Viskoflex Vmc_090_gb_reach

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VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 1 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 SECTION 1 – PRODUCT AND COMPANY IDENTIFICATION Trade name: Viskoflex VMC 090 (Ink thinner for REA-JET SC – Viscosity control – for all REA-JET SC’s with TMC ink Product use: Thinner Company: REA Elektronik GmbH Teichwiesenstrasse 1 D-64367 Mühltal-Waschenbach Phone: +49 (0) 6154 638-0 Fax: +49 (0) 6154 638-195 Emergency Telephone: +49 (0) 6131 - 19240 Giftinfo Mainz Klinische Toxikologie der II. Medizinischen Klinik der Johannes Gutenberg Universität Mainz Langenbeckstrasse 1 D - 55131 Mainz - Germany SECTION 2 – HAZARDS IDENTIFICATION − Hazard designation: Xi Irritant F Highly flammable − Information pertaining to particular dangers for man and environment R 11 Highly flammable. R 36 Irritating to eyes. R 66 Repeated exposure may cause skin dryness or cracking. R 67 Vapours may cause drowsiness and dizziness. SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTS − Chemical characterization: Content: 99 % − CAS No. Designation: 78-93-3 2-Butanon 2-Butanon (Methylethylketon, MEK) CH3COC2H5 − Identification no(s): − EINECS no.: 201-159-0 − Index number: 606-002-00-3 SECTION 4 – FIRST AID MEASURES − General advice: Instantly remove any clothing soiled by the product. Take affected persons into the open air. − After inhalation: The affected person to be taken out of the danger zone taking suitable protective measures. If the breathing is irregular or respiratory stand still has occurred, artificial respiration to be made. Person affected to be immobilized and immediately medical care ensured. − After skin contact: Remove contaminated clothing immediately. Wash afected areas with plenty of water und soap. If irritation continues, contact a doctor. − After eye contact: Rinse immediately opened eye for several minutes under running water. Then consult doctor. VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 2 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 − After swallowing: No vomiting to release. Ensure plenty of water with activated carbon to redrink. A doctor to consult immediately. − Information for doctor: Dermatitis may result from prolonged or repeated exposure. Causes central nervous system depression. Symptomatic treatment. Ensure water with activated carbon to drink. The greasy film of the skin to recover to prevent from dermatitis (skin inflammation). − The following symptoms may occur: Irritant effect to skin, eyes and respiratory organs; headaches; nausea; dizziness feeling; imbalances; anesthesia; unconsciousness. SECTION 5 – FIRE FIGHTING MEASURES − − − − − Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. For safety reasons unsuitable extinguishing agents Water with a full water jet. Special hazards caused by the material, its products of combustion or flue gases: Can form explosive gas-air mixtures. In case of incomplete combustion carbon monoxide can arise. Fumes are heavier than air and distributed over ground. Inflammation is possible from a far distance. Protective equipment: Wear self-contained breathing apparatus. Wear full protective suit. Additional information Endangered containers in the surrounding area should be cooled with a water-hose. Collect contaminated fire fighting water separately. It must not enter drains. temperature class: T 1 (DIN 57165) explosion class: I A (DIN 57165) fire class: B SECTION 6 – ACCIDENTAL RELEASE MEASURES − Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Extinguish naked flames. Remove flammable sources. No smoking. Avoid sparks. Avoid contact with skin, eyes and clothing. Avoid inhalation of fumes. Air contaminated rooms thoroughly. Protect against electrostatic sparks. − Measures for environmental protection: Prevent material from reaching sewage system, holes and cellars. If large amounts are released, the authorities must be informed. Kontamination von Wasser und Boden verhindern. − Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. Dispose of contaminated material as waste according to item 13. SECTION 7 – HANDLING AND STORAGE − − Handling Information for safe handling: Store in cool, dry place in tightly closed containers. Ensure good ventilation/exhaustion at the workplace. Avoid repeated or long-term skin contact. VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 3 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 − Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. − Storage Protect against direct sunlight, other heat sources and flammable sources. − Requirements to be met by storerooms and containers: Suitable material for interior lining: zinc silicate. Observe official regulations on storage and handling of water hazardous substances − Information about storage in one common storage facility: According to guidelines of the VbF, flammable liquids should not be stored together. − Further information about storage conditions: Attention should be paid to the guidelines of the VbF and the related technical regulations of the TRbF − Storage class 3 (VCI - Konzept, 2007) SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION - Components with critical values that require monitoring at the workplace: 78-93-3 butanone (50-100%) WEL Short-term value: 899 mg/m³, 300 ppm ³ Long-term value: 600 mg/m , 200 ppm Sk − Additional information: The lists that were valid during the compilation were used as basis. − Personal protective equipment − General protective and hygienic measures Keep away from food, beverages and fodder. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Gases, fumes and aerosols should not be inhaled. − Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Short term: filter A2 − Protection of hands: Solvent resistant gloves − Material of gloves Butyl rubber, BR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. − Penetration time of glove material Material of gloves is recommended for a short-term single use to protect from splashes. For permanent usage contact manufacturer of gloves. - Eye protection: Tightly sealed safety glasses. − Body protection: Standard protective working clothes, chemical resistant safety-shoes or wellingtons. If skin contact is possible, wear impenetrable protective clothing. VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 4 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES − General Information Form: Colour: Smell: Fluid Colourless Characteristic - Change in condition Melting point/Melting range: Boiling point/Boiling range: -86°C 79-80. 5°C (DIN 53171) - Flash point: -4°C (DIN 51748) - Ignition temperature: 514°C (DIN 51794) - Danger of explosion: Product is not explosive. However, formation of explosive air/steam mixtures is possible. - Critical values for explosion: Lower: Upper: 1.8 Vol % 11.5 Vol % - Vapour pressure at 20°C: 89 mbar - Density at 20°C 0.804-0.807 g/cm3 (DIN 51757) - Solubility in / Miscibility with Water at 20°C: 250 g/l - pH-value: not applicable - Segregation coeficient (n-octanol/water): 1.8-2.0 log POW - Viscosity: dynamic at 20°C: - Additional information - molecular weight (weight average/Mw): 0.40 mPas (DIN 5301 5) Evaporation number: 3,3 (ether = 1) DIN 53170 72,12 g/mol SECTION 10 – STABILITY AND REACTIVITY − Thermal decomposition / conditions to be avoided: Can be distilled without decomposing at normal pressure − Materials to be avoided: strong oxidizing agents strong bases Strong acids − Dangerous reactions Reacts with oxidizing agents Development of peroxides VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 5 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 − Dangerous products of decomposition: Formation of carbon monoxide and carbon dioxide in case of fire. If vapours heat up over 300°C., peroxides and "cold flames" are produced SECTION 11 – TOXICOLOGICAL INFORMATION Acute toxicity: - LD/LC50 values that are relevant for classification: Oral LD50 3300 mg/kg (rat) Dermal LD50 5000 mg/kg (rbt) Inhalative LC50/4 h 12000 mg/l (rat) − Primary irritant efect: − on the skin: Prolonged/repeated skin contact may cause defatting, dryness and other skin complaints and inflammations (dermatitis). no irritant effect − on the eye: Irritant effect. − Sensitization: No sensitizing effect known. − Subacute to chronic toxicity: Can lead to liverdamage − Additional toxicological information: High exposures can cause drowsiness and dizziness. Respiratory and eye irritant. Prolonged/repeated contact may cause defatting of the skin which can lead to dermatitis SECTION 12 – ECOLOGICAL INFORMATION - Information about elimination (persistence and degradability − Biodegrability: BOD 5 (20 °C): 83 % of ThOD (not adapt) BOD 20 (20 °C): 89 % of ThOD (not adapt) − Behaviour in environmental systems: − Mobility and bioaccumulation potential: No bioaccumulation − Ecotoxical efects: − Aquatic toxicity: − Type of test Efective concentration Method Assessment − orfe 4600 mg/l LC50 (96 h) goldfish > 5000 mg/l LC50 (24 h) daphnia magna 8900 mg/l LC50 (48 h) green algea 4300 mg/l (8 d) no efect bacterial (Pseudomonas putida) 11 50 mg/l − General notes: Do not allow to enter drainage system, surface or ground water. Water hazard class 1 (Assessment by list): slightly hazardous for water. (16 h) no effect VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 6 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 SECTION 13 – DISPOSAL CONSIDERATIONS − Product: The following advice is related to new material and not to any processed products. In case of a mixture with other products other disposal methods may become necessary. If in doubt seek advice from product supplier or from local authorities. − Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. A special treatment to perform in line with the local administrative regulations. − Waste disposal key number: Since 01/01/99 the waste code numbers have not only been product-related but are also essentially application related. The valid waste code number of the application can be obtained from the European waste catalogue. 553 01 Acetone and other aliphatic ketones − Uncleaned packagings: Disposal must be made according to official regulations. − Recommendation: Rented packaging: After optimal emptying, close immediately and return to the supplier without cleaning. Care should be taken that no other materials get into the packaging. Other containers: After complete emptying and cleaning, send to be reconditioned or recycled. Caution: Leftovers in the containers may cause the risk of explosion. Uncleaned containers should not be perforated, cut or welded. SECTION 14 – TRANSPORT INFORMATION Land transport ADR/RID and GGVSEB/GGVE (cross-border/domestic): UN-Number: 1263 ADR/RID-GGVS/E Class: 3 Classification code: F1 (Flammable liquids) Kemler Number: 33 Packing group: II Label: 3 Transport Category: 2 Limited quantity: LQ6 (5L) Proper Shipping Name: : Paint related material UN 1263 Special instructions: 163 / 640D/ 650 Tunnel restriction code: D/E Maritime transport IMDG/GGVSea: UN Number: IMDG/GGVSea Class: Label Packing group: EmS Number: Marine pollutant: Limited quantity: Proper Shipping Name: Special instructions: 1263 3 3 II F-E, S-E no 5L Paint related material 163 VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 7 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 Air transport ICAO-TI and IATA-DGR: UN Number: ICAO/IATA Class: Label Packing group: IATA Limited quantity – Passenger Aircraft: IATA Packing instructions – Passenger Aircraft: IATA max. quantity – Passenger Aircraft: IATA Packing instructions – Passenger Aircraft: IATA max. quantity – Cargo Aircraft: IATA Packing instructions – Cargo Aircraft: Proper Shipping Name: Special instructions: 1263 3 3 II 1L Y305 5L 305 60L 307 Paint related material UN 1263 A72 SECTION 15 – REGULATORY INFORMATION − Designation according to EC guidelines: The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStofV) − Code letter and hazard designation of product: Xi Irritant F Highly flammable − Hazard-determining components of labelling: butanone − Risk phrases: 11 Highly flammable. 36 Irritating to eyes. 66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. − Safety phrases: 2 Keep out of the reach of children. 9 Keep container in a well-ventilated place. 16 Keep away from sources of ignition - No smoking. Labelling Irritant highly flammable − National regulations − Decree to be applied in case of technical fault: Material group 2 (light flammable liquids) mixing-swell to be observed VISKOFLEX VMC 090 (INK THINNER FOR REA SC – VISCOSITY CONTROL - DATE February 2010 PAGE 8 of 8 FOR ALL REA-JET SC’S WITH TMC INK) EC - MATERIAL SAFETY DATA SHEET according to 1907/2006/EC, Article 31 − Technical instructions (air): Class NK Share in % 50 - 100 − Water hazard class: Water hazard class 1 (self assessment according to German VwVwS (Regulations for waterhazardous substances): slightly hazardous for water. SECTION 16 – OTHER INFORMATION The data given here are based on current knowledge and experience. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. − Department issuing data specification sheet: see item 1: Informing department − * Data compared to the previous version altered. To be used only for industrial purposes of application!