply. 15.3 WHMIS: The products have been classified in accordance with the hazard criteria of the Controlled Product Regulations and this Material Safety Data Sheet contains all the information required by the Controlled Product Regulations 15.3.1: WHMIS IDL: No components are listed on the IDL 15.3.2: WHMIS Classification: No components are classified as controlled products. 16. Further Information: 16.1 Potential Health Effects: IARC Monograph Man-made Vitreous Fibres, press release October 2001 Safety in the Use of Mineral and Synthetic Fibers, Occupational Safety and Health Series. International Labor Office (ILO). Information about “Health and Safety Research on Rock- and Slag-wool” can be obtained from the North American Insulation Manufacturers Association (NAIMA), 44 Canal Center Plaza, Suite 310, Alexandria, VA 22314, USA). Home-page: http://www.naima.org 16.2 Key/Legend: ACGIH = American Conference of Governmental Industrial Hygienists; CAA = Clean Air Act; CAS = Chemical Abstracts Service; CERCLA = Comprehensive Environmental Response, Compensation and Liability Act; DOT = Department of Transportation; EPA = Environmental Protection Agency; HMIS = Hazardous Material Identification System; HSPP = Health and Safety Partnership Program; IARC = International Agency for Research on Cancer; MSDS = Material Safety Data Sheet; NAIMA = North American Insulation Manufacturers Association; NFPA = National Fire Protection Association; NIOSH = National Institute for Occupational Safety and Health; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit; RCRA = Resource Conservation and Recovery Act; RQ = Reportable Quantity; SVF = synthetic vitreous fibers; TSCA = Toxic Substances Control Act; TWA = time-weighted average; WHMIS = Workplace Hazardous Materials Information System. 16.3 References: Complete citations, or copies, of all references cited in this Material Safety Data Sheet can be obtained from Roxul Inc. (see Section 1). 16.4 Accuracy: The information contained herein is based upon data considered to be accurate. However, no warranty is expressed or implied regarding the accuracy of these data, the results to be obtained from the use thereof, or that any such use will not infringe upon any patent. This information is furnished as a guide only and upon the condition that the person receiving it shall make tests to determine the accuracy and suitability for his or her own purpose. Page 7 of 7 Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010 (Effective Date January 1, 2014) MATERIAL SAFETY DATA SHEET Manufacturer’s Data: Floor Sweep, Inc. 4239 Joe Street Charlotte, N.C. 28206 Telephone : 704-596-4570 Fax : 704-596-5588 Contact: Robin D. Garner I. Product Identification Oil Base :Sweeping compound (Intended use on concrete or non-waxed surfaces) Wax Base : Sweeping compound (Intended use on resilient tile,linoleum,terazzo) Ingredients : Trade Secret, Info withheld per OSHA (CFR 1910.1200) II. Hazardous Components No known hazardous components per 29 CFR 1910.1200 NFPA Codes: Health code: 1, Flammability: 1, Reactivity: 0, Personal protection: N/A III. Physical and Chemical Characteristics Volatility and Solubility : Nil Appearance : Oil Base - Green with Pine Scent Wax Base - Red with Pine Scent IV. Fire and Explosion Data Flashpoint : Greater than 350 degrees F The compounds should be stored away from fire sources. If ignited by exposure to high temperatures, treat as sawdust fire and extinguish with CO2 or Foam. Considered Stable: Will not flash spontaneously. V. Health Hazard Data First Aid Procedures : The products require no respiratory or other forms of protective equipment as there is little or no effects form overexposure. If irritation occurs, wash irritated area with soap and water. VI. Environmental Protection Sweep up and dispose utilizing permitted industrial waste disposal site. Not considered EPA hazardous waste. VII. Other Data : Instructions for use, and Shelf Life Data Products should be applied to floor surface and swept up immediately as surface could become slippery if applied for extended periods of time. Shelf Life : Products should be used within 6 months from date of purchase. MATERIAL SAFETY DATA SHEET SECTION 1 – PRODUCT INFORMATION Product Name: Propane Trade Name: Supplier: Superior Propane A Division of Superior Plus LP 1111 - 49th Avenue N.E. Calgary, AB T2E 8V2 Business: (403) 730-7500 LPG (Liquefied Petroleum Gas), LP-Gas Chemical Formula: C3H8 WHMIS Classification Class A – Compressed Gas Class B, Division 1 – Flammable G 24-Hour Emergency Contact: Canutec (613) 996-6666 Application and Use: Propane is commonly used as a fuel for heating, cooking, automobiles, forklift trucks, crop drying and welding and cutting operations. Propane is used in industry as a refrigerant, solvent and as a chemical feedstock. SECTION 2 – HAZARDOUS INGREDIENTS COMPONENTS Propane LD 50 (RAT, ORAL) % VOLUME (v/v) CAS No 74-98-6 90% -99% Not Applicable Propylene 115-07-1 0% - 5% Not Applicable E thane 74-84-0 0% - 5% Not Applicable Butane and heavier hydro carbons 106-97-8 0% - 2.5% Not Applicable Occupational Exposure Limit: Based upon animal test data, the acute toxicity of this product is expected to be inhalation: 4 hour LC50 = 280,000 ppm (Rat) Note: Composition is typical for HD-5 Propane per The Canadian General Standard Board CGSB 3.14 National Standard of Canada. Exact composition will vary from shipment to shipment. SECTION 3 – CHEMICAL AND PHYSICAL DATA Form: Liquid and vapour while stored under pressure Boiling Point: -42°C @ 1 atm Freezing Point: -188°C Evaporation Rate: Rapid (Gas at normal ambient conditions) Vapour Pressure: 1435 kPa (maximum) @ 37.8°C Vapour Density: 1.52 (Air = 1) pH: Not available Solubility in Water: Slight, 6.1% by volume @ 17.8°C Specific Gravity: 0.51 (water = 1) Appearance/Odour: Colourless liquid and vapour while stored under pressure. Colourless and odourless gas in natural state at any concentration. Commercial propane has an odourant added, ethyl mercaptan, which has an odour similar to boiling cabbage. Coefficient of Water/Oil Distribution: Not available Odour Threshold: 4800 ppm With proper handling, transportation and storage, adding a chemical odourant such as ethyl mercaptan has proven to be a very effective warning device, but all odourants have certain limitations. The effectiveness of the odourant may be diminished by a person’s sense of smell, by competing odours and by oxidation which may cause a potentially dangerous situation. SECTION 4 – FIRE OR EXPLOSION HAZARD Flash Point: -103.4°C Method: Closed cup Flammable Limits: Lower 2.4%, Upper 9.5% Auto Ignition Temperature: 432 °C Hazardous Combustion Products: Carbon monoxide can be produced when primary air and secondary air are while combustion is taking place. Fire and Explosive Hazards: Explosive air - vapour allowed to leak to atmosphere. Sensitivity to Impact: No Sensitivity to Static Discharge: Fire Extinguishing Precautions: Use water spray to cool exposed cylinders or tanks. Do not extinguish fire unless the source of the escaping gas that is fueling the fire can be turned off. Fire can be extinguished with carbon dioxide and/or dry chemical (BC). Container metal shells require cooling with water to prevent impingement and the weakening of metal. If sufficient water is not available to protect the container shell from weakening, the area will be required to be evacuated. If gas has not ignited, liquid or vapour may be dispersed by water spray or flooding. Special Fire Fighting Equipment: Protective clothing, hose monitors, fog nozzles, self-contained breathing apparatus material, drains and openings to building Yes SECTION 5 – REACTIVITY DATA Conditions to Avoid: Keep separate from oxidizing agents. Gas explodes spontaneously when mixed with chloride dioxide. Incompatibility: Remove sources of ignition and observe distance requirements for storage tanks from combustible MSDS-Propane-32003-2 (01/14) Hazardous Decomposition Products: Deficient primary and secondary air can produce carbon monoxide. Hazardous Polymerization: Will not occur. Side 1 of 2 SECTION 6 – TOXICOLOGICAL PROPERTIES OF MATERIAL Routes of Entry: Skin Contact, Eye Contact, Inhalation Acute Exposure: Contact with Liquefied Petroleum Gas may cause frostbite or cold burns. Propane acts as a simple asphyxiant as oxygen content in air is displaced by the propane. At increasing concentration levels, propane may cause dizziness, headaches, loss of coordination, fatigue, unconsciousness and death. Inhalation: Simple asphyxiant. No effect at concentrations of 10,000 ppm (peak exposures). Higher concentrations may cause central nervous system disorder and/or damage. Lack of oxygen may cause dizziness, loss of coordination, weakness, fatigue, euphoria, mental confusion, blurred vision, convulsions, breathing failure, coma and death. Breathing high vapour concentrations (saturated vapours) for a few minutes may be fatal. Saturated vapours may be encountered in confined spaces and/or under conditions of poor ventilation. Avoid breathing vapours or mist. Chronic Exposure: exposure. No reported effects from long term low level Sensitization to Product: Not known to be a sensitizer. Occupational Exposure Limits: American Conference of Governmental Industrial Hygienists (ACGIH) lists as a simple asphyxiant. Skin and Eye Contact: Exposure to vapourizing liquid may cause frostbite (cold burns) and permanent eye damage. ACGIH TLV: 1000 ppm Carcinogenicity, Reproductive Toxicity, Teratogenicity, Mutagenicity: No effects reported. Ingestion: Not considered to be a hazard. Other Toxicological Effects: None SECTION 7 – PREVENTATIVE MEASURES Eyes: Safety glasses or chemical goggles are recommended when transferring product. Skin: Insulated gloves required if contact with liquid or liquid cooled equipment is expected. Wear gloves and long sleeves when transferring product. Inhalation: Where concentration in air would reduce the oxygen level below 18% air or exceed occupational exposure limits in section 6, self-contained breathing apparatus is required. Ventilation: Use in well-ventilated areas. Use with explosion proof mechanical ventilation in confined spaces or poorly ventilated areas. SECTION 8 – EMERGENCY AND FIRST AID PROCEDURES Eyes: Should eye contact with liquid occur, flush eyes with lukewarm water for 15 minutes. Obtain immediate medical care. Skin: In case of Cold Burn from contact with liquid, immediately place affected area in lukewarm water and keep at this temperature until circulation returns. If fingers or hands are frostbitten, have the victim hold his hand next to his body such as under the armpit. Obtain immediate medical care. Ingestion: None considered necessary. Inhalation: Remove person to fresh air. If breathing is difficult or has stopped, administer artificial respiration. Obtain immediate medical care. Spill or Leak: Eliminate leak if possible. Eliminate source of ignition. Ensure cylinder is upright. Disperse vapours with hose streams using fog nozzles. Monitor low areas as propane is heavier than air and can settle into low areas. Remain upwind of leak. Keep people away. Prevent vapour and/or liquid from entering into sewers, basements or confined areas. SECTION 9 – TRANSPORTATION, HANDLING AND STORAGE • • Transport and store cylinders and tanks secured in an upright position in a ventilated space away from ignition sources (so the pressure relief valve is in contact with the vapour space of the cylinder or tank). Cylinders that are not in use must have the valves in the closed position and be equipped with a protective cap or guard. Transportation of Dangerous Goods (TDG) TDG Classification: Flammable Gas 2.1 • Do not store with oxidizing agents, oxygen, or chlorine cylinders. • Empty cylinders and tanks may contain product residue. Do not pressurize, cut, heat or weld empty containers. • Transport, handle and store according to applicable federal and provincial codes and regulations. TDG Shipping Name: Liquefied Petroleum Gas (Propane) PIN Number: UN1075 SECTION 10 – PREPARATION INFORMATION Prepared by: Superior Propane Health Safety and Environment Team Telephone: (403) 730-7500 Revision: January 17, 2014 Supersedes: January 17, 2011 The information contained herein is believed to be accurate. It is provided independently of any sale of the product. It is not intended to constitute performance information concerning the product. No express warranty, implied warranty of merchantability or fitness for a particular purpose is made with respect to the product information contained herein. MSDS-Propane-32003-2 (01/14) Side 2 of 2 MATERIAL SAFETY DATA SHEET ISSUE DATE: 5/4/98 REVISED DATE: 6/22/12 Supersedes: Any Previous M.S.D.S. On This Product EMERGENCY PHONE NUMBER: CHEM-TEL, INC. 1-800-255-3924 I. IDENTIFICATION PROtack/PROtack HV PRODUCT NAME: PRODUCT CLASS: Water Based Duct Liner Adhesive DUCTMATE INDUSTRIES, INC. 210 5th St. Charleroi, PA 15022 II. HAZARDOUS INGREDIENTS REPORTING REQUIREMENTS: OSHA Hazard Communication Standard (29CFR1910.1200) hazard class………………….….None EPA SARA Title III Section 312 (40CFR370) hazard class……………………………………..None EPA SARA Title III Section 313 (40CFR372) toxic chemicals above “de minimis” level are….None CALIFORNIA PROP 65 substances listed by the State of California under the “Safe Drinking Water and Toxic Enforcement Act of 1986”. No such substances are present in reportable amounts for occupational exposure as per OSHA’s approval of the California Hazard Communication Standard, Federal Register, page 31159 ff, 6 June 1997. III. PHYSICAL DATA APPEARANCE: Grey Liquid SOLUBILITY IN WATER: Dilutable BOILING POINT: 100 C / 212 F WEIGHT PER GALLON: 9.5 .2 lbs./gallon VOLATILE BY WEIGHT: 60% 2% (Water) VAPOR DENSITY: Heavier than Air. EVAPORATION RATE: Slower than Ether. ODOR: Mild PHYSICAL STATE: Liquid Ph: 8 to 9.5 VOC CONTENT: 40 g/L EPA Method 24 IV. HEALTH AND FIRST AID CAUTION: May cause discomfort in eyes. Prolonged or repeated contact with skin may cause dryness. IN EYES: Flush with water for 15 minutes. ON SKIN: Wash with soap and water. INGESTED: Seek medical attention. INHALATION: No effects expected. If difficulty breathing occurs remove to fresh air and consult physician. V. FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASS (OSHA/NFPA): None. FLASH POINT: >212 F PM Closed Cup EXTINGUISHING MEDIA: Water or dry type extinguisher. UNUSUAL FIRE HAZARD: Containers may burst when exposed to extreme heat. FIRE FIGHTING PROCEDURES: Firemen should wear equipment to protect against noxious fumes. apparatus may be needed. PRODUCT OF COMBUSTION: May yield Carbon Monoxide and/or Carbon Dioxide. Self contained breathing VI. SPILL OR LEAK PROCEDURES Dike area to prevent spill from spreading. Collect spilled material in salvage container. Small amounts may be absorbed into appropriate absorbents. Prevent spill from entering sewers, drains, and waterways. Dispose of product in accordance with applicable local, state, and federal regulations. VII. SPECIAL PROTECTION VENTILATION: Provide sufficient ventilation to maintain constant fresh air in workplace. EYE PROTECTION: Use safety goggles when splash potential exists. HAND PROTECTION: Protective impervious gloves are recommended. OTHER: A clean source of water should be available for washing eyes and skin. VIII. TRANSPORTATION INFORMATION Non-flammable, as a Latex compound U.S.A.: Regulation by the following: DOT, IMO, ICAD/IATA: None Canada: Regulation by the following: DSL, WHMIS: None European: EEC SYMBOL: None EEC Classification, Packaging and Labeling of Dangerous Substances: None TSCA 12(b) Export Notification Requirement: TSCA 12(b) Export Notification Requirement: All components of this product are either listed on the U.S. Toxic Substances Control Act (TSCA) inventory of chemicals or are otherwise compliant with TSCA regulations. Acrylic Acid residual monomer CAS# 79-10-7 IX. REACTIVITY DATA STABILITY: Stable under normal conditions of handling and use. INCOMPATIBILITY: Products may react violently with products that react with water. HAZARDOUS DECOMPOSITION: Fumes produced when heated to decomposition may include: oxides of carbon, nitrogen, and sulfur along with hydrocarbon residues. HAZARDOUS POLYMERIZATION: Will not occur. X. SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in tightly closed containers, at temperatures 45 F to 90 F. Guard against inhalation of excess vapors, ingestion, and contact with skin and eyes. Change soiled workclothes frequently. Clean hands after handling. Precautions also apply to emptied containers. Keep containers away from extreme heat and cold. Prevent from freezing, but if product is allowed to freeze, thaw completely before use. This information is taken from sources or based upon data believed to be reliable; however, DUCTMATE INDUSTRIES, INC. makes no warranty as to the absolute correctness or sufficiency of any of the foregoing or that additional or other measures may not be required under particular conditions. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist, as all materials may present unknown health hazards. 199/6-12 USED OIL MATERIAL SAFETY DATA SHEET SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: USED OIL SYNONYMS: Waste oil; Used lubricating oil; Oil and water mixture PRODUCT PART NUMBER(S): Not applicable. PRODUCT USE: Oil or water mixture for re-refining or reprocessing. If this product is used in combination with other products, refer to the Material Safety Data Sheets for those products. These numbers are for emergency use only. If you desire non-emergency product information, please call a phone number listed below. 24-HOUR EMERGENCY PHONE NUMBERS MEDICAL AND TRANSPORTATION (SPILL): 1-800-468-1760 MANUFACTURER/ SUPPLIER: Safety-Kleen Systems, Inc. 2600 North Central Expressway Suite 400 Richardson, Texas 75080 USA 1-800-669-5740 www.safety-kleen.com TECHNICAL INFORMATION: 1-800-669-5740 Press 1 then 1 then Extension 7500 MSDS FORM NUMBER: 81451 ISSUE: September 15, 2013 ORIGINAL ISSUE: January 15, 1990 SUPERSEDES: September 15, 2010 PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force Revision 9/13; MSDS Form No. 81451 - Page 1 of 10 USED OIL MATERIAL SAFETY DATA SHEET SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS WT% NAME SYNONYM CAS NO. TWA OSHA PEL STEL ACGIH TLV® TWA STEL 80 to 100 Lubricating oils, used Used oil 70514-12-4 N. Av. N. Av. N. Av. N. Av. LDa N. Av. LCb N. Av. 0 to 20* Water/solids N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. 0 to 10* Hydrocarbon solvents. May include gasoline, diesel fuel, jet fuel, mineral spirits, etc. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. 0 to 1.5* Metals. May include lead, iron, zinc, copper, chromium, arsenic, nickel, and others: each below 1.0 WT%. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. 0 to 1.0* Polynuclear aromatics. May include naphthalene, fluoranthene, phenanthrene, pyrene, and others: each below 0.3 WT%. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. 0 to 0.5* Chlorinated solvents. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N.Av. = Not Available *Even though the concentration range does not fall under the ranges prescribed aOral-Rat LD (mg/kg) 50 by WHMIS, this is the actual range which varies with each batch of the product. bInhalation-Rat LC 50 SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW APPEARANCE Liquid, black and viscous (thick), petroleum odor. WARNING! PHYSICAL HAZARDS Combustible liquid. HEALTH HAZARDS May be harmful if inhaled. May be harmful if absorbed through skin. May be harmful or fatal if swallowed. May irritate the respiratory tract (nose, throat, and lungs), eyes, and skin. Suspect cancer hazard. Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Contains material which can cause birth defects. Contains material which can cause central nervous system damage. ENVIRONMENTAL HAZARDS Product may be toxic to fish, plants, wildlife, and/or domestic animals. Revision 9/13; MSDS Form No. 81451 - Page 2 of 10 USED OIL MATERIAL SAFETY DATA SHEET POTENTIAL HEALTH EFFECTS Effects may vary depending on material composition. Typical effects may include: INHALATION High concentrations of vapor or mist may be harmful if inhaled. High (BREATHING): concentrations of vapor or mist may irritate the respiratory tract (nose, throat, and lungs). High concentrations of vapor or mist may cause nausea, vomiting, headaches, dizziness, loss of coordination, numbness, and other central nervous system effects. Massive acute overexposure may cause rapid central nervous system depression, sudden collapse, coma, and/or death. EYES: May cause irritation. SKIN: May cause irritation. Product may be absorbed through the skin and cause harm as noted under INHALATION (BREATHING). INGESTION May be harmful or fatal if swallowed. May cause throat irritation, (SWALLOWING): nausea, vomiting, and central nervous system effects as noted under INHALATION (BREATHING). Breathing product into the lungs during ingestion or vomiting may cause lung injury and possible death. MEDICAL CONDITIONS Individuals with pre-existing cardiovascular, liver, kidney, AGGRAVATED BY respiratory tract (nose, throat, and lungs), central nervous EXPOSURE: system, eye, and/or skin disorders may have increased susceptibility to the effects of exposure. CHRONIC: CANCER INFORMATION: Prolonged or repeated inhalation may cause oil pneumonia, lung tissue inflammation, fibrous tissue formation, and/or toxic effects as noted under INHALATION (BREATHING). Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis). This product contains mineral oils, untreated or mildly treated, which can cause cancer. This product may contain hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics which can cause cancer. Risk of cancer depends on duration and level of exposure. For more information, see SECTION 11: CARCINOGENICITY. POTENTIAL ENVIRONMENTAL EFFECTS Product may be toxic to fish, plants, wildlife, and/or domestic animals. Also see SECTION 12: ECOLOGICAL INFORMATION. Revision 9/13; MSDS Form No. 81451 - Page 3 of 10 USED OIL MATERIAL SAFETY DATA SHEET SECTION 4: FIRST AID MEASURES INHALATION: (BREATHING) Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Oxygen should only be administered by qualified personnel. Someone should stay with victim. Get medical attention if breathing difficulty persists. EYES: If irritation or redness from exposure to vapor develops, move away from exposure into fresh air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15 minutes. Get medical attention. SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical attention if irritation or pain develops or persists. INGESTION: (SWALLOWING) Do NOT induce vomiting. Immediately get medical attention. Call 1-800-468-1760 for additional information. If spontaneous vomiting occurs, keep head below hips to avoid breathing the product into the lungs. Never give anything to an unconscious person by mouth. NOTE TO PHYSICIANS: Treat symptomatically and supportively. Treatment may vary with condition of victim and specifics of incident. Call 1-800-468-1760 for additional information. SECTION 5: FIRE FIGHTING MEASURES FLASH POINT: >200°F (93°C) (minimum) Pensky-Martens Closed Cup FLAMMABLE LIMITS IN AIR: Not available. AUTOIGNITION TEMPERATURE: Not available. HAZARDOUS COMBUSTION PRODUCTS: CONDITIONS OF FLAMMABILITY: Decomposition and combustion materials may be toxic. Burning may produce phosgene gas, nitrogen oxides, carbon monoxide, and unidentified organic compounds. Heat, sparks, or flame. Product may burn but does not ignite readily. EXTINGUISHING MEDIA: Use carbon dioxide, regular foam, dry chemical, water spray, or water fog. Revision 9/13; MSDS Form No. 81451 - Page 4 of 10 USED OIL MATERIAL SAFETY DATA SHEET NFPA 704 HAZARD IDENTIFICATION: This information is intended solely for the use by individuals trained in this system. FIRE HAZARD (RED) HEALTH HAZARD (BLUE) 1 SPECIFIC HAZARD (WHITE) 1 0 0 REACTIVITY (YELLOW) FIRE FIGHTING INSTRUCTIONS: Keep storage containers cool with water spray. A positive-pressure, self-contained breathing apparatus (SCBA) and full-body protective equipment are required for fire emergencies. FIRE AND EXPLOSION HAZARDS: Heated containers may rupture. “Empty” containers may retain residue and can be dangerous. Product is not sensitive to mechanical impact. Product may be sensitive to static discharge, which could result in fire or explosion. SECTION 6: ACCIDENTAL RELEASE MEASURES Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist. A vapor suppressing foam may be used to reduce vapors. Contain spill away from surface waters and sewers. Contain spill as a liquid for possible recovery, or sorb with compatible sorbent material and shovel with a clean, sparkproof tool into a sealable container for disposal. Additionally, for large spills: Water spray may reduce vapor, but may not prevent ignition in closed spaces. Dike far ahead of liquid spill for collection and later disposal. There may be specific federal regulatory reporting requirements associated with spills, leaks, or releases of this product. Also see SECTION 15: REGULATORY INFORMATION. Revision 9/13; MSDS Form No. 81451 - Page 5 of 10 USED OIL MATERIAL SAFETY DATA SHEET SECTION 7: HANDLING AND STORAGE HANDLING: Keep away from heat, sparks, or flame. Where flammable mixtures may be present, equipment safe for such locations should be used. Use clean, sparkproof tools and explosion-proof equipment. When transferring product, storage tanks, tanker trucks, and rail tank cars should be grounded and bonded. Do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with eyes, skin, clothing, and shoes. Do not smoke while using this product. SHIPPING AND STORING: Keep container tightly closed when not in use and during transport. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away from heat, flame, sparks, static electricity, or other sources of ignition. Empty product containers may retain product residue and can be dangerous. See SECTION 14: TRANSPORT INFORMATION for Packing Group information. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Use general ventilation, process enclosures, local exhaust ventilation, or other engineering controls to control air-borne levels. Where explosive mixtures may be present, equipment safe for such locations should be used. PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY A respiratory protection program which meets USA’s OSHA General PROTECTION: Industry Standard 29 CFR 1910.134 or Canada’s CSA Standard Z94.4-M1982 requirements must be followed whenever workplace conditions warrant a respirator’s use. Consult a qualified Industrial Hygienist or Safety Professional for respirator selection guidance. EYE PROTECTION: Wearing chemical goggles is recommended. Contact lens may be worn with eye protection. SKIN PROTECTION: Where prolonged or repeated skin contact is likely, wear neoprene, nitrile (4 mil minimum), PVC (polyvinyl chloride), or equivalent protective gloves; wearing natural rubber or equivalent gloves is not recommended. When product is heated and skin contact is likely, wear heat-insulating gloves, boots, and other protective clothing. To avoid prolonged or repeated contact with product where spills and splashes are likely, wear appropriate chemical-resistant faceshield, boots, apron, whole body suits, or other protective clothing. Revision 9/13; MSDS Form No. 81451 - Page 6 of 10 USED OIL MATERIAL SAFETY DATA SHEET PERSONAL HYGIENE: Wash thoroughly with soap and water after handling product and before eating, drinking, or using tobacco products. Clean affected clothing, shoes, and protective equipment before reuse. Discard affected clothing, shoes, and/or protective equipment if they cannot be thoroughly cleaned. Discard leather articles, such as shoes, saturated with the product. OTHER PROTECTIVE EQUIPMENT: Where spills and splashes are likely, facilities storing or using this product should be equipped with an emergency eyewash and shower, both equipped with clean water, in the immediate work area. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE, APPEARANCE, AND ODOR: Liquid, black and viscous (thick), petroleum odor. ODOR THRESHOLD: Not available. MOLECULAR WEIGHT: Not applicable. SPECIFIC GRAVITY: 0.8 to 1.0 at 60°F (15.6°C) (water = 1) DENSITY: 6.7 to 8.3 LB/US gal (800 to 1000 g/l) (approximately) VAPOR DENSITY: greater than 1 (air = 1) (based on kerosene) VAPOR PRESSURE: Not available. BOILING POINT: Not available. FREEZING/MELTING POINT: Not available. pH: Not applicable. EVAPORATION RATE: less than 1 (butyl acetate = 1) SOLUBILITY IN WATER: Slight. FLASH POINT: >200°F (93°C) (minimum) Pensky-Martens Closed Cup FLAMMABLE LIMITS IN AIR: Not available. AUTOIGNITION TEMPERATURE: Not available. Revision 9/13; MSDS Form No. 81451 - Page 7 of 10 USED OIL MATERIAL SAFETY DATA SHEET SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable under normal temperatures and pressures. Avoid heat, sparks, or flame. INCOMPATIBILITY: Avoid acids, alkalies, oxidizing agents, reducing agents, reactive halogens, or reactive metals. REACTIVITY: Polymerization is not known to occur under normal temperatures and pressures. Not reactive with water. HAZARDOUS DECOMPOSITION PRODUCTS: None under normal temperatures and pressures. Also see SECTION 5: HAZARDOUS COMBUSTION PRODUCTS. SECTION 11: TOXICOLOGICAL INFORMATION SENSITIZATION: Based on best current information, there may be known human sensitization associated with this product. MUTAGENICITY: Based on best current information, there may be mutagenicity associated with this product. CARCINOGENICITY: Mineral oils, untreated or mildly treated are listed by IARC as a known carcinogen. Mineral oils, untreated or mildly treated are classified by NTP as having limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals. There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are listed by OSHA as known carcinogens. There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are listed by IARC as known, probable, or possible carcinogens. There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are classified by NTP as known carcinogens or as having limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals. There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are recognized by ACGIH as confirmed or suspected human carcinogens. Also see SECTION 3: CANCER INFORMATION. Revision 9/13; MSDS Form No. 81451 - Page 8 of 10 USED OIL MATERIAL SAFETY DATA SHEET REPRODUCTIVE TOXICITY: Based on best current information, there may be reproductive toxicity associated with this product. TERATOGENICITY: Based on best current information, there may be teratogenicity associated with this product. TOXICOLOGICALLY SYNERGISTIC Based on best current information, there may be toxicologically PRODUCT(S): synergistic products associated with this product. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICITY: Not available. OCTANOL/WATER PARTITION COEFFICIENT: Not available. VOLATILE ORGANIC COMPOUNDS: Not available. As per 40 CFR Part 51.100(s). SECTION 13: DISPOSAL CONSIDERATIONS Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also apply to empty containers. The responsibility for proper waste disposal lies with the owner of the waste. Contact Safety-Kleen regarding proper recycling or disposal. SECTION 14: TRANSPORT INFORMATION DOT: Not regulated. TDG: Not regulated. EMERGENCY RESPONSE Not applicable. GUIDE NUMBER: Reference North American Emergency Response Guidebook SECTION 15: REGULATORY INFORMATION USA REGULATIONS Based on the ingredient(s) listed in SECTION 2, this product does not SARA SECTIONS contain any "extremely hazardous substances" listed pursuant to Title III 302 AND 304: of the Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified in 40 CFR Part 355, Appendix A and B. Revision 9/13; MSDS Form No. 81451 - Page 9 of 10 USED OIL MATERIAL SAFETY DATA SHEET SARA SECTIONS 311 AND 312: This product poses the following physical and health hazards as defined in 40 CFR Part 370 and is subject to the requirements of sections 311 and 312 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard SARA SECTION 313: This product may contain "toxic" chemicals subject to the requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372. CERCLA: This product may contain “hazardous substances” listed pursuant to Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4. TSCA: Not available. CALIFORNIA: This product is not for sale or use in the State of California. CANADIAN REGULATIONS WHMIS: Not regulated CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): Not available. SECTION 16: OTHER INFORMATION REVISION INFORMATION: Regulatory review. Update to Section 1. LABEL/OTHER INFORMATION: Not available. User assumes all risks incident to the use of this product. To the best of our knowledge, the information contained herein is accurate. However, Safety-Kleen assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representations or warranties, either express or implied, of merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the product to which information refers. The data contained on this sheet apply to the product as supplied to the user. Revision 9/13; MSDS Form No. 81451 - Page 10 of 10 MATERIAL SAFETY DATA SHEET HMIS RATINGS: HEALTH:1, FLAMMABITY:0, REACTIVITY:0 Identity: Uvex Clear Lens Cleaner - # S461, S463, S464, S467 Section I Manufacturer: Uvex Safety, Inc. Address: 900 Douglas Pike Smithfield, RI 02917 Emergency Telephone: 401-232-1200 Information Telephone: 800-343-3411 Date Prepared: 04/23/12 Section II - Hazardous Ingredients/Identity Information Hazardous Components (Specific Chemical Identity; Common Name(s)) Ethylene Glycol Mono Butyl Ether #111-76-2 OSHA PEL 1 ACGIH TLV 1 25 PPM TWA (SKIN) 25 PPM TWA (SKIN) Other limits % (optional) recommended N/A <6% Section III - Physical/Chemical Characteristics Boiling Point: 212° F (100° C) Specific Gravity (H2O=1): 0.98 at 77° F (25° C) Melting Point: N/A Vapor Pressure (mm Hg.): 22 mm Hg at 70° F (20° C) Vapor Density (Air = 1) : NOT DETERMINED Evaporation Rate (Butyl Acetate = 1): < 1 Solubility in Water: 100% Appearance and Odor: CLEAR TINTED LIQUID WITH A SLIGHT ODOR. Section IV - Fire and Explosion Hazard Data LEL: N/A UEL: N/A Flammable Limits: NOT FLAMMABLE UNDER NORMAL CONDITIONS OF STORAGE & USE. Extinguishing Media: 1. WATER FOG OR SPRAY, 2. CARBON DIOXIDE (CO2), 3. DRY CHEMICAL, 4. CLASS B EXTINGUISHERS Special Fire Fighting Procedures: KEEP FIRE EXPOSED CONTAINERS COOL. WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL PROTECTIVE EQUIPMENT. Unusual Fire and Explosion Hazards: N/A Flash Point (Method Used): >212°F Section V - Reactivity Data Stability Unstable: NO Conditions to Avoid: DO NOT FREEZE, STORE IN COOL AREA. AVOID IGNITION SOURCES. Stable: YES Incompatibility (Materials to Avoid): STRONG ACIDS, ALKALIES, AND OXIDIZERS. Hazardous Decomposition or Byproducts: NONE Hazardous May Occur: NO Conditions to Avoid: NONE Polymerization Will Not Occur: YES Section VI - Health Hazard Data Route(s) of Entry: Inhalation? YES Skin? NO Ingestion? YES Health Hazards (Acute and Chronic): . EYE CONTACT: IN SOME CASES EYE IRRITATION MAY OCCUR. IMMEDIATELY FLUSH WITH A WATER OR EYEWASH SOLUTION AND CONSULT A PHYSICIAN. IN SOME CASES SKIN CONTACT MAY CAUSE IRRITATION, IMMEDIATELY FLUSH WITH SOAP AND WATER, REMOVE CONTAMINATED CLOTHING AND CONSULT A PHYSICIAN. INGESTION: GASTRIC IRRITATION AND VOMITING. DO NOT INDUCE VOMITING, GIVE PLENTY OF WATER AND CONSULT A PHYSICIAN. PREVENT ASPIRATION OF VOMITED MATERIAL INDUCED BY INGESTION OF PRODUCT. Carcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO Signs and Symptoms of Exposure: EYE, SKIN OR GASTRIC IRRITATION, NAUSEA, DIZZINESS, HEADACHE. Medical Conditions Generally Aggravated by Exposure: NONE KNOWN Emergency First Aid Procedures: SEEK MEDICAL ATTENTION IF LARGE QUANTITIES ARE SWALLOWED. WASH EXPOSED SKIN THOROUGHLY WITH SOAP & WATER. FLUSH EXPOSED EYES WITH WATER OR EYEWASH SOLUTION FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IN ALL CASES. Section VII - Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Released or Spilled: IN CASE OF LARGE SPILLS WEAR PROTECTIVE CLOTHING, NEOPRENE GLOVES AND CHEMICAL SPLASH GOGGLES. Waste Disposal Method: ABSORB WITH SAND OR INERT MATERIAL. THEN REMOVE AND A DISPOSE OF ABSORBED MATERIAL IN AN APPROPRIATE MANNER. Precautions to Be Taken in Handling and Storing: AVOID SKIN & EYE CONTACT. AVOID INHALATION AND INGESTION. WEAR PROTECTIVE CLOTHING, GLOVES AND SAFETY GLASSES WHEN A LARGE SPILL OR SPLASH HAZARD EXISTS. HANDLE AND STORE IN A WELL-VENTILATED AND COOL AREA. Other Precautions: DO NOT FREEZE. STORE IN A COOL, WELL-VENTILATED AREA. Section VIII - Control Measures Ventilation Local Exhaust: GENERAL AIR CIRCULATION SUFFICIENT FOR NORMAL PRODUCT USE. Special: N/A Mechanical: ADEQUATE VENTILATION Other: N/A Protective Gloves: NONE REQUIRED FOR NORMAL PRODUCT USE. Eye Protection: NONE REQUIRED FOR NORMAL PRODUCT USE. 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ate Revised: JUN 2013 XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe Supersedes: JAN 2012 SECTION I - PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe PRODUCT USE: Low VOC Solvent Cement for PVC Plastic Pipe SUPPLIER: IPEX Inc. 807 Pharmacy Avenue Scarborough, Ontario M1L 3K2, CAN MANUFACTURER: EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) IPS Corporation 17109 South Main Street, Gardena, CA 90248-3127 P.O. Box 379, Gardena, CA 90247-0379 Tel. 1-310-898-3300 Medical: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) SECTION 2 - HAZARDS IDENTIFICATION GHS CLASSIFICATION: Health Acute Toxicity: Category 4 Skin Irritation: Category 3 Skin Sensitization: NO Eye: Category 2B Acute Toxicity: Chronic Toxicity: Environmental None Known None Known GHS LABEL: Physical Flammable Liquid Signal Word: Danger OR WHMIS CLASSIFICATION: Hazard Statements Category 2 CLASS B, DIVISION 2 Precautionary Statements H225: Highly flammable liquid and vapor P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking H319: Causes serious eye irritation P261: Avoid breathing dust/fume/gas/mist/vapors/spray H332: Harmful if inhaled P280: Wear protective gloves/protective clothing/eye protection/face protection H335: May cause respiratory irritation P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing H336: May cause drowsiness or dizziness P403+P233: Store in a well ventilated place. Keep container tightly closed EUH019: May form explosive peroxides P501: Dispose of contents/container in accordance with local regulation SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS CAS# Tetrahydrofuran (THF) Methyl Ethyl Ketone (MEK) Cyclohexanone EINECS # 109-99-9 78-93-3 108-94-1 203-726-8 201-159-0 203-631-1 REACH Pre-registration Number CONCENTRATION % by Weight 05-2116297729-22-0000 05-2116297728-24-0000 05-2116297718-25-0000 25 - 50 5 - 36 15 - 30 All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing. * Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372). # indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity. SECTION 4 - FIRST AID MEASURES Contact with eyes: Skin contact: Inhalation: Ingestion: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice. Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice. Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately. SECTION 5 - FIREFIGHTING MEASURES Suitable Extinguishing Media: Unsuitable Extinguishing Media: Exposure Hazards: Combustion Products: Protection for Firefighters: Dry chemical powder, carbon dioxide gas, foam, Halon, water fog. Water spray or stream. Inhalation and dermal contact Oxides of carbon, hydrogen chloride and smoke Health Flammability Reactivity PPE Self-contained breathing apparatus or full-face positive pressure airline masks. HMIS 2 3 0 B NFPA 2 3 0 0-Minimal 1-Slight 2-Moderate 3-Serious 4-Severe SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame. Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment. Prevent contact with skin or eyes (see section 8). Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course. Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel. Materials not to be used for clean up: Aluminum or plastic containers SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing. Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods. Do not eat, drink or smoke while handling. Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight. Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates. Follow all precautionary information on container label, product bulletins and solvent cementing literature. SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION EXPOSURE LIMITS: Component Tetrahydrofuran (THF) Methyl Ethyl Ketone (MEK) Cyclohexanone ACGIH TLV ACGIH STEL OSHA PEL 50 ppm 200 ppm 20 ppm 100 ppm 300 ppm 50 ppm 200 ppm 200 ppm 50 ppm OSHA STEL: Engineering Controls: Use local exhaust as needed. Monitoring: Maintain breathing zone airborne concentrations below exposure limits. Personal Protective Equipment (PPE): Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields, etc. as may be appropriate for the exposure. Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion. Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application practices and procedures are used for making structural bonds. Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use local exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above. With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment. Filename: XIRTEC 5 GRY_LoVoc 6-13.xls Page 1 of 2 6/12/2013 9:34 AM GHS SAFETY DATA SHEET IPEX Date Revised: JUN 2013 XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe Supersedes: JAN 2012 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Gray, medium syrupy liquid Odor: Ketone Odor Threshold: 0.88 ppm (Cyclohexanone) pH: Not Applicable Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 66°C (151°F) to 156°C (313°F) Boiling Point: 66°C (151°F) Based on first boiling component: THF Evaporation Rate: > 1.0 (BUAC = 1) Flash Point: -20°C (-4°F) TCC based on THF Flammability: Category 2 LEL: 1.1% based on Cyclohexanone Specific Gravity: 0.9611 @23°C ( 73°F) Flammability Limits: UEL: 11.8% based on THF Solubility: Solvent portion soluble in water. Resin portion separates out. Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 129 mm Hg @ 20°C (68°F)based on THF Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2 (Air = 1) Decomposition Temperature: Not Applicable Other Data: Viscosity: Medium bodied When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l. VOC Content: SECTION 10 - STABILITY AND REACTIVITY Stability: Hazardous decomposition products: Conditions to avoid: Incompatible Materials: Stable None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke. Keep away from heat, sparks, open flame and other ignition sources. Oxidizers, strong acids and bases, amines, ammonia SECTION 11 - TOXICOLOGICAL INFORMATION Likely Routes of Exposure: Inhalation, Eye and Skin Contact Acute symptoms and effects: Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages. Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid. Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact. Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness. Chronic (long-term) effects: None known to humans LD50 LC50 Toxicity: Inhalation 3 hrs. 21,000 mg/m3 (rat) Tetrahydrofuran (THF) Oral: 2842 mg/kg (rat) Inhalation 8 hrs. 23,500 mg/m3 (rat) Methyl Ethyl Ketone (MEK) Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit) Cyclohexanone Oral: 1535 mg/kg (rat), Dermal: 948 mg/kg (rabbit) Inhalation 4 hrs. 8,000 PPM (rat) Reproductive Effects Not Established Teratogenicity Not Established Mutagenicity Not Established Embryotoxicity Not Established Sensitization to Product Not Established Synergistic Products Not Established SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: Mobility: Degradability: Bioaccumulation: None Known In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l. Biodegradable Minimal to none. SECTION 13 - WASTE DISPOSAL CONSIDERATIONS Follow local and national regulations. Consult disposal expert. SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Hazard Class: Secondary Risk: Identification Number: Packing Group: Label Required: Marine Pollutant: Adhesives 3 EXCEPTION for Ground Shipping DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package. None Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" . UN 1133 PG II Class 3 Flammable Liquid TDG INFORMATION NO TDG CLASS: FLAMMABLE LIQUID 3 SHIPPING NAME: ADHESIVES UN NUMBER/PACKING GROUP: UN 1133, PG II SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Symbols: F, Xi Risk Phrases: R11: Highly flammable. Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia AICS, Korea ECL/TCCL, Japan MITI (ENCS) R20: Harmful by inhalation. R36/37: Irritating to eyes and respiratory system. Safety Phrases: S9: Keep container in a well-ventilated place. S16: Keep away from sources of ignition - No smoking. S25: Avoid contact with eyes. R66: Repeated exposure may cause skin dryness or cracking R67: Vapors may cause drowsiness and dizziness S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33: Take precautionary measures against static discharges. S46: If swallowed, seek medical advise immediately and show this container or label. SECTION 16 - OTHER INFORMATION Specification Information: Department issuing data sheet: Safety Health & Environmental Affairs Training necessary: Reissue date / reason for reissue: Intended Use of Product: Yes, training in practices and procedures contained in product literature. 6/12/2013 / Updated GHS Standard Format Solvent Cement for PVC Plastic Pipe All ingredients are compliant with the requirements of the European Directive on RoHS (Restriction of Hazardous Substances). This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Filename: XIRTEC 5 GRY_LoVoc 6-13.xls Page 2 of 2 6/12/2013 9:34 AM Product Name: XYLENE Revision Date: 26 Feb 2013 Page 1 of 11 ______________________________________________________________________________________________________________________ MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT Product Name: XYLENE Product Description: Aromatic Hydrocarbon MSDS Number: 4562 Intended Use: Chemical feedstock, Solvent COMPANY IDENTIFICATION Supplier: IMPERIAL OIL CHEMICALS DIVISION 240 4th Avenue S.W. CALGARY, ALBERTA. T2P 3M9 Canada 24 Hour Environmental / Health Emergency 1-866-232-9563 Telephone Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-663-4109 SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Mixed Xylenes 1330-20-7 Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# ETHYL BENZENE 100-41-4 Concentration* 100 % Concentration* 10 - 20% Acute Toxicity Oral Lethality: LD50 > 5000 mg/kg (Rat) Acute Toxicity Inhalation Lethality: LC50 17.8 mg/l (Rat); Oral Lethality: LD50 3.5 g/kg (Rat) * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS FLAMMABLE. In use, may form flammable/explosive vapour-air mixture. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition. HEALTH EFFECTS Irritating to skin. May cause cancer. May cause harm to the unborn child. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. Target Organs: Skin | Product Name: XYLENE Revision Date: 26 Feb 2013 Page 2 of 11 ______________________________________________________________________________________________________________________ NFPA Hazard ID: HMIS Hazard ID: Health: Health: 2 2* Flammability: 3 Flammability: 3 Reactivity: 0 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. SKIN CONTACT Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. EYE CONTACT Flush thoroughly with water for at least 15 minutes. Get medical assistance. INGESTION Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided. SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water FIRE FIGHTING Fire Fighting Instructions: FLAMMABLE. Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Product Name: XYLENE Revision Date: 26 Feb 2013 Page 3 of 11 ______________________________________________________________________________________________________________________ Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIES Flash Point [Method]: >23°C (73°F) [ASTM D-56] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 432°C (810°F) - 528°C (982°F) [Technical literature] SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapoursuppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken. ENVIRONMENTAL PRECAUTIONS Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas. SECTION 7 HANDLING AND STORAGE HANDLING Avoid contact with skin. Avoid contact with eyes. Prevent exposure to ignition sources, for example use non- Product Name: XYLENE Revision Date: 26 Feb 2013 Page 4 of 11 ______________________________________________________________________________________________________________________ sparking tools and explosion-proof equipment. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Loading/Unloading Temperature: [Ambient] Transport Temperature: [Ambient] Transport Pressure: [Ambient] Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid. STORAGE Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, wellventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge. Storage Temperature: [Ambient] Storage Pressure: [Ambient] Suitable Containers/Packing: Tankers; Drums; Tank Trucks; Barges; Tank Cars Suitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Polyester; Stainless Steel; Teflon Unsuitable Materials and Coatings: Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene monomer (EPDM); Polystyrene; Polyethylene; Polypropylene; PVC; Polyvinyl Alcohol; Polyacrylonitrile; Compatibility with plastics will vary SECTION 8 Substance Name ETHYL BENZENE Mixed Xylenes Mixed Xylenes Mixed Xylenes EXPOSURE CONTROLS / PERSONAL PROTECTION Form Vapour. Limit/Standard TWA 20 ppm RCP 434 mg/m3 100 ppm TWA STEL TWA 150 ppm 100 ppm NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS Note Total Hydrocarbon s Source ACGIH Supplier ACGIH ACGIH Product Name: XYLENE Revision Date: 26 Feb 2013 Page 5 of 11 ______________________________________________________________________________________________________________________ The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider: Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosionproof ventilation equipment. PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include: Half-face filter respirator For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include: Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include: Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping. ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION Physical State: Liquid Form: Clear Product Name: XYLENE Revision Date: 26 Feb 2013 Page 6 of 11 ______________________________________________________________________________________________________________________ Colour: Colourless Odour: Aromatic Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION Relative Density (at 15 °C): 0.869 [Technical literature] Density (at 15 ºC): 870 kg/m³ (7.26 lbs/gal, 0.87 kg/dm³) [ISO 12185] Flash Point [Method]: >23°C (73°F) [ASTM D-56] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 432°C (810°F) - 528°C (982°F) [Technical literature] Boiling Point / Range: 136°C (277°F) - 145°C (292°F) [Technical literature] Vapour Density (Air = 1): < 1 at 101 kPa [Technical literature] Vapour Pressure: 0.8 kPa (6 mm Hg) at 20ºC [Calculated] Evaporation Rate (n-butyl acetate = 1): 0.85 [In-house method] pH: N/D Log Pow (n-Octanol/Water Partition Coefficient): 3.12 - 3.16 [Technical literature] Solubility in Water: Negligible Viscosity: [N/D at 40 °C] | 0.79 cSt (0.79 mm2/sec) at 20°C [ASTM D7042] Oxidizing Properties: See Hazards Identification Section. OTHER INFORMATION Freezing Point: -54°C (-65°F) [Technical literature] Melting Point: -39°C (-39°F) [Technical literature] Pour Point: -95°C (-139°F) - 13°C (56°F) [Technical literature] Molecular Weight: 106 G/MOLE [Calculated] Hygroscopic: No Coefficient of Thermal Expansion: 0.00105 V/V/DEG C [Calculated] [In-house method] Decomposition Temperature: N/D SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 ACUTE TOXICITY Route of Exposure Inhalation Toxicity (Rat): LC50 > 20 mg/l Irritation: No end point data for material. Ingestion TOXICOLOGICAL INFORMATION Conclusion / Remarks Minimally Toxic. Based on test data for the material. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Product Name: XYLENE Revision Date: 26 Feb 2013 Page 7 of 11 ______________________________________________________________________________________________________________________ Toxicity (Rat): LD50 > 3523 mg/kg Minimally Toxic. Based on test data for the material. Skin Toxicity (Rabbit): LD50 > 4200 mg/kg Irritation: Data available. Minimally Toxic. Based on test data for the material. Irritating to the skin. Based on test data for the material. Eye Irritation: Data available. Moderately irritating to the eyes. Based on test data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself: Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits), and to heart-stimulating substances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may initiate arrhythmias. Contains: ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is uncertain. XYLENES: High exposures to xylenes in some animal studies have been reported to cause health effects on the developing embryo/fetus. These effects were often at levels toxic to the mother. The significance of these findings to humans has not been determined. CMR Status: Chemical Name ETHYL BENZENE Mixed Xylenes 1 = IARC 1 2 = IARC 2A CAS Number 100-41-4 1330-20-7 List Citations 3, 4 4 --REGULATORY LISTS SEARCHED-3 = IARC 2B 5 = ACGIH A1 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be toxic to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms. MOBILITY Material -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Product Name: XYLENE Revision Date: 26 Feb 2013 Page 8 of 11 ______________________________________________________________________________________________________________________ Material -- Expected to be readily biodegradable. Hydrolysis: Material -- Transformation due to hydrolysis not expected to be significant. Photolysis: Material -- Transformation due to photolysis not expected to be significant. Atmospheric Oxidation: Material -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Material -- Potential to bioaccumulate is low. OTHER ECOLOGICAL INFORMATION VOC (EPA Method 24): 7.252 lbs/gal SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. SECTION 14 TRANSPORT INFORMATION LAND (TDG) Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene) Hazard Class & Division: 3 UN Number: 1993 Packing Group: III Special Provisions: 16 LAND (DOT) Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene ) Hazard Class & Division: 3 ID Number: 1993 Packing Group: III Product RQ: 100 LBS - Mixed Xylenes ERG Number: 128 Product Name: XYLENE Revision Date: 26 Feb 2013 Page 9 of 11 ______________________________________________________________________________________________________________________ Label(s): 3 Transport Document Name: UN1993, FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene), 3, PG III SEA (IMDG) Proper Shipping Name: XYLENES Hazard Class & Division: 3 EMS Number: F-E, S-D UN Number: 1307 Packing Group: III Label(s): 3 Transport Document Name: UN1307, XYLENES, 3, PG III, (>23°C c.c.) AIR (IATA) Proper Shipping Name: XYLENES Hazard Class & Division: 3 UN Number: 1307 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name: UN1307, XYLENES, 3, PG III SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name ETHYL BENZENE Mixed Xylenes CAS Number 100-41-4 1330-20-7 1 = TSCA 4 2 = TSCA 5a2 --REGULATORY LISTS SEARCHED-3 = TSCA 5e 5 = TSCA 12b 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable List Citations 6 6 Product Name: XYLENE Revision Date: 26 Feb 2013 Page 10 of 11 ______________________________________________________________________________________________________________________ THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Protective Measures was modified. Section 09: Boiling Point C(F) was modified. Section 09: Pour Point C(F) was modified. Section 09: Density - Header was modified. Section 09: Density kg/m3(lbs/gal) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapour Pressure was modified. Section 11: Inhalation Irritation Test Data was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Autoignition Temperature was modified. Section 09 Viscosity was modified. Section 09 Viscosity was modified. Section 14: Transport Document Name was modified. Section 15: National Chemical Inventory Listing was modified. Section 11: Additional Health Information was modified. Section 16: MSN,MAT ID was modified. Section 09: Freezing Point ºC(ºF) was modified. Section 09: Melting Point C(F) was modified. Composition: Component table was modified. Composition: Component table was modified. Section 08: Exposure Limits Table was modified. Section 15: Canadian List Citations Table was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. Section 16: CA Contains was added. Section 16: CA Contains - Header was added. ------------------------------------------------------------------------------------------------------------------- ---------------------------------PRECAUTIONARY LABEL TEXT: Contains: Mixed Xylenes WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS Irritating to skin. May cause cancer. May cause harm to the unborn child. If swallowed, may be aspirated and cause lung damage. Target Organs: Skin | PHYSICAL HAZARDS In use, may form flammable/explosive vapour-air mixture. Material can accumulate static charges which may cause an ignition. FLAMMABLE. PRECAUTIONS Avoid contact with skin. Avoid contact with eyes. Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. Product Name: XYLENE Revision Date: 26 Feb 2013 Page 11 of 11 ______________________________________________________________________________________________________________________ FIRST AID Eye: Flush thoroughly with water for at least 15 minutes. Get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. Report spills as required to appropriate authorities. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. ----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------- -----------------------DGN: 5004671 (1020902) ----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, Solvents

Sheet Metal Msds Safety

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